AppendixB
Physical Property Tables
TABLE
PAGES
Selected Physical Property Data
Heat Capacities
Vapor Pressure of Water
Antoine Equation Constants
Properties of Saturated Steam: Temperature Table
Properties of Saturated Steam: Pressure Table
Properties of Superheated Steam
B.8 Specific Enthalpies of Selected Gases: SI Units
B.9 Specific Enthalpies of Selected Gases: American Engineering Units
B.10 Atomic Heat Capacities for Kopp's Rule
B.11 Integral Heats of Solution and Mixing at 2SOC
628-634
635-637
638-639
B.1
B.2
B.3
B.4
B.5
B.6
B.7
640-641
642-643
644--M9
650-651
652
652
653
653
627
:;-.,
N
00
Table
;l>
n.1 Selected Physical Property Data"
SO
t::.ffm(TIll)',j
kJ/mol
eft,
Mol. Wt.
(20 0 W)
Tm(OC)b
CH 3 CHO
CH3 COOH
44,05
60.05
0,783 IS '
1.049
-123.7
16.6
12.09
20.2
118.2
Acetone
C3 H 6 O
58.08
0.791
-95.0
5.69
56.0
Acetylene
Ammonia
C 2H 2
NH 3
26.04
17.03
-
-
-81.5
-33.43
-
Compound
Formula
Acetaldehyde
Acetic acid
Ammonium
hydroxide
Ammonium
nitrate
Ammonium
sulfate
Aniline
Benzaldehyde
NH 40H
35.03
NH 4N0 3
80.05
Benzene
C 6 H(i
Benzoic acid
Benzyl alcohol
Bromine
1,2-Butadiene
1,3-Butadiene
n-Butane
C 7 H(i°2
C7 HsO
Br2
C4H 6
C 4H 6
C 4 H IO
lsobutane
C4 H lO
I-Butene
Calcium
carbide
Calcium
carbonate
Calcium
chloride
C4H s
CaC2
-
-77.8
-
5.653
-
1.725 25 '
169.6
513
-
C6 H 7 N
C/lH 5CHO
93.12
106.12
1.022
1.046
-6.3
-26.0
-
78.11
0.879
2.152 15 '
309.5
405.5
61.6
111.3
-
-
-
9.837
184.2
179.0
80. 10
30.705
502.0
-
-
-
-
-
-
4R6
36.0
-185.3
2300
3.8480
-6.25
21.916
419.6
39.7
ItUs
-
-
-
31.0
42.7
37.47
Decomposes at 825°C
782
28.37
>1600
-
22.305
-
-
-
-88.83(1)
-40.04(g)
+48.06(1)
+H2.93(g)
-
584
446
425
425.17
-
-166.2(g)
-486.18(1)
-438.15(g)
- 248.2(1)
-216.7(g)
+226.75(g)
-67.20(1)
-46.19(g)
-366.48(aq)
(t::.ffeo)'-i
kJ/mol
-1192.4(g)
-871.69(1)
-919.73(g)
-1785.7(1)
-1821.4(g)
-1299.6(g)
-382.58(g)
52.4
408.1
-
(t::..fffO)h,j
kJ/mol
-365.14(c)
- 399.36(aq)
-1179.3(c)
-1173.I(aq)
21.292
2.22 1S'
110.99
17.6
23.351
-11.73
56.10
64.10
CaCI 2
47.0
4.540
-
2.93
508.0
-159.6
58.J2
100.09
30.2
4.661
-
CaC0 3
57.1
PcCatm)!!
249.8
205.2
58.6
10.1
-4.6
-0.6
122.2
-15.4
-7.4
-136.5
-109.1
-138.3
-
461.0
594.8
Decomposes at 513°C
after melting
699
38.40
1.769
1.266 15'
1.045
3.119
25.1
24.39
Decomposes at 2l0°C
132.14
122.12
108.13
159.83
54.09
54.09
58.12
-
Te(K)!
