DOI: 10.1002/fuce.201700012 R. Scataglini1, M. Wei1*, A. Mayyas1, S. H. Chan2, T. Lipman3, M. Santarelli4 1 2 3 4 Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Mailstop 90R-2002, Berkeley, CA, 94720, USA Department of Mechanical Engineering, University of California, Berkeley, Etcheverry Hall, Hearst Ave #6141, Berkeley, CA 94720, USA Transportation Sustainability Research Center, University of California, Berkeley, University of California Richmond Field Station 1301 S. 46th Street, Building 190, Richmond, CA, 94804-3580, USA Department of Energy, Polytechnic University of Turin, Corso Duca degli Abruzzi, 24, 10129 Torino, Italy Received May 01, 2017; accepted October 23, 2017; published online November 21, 2017 Abstract This work details efforts to estimate the direct manufacturing cost of solid oxide fuel cell (SOFC) stack components for combined heat and power applications. The main research goals are to identify the major contributors to fuel cell stack manufacturing costs, examine the influence of both production volume and stack size on cost, and compare the results of the cost trajectories with the U.S. Department of Energy SOFC stack manufacturing cost target of $238 kWe–1 (in 2015) and industry reported cost projections and to identify critical areas for manufacturing research and development. Stack component direct manufacturing costs are modeled for net electricity capacity of 1, 10, 50, 100 and 250 kWe across 1 Introduction Fuel cell systems are an emerging technology for supplying efficient, clean power for a wide range of settings, including stationary combined heat and power (CHP) applications, forklifts, emergency backup systems, and automotive and bus/ truck applications. Fuel cells offer a promising role in addressing energy security and carbon emissions, due to their efficient energy conversion processes and clean emission profiles in comparison with fossil fuel combustion based-systems [1]. In particular, CHP fuel cell systems are attractive applications from both an economic and environment standpoint, due to their ability to produce both power and useful heat onsite, thus augmenting any additional heat needed to meet heating demands [2]. Solid oxide fuel cells (SOFC) are ceramic-based electrolyte fuel cells which operate between 600–1,000 C. They are of particular interest in the CHP applications, due to their point-of-use power generation ability on both small and large FUEL CELLS 17, 2017, No. 6, 825–842 annual production volumes of 10, 1,000, 10,000 and 50,000 systems per year. Overall stack manufacturing costs range from $5,387 kWe–1 to a minimum of about $166 kWe–1 for a 250 kWe system at 50,000 systems per year. To meet the manufacturing cost target of $238 kWe–1, a minimum annual production of 100–250 MWe per year would be required. Reduction opportunities for stack cost are expected to be available, mainly with the adoption of thinner cells and stack components, higher levels of factory automation, and more sensitive in-line defect diagnostics. Keywords: Combined Heat and Power, Electrode–electrolyte Assembly, Interconnects, Sealing, Solid Oxide Fuel Cell System scale, high fuel-to-power conversion efficiency, and the high quality waste heat produced [3]. Despite the numerous advantages over conventional and alternative power generation sources, fuel cells are not yet manufactured in high volumes. In addition to the absence of a mature hydrogen supply infrastructure (but note that SOFC operates directly with other types of fuels, such as natural gas and bio/syn-gas), one main adoption barrier is the high capital costs of fuel cells [4]. Numerous studies and cost projections have been done for automotive fuel cells systems [5], but fewer studies have been done for CHP applications. Additionally, current literature addressing fuel cells stack manufacturing costs are: (i) either too narrow in scope in terms of fuel cell components, featuring only fuel cell stack parts but not bal- – [*] Corresponding author, mwei@lbl.gov ª 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 825 ORIGINAL RESEARCH PAPER A Direct Manufacturing Cost Model for Solid-Oxide Fuel Cell Stacks ORIGINAL RESEARCH PAPER Scataglini et al.: A Direct Manufacturing Cost Model for Solid-Oxide Fuel Cell Stacks ance of plant components or vice versa [6, 7]; (ii) not detailed enough and omitting detailed system characterization [8]; (iii) lacking assessment or modeling of costs [9]; or 4) a combination of the above. This can result in an analysis with limited applicability outside the fixed system requirements. This work addresses these gaps by extending our analysis to provide a fuller treatment to the design and manufacturing of a solid oxide fuel cell stack. The overarching approach is to utilize ‘‘Design for Manufacturing and Assembly’’ (DFMA) techniques to optimize system design, materials and manufacturing flow for lowest manufacturing costs (reference: DFMA). The model considers fuel cell systems ranging from 1–250 kWe of net electrical power across various annual production rates to estimate the direct manufacturing costs for key fuel cell stack components. Sensitivity analysis is then performed to gain insight into the effects of manufacturing operation parameters on stack costs. This work will help identify dominant cost drivers in a fuel cell stack, determine cost effective fuel cell components manufacturing options, and identify cost-reduction opportunities to accelerate adoption of fuel cellbased systems. 2 Manufacturing Cost Modeling 2.1 Cost Analysis Methodology The starting point of the cost analysis methodology is the definition of the system boundaries and identification of stack components. Based upon a search of relevant fuel cell literature and patents, industry system specifications sheets as well as industry and academic advisor inputs, operational and performance requirements are identified and system design and the functional specifications of the fuel cell were determined. Process modeling or optimization of the stack design from a detailed thermodynamic and thermo-chemical point of view is not described in this paper. However, a ‘‘medium fidelity’’ design, based on feedback from industry advisors, is used to be representative of actual fuel cell systems. The second step is to determine which components are expected to be purchased and which are manufactured inhouse. This model assumes a business scenario of vertical integration where the fuel cell manufacturer is presumed to manufacture all stack components. This assumption is geared towards the case of higher volume production, since at lower production volume it may be more cost-effective to purchase finished or partially finished stack components. This is because at very low volumes the investment costs for vertical integration are high and equipment utilization is low for some elements of the manufacturing chain. The third step is to design a base manufacturing process flow for each stack component by combining a literature search with industry and vendor inputs. The outputs of the cost model are the direct manufacturing costs. These include capital costs, operation and management costs (O&M), labor costs, materials costs, scrap costs and factory building costs, subjected to global assumptions such as discount rate, infla- 826 ª 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim tion rate and tool lifetimes. This methodology follows that of other similar cost studies [10]. The annualized manufacturing cost of each component is quoted as the sum of all these direct manufacturing costs normalized to the annual equivalent production volume in kWe, units or meter squared of cell surface area per year. A detailed bottom up costing is done for all major stack components (e.g., electrode-electrolyte assembly functional cell, frame, cellto-frame seals, interconnect and nickel mesh) and for the final stack assembly and conditioning process. The stack manufacturing