ENTEK® CU-56 Tarnish and corrosion inhibitor for copper and brass Entek® CU-56 is a liquid material added to rinse water to prevent tarnishing, staining, green salt formation, pit corrosion, finger marking and spotting-out of copper and brass. Prior to using this product, refer to "OPERATING CONDITIONS", "CONTROL", and "PRECAUTIONARY INFORMATION" sections for proper handling and usage procedures. READ ENTIRE TECHNICAL DATA SHEET BEFORE USING THIS PRODUCT. Entek CU-56 replaces water-dip lacquers and requires no additional processing steps. Alkaline cleaning (soak or electrolytic) removes the Entek CU-56 coating prior to subsequent plating processing. It is rapid and the coating does not interfere with painting or soldering. The presence of the coating improves the adhesion of lacquers and enamels and improves solderability. NOTE: Some clear epoxies may be darkened by the Entek CU-56 film. Entek CU-56 is ideal for use in the final rinse tank following copper or brass plating because it will preserve the freshly-plated appearance for weeks even under high humidity storage conditions. On mill products, Entek CU-56 solutions may be used to treat copper and brass strip prior to coiling to prevent corrosion in storage due to moisture trapped in the tightly wound coils. The coating produced by Entek CU-56 is completely invisible and has many times the corrosion resistance of bare copper and brass. It will withstand 200 hours exposure to tropical humidity conditions without discoloration whereas bare copper or brass will start to corrode after one hour. However, Entek CU-56 is not recommended for protection against outdoor exposure. The primary function of the Entek CU-56 coating is to prevent tarnishing, corrosion, and spotting-out of copper and brass during storage. Entek CU-56 does not contain chromates and is very economical to use. One gallon of operating solution will treat approximately 500 ft.2 (47 m2) of metal surface. HOW TO USE ENTEK CU-56 OPERATING CONDITIONS Concentration 1% by volume Entek CU-56 in water Temperature Room Temperature to 140°F. (60°C.) Time 5 to 45 seconds OPERATION Entek CU-56 is added to water at a concentration of 1% by volume. The work should be rinsed in the Entek CU-56 solution for a minimum of 30 seconds at room temperature and then dried. Rinsing in water after rinsing in Entek CU-56 will lessen the degree of protection obtained. To aid in drying, the solution may be heated to 140°F. (60°C.) in which case the immersion time may be reduced to 5 to 10 seconds. Where it is desired to operate the final rinse at temperatures above 140°F. (60°C.), Entek CU-55, which reacts more slowly with copper and brass, © 2000, Enthone-OMI, Inc. Entek® CU-56 Technical Data Sheet Page 2 of 4 should be sued. Literature on Entek CU-55 is available from Enthone-OMI upon request. Above 140°F. (60°C.) Entek CU-56 may form a visible film on the metal surface. OPERATION (CONT) Work entering the Entek CU-56 rinse should be clean, wet and free of water-breaks. This is usually the case after plating, pickling or other wet processing. the solution has no cleaning ability of its own and the protective Entek CU-56 coating will not form on unclean surfaces. For maximum effectiveness, work entering the Entek CU-56 rinse should have an alkaline rather than an acid surface condition. For example, after bright dipping of copper or brass in a nitric-sulfuric solution, the work should be neutralized by dipping in a soda ash or sodium hydroxide solution, rinsed thoroughly, and then rinsed in Entek CU-56. EQUIPMENT Entek CU-56 solutions should be contained in stainless steel, fiberglass, plastic or rubber-lined steel tanks, polyethylene or ceramic crocks. Plain steel tanks will tend to rust and interfere with the application of the protective film. For heating, use stainless steel, copper or copper-plated steel steam coils, or Platecoils. Ventilation is recommended to keep vapors below recommended TLV level. CONTROL The simplest control is to observe the work coming out of the Entek CU-56 solution. Failure of the solution to "break" cleanly from the metal surface will indicate that the concentration of Entek CU-56 is low. An addition of 1/2 percent by volume of Entek CU-56 should be made at this point. A more accurate, analytical method is available from Enthone-OMI upon request. WASTE TREATMENT Entek CU-56 solutions consist of organic chemicals dissolved in a methanol-water solution and may contain metals processed through the operating solution. Consult local agencies regarding waste effluent regulations. PRECAUTIONARY INFORMATION DANGER! FLAMMABLE, CONTAINS METHYL ALCOHOL FLAMMABLE, TOXIC: Keep away from heat, sparks, flames and all ignition sources. Vapors may travel to distant points of ignition sources. Inhalation may cause dizziness, drowsiness, vision problems and irritation of respiratory tract. Ingestion may cause nausea, vomiting, vision problems, blindness, dizziness, coma and death. Prolonged contact may cause reddening and defatting of the skin, absorption of harmful amounts of methyl alcohol. Do not get in