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Potenciales normales de reducción

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Instituto Tecnológico de Buenos Aires
Página 1
Potenciales Normales de Reducción ( E  ) relativos al Electrodo Normal de Hidrógeno
a 25 C
 = Solución saturada en presencia de una sustancia sólida o líquida.
 = Solución saturada con gas a una presión de 1 atm.
Símbolo del
Grado mas alto de
+ n eGrado mas bajo de
E  en Volts
Elemento
oxidación
oxidación
Ag2 +
+ eAg +
+2.00
+
Ag
+e
+0.7994
Ag 
+e
+0.071
AgBr 
Ag  + Br
+e
+0.55
AgBrO3 
Ag  + BrO3
+
e
+0.64
AgC2H3O2 
Ag  + C2H3O2
+e
-0.04
AgCN 
Ag  + CN
Ag(CN)2
+e
-0.29
Ag  + 2CN
2Ag(CN)3
+e
-0.51
Ag  + 3CN
+e
+0.41
AgCNO 
Ag  + CNO
2
+2 e
+0.46
Ag2CO3 
2 Ag  + CO3
2
+2 e
+0.472
Ag2C2O4 
2 Ag  + C2O4
+e
+0.224
AgCl 
Ag  + Cl
2
+2 e
+0.447
Ag2CrO4 
2 Ag  + CrO4
4
+4 e
+0.194
Ag4Fe(CN)6 
4 Ag  + Fe(CN)6
+
e
-0.152
AgI 
Ag  + I
+e
+0.35
Ag
AgIO3 
Ag  + IO3
2
+2 e
+0.49
Ag2MoO4 
2 Ag  + MoO4
+
Ag(NH3)2
+e
+0.373
Ag  + 2 NH3
+e
+0.59
AgNO2 
Ag  + NO2
+e
+0.293
AgN3 
Ag  + N3
+2 e
+0.6
2 AgO  + H2O
Ag2O  + 2 OH
+
+
2+
AgO + 2H
+e
Ag + H2O
+2.1
+2
e
+0.344
Ag2O  + H2O
2 Ag  + 2 OH
+2
e
+0.74
Ag2O3  + H2O
2 AgO  + 2 OH 2+2 e
-0.71
Ag2S 
2 Ag  + S
+e
+0.09
AgSCN 
Ag  + SCN
32
Ag(SO3)2
+e
+0.43
Ag  + 2 SO3
32
Ag(S2O3)2
+e
+0.01
Ag  2 S2O3
2+2 e
+0.653
Ag2SO4 
Ag  SO4
2+2 e
+0.53
Ag2WO4 
2 Ag  WO4
3+
Al
+3 e
-1.66
Al 
AlO2 + 2 H2O
+3 e
-2.35
Al  + 4 OH
+3 e
.-2.31
Al
Al (OH)3 
Al  + 3 OH
3Al F6
+3 e
-2.07
Al  + 6 F
+
+3 e
-0.50
As  + 3 H
AsH3 
+3 e
-1.37
As  + 3 H2O
AsH3  + 3 OH
+
HAsO2 + 3 H
+3 e
+0.247
As
As  + 2 H2O
+
H3AsO4 + 2 H
+2 e
HAsO2 + 2 H2O
+0.581
AsO2 + 2 H2O
+3 e
-0.68
As  + 4 OH
AsO43- + 2 H2O
+2 eAsO2- + 4 OH -0.71
Página 2
Símbolo del
Elemento
Au
B
Ba
Be
Bi
Br
Grado mas alto de
oxidación
3+
Au
Au3 +
Au+
AuBr2AuBr4AuBr4Au(CN)2AuCl2AuCl4AuCl4H2AuO3- + H2O
Au(SCN)2Au(SCN)4Au(SCN)4H3BO3 + 3 H +
H2BO3- + H2O
BF4Ba2 +
Be2 +
Be2O32 - + 3 H2O
BiO+ + 2 H +
Bi  + 3 H +
NaBiO3  + 4 H+
BiCl4Bi2O4  + 4 H+
Bi2O4  + H2O
Bi2O3  + 3 H2O
BiOCl  + 2H+
Br2
Br32 HBrO + 2 H +
2 BrO - + 2 H2O
HBrO + H+
BrO - + H2O
BrO3- + 5 H +
BrO3- + 2 H2O
2 BrO3- + 12 H +
2 BrO3- + 6H2O
BrO3-+ 6 H+
BrO3- + 3 H2O
+ n e+2 e+3 e+ e+ e+2 e+3 e+ e+ e+2 e+3 e+3 e+ e+2 e+3 e+3 e+3 e+3 e+2 e+2 e+4 e+3 e+3 e+2 e+3 e+2 e+2 e+6 e+3 e+2 e+2 e+2 e+2 e+2 e+2 e+4 e+4 e+10 e+10 e+6 e+6 e-