cost is then the sum of costs of all stack components analyzed. Sensitivity analysis is performed at the component level and at stack level in order to identify key cost drivers, cost reduction opportunities and manufacturing R&D areas. Stack direct manufacturing costs are mainly modeled for net electricity capacities of 1 kWe, 10 kWe, 50 kWe, 100 kWe and 250 kWe across annual production volumes of 100, 1,000, 10,000 and 50,000 units per year. Stack design does not change with production rate, but material costs, manufacturing processes and equipment size often vary. For some components (interconnects, frames and cell-to-frame seals), multiple designs and manufacturing approaches are analyzed. An annualized cost of tool approach is adopted from Haberl [11]. The annualized cost equation can be expressed in constant currency as follows: Cy ¼ Cc þ Cr þ Coc þ Cp þ Cbr þ Ci þ Cm Cs Cint Cdep (1) where Cy is the total annualized cost, Cc is the capital/system cost (with interest), Cr is the replacements or disposal cost, Coc is the operating costs (e.g., electricity cost) excluding labor, Cp is the property tax cost, Cbr is the building or floor space cost, Ci is the tool insurance cost, Cm is the maintenance cost, Cs is the end-of-life salvage value, Cint is the deduction from income tax and Cdep is the deduction due to tool depreciation. The interest tax deduction is not included in the calculations since it is assumed no net income for fuel cell manufacturers [1]. Direct material costs are determined from the exact type and mass of material employed in the component. Material scrap costs include cost of waste material (e.g. due to cutting or punching processes) and direct manufacturing cost of defective parts. Labor costs are estimated based upon the number of people required to operate each machine. A labor rate of $30 hour–1 is assumed for all process labor, a daily working time of 16 h (2 shifts), and 240 operating days per year. Building costs are amortized with building depreciation for a building life of 31 years. Building area is quoted as the sum of each specific process module footprint multiplied by a 2.8 space correction factor [12]. Capital costs for each manufacturing machine are estimated based on quotes from manufacturers. In case the vendor does not provide information about installation and maintenance costs, it is assumed that cost to install the equipment is equal to 20% of the machine capital cost and an annual maintenance factor is equal to 10% of installed equipment cost. Equipment costs are based on a www.fuelcells.wiley-vch.de FUEL CELLS 17, 2017, No. 6, 825–842 Scataglini et al.: A Direct Manufacturing Cost Model for Solid-Oxide Fuel Cell Stacks 2.2 Stack Design and Functional Specifications System designs and functional specifications for SOFC CHP applications were developed across the range of system power levels mentioned above. The general structure of a SOFC stack is shown in Figure 1. A typical SOFC stack is made up of two electrodes (anode and cathode), an electrolyte, seals, interconnect plates, and a frame. The electrodes and electrolyte form the electrolyte electrode assembly (EEA) and is the core component of the fuel cell where the electrochemical reactions take place. An anode supporting layer and cathode supporting layer is often added to the EEA, which are designed to support the cathode and anode layers as shown in Figure 2. This work is primarily based on FCE/VersaPower’s anode-supported cell architecture and reported process steps and stack materials. In an anode-supported cell, the anode layer provides the structural support for the electrically-active components. Table 1 Manufacturing cost shared parameters. Parameter Symbol Value Units Comments Operating hours ths varies Hours 8 h base shift; (2–3 shifts per day) Annual operating days tdy 240 Days 52 wks*5 days/wk – 10 vacation days –10 holidays Avg. inflation rate j 0.023 US average for past 10 years [13] Avg. mortgage rate jm 0.051 Trading Economics [14] Discount rate jd 0.10 Energy inflation rate je 0.056 US average for last 3 years [13] Income tax ii 0 No net income Property tax ip 0.01035 US average [15] Assessed value iav 0.4 Salvage tax is 0.5 EOL salvage value keol 0.02 Tool lifetime Tt 15 Energy tax credits ITC 0 Dollars Energy cost ce 0.10 $ kWhe–1 Assume 2% of end-of-life value Years Typical value in practice Typical U.S. value –2 Floor space cost cfs 1,291 Building depreciation jbr 0.031 Building recovery Tbr 31 Years U.S. Department of Commerce [17] Hourly labor cost clabor 30 $ hr–1 Hourly wage per worker $m US average for factory [16] U.S. Department of Commerce [17] Table 2 General assumptions for scaling manufacturing process from low volume to high volume. Manufacturing Area Low Volume Manufacturing High Volume Manufacturing Labor and automation of manufacturing processes Mostly manual work with some automation High degree of automation with low direct labor requirements Quality inspection and defect metrology Mostly manual inspection Shift to more automated inspection systems Materials purchasing Low volume purchases and few suppliers High volume of purchases with more suppliers Throughput Low throughput and low tool utilization High throughput with high tool utilization Process rework and material scrappage Higher rates of process rework and material scrappage Low rates process rework rates and material scrappage FUEL CELLS 17, 2017, No. 6, 825–842 www.fuelcells.wiley-vch.de ª 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 827 ORIGINAL RESEARCH PAPER 15 year lifetime [1]. An electricity rate of $0.10 kWh–1 is assumed and an electricity cost corresponding to the energy requirements for each piece of equipment. General manufacturing cost parameters are summarized in Table 1. General assumptions for scaling manufacturing process from low volume to high volume are shown in Table 2. At low volumes, manufacturing processes have a greater degree of manual labor, e.g., quality inspections and defect metrology have a high degree of manual intervention. Manufacturing lines generally have low tool utilization and relatively high rates of process rework and material scrappage, and supply chains are not well developed with low-volume of purchases and few suppliers. At high volume, manufacturing process flows and quality inspection steps are assumed to be more automated with higher tool utilization and low rates of process rework and material scrappage. Supply chains are assumed to be more developed with multiple suppliers. ORIGINAL RESEARCH PAPER Scataglini et al.: A Direct Manufacturing Cost Model for Solid-Oxide Fuel Cell Stacks Fig. 2 Electrolyte-electrode assembly (EEA) schematic. Fig. 1 Typical SOFC stack configuration [18]. For an SOFC stack, the electrolyte is typically made up of a ceramic material, such as yttria-stabilized zirconia (YSZ), due to its good ionic conductivity and robust mechanical proper- ties under high-temperature operation. The anode is made up of a porous cermet material composed of nickel oxide mixed with YSZ to allow the fuel to be diffused to the reaction sites close to the electrolyte layer, for the oxygen ions to oxidize the fuel, and for the delivered electrons to be conducted to the next cell or to the external load. The anode is formed by mixing NiO and 8YSZ powder in the common volume ratio of 70:30 [19]. The composition and manufacturing process for the EEA is summarized in Table 3 and an overall process flow diagram in Figure 3. The interconnections provide both electrical contacts and gas channels between individual cells. Metallic interconnects Table 3 EEA composition and manufacturing process. Component Materials Thickness / mm Process Anode Ni/YSZ 700 Tape casting Anode electrolyte interlayer 50% YSZ 50% NiO 10 Screen printing Electrolyte YSZ (Yttria-Stabilized Zirconia) 10 Screen printing Electrolyte/cathode Interlayer 50% YSZ 50% LSM 10 Screen printing Cathode LSM (lanthanum strontium manganite ) 50 Screen printing Fig. 3 Process flow-diagram for EEA. 828 ª 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim www.fuelcells.wiley-vch.de FUEL CELLS 17, 2017, No. 6, 825–842 Scataglini et al.: A Direct Manufacturing Cost Model for Solid-Oxide Fuel Cell Stacks Table 4 Functional specifications. Parameter 10kWe CHP system reformate fuel 50kWe CHP system with reformate fuel Units Gross system power 11.0 54.9 kW DC Net system power 10 50 kW AC Electrical output 220 V AC 480 V AC Volts AC or DC DC/AC inverter efficiency 95 95 % Operating temperature 700–800 700–800 Temp. C Waste heat grade 220 220 Temp. C Fuel utilization % (overall) N/A N/A % Net electrical efficiency 59 59 % LHV Thermal efficiency 24 24 % LHV Total efficiency 84 84 Elect.