DEPARTMENT FOR CURRICULUM, RESEARCH, INNOVATION AND LIFELONG LEARNING Directorate for Learning and Assessment Programmes Educational Assessment Unit Track 2 Annual Examinations for Secondary Schools 2018 YEAR 9 CHEMISTRY TIME: 2 hours Name: ______________________________________ Class: ______________________________________ Useful Data Atomic numbers and relative atomic masses are shown in the periodic table printed on a separate page. Marks Grid [ For Examiner’s use only ] Question No. 1 Max Mark 10 2 Section A 3 4 5 6 7 10 10 10 10 20 10 Section B 8 9 20 20 Theory Total Actual Mark Theory Paper: 85% Chemistry – Year 9 – Track 2 – 2018 Practical: 15% Final Score: 100% Page 1 of 12 SECTION A – Answer ALL questions in the spaces provided. This section carries 60 marks. 1) With the help of the periodic table of the elements, give the name or symbol of an element which: a) does not form compounds _______________ b) is a shiny solid and conducts electricity _______________ c) is the gas most abundant in air _______________ d) is a liquid metal at room temperature _______________ e) is a solid non-metal that burns in air to form an acidic oxide _______________ f) is a metal that forms an amphoteric oxide _______________ g) is a gas that produces water on combustion _______________ h) is a non-metal, one of its oxides sublimes _______________ i) has 3 electron shells and 6 electrons in its outer shell _______________ j) forms a positive ion with an electronic configuration of 2,8 and a charge of +2 _______________ (1 mark each – Total 10 marks) 2) Matter is made of particles. The physical state of matter can be changed by heating as shown in the graph below: a) Which state of matter do the following lines on the graph represent? CD __________________ EF ___________________ (2) b) Use the Kinetic Theory of Matter to: i) Draw a diagram that represents the arrangement of the particles in AB (1) Page 2 of 12 Chemistry – Year 9 – Track 2 – 2018 ii) Explain the arrangement of the particles when the substance is in the physical state represented by AB. ________________________________________________________________________ ________________________________________________________________________ _____________________________________________________________________ (2) c) In the state represented by EF, the substance is said to be compressible. i) Draw the arrangement of particles in the box below. (1) ii) Explain why gases are compressible ____________________________________________________________________ ____________________________________________________________________ _________________________________________________________________ (1) d) Give the names of the processes represented by: BC _____________________ DE _______________________ (2) e) When heating a substance, heat energy is absorbed by the particles of that substance and its temperature increases. Explain why during DE, the temperature of the substance does not increase. _______________________________________________________________________ _______________________________________________________________________ ____________________________________________________________________ (1) Total: 10 marks Chemistry – Year 9 – Track 2 – 2018 Page 3 of 12 3) The picture shows how the solubility in water of various solutes changes with temperature. a) Two of the solutes shown are gases while the others are salts. State how the solubility of gases and salts in water changes with temperature. _______________________________________________________________________ ____________________________________________________________________ (2) b) From the graph: i. What temperature is required to completely dissolve 45 g of KCl in 100 g of pure water? __________________________________________________________________ (1) ii. If the solution mentioned in (b)(i) is cooled to 10 °C, how much KCl, in grams, would crystallizes out of solution? __________________________________________________________________ (1) c) Sodium chloride is an ionic substance. Draw a dot-cross diagram of the sodium chloride ions showing all electron shells. (3) Page 4 of 12 Chemistry – Year 9 – Track 2 – 2018 d) Using a dot-cross diagram, draw the bonding in water, H2O, showing outer shells only. (3) Total: 10 marks 4) This question is about water hardness. a) What happens when soap is added to hard water? ____________________________________________ ________________________________________ (1) b) Give the name or formula of a substance that causes: i) Temporary hardness ____________________________________________ (1) ii) Permanent hardness ____________________________________________ (1) c) State a method which removes i) Temporary hardness only ____________________________________________ (1) ii) Both temporary and permanent hardness _______________________________ (1) d) Give one advantage and one disadvantage of water hardness ______________________________________________________________________ ______________________________________________________________________ ___________________________________________________________________ (2) e) Hard water usually leaves behind deposits of calcium carbonate (CaCO3) in the form of limescale, as can be seen in the picture above. Which of the following substances would be suitable to remove the limescale from the water tap in the picture? (underline the correct answer) ammonia solution (1) vinegar dilute sodium hydroxide f) Carbon dioxide dissolves in rain water to make it slightly acidic. Rain water dissolves carbonates of calcium and magnesium that are major constituents of rock. This is also how natural water becomes hard. Give a balanced chemical equation that happens when rain water