Grado mas bajo de
oxidación
+
Au
Au 
Au 
Au  + 2 Br AuBr2- + 2 Br Au  + 4 Br Au  + 2 CN Au  + 2 Cl AuCl2- + 2 Cl Au  + 4 Cl Au  + 4 OH Au  + 2 SCN Au(SCN)2- + 2 SCN Au  + 4 SCN B  + 3 H2O
B  + 4 OH B  + 4 FBa 
Be 
2Be  + 6 OH Bi  + H2O
BiH3 
BiO+ + Na+ + 2 H2O
Bi  + 4 Cl 2 BiO+ + 2 H2O
Bi2O3  + 2 OH 2 Bi  + 6 OH Bi  + H2O + Cl 2 Br 3 Br Br2 + 2 H2O
Br2 + 4 OH Br - + H2O
Br - + 2 OH HBrO + 2 H2O
BrO - + 4 OH Br2 + 6 H2O
Br2 + 12 OH Br - + 3 H2O
Br - + 6 OH -
E  en Volts
+1.41
+1.50
+1.68
+0.96
+0.82
+0.87
-0.61
+1.11
+0.93
+0.99
+0.7
+0.69
+0.64
+0.66
-0.87
-1.79
-1.04
-2.90
-1.85
-2.62
+0.32
< -0.8
> +1.8
+0.16
+1.59
+0.56
-0.46
+0.16
+1.087
+1.05
+1.6
+0.45
+1.34
+0.76
+1.45
+0.54
+1.52
+0.50
+1.45
+0.51
Instituto Tecnológico de Buenos Aires
Símbolo del
Elemento
C
Ca
Cd
Ce
Cl
Grado mas alto de
oxidación
CH3OH + 2 H +
C2H6OH + 2 H +
C6H4O2 + 2 H+
(CN)2 + 2 H+
2HCNO + 2 H+
HCNO + 2 H+
CNO - + H2O
HCHO + 2 H+
CH3CHO + 2 H+
HCOOH + 2 H+
CH3COOH + 2 H+
HCOO - + 2 H2O
CO2 + 2 H+
CO2 + N2 + 6 H+
CO2 + 2 H+
2CO2 + 2 H+
Ca2+
Ca(OH)2 
Cd2+
CdCO3 
Cd(CN)42Cd(NH3)42+
Cd(OH)2 
CdS
Ce 3+
Ce(ClO4)62 Ce(NO3)62 Ce(SO4)32 Cl2
2 HClO + 2 H+
2 ClO - + 2 H2O
HClO + H+
ClO - + H2O
HClO2 + 2 H+
2HClO2 + 6 H+
HClO2 + 3 H+
ClO2- + H2O
ClO2- + 2 H2O
ClO3- + 3 H+
ClO3- + H2O
ClO3- + 2 H+
ClO2  + H+
ClO3- + 6 H+
+ n e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+6 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+3 e+ e+ e+ e+2 e+2 e+2 e+2 e+2 e+2 e+6 e+4 e+2 e+4 e+2 e+2 e+ e+ e+6 e-
Grado mas bajo de
oxidación
CH4 + H2O
C2H7 + H2O
C6H4(OH)2
2 HCN
2 H2O + (CN)2
HCN + H2O
CN - + 2 OH CH3OH
C2H5OH
HCHO + H2O
CH3CHO + H2O
HCHO + 3 OH CO + H2O
CO(NH2)2 + H2O (urea)
HCOOH
H2C2O4
Ca 
Ca  + 2 OH Cd 
Cd  + CO32Cd  + 4CNCd  + 4NH3
Cd  + 2OHCd  + S2Ce 
Ce 3+ + 6ClO4Ce 3+ + 6NO3 Ce 3+ + 3SO42 2Cl Cl2 + 2 H2O
Cl2 + 4 OH Cl - + H2O
Cl - + 2 OH HClO + H2O
Cl2 + 4 H2O
Cl - + 2 H2O
ClO - + 2 OH Cl - + 4 OH HClO2 + H2O
ClO2- + 2 OH ClO2  + H2O
HClO2
Cl - + 3 H2O
Página 3
E  en Volts
+0.59
+0.46
+0.6994
+0.37
+0.33
+0.35
-0.97
+0.19
+0.19
-0.01
-0.12
-1.07
-0.12
+0.1
-0.20
-0.49
-2.87
-3.03
-0.402
-0.74
-1.09
-0.61
-0.81
-1.17
-2.33
+1.70
+1.60
+1.44
+1.359
+1.63
+0.40
+1.50
+0.88
+1.61
+1.63
+1.56
+0.66
+0.77
+1.21
+0.33