5.4
(NH 4hS04
5.53
h(°C)"
t::.fi v
)c,}
kJ/mol
102
-
-
-3520.0(1)
-3207.6(1)
-3301.5(g)
- 3226.7(g)
-374U!(l)
0(1)
-J47.0(l)
-124.7(g)
-158.4(1)
-134.5(g)
+ 1.17(g)
-62.76(c)
-1206.9(c)
-794.96(c)
-2855.6(1)
-2878.5(g)
-2849.0(1)
-2868.8(g)
-2718.6(g)
"0
"0
ro
~
0-
;;<'
to
Calcium
hydroxide
Calcium oxide
Calcium
phosphate
Calcium
silicate
Calcium
sulfate
Calcium
sulfate
(gypsum)
Carbon
(graphite)
Carbon
dioxide
Carbon
disullide
Carbon
monoxide
Carbon
tetrachloride
Chlorine
Chlorobenzene
Chloroethane
(- H 20 at 580°C)
-986.59(c)
Ca(OHh
74.10
2.24
CaO
CU3(P04h
56.08
310.19
3.32
3.14
2570
1670
50
CaSi0 3
116.17
2.915
1530
48.62
-1584(c)
CaS04
136.15
2.96
CaS04·2H20
172.18
2.32
(-1.5 H 20 at 128°C)
-1432.7(c)
- 1450.4(aq)
-2021(c)
C
12.010
2.26
CO 2
44.01
CS 2
76.14
CO
28.01
CCI 4
153.84
Ch
70.91
112.56
1.107
See ethyl chloride
CoHsCI
C2 H sCi
1.261 22°/20°
1.595
3600
46.0
-56.6
at 5.2 atm
-112.1
4.39
-205.1
0.837
-22.9
-101.00
-45
8.33
2.51
6.406
-635.6(c)
-4138(c)
2850
4200
(Sublimes at -78°C)
46.25
-191.5
26.8
6.042
304.2
72.9
552.0
78.0
133.0
34.5
76.7
30.0
556.4
45.0
-34.06
132.10
20.4
36.5
417.0
632.4
76.1
44.6
O(c)
-393.51(c)
-412.9(1)
-393.5(g)
+87.9(1)
+115.3(g)
-110.52(g)
-1075.2(1)
1102.6(g)
-282.99(g)
-139.5(1)
-106.7(g)
- 352.2(1)
-385.0(g)
O(g)
"Adapted in part from D. M. Himmelblau, Balk Principles and Calclliations in Chemicul Engineering, 3rd Edition, ©1974, Tables D.1 and FI. Adapted by permission of
Prentice-Hall, Inc., Englewood Cliffs, NJ.
bMelting point at I atm.
'Heat of fusion at I'm and 1 atm.
"Boiling point at 1 atm.
"tl
:r
"Heat of vaporization at I'll and 1 atm.
'<
C/l
(=i'
fCritical temperature.
::..
..,"tl
"Critical pressure.
o
/, lleat of formation at 25°C and 1 atm.
"0
'lleat of combustion at 25°C and I atm. Standard statcs of products arc CO 2(g), 11 20(1), S02(g), IICI(aq), and NAg). To calculatc M}~ with Hl)(g) as a product, add
·\4.0 lllw to the tabulated value, where II w = molcs I-hO formcd/molc fuel burned.
iTo convert
I1H
to kcal/mol, dividc given value by 4.184; to convert to Btu/lb-mole, multiply by 430.28.
..,...
(l)
'<
~
0-
«('ontin lied)
ro
C/l
0'1
N
I,Q
Q'I
W
Q
?
Table B.t (Continued)
'0
'0
(l)
TmCC)b
tJ.H m (T In y.j
kllmol
-63.7
1083
13.DI
tJ.H,(Tb)'·i
kllmol
Mol. Wt.
