Preface to the Second Edition A decade after the first edition of this volume was published, a second edition is being brought out partly due to the excellent response to the first edition and also to update the many improvements in deposition technologies, the mechanisms and applications. The entire volume has been extensively revised and contains 50% or more new material. Five entirely new chapters have been added. The organization of the book has also been changed in the following respects: 1. Considerably more material has been added in Plasma Assisted Vapor Deposition Processes. 2. A new chapter on Metallurgical Coating Applications has been added. The chapter in the first edition on Polymeric Coating techniques has been omitted as it deserves a volume by itself. Large topics such as coatings technology in microelectronics, diamond films, etc., have been treated in separate volumes in this series. Although there are some new competing volumes dealing with selected topics on the materials science of thin films, this volume remains the only comprehensive treatment of the entire subject of Deposition Technology. Applications of films and coatings spans the entire gamut of science and technology. Generic application areas include electronic, magnetic, optical, mechanical, chemical and decorative applications. New deposition technologies such as arc evaporation, unbalanced magnetron sputtering, ion beam assisted deposition, and metal-organic CVD have come on stream for critical applications. In this post cold war era, many economic solutions to engineering problems will necessarily involve coatings, e.g., battery materials for the emerging electric car industry. ix x Preface Contents The core subjects are the basic technologies for the deposition of films and coatings. These are the Physical Vapor Deposition (PVD) Processes consisting of Evaporation, Sputtering, and Ion Plating; Chemical Vapor Deposition (CVD) and Plasma-Assisted Chemical Vapor Deposition (PACVD); Electrodeposition and Electroless Plating; Thermal Spraying, Plasma Spraying and Detonation Gun Technologies. Chapters on other subjects common to the above technologies are included. These are: Adhesion of Coatings, Cleaning of Substrates, Role of Plasmas in Deposition Processes, Structure of PVD Deposits, Growth and Structure of PVD Films, Mechanical and Tribological Properties of PVD Deposits, Elemental and Structural Characterization Techniques, and Metallurgical Coatings. A relatively new development, Jet Vapor Deposition Process, was added as the last chapter in the book during the page proof stage because of its novelty. We hope that this volume will be useful to the multitude of disciplines represented by the workers in this field and provide a source for future developments. University of California Los Angeles, California June, 1993 Rointan F. Bunshah