+thermal / % Stack power 11.0 54.9 kW Total plate area 540 540 cm2 Actively catalyzed area 329 329 cm2 Single cell active area 299 299 cm2 Gross cell inactive area 45 45 % Cell amps 105 105 A Current density 0.35 0.35 A cm–2 Reference voltage 0.8 0.8 V Power density 0.28 0.28 W cm–2 Single cell power 84 84 W Cells per stack 130 130 cells Stacks per system 1 5 stacks Parasitic loss 0.5 2.5 kW AC FUEL CELLS 17, 2017, No. 6, 825–842 www.fuelcells.wiley-vch.de ª 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 829 ORIGINAL RESEARCH PAPER tional specifications were developed based on a variety of industry sources and literature and include calculated parameters for stack and system efficiencies for an ‘‘internally consistent’’ set of reference values. The determination of gross system power reflects about 10% overall parasitic power at 10 kWe and 50 kWe, including losses through the inverter. DC to AC inverter efficiency is assumed to be 95% and constant across the system power ranges. Additional parasitic losses are from compressors, blowers and other parasitic loads and are assumed to be direct DC power losses from the fuel cell stack output power. The waste heat grade from the coolant system is taken to be 220 C for all system sizes although a range of other temperatures are possible, mostly over the range of 50–70 C. The heat exchanger configuration can also depend on the demand temperatures for the heating streams, and the exact cooling and heating loops will be location and system specific. Additional waste heat streams from the anode and cathode exhaust can be routed to the fuel processor reactor burner. At the reference cell voltage of 0.8 V, the net electrical efficiency is 59% (lower heating value, or LHV) for the reformate systems. These overall electrical efficiency levels are similar to those reported in literature [10]. The total overall CHP system efficiency of 84% is viewed as a benchmark value for the case where a large reservoir of heat demand exists and represents are preferred for intermediate temperature SOFCs which usually operate at £800 C and typically have lower manufacturing costs than ceramic-based interconnects. Glass seals between the EEA and interconnects prevent the mixing of fuel and oxidant within the stack, leaking of fuel and oxidant from the stack, and also provide mechanical bonding for the components [20]. Barium-calcium-aluminosilicate (BCAS), an alkaline earth aluminosilicate glass, is most commonly used for SOFC seals due to its high electrical resistivity, high thermal expansion, and rapid crystallization kinetics [21] and was modeled in this study. The EEA, seals, and interconnects together form the ‘‘stack repeating unit’’ (SRU) of the cell. These repeating units are connected together to provide a wide range of power output, forming a ‘‘stack’’. Finally, a support structure, such as endplates with tie-rods, hold the fuel cell stack together to provide structural support. In this study, two different stack designs are considered, a base design with SS441 interconnect and frame and an alternative design with Crofer 22 APU interconnect and frame. The Crofer interconnect has a thickness of 315 mm and a mass of 123 grams, whereas SS441 Interconnect has a thickness of 630 mm and a mass of 247 grams [22]. Functional specifications for the 10 kWe and 50 kWe CHP systems with reformate fuel are shown in Table 4 below and a system schematic diagram is show in Figure 4. These func- ORIGINAL RESEARCH PAPER Scataglini et al.: A Direct Manufacturing Cost Model for Solid-Oxide Fuel Cell Stacks Fig. 4 SOFC CHP system design schematics for 50kW CHP system. the maximal total efficiency of the system. Actual waste heat utilization and total efficiency will be highly dependent on the site and heating demands. For example, smaller overall heat efficiency can result, if waste heat utilization is confined to building water heating and the building has a relatively low demand for hot water. Total fuel cell plate area is taken to be 540 cm2. Active catalyzed area is about 61% of this area, due to plate border regions and manifold openings. Single cell active area has an additional 10% area loss, due to the frame sealing process. The 10kWe system consists of 130 cells in a single stack, while the 50kW system has 5 stacks of 130 cells each. 2.3 Stack Manufacturing Process Flow Three different process parameters have been taken into account in the cost model: (i) ‘‘Availability,’’ or the percentage of time that equipment is available to run during the total possible planned production up-time; (ii) ‘‘Performance,’’ a measure of how well the equipment runs within its time of operation; and (iii) ‘‘Process Yield or Quality,’’ a measure of the number of parts that meet specification compared to how many were produced. A major challenge for fuel cell manufacturing cost modeling is that these parameters are not available since data collected by fuel cell manufacturers are not accessible, and each fuel cell manufacturer uses different toolsets, different manufacturing techniques and produces no more than 100 MW per 830 ª 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim year. As in other costing studies [23–25], the model assumes that losses decrease with increasing manufacturing volumes and level of automation, due to: (i) improvement of inline inspection with greater inspection sensitivity and more accurate response to defects an inline signals; (ii) development of models that relate inline metrics and measurements to output responses and performance [26]; and (iii) utilization of greater feedback systems in manufacturing processing for real time adjustment of process parameters. Since vendors and industry advisors do not provide exact information about these parameters, the approach is to assume a range for each parameter as described below and then estimate intermediate values through exponential interpolation depending on annual production volume. The advantage of introducing these parameters in the model is because using sensitivity analysis it is possible to estimate the impact of these parameters on manufacturing costs. 