+1.15
+1.27
+1.45
Página 4
Símbolo del
Elemento
Cl
Co
Cr
Cs
Cu
Grado mas alto de
oxidación
2 ClO3- + 12 H+
ClO3- + 3 H2O
ClO2  + 4 H+
ClO2  + 2 H2O
ClO4- + 2 H+
ClO4- + H2O
2ClO4- + 16 H+
ClO4- + 8H+
ClO4- + 4H2O
Co 3+
Co 3+
Co 2+
CoCO3 
Co(NH3)63+
Co(NH3)62+
Co(OH)2 
Co(OH)3 
CoS  
CoS  
Cr 3+
Cr 3+
Cr 2+
Cr(OH)3 
Cr(OH)2 
CrO2- + 2H2O
Cr2O72 - + 14 H+
CrO42 - + 4 H2O
Cs +
Cu 2+
Cu +
Cu 2+
Cu 2+ + Br Cu 2+ + Cl Cu 2+ + I CuBr 
Cu(CN)2 CuCl 
CuI 
Cu(NH3)4 2+
Cu(NH3)2 +
Cu(NH3)4 2+
2 Cu(OH)2 
+ n e+10 e+6 e+5 e+5 e+2 e+2 e+14 e+8 e+8 e+ e+3 e+2 e+2 e+ e+2 e+2 e+ e+2 e+2 e+ e+3 e+2 e+3 e+2 e+3 e+6 e+3 e+ e+2 e+ e+ e+2 e+ e+ e+ e+ e+ e+ e+ e+ e+2 e+2 e-
Grado mas bajo de
oxidación
Cl2  + 6 H2O
Cl - + 6 OH Cl - + 2 H2O
Cl - + 4 OH ClO3- + H2O
ClO3- + 2 OH Cl2  + 8 H2O
Cl - + 4H2O
Cl - + 8OHCo 2+
Co 
Co 
Co  + CO32Co(NH3)62+
Co  + 6NH3
Co + 2OH Co(OH)2  + OH Co  + S 2Co  + S 2Cr 2+
Cr 
Cr 
Cr  + 3 OH Cr  + 2 OH Cr  + 4 OH 2 Cr 3 + + 7 H2O
Cr(OH)3  + 5 OH Cs 
Cu 
Cu 
Cu +
CuBr 
CuCl 
CuI 
Cu + Br Cu  + 2CN Cu  + Cl Cu  + I Cu(NH3)2 + + 2 NH3
Cu  + 2 NH3
Cu  + 4NH3
Cu2O  + 2OH- + H2O
E  en Volts
+1.47
+0.63
+1.50
+0.85
+1.19
+0.36
+1.39
+1.38
+0.56
+1.84
+0.33
-0.28
-0.64
+0.1
-0.42
-0.73
+0.17
-0.88
-1.01
-0.41
-0.74
-0.91
-1.3
-1.4
-1.2
+1.33
-0.13
-2.914
+0.337
+0.521
+0.153
+0.64
+0.54
+0.86
+0.033
-0.43
+0.137
-0.185
-0.01
-0.12
-0.07
-0.08
Instituto Tecnológico de Buenos Aires
Símbolo del
Elemento
Cu
F
Fe
Ga
Ge
H
Hf
Hg
Grado mas alto de
oxidación
Cu2O  + H2O
Cu(OH)2 
CuS 
Cu2S 
CuSCN 
F2 
Fe 3 +
Fe 3 +
Fe 2 +
Fe(CN)6 3 FeCO3 
Fe(C12H8N2)3 3 +
Fe(OH)3 
Fe(OH)2 
FeO42 - + 8 H+
Fe3O4  + 8 H+
FeS 
Ga 3 +
H2GaO3- + H2O
Ge  + 4H +
Ge 2 +
GeO  + 2H +
GeO2  + 4H +
H2GeO3 + 4H +
GeO2  + 2H +
H2GeO3 - + 2H2O
2H +
2H2O ([H+] =10-7M)
H2 
2H2O
H2O2 + 2H +
HO2- + H2O
HfO2 + + 2H +
HfO2  + 4H +
HfO(OH)2  + H2O
2 Hg +2
Hg +2
Hg2+2
Hg2Br2 
Hg(CN)42 Hg2(CH3COO)2 
Hg2C2O4 
+ n e+2 e+2 e+2 e+2 e+ e+ 2 e+ e+3 e+2 e+ e+2 e+ e+ e+2 e+3 e+8 e+2 e+3 e+3 e+4 e+2 e+2 e+4 e+4 e+2 e+4 e+2 e+2 e+2 e+2 e+2 e+2 e+4 e+4 e+4 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e-
Grado mas bajo de
oxidación
2Cu  + 2OH Cu  + 2OH Cu  + S 2 2Cu  + S 2 Cu  + SCN 2F Fe 2 +
Fe 
Fe 
Fe(CN)6 4 Fe  + CO32 Fe(C12H8N2)3 2 +
Fe(OH)2  + OH Fe  + 2OH Fe 3 + + 4 H2O
3Fe + 4 H2O
Fe  + S 2 Ga 
Ga  + 4OH GeH4 
Ge 
