IV.6 Depositional Environment, Diagenesis and Reservoir Properties of Oncolitic Packstones, Macae Formation (Albian-Cenomanian), Campos Basin, Offshore Rio de Janeiro, Brazil Albert V. Carozzi 1, Frank U. H. Falkenhein 2, and Milton R. Franke 2 1 Introduction and Geologic Framework The stratigraphy of the Campos Basin (Fig. 1 A, B) was controlled by the following sequence of tectonic stages characteristic of rifted continental margins (Ponte et al. 1980); pre-rift arching: denudation of Paleozoic cover (Permian-Jurassic); intracratonic rift valley: N-S collapse trough enlarged to rift valley system (late Jurassic - early Cretaceous) filled by Lagoa Feia fluvio-deltaic to lacustrine clastics; proto-oceanic gulf: restricted embayment (late Aptian) with deposition of Lagoa Feia evaporites; open marine continental margin: subsidence and seaward tilting, generation of carbonate platform consisting of offshore bars of oncolitic packs tones separated by mudstones (Lower Macae, Albian); further tilting, subsidence of platform, transgression of argillaceous pelagic mudstones and intercalated turbidites (Upper Macae, Cenomanian) followed by basinal shales and turbidites (Carapebus Member, Campos Formation, SenonianEocene); renewed tilting of continental margin and rejuvenation of source areas with intense deltaic progradation (Ubatuba Member, Campos Formation (Oligocene - Pliocene). The structural framework (Fig. 1 C, D) is characterized by basement tectonics restricted to Aptian rifting and overlain by numerous dome-like structures separated by curved growth faults. The latter display a down-to-basin arrangement and disrupt only the Macae Formation and the lower part of the Campos Formation. During the Albian-Cenomanian basinward tilting, growth faults developed with related antithetic rotation of the down-thrown blocks by gravity gliding of the limestone section over the underlying Lagoa Feia evaporites acting as a lubricant. A major result was the formation of a large SW-NE trending positive area (Fig. 2) that strongly influenced carbonate depositional patterns. I Department of Geology, University of Illinois at Urbana-Champaign, 254 N.H. Building, Urbana, IL, 61801, USA 2 Petr6leo Brasileiro S. A. PETROBRAs, Exploration Department (DEPEX), Rio de Janeiro, R. J., 20035, Brazil Coated Grains (ed. by T.M. Peryt) © Springer-Verlag Berlin Heidelberg 1983 Depositional Environment, Diagenesis and Reservoir Properties of Oncolitic Packstones 331 Onshore Geology !i:'·:::;;"~,J ,.. .- . i ",,' Cenozoic l._ . ...- ~", , ; i b Brazil .~-_ ...., ''' , 0 " i !IO Klle",.t., • ..... / " .:..... · ·· • N ~ . ... Field A. Location Map C. Structural Framework Ouol. SL " ..... . Miocene .... . .. Oligocene Pol e en MoeSTricht. 10 . ~ Cenomanian Albion o c; <; ~ .. : ..... . . = ...,-;""'- Eocene u o A' A PH """"",=;;i,-= Apl ion Neocomian B. Geologic Column I: " ~~~I U. Cret. - Cenozoic ~ Albian -Cenomanian E3 Aptian Evaporites k~.:;/ I Aptian Clastics D. Schematic Cross-Section Fig. 1. Campos Basin: location, geologic column and structural framework 2 Recent Models of Formation of Oncoids Marine oncoids are forming today in tropical shallow subtidal settings by disruption of blue-green algal mats in Bermuda (Gebelein 1969), the Bahamas (Neumann et al. 1970, Scoffin 1970, Gebelein 1976), and Bonaire (Pratt 1979). In all these cases, algal mats occur adjacent to areas of extensive growth of marine grasses (Tha/assia) and seaward of sandy bottoms. The seagrass beds support a dense epiphytic growth of calcareous red algae, bryozoans and foramini- A. V. Carozzi et al. 332 Slice 1 .... :::::::~:: . , . ....: :. : .. . ... . .... . .. Sl ice 4 t,__ N r-:-:-:l L.:.:J Fluv io-de lt aic aren ites and sho les Arenaceous mudstones LI Biogen i c content 5%, IBDB I,plonkt ics 0% ~ Evapor ites ~ Shorefoce shools, pisooncolitic - ooli t ic packstones D G\o" Mudstones, b iogenic conlent 7%,IBDB 3,plonktics 18% ~ OffShore shoals, microoncoli t ic pockslones o :;:;:::.d • Mudstones, biogen ic content 10%, IBOB 5, planktics 45% ~ Offshore shoals, pisooncolit ic pockstones D Mudslones, biogenic contenl 5%, IBOB I, plankt ics 86% ~ Mudstones, biogen ic conlen! 