2.3.1 Electrode–electrolyte Assembly Functional Cell (EEA) Based on a literature search and discussions with industry experts, the steps required for the fabrication of the EEA functional cell are: (i) Preparing the anode slurry using a two steps ball milling process; (ii) Sieving and de-airing of the anode slurry; (iii) Tape casting and infrared drying of the anode tape; (iv) Rolling in a take-up roll of the green tape; www.fuelcells.wiley-vch.de FUEL CELLS 17, 2017, No. 6, 825–842 Scataglini et al.: A Direct Manufacturing Cost Model for Solid-Oxide Fuel Cell Stacks Cutting and blanking into sheets of the green tape; Screen printing and infrared drying of subsequent layers (anode-electrolyte interlayer, electrolyte, cathode-electrolyte interlayer and cathode layer) above the anode sheet; (vii) First quality check (infrared imaging and ultrasonic spectroscopy); (viii) Bonding together the mini-stack of five layers by placing it in a furnace at elevated temperature (~1,300–1,400 C) for 24 h [27, 28]; (ix) Laser cutting of the EEA cell to the proper dimensions; (x) Final quality check (infrared imaging, ultrasonic spectroscopy and vacuum leak test). In this investigation, slurries are prepared by a two steps ball milling process. In the first step, solid powders are ball milled for 12 h in solvent. In the second step, binder and plasticizer are added and then ball milled for another 12 h [29]. Quantities of slurry to mill per day are estimated based on number of cells casted per day and slurry weight of each layer. Slurry drying time is estimated using the average evaporation rate value of aqueous slurry described by Mistler, et al. [30] as suggested in a Battelle report [31]. Assuming that the ratio of the freshly deposited layer thickness to the dried tape thickness is two [32] and multiplying this freshly deposited layer thickness by its corresponding liquid density it was possible to obtain the quantity of liquid removed per unit area. The corresponding slurry drying time is estimated dividing the quantity of liquid removed per unit area by an average evaporation rate of the solvent equal to 2.22 · 10–5 g cm–2 s–1 at room temperature for an air flow rate of 75 L min–1 [30]. Estimated slurry drying times are: 24.7 min for the anode slurry, 0.48 min for the electrolyte slurry, 2.2 min for the cathode slurry and 0.44 min for interlayer slurries. In reality, evaporation rates may be expected to be faster than the ones considered in this study since water evaporates more slowly than most organic solvents as n-butyl acetate or 2-butoxyethanol [33]. In the last few years, many studies have been conducted to evaluate and compare co-fired cells performance and costs to cells made by multiple firing steps. During co-firing (or co-sintering), all the layers are subjected to the same thermal treatment. A good choice of the sintering temperature is the most important requirement to consider since it allows to minimize chemical interaction between various layers and the distortion of the structure due to mismatch in thermomechanical and physical properties of the various layers [34]. This means that the common temperature must be necessarily a compromise between the highest and the lowest sintering temperature of the different layers but the residence time in furnace must be long enough to allow the sintering of the most refractory layers [28]. The anode is the least refractory layer and must be highly porous (30–40% porosity). If it is sintered for a longer time than necessary, the porosity could decrease dramatically and an over-densification could occur. For this reason, during slurry formulation, usually pore formers are added in order to control the porosity of the anode layer. On the contrary, the electrolyte FUEL CELLS 17, 2017, No. 6, 825–842 www.fuelcells.wiley-vch.de has the highest sintering temperature and has a dense structure with low porosity. Typical co-firing temperature for anode supported cell fabrication with Ni/YSZ anode, YSZ electrolyte and LSM cathode varying from 1,250 to 1,400 C and co-firing process lasts about 16–24 h [27, 28, 34]. Deformation during sintering is related to different factors as elastic deformation, thermal deformation, visco-plastic deformation and shrinkage due to densification. The shrinkage is the factor which most affects the overall deformation and references [28] and [34] report the linear shrinkage decreases with increasing total volume percentage of dispersant, binder and plasticizer. Equipment size, cycle times and level of automation vary with annual production rates. Tape casting machines are sized depending on production volume, slurry drying time and casting speed. Tape casting speed varies with annual production volume and machine size from 0.25 m min–1 to 1 m min–1. Subsequent process modules included in the production line are sized based on the estimated production capacity and cycle time of the tape casting machine. Line availability is assumed to be 80% and process yield to be 85% at low volumes (<100,000 EEA cells year–1, 10 MWe). At the highest volumes (>10,000,000 EEA cells year–1, 500 MWe year–1), line availability and process yield are assumed equal to 95%. For volumes between 100,000 and 10,000,000 EEA cells year–1, the process parameters are found through exponential interpolation. Line performance is considered equal to 89% for manual configuration and 95% for semi-automatic and automatic configurations. As a comparison, Fuel Cell Energy Inc. has reported a fabrication yield of 95% at a production volume of 500 kWe year–1 [22]. 2.3.2 Interconnect and Frame The interconnect manufacturing process flow consists of the following modules: (i) stamping of a sheet roll of Stainless Steel 441 or Crofer 22 APU by means of a dual die stamper; (ii) post-stamp cleaning and drying of the metal plate; (iii) cathodic arc plasma vapor deposition (Arc-PVD) of a manganese cobalt oxide (MCO) spinel coating; and (iv) final inspection. The MCO layer is only applied to one side of the interconnects to protect the cells from chromium poisoning and to improve cell performance and durability [35]. The dual die stamper uses two strokes to punch out the manifolds, create the perimeter of the plate and form the flow fields. Three different manufacturing lines (manual, semi-automatic and fully automatic) are designed depending on the annual production volume. The physical vapor deposition step represents the bottleneck process. Other process modules included in the production line are sized based on the estimated production capacity and cycle time of the physical vapor deposition process. Assuming a 1 cm margin on each side of the interconnect [31] and that manifold areas are punched out during stamping process, a material scrap of 20% is estimated. The model also assumes that interconnect material waste is recyclable and sold at a price equal to 40% of the raw material purchase price. ª 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 831 ORIGINAL RESEARCH PAPER (v) (vi) ORIGINAL RESEARCH PAPER Scataglini et al.: A Direct Manufacturing Cost Model for Solid-Oxide Fuel Cell Stacks Line performance is assumed to be 89% for manual configuration and 95% for semi-automatic and automatic configurations. At low volumes (< 100,000 interconnects year–1, 10 MWe year–1) line availability is assumed to be 80% and process yield to be 85%. At high volumes (>10,000,000 interconnects year–1, 500 MWe year–1), line availability is estimated to be 95% and process yield to be 99%. For volumes between 100,000 and 10,000,000 interconnects year–1, the process parameters are found through exponential interpolation. Frames are manufactured the same way using the same machines and materials. In case of high tool utilization, additional lines are needed for manufacturing of the frame and a similar line is considered. If this is the case, a single die stamper can replace the dual die stamper since no bending is required for the frame. Assuming a 1 cm margin on each side of the frame and that cell size slot and manifolds slots are punched out during stamping process, a material scrap of 72% is estimated. 2.3.3 Cell-to-frame Seal The method of creating a glass seal considered in this study is adopted from a PNNL study [33]: (i) ball milling of the glass paste; (ii) dispensing of the paste on EEA cell perimeter by means of a dispensing robot; (iii) placing of the cell onto the frame; (iv) placing of a weighted plate onto the cell; (v) loading of the piece in the annealing furnace; and (vi) annealing in furnace under a static load (450 to 2,200 N). The annealing process includes four steps: (i) heating up to 600 C with a heating rate of 3 C min–1; (ii) heating up to 750 C with a heating rate of 5 C min–1; (iii) holding at 750 C for 60 min; and (iv) cooling to 50 C with a cooling rate of 15 C min–1. Manual and automatic configurations are included in the analysis depending on production volume. The manual line requires three workers whereas the automatic line requires one worker in the dispensing line and another worker every four furnaces (1.25 worker line–1). Due to the long thermal cycle, the annealing process is the process bottleneck here. Capital costs vary from $600,000 to $1,350,000, based on furnace cost information from Abbot Furnace. Estimated cycle time ranges from 370 seconds to 62 seconds depending on the production capacity of each furnace. 