Ge  + H2O
Ge  + 2H2O
Ge  + 3H2O
GeO (marrón) + H2O
Ge  + 5OH H2 
H2  + 2OH2H H2  + 2OH 2H2O
3OH Hf  + H2O
Hf  + 2H2O
Hf  + 4OH Hg2+2
Hg 
2 Hg 
2 Hg  + 2 Br Hg  + 4 CN 2 Hg  + 2 CH3COO 2 Hg  + C2O42 -
Página 5
E  en Volts
-0.36
-0.22
-0.70
-0.88
-0.27
+2.87
+0.771
-0.036
-0.440
+0.356
-0.756
+1.06
-0.56
-0.877
> +1.9
-0.085
-0.95
-0.56
-1.22
< -0.3
0.0
-0.29
-0.15
-0.13
-0.12
-1.0
 0.0000
-0.414
-2.25
-0.828
+1.77
+0.88
-1.70
-1.57
-2.5
+0.907
+0.850
+0.792
+0.1392
-0.37
+0.540
+0.415
Página 6
Hg2Cl2 
Símbolo del
Elemento
Hg
I
In
Ir
K
Grado mas alto de
oxidación
Hg2I2 
Hg2(IO3)2 
HgO  (rojo) + H2O
HgS  (negro)
HgS  (rojo)
Hg2SO4 
I2 
I2
I32 IBr
2 IBr2ICN
2 ICN + 2H+
2 ICl
2 ICl22ICl3
2 HIO + 2H+
2 IO - + 2 H2O
HIO + H+
IO - + H2O
IO3 - + 5 H+
IO3 - + 2 H2O
2 IO3 - + 12 H+
2 IO3 - + 6 H2O
IO3 - + 6 H+
IO3 - + 3 H2O
H5IO6 + H+
H3IO62 H5IO6 + 7 H+
H3IO62 - + 3 H2O
In3+
In3+
In(OH)3 
Ir3+
IrCl63 IrCl62 IrCl62 IrO2  + 4 H +
IrO2  + 2 H2O
Ir2O3  + 3 H2O
K+
+2 e+ n e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+6 e+2 e+2 e+2 e+2 e+4 e+4 e+10 e+10 e+6 e+6 e+2 e+2 e+8 e+8 e+3 e+2 e+3 e+3 e+3 e+ e+4 e+4 e+4 e+6 e+ e-
2 Hg  + 2 Cl Grado mas bajo de
oxidación
2 Hg  + 2 I 2 Hg  + 2 IO3 Hg  + 2 OH Hg  + S 2 Hg  + S 2 2 Hg  + SO42 2I2I3II2  + 2 Br I2  + 4 Br I - + CN I2  + 2 HCN
I2  + 2 Cl I2  + 4 Cl I2  + 6 Cl I2  + 2 H2O
I2  + 4 OH I - + H2O
I - + 2 OH HIO + 2 H2O
IO - + 4 OH I2  + 6 H2O
I2  + 12 OH I - + 3 H2O
I - + 6 OH IO3 - + 3 H2O
IO3 - + 3 OH I - + 6 H2O
I - + 9 OH In 
In+
In  + 3 OH Ir 
Ir  + 6 Cl IrCl63 Ir  + 6 Cl Ir  + 2 H2O
Ir  + 4 OH 2 Ir  + 6 OH K
+0.2680
E  en Volts
-0.040
+0.394
+0.098
-0.67
-0.70
+0.614
+0.536
+0.621
+0.545
+1.02
+0.87
+0.30
+0.63
+1.19
+1.06
+1.28
+1.45
+0.45
+0.99
+0.49
+1.14
+0.14
+1.19
+0.21
+1.08
+0.26
~ +1.6
~ +0.7
~ +1.24
~ +0.37
-0.33
-0.40
-1.0
~ +1.15
+0.77
+1.02
+0.83
+0.93
+0.1
+0.1
-2.925
Instituto Tecnológico de Buenos Aires
Símbolo del
Elemento
La
Li
Mg
Mn
Mo
N
Grado mas alto de
oxidación
3+
La
La(OH)3 
Li+
Mg2+
Mg(OH)2 
Mn3+
Mn2+
Mn(CN)63 MnCO3 
Mn(OH)2 
Mn(OH)3 
MnO2 + 4 H +
MnO42 - + 4 H +
MnO42 - + 2 H2O
MnO4 MnO4 - + 4 H +
MnO4 - + 2 H2O
MnO4 - + 8 H +
Mo3+
Mo(CN)83 MoO2+ + 4 H +
MoO22+
H2MoO4 + 6 H +
MoO42 - + 4 H2O
HN3 + 11 H+
N3 - + 7 H2O
3 N2  + 2 H +
3 N2 
N2  + 2 H2O + 4 H +
N2 + 4 H2O
N2  + 5 H +
N2 + 4 H2O