3%, '0 Beachrock reservoir generol ion ~ IBDB 0 .5, plankt ics 96% • We II can! rol Structurel Mop On Top Of Lower Macae Formation Fig. 2. Paleoenvironmental maps and structural map of Lower Macae Formation Depositional Environment, Diagenesis and Reservoir Properties of Oncolitic Packstones 333 fers as well as numerous benthic organisms such as pelecypods and gastropods. Algal mats do not produce laminites because of environmental turbulence which continuously destroys them. Their chips, together with bioclasts from the adjacent seagrass community, become the cores of oncoids growing by means of further algal coatings and sediment binding. Final accumulation of oncoids occurs on sandy bottoms at depths of less than 1 m and accumulations of 10 to 100 oncoids m - 2 are common. Seagrass beds adjacent to algal mats are the critical ecologic factor. They have three main functions: (1) they provide a baffle effect which lowers the turbulence of the environment so as to protect the growth of algal mats but still allow enough periodical energy to generate oncoids from them; (2) they provide habitat and ecologic niches for the establishment of a stable and rich community (Brasier 1975, Taylor and Lewis 1970) which includes grazers and burrowers which otherwise would destroy the adjacent algal mats; (3) they generate large quantities of micrite mud from the disintegration of epibionts (Land 1970, Patriquin 1972). 3 Oncoids of the Macae Formation They have an irregular spheroidal to ellipsoidal shape, often deformed by compaction (Figs. 3A and 6D), and consist of pisooncoids (2 to 10 mm, in size) and microoncoids (less than 2 mm in size). Under the petrographic microscope a vague concentric layering is visible around cores of various types of bioclasts, chips of algal mats and grains of detrital quartz. Even under SEM pisooncoids no longer show filaments of blue-green algae, but only a typical internal structure of alternating porous and dense layers (Fig. 3 B). The former assumed to have been originally rich in filaments represent periods of growth of the pisooncoids whereas the latter apparently devoid of filaments represent periods of interruption of growth. There are numerous instances of major interruptions of growth superimposed on the finer couplets (Fig. 3 E). Natural broken surface of porous layers under SEM consists of a mosaic of micrite-size (0.5 to 4.0 J.lm) subhedral calcite crystals that does not give any indication of its origin (Fig. 3 C), in fact it is identical to that of micrite mud. Pore casts under SEM show a spongy network of microporosity with pores smaller than 2 J.lm (Fig. 3 D). A common feature of pisooncoids is the presence of filaments of endolithic boring algae appearing as empty flattened tubes (Fig. 3 F). 4 Application of Recent Models to Macae Oncolitic Carbonates Open marine shelf, shallow subtidal turbulent waters and baffle systems appear to be the required conditions to generate oncolitic carbonates. They would ideally result in the juxtaposition of three distinct microfacies: mudstones, wackestones (baffle system) and oncolitic packstones, but in reality the first two cannot be easily distinguished. Thalassia baffle systems can only be traced back as far as the late Cretaceous, therefore it is assumed that seagrass-like communities such Fig. 3A - F. SEM pictures of pisooncoids. A Pisooncoids extracted from a friable pisooncolitic packstone. Arrow points to deformation by compaction. B Pore cast of internal structure of pisooncoid. Couplets of porous and dense concentric layers around nucleus at left. C Broken natural surface of porous layer. Micrite size (0.5 to 4.0 ~m) subhedral calcite crystals with no indication of origin. D Pore cast of spongy microporous network. E Internal