2.3.4 Assembly and Conditioning The assembly and conditioning process is composed of 10 steps: (i) Feeding of the anode plate into the system; (ii) Adding the nickel mesh; (iii) Dispensing glass sealing paste along the edge of the anode plate and the perimeter of gas manifolds; (iv) Adding the EEA functional cell; (v) Dispensing glass sealing paste along the edge of the cathode plate; (vi) Adding the cathode plate; (vii) Pressing the whole stack and adding of end plates and compression springs etc.; (viii) Adding power electronics, hosing, and sensors; 832 ª 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim (ix) Adding stack housing; (x) Conditioning and testing of the stack. Note that steps 1 through 6 form a repeated unit and may be executed multiple times. The number of repeated units included in the fuel cell stack depends on the electrical and thermal characteristic curves and electrical power output of the fuel cell stack, which determines the fuel cell system size. Manual assembly of stack repeating units is assumed at low volume manufacturing (£ 5 MWe year–1), semi-automatic at production volume £ 50 MWe year–1 and automatic at all higher production rates. The difference between semi-automatic and automatic configuration is based on the number of Staubli 6-axis RX160 robots used. Non-repeating stack components are assembled manually at all rates in about 10 min. Cycle times range from 90 min in case of manual assembly of the 1 kWe stack block to approximately 20 min in case of automated assembly of the 10 kWe stack block. Three different Fuelcon vendor sintering and testing stations are considered (4-fold, 8-fold and 16-fold) depending on annual production volume. Sintering and testing process lasts about 24 h including load and unload time. Fuel utilization is 0.8 SLPM for the 1 kWe stack block and 0.91 SLPM for the 10 kWe stack block. For sealing paste preparation, the same ball mills used for manufacturing of EEA cells are considered and machines are sized depending on quantity of paste to mill per day. Line performance is assumed 89% for manual configuration, 95% for semi-automatic assembly line and 98% for automatic assembly line. Line availability is assumed to be 80% at low volumes (10 MWe) and 95% at high volumes (500 MWe). For volumes between 100,000 and 10,000,000 interconnects year–1, it is found through exponential interpolation. Process yield is assumed to be 99.5% at all rates since the vendor is assumed to take extra precautions and rework to ensure that no material is scrapped. The process yield is varied in the sensitivity analysis below in order to estimate the impact of this parameter to the assembly and conditioning costs. 2.4 Material Cost Material costs were obtained from multiple vendors from Japan, USA, and China. These countries are the primary suppliers for SOFC materials worldwide. Material prices were priced based on delivery to the geographical center of the USA. Material quality and prices from Chinese suppliers were also evaluated versus US distributors to determine their competiveness. Material prices for the EEA used in this study are shown in Table 5. For the EEA, material cost of each layer was calculated using the weight of the slurry constituents multiplied by the corresponding material cost ($ kg–1). For the anode supported cell design, the anode materials contribute to about 75–82% of the EEA material cost due to the thickness of the anode layer. Table 6 shows the material prices for the binders, plasticizers, pore formers, and solvents at different order quantities. As shown in the tables, material costs are highly dependent on annual production volume, especially for ceramic materials used in the fabrication of the EEA cells. www.fuelcells.wiley-vch.de FUEL CELLS 17, 2017, No. 6, 825–842 Scataglini et al.: A Direct Manufacturing Cost Model for Solid-Oxide Fuel Cell Stacks ORIGINAL RESEARCH PAPER Table 5 Anode-supported cell material prices. Function Material Vendor (Country) Order quantity / kg Price ($ kg–1) Comments Anode / Anode-Electrolyte interlayer NiO powder AIICHI JITSUGYO (Japan) 1 68.5 CIF USA by sea Anode / Electrolyte / Interlayers Anode / Electrolyte / Interlayers Anode / Electrolyte / Interlayers 8YSZ powder (8 mol% YSZ) AIICHI JITSUGYO (Japan) 8YSZ powder (8 mol% YSZ) Daiichi (Japan) 8YSZ powder (8 mol% YSZ) Inframat Advanced Materials (USA) Cathode / Electrolyte-Cathode interlayer LSM powder Cathode / Electrolyte-Cathode interlayer LSM powder Inframat Advanced Materials (USA) Qingdao Terio Corporation (China) 5 42.5 CIF USA by sea 10 37 CIF USA by sea 20 34 CIF USA by sea 100 78 CIF USA by sea 1 68 CIF USA by sea 5 63 CIF USA by sea 10 97 CIF USA by sea 100 95 CIF USA by air 1 83 CIF USA by sea 1 139.2 by rail or truck 5 115.8 by rail or truck 10 94.5 by rail or truck 50 71.6 by rail or truck 100 49.7 by rail or truck 1 35.2 by rail or truck 10 29.8 by rail or truck 100 170 by rail or truck 1 95 by rail or truck 10 70 by rail or truck 10 250 CIF USA by air 100 150 CIF USA by air 200 125 CIF USA by air 500 105 CIF USA by air 1 80 CIF USA by air 2 75 CIF USA by air 5 60 CIF USA by air CIF = price including cost, insurance and freight A summary for the interconnect materials is summarized in Table 7 with Stainless Steel 441 as the base case for this study. Table 8 shows specifications for the MCO powder. Note that a rough order of magnitude (ROM) estimate for the sealing prices were obtained from 3M’s Advanced Materials Division for this analysis and are not shown here, due to confidentiality restrictions from the supplier. At high volumes, material cost is one of the dominant cost drivers in a SOFC stack. In most cases, material prices from Chinese suppliers are competitive with US-based suppliers, while prices from Japanese suppliers were the highest among all vendors. 3 Results and Discussion Table 9 shows the cost model results for all system sizes and production rates. The choice of a more expensive material as Crofer 22 APU instead of SS441 increases the stack manu- FUEL CELLS 17, 2017, No. 6, 825–842 www.fuelcells.wiley-vch.de facturing cost by 1–14%. If multi-firing is implemented instead of co-firing, the EEA cost is estimated to increase by about 40– 50% and the stack costs by 20–25%. Considering the base design, stack cost per unit of electric power ($ kWe–1) decreases both with increasing system size and increasing annual production rate (Figures 5 and 6). When comparing the two key cost drivers, cost seems to be somewhat more sensitive to system size than to production rate, and the impact of system size diminishes at higher production volumes. At the same annual power production rate, stack costs decrease with larger SOFC system size (Figure 7). This cost reduction is only related to stack assembly and conditioning cost. It is more cost-effective to assemble and test fewer large stacks compared to a larger number of lower-power stacks. Figure 8 below shows stack manufacturing costs broken out by component for 10 kWe systems. The largest contributor to the stack manufacturing cost is the EEA, which constitutes about 50% of total cost in all cases analyzed. Interconnect and ª 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 833 ORIGINAL RESEARCH PAPER Scataglini et al.: A Direct Manufacturing Cost Model for Solid-Oxide Fuel Cell Stacks Table 6 Binders, plasticizers, pore formers, and solvent prices. Function Material Vendor (Country) Order quantity / kg Price / $ kg–1 Comments Solvent (Anode / Electrolyte) N-butyl acetate 99,5% Jiangsu Xiangcanghongrun Trade Co., Ltd. (China) 100 4.34 CIF USA