N2  + 8 H +
N2  + 8 H2O
(N2H4)H+ + 3 H+
N2H4 + 4 H2O
(NH2OH)H+ + 2 H+
NH2OH + 2 H2O
H2N2O2 + 2 H+
H2N2O2 + 6 H+
2 HNO2 + 4 H+
HNO2 + H+
+ n e+3 e+3 e+ e+2 e+2 e+ e+2 e+ e+2 e+2 e+ e+2 e+2 e+2 e+ e+3 e+3 e+5 e+3 e+ e+2 e+ e+6 e+6 e+8 e+6 e+2 e+2 e+2 e+2 e+4 e+4 e+6 e+6 e+2 e+2 e+2 e+2 e+2 e+4 e+4 e+ e-
Grado mas bajo de
oxidación
La 
La  + 3 OH Li 
Mg 
Mg  + 2 OH Mn2+
Mn 
Mn(CN)64 Mn  + CO32 Mn  + 2 OH Mn(OH)2  + OH Mn 2+ + 2 H2O
MnO2  + 2 H2O
MnO2  + 4 OH MnO42 MnO2 + 2 H2O
MnO2 + 4 OH Mn 2+ + 4 H2O
Mo 
Mo(CN)84 Mo3+ + 2 H2O
MoO2+
Mo  + 4 H2O
Mo  + 8 OH 3 NH4+
N2H4 + NH3 + 7 OH 2HN3
2 N3 2 (NH2OH )H+
2 NH2OH + 2 OH (N2H4)H+
N2H4 + 4 OH 2 NH4+
2 NH4OH + 6 OH 2 NH4+
2 NH4OH + 2 OH NH4+ + H2O
NH4OH + 2 OH N2  + 2 H2O
2 (NH2OH )H+
H2N2O2 + 2 H2O
NO  + H2O
Página 7
E  en Volts
-2.52
- 2.90
-3.03
-2.37
- 2.69
+1.51
-1.19
-0.244
-1.48
- 1.18
+0.1
+1.23
+2.26
+0.6
+0.56
+1.69
+0.60
+1.51
-0.2
+0.73
~ 0.0
+0.48
0.0
-1.05
+0.69
-0.6
-3.1
-3.4
-1.87
-3.04
-0.23
-1.16
+0.26
-0.74
+1.27
+0.1
+1.35
+0.42
+2.65
+0.50
+0.83
+0.99
Página 8
NO2 - + H2O
Símbolo del
Elemento
N
Na
Nb
Ni
Grado mas alto de
oxidación
2 HNO2 + 4 H+
2 HNO2 + 6 H+
2 NO2 - + 4 H2O
HNO2 + 7 H+
NO2 - + 6 H2O
N2O  + 2 H+
N2O  + H2O
2 NO  + 4 H+
2 NO  + 2 H2O
N2O4  + 2 H+
N2O4 
N2O4  + 8 H+
N2O4  + 4 H2O
NO3 - + 3 H+
NO3 - + H2O
NO3 - + 2 H+
NO3 - + H2O
NO3 - + 4 H+
NO3 - + 2 H2O
2 NO3 - + 12 H+
NO3 - + 8 H+
2 NO3 - + 17 H+
NO3 - + 10 H+
NO3 - + 7 H2O
Na+
Nb3+
Nb2O5  + 10 H+
NbO3+ + 2 H+
NbO(SO4)2 - + 2 H+
NbO(SO4)2 - + 2 H+
Ni2+
Ni(CN)42 NiCO3 
Ni(OH)2 
Ni(NH3)62 +
NiO2  + 4 H+
NiO2  + 2 H2O
NiO42 - + 8 H+
NiS  
NiS  
+ e-
+ n e+4 e+6 e+6 e+6 e+6 e+2 e+2 e+4 e+4 e+2 e+2 e+8 e+8 e+2 e+2 e+ e+ e+3 e+3 e+10 e+6 e+14 e+8 e+8 e+ e+3 e+10 e+2 e+2 e+5 e+2 e+ e+2 e+2 e+2 e+2 e+2 e+4 e+2 e+2 e-
NO  + 2 OH -
Grado mas bajo de
oxidación
N2O  + 3 H2O
N2  + 4 H2O
N2  + 8 OH NH4+ + 2 H2O
NH4OH + 7 OH N2  + H2O
N2  + 2 OH N2  + 2 H2O
N2  + 4 OH 2 HNO2
2 NO2N2  + 4 H2O
N2  + 8 OH HNO2 + H2O
NO2 - + 2 OH NO2  + H2O
NO2  + 2 OH NO  + 2 H2O
NO  + 4 OH N2  + 6 H2O
( NH2OH )H+ + 2 H2O
(N2H4)H+ + 6 H2O
NH4+ + 3 H2O
NH4OH + 9 OH Na 
Nb 
2 Nb  + 5 H2O
Nb3+ + H2O
Nb3+ + H2O + 2 SO42 Nb  + H2O + 2 SO42 Ni 
Ni(CN)32 - + CN Ni  + CO32 Ni  + 2 OH Ni  + 6 NH3
Ni2+ + 2 H2O
Ni(OH)2  + 2 OH Ni2+ + 4 H2O
Ni + S2 Ni  + S2 -
-0.45
E  en Volts
