CODATA KEY VALUES FOR THERMODYNAMICS Substance Ag Ag Ag+ AgCl Al Al Al+3 AlF3 Al2O3 Ar B B BF3 B2O3 Be Be BeO BrBr Br2 Br2 C C CO CO2 CO2 CO3-2 Ca Ca Ca+2 CaO Cd Cd Cd+2 CdO CdSO4•(8/3)H2O ClCl ClO4Cl2 Cs Cs Cs+ Cu Cu Cu+2 CuSO4 FF F2 Ge Ge GeF4 GeO2 H H+ HBr HCO3HCl HF HI State cr g aq cr cr g aq cr cr, corundum g cr, rhombic g g cr cr g cr aq g l g cr, graphite g g g aq,undissoc. aq cr g aq cr cr g aq cr cr aq g aq g cr g aq cr g aq cr aq g g cr g g cr, tetragonal g aq g aq g g g ∆fHº(298)/ kJ mol-1 0 284.9 ± 0.8 105.79 ± 0.08 -127.01 ± 0.05 0 330.0 ± 4.0 -538.4 ± 1.5 -1510.4 ± 1.3 -1675.7 ± 1.3 0 0 565 ± 5 -1136.0 ± 0.8 -1273.5 ± 1.4 0 324 ± 5 -609.4 ± 2.5 -121.41 ± 0.15 111.87 ± 0.12 0 30.91 ± 0.11 0 716.68 ± 0.45 -110.53 ± 0.17 -393.51 ± 0.13 -413.26 ± 0.20 -675.23 ± 0.25 0 177.8 ± 0.8 -543.0 ± 1.0 -634.92 ± 0.90 0 111.80 ± 0.20 -75.92 ± 0.60 -258.35 ± 0.40 -1729.30 ± 0.80 -167.080 ± 0.10 121.301 ± 0.008 -128.10 ± 0.40 0 0 76.5 ± 1.0 -258.00 ± 0.50 0 337.4 ± 1.2 64.9 ± 1.0 -771.4 ± 1.2 -335.35 ± 0.65 79.38 ± 0.30 0 0 372 ± 3 -1190.20 ± 0.50 -580.0 ± 1.0 217.998 ± 0.006 0 -36.29 ± 0.16 -689.93 ± 0.20 -92.31 ± 0.10 -273.30 ± 0.70 26.50 ± 0.10 Sº(298)/ J mol-1 K-1 42.55 ± 0.20 172.997 ± 0.004 73.45 ± 0.40 96.25 ± 0.20 28.30 ± 0.10 164.554 ± 0.004 -325 ± 10 66.5 ± 0.5 50.92 ± 0.10 154.846 ± 0.003 5.90 ± 0.08 153.436 ± 0.015 254.42 ± 0.20 53.97 ± 0.30 9.50 ± 0.08 136.275 ± 0.003 13.77 ± 0.04 82.55 ± 0.20 175.018 ± 0.004 152.21 ± 0.30 245.468 ± 0.005 5.74 ± 0.10 158.100 ± 0.003 197.660 ± 0.004 213.785 ± 0.010 119.36 ± 0.60 -50.0 ± 1.0 41.59 ± 0.40 154.887 ± 0.004 -56.2 ± 1.0 38.1 ± 0.4 51.80 ± 0.15 167.749 ± 0.004 -72.8 ± 1.5 54.8 ± 1.5 229.65 ± 0.40 56.60 ± 0.20 165.190 ± 0.004 184.0 ± 1.5 223.081 ± 0.010 85.23 ± 0.40 175.601 ± 0.003 132.1 ± 0.5 33.15 ± 0.08 166.398 ± 0.004 -98 ± 4 109.2 ± 0.4 -13.8 ± 0.8 158.751 ± 0.004 202.791 ± 0.005 31.09 ± 0.15 167.904 ± 0.005 301.9 ± 1.0 39.71 ± 0.15 114.717 ± 0.002 0 198.700 ± 0.004 98.4 ± 0.5 186.902 ± 0.005 173.779 ± 0.003 206.590 ± 0.004 Hº(298)-Hº(0)/ kJ mol-1 5.745 ± 0.020 6.197 ± 0.001 12.033 ± 0.020 4.540 ± 0.020 6.919 ± 0.001 11.62 ± 0.04 10.016 ± 0.020 6.197 ± 0.001 1.222 ± 0.008 6.316 ± 0.002 11.650 ± 0.020 9.301 ± 0.040 1.950 ± 0.020 6.197 ± 0.001 2.837 ± 0.008 6.197 ± 0.001 24.52 ± 0.01 9.725 ± 0.001 1.050 ± 0.020 6.536 ± 0.001 8.671 ± 0.001 9.365 ± 0.003 5.736 ± 0.040 6.197 ± 0.001 6.75 ± 0.06 6.247 ± 0.015 6.197 ± 0.001 8.41 ± 0.08 35.56 ± 0.04 6.272 ± 0.001 9.181 ± 0.001 7.711 ± 0.020 6.197 ± 0.001 5.004 ± 0.008 6.197 ± 0.001 16.86 ± 0.08 6.518 ± 0.001 8.825 ± 0.001 4.636 ± 0.020 7.398 ± 0.001 17.29 ± 0.10 7.230 ± 0.020 6.197 ± 0.001 8.648 ± 0.001 8.640 ± 0.001 8.599 ± 0.001 8.657 ± 0.001 state pressure is 100,000 Pa (1 bar). See the reference for information on the dependence of gas-phase entropy on the choice of standard state pressure. Substances are listed in alphabetical order of their chemical formulas when written in the most common form. The table is reprinted with permission of CODATA. Reference Cox, J. D., Wagman, D. D., and Medvedev, V. A., CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1989. Substance HPO4-2 HSO4H2 H2O H2O H2PO4H2S H2S H3BO3 H3BO3 He Hg Hg Hg+2 HgO Hg2+2 Hg2Cl2 Hg2SO4 II I2 I2 K K K+ Kr Li Li Li+ Mg Mg Mg+2 MgF2 MgO N NH3 NH4+ NO3N2 Na Na Na+ Ne O OHO2 P P P2 P4 Pb Pb Pb+2 PbSO4 Rb Rb Rb+ S S SHSO2 State aq aq g l g aq g aq, undissoc. cr aq, undissoc. g l g aq cr, red aq cr cr aq g cr g cr g aq g cr g aq cr g aq cr cr g g aq aq g cr g aq g g aq g cr, white g g g cr g aq cr cr g aq cr, rhombic g aq g ∆fHº(298)/ kJ mol-1 -1299.0 ± 1.5 -886.9 ± 1.0 0 -285.830 ± 0.040 -241.826 ± 0.040 -1302.6 ± 1.5 -20.6 ± 0.5 -38.6 ± 1.5 -1094.8 ± 0.8 -1072.8 ± 0.8 0 0 61.38 ± 0.04 170.21 ± 0.20 -90.79 ± 0.12 166.87 ± 0.50 -265.37 ± 0.40 -743.09 ± 0.40 -56.78 ± 0.05 106.76 ± 0.04 0 62.42 ± 0.08 0 89.0 ± 0.8 -252.14 ± 0.08 0 0 159.3 ± 1.0 -278.47 ± 0.08 0 147.1 ± 0.8 -467.0 ± 0.6 -1124.2 ± 1.2 -601.60 ± 0.30 472.68 ± 0.40 -45.94 ± 0.35 -133.26 ± 0.25 -206.85 ± 0.40 0 0 107.5 ± 0.7 -240.34 ± 0.06 0 249.18 ± 0.10 -230.015 ± 0.040 0 0 316.5 ± 1.0 144.0 ± 2.0 58.9 ± 0.3 0 195.2 ± 0.8 0.92 ± 0.25 -919.97 ± 0.40 0 80.9 ± 0.8 -251.12 ± 0.10 0 277.17 ± 0.15 -16.3 ± 1.5 -296.81 ± 0.20 Sº(298)/ J mol-1 K-1 -33.5 ± 1.5 131.7 ± 3.0 130.680 ± 0.003 69.95 ± 0.03 188.835 ± 0.010 92.5 ± 1.5 205.81 ± 0.05 126 ± 5 89.95 ± 0.60 162.4 ± 0.6 126.153 ± 0.002 75.90 ± 0.12 174.971 ± 0.005 -36.19 ± 0.80 70.25 ± 0.30 65.74 ± 0.80 191.6 ± 0.8 200.70 ± 0.20 106.45 ± 0.30 180.787 ± 0.004 116.14 ± 0.30 260.687 ± 0.005 64.68 ± 0.20 160.341 ± 0.003 101.20 ± 0.20 164.085 ± 0.003 29.12 ± 0.20 138.782 ± 0.010 12.24 ± 0.15 32.67 ± 0.10 148.648 ± 0.003 -137 ± 4 57.2 ± 0.5 26.95 ± 0.15 153.301 ± 0.003 192.77 ± 0.05 111.17 ± 0.40 146.70 ± 0.40 191.609 ± 0.004 51.30 ± 0.20 153.718 ± 0.003 58.45 ± 0.15 146.328 ± 0.003 161.059 ± 0.003 -10.90 ± 0.20 205.152 ± 0.005 41.09 ± 0.25 163.199 ± 0.003 218.123 ± 0.004 280.01 ± 0.50 64.80 ± 0.30 175.375 ± 0.005 18.5 ± 1.0 148.50 ± 0.60 76.78 ± 0.30 170.094 ± 0.003 121.75 ± 0.25 32.054 ± 0.050 167.829 ± 0.006 67 ± 5 248.223 ± 0.050 Hº(298)-Hº(0)/ kJ mol-1 8.468 ± 0.001 13.273 ± 0.020 9.905 ± 0.005 9.957 ± 0.010 13.52 ± 0.04 6.197 ± 0.001 9.342 ± 0.008 6.197 ± 0.001 9.117 ± 0.025 23.35 ± 0.20 26.070 ± 0.030 6.197 ± 0.001 13.196 ± 0.040 10.116 ± 0.001 7.088 ± 0.020 6.197 ± 0.001 6.197 ± 0.001 4.632 ± 0.040 6.197 ± 0.001 4.998 ± 0.030 6.197 ± 0.001 9.91 ± 0.06 5.160 ± 0.020 6.197 ± 0.001 10.043 ± 0.010 8.670 ± 0.001 6.460 ± 0.020 6.197 ± 0.001 6.197 ± 0.001 6.725 ± 0.001 8.680 ± 0.002 5.360 ± 0.015 6.197 ± 0.001 8.904 ± 0.001 14.10 ± 0.20 6.870 ± 0.030 6.197 ± 0.001 20.050 ± 0.040 7.489 ± 0.020 6.197 ± 0.001 4.412 ± 0.006 6.657 ± 0.001 10.549 ± 0.010 5-1 Thermochem The Committee on Data for Science and Technology (CODATA) has conducted a project to establish internationally agreed values for the thermodynamic properties of key chemical substances. This table presents the final results of the project. Use of these recommended, internally consistent values is encouraged in the analysis of thermodynamic measurements, data reduction, and preparation of other thermodynamic tables. The table includes the standard enthalpy of formation at 298.15 K, the entropy at 298.15 K, and the quantity H°(298.15 K)–H°(0). A value of 0 in the ∆f H° column for an element indicates the reference state for that element. The standard CODATA Key Values for Thermodynamics 5-2 Substance SO4-2 S2 Si Si SiF4 SiO2 Sn Sn Sn+2 SnO SnO2 Th Th ThO2 Ti State aq g cr g g cr, alpha quartz cr, white g aq cr, tetragonal cr, tetragonal cr g cr cr ∆fHº(298)/ kJ mol-1 -909.34 ± 0.40 128.60 ± 0.30 0 450 ± 8 -1615.0 ± 0.8 -910.7 ± 1.0 0 301.2 ± 1.5 -8.9 ± 1.0 -280.71 ± 0.20 -577.63 ± 0.20 0 602 ± 6 -1226.4 ± 3.5 0 Sº(298)/ J mol-1 K-1 18.50 ± 0.40 228.167 ± 0.010 18.81 ± 0.08 167.981 ± 0.004 282.76 ± 0.50 41.46 ± 0.20 51.18 ± 0.08 168.492 ± 0.004 -16.7 ± 4.0 57.17 ± 0.30 49.04 ± 0.10 51.8 ± 0.5 190.17 ± 0.05 65.23 ± 0.20 30.72 ± 0.10 Hº(298)-Hº(0)/ kJ mol-1 9.132 ± 0.002 3.217 ± 0.008 7.550 ± 0.001 15.36 ± 0.05 6.916 ± 0.020 6.323 ± 0.008 6.215 ± 0.001 8.736 ± 0.020 8.384 ± 0.020 6.35 ± 0.05 6.197 ± 0.003 10.560 ± 0.020 4.824 ± 0.015 Substance Ti TiCl4 TiO2 U U UO2 UO2+2 UO3 U3O8 Xe Zn Zn Zn+2 ZnO State ∆fHº(298)/ kJ mol-1 g g cr, rutile cr g cr aq cr, gamma cr g cr g aq cr 473 ± 3 -763.2 ± 3.0 -944.0 ± 0.8 0 533 ± 8 -1085.0 ± 1.0 -1019.0 ± 1.5 -1223.8 ± 1.2 -3574.8 ± 2.5 0 0 130.40 ± 0.40 -153.39 ± 0.20 -350.46 ± 0.27 Sº(298)/ J mol-1 K-1 180.298 ± 0.010 353.2 ± 4.0 50.62 ± 0.30 50.20 ± 0.20 199.79 ± 0.10 77.03 ± 0.20 -98.2 ± 3.0 96.11 ± 0.40 282.55 ± 0.50 169.685 ± 0.003 41.63 ± 0.15 160.990 ± 0.004 -109.8 ± 0.5 43.65 ± 0.40 Hº(298)-Hº(0)/ kJ mol-1 7.539 ± 0.002 21.5 ± 0.5 8.68 ± 0.05 6.364 ± 0.020 6.499 ± 0.020 11.280 ± 0.020 14.585 ± 0.050 42.74 ± 0.10 6.197 ± 0.001 5.657 ± 0.020 6.197 ± 0.001 6.933 ± 0.040 Thermochem STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES Δf Ho: Standard molar enthalpy (heat) of formation at 298.15 K in kJ/mol ΔfGo: Standard molar Gibbs energy of formation at 298.15 K in kJ/mol So: Standard molar entropy at 298.15 K in J/mol K Cp: Molar heat capacity at constant pressure at 298.15 K in J/ mol K The standard state pressure is 100 kPa (1 bar). The standard states are defined for different phases by: The standard state of a pure gaseous substance is that of the substance as a (hypothetical) ideal gas at the standard state pressure. The standard state of a pure liquid substance is that of the liquid under the standard state pressure. The standard state of a pure crystalline substance is that of the crystalline substance under the standard state pressure. An entry of 0.0 for Δf Ho for an element indicates the reference state of that element. See References 1 and 2 for further information on reference states. A blank means no value is available. The data are derived from the sources listed in the references, from other papers appearing in the Journal of Physical and Chemical Reference Data, and from the primary research literature. We are indebted to M. V. Korobov for providing data on fullerene compounds. Name Acenaphthene Acenaphthylene Acetaldehyde Acetamide Acetanilide Acetic acid Acetic anhydride Acetone Acetone cyanohydrin Acetonitrile Acetophenone Acetyl bromide Acetyl chloride Acetylene Acetyl fluoride Acetyl iodide 2-(Acetyloxy)benzoic acid 9-Acridinamine Acridine Acrolein Acrylamide Acrylic acid Acrylonitrile Actinium Adenine DL-Alanine D-Alanine ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 C12H10 C12H8 C2H4O C2H5NO C8H9NO C2H4O2 C4H6O3 C3H6O C4H7NO C2H3N C8H8O C2H3BrO C2H3ClO C2H2 C2H3FO C2H3IO C9H8O4 C13H10N2 C13H9N C3H4O C3H5NO C3H4O2 C3H3N Ac C5H5N5 C3H7NO2 C3H7NO2 Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 70.3 186.7 188.9 190.4 166.4 -317.0 -209.4 115.0 91.3 179.3 References 1. Cox, J. D., Wagman, D. D., and Medvedev, V. A., CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1989. 2. Wagman, D. D., Evans, W. H., Parker, V. B., Schumm, R. H., Halow, I., Bailey, S. M., Churney, K. L., and Nuttall, R. L., The NBS Tables of Chemical Thermodynamic Properties, J. Phys. Chem. Ref. Data, Vol. 11, Suppl. 2, 1982. 3. Chase, M. W., Davies, C. A., Downey, J. R., Frurip, D. J., McDonald, R. A., and Syverud, A. N., JANAF Thermochemical Tables, Third Edition, J. Phys. Chem. Ref. Data, Vol. 14, Suppl. 1, 1985. 4. Chase, M. W., NIST-JANAF Thermochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998. 5. Daubert, T. E., Danner, R. P., Sibul, H. M., and Stebbins, C. C., Physical and Thermodynamic Properties of Pure Compounds: Data Compilation, extant 1994 (core with 4 supplements), Taylor & Francis, Bristol, PA. 6. Pedley, J. B., Naylor, R. D., and Kirby, S. P., Thermochemical Data of Organic Compounds, Second Edition, Chapman & Hall, London, 1986. 7. Pedley, J. B., Thermochemical Data and Structures of Organic Compounds, Thermodynamic Research Center, Texas A & M University, College Station, TX, 1994. 8. Domalski, E. S., and Hearing, E. D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase, Volume III, J. Phys. Chem. Ref. Data, 25, 1–525, 1996. 9. Zabransky, M., Ruzicka , V., Majer, V., and Domalski, E. S., Heat Capacity of Liquids, J. Phys. Chem. Ref. Data, Monograph No. 6, 1996. 10. Gurvich, L. V., Veyts, I.V., and Alcock, C. B., Thermodynamic Properties of Individual Substances, Fourth Edition, Vol. 1, Hemisphere Publishing Corp., New York, 1989. 11. Gurvich, L. V., Veyts, I.V., and Alcock, C. B., Thermodynamic Properties of Individual Substances, Fourth Edition, Vol. 3, CRC Press, Boca Raton, FL, 1994. 12. NIST Chemistry Webbook, <webbook.nist.gov> ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 -192.2 -127.6 160.2 89.0 -484.3 -624.4 -248.4 -120.9 40.6 -142.5 -223.5 -272.9 -389.9 159.8 123.3 199.8 126.3 86.5 149.6 91.5 -208.0 200.8 117.0 -467.2 -163.5 -815.6 159.2 179.4 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 156.0 259.7 -166.2 -238.3 -432.2 -572.5 -217.1 74.0 -86.7 -190.4 -242.8 227.4 -442.1 -126.4 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 -133.0 263.8 55.3 -374.2 283.5 63.4 -152.7 295.3 74.5 91.9 243.4 52.2 -205.8 209.9 295.1 200.9 67.8 44.0 273.9 71.3 -212.1 0.0 96.9 -563.6 -561.2 110.6 56.5 27.2 147.0 -224.0 -383.8 147.1 -130.2 145.7 180.6 406.0 205.7 366.0 188.1 20.8 5-3 Thermochem This table gives the standard state chemical thermodynamic properties of about 2500 individual substances in the crystalline, liquid, and gaseous states. The properties tabulated are: Standard Thermodynamic Properties of Chemical Substances 5-4 Name L-Alanine Thermochem β-Alanine Allene Allyl acetate Allyl alcohol Allylamine Allylcyclopentane Aluminum Aluminum borohydride Aluminum bromide Aluminum chloride Aluminum dichloride Aluminum fluoride Aluminum hexabromide Aluminum hexachloride Aluminum hexafluoride Aluminum hexaiodide Aluminum hydride Aluminum iodide Aluminum monobromide Aluminum monochloride Aluminum monofluoride Aluminum monohydride Aluminum monoiodide Aluminum monosulfide Aluminum monoxide Aluminum nitride Aluminum oxide (α) Aluminum oxide (Al2O) Aluminum phosphate Aluminum phosphide Aluminum sulfide Americium Amidogen Aminetrifluoroboron 2-Aminobiphenyl 4-Aminobiphenyl 4-Aminobutanoic acid N-(Aminocarbonyl) acetamide 6-Aminohexanoic acid 3-Amino-1-nitroguanidine 5-Aminopentanoic acid Amminetrimethylboron Ammonia Ammonium azide Ammonium bromide Ammonium chloride Ammonium cyanide Ammonium fluoride Ammonium hexafluorosilicate Ammonium hydrogen carbonate Ammonium hydrogen phosphate Ammonium hydrogen sulfate Ammonium hydrogen sulfite Ammonium hydroxide Ammonium iodide Ammonium nitrate Ammonium nitrite Ammonium oxalate Ammonium perchlorate Ammonium phosphate Ammonium sulfate Aniline ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 C3H7NO2 C3H7NO2 C3H4 C5H8O2 C3H6O C3H7N C8H14 Al AlB3H12 AlBr3 AlCl3 AlCl2 AlF3 Al2Br6 Al2Cl6 Al2F6 Al2I6 AlH3 AlI3 AlBr AlCl AlF AlH AlI AlS AlO AlN Al2O3 Al2O AlO4P AlP Al2S3 Am H2N BF3H3N C12H11N C12H11N C4H9NO2 C3H6N2O2 C6H13NO2 CH5N5O2 C5H11NO2 C3H12BN H3N H4N4 BrH4N ClH4N CH4N2 FH4N F6H8N2Si Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 -604.0 -558.0 0.0 28.3 184.1 138.9 24.2 -16.3 -527.2 -704.2 -628.8 180.2 109.3 100.6 91.1 -1510.4 -1431.1 66.5 75.1 -46.0 -302.9 30.0 195.9 145.0 289.1 194.6 40.2 98.7 -318.0 -1675.7 -287.0 -1582.3 20.2 50.9 30.1 79.0 -1733.8 -166.5 -724.0 0.0 -1617.9 90.8 93.2 116.9 105.1 Cp(g)/ J mol-1 K-1 -124.5 -24.1 330.0 13.0 -425.1 -583.2 -331.0 -1204.6 -970.7 -1290.8 -2628.0 -516.7 289.4 147.0 164.6 379.2 21.4 -1188.2 277.1 62.6 -1220.4 490.0 -42.0 -74.1 -283.7 231.2 223.6 239.5 228.1 215.0 187.9 150.1 65.3 230.6 218.4 35.6 35.0 31.9 29.4 36.0 33.4 30.9 -130.0 -159.0 259.4 45.7 184.9 194.6 195.0 33.9 -45.9 -16.4 192.8 35.1 87.5 -7.0 317.9 107.9 -289.4 -4.0 -47.7 -258.2 259.2 65.5 200.9 91.2 -1353.9 93.8 81.0 -581.0 -544.2 184.4 -441.0 -441.2 -460.0 -79.3 218.0 115.5 -270.8 -314.4 0.4 -464.0 -2681.7 274.2 -175.2 -202.9 112.5 113.0 94.6 -348.7 -2365.3 72.0 280.2 CH5NO3 -849.4 -665.9 120.9 H9N2O4P -1566.9 H5NO4S H5NO3S H5NO H4IN H4N2O3 H4N2O2 C2H8N2O4 ClH4NO4 H12N3O4P H8N2O4S C6H7N -1027.0 -768.6 96.0 84.1 134.0 65.3 228.1 188.0 -361.2 -201.4 -365.6 -256.5 -1123.0 -295.3 -1671.9 -1180.9 Sº(g)/ J mol-1 K-1 -465.9 -424.0 190.5 -171.8 -10.0 -64.5 -637.3 22.1 -604.1 -284.1 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 -112.5 -183.9 117.0 151.1 -88.8 186.2 -901.7 220.1 -254.0 165.6 154.9 139.3 226.0 187.5 31.6 191.9 Standard Thermodynamic Properties of Chemical Substances C7H7NO2 C7H7NO2 C7H7NO2 C7H8O C14H10 C14H8O2 Sb Br3Sb Cl3Sb F3Sb I3Sb O5Sb2 C5H10O5 C6H14N4O2 Ar As AsH3O4 AsBr3 AsCl3 AsF3 AsI3 AsO As2O5 As2S3 As AsH3 C6H8O6 C4H8N2O3 C4H10N2O4 C4H7NO4 At C8H14ClN5 C8H12N4 C8H18N2 C6H14N2 C12H10N2O C10H8 C4H4N2O3 Ba BaBr2 CBaO3 BaCl2 BaCl2H4O2 BaF2 BaH2 BaH2O2 BaI2 BaN2O6 BaN2O4 BaO BaO4S BaS C7H6O C7H7NO C18H12 