VALENCE OF COMMON IONS AND RADICALS I. Monovalent or Univalent Ions A. Positive Ions Hydrogen H+ Lithium Li+ Sodium Na+ Potassium K+ Cuprous Cu+ or Cu2+2 B. Negative Ions Fluoride Chloride Bromide Iodide Hypo-halite Halite Halate Per-halate Hypophosphite Bicarbonate Bisulfate Bisulfite Metarsenite Primary Arsenate Primary Arsenite Primary Phosphite FClBrIXOXO2XO3XO4H2PO2HCO3HSO4HSO3AsO2H2AsO4H2AsO3H2PO3- Aurous Silver Ammonium Mercurous Metaborate Metaluminate Chromite Nitrite Nitrate Bismuthate Permanganate Cyanide Cyanate Thiocyanate Argenticyanide Acetate Hydroxide Formate Primary Phosphate Au+ Ag+ NH4+ Hg+ or Hg2+2 BO2AlO2CrO2NO2NO3BiO3MnO4CNCNOSCNAg(CN)2CH3COOOHHCOOH2PO4- Note: X above refers to halides: F, Cl, Br, and I. Thus FO- is hypofluorite, BrO2- is bromite, IO3- is iodate, ClO4- is perchlorate II. Divalent or Bivalent Ions A. Positive Ions Magnesium Mg+2 Calcium Ca+2 Strontium Sr+2 Barium Ba+2 Cadmium Cd+2 Cobaltous Co+2 Cupric Cu+2 Ferrous Fe+2 B. Negative Ions Oxide Peroxide Sulfide Sulfite Sulfate Thiosulfate Persulfate Pyrosulfate Tetrathionate Secondary Arsenate Secondary Arsenite Secondary Phosphite Secondary Phosphate Plumbous Manganese Mercuric Molybdenum Nickelous Stannous Zinc Pb+2 Mn+2 Hg+2 Mo+2 Ni+2 Sn+2 Zn+2 O-2 O2-2 S-2 SO3-2 SO4-2 S2O3-2 S4O8-2 S2O7-2 S4O6-2 HAsO4-2 HAsO3-2 HPO3-2 Stannite Stannate Chromate Dichromate Carbonate Oxalate Manganate Molybdate Zincate Tetraborate Metasilicate Plumbite SnO2-2 SnO3-2 CrO4-2 Cr2O7-2 CO3-2 C2O4-2 MnO4-2 MoO4-2 ZnO2-2 B4O7-2 SiO3-2 PbO2-2 HPO4-2 Tartrate C4H4O6-2 III. Trivalent Ions A. Positive Ions Aluminum Antimonous Arsenous Auric Bismuth B. Negative Ions Borate Antimonate Nitride Tertiary Phosphate or Orthophosphate Tertiary Phosphite or Orthophosphite Al+3 Sb+3 As+3 Au+3 Bi+3 BO3-3 SbO4-3 N-3 PO4-3 PO3-3 IV. Tetravalent or Quadrivalent Ions A. Positive ions Platinic Pt+4 Silicon Si+4 Stannic Sn+4 Plumbic Pb+4 V. Pentavalent or Quinquivalent Ions Antimonic Sb+5 Arsenic As+5 Chromic Cobaltic Ferric Nickelic Ferricyanide Aluminate Tertiary Arsenate or Orthoarsenate Tertiary Arsenite or Orthoarsenite Citrate B. Negative Ions Ferrocyanide Pyrophosphate Orthosilicate Cr+3 Co+3 Fe+3 Ni+3 Fe(CN)6-3 AlO3-3 AsO4-3 AsO3-3 C6H5O7-3 Fe(CN)6-4 P2O7-4 SiO4-4 COMMON COMPOUNDS ACIDS: HCl H2SO4 HNO3 FORMULA A mixture of 1 mole HNO3 & 3 moles HCl CH3COOH H3BO3 HCN BASES: NaOH KOH Ca(OH)2 Ba(OH)2 NH4OH or NH3 + H2O Mg(OH)2 CHEMICAL NAME COMMON NAME(S) Hydrochloric acid Sulfuric acid Nitric acid “strong water” Nitric acid and Hydrochloric acid Acetic acid, conc soln Acetic acid, dilute soln Boric acid Hydrocyanic acid Muriatic acid Oil of vitriol Aqua fortis Aqua regia “royal water” Glacial acetic acid Vinegar Agua boricada Prussic acid Sodium hydroxide Potassium hydroxide Calcium hydroxide, soln Calcium hydroxide Calcium hydroxide, susp Barium hydroxide, soln Ammonium hydroxide Magnesium hydroxide Caustic soda Caustic potash Lime water Slaked lime White wash Baryta water Ammonia water Milk of magnesia SALTS: NaCl NaHCO3 CaCO3 Sodium chloride Sodium chloride, soln Sodium bicarbonate Calcium carbonate CaF2 KNO3 NaNO3 Na2CO3 Hg2Cl2 HgCl2 Calcium fluoride Potassium nitrate Sodium nitrate Sodium carbonate (anhydrous) Mercurous chloride Mercuric chloride BaSO4 AgNO3 PbCrO4 PbS NH4Cl (CH3COO)2Pb or Pb(CH3COO)2 Na2SiO3 Barium sulfate Silver nitrate Lead chromate Lead sulfide Ammonium chloride Lead acetate Common table salt Brine Baking soda Limestone, Marble, Chalk, Whiting Fluospar Saltpeter, Salitre Chile saltpeter Soda ash Calomel Corrosive sublimate; bichloride of mercury Barite Lunar caustic Chrome yellow Galena Sal ammoniac Sugar of lead Sodium silicate, soln Waterglass HYDRATES (Hydrated salts): CuSO4. 5H2O Copper sulfate pentahydrate Na2B4O7. 10H2O Sodium tetraborate decahydrate FeSO4. 7H2O Ferrous sulfate heptahydrate MgSO4. 7H2O Magnesium sulfate heptahydrate Na2SO4. 10H2O Sodium sulfate decahydrate CaSO4. 2H2O Calcium sulfate dihydrate CaSO4. ½ H2O Calcium sulfate hemihydrate Na2S2O3. 5H2O Sodium thiosulfate pentahydrate Na2CO3. 10H2O Sodium carbonate decahydrate Blue vitriol Borax Copperas, Green vitriol Epsom salts Glauber’s salt Gypsum Plaster of paris Hypo Sal soda, washing soda DOUBLE SALTS: CaOClCl or CaOCl2 K2SO4. Al2(SO4)3 24H2O or KAl(SO4)2. 12H2O KNaC4H4O6 KHC4H4O6 OXIDES & PEROXIDES: CO2 SiO2 Al2O3 As2O3 Fe2O3 N2O PbO MgO CaO ZnO H2O2 Calcium chloride hypochlorite Potassium aluminum sulfate dodecahydrate Potassium sodium tartrate Potassium acid tartrate/ Potassium bitartrate Carbon dioxide Silicon dioxide Aluminum oxide Arsenous oxide Ferric oxide Nitrous oxide Lead oxide Magnesium oxide Calcium oxide Zinc oxide Hydrogen peroxide Bleaching powder Alum, tawas Rochelle/ Seignette salt Cream of tartar Choke damp Agate, sand, silica quarts Alumina Arsenic white Hematite Laughing gas Litharge Magnesia Quicklime Zinc white Agua oxigenada