+1.29
+1.44
+0.41
+0.86
-0.15
+1.77
+0.94
+1.68
+0.85
+1.07
+0.88
+1.35
+0.53
+0.94
+0.04
+0.80
-0.86
+0.96
-0.14
+1.24
+0.73
+0.84
+0.87
-0.12
-2.713
-1.1
-0.65
-0.34
-0.1
-0.63
-0.23
< -0.4
-0.45
-0.72
-0.49
+1.68
+0.49
> +1.8
+0.76
-0.99
Instituto Tecnológico de Buenos Aires
Símbolo del
Elemento
O
Os
P
Pb
Grado mas alto de
oxidación
O2  + 4 H+
O2  + 4 H+ (10-7 M)
O2  + 2 H2O
O2  + 2 H+
O2  + H2O
H2O2 + 2 H+
HO2 - + H2O
O3  + 2 H+
O3  + H2O
Os2 +
OsCl62 OsCl63 OsCl63 OsO4 + 6 Cl - + 8 H+
OsO4  + 8 H+
HOsO5 - + 4 H2O
P  + 3 H+
P  + 3 H2O
H3PO2 + H+
H2PO2H3PO3 + 3 H+
H3PO3 + 2 H+
HPO3 2 - + 2 H2O
H4P2O6 + 2 H+
H3PO4 + 5 H+
H3PO4 + 4 H+
2 H3PO4 + 2 H+
H3PO4 + 2 H+
PO43 - + 2 H2O
Pb2 +
Pb4 +
Pb4 +
PbBr2 
PbCO3 
PbCl2 
PbF2 
PbI2 
PbO  + H2O
HPbO2 - + H2O
PbO2  + H2O
PbO2  + 4 H+
+ n e+4 e+4 e+4 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+ e+3 e+ e+4 e+8 e+8 e+3 e+3 e+ e+ e+3 e+2 e+2 e+2 e+5 e+4 e+2 e+2 e+2 e+2 e+2 e+4 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e-
Grado mas bajo de
oxidación
2 H2O
2 H2O
4 OH H2O2
HO2 - + OH 2 H2O
3 OH O2  + H2O
O2  + 2 OH Os 
OsCl63 Os  + 6 Cl Os2 + + 6 Cl OsCl62 - + 4 H2O
Os + 4 H2O
Os  + 9 OH PH3 
PH3  + 3 OH P  + 2 H2O
P  + 2 OH P  + 3 H2O
H3PO2 + H2O
H2PO2- + 3 OH 2 H3PO3
P  + 4 H2O
H3PO2 + 2 H2O
H4P2O6 + 2 H2O
H3PO3 + H2O
HPO3 2 - + 3 OH Pb 
Pb2 +
Pb 
Pb  + 2 Br Pb  + CO3 2 Pb  + 2 Cl Pb  + 2 F Pb  + 2 I Pb  + 2 OH Pb  + 3 OH PbO  + 2 OH Pb2 + + 2 H2O
Página 9
E  en Volts
+1.229
+0.815
+0.404
+0.682
-0.076
+1.77
+0.88
+2.07
+1.24
+0.85
+0.85
+0.71
+0.4
+1.0
+0.85
+0.02
+0.06
-0.89
-0.51
-2.05
-0.50
-0.50
-1.57
+0.38
-0.41
-0.39
-0.94
-0.276
-1.12
-0.126
+1.8
+0.84
-0.274
-0.506
-0.266
-0.350
-0.364
-0.58
-0.54
+0.28
+1.455
Página 10
PbO2  + 4 H++SO4 2 +2 e-
PbSO4  + 2 H2O
+1.68
PbO22 - + 2 OH -
+0.2
-
PbO32 -  + H2O
Símbolo del
Elemento
Pb
Pd
Pt
Po
Ra
Rb
Re
Rh
Grado mas alto de
oxidación
PbS 
PbSO4 
Pd 2+
PdCl42 PdCl62 PdCl62 Pd(OH)2 
Pd(OH)4 
Pt 2 +
PtCl42 PtCl62 Pt(OH)2 
Pt(OH)2  + 2 H+
Po 3+
Po4 +
PoO22 +
PoO22 + + 4 H+
Po(OH)3 
Po(OH)4 
Ra 2 +
Rb +
Re 
Re +
Re3 +
ReO2  + 4 H+
ReO3  + 2 H+
ReO4 - + 8 H+
ReO4 - + 4 H+
ReO4 - + 2 H+
ReO4 - + 4 H2O
ReO4 - + 2 H2O
Rh3 +
RhCl63 Rh2O3  + 6 H+
RhO2 + 4 H+ + 6 Cl RhO2 + + 2 H+
RhO4 2 - + 6 H+
Ru2 +
RuCl3
+2 e-