C6H6 C6H8N2 C6H8N2 C6H8N2 C8H10O C6H6S C6H6O3 C6H6O3 C6H6O3 C12H12N2 C14H10O2 Sº(c)/ J mol-1 K-1 -401.1 -417.3 -410.0 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 177.8 -114.8 129.2 -188.5 0.0 -259.4 -382.2 -915.5 -100.4 -971.9 -1057.9 -623.5 207.5 210.5 45.7 207.1 184.1 25.2 -239.3 -323.7 -829.2 125.1 0.0 -906.3 -197.5 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 -296.0 -283.6 -296.7 -67.9 230.9 -75.7 262.3 -194.6 222.1 -223.9 180.3 372.9 20.8 80.2 0.0 302.5 261.0 154.8 174.2 20.8 20.8 -130.0 -261.5 -785.8 -159.0 -248.9 -770.8 363.9 327.2 289.1 388.3 79.2 75.7 65.6 80.6 68.9 222.8 38.1 107.9 250.6 232.0 35.1 24.6 -305.0 -821.3 -58.2 -59.4 213.1 105.8 -924.9 -169.0 14.6 -782.3 -168.6 105.4 163.6 116.5 116.3 -259.4 -774.2 216.3 181.2 126.6 70.0 66.4 -1164.6 -789.4 -1086.6 -973.3 0.0 -125.4 246.0 237.6 0.0 -40.1 11.5 243.4 212.3 -634.7 0.0 -757.3 -1213.0 -855.0 -1456.9 -1207.1 -177.0 -944.7 -602.1 -988.0 -768.2 -548.0 -1473.2 -460.0 62.5 146.0 112.1 123.7 203.0 96.4 63.0 28.1 -736.8 -1134.4 -806.7 -1293.2 -1156.8 -138.2 -792.6 214.0 151.4 -520.3 -1362.2 -456.0 72.1 132.2 78.2 47.3 101.8 49.4 9.2 51.3 342.0 289.1 180.0 129.7 269.2 82.4 -112.0 49.1 221.2 172.0 124.5 173.4 136.0 222.8 252.6 173.2 -36.7 -100.9 293.0 82.9 159.6 63.7 -551.1 -563.8 -584.6 70.7 -153.9 20.8 71.2 46.0 -87.0 154.5 170.2 86.0 75.1 -202.6 170.8 -0.3 -7.8 3.0 146.0 111.3 -434.2 -444.0 -452.9 -55.5 Thermochem Name Aniline-2-carboxylic acid Aniline-3-carboxylic acid Aniline-4-carboxylic acid Anisole Anthracene 9,10-Anthracenedione Antimony Antimony(III) bromide Antimony(III) chloride Antimony(III) fluoride Antimony(III) iodide Antimony(V) oxide α-D-Arabinopyranose D-Arginine Argon Arsenic (gray) Arsenic acid Arsenic(III) bromide Arsenic(III) chloride Arsenic(III) fluoride Arsenic(III) iodide Arsenic monoxide Arsenic(V) oxide Arsenic(III) sulfide Arsenic (yellow) Arsine L-Ascorbic acid L-Asparagine L-Asparagine, monohydrate L-Aspartic acid Astatine Atrazine 2,2'-Azobis[isobutyronitrile] Azobutane Azopropane trans-Azoxybenzene Azulene Barbituric acid Barium Barium bromide Barium carbonate Barium chloride Barium chloride dihydrate Barium fluoride Barium hydride Barium hydroxide Barium iodide Barium nitrate Barium nitrite Barium oxide Barium sulfate Barium sulfide Benzaldehyde Benzamide Benz[a]anthracene Benzene 1,2-Benzenediamine 1,3-Benzenediamine 1,4-Benzenediamine Benzeneethanol Benzenethiol 1,2,3-Benzenetriol 1,2,4-Benzenetriol 1,3,5-Benzenetriol p-Benzidine Benzil ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 5-5 Standard Thermodynamic Properties of Chemical Substances 5-6 Name Thermochem 1H-Benzimidazole Benzoic acid Benzonitrile Benzophenone Benzo[a]pyrene Benzo[f]quinoline p-Benzoquinone Benzo[b]thiophene 1H-Benzotriazole Benzoxazole Benzoyl chloride Benzoyl peroxide Benzyl acetate Benzyl alcohol Benzylamine N-Benzylaniline Berkelium (β form) Beryllium Beryllium bromide Beryllium carbonate Beryllium chloride Beryllium fluoride Beryllium hydroxide (α) Beryllium iodide Beryllium oxide Beryllium sulfate Beryllium sulfide 9,9'-Bianthracene Bicyclo[2.2.1]heptane 1,1'-Bicyclopentyl Biphenyl Bis(2-aminoethyl)amine Bis(2-chloroethyl) ether Bis(2-cyanoethyl) sulfide Bis(2-ethylhexyl) phthalate 2,2-Bis(4-hydroxyphenyl) propane Bismuth Bismuth hydroxide Bismuth oxide Bismuth oxychloride Bismuth sulfate Bismuth sulfide Bismuth trichloride Bismuth triiodide Borane(1) Borane(3) Borane carbonyl Borazine Boric acid Boron Boron dioxide Boron monosulfide Boron monoxide Boron nitride Boron oxide Boron sulfide Boron tribromide Boron trichloride Boron trifluoride Boron triiodide Bromine Bromine (atomic) Bromine chloride Bromine dioxide Bromine fluoride ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 C7H6N2 C7H6O2 C7H5N C13H10O C20H12 C13H9N C6H4O2 C8H6S C6H5N3 C7H5NO C7H5ClO C14H10O4 C9H10O2 C7H8O C7H9N C13H13N Bk Be BeBr2 CBeO3 BeCl2 BeF2 BeH2O2 BeI2 BeO BeO4S BeS C28H18 C7H12 C10H18 C12H10 C4H13N3 C4H8Cl2O C6H8N2S C24H38O4 C15H16O2 Bi BiH3O3 Bi2O3 BiClO Bi2O12S3 Bi2S3 BiCl3 BiI3 BH BH3 CH3BO B3H6N3 BH3O3 B BO2 BS BO BN B2O3 B2S3 BBr3 BCl3 BF3 BI3 Br2 Br BrCl BrO2 BrF 79.5 -385.2 Sº(c)/ J mol-1 K-1 167.6 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Cp(l)/ J mol-1 K-1 146.8 163.2 -34.5 Sº(l)/ J mol-1 K-1 209.1 165.2 224.8 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 181.7 -294.0 215.7 54.9 254.8 150.6 -185.7 100.6 236.5 -24.2 233.7 -122.9 166.3 335.5 44.8 -103.2 -281.7 129.0 -158.0 -369.4 -160.7 34.2 101.4 0.0 0.0 -353.5 -1025.0 -490.4 -1026.8 -902.5 -192.5 -609.4 -1205.2 -234.3 326.2 -95.1 -445.6 -979.4 -815.0 -580.1 -1093.8 9.5 108.0 52.0 75.8 53.4 45.5 121.0 13.8 77.9 34.0 216.7 148.5 217.9 207.2 16.4 69.4 65.0 62.4 51.8 62.1 71.1 25.6 85.7 34.0 -100.4 94.4 324.0 0.0 286.6 136.3 454.3 -54.8 151.0 20.8 0.0 -178.9 99.4 209.4 198.4 181.4 254.0 220.9 96.3 704.7 -368.6 0.0 -711.3 -573.9 -366.9 -2544.3 -143.1 -379.1 56.7 25.5 -493.7 -322.1 151.5 120.5 113.5 -140.6 -315.0 -175.3 200.4 177.0 122.2 105.0 -541.0 -1094.3 0.0 -968.9 -254.4 -1273.5 -240.6 -228.4 -1194.3 90.0 5.9 86.1 11.1 14.8 54.0 100.0 19.7 62.8 111.7 -239.7 -427.2 0.0 -392.7 -238.5 -387.4 207.1 168.2 187.0 20.8 -265.7 -256.0 358.9 79.7 442.7 89.2 -111.2 412.7 93.3 -92.9 171.8 188.2 249.4 29.2 36.0 59.5 521.0 -305.9 288.8 -4.0 614.5 -832.0 153.4 229.6 216.2 203.5 212.3 279.8 20.8 43.0 30.0 29.2 29.5 66.9 -232.5 -388.7 -1119.4 20.7 3.1 82.4 -1.0 155.0 -109.2 324.2 290.1 254.4 349.2 245.5 175.0 240.1 271.1 229.0 67.8 62.7 199.6 229.7 206.3 106.7 152.2 75.7 -994.1 565.0 -300.4 342.0 25.0 647.5 -843.8 67.0 -205.6 -403.8 -1136.0 71.1 30.9 111.9 14.6 152.0 -93.8 70.8 36.0 20.8 35.0 45.4 33.0 Standard Thermodynamic Properties of Chemical Substances BrO BrF5 BrF3 C2H3BrO2 C3H5BrO C2HBr C6H5Br BBr C4H9Br C4H9Br CBrClF2 Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 -458.6 -300.8 -351.8 -240.5 60.9 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 225.1 178.2 124.6 219.2 154.3 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 125.8 -428.9 -255.6 -383.5 -181.0 238.1 -107.1 -120.3 -143.8 -154.9 C2H4BrCl CHBrClF CH2BrCl C2HBrClF3 -675.3 -644.8 C2HBrClF3 -720.0 -690.4 109.6 -350.6 -229.4 -338.3 CBrF3 CBrN3O6 C4H6 C4H6 C4H8O C4H9NO C4H10 C4H10O2 C4H10O2 C4H10O2 C4H10O2 C4H10S2 C4H7N C4H10S C4H10S C4H8O2 C8H14O3 C4H10O Cp(g)/ J mol-1 K-1 233.0 320.2 292.5 337.0 34.2 99.6 66.6 80.5 253.7 55.7 225.0 32.9 318.5 74.6 304.3 287.6 63.2 52.7 330.6 80.0 316.4 295.1 67.4 58.7 -23.9 81.8 286.7 275.8 276.3 274.8 64.5 55.5 49.2 56.4 -26.3 246.4 42.4 262.4 52.8 38.6 195.4 130.1 CBrCl2F CHBrCl2 CHBrF2 C12H25Br C2H5Br C2H3Br CH2BrF BrGeH3 C7H15Br C16H33Br C6H13Br CH3Br C4H9Br C8H17Br C2BrF5 C5H11Br C3H7Br C3H7Br C3H5Br C3H5Br BrH3Si BrSi BrHSi C4H4BrNO2 C7H7Br CBrCl3 BrCl3Si C2H2BrF3 Sº(g)/ J mol-1 K-1 -344.7 -90.5 -218.4 -444.5 -194.2 -59.8 -164.4 -245.1 -25.8 198.7 453.0 100.8 204.0 -170.2 -121.9 -130.5 7.9 12.2 -424.9 -269.9 -61.9 79.2 -167.8 -350.2 -148.3 -35.4 -132.4 -189.3 -1064.4 -128.9 -87.0 -99.4 40.8 45.2 209.0 -464.4 -335.9 12.0 -41.1 350.1 85.3 90.9 -694.5 32.5 138.6 88.5 -239.2 199.0 246.6 123.6 163.7 -364.8 -147.3 -523.6 -501.0 -505.3 -541.5 -105.7 -5.8 -124.7 -131.0 -533.8 -327.3 140.9 223.4 200.1 213.0 171.2 222.2 225.8 178.6 283.7 177.2 -648.3 80.3 162.3 110.0 -204.8 -282.0 -125.7 -433.2 -428.7 -482.3 -50.6 33.6 -88.0 -96.9 -475.9 -274.9 69.3 343.7 103.4 Thermochem Name Bromine monoxide Bromine pentafluoride Bromine trifluoride Bromoacetic acid Bromoacetone Bromoacetylene Bromobenzene Bromoborane(1) 1-Bromobutane 2-Bromobutane, (±)Bromochlorodifluoromethane 1-Bromo-2-chloroethane Bromochlorofluoromethane Bromochloromethane 1-Bromo-2-chloro-1,1,2-trifluoroethane 2-Bromo-2-chloro-1,1,1-trifluoroethane Bromodichlorofluoromethane Bromodichloromethane Bromodifluoromethane 1-Bromododecane Bromoethane Bromoethene Bromofluoromethane Bromogermane 1-Bromoheptane 1-Bromohexadecane 1-Bromohexane Bromomethane 2-Bromo-2-methylpropane 1-Bromooctane Bromopentafluoroethane 1-Bromopentane 1-Bromopropane 2-Bromopropane cis-1-Bromopropene 3-Bromopropene Bromosilane Bromosilyldyne Bromosilylene N-Bromosuccinimide 4-Bromotoluene Bromotrichloromethane Bromotrichlorosilane 2-Bromo-1,1,1-trifluoroethane Bromotrifluoromethane Bromotrinitromethane 1,2-Butadiene 1,3-Butadiene Butanal Butanamide Butane 1,2-Butanediol, (±)1,3-Butanediol 1,4-Butanediol 2,3-Butanediol 1,4-Butanedithiol Butanenitrile 1-Butanethiol 2-Butanethiol Butanoic acid Butanoic anhydride 1-Butanol ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 5-7 Standard Thermodynamic Properties of Chemical Substances 5-8 Name Thermochem 2-Butanol 2-Butanone trans-2-Butenal 1-Butene cis-2-Butene trans-2-Butene trans-2-Butenedinitrile trans-2-Butenenitrile 3-Butenenitrile trans-2-Butenoic acid 2-Butoxyethanol N-Butylacetamide Butyl acetate tert-Butyl acetate Butyl acrylate Butylamine sec-Butylamine tert-Butylamine Butylbenzene sec-Butylbenzene, (±)tert-Butylbenzene Butyl chloroacetate Butyl 2-chloropropanoate Butyl 3-chloropropanoate Butylcyclohexane Butyl dichloroacetate 1-tert-Butyl-3,5-dimethylbenzene 5-Butyldocosane 11-Butyldocosane Butyl ethyl ether tert-Butyl ethyl ether Butyl ethyl sulfide Butyl formate tert-Butyl hydroperoxide tert-Butyl isobutyl ether tert-Butyl isopropyl ether 1-tert-Butyl-3-methylbenzene 1-tert-Butyl-4-methylbenzene Butyl methyl ether Butyl methyl sulfide tert-Butyl methyl sulfide Butyl oleate Butyl pentanoate sec-Butyl pentanoate N-Butylpiperidine Butyl stearate Butyl trichloroacetate Butylurea tert-Butylurea Butyl vinyl ether 1-Butyne 2-Butyne 2-Butynedinitrile 2-Butynedioic acid γ-Butyrolactone Cadmium Cadmium bromide Cadmium carbonate Cadmium chloride Cadmium fluoride Cadmium hydroxide Cadmium iodide Cadmium oxide Cadmium sulfate ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 C4H10O C4H8O C4H6O C4H8 C4H8 C4H8 C4H2N2 C4H5N C4H5N C4H6O2 C6H14O2 C6H13NO C6H12O2 C6H12O2 C7H12O2 C4H11N C4H11N C4H11N C10H14 C10H14 C10H14 C6H11ClO2 C7H13ClO2 C7H13ClO2 C10H20 C6H10Cl2O2 C12H18 Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 -342.6 -273.3 -138.7 -20.8 -29.8 -33.3 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 214.9 239.1 196.9 158.7 227.0 219.9 118.0 127.0 268.2 95.1 117.8 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 -292.8 -238.5 -100.6 0.1 -7.1 -11.4 340.2 134.3 159.7 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 359.5 339.9 112.7 101.7 167.7 20.8 281.0 -380.9 -529.2 -554.5 -422.6 -127.6 -137.5 -150.6 -63.2 -66.4 -71.9 -538.4 -571.7 -557.9 -263.1 -550.1 -146.5 227.8 231.0 251.0 179.2 321.2 192.1 243.4 345.0 271.0 -305.9 -485.3 -516.5 -375.3 -91.9 -104.6 -121.0 -11.8 -18.4 -23.0 -487.4 -517.3 -502.3 -213.7 -497.8 C26H54 C26H54 C6H14O C6H14O C6H14S C5H10O2 C4H10O2 C8H18O C7H16O C11H16 -713.5 -716.0 -587.6 -593.4 -293.6 -409.1 -392.8 -109.7 -245.9 -369.0 -358.1 C11H16 -109.7 -57.0 C5H12O C5H12S C5H12S C22H42O2 C9H18O2 C9H18O2 C9H19N C22H44O2 C6H9Cl3O2 C5H12N2O C5H12N2O C6H12O C4H6 C4H6 C4N2 C4H2O4 C4H6O2 Cd Br2Cd CCdO3 CdCl2 CdF2 CdH2O2 CdI2 CdO CdO4S -290.6 -142.9 -157.1 -816.9 -613.3 -624.2 -171.8 159.0 -313.9 -127.8 -172.3 200.2 295.3 307.5 276.1 192.7 200.9 199.9 -258.1 -102.4 -121.3 -560.2 -573.2 -545.8 -492.3 -419.5 -417.4 -218.8 141.4 119.1 500.4 232.0 -182.6 165.2 145.7 529.2 -420.9 141.4 -366.5 111.8 -577.3 0.0 -316.2 -750.6 -391.5 -700.4 -560.7 -203.3 -258.4 -933.3 -296.3 -669.4 -343.9 -647.7 -473.6 -201.4 -228.7 -822.7 51.8 137.2 92.5 115.3 77.4 96.0 161.1 54.8 123.0 26.0 76.7 74.7 80.0 43.4 99.6 Standard Thermodynamic Properties of Chemical Substances CdS CdTe Ca Br2Ca C2Ca CCaO3 CCaO3 -161.9 -92.5 0.0 -682.8 -59.8 -1207.6 -1207.8 CaCl2 C2CaN2 CaF2 CaH2 CaH2O2 CaI2 CaN2O6 C2CaO4 CaO Ca3O8P2 CaO4S CaS Cf C10H16O C6H11NO C12H9N C CO2 CSe2 CS2 C60 C70 C CS CO COS CBr2O CCl2O CClFO CF2O Ce Br3Ce CeCl3 CeI3 Ce2O3 CeO2 CeS Cs CsH2N BrCs CCs2O3 ClCs CsF CsH CHCsO3 CsF2H CsHO4S CsHO CsI BCsO2 CsNO3 Cs2O ClCsO4 Cs2O4S Cs2S Cs2O3S CsO2 Cl2 -795.4 -184.5 -1228.0 -181.5 -985.2 -533.5 -938.2 -1360.6 -634.9 -4120.8 -1434.5 -482.4 0.0 -319.4 -329.4 101.7 1.9 -156.5 -92.0 Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 -663.6 -64.9 -1129.1 -1128.2 64.9 100.0 41.6 130.0 70.0 91.7 88.0 62.7 83.5 82.3 -748.8 108.4 72.9 -1175.6 -142.5 -897.5 -528.9 -742.8 68.5 41.4 83.4 142.0 193.2 67.0 41.0 87.5 149.4 -603.3 -3884.7 -1322.0 -477.4 38.1 236.0 106.5 56.5 42.0 227.8 99.7 47.4 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 271.2 156.8 2.9 2.4 2302.0 2537.0 426.0 464.0 5.7 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 177.8 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 144.0 154.9 20.8 -393.5 -394.4 213.8 37.1 116.7 2502.0 2755.0 716.7 280.3 -110.5 -142.0 -96.2 -219.1 67.1 2442.0 2692.0 671.3 228.8 -137.2 -169.2 -110.9 -204.9 237.8 544.0 614.0 158.1 210.6 197.7 231.6 309.1 283.5 276.7 -639.8 423.0 385.0 191.8 45.4 512.0 585.0 20.8 29.8 29.1 41.5 61.8 57.7 52.4 46.8 23.1 76.5 49.6 175.6 20.8 -256.0 -256.5 254.8 49.7 223.1 33.9 -267.5 -239.6 200.7 6.1 520.0 650.0 8.5 -127.2 0.0 -891.4 -1060.5 -669.3 -1796.2 -1088.7 -459.4 0.0 -118.4 -405.8 -1139.7 -443.0 -553.5 -54.2 -966.1 -923.8 -1158.1 -416.2 -346.6 -972.0 -506.0 -345.8 -443.1 -1443.0 -359.8 -1134.7 -286.2 Cp(l)/ J mol-1 K-1 25.9 164.8 89.0 2327.0 2555.0 0.0 Sº(l)/ J mol-1 K-1 72.0 26.9 -984.8 151.0 87.4 -1706.2 -1024.6 -451.5 150.6 62.3 78.2 85.2 114.6 61.6 50.0 32.2 -391.4 -1054.3 -414.5 -525.5 113.1 204.5 101.2 92.8 52.9 123.9 52.5 51.1 -858.9 135.2 87.3 -371.8 -340.6 -915.0 -406.5 -308.1 -314.3 -1323.6 104.2 123.1 104.4 155.2 146.9 175.1 211.9 69.9 52.8 80.6 64.6 151.3 76.4 76.0 108.3 134.9 0.0 Thermochem Name Cadmium sulfide Cadmium telluride Calcium Calcium bromide Calcium carbide Calcium carbonate (calcite) Calcium carbonate (aragonite) Calcium chloride Calcium cyanide Calcium fluoride Calcium hydride Calcium hydroxide Calcium iodide Calcium nitrate Calcium oxalate Calcium oxide Calcium phosphate Calcium sulfate Calcium sulfide Californium Camphor, (±)Caprolactam Carbazole Carbon (diamond) Carbon dioxide Carbon diselenide Carbon disulfide Carbon [fullerene-C60] Carbon [fullerene-C70] Carbon (graphite) Carbon monosulfide Carbon monoxide Carbon oxysulfide Carbonyl bromide Carbonyl chloride Carbonyl chloride fluoride Carbonyl fluoride Cerium Cerium(III) bromide Cerium(III) chloride Cerium(III) iodide Cerium(III) oxide Cerium(IV) oxide Cerium(II) sulfide Cesium Cesium amide Cesium bromide Cesium carbonate Cesium chloride Cesium fluoride Cesium hydride Cesium hydrogen carbonate Cesium hydrogen fluoride Cesium hydrogen sulfate Cesium hydroxide Cesium iodide Cesium metaborate Cesium nitrate Cesium oxide Cesium perchlorate Cesium sulfate Cesium sulfide Cesium sulfite Cesium superoxide Chlorine ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 5-9 Standard Thermodynamic Properties of Chemical Substances 5-10 Name Thermochem Chlorine (atomic) Chlorine dioxide Chlorine fluoride Chlorine monoxide Chlorine oxide (ClO) Chlorine superoxide (ClOO) Chlorine trifluoride Chloroacetic acid Chloroacetyl chloride Chloroacetylene 2-Chloroaniline 3-Chloroaniline 4-Chloroaniline Chlorobenzene 2-Chlorobenzoic acid 3-Chlorobenzoic acid 4-Chlorobenzoic acid 3-Chlorobenzoyl chloride Chloroborane(1) 1-Chlorobutane 2-Chlorobutane 2-Chlorobutanoic acid 3-Chlorobutanoic acid 4-Chlorobutanoic acid Chlorocyclohexane Chlorodipropanemethane 1-Chloro-1,1-difluoroethane 1-Chloro-2,2-difluoroethene Chlorodifluoromethane 1-Chlorododecane Chloroethane 2-Chloroethanol Chloroethene 2-Chloroethyl ethyl ether 2-Chloroethyl vinyl ether 1-Chloro-1-fluoroethane Chlorofluoromethane Chlorogermane 2-Chlorohexane Chloromethane (Chloromethyl)benzene 1-Chloro-3-methylbutane 2-Chloro-2-methylbutane 2-Chloro-3-methylbutane 1-Chloro-2-methylpropane 2-Chloro-2-methylpropane 1-Chloronaphthalene 2-Chloronaphthalene 1-Chloro-4-nitrobenzene 1-Chlorooctadecane 1-Chlorooctane Chloropentafluorobenzene Chloropentafluoroethane 