structure of pisooncoid showing thick nonporous concentric layers corresponding to major interruptions of growth. F Filament of endolithic boring alga appearing as noncalcified empty tube of organic matter inside pisooncoid Depositional Environment, Diagenesis and Reservoir Properties of Oncolitic Packstones 335 as green algae with subordinate stalked pelmatozoans and red algae played a similar role in the Lower Macae carbonates. The effects of baffle systems is revealed by the following lithologic associations: the juxtaposition of mudstones with relatively abundant and diversified benthic bioclasts and packstones consisting only of microoncoids indicates a poorly-developed seagrass community whose ineffective baffle action allowed dispersal of bioclasts in all directions and afforded little protection to algal mats. The juxtaposition of mudstones with few bioclasts among which planktics predominate and packstones consisting of pisooncoids indicates a stable and rich seagrass community with an effective baffle action releasing bioclasts only in the direction of algal mats and thus adequately protecting them. In order to differentiate among oncolitic packstones, an index of biotic diversity of benthics (IBDB) is used for bioclasts forming the nuclei of oncoids and for those scattered in the matrix. The index ranges from 1 to 8 by cumulative increments of one for each of the following constituents: echinoids, gastropods, molluscs, foraminifers, annelids, red algae, rudistids and hexacorals. The percentage of planktics (ostracods, foraminifers and calcispheres) relative to the total amount of bioclasts is used to differentiate among mudstones. 5 Paleoenvironmental Maps They illustrate the depositional settings of four parachronostratigraphic slices representing basinwide shallowing tendencies (Falkenhein 1981). The datum line is the base of the Upper Macae, a reliable chronostratigraphic surface. Slice 1 (1000 -700 m below datum, Fig. 2). Shallow subtidal to high intertidal shoreface shoals developed in the central part of the basin. They consisted of grain-supported arenaceous pisooncolitic to oolitic packstones with micrite matrix and sparite cement: IBDB of bioclasts in matrix: 8, of bioclasts as cores of pisooncoids and ooids: 6. The highest areas of the shoals were exposed and beachrock reservoirs generated. Adjacent mudstones: biogenic content: 7ft/o, IBDB: 3, planktics: 18%. The baffle system of stable seagrass community is efficient. Slice 2 (700 - 400 m below datum, Fig. 2). Migration of the shoreface shoals of slice 1 to southwest part of basin. Development in east-central area of subtidal offshore shoals. They consisted of grain-supported microoncolitic packstones with micrite matrix and rare sparite cement. The microoncoids lacked internal structure. IBDB of bioclasts in matrix: 2, of bioclasts as cores of microoncoids: 1.5. Adjacent mudstones: biogenic content: 10%, IBDB: 5, planktics: 450,10. The baffle system of immature or unstable seagrass community is inefficient. Slice 3 (400 - 200 m below datum, Fig. 2). The shoreface shoals of slice 1 persist in southwest part of basin, but without development of reservoir conditions. Southern lobe of system changed into an offshore subtidal microoncolitic shoal with adjacent relatively fossiliferous mudstones. In east-central area, the offshore subtidal microoncolitic shoals of slice 2 changed into shallow subtidal to 336 A. V. Carozzi et al. intertidal pisooncolitic shoals. The pisooncolitic packstones with micrite matrix and sparite cement have: IBDB of bioclasts in matrix: 6, of bioclasts as cores of pisooncoids: 4 - 5. Beachrock reservoirs are occluded by meteoric phreatic cementation. Adjacent mudstones: biogenic content: 5OJo, IBDB: 1, plantics: 86%. The baffle system of stable seagrass community is efficient. Slice 4 (200 - 0 below datum, Fig. 2). Final stage of conditions of slice 3. It is characterized by extensive shallowing controlled by synsedimentary tectonism. Related development of reservoirs in the offshore pisooncolitic shoals of eastcentral area (Garoupa field), at northern tip of shoreface pisooncolitic-oolitic shoals and in offshore microoncolitic shoals of southern part of basin (Pampo field). 