+ n e+2 e+2 e+2 e+2 e+2 e+4 e+2 e+2 e+2 e+2 e+2 e+2 e+2 e+3 e+ e+ e+2 e+3 e+ e+2 e+ e+ e+2 e+3 e+4 e+2 e+7 e+3 e+ e+7 e+3 e+3 e+3 e+6 e+ e+ e+2 e+2 e+3 e-
Grado mas bajo de
oxidación
Pb  + S2 Pb  + SO42 Pd 
Pd  + 4 Cl PdCl42 - + 2 Cl Pd  + 6 Cl Pd  + 2 OH Pd(OH)2  + 2 OH Pt 
Pt  + 4 Cl PtCl42 - + 2 Cl Pt  + 2 OH Pt  + 2 H2O
Po 
Po 3+
PoO2 +
Po4 + + 2 H2O
Po  + 3 OH Po(OH)3  + OH Ra 
Rb 
Re Re Re 
Re  + 2 H2O
ReO2  + H2O
Re  + 4 H2O
ReO2  + 2 H2O
ReO3  + H2O
Re  + 8 OH ReO2  + 4 OH Rh 
Rh  + 6 Cl 2 Rh  + 3 H2O
RhCl63 - + 2 H2O
Rh3 + + H2O
RhO2 + + 3 H2O
Ru 
Ru  + 3 Cl -
E  en Volts
-0.91
-0.356
+0.987
+0.623
+1.29
+0.96
+0.07
~ +0.73
~ +1.2
+0.73
+0.720
+0.15
+0.98
-2.03
+0.970
+0.916
+1.04
-2.42
-0.95
-2.92
-2.93
-0.4
-0.23
~ +0.3
+0.26
+0.4
+0.37
+0.51
+0.77
-0.584
-0.595
~ +0.8
+0.44
+0.87
> +1.4
+1.40
+1.46
+0.45
+0.68
Página 11
Instituto Tecnológico de Buenos Aires
Ru
Símbolo del
Elemento
S
Sb
Sc
Se
Si
RuCl5 RuCl5OH 2 - + H+
RuO4 RuO4 
Grado mas alto de
oxidación
S
S  + 2 H+
5 S
(SCN)2 
S4O62 S2O32 - + 6 H+
2 H2SO3 + 2 H+
2 SO32 - + 3 H2O
2 H2SO3 + H+
2 SO32 - + 2 H2O
SO42 - + 4 H+
SO42 - + H2O
2 SO42 - + 10 H+
2 SO42 - + 5 H2O
SO42 - + 8 H+
SO42 - + 4 H2O
H2SO3 + 4H+
SO42 - + 10 H+
SO42 - + 4 H2O
S2O82 Sb  + 3 H+
SbO + + 2 H+
Sb2O3  + 6 H+
SbO2 - + 2 H2O
Sb2O4  + 4 H+
Sb2O5  + 4 H+
Sb2O5  + 6 H+
SbO3 - + H2O
Sc 3 +
Se  + 2 H+
H2SeO3 + 4 H+
SeO32 - + 3 H2O
SeO42 - + 4 H+
SeO42 - + H2O
Si  + 4 H+
Si  + 4 H2O
SiF62 SiO2  + 4 H+
H2SiO3 + 4 H+
+2 e+ e+ e+ e+ n e+2 e+2 e+2 e+2 e+2 e+4 e+4 e+4 e+2 e+2 e+2 e+2 e+8 e+8 e+6 e+6 e+4 e+8 e+8 e+2 e+3 e+3 e+6 e+3 e+2 e+4 e+4 e+2 e+3 e+2 e+4 e+4 e+2 e+2 e+4 e+4 e+4 e+4 e+4 e-
Ru2 + + 5 Cl RuCl52 - + H2O
RuO4 2 RuO4 Grado mas bajo de
oxidación
S2H2S 
S52 2 SCN 2 S2O32 2 S  + 3 H2 O
S2O32 - + 3 H2O
S2O32 - + 6 OH H S2O4 - + 2 H2O
S2O42 - + 4 OH H2SO3 + H2O
SO32 - + 2 OH S2O32 - + 5 H2O
S2O32 - + 10 OH S  + 4 H2O
S  + 8 OH S  + 3H2O
H2S  + 4 H2O
S2 - + 8 OH 2 SO42 SbH3
Sb  + H2O
2 Sb  + 3 H2O
Sb  + 4 OH 2 SbO + + 2 H2O
Sb2O3  + 2 H2O
2 SbO + + 3 H2O
SbO2 - + 2 OH Sc 
H2Se 
Se  + 3 H2O
Se  + 6 OH H2SeO3 + H2O
SeO32 - + 2 OH SiH4 
SiH4  + 4 OH Si  + 6 F Si  + 2 H2O
Si  + 3 H2O
+0.3
+1.3
+0.59
+1.00
E  en Volts
-0.48
+0.14
-0.34
+0.77
+0.09
+0.5
+0.40
-0.58
-0.08
-1.12
+0.17
-0.93
+0.29
-0.76
+0.36
-0.75
0.46
+0.31
-0.68
+2.0
-0.51
+0.212
+0.152
-0.675
+0.68
+0.69
+0.58