1-Chloropentane 2-Chlorophenol 3-Chlorophenol 4-Chlorophenol 1-Chloropropane 2-Chloropropane 3-Chloro-1,2-propanediol 2-Chloro-1,3-propanediol 2-Chloropropanoic acid 3-Chloropropanoic acid 2-Chloropropene 3-Chloropropene Chlorosilane ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 Cl ClO2 ClF Cl2O ClO ClO2 ClF3 C2H3ClO2 C2H2Cl2O C2HCl C6H6ClN C6H6ClN C6H6ClN C6H5Cl C7H5ClO2 C7H5ClO2 C7H5ClO2 C7H4Cl2O BCl C4H9Cl C4H9Cl C4H7ClO2 C4H7ClO2 C4H7ClO2 C6H11Cl CHBr2Cl C2H3ClF2 C2HClF2 CHClF2 C12H25Cl C2H5Cl C2H5ClO C2H3Cl C4H9ClO C4H7ClO C2H4ClF CH2ClF ClGeH3 C6H13Cl CH3Cl C7H7Cl C5H11Cl C5H11Cl C5H11Cl C4H9Cl C4H9Cl C10H7Cl C10H7Cl C6H4ClNO2 C18H37Cl C8H17Cl C6ClF5 C2ClF5 C5H11Cl C6H5ClO C6H5ClO C6H5ClO C3H7Cl C3H7Cl C3H7ClO2 C3H7ClO2 C3H5ClO2 C3H5ClO2 C3H5Cl C3H5Cl ClH3Si Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 121.3 102.5 -50.3 80.3 101.8 89.1 -163.2 -427.6 -244.8 -189.5 -509.7 -283.7 -33.3 -404.5 -424.3 -428.9 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 -4.6 -20.3 198.7 11.1 150.1 105.3 120.5 -51.8 97.9 98.1 105.0 -123.0 -368.5 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 165.2 256.8 217.9 266.2 226.6 263.7 281.6 325.9 21.8 42.0 32.1 45.4 31.5 46.0 63.9 78.8 242.0 54.3 213.2 31.7 327.7 307.2 303.0 280.9 69.2 82.5 72.1 55.9 147.3 163.2 52.0 -325.0 -342.3 -341.0 -189.7 149.5 -154.4 -161.1 -188.1 -192.8 -575.5 -556.3 -566.3 -207.2 -94.1 59.4 -392.3 -136.8 -295.4 14.6 -335.6 -208.1 -163.7 -59.3 190.8 104.3 -246.1 -32.5 -216.0 -235.7 -226.6 -191.1 -211.3 54.6 55.4 -48.7 120.9 212.6 -315.5 -482.6 -321.1 -112.1 -289.1 -60.4 276.0 62.8 37.2 -301.3 -170.1 -313.4 53.6 264.0 53.7 264.4 263.7 47.0 54.7 234.6 40.8 -204.3 -81.9 18.9 -179.7 -202.2 -185.1 -159.3 -182.2 119.8 137.4 250.2 -544.1 -291.3 -446.0 -238.9 -809.3 -1118.8 -174.9 -858.4 -213.2 184.2 188.7 -206.4 -197.7 -189.3 -181.3 -160.5 -172.3 -525.3 -517.5 -522.5 -131.9 -144.9 -475.8 -549.3 -21.0 125.1 250.7 51.0 Standard Thermodynamic Properties of Chemical Substances ClSi C4H4ClNO2 C7H7Cl C2H2ClF3 C2ClF3 CClF3 CClN3O6 BClO Cr Br2Cr Cl2Cr Cl3Cr Cl2CrO2 CrF2 CrF3 CrI2 CrI3 Cr2FeO4 Cr3O4 Cr2O3 CrO2 CrO3 C18H12 C6H8O7 Co Br2Co CCoO3 Cl2Co CoF2 CoH2O2 CoI2 CoN2O6 CoO Co3O4 CoO4S CoS Co2S3 Cu BrCu Br2Cu ClCu Cl2Cu CCuN CuF2 CuH2O2 CuI CuN2O6 Cu2O CuO CuSe CuO4S Cu2S CuS CuO4W C4H9N3O2 C4H7N3O C7H8O C7H8O C7H8O Cm CH2N2 CN C2N2 CBrN Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 Sº(g)/ J mol-1 K-1 189.9 Cp(g)/ J mol-1 K-1 36.9 -357.9 166.8 -522.7 -27.1 0.0 -302.1 -395.4 -556.5 -356.0 -486.1 23.8 23.4 115.3 123.0 71.2 91.8 -579.5 -778.0 -1159.0 -156.9 -205.0 -1444.7 -1531.0 -1139.7 -598.0 145.3 -1543.8 0.0 -220.9 -713.0 -312.5 -692.0 -539.7 -88.7 -420.5 -237.9 -891.0 -888.3 -82.8 -147.3 0.0 -104.6 -141.8 -137.2 -220.1 96.2 -542.7 -449.8 -67.8 -302.9 -168.6 -157.3 -39.5 -771.4 -79.5 -53.1 -1105.0 -537.2 -238.5 -204.6 -1088.0 93.9 78.7 -1343.8 146.0 133.6 -1058.1 81.2 118.7 30.0 24.8 79.5 -269.8 -647.2 -454.3 109.2 82.0 79.0 78.5 68.8 -214.2 -774.0 -782.3 53.0 102.5 118.0 55.2 123.4 -100.8 33.2 96.1 24.4 54.7 -119.9 -175.7 111.3 86.2 108.1 84.5 48.5 71.9 -69.5 96.7 54.1 -146.0 -129.7 93.1 42.6 63.6 42.3 -662.2 -86.2 -53.6 109.2 120.9 66.5 76.3 47.8 165.4 154.6 167.3 150.2 285.9 140.5 221.8 89.1 -505.5 -706.3 18.4 -314.0 396.6 -523.8 322.1 83.9 66.9 351.8 174.5 20.8 -538.1 -501.6 329.8 84.5 266.2 56.0 -292.9 269.8 -194.0 -199.3 0.0 58.8 -510.8 326.5 424.7 380.3 179.5 23.0 337.4 297.7 166.4 20.8 407.5 202.6 241.9 248.3 29.2 56.8 46.9 Thermochem Name Chlorosilylidyne N-Chlorosuccinimide 2-Chlorotoluene 2-Chloro-1,1,1-trifluoroethane Chlorotrifluoroethene Chlorotrifluoromethane Chlorotrinitromethane Chloroxyborane Chromium Chromium(II) bromide Chromium(II) chloride Chromium(III) chloride Chromium(VI) dichloride dioxide Chromium(II) fluoride Chromium(III) fluoride Chromium(II) iodide Chromium(III) iodide Chromium iron oxide Chromium(II,III) oxide Chromium(III) oxide Chromium(IV) oxide Chromium(VI) oxide Chrysene Citric acid Cobalt Cobalt(II) bromide Cobalt(II) carbonate Cobalt(II) chloride Cobalt(II) fluoride Cobalt(II) hydroxide Cobalt(II) iodide Cobalt(II) nitrate Cobalt(II) oxide Cobalt(II,III) oxide Cobalt(II) sulfate Cobalt(II) sulfide Cobalt(III) sulfide Copper Copper(I) bromide Copper(II) bromide Copper(I) chloride Copper(II) chloride Copper(I) cyanide Copper(II) fluoride Copper(II) hydroxide Copper(I) iodide Copper(II) nitrate Copper(I) oxide Copper(II) oxide Copper(II) selenide Copper(II) sulfate Copper(I) sulfide Copper(II) sulfide Copper(II) tungstate Creatine Creatinine o-Cresol m-Cresol p-Cresol Curium Cyanamide Cyanide Cyanogen Cyanogen bromide ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 5-11 212.6 224.9 -128.6 -132.3 -125.4 437.6 306.7 186.2 165.3 Standard Thermodynamic Properties of Chemical Substances 5-12 Name Thermochem Cyanogen chloride Cyanogen fluoride Cyanogen iodide Cyclobutanamine Cyclobutane Cyclobutanecarbonitrile Cyclobutene Cycloheptane Cyclohexane Cyclohexanecarbonitrile Cyclohexanethiol Cyclohexanol Cyclohexanone Cyclohexene 1-Cyclohexenecarbonitrile Cyclohexylamine Cyclohexylbenzene Cyclohexylcyclohexane Cyclooctane 1,3-Cyclopentadiene Cyclopentane Cyclopentanecarbonitrile cis-1,2-Cyclopentanediol trans-1,2-Cyclopentanediol Cyclopentanethiol Cyclopentanol Cyclopentanone Cyclopentene 1-Cyclopentenecarbonitrile Cyclopentylamine Cyclopentyl methyl sulfide Cyclopropane Cyclopropanecarbonitrile Cyclopropene Cyclopropylamine Cyclopropylbenzene Cyclotetramethylenetetranitramine L-Cysteine L-Cystine Cytosine Decaborane(14) cis-Decahydronaphthalene trans-Decahydronaphthalene Decane Decanedioic acid 1,10-Decanediol Decanenitrile 1-Decanethiol Decanoic acid 1-Decanol 1-Decene Decylbenzene Decylcyclopentane 11-Decylheneicosane Diacetone alcohol Dialuminum 4,4'-Diaminodiphenylmethane Diantimony Diarsenic Diazomethane Dibenz[a,h]anthracene Dibenzofuran Dibenzothiophene Dibismuth ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 CClN CFN CIN C4H9N C4H8 C5H7N C4H6 C7H14 C6H12 C7H11N C6H12S C6H12O C6H10O C6H10 C7H9N C6H13N C12H16 C12H22 C8H16 C5H6 C5H10 C6H9N C5H10O2 C5H10O2 C5H10S C5H10O C5H8O C5H8 C6H7N C5H11N C6H12S C3H6 C4H5N C3H4 C3H7N C9H10 C4H8N8O8 C3H7NO2S C6H12N2O4S2 C4H5N3O B10H14 C10H18 C10H18 C10H22 C10H18O4 C10H22O2 C10H19N C10H22S C10H20O2 C10H22O C10H20 C16H26 C15H30 C31H64 C6H12O2 Al2 C13H14N2 Sb2 As2 CH2N2 C22H14 C12H8O C12H8S Bi2 Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 112.1 166.2 185.0 96.2 5.6 3.7 103.0 -156.6 -156.4 -47.2 -140.7 -348.2 -271.2 -38.5 48.1 -147.6 -76.6 -273.7 -167.7 105.9 -105.1 0.7 154.9 255.6 214.6 192.6 208.2 182.2 148.3 204.5 128.8 256.9 204.1 165.2 182.5 201.2 122.4 241.0 181.2 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 138.0 131.0 225.5 41.2 27.7 147.4 156.7 -118.1 -123.4 4.8 -96.2 -286.2 -226.1 -5.0 101.6 -104.0 -16.7 -215.7 -124.4 134.3 -76.4 44.1 196.6 Sº(g)/ J mol-1 K-1 236.2 224.7 256.8 Cp(g)/ J mol-1 K-1 45.0 41.8 48.3 -485.0 -490.1 -89.5 -300.1 -235.9 4.3 111.5 -95.1 -109.8 35.2 140.8 45.8 100.3 -534.1 -1032.7 -221.3 187.7 147.1 -48.1 -242.5 -192.1 34.0 156.5 -54.9 -64.7 53.3 182.8 277.1 77.0 150.5 187.9 362.9 104.5 237.5 55.6 568.8 275.5 232.8 350.7 186.1 485.9 433.3 233.2 36.4 235.6 222.2 187.0 171.9 254.9 239.4 242.9 36.4 35.0 52.5 283.9 132.6 -219.4 -230.6 265.0 264.9 -300.9 232.0 228.5 314.4 -1082.6 -678.9 -158.4 -276.5 -684.3 -478.1 -173.8 -218.3 -367.3 -848.0 -309.9 -713.7 476.1 350.4 425.0 370.6 300.8 47.3 -169.2 -182.1 -249.5 -921.9 -91.5 -211.5 -594.9 -396.6 -123.3 -138.6 -705.8 221.3 270.9 -5.3 120.0 83.4 205.1 219.7 36.9 Standard Thermodynamic Properties of Chemical Substances Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 B2H6 B2 B2O2 C4H8Br2 C4H8Br2 C4H8Br2 C4H8Br2 CBr2ClF ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 36.4 830.5 -454.8 -91.6 -142.1 -148.0 -140.3 -139.6 C2Br2ClF3 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 -691.7 56.7 30.5 57.3 342.8 82.4 347.8 325.3 327.7 87.1 77.0 80.8 311.3 313.5 316.8 68.8 70.3 65.1 293.2 54.7 309.7 65.5 775.9 199.4 43.2 -439.4 -70.8 300.8 305.1 308.4 289.0 289.6 290.0 320.2 313.9 72.3 76.2 78.7 67.1 65.1 66.7 88.7 76.5 -656.6 -66.2 -79.2 223.3 136.0 -212.3 -37.5 -157.9 -137.6 C4H8Br2 -156.6 -113.3 C3H6Br2 Br2H2Si C2Br2F4 -113.6 -71.6 -817.7 -789.1 C16H22O4 C18H34O4 C8H18S C8H18S C8H18S C8H18O3S C2 C2H2Cl2O2 C2HCl3O C6H5Cl2N C6H4Cl2 C6H4Cl2 C6H4Cl2 C4H8Cl2 C4H8Cl2 CCl2F2 C2H4Cl2 C2H4Cl2 C2H2Cl2 C2H2Cl2 C2H2Cl2 C2H3Cl2F C2HCl2F 232.1 201.9 242.5 -36.9 CBr2Cl2 CBr2F2 C2H4Br2 C2H4Br2 C2H2Br2 C2H2Br2 CHBr2F C7H14Br2 CH2Br2 C5H10Br2 C15H24O Cp(g)/ J mol-1 K-1 -87.8 -102.0 C2H2Br2Cl2 C10H22O2 C8H19N C14H22 C14H22 C8H18S2 C8H18S2 C10H20 C8H18O C8H18O C8H18O C15H24 87.6 774.0 -462.3 Sº(g)/ J mol-1 K-1 350.0 292.9 -206.0 -188.8 Thermochem Name Diborane Diboron Diboron dioxide 1,2-Dipropanebutane 1,3-Dipropanebutane 1,4-Dipropanebutane 2,3-Dipropanebutane Dipropanechlorofluoromethane 1,2-Dibromo-1-chloro-1,2,2trifluoroethane 1,2-Dibromo-1,2-dichloroethane Dipropanedichloromethane Dipropanedifluoromethane 1,1-Dipropaneethane 1,2-Dipropaneethane cis-1,2-Dipropaneethene trans-1,2-Dipropaneethene Dipropanefluoromethane 1,2-Dipropaneheptane Dipropanemethane 2,3-Dibromo-2methylbutane 1,2-Dibromo-2-methylpropane 1,2-Dipropanepropane Dipropanesilane 1,2-Dipropanetetrafluoroethane 1,2-Dibutoxyethane Dibutylamine 1,3-Di-tert-butylbenzene 1,4-Di-tert-butylbenzene Dibutyl disulfide Di-tert-butyl disulfide cis-1,2-Di-tert-butylethene Dibutyl ether Di-sec-butyl ether Di-tert-butyl ether 1,3-Di-tert-butyl-5-methylbenzene 2,6-Di-tert-butyl-4methylphenol Dibutyl phthalate Dibutyl sebacate Dibutyl sulfide Di-sec-butyl sulfide Di-tert-butyl sulfide Dibutyl sulfite Dicarbon Dichloroacetic acid Dichloroacetyl chloride 3,4-Dichloroaniline o-Dichlorobenzene m-Dichlorobenzene p-Dichlorobenzene 1,3-Dichlorobutane 1,4-Dichlorobutane Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,1-Dichloro-1-fluoroethane 1,1-Dichloro-2-fluoroethene ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 5-13 -156.6 -212.0 -222.9 -255.2 -163.6 -377.9 -401.5 -399.6 -160.6 -201.0 278.2 276.1 -332.8 -360.6 -362.0 -245.8 -410.0 -296.9 -842.6 -750.9 -220.7 -220.7 -232.6 -693.1 405.1 619.0 284.3 -496.3 -280.4 -167.7 -167.7 -188.8 -625.3 831.9 -241.0 -89.1 -17.5 -20.7 -42.3 175.4 162.4 147.8 -237.3 -229.8 -158.4 -166.8 -23.9 -26.4 -24.3 -73.8 211.8 24.1 201.5 198.4 195.9 27.3 126.3 128.4 111.3 116.4 116.8 30.2 25.7 22.5 -195.0 -183.4 -477.4 -127.7 -126.4 2.8 4.6 5.0 25.4 28.6 Standard Thermodynamic Properties of Chemical Substances 5-14 Name Thermochem Dichlorofluoromethane Dichloromethane 2,4-Dichlorophenol 1,2-Dichloropropane, (±)1,3-Dichloropropane 2,2-Dichloropropane 2,3-Dichloro-1-propanol 1,3-Dichloro-2-propanol 2,3-Dichloropropene Dichlorosilane 1,2-Dichloro-1,1,2,2-tetrafluoroethane 2,2-Dichloro-1,1,1-trifluoroethane Dicopper Diethanolamine 1,1-Diethoxyethane 1,2-Diethoxyethane Diethoxymethane 2,2-Diethoxypropane Diethylamine Diethylamine hydrochloride 2-Diethylaminoethanol o-Diethylbenzene m-Diethylbenzene p-Diethylbenzene Diethyl carbonate Diethyl 3,5-dimethylpyrrole-2,4-dicarboxylate Diethyl disulfide Diethylene glycol Diethylene glycol dibutyl ether Diethylene glycol diethyl ether Diethylene glycol dimethyl ether Diethylene glycol monobutyl ether Diethylene glycol monoethyl ether Diethylene glycol monomethyl ether Diethyl ether Diethyl malonate Diethyl mercury Diethyl oxalate 3,3-Diethylpentane Diethyl phthalate Diethyl sulfate Diethyl sulfide Diethyl sulfite Diethyl sulfoxide N,N-Diethylurea Difluoramine Difluorine dioxide Difluoroamidogen o-Difluorobenzene m-Difluorobenzene p-Difluorobenzene cis-Difluorodiazine trans-Difluorodiazine 1,1-Difluoroethane 1,1-Difluoroethene cis-1,2-Difluoroethene Difluoromethane Difluorosilylene ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 CHCl2F CH2Cl2 C6H4Cl2O C3H6Cl2 C3H6Cl2 C3H6Cl2 C3H6Cl2O C3H6Cl2O C3H4Cl2 Cl2H2Si C2Cl2F4 Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 -124.2 Sº(l)/ J mol-1 K-1 177.8 Cp(l)/ J mol-1 K-1 101.2 -226.4 -198.8 -199.9 -205.8 -381.5 -385.3 -73.3 149.1 -960.2 111.7 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 -493.8 233.5 -491.4 -451.4 -450.5 -538.9 -103.7 259.4 169.2 60.9 51.0 285.7 60.5 352.8 102.5 241.6 36.6 342.7 119.5 368.1 117.0 58.2 57.8 252.8 277.2 249.9 43.4 62.1 41.0 -628.0 282.5 266.2 268.3 246.7 252.7 67.8 60.1 58.2 42.9 43.9 -937.0 484.2 -397.1 -453.5 -408.1 -414.7 -506.9 -72.2 431.9 -358.6 -305.9 -68.5 -73.5 -72.8 -681.5 -637.9 -916.7 C4H10S2 C4H10O3 C12H26O3 -120.1 -628.5 305.0 204.0 244.8 452.0 C8H18O3 341.4 C6H14O3 274.1 C8H18O3 354.9 C6H14O3 301.0 C5H12O3 271.1 C4H10O C7H12O4 C4H10Hg C6H10O4 C9H20 C12H14O4 C4H10O4S C4H10S C4H10O3S C4H10OS C5H12N2O F2HN F2O2 F2N C6H4F2 C6H4F2 C6H4F2 F2N2 F2N2 C2H4F2 C2H2F2 C2H2F2 CH2F2 F2Si Cp(g)/ J mol-1 K-1 293.1 270.2 -95.4 -156.3 -162.8 -159.2 -173.2 -316.3 -318.4 C2HCl2F3 Cu2 C4H11NO2 C6H14O2 C6H14O2 C5H12O2 C7H16O2 C4H11N C4H12ClN C6H15NO C10H14 C10H14 C10H14 C5H10O3 C12H17NO4 Sº(g)/ J mol-1 K-1 -279.5 30.1 -805.5 -275.4 -776.6 -813.2 -119.4 -600.7 -268.0 253.5 172.5 285.0 182.8 425.1 278.2 366.1 269.3 171.4 -79.4 -571.2 -252.1 75.3 -742.0 -233.3 -688.4 -756.3 -83.5 -552.2 -205.6 -372.2 -330.0 -343.9 -342.3 222.6 223.8 159.0 159.1 157.5 19.2 43.1 -293.8 -309.2 -306.7 69.5 82.0 -497.0 -335.0 -452.3 -619.0 Standard Thermodynamic Properties of Chemical Substances Ga2 Ge2H6 Ge2 Au2 C5H8O2 C10H10 C10H10 C4H6S C4H6S C14H8O4 In2 C2I2 C4H8I2 C2H4I2 C2H2I2 CH2I2 C3H6I2 C3H6I2 C8H19N C8H18S C10H22O C10H22S C6H15N C6H14O C6H14S C4H4O2 Li2 Mg2 Hg2 C8H10O2 C4H10O2 C3H8O2 C5H12O2 C5H12O2 C4H10O2 C4H9NO C2H7N C2H8ClN Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 438.5 162.3 473.1 515.1 -406.5 137.3 -461.3 71.6 84.2 52.9 47.0 90.7 86.9 -471.7 -595.8 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 416.3 252.8 35.6 36.9 133.5 131.6 303.5 297.1 79.8 83.3 313.1 70.3 95.8 309.7 57.7 174.4 197.0 36.1 68.2 288.1 37.4 68.5 273.1 70.7 146.9 303.0 380.9 -30.0 9.3 68.5 90.4 174.1 134.0 -9.0 -218.5 -229.2 75.0 -207.4 119.5 35.6 -179.2 -180.5 379.0 -281.8 -178.5 -351.5 -181.6 -233.1 -290.3 -376.6 -377.8 -443.6 -459.4 -420.6 -278.3 -43.9 313.0 244.0 70.0 182.3 216.8 232.0 -221.5 -143.8 -319.2 -142.0 -190.3 215.9 287.7 108.8 -223.3 193.3 162.0 -348.5 175.6 137.7 -429.9 -389.7 -228.0 -18.8 -289.3 C8H11N C8H11N C8H11N C8H11N C6H14 C6H14 C6H14S C6H12O C6H12 C6H12 C6H12 C6H10 C2H6Cd C8H16 C8H16 -39.2 -38.9 46.0 -213.8 -207.4 -187.1 -328.6 -93.2 -87.5 -101.4 78.4 63.6 -218.7 -211.8 C8H16 238.9 272.5 287.8 191.9 189.7 270.2 174.7 100.5 -185.9 -178.1 -147.9 -290.6 -62.4 -60.3 -68.1 201.9 267.2 274.1 132.0 209.2 210.2 101.6 -180.9 -172.1 -218.2 273.2 209.4 -179.9 C8H16 -222.9 272.6 209.4 -184.6 C8H16 -215.7 276.3 212.8 -176.5 C8H16 -215.6 271.1 212.1 -176.6 C8H16 -222.4 268.0 210.2 -184.5 C7H14 -172.1 139.0 -138.2 Thermochem Name Digallium Digermane Digermanium Digold Dihydro-5-methyl-2(3H)furanone 1,2-Dihydronaphthalene 1,4-Dihydronaphthalene 2,3-Dihydrothiophene 2,5-Dihydrothiophene 1,4-Dihydroxy-9,10anthracenedione Diindium Diiodoacetylene 1,4-Diiodobutane 1,2-Diiodoethane cis-1,2-Diiodoethene Diiodomethane 1,2-Diiodopropane 1,3-Diiodopropane Diisobutylamine Diisobutyl sulfide Diisopentyl ether Diisopentyl sulfide Diisopropylamine Diisopropyl ether Diisopropyl sulfide Diketene Dilithium Dimagnesium Dimercury 1,2-Dimethoxybenzene 1,2-Dimethoxyethane Dimethoxymethane 1,1-Dimethoxypropane 2,2-Dimethoxypropane Dimethylacetal N,N-Dimethylacetamide Dimethylamine Dimethylamine hydrochloride 2,4-Dimethylaniline 2,5-Dimethylaniline 2,6-Dimethylaniline N,N-Dimethylaniline 2,2-Dimethylbutane 2,3-Dimethylbutane 2,3-Dimethyl-2-butanethiol 3,3-Dimethyl-2-butanone 2,3-Dimethyl-1-butene 3,3-Dimethyl-1-butene 2,3-Dimethyl-2-butene 3,3-Dimethyl-1-butyne Dimethyl cadmium 1,1-Dimethylcyclohexane cis-1,2-Dimethylcyclohexane trans-1,2-Dimethylcyclohexane cis-1,3-Dimethylcyclohexane