by sea 1 1,516 CIF USA by sea 10 1.29 CIF USA by sea Binder (Cathode / Interlayers) Methocel A4M ChemPoint Inc. (USA) 1–45,400 18.5–29.6 CIF price Binder (Anode / Electrolyte) Butvar B-76 Dowd & Guild, Inc. (CA) 63.5 23.37 by rail or truck 200 21.42 by rail or truck 500 19.47 by rail or truck 1 18.36 by rail or truck 2 17.14 by rail or truck 5.000 16.07 by rail or truck Plasticizer (Anode/Electrolyte) Santicizer 160 Univar USA Confidential information from vendor Pore former (Anode) Thermax N990 Thermal Carbon Black Cancarb Limited (USA) Confidential information from vendor Solvent (Cathode / Interlayers) 2-Butoxyethanol Jinan Shijitongda Chemical Co., Ltd. (China) 1 3.07 CIF USA 10 3.07 CIF USA 100 2.53 CIF USA 1,000,000 2.32 CIF USA 10,000,000 2.29 CIF USA CIF = price including cost, insurance and freight. Table 7 Interconnect material costs. Table 9 Direct manufacturing cost results for SOFC stack. Component Material Cost / $ kg–1 Sheet metal SS 441 (Tianjin Brilliant Import & Export Co.,Ltd.) 2.3–1.5 Sheet metal Crofer 22 APU (Elcogen) 25–10.0 Coating powder MCO (Qingdao Terio Corporation) 300–250 Table 8 Manganese cobalt oxide powder specifications. Grade and Specifications Grades MCO 2 Specific surface area / m g –1 5.0–10.0 Particle size (D50 / mm) 0.4–0.6 Feature Spinel phase black powder Source: Qingdao Terio Corporation. cell-to-frame seal each constitute 11–15 % of the stack cost and decrease with production volume. Stack assembly and conditioning process remains constant at about 9% of the stack cost. The relative contribution of frame manufacturing cost to overall stack cost increases with production volume, since at low volumes is assumed that interconnect manufacturing lines are used and there is no capital cost and building cost associated with the frames. At low volumes, process capital and labor costs are the categories that most affect the stack cost whereas at high vol- 834 ª 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim System power / kWe Systems year–1 Stack cost Base design / $ kWe–1 Stack cost Cost increase Alternative /% –1 design / $ kWe 1 100 5,387 5,463 1.4% 1 1,000 1,196 1,252 4.7% 1 10,000 451 485 7.4% 1 50,000 322 347 7.7% 10 100 1,039 1,096 5.4% 10 1,000 342 376 9.7% 10 10,000 197 221 12.3% 10 50,000 178 202 13.1% 50 100 478 514 7.7% 50 1,000 215 240 11.5% 50 10,000 176 200 13.2% 50 50,000 170 193 13.5% 100 100 339 372 9.8% 100 1,000 194 219 12.4% 100 10,000 171 194 13.5% 100 50,000 168 191 13.7% 250 100 249 274 10.0% 250 1,000 181 204 13.0% 250 10,000 167 190 13.7% 250 50,000 166 189 13.9% www.fuelcells.wiley-vch.de FUEL CELLS 17, 2017, No. 6, 825–842 Scataglini et al.: A Direct Manufacturing Cost Model for Solid-Oxide Fuel Cell Stacks 4 Sensitivity Analysis for Stack Manufacturing Cost Fig. 5 Stack manufacturing cost variation with system size. Fig. 6 Stack manufacturing cost variation with annual production rate. Sensitivity analysis at the component level is done for 50 kWe systems at all annual production rates. Sensitivity analysis at the stack level is then obtained summing the effects of sensitivity analysis performed at the component level. Global sensitivity parameters are power density, process yield, manufacturing line performance, manufacturing line availability, capital cost, discount rate, building cost, operational cost and hourly labor rate. The impact to the stack manufacturing cost in $ kWe–1 is calculated for a +20% change in the sensitivity parameter being varied. Figures 10 and 11 show results for production volumes of 100 and 50,000 systems year–1, respectively. Power density and process yield are the parameters having the greatest impact on stack manufacturing cost. In addition, the sensitivity of these parameters increases with the annual production volume. Line performance also deeply affects the stack manufacturing cost, since equipment speed losses cause an increase of annual operating hours and therefore labor and operational costs. Availability has negligible impact at the low volume of 100 systems per year, since in that case, its variation causes only an increase of manufacturing line utilization rate but not an increase of machines needed to guarantee the required annual production. Labor rate is less important with higher production volume because of higher levels of automation. Operating and building costs are factors which have less impact on stack manufacturing cost in all cases. 5 Comparison to Cost Targets and Other Industry Cost Estimates Fig. 7 Stack manufacturing costs at the same global produced capacity of 10 MWe. FUEL CELLS 17, 2017, No. 6, 825–842 www.fuelcells.wiley-vch.de A comparison of these results with U.S. Department of Energy (DOE) cost targets and industry reported costs is shown in Figure 12. A DOE NETL (National Energy Technology Laboratory) report [36] states a target of $225 kWe–1 (in 2011 or about ª 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 835 ORIGINAL RESEARCH PAPER ume material cost dominates followed by process capital cost. Figure 9 demonstrates that with increasing production volume process/operational costs increase and labor cost decreases at greater level of automation. Capital and building costs decrease due to the higher equipment utilization, and scrap cost decreases since the cost model assumes lower defective rate at higher production volumes. ORIGINAL RESEARCH PAPER Scataglini et al.: A Direct Manufacturing Cost Model for Solid-Oxide Fuel Cell Stacks meet the DOE target above an annual production volume of about 350 MWe. Across the range of capacities from 250 MWe to 1,000 MWe shown in Figure 12 the modeled results (Model (Base Case)) are within 17–20% of FCE’s estimated costs and below the DOE target across this range of power levels. The lower modeled cost is perhaps not surprising given that the cost model may not capture all process steps including defect inspections and metrology steps, may underestimate process losses and product rework operations and frequency, and may overestimate product cycle times and process equipment performance levels, among other factors. Indeed, other cost models in the literature add a 10–20% ‘‘cost margin’’ or cost contingency to their manufacturing cost estimates to account for this additional manufacturing cost, e.g., Fig. 8 Disaggregation of stack cost by relative percentage of stack components cost for minor pieces of equipment or part replacements to overall stack cost for 50 kWe systems. that are not explicitly costed [10, 36]. Factoring a cost margin of 20% into our model, in order to reach the DOE target it would be necessary to produce (see Figure 13) at least an annual equivalent power of 100 MWe (10,000 units of 10 kWe power or 1,000 units of 100 kWe power) or 250MWe for 5kWe systems at 50,000 units year–1. In contrast, adding a cost margin higher than 20%, a production of 100 MWe would not be sufficient to meet the DOE target. Figure 14 shows the modeled stack costs at much lower annual manufacturing volumes (2.5–50 MWe). Here even with a 30% cost margin, modeled costs are 34–47% lower than recently reported results from SOLIDpower [37]. SOLIDpower results correspond to a 2.5 kWe system at volumes of 1000, 5000, and 20,000 units per year. If we assume a 30% lower process yield for the various stack modules and apply a 30% cost margin, modeled costs are still Fig. 9 Disaggregation of stack cost by relative percentage of cost components to 10–20% lower than SOLIDpowers estimates. There overall stack cost for 50 kWe systems. are three primary factors for why modeled stack costs are much lower for this case of low power, lower annual volume production: (i) This work is primarily based on FCE/VersaPower’s $238 kWe–1 in 2015) for mass manufacturing but without speciSOFC stack architecture and reported process steps and fying a manufacturing level.1) We assume this is for a level of stack materials. The base FCE/VersaPower power 100 MWe per year and above. Also shown are