eyes, on skin, or on clothing. Do not inhale or take internally. FIRST AID: In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; hold eye-lids apart to ensure flushing of entire surface, seek immediate medical attention. If ingested, drink large amounts of water and INDUCE VOMITING, seek immediate medical attention. In case of inhalation, remove person from area. If breathing has stopped, resuscitate and administer oxygen if necessary, seek immediate medical attention. Remove and wash contaminated clothing. HANDLING INFORMATION: Always wear goggles, face-shield, rubber gloves, apron and boots, respirator and protective clothing when handling. Use with adequate ventilation. Avoid contact with alkali metals, acids or any other foreign material. Avoid contamination from any source. Exhaust ventilation is Entek® CU-56 Technical Data Sheet Page 3 of 4 recommended to remove mist or vapors that may be generated during make-up and operation. Wash thoroughly after handling. CONTAINER INFORMATION: Store in a cool, dry, well-ventilated area. Keep out of sun and away from heat, combustibles and ignition sources. Loosen closure cautiously, when opening. Do not reuse container, wash thoroughly before disposal. Improper disposal or reuse of container may be dangerous and illegal. REFER TO MSDS FOR FURTHER SAFETY AND HANDLING INFORMATION. Issued: 07/17/00 Spsds: 10/12/90 Entek® CU-56 Technical Data Sheet Page 4 of 4 MATERIAL SAFETY DATA SHEETS For more detailed information on the toxicological properties of the products described herein, reference can be made to the Material Safety Data Sheet (MSDS) for each product. If you do not have the proper MSDS, it can be requested from: Enthone Inc., attention: Regulatory Affairs Department, 350 Frontage Road, West Haven, CT 06516. For emergency assistance call CHEMTREC (800) 424-9300. WARRANTY AND DISCLAIMER The information presented herein is to the best of our knowledge true and accurate and all recommendations and suggestions appearing in this bulletin covering the use of our products are based upon information believed to be reliable. However, since the conditions of use are beyond our control, this information is given on the express condition and agreement that Enthone Inc. will not be liable to any person in contract, tort (including negligence), strict liability or otherwise for any claims, damages or losses whatsoever. Nothing herein shall be deemed a recommendation to use any product or process in violation of any existing patent rights and no warranties, expressed or implied, are made regarding the information, product, processes, recommendations, description and safety notations contained herein. The above includes proprietary information of Enthone Inc. and is furnished to you for your use solely on products or processes supplied by us to you. Enthone Inc. (Canada) MATERIAL SAFETY DATA SHEETS For detailed information on the toxicological properties of the products described herein, reference can be made to the Material Safety Data Sheet (MSDS) for each product. If you do not have a current MSDS, it can be requested from the W.H.M.I.S. coordinator, Enthone Inc. (Canada), 121 Watline Avenue, Mississauga, Ontario, L4Z-1P2. For emergency assistance regarding accidents with this product resulting in container rupture, spills, poisoning, bodily injury or threats to health call: CHEMTREC (800) 424-9300. Enthone Inc. (Canada) WARRANTY AND DISCLAIMER The information presented herein is to the best of our knowledge true and accurate and all recommendations and suggestions appearing in this bulletin covering the use of our products are based upon information believed to be reliable. However, since the conditions of use are beyond our control, this information is given on the express condition and agreement that Enthone Inc. (Canada) will not be liable to any person in contract, tort (including negligence), strict liability or otherwise for any claims, damages or losses whatsoever. Nothing herein shall be deemed a recommendation to use any product or process in violation of any existing patent rights and no warranties, expressed or implied, are made regarding the information, product, processes, recommendations, description and safety notations contained herein. The above includes proprietary information of Enthone Inc. (Canada) and is furnished to you for your use solely on products or processes supplied by us to you. CUSTOMER ORDER CENTERS UNITED STATES West Haven, Connecticut Performance Coatings (800) 496-8326 Precious Metal Products (800) 560-7214 Fax (203) 933-0249 ctchemorders@cooksonelectronics.com PWB Chemistry Londonderry, New Hampshire CANADA Mississauga, Ontario Fax (905) 507-9943 Pointe Claire, Quebec Fax (514) 426-1453 MEXICO www.cooksonelectronics.com 03 May 04 Mexico, D.F. Fax (011-52-5) 567-6326 (800) 877-9871 Fax (603) 645-4402 (800) 387-3766; (905) 507-9949 (514) 426-1451 (011-52-55) 5078-3904 ® Registered Trademark of Enthone Inc. ™ Trademark of Enthone Inc. [Enthone Inc. (Canada) Inc. is the registered user in Canada under license from Enthone Inc. (USA)]