trans-1,3-Dimethylcyclohexane cis-1,4-Dimethylcyclohexane trans-1,4-Dimethylcyclohexane 1,1-Dimethylcyclopentane ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 5-15 Standard Thermodynamic Properties of Chemical Substances 5-16 Name Thermochem cis-1,2-Dimethylcyclopentane trans-1,2-Dimethylcyclopentane cis-1,3-Dimethylcyclopentane trans-1,3-Dimethylcyclopentane 1,1-Dimethylcyclopropane cis-1,2-Dimethylcyclopropane trans-1,2-Dimethylcyclopropane Dimethyl disulfide N,N-Dimethylethanolamine Dimethyl ether N,N-Dimethylformamide 3,4-Dimethyl-2,5-furandione Dimethylglyoxime 2,2-Dimethylheptane 2,6-Dimethyl-4-heptanone 2,2-Dimethylhexane 2,3-Dimethylhexane 2,4-Dimethylhexane 2,5-Dimethylhexane 3,3-Dimethylhexane 3,4-Dimethylhexane 2,5-Dimethyl-2,5-hexanediol cis-2,2-Dimethyl-3-hexene trans-2,2-Dimethyl-3hexene 1,1-Dimethylhydrazine 1,2-Dimethylhydrazine 1,1-Dimethylindan Dimethyl isophthalate Dimethyl maleate Dimethyl mercury cis, cis-2,6-Dimethyl-2,4,6octatriene Dimethyl oxalate 3,3-Dimethyloxetane 2,2-Dimethylpentane 2,3-Dimethylpentane 2,4-Dimethylpentane 3,3-Dimethylpentane 2,2-Dimethyl-3-pentanone 2,4-Dimethyl-3-pentanone 2,4-Dimethyl-1-pentene 4,4-Dimethyl-1-pentene 2,4-Dimethyl-2-pentene cis-4,4-Dimethyl-2-pentene trans-4,4-Dimethyl-2pentene Dimethyl phthalate 2,2-Dimethylpropanamide 2,2-Dimethyl-1,3propanediol 2,2-Dimethylpropanenitrile 2,2-Dimethyl-1-propanethiol 2,2-Dimethylpropanoic acid 2,2-Dimethyl-1-propanol 2,3-Dimethylpyridine 2,4-Dimethylpyridine 2,5-Dimethylpyridine 2,6-Dimethylpyridine 3,4-Dimethylpyridine 3,5-Dimethylpyridine ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 C7H14 -165.3 C7H14 -171.2 -136.6 C7H14 -170.1 -135.8 C7H14 -168.1 -133.6 C5H10 C5H10 -33.3 -26.3 -8.2 C5H10 -30.7 C2H6S2 C4H11NO C2H6O C3H7NO C6H6O3 C4H8N2O2 C9H20 C9H18O C8H18 C8H18 C8H18 C8H18 C8H18 C8H18 C8H18O2 C8H16 C8H16 C2H8N2 C2H8N2 C11H14 C10H10O4 C6H8O4 C2H6Hg C10H16 C4H6O4 C5H10O C7H16 C7H16 C7H16 C7H16 C7H14O C7H14O C7H14 C7H14 C7H14 C7H14 C7H14 C10H10O4 C5H11NO C5H12O2 C5H9N C5H12S C5H10O2 C5H12O C7H9N C7H9N C7H9N C7H9N C7H9N C7H9N 269.2 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 -62.6 -253.7 -203.3 -239.3 235.4 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 -129.5 146.1 150.6 -24.7 -203.6 -184.1 -192.4 -112.6 266.4 64.4 146.1 306.0 83.3 -581.4 -199.7 -288.1 -408.5 -261.9 -252.6 -257.0 -260.4 -257.5 -251.8 297.3 249.2 246.6 -357.6 -224.5 -213.8 -219.2 -222.5 -219.9 -212.8 -681.7 -126.4 -144.9 -89.3 -107.7 48.9 52.7 -53.6 206.4 198.0 59.8 -24.0 140.3 209.0 164.1 84.1 92.2 -1.6 -730.9 263.2 94.4 -756.3 -182.2 -238.3 -233.1 -234.6 -234.2 -356.1 -352.9 -117.0 -110.6 -123.1 -105.3 -121.7 300.3 221.1 303.2 224.2 318.0 233.7 -708.9 -148.2 -205.7 -198.7 -201.6 -201.0 -313.6 -311.3 -83.8 -81.6 -88.7 -72.6 -88.8 303.1 -399.7 -551.2 -313.1 -39.8 -165.4 232.0 179.4 -2.3 -129.0 -491.3 243.7 248.5 248.8 244.2 240.7 241.7 189.5 184.8 184.7 185.2 191.8 184.5 67.1 63.6 66.5 58.1 68.8 72.0 -564.5 -399.4 19.4 16.1 18.7 12.7 18.3 22.5 Standard Thermodynamic Properties of Chemical Substances C6H9N C6H9N C2H6O4S C2H6S C2H6O3S C2H6O2S C2H6OS C10H10O4 C3H8N2O C3H8N2O C2H6Zn C6H5N3O4 C6H5N3O4 C6H5N3O4 C6H5N3O4 C6H5N3O4 C6H4N2O4 C6H4N2O4 C6H4N2O4 C7H4N2O6 C4H8N2O4 C2H4N2O4 C2H4N2O4 CH2N2O4 C10H6N2O4 C10H6N2O4 C6H4N2O5 C3H6N2O4 C3H6N2O4 C3H6N2O4 C4H8O2 C4H8O2 C3H6O2 C3H2O3 C10H16 C10H22O C10H22S C14H10 C12H11N C26H18 C14H14 C14H14 C12H10O C13H12 C20H14O4 H4P2 H4O7P2 P2 K2 C6H15N C6H14S2 C6H14O C6H14O4S C6H14OS C9H10N2 Se2 H6Si2 Si2 Ag2 Na2 S2 Te2 C4H8S2 C4H8S2 C3H6S2 C3H6S2 Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 -422.3 -16.7 -735.5 -65.3 -523.6 -450.1 -302.4 196.4 118.1 188.3 153.0 39.8 -687.0 -37.4 -483.4 -373.1 -151.3 201.6 129.2 53.0 142.0 -204.2 -732.6 -319.1 -312.1 -99.9 -272.7 286.0 74.1 310.6 100.0 358.1 86.4 261.1 23.4 -11.7 -67.8 -44.3 -50.6 -38.9 -2.0 -27.0 -38.0 -409.8 200.4 197.5 200.0 -36.0 -237.5 -148.2 -165.2 -104.9 -61.5 29.8 39.7 -232.7 -163.2 -207.1 -181.2 -379.7 -353.9 -333.5 -459.9 -50.8 -128.1 -100.7 270.2 143.9 152.1 118.0 249.4 250.0 -266.4 312.4 130.2 308.7 Thermochem Name 2,4-Dimethylpyrrole 2,5-Dimethylpyrrole Dimethyl sulfate Dimethyl sulfide Dimethyl sulfite Dimethyl sulfone Dimethyl sulfoxide Dimethyl terephthalate N,N-Dimethylurea N,N'-Dimethylurea Dimethyl zinc 2,3-Dinitroaniline 2,4-Dinitroaniline 2,5-Dinitroaniline 2,6-Dinitroaniline 3,5-Dinitroaniline 1,2-Dinitrobenzene 1,3-Dinitrobenzene 1,4-Dinitrobenzene 3,5-Dinitrobenzoic acid 1,4-Dinitrobutane 1,1-Dinitroethane 1,2-Dinitroethane Dinitromethane 1,5-Dinitronaphthalene 1,8-Dinitronaphthalene 2,4-Dinitrophenol 1,1-Dinitropropane 1,3-Dinitropropane 2,2-Dinitropropane 1,3-Dioxane 1,4-Dioxane 1,3-Dioxolane 1,3-Dioxol-2-one Dipentene Dipentyl ether Dipentyl sulfide Diphenylacetylene Diphenylamine 9,10-Diphenylanthracene 1,1-Diphenylethane 1,2-Diphenylethane Diphenyl ether Diphenylmethane Diphenyl phthalate Diphosphine Diphosphoric acid Diphosphorus Dipotassium Dipropylamine Dipropyl disulfide Dipropyl ether Dipropyl sulfate Dipropyl sulfoxide 2,2'-Dipyrrolylmethane Diselenium Disilane Disilicon Disilver Disodium Disulfur Ditellurium 1,3-Dithiane 1,4-Dithiane 1,2-Dithiolane 1,3-Dithiolane ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 5-17 -340.6 -315.3 -298.0 -418.6 -2.6 -204.9 225.9 219.3 465.6 48.7 51.5 -32.1 71.5 -489.2 -2241.0 233.9 239.3 216.6 142.9 52.0 139.0 -14.9 89.7 -5.0 -2231.7 -156.1 -171.5 -328.8 -859.0 -329.4 20.9 323.9 221.6 144.0 123.7 -116.0 -118.3 -293.0 -792.0 -254.9 103.5 87.5 218.1 249.7 32.1 37.9 146.0 80.3 594.0 410.0 142.1 128.6 168.2 -10.0 0.0 0.0 10.0 96.2 127.3 536.0 358.8 103.9 79.7 118.0 72.4 84.5 47.7 54.7 252.0 272.7 229.9 257.1 230.2 228.2 268.1 333.5 326.2 313.5 323.3 35.4 80.8 34.4 37.0 37.6 32.5 36.7 110.4 109.7 86.5 84.7 126.2 Standard Thermodynamic Properties of Chemical Substances 5-18 Name Thermochem Diuron cis-1,2-Divinylcyclobutane trans-1,2-Divinylcyclobutane Divinyl ether trans-13-Docosenoic acid 3,9-Dodecadiyne 5,7-Dodecadiyne Dodecane Dodecanedioic acid Dodecanoic acid 1-Dodecanol 1-Dodecene Dotriacontane Dysprosium Dysprosium(III) bromide Dysprosium(III) chloride Dysprosium(III) iodide Dysprosium(III) oxide Eicosanoic acid Einsteinium Epichlorohydrin 1,2-Epoxybutane Erbium Erbium chloride Erbium fluoride Erbium oxide Ethane Ethanedial dioxime 1,2-Ethanediamine 1,2-Ethanediol 1,2-Ethanediol, diacetate Ethanedithioamide 1,2-Ethanedithiol Ethanethiol Ethanol Ethanolamine Ethoxybenzene 2-Ethoxyethanol 2-Ethoxyethyl acetate (Ethoxymethyl)oxirane Ethyl acetate Ethyl acetoacetate Ethyl acrylate Ethylamine N-Ethylaniline Ethylbenzene Ethyl benzoate Ethyl butanoate 2-Ethyl-1-butene Ethyl trans-2-butenoate Ethyl carbamate Ethyl 4-chlorobutanoate Ethyl chloroformate Ethyl cyanoacetate Ethylcyclobutane Ethylcyclohexane Ethylcyclopentane 1-Ethylcyclopentene Ethylcyclopropane 1-Ethyl-2,4-dimethylbenzene 1-Ethyl-3,5-dimethylbenzene 2-Ethyl-1,3-dimethylbenzene 2-Ethyl-1,4-dimethylbenzene 3-Ethyl-1,2-dimethylbenzene 4-Ethyl-1,2-dimethylbenzene ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 C9H10Cl2N2O C8H12 C8H12 C4H6O C22H42O2 C12H18 C12H18 C12H26 C12H22O4 C12H24O2 C12H26O C12H24 C32H66 Dy Br3Dy Cl3Dy DyI3 Dy2O3 C20H40O2 Es C3H5ClO C4H8O Er Cl3Er ErF3 Er2O3 C2H6 C2H4N2O2 C2H8N2 C2H6O2 C6H10O4 C2H4N2S2 C2H6S2 C2H6S C2H6O C2H7NO C8H10O C4H10O2 C6H12O3 C5H10O2 C4H8O2 C6H10O3 C5H8O2 C2H7N C8H11N C8H10 C9H10O2 C6H12O2 C6H12 C6H10O2 C3H7NO2 C6H11ClO2 C3H5ClO2 C5H7NO2 C6H12 C8H16 C7H14 C7H12 C5H10 C10H14 C10H14 C10H14 C10H14 C10H14 C10H14 Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 -329.0 124.3 101.3 166.5 143.5 -39.8 -13.6 -960.7 197.8 181.5 -350.9 -1130.0 -774.6 -968.3 0.0 -836.2 -1000.0 -620.5 -1863.1 -1011.9 0.0 404.3 -1771.5 75.6 28.2 149.8 116.3 545.1 375.8 -737.9 -528.5 -226.2 484.8 -940.0 -1808.7 73.2 28.1 100.0 155.6 108.5 254.4 196.6 20.8 317.1 280.7 195.6 20.8 -84.0 -32.0 229.2 52.5 303.8 82.7 -4.8 -167.9 296.2 281.6 72.7 65.6 36.3 283.8 71.5 -812.4 -148.4 -168.9 0.0 -998.7 -1711.0 -1897.9 438.1 360.7 -289.4 -976.9 -642.0 -436.6 -165.4 -697.2 290.4 230.9 131.6 147.0 -107.8 -90.5 -63.0 -460.0 163.2 172.6 148.6 310.0 -20.8 -54.3 -73.6 -277.6 -5.5 -174.8 207.0 160.7 -152.6 -296.5 -479.3 257.7 -370.6 -74.1 8.2 -12.3 -517.1 156.4 117.9 112.3 195.5 228.5 210.8 376.0 170.7 248.0 130.0 183.2 246.0 228.0 -87.1 -420.0 -497.3 -566.5 -505.3 -18.0 -392.2 83.0 -9.7 -46.1 -234.8 -101.6 -443.6 -354.2 -47.5 56.3 29.9 -56.0 -375.6 -446.3 -513.8 -462.9 220.2 -59.0 -212.1 -163.4 -53.3 -24.8 -84.1 -87.8 -80.1 -84.8 -80.5 -86.0 280.9 279.9 211.8 -27.5 -171.5 -126.9 -19.8 Standard Thermodynamic Properties of Chemical Substances Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 C9H20 C9H20 C7H14O2 -474.5 C9H13NO2 -463.2 C9H13NO2 -478.7 C9H13NO2 -470.3 Cp(l)/ J mol-1 K-1 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 -536.0 -682.8 133.9 52.4 -508.4 68.4 219.3 42.9 309.2 93.3 -1759.5 C2H5N C3H6O2 C8H16O C8H18 C8H16O2 C8H18O C8H14 C3H5N C5H12S C5H10O3 C7H14O2 C7H14 C8H16 91.9 126.5 149.3 -348.5 -250.4 -635.1 -432.8 -103.5 108.6 -156.1 347.0 317.5 -299.6 -210.7 -559.5 -365.3 -59.5 141.7 -118.3 254.0 -571.0 -114.1 -193.8 C8H16 -190.8 C8H16 -195.1 C8H16 -194.4 C8H16 -196.0 C3H8O C8H18 C8H18 C8H16 C3H8S C2H5NO3 C4H7NO4 C5H11NO4 -249.6 -252.8 -137.9 -91.6 -190.4 -487.1 C20H38O2 C20H38O2 C7H16 C7H14O2 C7H10O2 C8H10O C8H10O C8H10O C5H10O2 C5H12O C5H12S C8H20O4Si C4H8OS C9H12 C9H12 C9H12 C9H15N Sº(l)/ J mol-1 K-1 -272.7 -269.7 -577.2 C9H13NO2 C2H4 C3H4O3 C10H16N2O8 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 -527.0 -79.5 -156.2 239.1 144.6 314.5 219.6 295.0 309.5 533.1 197.2 198.4 364.4 -216.4 -211.0 -214.8 -100.3 -59.6 -154.1 -606.4 -775.8 -773.3 -224.9 -553.0 -301.8 -208.8 -214.3 -224.4 206.9 -502.7 -303.6 -144.8 -268.2 -46.4 -48.7 -49.8 -89.2 Thermochem Name 3-Ethyl-2,2-dimethylpentane 3-Ethyl-2,4-dimethylpentane Ethyl 2,2-dimethylpropanoate Ethyl 3,5-dimethylpyrrole-2carboxylate Ethyl 2,4-dimethylpyrrole-3carboxylate Ethyl 2,5-dimethylpyrrole-3carboxylate Ethyl 4,5-dimethylpyrrole-3carboxylate Ethylene Ethylene carbonate Ethylenediaminetetraacetic acid Ethyleneimine Ethyl formate 2-Ethylhexanal 3-Ethylhexane 2-Ethylhexanoic acid 2-Ethyl-1-hexanol Ethylidenecyclohexane Ethyl isocyanide Ethyl isopropyl sulfide Ethyl lactate Ethyl 3-methylbutanoate 2-Ethyl-3-methyl-1-butene 1-Ethyl-1-methylcyclopentane cis-1-Ethyl-2-methylcyclopentane trans-1-Ethyl-2-methylcyclopentane cis-1-Ethyl-3-methylcyclopentane trans-1-Ethyl-3-methylcyclopentane Ethyl methyl ether 3-Ethyl-2-methylpentane 3-Ethyl-3-methylpentane 3-Ethyl-2-methyl-1-pentene Ethyl methyl sulfide Ethyl nitrate Ethyl nitroacetate 2-Ethyl-2-nitro-1,3propanediol Ethyl cis-9-octadecenoate Ethyl trans-9-octadecenoate 3-Ethylpentane Ethyl pentanoate Ethyl 2-pentynoate 2-Ethylphenol 3-Ethylphenol 4-Ethylphenol Ethyl propanoate Ethyl propyl ether Ethyl propyl sulfide Ethyl silicate S-Ethyl thioacetate 2-Ethyltoluene 3-Ethyltoluene 4-Ethyltoluene 3-Ethyl-2,4,5-trimethylpyrrole ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 5-19 -189.5 -505.9 -250.3 -145.2 -146.1 -144.1 -463.4 -272.0 -104.8 -228.1 1.3 -1.8 -3.2 Standard Thermodynamic Properties of Chemical Substances 5-20 Name Thermochem N-Ethylurea Ethyl vinyl ether Ethynylsilane Europium Europium(III) chloride Europium(II,III) oxide Europium(III) oxide Fermium Fluoranthene 9H-Fluorene Fluorine Fluorine (atomic) Fluorine monoxide Fluorine oxide Fluorine superoxide (FOO) Fluoroacetylene Fluorobenzene Fluoroborane(1) Fluoroethane Fluoroethene Fluorogermane Fluoromethane Fluorooxyborane 1-Fluoropropane 2-Fluoropropane Fluorosilane Fluorosilylidyne 4-Fluorotoluene Formaldehyde Formamide Formic acid Formyl fluoride Francium β-D-Fructose Fumaric acid Furan 2-Furancarboxylic acid 3-(2-Furanyl)-2-propenal Furfural Furfuryl alcohol Gadolinium Gadolinium(III) chloride Gadolinium(III) fluoride Gadolinium(III) oxide Galactitol D-Galactose Gallium Gallium antimonide Gallium arsenide Gallium(III) bromide Gallium(III) chloride Gallium(III) fluoride Gallium(III) hydroxide Gallium(III) iodide Gallium monofluoride Gallium monoxide Gallium nitride Gallium(III) oxide Gallium phosphide Gallium suboxide Germane Germanium Germanium(IV) bromide Germanium(IV) chloride Germanium(IV) fluoride Germanium(IV) iodide ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 C3H8N2O C4H8O C2H4Si Eu Cl3Eu Eu3O4 Eu2O3 Fm C16H10 C13H10 F2 F F2O FO FO2 C2HF C6H5F BF C2H5F C2H3F FGeH3 CH3F BFO C3H7F C3H7F FH3Si FSi C7H7F CH2O CH3NO CH2O2 CHFO Fr C6H12O6 C4H4O4 C4H4O C5H4O3 C7H6O2 C5H4O2 C5H6O2 Gd Cl3Gd F3Gd Gd2O3 C6H14O6 C6H12O6 Ga GaSb AsGa Br3Ga Cl3Ga F3Ga GaH3O3 GaI3 FGa GaO GaN Ga2O3 GaP Ga2O GeH4 Ge Br4Ge Cl4Ge F4Ge GeI4 Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 -357.8 -167.4 0.0 -936.0 -2272.0 -1651.4 0.0 189.9 89.9 -2142.0 -1556.8 77.8 27.7 205.0 146.0 122.2 230.6 207.3 230.2 203.1 -140.8 269.4 188.8 72.6 20.8 202.8 158.8 247.5 216.4 259.5 231.7 173.1 31.3 22.7 43.3 32.0 44.5 52.4 200.5 264.5 29.6 58.6 252.8 222.9 51.6 37.5 -24.3 238.4 225.8 47.4 32.6 -102.5 218.8 35.4 246.6 39.9 267.2 65.4 359.8 194.3 27.5 272.0 233.7 169.0 25.3 -251.9 279.5 253.5 231.1 33.3 32.1 90.8 372.0 -300.0 -495.8 -1190.2 -56.9 113.4 331.2 -318.0 -457.3 -1150.0 -106.3 217.1 167.9 396.2 347.7 301.9 428.9 175.3 -150.6 205.9 146.4 142.2 289.0 175.0 0.0 79.4 24.5 109.0 25.4 62.3 41.8 105.3 39.4 -115.9 -122.2 -149.8 -138.8 -607.0 -285.9 -293.5 -186.9 -254.0 -425.0 0.0 -1265.6 -811.7 171.2 -361.4 129.0 99.0 7.1 -147.4 -108.6 -193.9 -378.7 95.4 168.0 142.0 -62.3 177.0 114.8 -498.4 -182.0 -201.6 -276.2 0.0 -1008.0 68.1 163.2 204.0 37.0 88.0 -675.8 -34.8 -390.0 -105.9 -151.0 -211.8 397.5 -1297.0 -1819.6 106.7 -1317.0 -1286.3 0.0 -41.8 -71.0 -386.6 -524.7 -1163.0 -964.4 -238.9 -110.5 -1089.1 -88.0 -356.0 0.0 -38.9 -67.8 -359.8 -454.8 -1085.3 -831.3 -998.3 0.0 40.8 76.1 64.2 180.0 142.0 84.0 100.0 205.0 26.0 48.5 46.2 5.6 100.0 85.0 92.1 31.1 23.3 -347.7 -531.8 -141.8 -144.3 271.1 -331.4 -462.7 280.7 245.6 45.0 30.7 101.8 96.1 104.1 Standard Thermodynamic Properties of Chemical Substances BrGe ClGe FGe GeO GeO2 GeP GeS GeTe C6H12O6 C16H22O11 C16H22O11 C5H9NO4 C5H9NO4 C5H10N2O3 C3H8O3 C5H10O4 C9H14O6 C2H5NO2 C2H4O3 C4H8N2O3 C2H2O2 Au AuBr AuBr3 AuCl AuCl3 AuF3 AuH AuI CH5N3 C5H5N5O Hf Cl4Hf F4Hf HfO2 He C17H34O2 C7H14O C7H16 C7H16O2 C7H13N C7H16S C7H14O2 C7H16O C7H14O C7H14O C7H14O C7H14 C7H14 C7H14 C7H14 C7H14 B6H10 C2Br6 C6Cl6 C4Cl6 C2Cl6 C16H34 C16H32O2 C16H34O C16H32 C6H10 C6H6 C5H2F6O2 C6F6 F6Si2 -261.9 -580.0 -21.0 -69.0 20.0 -1273.3 -2249.4 -2232.6 -1005.3 -1009.7 -826.4 -237.2 -521.4 -17.0 -71.5 Sº(c)/ J mol-1 K-1 50.0 39.7 63.0 71.0 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 235.6 155.2 -33.4 -46.2 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 124.2 247.0 -73.2 224.3 37.1 36.9 34.7 30.9 42.0 234.0 33.7 52.1 92.0 -669.6 -909.2 -1330.8 206.3 218.9 -577.9 458.3 384.7 -1245.0 -392.1 -583.0 -504.9 318.6 87.1 -212.0 366.1 -189.7 326.3 272.5 180.5 60.6 20.8 295.0 265.7 211.2 29.2 619.2 -884.5 -1669.8 576.5 186.9 20.8 126.2 20.8 211.3 296.8 441.9 125.7 139.3 -2307.3 391.0 129.9 -528.5 -747.7 0.0 -14.0 -53.3 -34.7 -117.6 -363.6 0.0 -56.0 -183.9 0.0 -990.4 -1930.5 -1144.7 47.4 -901.3 -1830.4 -1088.2 43.6 190.8 113.0 59.3 25.4 25.7 120.5 60.3 0.0 -924.4 475.7 -865.6 -311.5 -224.2 -574.2 -82.8 -200.5 -610.2 -403.3 -97.9 -105.1 -109.5 -104.3 -109.3 56.3 -127.6 260.2 335.4 230.1 224.7 265.4 272.1 232.6 327.6 211.8 -263.8 -187.6 -31.0 -149.9 -536.2 -336.5 -297.1 -298.3 -62.3 94.6 201.2 -35.5 -24.5 -202.8 237.3 -891.5 -686.5 452.4 198.2 460.7 422.0 -456.1 -838.1 501.6 -328.7 54.1 384.2 587.9 488.9 -991.3 280.8 221.6 -143.6 -374.8 -737.1 -517.0 -248.4 84.2 -2286.7 -2427.0 -2299.7 219.1 129.5 -955.4 -2383.3 Thermochem Name Germanium monobromide Germanium monochloride Germanium monofluoride Germanium(II) oxide Germanium(IV) oxide Germanium phosphide Germanium(II) sulfide Germanium(II) telluride α-D-Glucose