manufacturing system is also a larger system (10–50 kWe and higher) cost projections reported by FuelCell Energy (FCE) [22]. Note versus the micro-CHP system sized of SOLIDpower that the FCE model assumes a slightly higher power density (2.5 kWe). Thus, differences could arise both in material at 0.299 W cm–2 than the 0.282 W cm–2 assumed in this work. compositions and differences in process assumptions. In the past years, FuelCell Energy Inc. has performed stack For example, the EES stack is known to be a key cost cost modeling for net electricity capacity of 5 kWe, 10 kWe and driver for processing and materials, and the implemen20 kWe and a production volume of 50,000 units per year. tation of single step co-firing versus multi-step firing is a Figure 12 shows that the FCE estimates for manufacturing cost critical contributor to reducing capital and overall manufacturing costs. (ii) Lower volume may include more purchased compo– nents. As described above, our analysis is focused on 1) From NETL [34]: ‘‘The stack cost target for the Nth of a kind costs that can be achieved at scaled up, high process volunit assuming mass-manufacturing related cost advantages umes and a vertically integrated factory is assumed. At along with learning from repetition and increased capacity.’’ 836 ª 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim www.fuelcells.wiley-vch.de FUEL CELLS 17, 2017, No. 6, 825–842 Scataglini et al.: A Direct Manufacturing Cost Model for Solid-Oxide Fuel Cell Stacks Fig. 10 Global sensitivity analysis for 50 kWe system at the production volume of 100 systems year–1. 6 Conclusions Fig. 11 Global sensitivity analysis for 50 kWe system at the production volume of 50000 systems year–1. Fig. 12 Stack manufacturing costs for annual manufacturing volumes of 250-1000 MW. The base case result is within 17-20% of FCE’s reported cost estimates. FUEL CELLS 17, 2017, No. 6, 825–842 www.fuelcells.wiley-vch.de Presented here are the results of a detailed manufacturing cost model for SOFC fuel cell stacks, and comparisons of those results to stack manufacturing costs made by two SOFC stack manufacturers. Under the assumptions made here, manufacturing costs are within 17–20% of industry-estimated costs. Factoring in a 20% cost margin into our modeled results implies that the DOE target of $238 kWe–1 can be achieved at an annual manufacturing volume of 100–250 MWe depending on system size and annual production rate. Key assumptions include vertically integrated manufacturing and high speed, relatively high yield stack deposition processes for the EEA, and cost reductions in material costs with higher volume purchases from material suppliers. Implicit in these assumptions is the assumption of continuous ‘‘learning-by-doing’’ as manufacturing volumes increase to improve process yields, and accumulation of knowledge regarding best manufacturing processes and defect mode characterization and understanding. We found that the EEA makes up about 50% of the stack cost at all annual production volumes, followed by the cell sealing process at 10–18% and interconnects at 10–18% of the stack manufacturing cost. Single step co-firing of the EEA vs. multi-step co-firing, process yield and power density are the most sensitive parameters for the stack cost at both low and high annual production volumes. At low production volumes (5 MWe per year), line perfor- ª 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 837 ORIGINAL RESEARCH PAPER (iii) lower volumes, there may be more purchased parts than have been assumed here and these could drive up costs since any purchased stack component would incur an additional markup. For example, the base cost shown in Figure 14 would be about 10% higher if interconnects were purchased from a third party vendor which has the same cost structure assumed here and assuming a 100% markup. At low manufacturing volumes, process yields are expected to be lower and process costs higher than at high manufacturing volumes. The range or errors in modeled costs can thus be expected be higher than at higher process volumes when high process yields are assumed at high volumes. For example, costs can be higher at lower volumes due to higher labor costs (more engineering labor vs. factory workers, more tool set up time, more reworked processes, more manual inspection, lower tool availability and tool performance, lower process yield, etc.). Scataglini et al.: A Direct Manufacturing Cost Model for Solid-Oxide Fuel Cell Stacks ORIGINAL RESEARCH PAPER scope of this work. Additional future work includes further detailed study of lower power (1–5 kWe) fuel cell stack design and manufacturing, and expanding the scope of the analysis to include balance of plant costs and overall fuel cell system total costs of ownership. Acknowledgements Fig. 13 DOE cost target vs. modeled stack manufacturing costs with a 20% cost margin. This work was supported by the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy (EERE) Fuel Cells Technologies Office (FCTO) under Lawrence Berkeley National Laboratory Contract No. DE-AC02- 05CH11231. The authors would also like to acknowledge inputs from contributions of Brian Borglum (FuelCell Energy), Nguyen Minh (University of California San Diego), and Prof. Jack Brouwer (University of California, Irvine). Fig. 14 Stack manufacturing costs for annual manufacturing volumes of 2.5– 50 MW. Even with a 30% margin, modeled costs are 34–47% lower than SOLIDpower cost estimates (both estimates are in 2015). mance and labor rate are the next most sensitive parameters, while at high production volume (2500 MWe per year), material costs and tool availability also become important cost sensitivities. Key uncertainties in this type of modeling are the exact ‘‘state of the art’’ design details for SOFC stacks, the actual process yields of stack process modules, and the details of stack composition and materials. Reverse engineering of a commercial fuel cell through stack performance characterization and cross sectional analysis of an actual fuel cell stack would provide valuable information but this was beyond the 838 ª 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim www.fuelcells.wiley-vch.de FUEL CELLS 17, 2017, No. 6, 825–842 Scataglini et al.: A Direct Manufacturing Cost Model for Solid-Oxide Fuel Cell Stacks ORIGINAL RESEARCH PAPER Appendix Table A.1 Process parameters for tape casting machines. Tape casting machines (HED International Inc.) 1 Model TC-251 TC-501 TC-502 TC-1002 TC-1004 Cost ($) Contact vendor1 Contact vendor1 Contact vendor1 Contact vendor1 Contact vendor1 Estimated capacity / MWe year–1 £5 10–25 50–100 250–500 ‡1,000 # of machines 1 1 1 2–3 ‡6 # of workers/machine 2 2 2 2 2 Casting Length / m 7.7 15.4 15.4 30.8 30.8 Casting Width / mm 300 300 600 600 1,200 Casting Speed / m min–1 0.25 0.5 0.5 1.00 1.00 Drying time / min 10.0 10.0 10.0 10.0 10.0 Required tunnel length / m 6.17 12.35 12.35 24.7 24.7 No of cells casted in a row 1 1 3 3 6 Cell dimensions including margin / mm 0.1915 0.1915 0.1915 0.1915 0.1915 Mylar roll length / m 1,000 1,000 1,000 1,000 1,000 Cycle time / part–1 53.02 25.57 8.52 4.49 2.25 Vendor shared equipment costs with authors for this study, but asked not to disclose them. Table A.2 Process parameters for screen printing lines Screen printing lines (Manncorp) Manual Line (£ 5 MWe) Cost / $ Length / m Width / m Consumption / kW Cycle time / s Parts cycle–1 # of workers Screen printer (PB-2300) 20,000 0.745 0.96 3.00 35 1 1 Cycle time / s Parts cycle–1 # of workers 12 1 1 Cycle time / s Parts cycle–1 # of workers 12 3 1 Cycle time / s Parts cycle–1 # of workers 12 3 1 Reflow oven (CR-3000) 10,000 1.8 0.855 10.00 PCB conveyor (BC-100X-W1) 3,595 1.2 0.8 0.1 Automatic Line #1 (5-25 MWe) Cost / $ Length / m Width / m Consumption / kW PCB Loader (BL-460W-ST) 10,695 1.75 0.96 0.3 Screen Printer (AP430) 60,000 1.45 1.12 3 PCB conveyor (BC-100X-W1) 3,595 1.2 0.8 0.1 Reflow oven (CR-4000) 