6 Comparison with Other Mesozoic Oncolitic Environments Oncolitic and oncolitic-oolitic packstones of Mesozoic carbonate shelves have been described on a worldwide basis: Dachstein of Austria (Fischer 1964), Jurassic of Paris Basin (Purser 1978) and of the Jura Mountains of Switzerland (Bolliger and Burri 1970), Jurassic Smackover of the Gulf Coast (Bishop 1968, Becher and Moore 1979), Albian Edwards Limestone of Texas (Bebout et al. 1977), and Albian-Cenomanian Regencia Formation of Espirito Santo Basin, Brazil (Tibana and Alves 1973). The Albian-Cenomanian Madiela and Catumbella Formations of Gabon and Angola basins also contain undescribed oncolitic carbonates (de Klasz 1978). The above-mentioned examples are similar to those described here in the following critical aspects: occurrence as subtidal to intertidal offshore shoals with subordinate shoreface shoals and longshore belts, associated subtidal mudstones with very low fossil content, absence of other types of packstones and general paucity of fossils of carbonate platforms bearing large oncolite deposits. 7 Depositional-Diagenetic Sequence The oil traps in the upper part of the Lower Macae are mixed structural-stratigraphic resulting from closure by domes and growth faults combined with favorable depositional-diagenetic conditions. The latter are part of a sequence of ten stages of early to burial diagenesis distinguished on petrographic and cathode luminescence textures, and confirmed by stable isotope data (Franke 1981). Low Intertidal Environment. Stage 1 (Fig. 4): deposition of initial unconsolidated sediment consisting of a framework of abraded pisooncoids with interstitial sand-size bioclasts and intraclasts set in a finer matrix interpreted as "oncoid flour" derived from the abrasion of the larger pisooncoids. Stage 2 (Figs. 4A and 5A, B): diagenetic, precipitation of thin isopachous rim cement of fibrous calcite (high magnesium and/or aragonite?). Depositional Environment, Diagenesis and Reservoir Properties of Oncolitic Packs tones Stage 1- Depositional Stage 2 - Diagenet ic: cementat ion ~. @ • ~ ... ... ' . w: ti ·.., ~® ,iro.."," ',', : . .~ ,ntroclost <D .;, ....... pisoonco id /wilh iSopochous : ~ri mcement .' ~ " '" I'??'i_ . ,~ ~ ~ biOClost~ bIOClost~' ~~ ,<0 •• ~~ .. oncoid Iiour oncoid I lou r a·.:··. . · Stage 3-Depositional (if) ~r""" ""m'" ~,.~.~.~:. &\ ~0~'f(j;) Stage 5-D iagenet ic: cementation Stage 6- Diagenetic: dissolution Reservoir Stage 7 -Diagenet ic : cementation Stage 8-Diagenetic : compaction Non-Reservoi r rim spo il ing pressure solution Stage 9 - Diagenet i c: dissolution Stage 10 -Di agenet ic: cementat ion euhedrol rhomb fracture ~g;~~~~~~r;ee;:nlargement Fig. 4. Depositional-diagenetic sequence thi n rim 337 338 A. V. Carozzi et al. High Intertidal Environment. Stage 3 (Figs. 4 and SA - C): depositional, re- moval and reorganization of interstitial constituents into an internal sediment with geopetal features and horizontal surfaces. Energy high, predominant downward circulation of seawater, probably adjacent to a beachrock. Beachrock Environment. Stage 4 (Figs. 4 and SD): diagenetic, lithification of in- ternal sediment by interparticle sparite cement followed by solution which generated secondary vuggy to channel porosity cutting across pisooncoids and internal sediment. Stage S (Figs. 4 and SE): diagenetic, precipitation of rim cement of bladed calcite (high magnesium and/ or aragonite?) along boundaries of all previously generated open spaces. If preserved after burial, this stage is a reservoir. Beachrock Vadose Environment. Stage 6 (Figs. 4 and SF - H): diagenetic, its re- sults whenever preserved after burial correspond to the best reservoir rocks. Intense