SG
(20 W)
CHCh
Cu
CUS04
119.39
63.54
159.61
1.489
8.92
3.606 15°
C6 H I2
84.16
D.779
6.7
2.677
80.7
30.1
553.7
40.4
Cyclopentane
C 5H IO
70.13
0.745
-93.4
0.609
49.3
27.30
511.8
44.55
n-Decane
C IO H 22
142.28
0.730
-29.9
619.0
20.8
Diethyl ether
Ethane
Ethyl acetate
(C2H 5hO
C 2H 6
C 4H H0 2
74.12
30.07
88.10
467
305.4
523.1
35.6
48.2
37.8
Ethyl alcohol
(Ethanol)
Ethyl benzene
C 2H 5OH
Compound
Formula
Chloroform
Copper
Cupric
sulfate
Cyclohexane
0
0.708 25'
-
7.30
2.859
0.901
-116.3
-183.3
-83.8
46.07
0.789
-114.6
CsH IO
106.16
0.867
Ethyl bromide
Ethyl chloride
3-Ethyl
hexane
Ethylene
Ethylene
glycol
Ferric oxide
Ferrous oxide
Ferrous
sulfide
Formaldehyde
Formic acid
C 2H 5Br
C 2H 5CI
C HH I8
108.98
64.52
114.22
1.460
0.903 15'
0.717
C2H 4
C2H 6 0 2
28.05
62.07
1.113 19'
H 2CO
CH20 2
Glycerol
Helium
C3 H s 0 3
He
Fe203
FeO
FeS
159.70
71.85
87.92
-
Tb(°C)d
61.0
2595
304.6
Decomposes> 600°C
173.8
Pe(atm)g
536.0
54.0
-
34.6
-88.6
77.0
26.05
14.72
5.021
78.5
38.58
516.3
63.0
9.163
136.2
35.98
619.7
37.0
-119.1
-138.3
-
4.452
38.2
13.1
118.5
24.7
34.27
504
460.4
567.0
61.5
52.0
26.4
-169.2
-13
3.350
11.23
-103.7
197.2
13.54
56.9
283.1
50.5
-94.67
-
-
5.12
5.7
4.84
1193
30.03
46.03
0.815- 20'
1.220
-92
8.30
12.68
-19.3
100.5
92.09
4.00
1.26050'
18.20
-269.7
18.30
0.02
290.0
-268.9
-
-
Te(K)!
-
-
-
Decomposes at 1560°C
-
-
-
24.48
22.25
-
0.084
-
-
-
-
5.26
2.26
-
(liHt)"·j
klima I
(tJ.H eO)U
kllmol
-131.8(1)
O(c)
-769.9(c)
-843.1(aq)
-156.2(1)
-123.1(g)
-105.9(1)
-77.2(g)
-249.7(1)
- 373(1)
-272.8(1)
-84.67(g)
-463.2(1)
-426.8(g)
-277.63(1)
-235.31(g)
-12.46(1)
+29.79(g)
-54.4(g)
-105.0(g)
-250.5(1)
-21O.9(g)
+52.28(g)
-451.5(1)
- 387.1(g)
-822.2(c)
-266.5(c)
-95.1(c)
-115.90(g)
-409.2(1)
-362.6(g)
-665.9(1)
O(g)
-3919.9(1)
- 3953.0(g)
- 3290.9(1)
-3319.5(g)
-6778.3(1)
-6829.7(g)
-2726.7(1)
--1559.9(g)
-2246.4(1)
-1366.91(1)
-1409.25(g)
-4564.9(1)
-4607.1 (g)
- 5407.1 (1)
-5509.8(g)
-14lO.99(g)
-1179.5(1)
-563.46(g)
-262.8(1)
-1661.1(1)
::3
0.