α-D-Glucose pentaacetate β-D-Glucose pentaacetate D-Glutamic acid L-Glutamic acid L-Glutamine Glycerol Glycerol 1-acetate Glycerol triacetate Glycine Glycolic acid N-Glycylglycine Glyoxal Gold Gold(I) bromide Gold(III) bromide Gold(I) chloride Gold(III) chloride Gold(III) fluoride Gold hydride Gold(I) iodide Guanidine Guanine Hafnium Hafnium(IV) chloride Hafnium(IV) fluoride Hafnium(IV) oxide Helium Heptadecanoic acid Heptanal Heptane 1,7-Heptanediol Heptanenitrile 1-Heptanethiol Heptanoic acid 1-Heptanol 2-Heptanone 3-Heptanone 4-Heptanone 1-Heptene cis-2-Heptene trans-2-Heptene cis-3-Heptene trans-3-Heptene Hexaborane(10) Hexapropaneethane Hexachlorobenzene Hexachloro-1,3-butadiene Hexachloroethane Hexadecane Hexadecanoic acid 1-Hexadecanol 1-Hexadecene 1,5-Hexadiene 1,5-Hexadiyne Hexafluoroacetylacetone Hexafluorobenzene Hexafluorodisilane ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 5-21 Standard Thermodynamic Properties of Chemical Substances 5-22 Name Thermochem Hexafluoroethane Hexahydro-1,3,5-trinitro1,3,5-triazine Hexamethylbenzene Hexamethyldisiloxane Hexamethylphosphoric triamide Hexanal Hexanamide Hexane 1,6-Hexanediamine Hexanedinitrile 1,6-Hexanedioic acid 1,2-Hexanediol 1,6-Hexanediol 1-Hexanethiol Hexanoic acid 1-Hexanol 2-Hexanol 3-Hexanol 2-Hexanone 3-Hexanone 1-Hexene cis-2-Hexene trans-2-Hexene cis-3-Hexene trans-3-Hexene Hexyl acetate L-Histidine Holmium Holmium chloride Holmium fluoride Holmium oxide Hydrazine Hydrazinecarbothioamide 1,2-Hydrazinedicarboxamide Hydrazoic acid Hydrogen (atomic) Hydrogen Hydrogen bromide Hydrogen chloride Hydrogen cyanide Hydrogen disulfide Hydrogen fluoride Hydrogen iodide Hydrogen peroxide Hydrogen selenide Hydrogen sulfide Hydrogen telluride Hydroperoxy p-Hydroquinone 2-Hydroxybenzoic acid Hydroxyl Hydroxylamine 2-(Hydroxymethyl)-2methyl-1,3-propanediol Hypochlorous acid Hypoxanthine Imidazole Imidogen Iminodiacetic acid Indan 1H-Indazole Indene Indium Indium antimonide Indium arsenide ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 C2F6 C3H6N6O6 C12H18 C6H18OSi2 C6H18N3OP C6H12O C6H13NO C6H14 C6H16N2 C6H8N2 C6H10O4 C6H14O2 C6H14O2 C6H14S C6H12O2 C6H14O C6H14O C6H14O C6H12O C6H12O C6H12 C6H12 C6H12 C6H12 C6H12 C8H16O2 C6H9N3O2 Ho Cl3Ho F3Ho Ho2O3 H4N2 CH5N3S C2H6N4O2 HN3 H H2 BrH ClH CHN H2S2 FH HI H2O2 H2Se H2S H2Te HO2 C6H6O2 C7H6O3 HO H3NO C5H12O3 ClHO C5H4N4O C3H4N2 HN C4H7NO4 C9H10 C7H6N2 C9H8 In InSb AsIn ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 -1344.2 192.0 -162.4 306.3 245.6 -815.0 -541.5 433.8 311.4 321.0 280.3 210.4 -423.0 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 332.3 482.4 106.7 230.2 -534.5 535.0 238.5 300.8 264.8 195.6 20.8 95.4 159.4 238.5 48.4 294.1 218.0 0.0 -36.3 -92.3 135.1 15.5 -273.3 26.5 -136.3 29.7 -20.6 99.6 10.5 -265.3 -494.8 39.0 328.1 203.3 -53.4 -95.3 124.7 239.0 114.7 130.7 198.7 186.9 201.8 43.7 20.8 28.8 29.1 29.1 35.9 51.5 -275.4 1.7 -105.6 15.9 -33.4 173.8 206.6 232.7 219.0 205.8 29.2 43.1 34.7 34.2 22.6 229.0 34.9 34.2 183.7 29.9 -78.7 -66.1 236.7 37.2 132.9 351.5 345.6 181.2 29.2 208.7 173.8 20.8 -77.4 -777.7 -198.7 195.6 -324.2 -166.9 85.1 128.7 149.5 -205.0 -994.3 -577.1 -548.6 -175.7 -583.8 -377.5 -392.0 -392.4 -322.0 -320.2 -74.2 -83.9 -85.5 -78.9 -86.1 -569.9 287.4 240.4 305.3 295.2 286.2 213.3 216.9 183.3 -490.1 -461.2 -129.9 -511.9 -315.9 -333.5 -278.9 -277.6 -43.5 -52.3 -53.9 -47.6 -54.4 282.8 -466.7 0.0 -1005.4 -1707.0 -1880.7 -1791.1 75.3 27.2 88.0 158.2 115.0 50.6 149.3 121.2 264.0 327.3 140.6 98.9 24.7 -498.7 -364.5 -589.9 108.9 -18.1 -299.8 125.0 -187.8 -120.4 112.8 109.6 70.6 84.1 89.1 136.0 -114.2 -744.6 -110.8 49.8 145.6 134.5 -932.6 11.5 234.4 190.2 110.6 215.3 186.9 151.9 0.0 -30.5 -58.6 -25.5 -53.6 57.8 86.2 75.7 26.7 49.5 47.8 60.3 243.0 163.4 243.3 344.3 Standard Thermodynamic Properties of Chemical Substances BrIn Br3In ClIn Cl3In FIn IIn I3In InO In2O3 InP InS In2S3 In2Te5 C8H7N C8H5NO2 HIO3 I2 I BrI ClI FI IO F5I C3H5IO C6H5I C2H5I C2H3I GeH3I CH3I C4H9I C4H9I C10H7I C10H7I C3H7I C3H7I C3H5IO2 C3H5I H3ISi Ir Cl3Ir F6Ir IrO2 Ir2S3 IrS2 Fe Br2Fe Br3Fe CFe3 CFeO3 Cl2Fe Cl3Fe FeS2 F2Fe FeI2 FeI3 FeMoO4 Fe2O4Si FeO Fe3O4 Fe2O3 C5FeO5 FeO4S FeS FeO4W C4H8O C4H10 Sº(c)/ J mol-1 K-1 -175.3 -428.9 -186.2 -537.2 -169.0 113.0 -116.3 -238.0 -120.5 130.0 -925.8 -88.7 -138.1 -427.0 -175.3 86.6 -268.2 -230.1 0.0 -830.7 -77.0 -131.8 -412.5 104.2 59.8 67.0 163.6 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 -56.9 -282.0 -75.0 -374.0 -203.4 7.5 -120.5 387.0 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 -94.3 259.5 36.7 -37.7 267.3 36.8 364.4 236.5 32.6 19.3 70.2 3.7 -5.5 -118.5 102.5 -751.7 260.7 180.8 258.8 247.6 236.2 239.6 327.7 36.9 20.8 36.4 35.6 33.4 32.9 99.2 19.2 306.0 285.0 283.2 254.1 66.9 57.9 57.5 44.1 92.0 45.4 238.0 118.0 156.5 116.1 54.4 -23.9 -13.6 135.1 14.7 205.4 211.7 158.7 115.1 163.2 126.0 162.3 -864.8 117.2 -40.0 -13.6 -107.5 161.5 62.4 106.8 40.8 17.8 -95.7 126.0 -822.5 -130.5 164.9 -8.1 14.4 -66.0 -74.8 -72.1 233.8 235.1 -30.0 -40.3 53.7 91.5 144.3 Thermochem Name Indium(I) bromide Indium(III) bromide Indium(I) chloride Indium(III) chloride Indium(I) fluoride Indium(I) iodide Indium(III) iodide Indium monoxide Indium(III) oxide Indium phosphide Indium(II) sulfide Indium(III) sulfide Indium(IV) telluride 1H-Indole 1H-Indole-2,3-dione Iodic acid Iodine Iodine (atomic) Iodine bromide Iodine chloride Iodine fluoride Iodine monoxide Iodine pentafluoride Iodoacetone Iodobenzene Iodoethane Iodoethene Iodogermane Iodomethane 1-Iodo-2-methylpropane 2-Iodo-2-methylpropane 1-Iodonaphthalene 2-Iodonaphthalene 1-Iodopropane 2-Iodopropane 3-Iodopropanoic acid 3-Iodopropene Iodosilane Iridium Iridium(III) chloride Iridium(VI) fluoride Iridium(IV) oxide Iridium(III) sulfide Iridium(IV) sulfide Iron Iron(II) bromide Iron(III) bromide Iron carbide Iron(II) carbonate Iron(II) chloride Iron(III) chloride Iron disulfide Iron(II) fluoride Iron(II) iodide Iron(III) iodide Iron(II) molybdate Iron(II) orthosilicate Iron(II) oxide Iron(II,III) oxide Iron(III) oxide Iron pentacarbonyl Iron(II) sulfate Iron(II) sulfide Iron(II) tungstate Isobutanal Isobutane ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 5-23 -460.0 0.0 -245.6 -579.7 -274.1 -234.0 -138.0 0.0 -249.8 -268.2 25.1 -740.6 -341.8 -399.5 -178.2 -711.3 -113.0 35.5 -461.6 25.1 247.7 665.3 617.9 270.9 193.6 54.4 20.8 -544.0 -460.0 357.8 121.1 416.3 370.7 180.5 25.7 57.3 27.3 140.6 25.1 -238.1 20.1 -666.7 -302.3 -334.0 -166.9 -668.6 104.6 92.9 118.0 142.3 52.9 87.0 105.9 82.1 76.7 96.7 62.2 68.1 71.0 -1075.0 -1479.9 -272.0 -1118.4 -824.2 -975.0 -1379.0 129.3 145.2 118.5 132.9 -1015.4 -742.2 146.4 87.4 143.4 103.9 -928.4 -100.0 -1155.0 -820.8 -100.4 -1054.0 107.5 60.3 131.8 100.6 50.5 114.6 -774.0 -247.3 -154.2 -705.3 338.1 240.6 -215.7 -134.2 Standard Thermodynamic Properties of Chemical Substances 5-24 Name Thermochem Isobutene Isobutyl acetate Isobutylamine Isobutylbenzene Isobutyl 2-chloropropanoate Isobutyl 3-chloropropanoate Isobutyl isobutanoate Isobutyl pentanoate Isobutyl trichloroacetate Isocyanic acid (HNCO) Isocyanomethane DL-Isoleucine L-Isoleucine Isopentane Isopentyl acetate Isopentyl trichloroacetate Isophorone Isophthalic acid Isopropyl acetate Isopropylamine Isopropylbenzene Isopropylbenzene hydroperoxide 1-Isopropyl-2-methylbenzene 1-Isopropyl-3-methylbenzene 1-Isopropyl-4-methylbenzene Isopropyl methyl ether Isopropyl methyl sulfide Isopropyl nitrate Isopropyl pentanoate 2-Isopropylphenol 3-Isopropylphenol 4-Isopropylphenol Isoquinoline Isothiocyanic acid Isoxazole Ketene Krypton β-D-Lactose α-Lactose monohydrate Lanthanum Lanthanum chloride Lanthanum iodide Lanthanum monosulfide Lanthanum oxide Lawrencium Lead Lead(II) bromide Lead(II) carbonate Lead(II) chloride Lead(IV) chloride Lead(II) chromate Lead(II) fluoride Lead(IV) fluoride Lead(II) iodide Lead(II) metasilicate Lead(II) molybdate Lead(II) nitrate Lead(II) orthosilicate Lead(II) oxalate Lead(II,II,IV) oxide Lead(IV) oxide Lead(II) oxide (litharge) Lead(II) oxide (massicot) ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 C4H8 C6H12O2 C4H11N C10H14 C7H13ClO2 C7H13ClO2 C8H16O2 C9H18O2 C6H9Cl3O2 CHNO C2H3N C6H13NO2 C6H13NO2 C5H12 C7H14O2 C7H11Cl3O2 C9H14O C8H6O4 C5H10O2 C3H9N C9H12 C9H12O2 Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Cp(l)/ J mol-1 K-1 -37.5 130.8 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 -16.9 233.8 183.2 -132.6 -69.8 -603.1 -572.6 -587.4 -620.0 -553.4 159.5 159.0 -98.7 -21.9 -549.6 -517.3 -542.9 -568.6 -500.2 165.7 238.0 246.9 44.9 52.9 32.2 312.2 97.5 113.0 247.8 46.9 -48.3 247.6 164.1 51.8 20.8 431.0 393.6 182.4 22.8 195.2 162.2 175.4 20.8 163.5 -635.3 -637.8 -178.4 260.4 164.8 248.5 -580.9 -153.6 -523.1 253.5 -803.0 -518.9 -112.3 -41.1 -148.3 C10H14 -73.3 C10H14 -78.6 C10H14 -78.0 C4H10O C4H10S C3H7NO3 C8H16O2 C9H12O C9H12O C9H12O C9H7N CHNS C3H3NO C2H2O Kr C12H22O11 C12H24O12 La Cl3La I3La LaS La2O3 Lr Pb Br2Pb CO3Pb Cl2Pb Cl4Pb CrO4Pb F2Pb F4Pb I2Pb O3PbSi MoO4Pb N2O6Pb O4Pb2Si C2O4Pb O4Pb3 O2Pb OPb OPb Sº(l)/ J mol-1 K-1 218.3 199.4 163.8 210.7 236.4 -278.8 -124.7 -229.7 -592.2 -233.7 -252.5 253.8 263.1 161.9 172.4 144.3 216.0 196.2 -270.0 42.1 -67.9 -2236.7 -2484.1 0.0 -1072.2 -668.9 -456.0 -1793.7 0.0 0.0 -278.7 -699.1 -359.4 56.9 27.1 108.8 -451.5 -1705.8 73.2 127.3 59.0 108.8 -261.9 -625.5 -314.1 64.8 161.5 131.0 136.0 26.8 80.1 87.4 -329.3 -930.9 -664.0 -941.8 -175.5 -1145.7 -1051.9 -451.9 -1363.1 -851.4 -718.4 -277.4 -219.0 -217.3 -617.1 110.5 -173.6 -1062.1 -951.4 174.9 109.6 166.1 77.4 90.0 119.7 -1252.6 -750.1 -601.2 -217.3 -188.9 -187.9 186.6 146.0 211.3 68.6 66.5 68.7 137.2 105.4 146.9 64.6 45.8 45.8 -696.3 -481.6 -83.7 4.0 -78.4 -252.0 -90.5 -191.0 -544.9 -182.2 -196.0 -175.3 204.6 127.6 78.6 -47.5 0.0 Standard Thermodynamic Properties of Chemical Substances O4PbSe PbSe O4PbS PbS O3PbS PbTe C6H13NO2 C6H13NO2 C6H13NO2 C10H16 Li AlH4Li H2LiN BH4Li BrLi CLi2O3 ClLi FLi HLi HLiO ILi BLiO2 Li2O3Si LiNO3 LiNO2 Li2O ClLiO4 Li2O2 Li3O4P Li2O4S Li2S Lu Cl3Lu I3Lu Lu2O3 C6H14N2O2 Mg Br2Mg CMgO3 Cl2Mg F2Mg H2Mg H2MgO2 I2Mg MgN2O6 Mg2O4Si C2MgO4 MgO MgO4Se MgO4S MgS C4H4O4 C4H2O3 C3H2N2 Mn Br2Mn CMnO3 Cl2Mn MnO3Si MnN2O6 Mn2O4Si MnO Mn3O4 Mn2O3 MnO2 MnSe -609.2 -102.9 -920.0 -100.4 -669.9 -70.7 -640.6 -637.3 -637.4 Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 -504.9 -101.7 -813.0 -98.7 167.8 102.5 148.5 91.2 50.2 103.2 49.5 -69.5 110.0 50.5 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Cp(l)/ J mol-1 K-1 200.1 -44.7 29.1 78.7 24.9 83.2 -125.0 -342.0 -1132.1 -384.4 -587.7 -68.3 -441.5 -270.3 -976.1 -1557.2 -381.1 -302.0 -561.2 75.9 74.3 90.4 59.3 35.7 20.0 42.8 86.8 51.5 79.8 90.0 96.0 37.6 82.6 -1321.7 115.1 117.6 51.0 26.9 -1789.0 110.0 101.8 32.7 117.2 65.7 89.6 57.2 31.1 63.2 129.7 164.0 95.1 24.9 -503.8 -1012.1 -591.8 -1071.1 -35.9 -833.5 -358.2 -589.4 -2055.1 141.9 118.5 -569.3 27.0 37.2 -1170.6 -341.8 91.6 50.3 160.8 96.5 45.6 137.0 32.0 26.3 -816.7 -440.5 -1240.5 85.8 118.2 89.1 81.5 72.9 86.4 -1632.1 -362.9 -1283.2 -881.1 -465.1 -111.7 163.2 59.7 155.6 110.5 53.1 90.8 129.9 45.4 139.7 107.7 54.1 51.0 99.1 48.0 41.6 27.9 49.6 51.0 59.8 99.1 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 -486.8 -54.5 0.0 -116.3 -179.5 -190.8 -351.2 -1215.9 -408.6 -616.0 -90.5 -487.5 -270.4 -1032.2 -1648.1 -483.1 -372.4 -597.9 -381.0 -634.3 -2095.8 -1436.5 -441.4 0.0 -945.6 -548.0 -1878.2 -678.7 0.0 -524.3 -1095.8 -641.3 -1124.2 -75.3 -924.5 -364.0 -790.7 -2174.0 -1269.0 -601.6 -968.5 -1284.9 -346.0 -789.4 -469.8 186.4 0.0 -384.9 -894.1 -481.3 -1320.9 -576.3 -1730.5 -385.2 -1387.8 -959.0 -520.0 -106.7 Sº(l)/ J mol-1 K-1 249.0 159.3 126.6 138.8 20.8 -229.0 -234.2 214.4 46.0 427.6 -649.0 387.8 184.8 20.9 147.1 112.5 148.6 20.8 -679.4 -398.3 265.5 280.7 238.5 173.7 20.8 54.1 75.5 71.4 61.6 35.4 77.0 Thermochem Name Lead(II) selenate Lead(II) selenide Lead(II) sulfate Lead(II) sulfide Lead(II) sulfite Lead(II) telluride DL-Leucine D-Leucine L-Leucine d-Limonene Lithium Lithium aluminum hydride Lithium amide Lithium borohydride Lithium bromide Lithium carbonate Lithium chloride Lithium fluoride Lithium hydride Lithium hydroxide Lithium iodide Lithium metaborate Lithium metasilicate Lithium nitrate Lithium nitrite Lithium oxide Lithium perchlorate Lithium peroxide Lithium phosphate Lithium sulfate Lithium sulfide Lutetium Lutetium chloride Lutetium iodide Lutetium oxide DL-Lysine Magnesium Magnesium bromide Magnesium carbonate Magnesium chloride Magnesium fluoride Magnesium hydride Magnesium hydroxide Magnesium iodide Magnesium nitrate Magnesium orthosilicate Magnesium oxalate Magnesium oxide Magnesium selenate Magnesium sulfate Magnesium sulfide Maleic acid Maleic anhydride Malononitrile Manganese Manganese(II) bromide Manganese(II) carbonate Manganese(II) chloride Manganese(II) metasilicate Manganese(II) nitrate Manganese(II) orthosilicate Manganese(II) oxide Manganese(II,III) oxide Manganese(III) oxide Manganese(IV) oxide Manganese(II) selenide ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 5-25 Standard Thermodynamic Properties of Chemical Substances 5-26 Name Thermochem Manganese(II) sulfide (α form) D-Mannitol D-Mannose Mendelevium Mercapto Mercury Mercury(I) bromide Mercury(II) bromide Mercury(I) carbonate Mercury(I) chloride Mercury(II) chloride Mercury(I) iodide Mercury(II) iodide (red) Mercury(II) oxalate Mercury(II) oxide Mercury(I) sulfate Mercury(II) sulfate Mercury(II) sulfide (red) Mercury(II) telluride Mesityl oxide Metaboric acid (β form) Metaphosphoric acid Metasilicic acid Methacrylic acid Methane Methanethiol Methanol L-Methionine 2-Methoxyethanol 2-Methoxyethyl acetate Methyl Methyl acetate Methyl acetoacetate Methyl acrylate 2-Methylacrylonitrile Methylamine Methylamine hydrochloride 2-Methylaniline 3-Methylaniline 4-Methylaniline N-Methylaniline Methyl benzoate 1-Methylbicyclo[3.1.0] hexane 3-Methyl-1,2-butadiene 2-Methyl-1,3-butadiene 2-Methyl-1-butanethiol, (+) 3-Methyl-1-butanethiol 2-Methyl-2-butanethiol 3-Methyl-2-butanethiol Methyl butanoate 2-Methylbutanoic acid 3-Methylbutanoic acid 2-Methyl-1-butanol, (±)3-Methyl-1-butanol 2-Methyl-2-butanol 3-Methyl-2-butanol, (±)3-Methyl-2-butanone 2-Methyl-1-butene 3-Methyl-1-butene 2-Methyl-2-butene Methyl trans-2-butenoate 3-Methylbutyl 2-chloropropanoate 3-Methylbutyl 3-chloropropanoate ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 MnS C6H14O6 C6H12O6 Md HS Hg Br2Hg2 Br2Hg CHg2O3 Cl2Hg2 Cl2Hg Hg2I2 HgI2 C2HgO4 HgO Hg2O4S HgO4S HgS HgTe C6H10O BHO2 HO3P H2O3Si C4H6O2 CH4 CH4S CH4O C5H11NO2S C3H8O2 C5H10O3 CH3 C3H6O2 C5H8O3 C4H6O2 C4H5N CH5N CH6ClN C7H9N C7H9N C7H9N C7H9N C8H8O2 C7H12 -214.2 -218.4 Sº(c)/ J mol-1 K-1 78.2 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 50.0 -1314.5 -1263.0 0.0 0.0 -206.9 -170.7 -553.5 -265.4 -224.3 -121.3 -105.4 -678.2 -90.8 -743.1 -707.5 -58.2 -42.0 -181.1 -153.1 -468.1 -210.7 -178.6 -111.0 -101.7 218.0 172.0 180.0 191.6 146.0 233.5 180.0 -58.5 -625.8 70.3 200.7 44.1 132.0 -50.6 82.4 48.4 -794.3 -948.5 -1188.7 -723.4 38.0 -1092.4 134.0 75.9 28.0 142.7 61.4 113.3 31.8 195.7 175.0 32.3 20.8 -561.9 -551.0 240.1 42.2 -74.6 -22.9 -201.0 -413.5 -50.5 -9.3 -162.3 186.3 255.2 239.9 35.7 50.3 44.1 145.7 -413.3 147.9 194.2 324.4 38.7 86.0 -22.5 32.7 242.9 50.1 56.4 54.6 55.3 167.6 165.4 167.7 351.0 352.5 347.0 130.2 125.5 126.2 212.5 161.1 -46.7 -239.2 -7.7 -166.6 169.2 126.8 90.5 81.1 -577.5 171.1 310.0 -445.9 -623.2 -362.2 -47.3 141.9 239.5 35.7 150.2 158.8 126.3 102.1 -333.0 -298.1 -6.3 -8.1 -23.5 207.1 221.3 -343.5 -33.2 C5H8 C5H8 C5H12S C5H12S C5H12S C5H12S C5H10O2 C5H10O2 C5H10O2 C5H12O C5H12O C5H12O C5H12O C5H10O C5H10 C5H10 C5H10 C5H8O2 C8H15ClO2 101.2 48.2 -154.4 -154.4 -162.8 -158.8 -554.5 -561.6 -356.6 -356.4 -379.5 -366.6 -299.5 -61.1 -51.5 -68.6 -382.9 -627.3 C8H15ClO2 -593.4 229.3 152.6 290.1 198.1 -287.9 1.7 75.5 -114.9 -114.9 -127.1 -121.3 198.2 247.1 268.5 254.0 253.3 251.0 179.9 157.2 156.1 152.8 -510.0 -301.4 -300.7 -329.3 -313.5 -262.6 -35.2 -27.5 -41.7 -341.9 -575.0 -539.4 Standard Thermodynamic Properties of Chemical Substances C5H12O C13H11N C3H5ClO2 C5H10 C6H10O2 Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 -313.6 C9H18O2 C19H36O2 C4H7NO C3H6O Sº(l)/ J mol-1 K-1 265.3 Cp(l)/ J mol-1 K-1 187.5 105.5 -487.0 -44.5 -395.0 C7H14 C7H14O C7H14O C7H14O C7H14O C7H14O C7H14O C6H12 C6H12O C6H10O C6H10 C6H10 C6H10 C4H8 C11H22O2 C6H12O2 C7H6N2O4 C5H10O2 C4H8O2 C13H26O2 CH2 C5H8 C7H12 C7H12O C2H5NO C2H4O2 C5H4O3 C7H14O6 C8H18 C8H18 C8H18 C8H16O2 C7H16 C7H16 C7H14O2 C7H14 C7H14 C7H14 C7H10O2 CH6N2 CH C2H3NO C2H3NS C5H8O2 C11H10 C11H10 CH3NO3 CH3NO2 C3H5NO4 C4H9NO2 C4H9NO3 C10H22 C10H22 C10H20O2 C19H36O2 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 -283.7 201.0 -444.0 -350.2 -190.1 -390.2 -415.7 -416.1 -394.4 -413.2 -433.3 -137.9 -345.5 -265.2 -36.4 -23.7 -17.6 1.7 -640.5 -530.0 184.8 -154.7 -327.0 -352.5 -350.9 -329.1 -347.5 -367.2 -106.2 -3.8 7.4 14.6 257.9 -66.4 -573.8 -491.2 33.2 -376.9 -352.0 -614.9 390.4 121.6 -25.2 -416.1 -386.9 -693.0 93.8 -61.3 -277.6 123.8 119.1 -386.1 -504.5 372.9 -357.4 -447.2 194.9 33.8 285.3 64.4 278.8 71.1 305.8 76.6 286.9 72.6 -1233.3 -255.0 -252.3 -251.6 -567.1 -229.5 -226.4 -540.2 -100.0 -115.9 -112.7 -242.7 54.2 356.4 362.6 180.0 323.3 252.0 250.2 251.1 285.1 222.9 -215.3 -212.5 -211.9 -515.5 -194.5 -191.3 -492.2 -65.7 -79.4 -76.8 165.9 134.9 94.7 595.8 254.8 191.2 224.4 217.1 157.3 187.0 -92.0 79.4 56.3 44.9 220.0 196.0 -156.3 -43.4 -464.0 -217.2 106.7 -122.0 -66.1 -177.1 -410.1 -309.8 -307.9 -616.2 -737.0 -590.3 -734.5 -169.5 -123.0 420.1 423.8 196.5 313.3 314.4 120.4 -260.2 -258.6 -554.2 -533.9 -649.9 -130.5 -94.7 Thermochem Name Methyl tert-butyl ether 9-Methyl-9H-carbazole Methyl chloroacetate Methylcyclobutane Methyl cyclobutanecarboxylate Methylcyclohexane cis-2-Methylcyclohexanol trans-2-Methylcyclohexanol,(±)cis-3-Methylcyclohexanol,(±)trans-3-Methylcyclohexanol,(±)cis-4-Methylcyclohexanol trans-4-Methylcyclohexanol Methylcyclopentane cis-2-Methylcyclopentanol 2-Methylcyclopentanone 1-Methylcyclopentene 3-Methylcyclopentene 4-Methylcyclopentene Methylcyclopropane Methyl decanoate Methyl 2,2-dimethylpropanoate 1-Methyl-2,4-dinitrobenzene 4-Methyl-1,3-dioxane 2-Methyl-1,3-dioxolane Methyl dodecanoate Methylene Methylenecyclobutane Methylenecyclohexane 2-Methylenecyclohexanol N-Methylformamide Methyl formate 3-Methyl-2,5-furandione Methyl α-D-glucopyranoside 2-Methylheptane 3-Methylheptane 4-Methylheptane Methyl heptanoate 2-Methylhexane 3-Methylhexane Methyl hexanoate 5-Methyl-1-hexene cis-3-Methyl-3-hexene trans-3-Methyl-3-hexene Methyl 2-hexynoate Methylhydrazine Methylidyne Methyl isocyanate Methyl isothiocyanate Methyl methacrylate 1-Methylnaphthalene 2-Methylnaphthalene Methyl nitrate Methyl nitrite Methyl nitroacetate 2-Methyl-2-nitropropane 2-Methyl-2-nitro-1-propanol 2-Methylnonane 5-Methylnonane Methyl nonanoate Methyl trans-9-octadecenoate Methyl octanoate Methyl cis-9-octadecenoate 2-Methyl-2-oxazoline Methyloxirane ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 5-27 Standard Thermodynamic Properties of Chemical Substances 5-28 Name Thermochem Methyl pentadecanoate 2-Methylpentane 3-Methylpentane 2-Methyl-2,4-pentanediol 2-Methyl-2-pentanethiol Methyl pentanoate 2-Methyl-1-pentanol 3-Methyl-2-pentanol 4-Methyl-2-pentanol 2-Methyl-3-pentanol 3-Methyl-3-pentanol 4-Methyl-2-pentanone 2-Methyl-3-pentanone 2-Methyl-1-pentene 3-Methyl-1-pentene 4-Methyl-1-pentene 2-Methyl-2-pentene 3-Methyl-cis-2-pentene 3-Methyl-trans-2-pentene 4-Methyl-cis-2-pentene 4-Methyl-trans-2-pentene Methyl pentyl sulfide 2-Methylpiperidine, (±)1-Methyl-2-piperidinone 2-Methylpropanamide N-Methylpropanamide 2-Methyl-1,2propanediamine 2-Methyl-1,2-propanediol 2-Methylpropanenitrile 2-Methyl-1-propanethiol 2-Methyl-2-propanethiol Methyl propanoate 2-Methylpropanoic acid 2-Methyl-1-propanol 2-Methyl-2-propanol Methyl propyl ether Methyl propyl sulfide 2-Methylpyridine 3-Methylpyridine 4-Methylpyridine 1-Methylpyrrole 2-Methylpyrrole 3-Methylpyrrole N-Methyl-2-pyrrolidinone Methyl salicylate Methylsilane Methyl tetradecanoate 4-Methylthiazole Methylthiirane 2-Methylthiophene 3-Methylthiophene Methyl tridecanoate Methyl undecanoate N-Methylurea Molybdenum Molybdenum carbonyl Molybdenum(VI) fluoride Molybdenum(IV) oxide Molybdenum(VI) oxide Molybdenum silicide (Mo3Si) Molybdenum(IV) sulfide Morpholine β-Myrcene Naphthalene 1-Naphthaleneacetic acid ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 C16H32O2 C6H14 C6H14 C6H14O2 C6H14S C6H12O2 C6H14O C6H14O C6H14O C6H14O C6H14O C6H12O C6H12O C6H12 C6H12 C6H12 C6H12 C6H12 C6H12 C6H12 C6H12 C6H14S C6H13N C6H11NO C4H9NO C4H9NO C4H12N2 C4H10O2 C4H7N C4H10S C4H10S C4H8O2 C4H8O2 C4H10O C4H10O C4H10O C4H10S C6H7N C6H7N C6H7N C5H7N C5H7N C5H7N C5H9NO C8H8O3 CH6Si C15H30O2 C4H5NS C3H6S C5H6S C5H6S C14H28O2 C12H24O2 C2H6N2O Mo C6MoO6 F6Mo MoO2 MoO3 Mo3Si MoS2 C4H9NO C10H16 C10H8 C12H10O2 Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 -771.0 -204.6 -202.4 Sº(l)/ J mol-1 K-1 290.6 292.5 -188.3 -514.2 Cp(l)/ J mol-1 K-1 193.7 190.7 336.0 229.3 248.0 275.9 273.0 -394.7 -396.4 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 -680.0 -174.6 -171.9 -148.3 -471.1 293.4 213.3 -325.9 -90.0 -78.2 -80.0 -98.5 -94.5 -94.6 -87.0 -91.6 -167.1 -124.9 -293.0 -286.0 -59.4 -49.5 -51.3 -66.9 -62.3 -63.1 -57.5 -61.5 -121.8 -84.4 -368.6 -282.6 179.0 -133.9 -90.3 -539.7 -13.8 -132.0 -140.5 23.4 -97.3 -109.6 -334.7 -359.2 -266.0 -118.5 56.7 61.9 59.2 62.4 23.3 20.5 -262.2 214.7 193.3 262.9 272.5 216.3 209.1 -877.7 28.7 325.9 24.1 242.3 -588.9 -745.1 -125.2 -235.1 -533.0 -668.0 -125.7 -225.9 46.3 77.7 106.3 62.6 56.0 75.0 93.1 63.6 -1585.5 -283.8 -312.5 -238.1 -82.2 99.2 106.4 103.8 103.1 74.0 70.2 326.7 113.6 256.5 65.9 307.8 249.0 -743.9 67.9 11.3 44.6 43.1 -717.9 -665.2 -332.8 0.0 -982.8 171.2 173.0 181.5 218.6 165.4 171.6 158.6 158.7 159.0 218.5 -1473.0 259.7 149.8 169.8 -656.9 111.8 45.8 83.5 82.5 -635.3 -593.8 658.1 -912.1 -1557.7 612.5 -856.0 -1472.2 182.0 490.0 350.5 20.8 205.0 120.6 150.6 224.1 333.1 131.9 164.8 14.5 78.5 -359.2 201.6 167.4 165.7 Standard Thermodynamic Properties of Chemical Substances Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 C12H10O2 C11H8O2 -371.9 -333.5 -223.1 C11H8O2 -346.1 -232.5 C10H8O C10H8O C10H9N C10H9N Nd Cl3Nd F3Nd Nd2O3 Ne C5H12 Ni Br2Ni C4NiO4 Cl2Ni F2Ni H2NiO2 I2Ni Ni2O3 NiO4S NiS Nb Cl5Nb F5Nb NbO NbO2 Nb2O5 H2N2O2 HNO3 NO C6H9NO6 C3H5NO3 C6H6N2O2 C6H6N2O2 C6H6N2O2 C6H5NO2 C7H5NO4 C7H5NO4 C7H5NO4 C4H9NO2 C4H9NO3 C10H21NO2 C4H10N2O2 C2H5NO2 C2H5NO3 C2H3NO2 C4H3NO3 C5H3NO5 N2 N NO2 N2O5 N2O4 Cl3N F3N N2O3 CH4N4O2 CH3NO2 C7H7NO2 C10H7NO2 C5H11NO2 C6H5NO3 -121.5 -124.1 67.8 60.2 0.0 -1041.0 -1657.0 -1807.9 179.0 -1720.8 166.9 172.8 71.5 27.5 113.0 158.6 111.3 -30.4 -29.9 132.8 134.3 327.6 -190.2 0.0 -212.1 29.9 26.1 -259.0 -604.1 -447.2 97.7 73.6 88.0 71.7 64.1 -759.7 -79.5 92.0 53.0 36.4 210.5 160.2 48.1 54.5 137.2 138.0 47.1 24.6 148.1 134.7 41.3 57.5 132.1 -633.0 -305.3 -651.4 -529.7 -78.2 -489.5 -872.9 -82.0 0.0 -797.5 -1813.8 -405.8 -796.2 -1899.5 -89.5 -683.2 -1699.0 -378.6 -740.5 -1766.0 -174.1 -588.2 -80.7 313.4 155.6 204.6 109.9 292.4 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 366.6 149.4 147.8 189.4 22.1 146.3 20.8 0.0 -168.0 429.7 384.5 182.2 23.4 -602.9 -587.2 410.6 145.2 725.9 -703.7 -1739.7 681.1 -646.0 -1673.6 186.3 400.6 321.9 30.2 120.8 97.1 -133.9 91.3 -73.5 87.6 266.9 210.8 54.1 29.9 63.8 58.4 58.8 68.5 348.8 120.4 -143.9 369.9 115.1 -53.0 -103.8 320.5 79.0 300.5 73.7 -1311.9 -26.1 -38.3 -42.0 166.0 158.8 167.0 -278.6 -9.4 -14.4 -20.7 12.5 185.8 -378.8 -394.7 -392.2 -192.5 -390.0 -351.5 -106.2 -143.9 -350.7 134.4 33.3 -28.8 -104.1 -516.8 -43.1 113.9 178.2 143.1 -19.5 230.0 97.5 209.2 142.7 50.3 0.0 472.7 33.2 13.3 11.1 455.5 51.3 117.1 99.8 191.6 153.3 240.1 355.7 304.4 29.1 20.8 37.2 95.3 79.2 -132.1 86.6 -90.6 142.4 260.8 314.7 53.4 72.7 282.9 55.5 390.9 137.1 -92.4 -112.6 -22.8 42.6 -215.4 -202.4 -14.4 171.8 106.6 -80.8 30.7 111.2 -164.4 Thermochem Name 2-Naphthaleneacetic acid 1-Naphthalenecarboxylic acid 2-Naphthalenecarboxylic acid 1-Naphthol 2-Naphthol 1-Naphthylamine 2-Naphthylamine Neodymium Neodymium(III) chloride Neodymium(III) fluoride Neodymium(III) oxide Neon Neopentane Nickel Nickel(II) bromide Nickel carbonyl [Ni(CO)4] Nickel(II) chloride Nickel(II) fluoride Nickel(II) hydroxide Nickel(II) iodide Nickel(III) oxide Nickel(II) sulfate Nickel(II) sulfide Niobium Niobium(V) chloride Niobium(V) fluoride Niobium(II) oxide Niobium(IV) oxide Niobium(V) oxide Nitramide Nitric acid Nitric oxide Nitrilotriacetic acid Nitroacetone 2-Nitroaniline 3-Nitroaniline 4-Nitroaniline Nitrobenzene 2-Nitrobenzoic acid 3-Nitrobenzoic acid 4-Nitrobenzoic acid 1-Nitrobutane 3-Nitro-2-butanol 1-Nitrodecane N-Nitrodiethylamine Nitroethane 2-Nitroethanol Nitroethene 2-Nitrofuran 5-Nitro-2-furancarboxylic acid Nitrogen Nitrogen (atomic) Nitrogen dioxide Nitrogen pentoxide Nitrogen tetroxide Nitrogen trichloride Nitrogen trifluoride Nitrogen trioxide Nitroguanidine Nitromethane (Nitromethyl)benzene 1-Nitronaphthalene 1-Nitropentane 2-Nitrophenol ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 5-29 Standard Thermodynamic Properties of Chemical Substances 5-30 Name Thermochem N-Nitropiperidine 1-Nitropropane 2-Nitropropane N-Nitrosodiphenylamine N-Nitrosopiperidine Nitrosyl bromide Nitrosyl chloride Nitrosyl fluoride 2-Nitrotoluene 3-Nitrotoluene 4-Nitrotoluene Nitrous acid Nitrous oxide Nitryl chloride Nitryl fluoride Nobelium Nonaborane(15) Nonane Nonanedioic acid 1,9-Nonanediol Nonanoic acid 1-Nonanol 2-Nonanone 5-Nonanone 1-Nonyne L-Norleucine Octadecane cis-9-Octadecenoic acid 1,7-Octadiyne Octanal Octanamide Octane 1,8-Octanediol Octanenitrile Octanoic acid 1-Octanol 2-Octanol 2-Octanone 1-Octene cis-2-Octene trans-2-Octene 1-Octen-3-yne Octyldimethylamine Orthosilicic acid Osmium Osmium(III) chloride Osmium(VI) fluoride Osmium(VIII) oxide Oxalic acid Oxalyl chloride Oxalyl dihydrazide Oxamic acid Oxamide Oxazole Oxetane 2-Oxetanone Oxirane Oxomethyl (HCO) Oxygen Oxygen (atomic) Oxymethurea Ozone Palladium Palladium(II) oxide Palladium(II) sulfide Paraformaldehyde ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 C5H10N2O2 C3H7NO2 C3H7NO2 C12H10N2O C5H10N2O BrNO ClNO FNO C7H7NO2 C7H7NO2 C7H7NO2 HNO2 N2O ClNO2 FNO2 No B9H15 C9H20 C9H16O4 C9H20O2 C9H18O2 C9H20O C9H18O C9H18O C9H16 C6H13NO2 C18H38 C18H34O2 C8H10 C8H16O C8H17NO C8H18 C8H18O2 C8H15N C8H16O2 C8H18O C8H18O C8H16O C8H16 C8H16 C8H16 C8H12 C10H23N H4O4Si Os Cl3Os F6Os O4Os C2H2O4 C2Cl2O2 C2H6N4O2 C2H3NO3 C2H4N2O2 C3H3NO C3H6O C3H4O2 C2H4O CHO O2 O C3H8N2O3 O3 Pd OPd PdS (CH2O)x Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 -93.0 -167.2 -180.3 Cp(l)/ J mol-1 K-1 170.3 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 -44.5 -124.3 -138.9 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 350.0 104.1 227.2 -31.1 16.6 82.2 51.7 -66.5 82.4 66.1 -51.0 273.7 261.7 248.1 45.5 44.7 41.3 31.0 -79.5 81.6 12.6 -46.0 103.7 54.4 254.1 220.0 272.2 260.4 45.6 38.6 53.2 49.8 357.5 364.9 187.0 -9.7 -31.5 -48.1 172.3 0.0 -274.7 284.4 -659.7 -453.4 -397.2 -398.2 16.3 362.4 158.4 -228.2 -1054.3 -657.6 -639.1 -567.4 480.2 401.4 303.6 485.6 -577.3 -376.5 -340.7 -344.9 62.3 -414.6 577.0 334.4 -473.2 -250.1 254.6 -291.9 -362.7 -208.5 365.4 -626.6 -107.3 -636.0 -426.5 297.9 305.2 330.1 273.3 241.0 239.0 239.0 -124.5 -135.7 -135.7 140.7 -232.8 -1481.1 0.0 -190.4 -1332.9 -394.1 -829.9 -304.9 192.0 32.6 246.0 143.9 109.8 -50.5 -554.3 -355.6 -81.3 24.7 791.0 745.0 192.6 20.8 91.0 -337.2 -731.8 -335.8 -292.8 -662.7 358.1 293.8 320.6 120.8 74.1 86.2 47.9 34.6 29.4 21.9 39.2 20.8 -367.6 -295.2 -661.2 -504.4 -48.0 -110.8 -329.9 -78.0 -11.8 175.3 153.9 122.1 88.0 -552.3 -387.1 -15.5 -80.5 -282.9 -52.6 43.1 0.0 249.2 231.7 242.5 224.7 205.2 161.1 142.7 378.2 348.9 163.2 339.7 325.9 238.9 167.1 218.0 -13.0 28.0 -717.0 0.0 -85.4 -75.0 -177.6 37.6 -67.0 46.0 26.0 31.4 Standard Thermodynamic Properties of Chemical Substances C6H12O3 B5H9 B5H11 C2HCl5 C6HCl5O C15H30O2 C15H32O C5H8 C5H8 C5H8 C5H8 C5H8 C5H12O4 C5H8N4O12 C6HF5 C2HF5 C6HF5O C7H3F5 C11H16 C5H10O C5H11NO C5H12 C5H8O4 C5H12O2 C5H8O2 C5H9N C5H12S C5H10O2 C5H12O C5H12O C5H12O C5H10O C5H10O C5H10 C5H10 C5H10 C5H7N C5H8O2 C5H6 C5H6 C14H23N3O10 C7H14O2 C5H13N ClHO4 ClFO3 C4F10 C4F8 C6F12 C6F10 C7F16 C7F14 C3F8 C7F8 C2H4O3 HO4Re C20H12 C14H10 C14H8O2 C13H9N C12H8N2 C6H6O C9H11NO2 C6H8N2 C7H8N2O C8H8O H3P Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 -673.1 42.7 73.2 -187.6 -292.5 -861.7 -658.2 253.2 202.0 443.3 -920.6 -538.6 -852.7 171.8 Sº(l)/ J mol-1 K-1 184.2 Cp(l)/ J mol-1 K-1 151.1 173.8 -811.7 -1007.7 -883.8 -631.7 73.2 103.3 -142.0 173.6 230.6 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 280.6 321.0 99.6 130.3 614.7 294.8 279.0 64.9 -699.0 140.7 81.4 76.1 105.7 133.1 -776.7 -387.0 -806.5 -1100.4 -841.8 -1024.1 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 306.4 225.8 -144.6 -267.2 -379.5 -173.5 167.2 -842.7 -67.2 -228.4 -290.2 -146.9 -960.0 -528.8 -423.8 -33.1 -151.3 -559.4 -351.6 -365.2 -368.9 -297.3 -296.5 -46.9 -53.7 -58.2 80.9 -430.6 226.5 228.2 259.8 266.0 262.6 258.6 256.5 210.3 208.1 239.7 184.1 190.9 154.0 151.7 157.0 -450.8 -382.0 10.5 -110.0 -491.9 -294.6 -311.0 -314.9 -258.8 -257.9 -21.1 -27.6 -31.9 125.7 Thermochem Name Paraldehyde Pentaborane(9) Pentaborane(11) Pentachloroethane Pentachlorophenol Pentadecanoic acid 1-Pentadecanol 1,2-Pentadiene cis-1,3-Pentadiene trans-1,3-Pentadiene 1,4-Pentadiene 2,3-Pentadiene Pentaerythritol Pentaerythritol tetranitrate Pentafluorobenzene Pentafluoroethane Pentafluorophenol 2,3,4,5,6-Pentafluorotoluene Pentamethylbenzene Pentanal Pentanamide Pentane Pentanedioic acid 1,5-Pentanediol 2,4-Pentanedione Pentanenitrile 1-Pentanethiol Pentanoic acid 1-Pentanol 2-Pentanol 3-Pentanol 2-Pentanone 3-Pentanone 1-Pentene cis-2-Pentene trans-2-Pentene trans-3-Pentenenitrile 4-Pentenoic acid cis-3-Penten-1-yne trans-3-Penten-1-yne Pentetic acid Pentyl acetate Pentylamine Perchloric acid Perchloryl fluoride Perfluorobutane Perfluorocyclobutane Perfluorocyclohexane Perfluorocyclohexene Perfluoroheptane Perfluoromethylcyclohexane Perfluoropropane Perfluorotoluene Peroxyacetic acid Perrhenic acid Perylene Phenanthrene 9,10-Phenanthrenedione Phenanthridine Phenazine Phenol L-Phenylalanine Phenylhydrazine Phenylurea Phenyl vinyl ether Phosphine ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 5-31 -2225.2 261.0 218.0 -40.6 -23.8 48.2 127.2 -2406.3 -1963.5 -3420.0 -2931.1 -1311.1 561.8 419.0 353.1 355.5 262.3 -1542.6 -2370.4 -1932.7 -3383.6 -2897.2 -1783.2 82.4 -762.3 182.8 116.2 -154.7 141.9 237.0 -165.1 -466.9 -656.4 158.2 264.6 215.1 274.9 220.6 144.0 213.6 127.4 203.0 141.0 217.0 207.5 -46.6 240.5 328.8 -96.4 -312.9 202.9 -218.6 -26.2 22.7 5.4 13.5 210.2 37.1 Standard Thermodynamic Properties of Chemical Substances 5-32 Name Thermochem Phosphinic acid Phosphonic acid Phosphonium chloride Phosphoric acid Phosphorus (white) Phosphorus (red) Phosphorus (black) Phosphorus(III) bromide Phosphorus(V) bromide Phosphorus(III) chloride Phosphorus(V) chloride Phosphorus dioxide Phosphorus(III) fluoride Phosphorus(V) fluoride Phosphorus(III) iodide Phosphorus monoxide Phosphorus nitride Phosphoryl bromide Phosphoryl chloride Phosphoryl fluoride Phthalic acid Phthalic anhydride α-Pinene β-Pinene Piperazine 2,5-Piperazinedione Piperidine 2-Piperidinone Platinum Platinum(II) bromide Platinum(III) bromide Platinum(IV) bromide Platinum(II) chloride Platinum(III) chloride Platinum(IV) chloride Platinum(VI) fluoride Platinum(IV) iodide Platinum(II) sulfide Platinum(IV) sulfide Plutonium Polonium Potassium Potassium acetate Potassium aluminum hydride Potassium amide Potassium borohydride Potassium bromate Potassium bromide Potassium carbonate Potassium chlorate Potassium chloride Potassium cyanide Potassium dihydrogen phosphate