vadose dissolution after exposure of beachrock to subaerial conditions but without generation of a freshwater lens: removal of large amounts of bladed rim cement, corrosion of margins of pisooncoids, deep etching of upper surface of cemented internal sediment and local differential solution of nuclei and concentric layers of pisoooncoids. These mesopores provide a measured porosity of 2S to 300;0 and 200 to 400 md permeability. Freshwater Meteoric Phreatic Environment. Stage 7 (Figs. 4 and 6A, B): diagene- tic, with cementation in a freshwater lens generated upon extensive subaerial exposure. Reservoirs formed during the previous beachrock stage, including any enhancement by subsequent meteoric vadose conditions were occluded by calcite precipitation when transferred by subsidence into the meteoric phreatic zone prior to permanent burial. The phreatic calcite cement occurs as single crystals and coarse crystalline irregular to highly interlocked equant mosaic. Frequent oc- currence of intense and distorted twinning indicates that cementation preceded major compaction. Burial Environment. Stage 8 (Figs. 4 and 6C - E): compaction with grain break- age by radial microfractures, reciprocal grain interpenetration by pressure solution and stylolitization, spalling of bladed rim cement with penetration in pisooncoids, pisooncoid spalling, non-fabric selective fracturation at least in two gener- Fig. 5 A-H. Submarine to beachrock vadose diagenesis. Plane polarized pictures of thin sections impregnated with blue plastic, porosity appears in various shades of gray. A Submarine isopachous rim cement of fibrous calcite with traces of dissolution (arrow) and surrounding graded internal sediment. B Isopachous rim of fibrous calcite cement overlain by graded internal sediment with geopetal attitude. Note vadose dissolution effects preceding phreatic sparite cementation. C Horizontal surface of geopetal internal sediment. D Vuggy to channel secondary porosity cutting across pisooncoid (right side) and internal sediment. Pores rimmed by bladed calcite cement (arrow). E Rim cement of bladed calcite (upper right), elsewhere same calcite is cavity-filling. F Relic of bladed calcite rim cement on pisooncoid surface (arrow) from vadose dissolution before phreatic sparite cementation. G Reservoir rock showing vadose dissolution effects on bladed calcite rim cement (arrow). H Reservoir rock showing vadose dissolution of bladed calcite rim cement and of cortical layers of pisooncoid Depositional Environment, Diagenesis and Reservoir Properties of Oncolitic Packstones 339 340 A. V. Carozzi et al. Depositional Environment, Diagenesis and Reservoir Properties of Oncolitic Packstones 341 +6 3 2 • 11 -16 -14 -12 + ; / ) water 5 6 ,,-whole rock l iCr;taceous1 +'2 :marine Ims. : " _/ __ ..... '" ~I Holocene pelagic Ims. 1 1 I 1 1 ' .. _ .... / -6' - - -8 -10 Holocene shallow limestones .......... ) 8,7 ..~. ~4- • - -.12 +2 +4 +10 1 ,- - I 1 - - - - I - JIIr- - ,.... I I :-Cretaceous freshwater limestones 1 1 1 " -2 ..... _ ........ : ........ 1 1 I 1 I A cement ' ..... :.~ .... "J '3 • \ . \ , " '.. / -10 II I I -12 I I .. 1 freshwater limestones I I '.. """ -14 ................ • 12 Solenhofen Limestone \ -8 "10 Standard "- ~\ Holocene - - - - - -, - - --- \ -, -6 • 9 Samples 2,3,4,5,7,8,11 Rim cement or whole rock 6 Pisooncoids 9,10,12,13 Cavity filling cement or whole rock -_-.16 I .."