25,000 2 1.2 15 Automatic Line #2 (50-100 MWe) Cost / $ Length / m Width / m Consumption / kW PCB Loader (BL-460W-ST) 10,695 1.75 0.96 0.3 Screen Printer (AP660) 80,200 1.13 0.89 3 PCB conveyor (BC-100X-W1) 3,595 1.2 0.8 0.1 Reflow oven (CR-5000) 35,000 3 1.51 22 Automatic Line #3 (‡ 250 MWe) Cost / $ Length / m Width / m Consumption / kW PCB Loader (BL-460W-ST) 10,695 1.75 0.96 0.3 Screen Printer (AP660) 80,200 1.13 0.89 3 PCB conveyor (BC-100X-W1) 3,595 1.2 0.8 0.1 Reflow oven (CR- 8000) 50,000 4.8 1.51 40 FUEL CELLS 17, 2017, No. 6, 825–842 www.fuelcells.wiley-vch.de ª 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 839 ORIGINAL RESEARCH PAPER Scataglini et al.: A Direct Manufacturing Cost Model for Solid-Oxide Fuel Cell Stacks Table A.3 Process parameters for co-firing kilns. Co-firing kilns (Keith Company) Model Low volume (envelope) Mid volume (envelope) High volume (robotic) Type of load manual manual robotic Kiln capacity / parts cycle–1 256 2,000 4,960 Kiln capacity / MWe year–1 0.1 1–5 >5 Furniture cost / $ 30000 146,000 200,000 Cost + installation / $ 150,000 730,000 2,000,000 Furnace total cost / $ 180,000 876,000 2,200,000 Load/unload time / h cycle –1 2.2 16.7 6 # of workers 2 2 0 Sintering time / h 24 24 24 Total cycle time / h 26.2 40.7 30 Average consumption / kW 50 240 320 Table A.4 Process parameters for interconnect manufacturing lines. Interconnect manufacturing lines Equipment Manual Line Semi-Automatic Line Automatic Line Cost / $ Average Consumption / kW Cost / $ Average Consumption / kW Cost / $ Average Consumption / kW 50,000 7.5 480,000 17 480,000 17 165,000 2 165,000 2 200,000 5 500,000 10 750,000 10 165,000 2 165,000 2 500,000 140 1,920,000 504 2,875,000 756 Pick & Place Robot 165,000 2 Inspection 250,000 10 Dual Die Stamper Pick & Place Robot Cleaner/Dryer Pick & Place Robot PVD Cycle Time / s part –1 # of workers line–1 28 10 7 1 1 0 Table A.5 Process parameters for annealing furnaces. Annealing Furnaces (Abbott Furnace Company) Model Type A Type B Type C Type D Type of load Manual Robotic Robotic Robotic Furnace capacity / MWe year–1 £1 =5 = 10 >10 Conveyor speed / m min–1 0.05 0.09 0.09 0.09 Furnace width / m 0.32 0.32 0.64 0.92 Furnace length / m 15 30 30 30 Drying time / min 330 330 330 330 Piece width / m 0.28 0.28 0.28 0.28 Piece length / m 0.28 0.28 0.28 0.28 Cycle time per row / s 369.6 184.8 184.8 184.8 Pieces per row 1 1 2 3 Cycle time per piece / s 369.60 184.80 92.40 61.60 # of workers 2 0 0 0 Average consumption / kW 35 35 67 100 Furnace Cost / $ 600,000 1,100,000 1,200,000 1,350,000 840 ª 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim www.fuelcells.wiley-vch.de FUEL CELLS 17, 2017, No. 6, 825–842 Scataglini et al.: A Direct Manufacturing Cost Model for Solid-Oxide Fuel Cell Stacks ORIGINAL RESEARCH PAPER Table A.6 Process parameters for assembly and testing. Stack assembly lines Model –1 Manual Semi-automatic Automatic <100 k 100 k–600 k >600 k Cost / $ 20,000 400,000 850,000 # of workers / line–1 2 2 1 Cycle time / s stack–1 120 28 20 4-fold station with 1 cart 8-fold station with 2 carts 16-fold station with 4 carts No. of EEA cells / year Stack sintering and testing stations (FuelCon) Model Stacks tested / cycle –1 4 8 16 Cost / $ unit–1 400,000 700,000 1,300,000 # of workers station–1 1 1 1 Loading time / min 20 40 60 Cycle time / h 16–24 16–24 16–24 Average consumption / kW 15 30 60 References [1] M. Wei, T. Lipman, A. Mayyas, J. Chien, S. H. Chan, D. Gosselin, H. Breunig, M. Stadler, T. McKone, P. Beattie, P. Chong, W. G. Colella, B. D. James, LBNL Report 6772E, 2014. [2] W. G. Colella, Journal of Power Sources 2003, 118, 129. [3] M. R. Ormerod, Chemical Society Reviews 2003, 32, 17. [4] K. Sopian, W. R. Daud, Renewable Energy 2006, 31, 719. [5] E. J. Carlson, P. Kopf, J. Sinha, S. Sriramulu, NREL/SR560-39104, 2005. [6] C. Wannek, A. Glüsen, D. Stolten, Desalination 2010, 250, 1038. [7] F. Tietz, H.-P. Buchkremer, D. Stöver, Solid State Ionics 2002, 152–153, 373. [8] I. Bar-On, R. Kirchain, R. Roth, Journal of Power Sources 2002, 109, 71. [9] V. Mehta, J. S. Cooper, Journal of Power Sources 2003, 114, 32. [10] B. D. James, A. Spisak, W. Colella, Manufacturing Cost Analysis of Stationary Fuel Cell Systems, Strategic Analysis, 2012. [11] J. S. Haberl, Economic Calculations for ASHRAE Handbook, EST-TR-93-04-07, Energy Systems Laboratory, College Station, Texas A&M University, TX 1993. Available at http://oaktrust.library.tamu.edu/bitstream/handle/ 1969.1/2113/ESL-TR-93-04-07.pdf. [12] J. Verrey, M. D. Wakeman, V. Michaud, J.-A. E. Månson, Composites Part A: Applied Science and Manufacturing 2006, 37, 9. [13] Forecast-Chart, can be found under http://www. forecast-chart.com/forecast-inflation-rate.html, 2015. [14] Trading Economics, can be found under http://www. tradingeconomics.com/united-states/mortgage-rate, 2015. FUEL CELLS 17, 2017, No. 6, 825–842 www.fuelcells.wiley-vch.de [15] Tax-rates.org, can be found under http://www.taxrates.org/taxtables/property-tax-by-state, 2015. [16] RSMeans, can be found under http://learn.rsmeans. com/rsmeans/models/factory2/, 2017. [17] U.S. Department of Commerce, Bureau of Economic Analysis, can be found under https://www.bea.gov/, 2015. [18] Virginia Polytechnic Institute, can be found under https://www.eng.vt.edu/news/glass-based-seal-solidoxide-fuel-cells-could-help-bring-efficient-energytechnology-market, 2016. [19] M. Kishimoto, K. Miyawaki, H. Iwai, M. Saito, H. Yoshida, Fuel Cells 2013, 13, 476. [20] J. Stevenson, paper presented at the SOFC Seal Meeting, SECA Core Technology Program, Sandia National Laboratory, Albuquerque, New Mexico, 2003. [21] G.-B. Jung, can be found under http://www.enedu. org.tw/files/DownloadFile/20131010130452.pdf, 2013. [22] H. Ghezel Ayagh, paper presented at the 15th Annual SECA Workshop, National Energy Technology Laboratory, Pittsburgh, Pennsylvania, 2014. [23] B. Borglum, in Fuel Cell Seminar 2008 (Eds. M. Williams, K. Krist, N. Garland), The Electrochemical Society, Pennington, New Jersey, 2008, pp. 9. [24] E. J. Carlson, Y. Yang, C. Fulton, Tiax Report for National Energy Technology Laboratory, 2004. [25] H. K. Woodward, M.S. Thesis, Worcester Polytechnic Institute, Worcester, Massachusetts, 2003. [26] ACI Technologies, Inc., Report under U.S. Government Contract No. N00014-08-D-0758, 2011. [27] W. Schafbauer, N. Menzler, H. P. Buchkremer, International Journal of Applied Ceramic Technology 2014, 11, 125. [28] A. Thorel, Tape Casting Ceramics for High Temperature Fuel Cell Applications, Ceramic Materials, (Ed. Wilfried Wunderlich), Sciyo, InTech, Rijeka, Croatia, 2010, Available ª 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 841 ORIGINAL RESEARCH PAPER Scataglini et al.: A Direct Manufacturing Cost Model for Solid-Oxide Fuel Cell Stacks [29] [30] [31] [32] from: http://www.intechopen.com/books/ceramic-materials/tape-casting-ceramics-for-high-temperature-fuelcellapplications. Q. L. Liu, C. Fu, S. Chan, G. Pasciak, IOP Conf. Ser.: Mater. Sci. Eng. 2011, 18, 132006. R. Mistler, R. Runk, D. Shanefield, in Ceramic Fabrication Processing Before Firing (Eds. George Y. Onoda, L. Hench), John Wiley & Sons, New York, 1978, pp. 411. Battelle Memorial Institute, Report for U.S. Department of Energy under Contract No. DE-EE0005250, 2014. A. Burggraaf, L. Cot, Fundamentals of Inorganic Membrane Science and Technology, Elsevier, Amsterdam, 1996. [33] M. Weimar, D. Gotthold, L. Chick, G. Whyatt, PNNL22732, 2013. [34] G. Ye, F. C. Ju, The Electrochemical Society 2005, 7, 451. [35] S. R. Akanda, Journal of Power Sources 2011, 210, 254. [36] K. Krullam, A. Iyengar, D. Keairns, D. Newby, DOE/ NETL-342/093013, 2013 [37] M. Bertoldi, paper presented at the 2015 Fuel Cell Seminar and Energy Exposition, Fuel Cell Seminar and Energy Exposition, Los Angeles, California, 2015. ______________________ 842 ª 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim www.fuelcells.wiley-vch.de FUEL CELLS 17, 2017, No. 6, 825–842