Potassium fluoride Potassium formate Potassium hexafluorosilicate Potassium hydride Potassium hydrogen carbonate Potassium hydrogen fluoride Potassium hydrogen sulfate Potassium hydroxide Potassium iodate Potassium iodide ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 H3O2P H3O3P ClH4P H3O4P P P P Br3P Br5P Cl3P Cl5P O2P F3P F5P I3P OP NP Br3OP Cl3OP F3OP C8H6O4 C8H4O3 C10H16 C10H16 C4H10N2 C4H6N2O2 C5H11N C5H9NO Pt Br2Pt Br3Pt Br4Pt Cl2Pt Cl3Pt Cl4Pt F6Pt I4Pt PtS PtS2 Pu Po K C2H3KO2 AlH4K -604.6 -964.4 -145.2 -1284.4 0.0 -17.6 -39.3 H2KN BH4K BrKO3 BrK CK2O3 ClKO3 ClK CKN H2KO4P -128.9 -227.4 -360.2 -393.8 -1151.0 -397.7 -436.5 -113.0 -1568.3 FK CHKO2 F6K2Si HK CHKO3 -567.3 -679.7 -2956.0 -57.7 -963.2 F2HK HKO4S HKO IKO3 IK -927.7 -1160.6 -424.6 -501.4 -327.9 Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 -595.4 -1124.3 110.5 41.1 22.8 106.1 23.8 21.2 -1271.7 -1123.6 150.8 145.0 316.5 280.1 163.2 20.8 -184.5 -175.7 240.2 -139.3 -162.8 348.1 76.0 -319.7 -272.3 217.1 -287.0 -374.9 -279.9 -958.4 -1594.4 -267.8 -305.0 -281.6 -936.9 -1520.7 -28.5 171.5 -51.9 149.4 -558.5 -1254.3 -512.9 -1205.8 311.8 364.6 252.1 273.1 300.8 374.4 222.8 211.1 359.8 325.5 285.4 71.8 112.8 39.5 58.7 84.8 78.4 31.8 29.7 89.9 84.9 68.8 520.5 192.4 25.5 348.3 122.8 -269.9 -443.5 -45.6 -63.0 -458.6 -597.1 -782.0 -460.1 207.9 180.0 -520.8 222.5 138.8 188.1 160.0 -371.4 28.3 38.7 -16.4 -7.7 -45.6 -446.5 -86.4 -306.6 0.0 -82.0 -120.9 -156.5 -123.4 -182.0 -231.8 41.6 25.9 210.0 179.9 -47.1 565.3 235.6 -72.8 -81.6 -108.8 0.0 0.0 0.0 -723.0 -183.7 -76.1 -99.6 55.1 74.7 43.4 65.9 64.7 29.6 -160.3 -271.2 -380.7 -1063.5 -296.3 -408.5 -101.9 -1415.9 106.3 149.2 95.9 155.5 143.1 82.6 128.5 134.9 96.1 105.2 52.3 114.4 100.3 51.3 66.3 116.6 -537.8 66.6 49.0 -2798.6 226.0 -863.5 115.5 -859.7 -1031.3 -379.4 -418.4 -324.9 104.3 138.1 81.2 151.5 106.3 89.0 60.5 160.3 20.8 -214.6 -233.3 239.1 36.5 -232.0 -229.7 238.3 49.2 76.9 68.9 106.5 52.9 Standard Thermodynamic Properties of Chemical Substances Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 BKO2 KNO3 KNO2 C2K2O4 K2O BrKO4 ClKO4 IKO4 KMnO4 K2O2 K3O4P KNa K2O4S K2S KO2 CKNS Pr Cl3Pr O3Pr2 C5H9NO2 Pm C3H6O C3H7NO C3H8 C3H6N2O2 C3H10N2 C3H8O2 C3H8O2 C3H4O2 C3H8S2 C3H5N C3H8S C3H8S C3H6O2 C6H10O3 C3H8O C3H8O C3H6 C5H6O4 -981.6 -494.6 -369.8 -1346.0 -361.5 -287.9 -432.8 -467.2 -837.2 -494.1 -1950.2 -923.4 -394.9 -306.6 80.0 133.1 152.1 66.7 96.4 107.4 -174.4 -303.1 -361.4 -737.6 -425.1 170.1 151.0 175.7 171.7 102.1 120.2 112.4 -1437.8 -380.7 -284.9 -200.2 0.0 -1056.9 -1809.6 -515.2 0.0 -1321.4 -364.0 -239.4 -178.3 175.6 105.0 116.7 124.3 73.2 131.5 C6H6O6 -1224.4 C6H6O6 -1232.7 C5H10O2 C3H9N C3H10ClN C9H12 C4H9NO2 C5H9ClO2 C7H13ClO2 C4H7ClO2 C6H11ClO2 C9H18 C8H16 C4H6O3 C4H8O2 C3H7NO3 C8H16O2 C3H5N C3H4 C3H2O2 Pa Br4Pa Cl4Pa Cl5Pa C5H4N4 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 117.6 6.3 77.5 88.5 27.2 100.0 117.4 355.6 320.9 189.8 21.4 187.1 304.5 24.3 80.7 270.3 73.6 322.6 309.2 85.6 89.3 325.4 91.2 362.6 123.2 198.1 22.9 -366.2 -215.6 -185.6 -259.0 -103.8 -338.2 -120.9 -23.4 -546.1 -97.8 -501.0 -480.8 -309.1 -79.4 15.5 -99.9 -105.9 -510.7 -679.1 -302.6 -318.1 4.0 190.8 242.5 233.5 191.0 119.3 144.6 145.3 152.8 193.6 181.1 143.9 156.5 -53.6 -429.8 -408.0 -271.0 -29.8 51.7 -67.8 -76.2 -455.7 -626.5 -255.1 -272.6 20.0 Thermochem Name Potassium metaborate Potassium nitrate Potassium nitrite Potassium oxalate Potassium oxide Potassium perbromate Potassium perchlorate Potassium periodate Potassium permanganate Potassium peroxide Potassium phosphate Potassium sodium Potassium sulfate Potassium sulfide Potassium superoxide Potassium thiocyanate Praseodymium Praseodymium(III) chloride Praseodymium(III) oxide L-Proline Promethium Propanal Propanamide Propane Propanediamide 1,2-Propanediamine, (±)1,2-Propanediol 1,3-Propanediol 1,2-Propanedione 1,3-Propanedithiol Propanenitrile 1-Propanethiol 2-Propanethiol Propanoic acid Propanoic anhydride 1-Propanol 2-Propanol Propene trans-1-Propene-1,2-dicarboxylic acid cis-1-Propene-1,2,3-tricarboxylic acid trans-1-Propene-1,2,3-tricarboxylic acid Propyl acetate Propylamine Propylamine hydrochloride Propylbenzene Propyl carbamate Propyl chloroacetate Propyl 2-chlorobutanoate Propyl chlorocarbonate Propyl 3-chloropropanoate Propylcyclohexane Propylcyclopentane Propylene carbonate Propyl formate Propyl nitrate Propyl pentanoate 2-Propyn-1-amine Propyne 2-Propynoic acid Protactinium Protactinium(IV) bromide Protactinium(IV) chloride Protactinium(V) chloride 1H-Purine ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 5-33 -824.4 196.2 164.1 -101.5 -70.1 39.9 -354.7 -38.3 287.8 214.7 311.9 310.8 242.0 216.3 218.6 -552.6 -515.5 -630.7 -533.4 -537.6 -237.4 -188.8 -613.2 -500.3 -214.5 -583.0 205.7 7.9 -471.4 -467.0 -578.4 -492.7 -485.7 -192.3 -147.7 -582.5 -462.7 -174.1 -533.6 184.9 -193.2 0.0 -824.0 -1043.0 -1145.0 169.4 -787.8 -953.0 -1034.0 51.9 234.0 192.0 238.0 607.0 563.0 Standard Thermodynamic Properties of Chemical Substances 5-34 Name Thermochem Pyrazine 1H-Pyrazole Pyrene Pyridazine Pyridine 3-Pyridinecarboxylic acid Pyrimidine Pyrocatechol Pyrrole 1H-Pyrrole-2carboxaldehyde Pyrrolidine 2-Pyrrolidone Quinoline 2-Quinolinecarbonitrile 3-Quinolinecarbonitrile 2-Quinolinol 8-Quinolinol Radium Radium nitrate Radium oxide Radium sulfate Radon Resorcinol Rhenium Rhenium(III) bromide Rhenium(III) chloride Rhenium(VII) oxide Rhodium Rhodium(III) chloride Rhodium monoxide Rhodium(III) oxide D-Ribose Rubidium Rubidium amide Rubidium bromide Rubidium carbonate Rubidium chloride Rubidium fluoride Rubidium hydride Rubidium hydrogen fluoride Rubidium hydrogen sulfate Rubidium hydroxide Rubidium iodide Rubidium metaborate Rubidium nitrate Rubidium nitrite Rubidium oxide Rubidium perchlorate Rubidium peroxide Rubidium sulfate Rubidium superoxide Ruthenium Ruthenium(III) bromide Ruthenium(III) chloride Ruthenium(III) iodide Ruthenium(IV) oxide Ruthenium(VIII) oxide Salicylaldehyde Salicylaldoxime Samarium Samarium(III) chloride Samarium(III) fluoride Samarium(III) oxide Sarcosine Scandium ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 C4H4N2 C3H4N2 C16H10 C4H4N2 C5H5N C6H5NO2 C4H4N2 C6H6O2 C4H5N C5H5NO C4H9N C4H7NO C9H7N C10H6N2 C10H6N2 C9H7NO C9H7NO Ra N2O6Ra ORa O4RaS Rn C6H6O2 Re Br3Re Cl3Re O7Re2 Rh Cl3Rh ORh O3Rh2 C5H10O5 Rb H2NRb BrRb CO3Rb2 ClRb FRb HRb F2HRb HO4RbS HORb IRb BO2Rb NO3Rb NO2Rb ORb2 ClO4Rb O2Rb2 O4Rb2S O2Rb Ru Br3Ru Cl3Ru I3Ru O2Ru O4Ru C7H6O2 C7H7NO2 Sm Cl3Sm F3Sm O3Sm2 C3H7NO2 Sc 139.8 105.4 125.5 Sº(c)/ J mol-1 K-1 224.9 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 63.1 156.4 127.7 196.1 179.4 225.7 278.3 140.4 -221.5 195.7 -267.5 108.2 -41.1 -286.2 141.2 204.1 156.6 -3.6 81.0 229.7 224.9 100.2 132.7 -344.9 145.9 -354.1 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 -106.4 246.5 242.3 -144.9 82.1 0.0 -992.0 -523.0 -1471.1 -368.0 0.0 -167.0 -264.0 -1240.1 0.0 -299.2 200.5 -25.5 -796.1 71.0 222.0 -1365.6 138.0 -188.0 -1066.0 159.0 36.9 25.5 0.0 -274.7 769.9 123.8 207.1 31.5 92.4 166.1 25.0 -1100.0 556.9 130.0 176.5 20.8 176.2 20.8 724.6 188.9 20.8 -994.0 510.8 452.0 185.8 21.0 80.9 53.1 170.1 20.8 -238.0 -239.1 248.5 49.5 642.7 595.8 186.5 21.5 206.7 172.8 183.0 30.4 -367.3 377.8 336.0 174.8 22.1 385.0 -343.0 -1047.2 0.0 -113.0 -394.6 -1136.0 -435.4 -557.7 -52.3 -922.6 -1159.0 -418.8 -333.8 -971.0 -495.1 -367.4 -339.0 -437.2 -472.0 -1435.6 -278.7 0.0 -138.0 -205.0 -65.7 -305.0 -239.3 103.8 76.8 31.1 -381.8 -1051.0 -407.8 110.0 181.3 95.9 52.8 117.6 52.4 -855.6 120.1 79.4 -373.9 -328.9 -913.0 -395.8 -306.2 94.0 118.4 94.3 147.3 172.0 69.0 53.2 74.1 102.1 -306.9 161.1 -1316.9 197.4 134.1 28.5 24.1 -152.2 146.4 222.0 -183.7 0.0 -1025.9 -1778.0 -1823.0 -513.3 0.0 -1734.6 69.6 29.5 151.0 114.5 34.6 25.5 Standard Thermodynamic Properties of Chemical Substances Br3Sc Cl3Sc F3Sc O3Sc2 H2O4Se Se Se Se Br2Se O2Se F6Se OSe C3H7NO3 C3H7NO3 H4Si Si CSi CSi O2Si SSi OSi N4Si3 Ag AgBrO3 AgBr CAg2O3 AgClO3 AgCl Ag2CrO4 CAgN AgF AgF2 AgIO3 AgI AgNO3 Ag2O Ag2O2 Ag2O3 AgClO4 Ag2O4S Ag2S HSi Na C2H3NaO2 AlH4Na H2NNa N3Na BH4Na BrNaO3 BrNa CNa2O3 ClNaO3 ClNa ClNaO2 CNNaO CNNa FNa CHNaO2 F6Na2Si HNa CHNaO3 F2HNa HNa2O4P HNaO4S HNaO INaO3 -743.1 -925.1 -1629.2 -1908.8 -530.1 0.0 6.7 5.0 -1555.6 -1819.4 Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 92.0 77.0 94.2 42.4 25.4 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 -1247.0 -1234.0 300.5 67.8 227.1 227.1 227.1 -21.0 187.0 176.7 20.8 -1117.0 53.4 -1017.0 26.8 313.9 234.0 110.5 31.3 34.3 450.0 56.9 405.5 204.6 168.0 42.8 22.3 -322.0 112.5 -99.6 60.9 -126.4 223.7 211.6 32.3 29.9 284.9 246.0 173.0 20.8 361.0 107.5 77.0 153.7 20.8 -143.1 -177.1 241.2 36.3 -191.0 -193.9 229.0 48.0 -225.4 -739.0 -732.7 0.0 -62.8 -65.3 -910.7 -743.5 0.0 -10.5 -100.4 -505.8 -30.3 -127.0 -731.7 146.0 -204.6 -360.0 -171.1 -61.8 -124.4 -31.1 -24.3 33.9 -31.1 -715.9 -32.6 0.0 -708.8 -115.5 -123.8 21.7 -188.6 -334.1 -361.1 -1130.7 -365.8 -411.2 -307.0 -405.4 -87.5 -576.6 -666.5 -2909.6 -56.3 -950.8 -920.3 -1748.1 -1125.5 -425.8 -481.8 -60.2 -62.8 -856.3 -642.6 18.8 16.5 16.6 41.5 20.0 26.7 26.9 44.4 71.3 -96.9 -436.8 64.5 -109.8 -641.8 156.9 101.3 42.6 151.9 107.1 167.4 142.0 96.3 217.6 107.2 -93.7 -66.2 -33.4 -11.2 27.6 121.4 149.4 115.5 140.9 121.3 117.0 100.0 102.9 56.8 93.1 65.9 88.0 -618.4 -40.7 200.4 144.0 131.4 76.5 -607.2 51.3 123.0 28.2 79.9 -64.0 93.8 -123.9 -242.6 -349.0 -1044.4 -262.3 -384.1 76.9 96.9 101.3 128.9 86.8 135.0 123.4 72.1 66.2 76.6 86.8 -358.1 -76.4 -546.3 -599.9 -2754.2 -33.5 -851.0 -852.2 -1608.2 -992.8 -379.7 96.7 115.6 51.1 103.8 207.1 40.0 101.7 90.9 150.5 113.0 64.4 25.4 52.4 112.3 50.8 142.3 66.7 51.4 112.3 Thermochem Name Scandium bromide Scandium chloride Scandium fluoride Scandium oxide Selenic acid Selenium (gray) Selenium (α form) Selenium (vitreous) Selenium dibromide Selenium dioxide Selenium hexafluoride Selenium monoxide DL-Serine L-Serine Silane Silicon Silicon carbide (hexagonal) Silicon carbide (cubic) Silicon dioxide (α-quartz) Silicon monosulfide Silicon monoxide Silicon nitride [Si3N4] Silver Silver(I) bromate Silver(I) bromide Silver(I) carbonate Silver(I) chlorate Silver(I) chloride Silver(I) chromate Silver(I) cyanide Silver(I) fluoride Silver(II) fluoride Silver(I) iodate Silver(I) iodide Silver(I) nitrate Silver(I) oxide Silver[II] oxide [Ag2O2] Silver(III) oxide Silver(I) perchlorate Silver(I) sulfate Silver(I) sulfide Silylidyne Sodium Sodium acetate Sodium aluminum hydride Sodium amide Sodium azide Sodium borohydride Sodium bromate Sodium bromide Sodium carbonate Sodium chlorate Sodium chloride Sodium chlorite Sodium cyanate Sodium cyanide Sodium fluoride Sodium formate Sodium hexafluorosilicate Sodium hydride Sodium hydrogen carbonate Sodium hydrogen fluoride Sodium hydrogen phosphate Sodium hydrogen sulfate Sodium hydroxide Sodium iodate ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 5-35 50.5 86.6 70.4 46.9 82.7 187.1 36.4 87.6 75.0 135.3 59.5 92.0 Standard Thermodynamic Properties of Chemical Substances 5-36 Name Thermochem Sodium iodide Sodium metaborate Sodium metasilicate Sodium molybdate Sodium nitrate Sodium nitrite Sodium oxalate Sodium oxide Sodium perchlorate Sodium periodate Sodium permanganate Sodium peroxide Sodium sulfate Sodium sulfide Sodium sulfite Sodium superoxide Sodium tetraborate Sodium tetrafluoroaluminate Sodium tetrafluoroborate L-Sorbose Spiro[2.2]pentane Spiro[5.5]undecane S-Propyl thioacetate Stannane Octadecanoic acid Stibine cis-Stilbene trans-Stilbene Strontium Strontium bromide Strontium carbonate Strontium chloride Strontium fluoride Strontium formate Strontium hydride Strontium hydroxide Strontium iodide Strontium metasilicate Strontium nitrate Strontium nitrite Strontium orthosilicate Strontium oxide Strontium selenide Strontium sulfate Strontium sulfide Styrene Succinamide Succinic acid Succinic anhydride Succinimide Succinonitrile Sucrose Sulfolane Sulfur (rhombic) Sulfur (monoclinic) Sulfur bromide [SSBr2] Sulfur chloride [SSCl2] Sulfur chloride pentafluoride Sulfur dichloride Sulfur dioxide Sulfur hexafluoride Sulfuric acid Sulfur monoxide Sulfur tetrafluoride Sulfur trioxide (α-form) Sulfuryl chloride ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 INa BNaO2 Na2O3Si MoNa2O4 NNaO3 NNaO2 C2Na2O4 Na2O ClNaO4 INaO4 MnNaO4 Na2O2 Na2O4S Na2S Na2O3S NaO2 B4Na2O7 AlF4Na BF4Na C6H12O6 C5H8 C11H20 C5H10OS H4Sn C18H36O2 H3Sb C14H12 C14H12 Sr Br2Sr CO3Sr Cl2Sr F2Sr C2H2O4Sr H2Sr H2O2Sr I2Sr O3SiSr N2O6Sr N2O4Sr O4SiSr2 OSr SeSr O4SSr SSr C8H8 C4H8N2O2 C4H6O4 C4H4O3 C4H5NO2 C4H4N2 C12H22O11 C4H8O2S S S Br2S2 Cl2S2 ClF5S Cl2S O2S F6S H2O4S OS F4S O3S Cl2O2S Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 -287.8 -977.0 -1554.9 -1468.1 -467.9 -358.7 -286.1 -920.7 -1462.8 -1354.3 -367.0 -284.6 98.5 73.5 113.9 159.7 116.5 103.8 -414.2 -383.3 -429.3 -1156.0 -510.9 -1387.1 -364.8 -1100.8 -260.2 -3291.1 -375.5 -254.9 -323.0 75.1 142.3 163.0 69.1 -447.7 -1270.2 -349.8 -1012.5 -218.4 -3096.0 95.0 149.6 83.7 145.9 115.9 189.5 89.2 128.2 120.3 72.1 186.8 -1750.1 145.3 120.3 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 52.1 65.9 141.7 92.9 -1318.0 -1869.0 -1844.7 -1271.5 157.5 -244.5 -294.5 -947.7 501.5 193.7 134.5 -884.7 183.3 136.9 0.0 -717.6 -1220.1 -828.9 -1216.3 -1393.3 -180.3 -959.0 -558.1 -1633.9 -978.2 -762.3 -2304.5 -592.0 -385.8 -1453.1 -472.4 -697.1 -1140.1 -781.1 -1164.8 55.0 135.1 97.1 114.9 82.1 26.8 75.3 81.4 75.6 70.0 -1549.7 -780.0 96.7 194.6 81.6 88.5 149.9 -2191.1 -561.9 153.1 54.4 134.3 45.0 -1340.9 -467.8 117.0 68.2 48.7 167.3 153.1 191.6 145.6 32.1 22.6 345.7 105.9 188.3 227.7 49.0 147.8 232.8 41.1 130.9 164.6 20.8 277.2 236.7 167.8 23.7 -296.8 -1220.5 -300.1 -1116.5 248.2 291.5 39.9 97.0 6.3 -763.2 -395.7 -364.0 -19.9 -722.0 -371.1 -320.0 222.0 299.6 256.8 311.9 30.2 77.6 50.7 77.0 185.2 -188.3 -250.4 162.8 -781.2 145.1 252.3 236.1 164.4 1.5 103.8 -581.2 -940.5 -608.6 -459.0 139.7 -2226.1 -1827.5 182.0 147.9 -823.0 -527.9 -375.4 209.7 180.0 0.0 0.3 -13.0 -59.4 -1065.7 -50.0 -320.5 -814.0 -454.5 -374.2 70.7 -441.0 -394.1 -690.0 -373.8 156.9 138.9 113.8 134.0 Standard Thermodynamic Properties of Chemical Substances F2O2S Ta Br5Ta Cl5Ta F5Ta HTa2 O5Ta2 Tc Te O2Te F6Te Br4Te Cl4Te Tb Cl3Tb O3Tb2 C8H6O4 C18H14 C18H14 C10H16 B4H10 C2H2Br4 C2Br4 CBr4 Br4Si C16H36IN B2Cl4 C2Cl4F2 0.0 -598.3 -859.0 -1903.6 -32.6 -2046.0 0.0 0.0 -322.6 Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 41.5 25.4 -69.0 -1911.2 79.1 143.1 90.8 135.1 25.7 -270.3 49.7 79.5 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 C8H18O5 C8H20Pb C8H20Si C9H20N2O C6H2F4 B2F4 C2F4 F4N2 CF4 C3H4F4O 73.2 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 782.0 739.3 284.0 185.2 66.0 20.9 678.0 196.7 157.1 181.1 182.7 20.8 20.8 138.5 28.9 349.7 203.6 24.6 279.0 -20.6 66.1 184.3 280.3 93.2 83.9 -415.5 67.0 -431.8 387.1 358.1 377.9 102.7 91.2 97.1 -490.4 -489.9 -460.6 -407.0 357.4 382.9 95.4 123.4 356.0 362.8 102.7 100.8 388.7 115.9 -717.9 298.8 285.6 163.0 274.8 278.7 337.1 369.1 165.7 29.4 47.7 212.5 144.3 -457.3 -443.9 277.8 -523.0 -464.8 262.3 -498.6 137.7 173.6 -195.0 -50.6 -128.2 -208.7 -251.8 -687.0 3.0 -619.8 246.9 266.9 162.3 143.4 130.7 -149.2 -10.9 -95.7 239.7 145.3 -657.0 705.0 -174.9 -693.7 464.6 428.8 307.4 298.1 -883.0 109.6 623.8 -833.5 -629.6 -342.7 432.0 388.0 -260.2 -788.8 -580.6 -981.7 52.7 -380.0 -683.8 -1114.9 -216.2 -435.7 -29.2 -258.3 -436.7 33.5 -72.9 305.0 -392.9 -189.5 83.3 -617.0 330.7 90.3 -1440.1 -658.9 -8.4 -933.6 -1061.3 -1410.4 317.3 300.1 301.2 261.6 79.1 80.5 79.2 61.1 -1615.0 -184.1 -369.1 26.0 -1572.8 282.8 302.4 73.6 76.3 45.8 309.6 92.5 391.9 95.9 -316.4 -820.5 F4Si C4H8O C5H10O2 C10H12 C5H10O C5H8O2 C5H9N C4H8S C2I4 CI4 I4Si ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 -1318.0 -190.4 -326.4 0.0 -997.0 -1865.2 -816.1 C2Cl4F2 C2H2Cl4 C2H2Cl4 C2Cl4 CCl4 C3H4Cl4 C3H4Cl4 Cl4Si C6N4 C14H27N C14H28O2 C14H30O C8H20BrN Cp(l)/ J mol-1 K-1 204.3 124.0 