-0.43
-2.08
+0.40
+0.74
-0.366
+1.15
+0.05
+0.10
-0.73
-1.2
-0.86
-0.79
Página 12
SiO32 - + 3 H2O
Símbolo del
Elemento
Sn
Sr
Ta
Te
Th
Ti
Tl
U
Grado mas alto de
oxidación
2+
Sn
Sn4 +
Sn4 +
HSnO2 - + H2O
Sn(OH)62 Sr2 +
Ta2O5  + 10 H+
Te  + 2 H+
Te 
TeO2  + 4 H+
TeO2H + + 3 H+
TeO32 - + 3 H2O
H6TeO6 + 2 H+
TeO42 - + H2O
Th4 +
Th(OH)4 
Ti2 +
TiO2  + 4 H+
TiO2 + + 2 H+
TiO2 + + 2 H+
Ti3 +
TiF62 Tl+
TlBr 
TlCl 
TlOH
Tl 3 +
Tl2O3  + 3 H2O
U 3+
U 4+
U(OH)3 
UO2  + 2 H2O
UO2+ + 4 H +
UO22 +
UO22 + + 4 H +
V 2+
V 3+
+4 e-
+ n e+2 e+2 e+4 e+2 e+2 e+2 e+10 e+2 e+2 e+4 e+4 e+4 e+2 e+2 e+4 e+4 e+2 e+4 e+4 e+ e+ e+4 e+ e+ e+ e+e+2 e+4 e+3 e+ e+3 e+4 e+ e+2 e+2 e+2 e+ e-
Si  + 6 OH -
-1.7
Grado mas bajo de
E  en Volts
oxidación
-0.140
Sn 
2+
Sn
+0.15
+0.01
Sn 
-0.91
Sn  + 3 OH
HSnO2 + 3 OH + H2O
-0.93
-2.89
Sr 
-0.81
2 Ta  + 5 H2O
-0.72
H2Te 
2Te
-1.14
+0.53
Te  + 2 H2O
+0.56
Te  + 2 H2O
-0.57
Te  + 6 OH
+1.02
TeO2  + 4 H2O
2TeO3 + 2 OH
> +0.4
-1.90
Th 
-2.48
Th  + 4 OH
-1.63
Ti 
-0.86
Ti  + 2 H2O
~ -0.88
Ti  + H2O
3+
Ti + H2O
~ +0.1
2+
Ti
-0.37
-1.19
Ti  + 6 F
-0.336
Tl 
-0.656
Tl  + Br
-0.557
Tl  + Cl
-0.344
Tl  + OH
+
Tl
+1.28
+
2 Tl + 6 OH
+0.02
-1.8
U
3+
U
-0.64
-2.17
U  + 3 OH
-2.39
U + 4 OH
4+
U + 2 H2 O
+0.55
+0.45
UO2 
4+
U + 2 H2 O
+0.33
+1.18
V
V 2+
+0.255
Instituto Tecnológico de Buenos Aires
V
Símbolo del
Elemento
W
Y
Zn
Zr
VO 2 + + 2 H+
VO 2 +
VO2+ + 2 H+
VO2+ + 4 H+
VO2+ + 4 H+
Grado mas alto de
oxidación
+
VO2 + 4 H+
VO43 - + 6 H+
H2VO4 - + 4 H+
WO2  + 4 H+
W(CN)83 W2O5  + 2 H+
WO3  + 6 H+
2 WO3  + 2 H+
WO42 - + 8 H+
WO42 - + 4 H2O
Y 3+
Zn2+
Zn(CN)42 Zn(NH3)42 +
Zn(OH)2 
ZnO22 - + 2 H2O
ZnS 
ZrO2 + + 2 H+
ZrO2  + 4 H+
H2ZrO3  + H2O
+ e+ e+ e+2 e+3 e-
+ n e+5 e+2 e+ e+4 e+ e+2 e+6 e+2 e+6 e+6 e+3 e+2 e+2 e+2 e+2 e+2 e+2 e+4 e+4 e+4 e-
V 3 + + H2O
VO +
VO 2 + + H2O
V 3 + + 2 H2 O
V 2 + + 2 H2 O
Grado mas bajo de
oxidación
V  + 2 H2 O
VO + + 3 H2O
VO 2 + + 3 H2O
W  + 2 H2 O
W(CN)84 2 WO2  + H2O
W  + 3 H2 O
W2O5  + H2O
W  + 4 H2 O
W  + 8 OH Y
Zn 
Zn  + 4 CN Zn  + 4 NH3
Zn  + 2 OH Zn  + 4 OH Zn  + S 2 Zr  + H2O
Zr  + 2 H2O
Zr  + 4 OH -
Página 13
+0.337
+0.044
+0.9994
+0.668
+0.360
E  en Volts
+0.25
+1.26
+1.31
-0.12
+0.457
-0.04
-0.09
-0.03
+0.05
-1.05
-2.37
-0.7628
-1.26
-1.04
-1.245
-1.216
-1.40
-1.57
-1.43
-2.36
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