x'
to
n-Heptane
C 7 H l6
100.20
0.684
-90.59
14.03
98.43
31.69
540.2
27.0
n-Hexane
C6 H I4
86.17
0.659
-95.32
13.03
68.74
28.85
507.9
29.9
H2
2.016
80.92
-
-259.19
-86
0.12
-252.76
-67
33.3
12.8
HBr
HCl
36.47
-
-114.2
1.99
HCN
27.03
-
-14
HF
20.0
-
H 2S
34.08
Hydrogen
Hydrllgen
bromide
Hydrogen
chloride
Hydrogen
cyanide
Hydrogen
fluoride
Hydrogen
sulfide
Iodine
Iron
Lead
Lead oxide
Magnesium
Magnesium
chloride
Magnesium
hydroxide
Magnesium
oxide
Mercury
Methane
Methyl
ncetnte
Methyl alcohol
(Methanol)
Melhyl
amine
Methyl
chloride
253.8
55.85
207.21
223.21
24.32
95.23
h
Fe
Pb
PbO
Mg
MgCh
4.93
7.7
11.3372()Oj2()O
9.5
1.74
2.325 25 °
0.904
-
81.5
-92.31(g)
-85.0
16.1
324.6
-
26
-
-
+ 130.54(g)
-83
-
20
503.2
-85.5
2.38
-60.3
-268.6(g)
-316.9(aq,
2(0)
-19.96(g)
113.3
1535
327.4
886
650
714
-
15.1
5.10
11.7
9.2
43.1
184.2
2800
1750
1472
lI20
1418
18.67
-
373.6
88.9
826.0
-
354.0
179.9
213
131.8
136.8
-
3600
-
-
-356.9
--161.5
57.1
8.179
-
-
-4816.9(1)
-4853.5(g)
-4163.1(1)
-4194.8(g)
-285.84(g)
-562.59(g)
O(c)
O(c)
O(c)
-219.2(c)
O(c)
-641.8(c)
Decomposes at 350°C
Mg(OHh
58.34
2.4
MgO
40.32
3.65
Hg
CH 4
C)H 6 0
200.61
16.04
74.08
13.546
2
-
-224.4(1)
-187.8(g)
~ 198.8(1)
-167.2(g)
O(g)
-36.23(g)
2900
-38.87
-]82.5
-98.9
0.933
77.4
0.94
-
-
-601.8(c)
-
190.70
506.7
45.8
46.30
O(c)
-74.85(g)
-409.4(1)
-890.36(g)
-1595(1)
'"t1
::r-
ell)OIl
32.04
0.792
CII~N
31.06
ON)<)
II"
--97.9
3.167
--<J2.7
-
64.7
-6.9
35.27
-
513.20
78.50
429.9
73.60
-238.6(1)
- 20 1.2(g)
-28.0(g)
726.6(1)
-7M.O(g)
-1071.5(1)
'<:
en
n'
~
'"t1
'"1
0
"0
CIVJ
50.49
-
- 97.9
-
-24
416.1
65.80
-81.92(g)
-
~
'"1
r+
'<:
~
(continued)
cr
n
en
....W'"
Q\
~
N
>-
Table n.l (Continued)
SG
(20 W)
0
Tm(OC)"
I1H m (Tm y,)
kllmol
Th(OC)"
I1Hv (Tb Y,j
kllmol
n"')
reCK)!
P,(atm)!J
(I1 H
kllmol
Compound
Formula
Mol. Wt.