217.5 79.9 -223.4 -379.6 -34.1 474.0 Thermochem Name Sulfuryl fluoride Tantalum Tantalum(V) bromide Tantalum(V) chloride Tantalum(V) fluoride Tantalum hydride (Ta2H) Tantalum(V) oxide Technetium Tellurium Tellurium dioxide Tellurium hexafluoride Tellurium tetrabromide Tellurium tetrachloride Terbium Terbium(III) chloride Terbium(III) oxide Terephthalic acid o-Terphenyl p-Terphenyl α-Terpinene Tetraborane(10) 1,1,2,2-Tetrapropaneethane Tetrapropaneethene Tetrapropanemethane Tetrapropanesilane Tetrabutylammonium iodide Tetrachlorodiborane 1,1,1,2-Tetrachloro-2,2-difluoroethane 1,1,2,2-Tetrachloro-1,2-difluoroethane 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrachloromethane 1,1,1,3-Tetrachloropropane 1,2,2,3-Tetrachloropropane Tetrachlorosilane Tetracyanoethene Tetradecanenitrile Tetradecanoic acid 1-Tetradecanol Tetraethylammonium bromide Tetraethylene glycol Tetraethyl lead Tetraethylsilane Tetraethylurea 1,2,4,5-Tetrafluorobenzene Tetrafluorodiborane Tetrafluoroethene Tetrafluorohydrazine Tetrafluoromethane 2,2,3,3-Tetrafluoro-1propanol Tetrafluorosilane Tetrahydrofuran Tetrahydrofurfuryl alcohol 1,2,3,4-Tetrahydronaphthalene Tetrahydropyran Tetrahydro-2H-pyran-2-one 1,2,5,6-Tetrahydropyridine Tetrahydrothiophene Tetraiodoethene Tetraiodomethane Tetraiodosilane ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 5-37 Standard Thermodynamic Properties of Chemical Substances 5-38 Name Thermochem 1-Tetralone Tetramethylammonium bromide Tetramethylammonium chloride Tetramethylammonium iodide 1,2,4,5-Tetramethylbenzene 2,2,3,3-Tetramethylbutane 2,2,4,4-Tetramethyl-1,3cyclobutanedione 1,1,2,2-Tetramethylcyclopropane Tetramethyl lead N,N,N',N'-Tetramethylmethanediamine 2,2,3,3-Tetramethylpentane 2,2,3,4-Tetramethylpentane 2,2,4,4-Tetramethylpentane 2,3,3,4-Tetramethylpentane 2,2,6,6-Tetramethylpiperidine 2,2,6,6-Tetramethyl-4piperidinone Tetramethylsilane Tetramethylstannane Tetramethylthiourea Tetramethylurea Tetranitromethane Tetraphosphorus Thallium Thallium(I) bromide Thallium(I) carbonate Thallium(I) chloride Thallium(III) chloride Thallium(I) fluoride Thallium(I) hydroxide Thallium(I) iodide Thallium(I) nitrate Thallium(I) oxide Thallium(I) selenide Thallium(I) sulfate Thallium(I) sulfide Thiacyclohexane Thianthrene Thiepane Thietane Thiirane Thiirene Thioacetamide Thioacetic acid Thiolactic acid Thionitrosyl fluoride (NSF) Thionyl chloride Thionyl fluoride Thiophene Thiourea Thiram Thorium Thorium(IV) chloride Thorium(III) fluoride Thorium(IV) fluoride Thorium hydride Thorium(IV) oxide DL-Threonine L-Threonine Thulium ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 C10H10O C4H12BrN -209.6 -251.0 C4H12ClN -276.4 C4H12IN -203.9 C10H14 C8H18 C8H12O2 -119.9 -269.0 -379.9 Sº(c)/ J mol-1 K-1 245.6 273.7 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 -226.0 -307.6 -119.8 C4H12Pb C5H14N2 97.9 -51.1 C9H20 C9H20 C9H20 C9H20 C9H19N -278.3 -277.7 -280.0 -277.9 -206.9 C4H12Si C4H12Sn C5H12N2S C5H12N2O CN4O8 P4 Tl BrTl CO3Tl2 ClTl Cl3Tl FTl HOTl ITl NO3Tl OTl2 SeTl2 O4STl2 STl2 C5H10S C12H8S2 C6H12S C3H6S C2H4S C2H2S C2H5NS C2H4OS C3H6O2S FNS Cl2OS F2OS C4H4S CH4N2S C6H12N2S4 Th Cl4Th F3Th F4Th H2Th O2Th C4H9NO3 C4H9NO3 Tm Cp(l)/ J mol-1 K-1 215.1 239.2 C7H14 C9H17NO Sº(l)/ J mol-1 K-1 135.9 -18.2 271.5 266.3 -334.2 -273.4 -264.0 -52.3 -100.0 277.3 204.1 -38.1 -262.2 38.4 0.0 -173.2 -700.0 -204.1 -315.1 -324.7 -238.9 -123.8 -243.9 -178.7 -59.0 -931.8 -97.1 -167.4 -614.6 -184.9 64.2 120.5 155.2 111.3 -195.8 -125.4 -152.4 -147.3 -59.0 -830.4 -93.7 88.0 127.6 160.7 126.0 172.0 230.5 151.0 26.3 50.9 -99.9 359.0 143.9 24.4 147.4 503.7 280.0 181.0 176.1 67.2 20.8 -67.8 -182.4 7.1 99.5 -106.3 218.2 24.7 51.6 184.9 163.3 -63.5 286.0 -65.8 60.6 82.0 300.0 11.4 -175.1 53.1 323.0 109.7 79.4 107.1 96.8 275.8 363.5 285.0 255.2 255.3 131.3 68.3 53.3 54.7 121.0 -212.5 -198.3 123.8 114.9 22.9 126.1 259.8 309.8 278.7 278.8 44.1 66.5 56.8 72.8 602.0 -964.4 -1166.1 -1759.0 560.7 -932.0 -1160.6 -1724.0 190.2 390.7 339.2 341.7 20.8 107.5 73.3 93.0 232.2 197.5 190.1 20.8 -71.7 -216.9 -468.4 -245.6 80.2 -2097.8 -139.7 -1226.4 -758.8 -807.2 0.0 -239.1 -18.8 44.9 82.4 58.9 182.2 -37.7 182.0 -89.1 40.2 0.0 -1186.2 -237.1 -236.9 -241.6 -236.1 -159.9 -1094.1 51.8 190.4 301.7 27.3 120.3 -2003.4 -100.0 -1169.2 142.0 50.7 65.2 110.7 36.7 61.8 74.0 27.0 181.2 Standard Thermodynamic Properties of Chemical Substances Cl3Tm O3Tm2 C5H6N2O2 C10H14O Br2Sn Br4Sn Cl2Sn Cl4Sn Sn H2O2Sn I2Sn I4Sn OSn O2Sn SSn Sn Ti Br2Ti Br3Ti Br4Ti Cl2Ti Cl3Ti Cl4Ti I4Ti OTi O3Ti2 O5Ti3 O2Ti C7H8 C9H6N2O2 C8H8O2 C8H8O2 C8H8O2 C6H9NO3 C2H4N4 CBr3Cl Br3ClSi CBr3F CHBr3 Br3HSi C12H27N C18H30 C12H27O4P C2HCl3O C2H2Cl3NO C2HCl3O2 C2Cl3N C2Cl4O C6H3Cl3 C6H3Cl3 C6H3Cl3 C2H3Cl3 C2H3Cl3 C2HCl3 CCl3F CHCl3 CCl3 CH3Cl3Si C3H5Cl3 C3H3Cl3 Cl3HSi C2Cl3F3 C21H21O4P C13H28 C13H24O4 -986.6 -1888.7 -462.8 -309.7 -243.5 -377.4 -325.1 -1794.5 Sº(c)/ J mol-1 K-1 139.7 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 116.7 150.8 -350.2 264.4 -2.1 -561.1 -143.5 0.1 -491.6 44.1 155.0 -280.7 -577.6 -100.0 0.0 0.0 -402.0 -548.5 -616.7 -513.8 -720.9 -251.9 -515.8 -98.3 57.2 49.0 77.0 51.2 30.7 84.9 44.3 52.6 49.3 27.0 25.1 -523.8 -589.5 -464.4 -653.5 176.6 243.5 87.4 139.7 101.7 131.5 69.8 97.2 -375.7 -519.7 -1520.9 -2459.4 -944.0 -371.5 -495.0 -1434.2 -2317.4 -888.8 249.4 50.0 78.8 129.3 50.6 125.7 40.0 97.4 154.8 55.0 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 -328.7 -218.5 -511.3 -440.1 258.6 -314.6 -331.4 411.9 103.4 -471.5 -432.2 365.8 98.3 15.1 -8.4 446.1 232.1 105.4 31.6 301.2 473.0 266.2 428.4 168.5 180.3 21.3 24.4 -549.4 -568.2 398.4 100.8 145.2 -763.2 -277.8 -726.3 353.2 95.4 157.3 287.8 50.5 8.0 -328.5 357.8 377.1 345.9 330.9 348.6 89.4 95.3 84.4 71.2 80.8 336.6 96.1 323.1 337.2 324.8 295.7 93.3 89.0 80.3 78.1 65.7 351.1 102.4 313.9 75.8 165.3 25.8 -804.2 -737.2 252.3 12.4 -416.5 -426.1 -429.2 Cp(l)/ J mol-1 K-1 Thermochem Name Thulium(III) chloride Thulium(III) oxide Thymine Thymol Tin(II) bromide Tin(IV) bromide Tin(II) chloride Tin(IV) chloride Tin (gray) Tin(II) hydroxide Tin(II) iodide Tin(IV) iodide Tin(II) oxide Tin(IV) oxide Tin(II) sulfide Tin (white) Titanium Titanium(II) bromide Titanium(III) bromide Titanium(IV) bromide Titanium(II) chloride Titanium(III) chloride Titanium(IV) chloride Titanium(IV) iodide Titanium(II) oxide Titanium(III) oxide Titanium(III,IV) oxide Titanium(IV) oxide (rutile) Toluene Toluene-2,4-diisocyanate o-Toluic acid m-Toluic acid p-Toluic acid Triacetamide 1H-1,2,4-Triazol-3-amine Tripropanechloromethane Tripropanechlorosilane Tripropanefluoromethane Tripropanemethane Tripropanesilane Tributylamine 1,3,5-Tri-tert-butylbenzene Tributyl phosphate Trichloroacetaldehyde 2,2,2-Trichloroacetamide Trichloroacetic acid Trichloroacetonitrile Trichloroacetyl chloride 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,3,5-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane Trichloromethane Trichloromethyl Trichloromethylsilane 1,2,3-Trichloropropane 1,2,3-Trichloro-1-propene Trichlorosilane 1,1,2-Trichloro-1,2,2-trifluoroethane Tri-o-cresyl phosphate Tridecane Tridecanedioic acid ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 5-39 174.9 163.6 169.0 -610.5 -550.1 76.8 -22.3 -355.6 -281.6 -5.0 -336.4 220.9 248.1 130.7 23.8 -317.6 -320.0 379.4 151.0 -234.5 -196.6 -358.0 -503.3 -280.8 227.4 232.6 228.4 225.4 201.7 144.3 150.9 124.4 121.6 114.2 262.8 163.1 183.6 -239.8 3.8 -8.1 -13.4 -144.4 -151.3 -9.0 -268.3 -102.7 59.0 -528.9 -182.9 170.1 -513.0 -716.8 -70.8 -63.1 -78.4 -177.4 -190.8 -43.6 -301.3 -134.1 -230.6 -101.8 -539.3 -745.0 570.0 -236.8 -73.7 -482.5 227.6 578.0 406.7 -1148.3 6.0 -482.0 Standard Thermodynamic Properties of Chemical Substances 5-40 Name Thermochem 1-Tridecanol 1-Tridecene Triethanolamine Triethylamine Triethylborane Triethylene glycol Trifluoroacetic acid Trifluoroacetonitrile 1,1,1-Trifluoroethane 1,1,2-Trifluoroethane 2,2,2-Trifluoroethanol Trifluoroethene 1,1,1-Trifluoro-2-iodoethane Trifluoroiodomethane Trifluoromethane Trifluoromethyl (Trifluoromethyl)benzene 1,1,1-Trifluoro-2,4pentanedione 3,3,3-Trifluoro-1-propene Trifluorosilane Trigermane Trihexylamine Trihydro(phosphorus trifluoride)boron Triiodomethane Trimethyl aluminum Trimethylamine Trimethylamine borane Trimethylamine hydrochloride 1,2,3-Trimethylbenzene 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Trimethylborane Trimethyl borate 2,2,3-Trimethylbutane 2,3,3-Trimethyl-1-butene Trimethylchlorosilane 1α,3α,5β-1,3,5-Trimethylcyclohexane 1,1,2-Trimethylcyclopropane 2,2,3-Trimethylhexane 2,2,4-Trimethylhexane 2,2,5-Trimethylhexane 2,3,3-Trimethylhexane 2,3,5-Trimethylhexane 2,4,4-Trimethylhexane 3,3,4-Trimethylhexane Trimethylolpropane 2,2,3-Trimethylpentane 2,2,4-Trimethylpentane 2,3,3-Trimethylpentane 2,3,4-Trimethylpentane 2,2,4-Trimethyl-3-pentanone 2,4,4-Trimethyl-1-pentene 2,4,4-Trimethyl-2-pentene Trimethylsilane Trimethylurea Trinitroacetonitrile 1,3,5-Trinitrobenzene 2,4,6-Trinitro-1,3benzenediol Trinitroglycerol Trinitromethane 2,4,6-Trinitrophenol 2,4,6-Trinitrotoluene ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 C13H28O C13H26 C6H15NO3 C6H15N C6H15B C6H14O4 C2HF3O2 C2F3N C2H3F3 C2H3F3 C2H3F3O C2HF3 C2H2F3I CF3I CHF3 CF3 C7H5F3 C5H5F3O2 Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 C3H5N3O9 CHN3O6 C6H3N3O7 C7H5N3O6 Cp(l)/ J mol-1 K-1 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 391.8 -664.2 389.0 -127.7 -194.6 -804.3 -1069.9 9.4 336.7 219.9 241.2 -932.4 -558.3 -92.7 -157.7 -725.0 -1031.4 -497.9 -744.6 -730.7 -888.4 -490.5 -644.5 -587.8 -695.4 -477.0 16.1 437.8 298.1 279.9 77.9 78.2 307.4 259.7 264.5 70.9 51.0 49.6 271.9 60.5 356.2 75.0 287.1 91.8 -35.9 314.7 88.5 -243.5 369.1 -464.0 188.4 -1040.2 -993.3 -614.2 193.7 -433.0 226.8 -854.0 -181.1 -136.4 -45.7 -142.5 -282.9 70.7 -9.9 209.4 208.5 155.6 137.9 267.9 216.4 215.0 209.3 251.0 -74.1 -23.6 187.0 C9H12 C9H12 C9H12 C3H9B C3H9BO3 C7H16 C7H14 C3H9ClSi C9H18 C6H12 C9H20 C9H20 C9H20 C9H20 C9H20 C9H20 C9H20 C6H14O3 C8H18 C8H18 C8H18 C8H18 C8H16O C8H16 C8H16 C3H10Si C4H10N2O C2N4O6 C6H3N3O6 C6H3N3O8 Sº(l)/ J mol-1 K-1 -599.4 C3H3F3 F3HSi Ge3H8 C18H39N BF3H3P CHI3 C3H9Al C3H9N C3H12BN C3H10ClN ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 -58.5 -61.8 -63.4 -143.1 -236.5 -117.7 -382.8 -32.1 238.9 292.2 -246.4 189.9 213.5 278.2 -96.2 -282.7 -282.8 -293.3 -281.1 -284.0 -280.2 -277.5 -9.5 -13.8 -15.9 -124.3 -204.4 -85.5 -352.8 -212.1 -242.6 -750.9 -256.9 -259.2 -253.5 -255.0 -381.6 -145.9 -142.4 329.3 239.1 245.6 247.3 -220.0 -224.0 -216.3 -217.3 -338.3 -110.5 -104.9 331.0 117.9 545.9 435.6 234.2 134.1 -330.5 183.7 -37.0 -467.5 214.6 -370.9 -32.8 -217.9 -63.2 239.7 243.3 -279.1 -13.4 Standard Thermodynamic Properties of Chemical Substances C24H51N C3H6O3 C18H15N C19H16O C18H15O4P C18H15P C9H21N C4H11NO3 H8Si3 C12F27N C3H6S3 CH2S3 C11H12N2O2 W Br6W Cl6W F6W O2W O3W C9H11NO3 C11H24 C11H24O C11H22 C4H4N2O2 U Cl3U Cl4U Cl6U F3U F4U F6U H3U OU O2U O9U4 O7U3 O8U3 O3U Cl2O2U F2O2U CH4N2O C5H4N4O3 C5H11NO2 C5H11NO2 V Br4V Cl3V Cl4V F4V F5V I4V OV O3V2 O5V3 O5V2 ClOV Cl3OV C4H6O2 C7H12 C6H6O H2O C5H4N4O2 C13H8O2 Xe F4Xe Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 -585.0 -522.5 234.7 -2.5 133.0 111.4 397.5 356.2 312.5 -465.9 326.8 -207.1 -161.0 -717.8 92.5 120.9 418.4 80.0 130.4 336.4 111.3 849.4 807.1 174.0 21.3 -513.8 -1721.7 -1632.1 341.1 119.0 -302.9 533.0 488.4 199.8 23.7 -809.6 -1013.0 -1058.5 -1598.7 -2147.4 -786.6 -928.0 -1051.9 -1572.7 -2063.7 419.0 431.0 331.9 368.0 377.9 74.3 91.2 129.6 21.0 -465.7 -471.5 274.6 51.4 -455.1 514.2 -336.8 754.4 182.3 26.0 24.0 -415.3 0.0 -348.5 -602.5 251.0 32.6 238.1 24.3 -1747.7 -589.7 -842.9 -685.1 -533.9 -764.0 50.5 75.9 214.0 -1631.4 251.5 56.1 73.8 216.4 -327.2 -504.8 344.9 -270.8 344.9 -429.4 0.0 -866.5 -1019.2 -1092.0 -1502.1 -1914.2 -2197.0 -127.2 -799.1 -930.0 -962.0 -1433.4 -1823.3 -2068.5 -72.8 50.2 159.0 197.1 285.8 123.4 151.7 227.6 63.7 120.5 27.7 102.5 122.0 175.7 95.1 116.0 166.8 49.3 -1085.0 -4510.4 -3427.1 -3574.8 -1223.8 -1243.9 -1653.5 -333.1 -618.8 -628.9 -617.9 0.0 -1031.8 -4275.1 -3242.9 -3369.5 -1145.7 -1146.4 -1557.4 77.0 334.1 250.5 282.6 96.1 150.5 135.6 63.6 293.3 215.5 238.4 81.7 107.9 103.2 173.2 166.1 28.9 24.9 -580.7 -511.2 131.0 93.2 -245.8 -569.4 -503.7 255.0 -525.5 -492.0 362.4 96.2 -1480.3 -1373.1 175.7 -1433.9 -122.6 -1369.8 320.9 98.6 -734.7 -349.2 -34.8 -10.3 -285.8 -668.5 244.3 -695.6 -314.4 -659.3 344.3 89.9 -237.1 70.0 -228.6 188.8 33.6 169.7 20.8 -1403.3 -431.8 -1218.8 -1933.0 -1550.6 -607.0 -379.6 -191.5 -404.2 -1139.3 -1803.0 -1419.5 -556.0 38.9 98.3 163.0 131.0 75.0 161.1 45.4 103.2 127.7 75.3 27.8 -241.8 151.3 0.0 -261.5 Thermochem Name Trioctylamine 1,3,5-Trioxane Triphenylamine Triphenylmethanol Triphenyl phosphate Triphenylphosphine Tripropylamine Tris(hydroxymethyl) methylamine Trisilane Tris(perfluorobutyl)amine 1,3,5-Trithiane Trithiocarbonic acid L-Tryptophan Tungsten Tungsten(VI) bromide Tungsten(VI) chloride Tungsten(VI) fluoride Tungsten(IV) oxide Tungsten(VI) oxide L-Tyrosine Undecane 1-Undecanol 1-Undecene Uracil Uranium Uranium(III) chloride Uranium(IV) chloride Uranium(VI) chloride Uranium(III) fluoride Uranium(IV) fluoride Uranium(VI) fluoride Uranium(III) hydride Uranium(II) oxide Uranium(IV) oxide Uranium(IV,V) oxide Uranium(IV,VI) oxide Uranium(V,VI) oxide Uranium(VI) oxide Uranyl chloride Uranyl fluoride Urea Uric acid DL-Valine L-Valine Vanadium Vanadium(IV) bromide Vanadium(III) chloride Vanadium(IV) chloride Vanadium(IV) fluoride Vanadium(V) fluoride Vanadium(IV) iodide Vanadium(II) oxide Vanadium(III) oxide Vanadium(III,IV) oxide Vanadium(V) oxide Vanadyl chloride Vanadyl trichloride Vinyl acetate Vinylcyclopentane 2-Vinylfuran Water Xanthine Xanthone Xenon Xenon tetrafluoride ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 5-41 Standard Thermodynamic Properties of Chemical Substances 5-42 Name Thermochem o-Xylene m-Xylene p-Xylene 2,3-Xylenol 2,4-Xylenol 2,5-Xylenol 2,6-Xylenol 3,4-Xylenol 3,5-Xylenol Xylitol D-Xylose Ytterbium Ytterbium(III) chloride Ytterbium(III) oxide Yttrium Yttrium chloride Yttrium fluoride Yttrium oxide Zinc Zinc bromide Zinc carbonate Zinc chloride Zinc fluoride Zinc hydroxide Zinc iodide Zinc nitrate Zinc orthosilicate Zinc oxide Zinc selenide Zinc sulfate Zinc sulfide (sphalerite) Zinc sulfide (wurtzite) Zirconium Zirconium(IV) bromide Zirconium(II) chloride Zirconium(IV) chloride Zirconium(IV) fluoride Zirconium(II) hydride Zirconium(IV) iodide Zirconium(IV) orthosilicate Zirconium(IV) oxide Zirconium(IV) sulfate Zirconium titanate ∆fHº(c)/ ∆fGº(c)/ Mol. form. kJ mol-1 kJ mol-1 C8H10 C8H10 C8H10 C8H10O C8H10O C8H10O C8H10O C8H10O C8H10O C5H12O5 C5H10O5 Yb Cl3Yb O3Yb2 Y Cl3Y F3Y O3Y2 Zn Br2Zn CO3Zn Cl2Zn F2Zn H2O2Zn I2Zn N2O6Zn O4SiZn2 OZn SeZn O4SZn SZn SZn Zr Br4Zr Cl2Zr Cl4Zr F4Zr H2Zr I4Zr O4SiZr O2Zr O8S2Zr O4TiZr Sº(c)/ J mol-1 K-1 Cp(c)/ J mol-1 K-1 ∆fHº(l)/ ∆fGº(l)/ kJ mol-1 kJ mol-1 -24.4 -25.4 -24.4 -241.1 -228.7 -246.6 -237.4 -242.3 -244.4 -1118.5 -1057.8 0.0 -959.8 -1814.6 0.0 -1000.0 -1718.8 -1905.3 0.0 -328.7 -812.8 -415.1 -764.4 -641.9 -208.0 -483.7 -1636.7 -350.5 -163.0 -982.8 -206.0 -192.6 0.0 -760.7 -502.0 -980.5 -1911.3 -169.0 -481.6 -2033.4 -1100.6 -2217.1 -2024.1 -1726.7 -1644.7 -1816.6 59.9 26.7 133.1 44.4 115.4 26.5 -312.1 -731.5 -369.4 -713.3 -553.5 -209.0 100.0 99.1 41.6 138.5 82.4 111.5 73.7 81.2 161.1 -1523.2 -320.5 -163.0 -871.5 -201.3 131.4 43.7 84.0 110.5 57.7 123.3 40.3 39.0 25.4 -889.9 -1809.9 -128.8 181.6 104.6 35.0 119.8 103.7 31.0 -1919.1 -1042.8 84.1 50.4 -1915.8 116.7 98.7 56.2 172.0 114.0 102.5 25.4 79.7 71.3 65.7 Sº(l)/ J mol-1 K-1 Cp(l)/ J mol-1 K-1 186.1 183.0 181.5 ∆fHº(g)/ ∆fGº(g)/ kJ mol-1 kJ mol-1 Sº(g)/ J mol-1 K-1 Cp(g)/ J mol-1 K-1 19.1 17.3 18.0 -157.2 -163.8 -161.6 -162.1 -157.3 -162.4 152.3 118.4 173.1 20.8 421.3 -750.2 -1288.7 381.1 179.5 -1277.8 311.8 25.9 75.0 70.3 130.4 94.8 161.0 20.8 566.5 181.4 26.7 -266.1 99.2 46.0 608.8