passes through rock. ____________________________________________________________________ (2) Total: 10 marks Chemistry – Year 9 – Track 2 – 2018 Page 5 of 12 5) Hydrogen is the first element of the periodic table. It is also the lightest gas and exists as diatomic molecules. a) Hydrogen has three isotopes. Their symbols are shown below. Explain what is meant by the term ‘isotopes’ in terms of protons and neutrons. Use hydrogen as an example. ______________________________________________________________________ ______________________________________________________________________ ___________________________________________________________________ (2) b) Hydrogen is produced in the laboratory by reacting a metal with a dilute acid. The following diagram shows the apparatus used to carry out the reaction. Complete the diagram below by drawing the apparatus you would use to collect hydrogen gas. (2) c) In an experiment, 1.2 g of magnesium are reacted with dilute hydrochloric acid, to produce hydrogen gas and magnesium chloride solution. The reaction is given below: Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g) (N.B. Relative atomic masses: Mg=24, H=1; Avogadro’s constant = 6x10 23) By showing your working, calculate: i) the amount (in moles) of magnesium reacting. ___________________________________________________________________ _________________________________________________________________ (1) ii) the amount (in moles) of magnesium chloride produced. _________________________________________________________________ (1) iii) the number of ions present in the magnesium chloride produced. ___________________________________________________________________ _________________________________________________________________ (2) Page 6 of 12 Chemistry – Year 9 – Track 2 – 2018 iv) the mass, in grams, of hydrogen gas produced. ___________________________________________________________________ ___________________________________________________________________ _________________________________________________________________ (2) Total: 10 marks 6) This question is about acidic and basic substances. a) Complete and balance the following chemical reactions: i) __ H2SO4 + __ NaOH → ___________________________________________ (2) ii) __ HCl + __ Na2SO3 → ______________________________________________ (2) iii) __ NaOH + __ NH4Cl → _____________________________________________ (2) b) Oxides are compounds that oxygen forms with many elements. Complete the following grid by drawing lines to match the different types of oxides with the correct description. Oxides Neutral Basic Amphoteric Acidic Definition React with both acids and alkalis Give solutions with pH less than 7 React with alkali to give salt + water Do not react with neither acids nor alkalis Give solutions with a pH greater than 7 React with acid to give salt + water (2) c) Give the name or formula of a basic oxide that is soluble in water. ____________________________________________________________________ (1) d) Universal indicator was used to show whether the solution obtained in (c) is acidic or alkaline. State the colour that results when this indicator is added. Colour: _____________________________________________________________ (1) Total: 10 marks Chemistry – Year 9 – Track 2 – 2018 Page 7 of 12 SECTION B – Answer TWO questions ONLY in the spaces provided. This section carries 40 marks. 7) The Earth’s atmosphere is a mixture of gases. a) The following setup can be used in a laboratory to remove some gases from the air. Stage 1: U-tube contains calcium hydroxide solution (limewater). Stage 2: U-tube contains solid anhydrous copper(II) sulfate. Stage 3: In the furnace, granules of copper metal are heated strongly. i) For each stage, Name which gas is removed (3) Stage 1: ______________________________ Stage 2: ______________________________ Stage 3: ______________________________ State what you would observe. Stage 1: (3) _________________________________________________________ _________________________________________________________________ Stage 2: _________________________________________________________ _________________________________________________________________ Stage 3: _________________________________________________________ _________________________________________________________________ Complete and balance the following chemical equations to explain the observations you mentioned. Stage 1: Ca(OH)2(aq) + (6) ________ (g) → Stage 2: CuSO4(s) + Stage 3: Cu(s) _______ (g) → + CaCO3(s) + _________ (l) _________ (g) → _________________ (s) __________ (s) ii) Predict which gas is mainly collected in the gas syringe. (1) ___________________________________________________________________ Page 8 of 12 Chemistry – Year 9 – Track 2 – 2018 b) Some gases should not be present at all in our atmosphere. Such gases are considered as pollutants. i) Give the name of one such gas. _______________________________________ (1) ii) Explain how this gas is formed. ___________________________________________ _________________________________________________________________ (1) iii) Mention one of its harmful effects. ________________________________________ _________________________________________________________________ (1) c) Hygroscopic substances such as anhydrous copper(II) sulfate readily absorb water vapour from the air around us to form hydrated crystals. Other substances behave differently when exposed to air. Give ONE word to describe the following substances and give ONE example of each: i) Compounds that absorb so much water from the atmosphere that they form a solution. ___________________________________________________________________ Example: _________________________________________________________ (2) ii) Substances that lose their water of crystallization to form the anhydrous salt. ___________________________________________________________________ Example: _________________________________________________________ (2) Total: 20 marks 8) This question is about salts and their preparation. a) Anhydrous copper(II) chloride, CuCl2, is a soluble salt and can be prepared in the laboratory by reacting an insoluble salt of copper with a dilute acid. The diagram below shows the method used. i) From the following list, choose the correct reactants that can be used in this experiment. Solid salts: Cu(NO3)2 or CuO Dilute acids: HCl or HNO3 Salt: ________________ Acid: ________________ Chemistry – Year 9 – Track 2 – 2018 (2) Page 9 of 12 ii) Write a balanced equation for the reaction between the reactants you have chosen to prepare copper(II) chloride. Include state symbols. __________________________________________________________________ (3) iii) The amount of solid salt used must be in excess of the quantity of acid. Explain why this is important. _____________________________________________________________________ __________________________________________________________________ (1) iv) Why is filtration required in the second step of the method? __________________________________________________________________ (1) v) The above setup is not suitable to obtain hydrated crystals. Draw the correct apparatus that should be used in the final step to obtain hydrated copper(II) chloride crystals. (3) b) Zinc carbonate, ZnCO3, was prepared by precipitation by mixing a solution containing 27.2 g of zinc chloride and a solution containing ammonium carbonate. (Relative atomic masses: Zn=65, Cl=35.5, C=12, O=16) i) Complete and balance the equation for the reaction. Include state symbols. ZnCl2(aq) + (NH4)2CO3(aq) → ______________________________ (3) ii) Work out the relative formula mass of zinc chloride, ZnCl 2 ________________________________________________________________ (1) iii) Calculate the number of moles of zinc chloride in the 27.2 g of ZnCl2 used. ____________________________________________________________________ ____________________________________________________________________ ________________________________________________________________ (2) iv) Use the equation to work out the number of moles of ZnCO3 produced. ____________________________________________________________________ _________________________________________________________________ (2) v) Calculate the mass, in grams, of zinc carbonate obtained. ____________________________________________________________________ ____________________________________________________________________ _________________________________________________________________ (2) Total: 20 marks Page 10 of 12 Chemistry – Year 9 – Track 2 – 2018 9) This question is about Oxygen. a) Oxygen can be prepared in the laboratory by the catalytic action of manganese(IV) oxide (MnO2) on hydrogen peroxide (H2O2). i) On the diagram label the reagents used for the reaction. (2) ii) Complete the diagram to show how you would collect the oxygen over water. Label your drawing. iii) Give a balanced chemical equation for the reaction. (3) (2) ____________________________________________________________________ iv) State how you would test and confirm that the gas produced is oxygen. (1) ____________________________________________________________________ v) Explain the function of manganese(IV) oxide in this reaction. (2) ____________________________________________________________________ ____________________________________________________________________ b) Rusting is a term used to refer to the corrosion of iron. In the experiment shown in the diagram, would you expect the iron nail in tubes B and C to rust? Explain your answer. Chemistry – Year 9 – Track 2 – 2018 Page 11 of 12 Tube B: ________________________________________________________________ ____________________________________________________________________ (2) Tube C: ________________________________________________________________ ____________________________________________________________________ (2) c) Oxygen, nitrogen and some noble gases can be obtained on a large scale from air. Give the name of the industrial process used. ____________________________________________________________________ (1) d) An allotrope of oxygen in the Earth’s atmosphere filters harmful radiation from the sun. Give its name or formula. ____________________________________________________________________ (1) e) Oxygen and nitrogen can form various gases between them. One such gas contains 30.43 % nitrogen and 69.57 % oxygen by mass. i) Calculate the number of moles of nitrogen atoms in the compound. (RAM Nitrogen = 14). ___________________________________________________________________ ________________________________________________________________ (1) ii) Calculate the number of moles of oxygen atoms in the compound. (RAM Oxygen = 16). ___________________________________________________________________ ________________________________________________________________ (1) iii) Find the mole ratio between nitrogen and oxygen in this compound. ___________________________________________________________________ ________________________________________________________________ (1) iv) Given that one mole of this gas has a mass of 46 g, work out the molecular formula of this gas. ___________________________________________________________________ ___________________________________________________________________ ________________________________________________________________ (1) Total: 20 marks Page 12 of 12 Chemistry – Year 9 – Track 2 – 2018