./ I / -18 -20 References ~ Milliman, 1974; James and Ginsburg, 1979. - Keith and Weber, 1964. A Prezbindowski, 1977. Fig. 7. Stable isotope measurements .. Fig. 6A - H. Meteoric phreatic to burial diagenesis. Plane polarized pictures of thin sections impregnated with blue plastic, porosity appears in various shades of gray. A Reservoir occlusion by phreatic coarsely crystalline equant mosaic of calcite. Earlier rim cement still visible. B Almost complete occlusion of pores by single crystal of calcite overgrowth on echinoid spine. Earlier bladed rim cement still visible. C Compaction effects: spalling of bladed calcite rim cement, grain breakage by microfractures, bladed rim cement penetrating pisooncoid margin (arrow). D Compaction effects: deformed pisooncoids, reciprocally penetrating pisooncoids and stylolitized contacts. E Compaction effects: first generation fracture cemented and second generation fracture (trending vertical) displacing the first and open. F Late dissolution pore (arrow) by differential solution of concentric layers of pisooncoid and showing thin rim of late calcite cement. G Thin rim of late calcite cement filling fractures of pisooncoid deformed by compaction. H Late cement as perfect rhombohedral crystals with oil staining growing on relics of earlier bladed calcite rim cement 342 A. V. Carozzi et al. ations. Early fractures cemented, other enlarged by late dissolution. In general, pores generated during compaction remain uncemented or show a very thin rim of late calcite cement. Stage 9 (Figs. 4 and 6F): late dissolution with enlargement of all previous compaction features and generation of intraparticle porosity by differential solution of some concentric layers of pisooncoids. Stage 10 (Figs. 4 and 6F - H): late cementation is widespread but not an important porosity reducer. It occurs as a thin rim of calcite crystals and as perfect rhombohedral crystals with frequent growth lines and inclusions (oil?). This cement may be coeval with oil migration. Other minor aspects of burial diagenesis are: aggrading neomorphism appearing as relatively large cloudy calcite crystals with diffused boundaries and abundant inclusions of unreplaced material; rare dolomite rhombs replacing matrix and cement; extremely rare silicification as overgrowth on detrital quartz grains and post-dating dolomitization; anhydritization selectively replacing pisooncoid layers and sparite cement. 8 Geochemistry of Diagenesis The beachrock rim cement of bladed calcite and the pisooncoids gave values of 8C13 and 80 18 typical of marine cements, while the cavity-filling sparite cement gave very light values of 8C13 corresponding to freshwater phreatic conditions (Fig. 7). The latter are further confirmed by a lack of cathode luminescence indicating an iron-rich, manganese-poor calcite (Meyers 1978). 9 Summary of Events and Oil Migration The growth fault activity was responsible for the successive phases of vertical evolution displayed by the oncolitic shoals, the most evident being in the eastcentral part of the basin where the change of offshore shoals from microoncolitic to pisooncolitic coincided with a general high of the structural map on top of the Lower Macae Formation. The same synsedimentary tectonic activity which localized the shoals also uplifted them into beachrock conditions, and higher into islands with extensive subaerial exposure and freshwater lenses. Subsidence of beachrocks preserved their reservoirs because no freshwater lenses had been related to them, whereas islands had their reservoirs occluded when subsidence transferred them through the phreatic environment. Reactivation of growth faults provided the necessary physical connection for the lateral migration of oil between source-beds (radioactive shale, Carapebus Member, Campos Formation) and the underlying oncolitic reservoirs. Acknowledgements. The authors are very grateful to the Board of Directors of Petroleo Brasileiro S. A. Petro bras for permission to publish this paper. Depositional Environment, Diagenesis and Reservoir Properties of Oncolitic Packstones 343 References Bebout DG, Schatzinger RA, Loucks RG (1977) Porosity distribution in the Stuart City Trend, Lower Cretaceous, South Texas. In: Bebout DG, Loucks RG (eds) Cretaceous carbonates of Texas and Mexico. Bur Econ Geol Univ Texas Rep Inv 89:234 - 256 Becher JW, Moore CH (1979) The Walker Creek field: A Smackover diagenetic trap. In: Moore CH (ed) Geology of carbonate porosity. 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