Methyl ethyl
ketone
Naphthalene
Nickel
Nitric acid
C 4H HO
72.10
0.805
-87,1
-
78.2
CIOHg
Ni
HN0 3
128.16
58.69
63.02
1.145
8.90
1.502
80.0
1452
-41.6
-
-
217.8
2900
86
30.30
C6 H 5 0 2 N
N2
N0 2
123.11
28.02
46.01
1,203
5.5
-210.0
-9.3
210.7
-195.8
21.3
5.577
14.73
126.20
431.0
33.5
100.0
O(g)
+33.8(g)
NO
179.20
65.0
+90.37(g)
1.63 1S
-163.6
30
13.78
N20 s
30.01
108,02
N2 0 4
92.0
1.448
N2 0
44,02
Nitrobenzene
Nitrogen
Nitrogen
dioxide
Nitric oxide
Nitrogen
pentoxide
Nitrogen
tetraoxide
Nitrous
oxide
n-Nonane
C 9 H 20
n-OCtane
CSH 1H
Oxalic acid
Oxygen
n-Pentane
-
10.47
-
0.720
7.335
32.0
-
-
-
-
-
-
-
-9.5
-
21.1
-
431.0
99.0
+9.3(g)
1.226- s9°
-91.1
-
-88.8
-
309.5
71.70
+81.5(g)
128,25
0.718
-53.8
-
150.6
-
595
23.0
-229.0(1)
114.22
0.703
-57.0
125.5
-
568.8
24.5
C 2 ]-h04
O2
C SH I2
90.04
32.00
72.15
1.90
O.63 1H
6,82
25.77
154.4
469.80
49.7
33.3
lsopentane
C SH 12
72.15
0.62 19°
-160.1
-
27.7
-
461.00
32.9
I-Pentene
Phenol
CsH IO
C6 H 5 OH
70.13
94.11
0.641
1.071 25°
-165.2
42.5
4.94
11.43
29.97
181.4
-
474
692.1
39.9
60.5
Phosphoric
acid
H 3 P0 4
98.00
1.834 18°
42.3
10.54
(- ~ H 2 0 at 213°C)
Phosphorus
(red)
P4
81.17
Ignites in air, 725°C
-249.9(1)
-208.4(g)
-826.8(c)
O(g)
- 173.0(1)
-146.4(g)
-179.3(1)
-152.0(g)
-20.9(g)
-158.1(1)
-90.8(g)
-1281.1(c)
-1278.6(aq,
1H 2 O)
-17.6(c)
O(c)
123.90
o
-
2.20
o
-218.75
-129.6
59043 aIm
2.301
Decomposes at 186°C
-182.97
0.444
8.393
36.07
-2436(1)
O(c)
-173.23(1)
-206.57(aq)
-151.8
47
-
(I1H/)"j
kllmol
~5157(g)
-
'"0
'"0
-
-
-
- 3092.8(1)
-6124.5(1)
-6171.0(g)
-5470.7(1)
-5512.2(g)
-251.9(s)
- 3509.5(1)
- 3536.1(g)
-3507.5(1)
-3529.2(g)
- 3375.8(g)
- 3063.5(s)
(1)
;:l
0..
S<.
tx:1
Phosphorus
(white)
Phosphorus
penloxide
Propane
123.90
1.82
5
141.95
2.387
C1 H H
44.09
-
P4
P2 0
44.2
2.51
280
49.71
Suhlimes at 250°C
- Hn.69
3.52
3.00
~-42.(17
-47.70
97.04
-
18.77
42.0
0.804
-185.2
-127
alcohol
Isopropyl
alcohol
C3H 7 OH
60.09
0.785
-89.7
-
I1~Propyl
C 9 H l2
120.19
0.862
-99.50
8.54
Si0 2
60.09
2.25
1710
NaHC0 3
84.01
2.20
NaHS0 4
120.07
2.742
Na2C03
105.99
2.533
NaCI
58.45
2.163
808
28.5
1465
170.7
-
NaCN
49.01
-
562
16.7
1497
155
-
-89.79(c)
NaOH
40.00
2.130
319
-
NaN0 3
85.00
2.257
310
15.9
Decomposes at 380°C
-4266(c)
-469.4(aq)
-466.7(c)
NaN0 2
69.00
2.168°0
271
-
Decomposes at 320°C
benzene
Silicon
dioxide
Sodium
bicarbonate
Sodium
bisulfate
Sodium
carbonate
Sodium
chloride
Sodium
cyanide
Sodium
hydroxide
Sodium
nitrate
Sodium
nitrite
Sodium
sulfate
Sodium
sulfide
Sodium
sultite
14.2
82.24
159.2
2230
-
38.24
-
45.4
49.95
508.8
53.0
638.7
31.3
IIIHi(l)
42.08
60.09
I1~Propyl
365.1
536.7
-~
-103.8(g)
+ 20.41 (g)
- 300.70(1)
-255.2(g)
-310.9(1)
C 3H 6
C 3H 7 OH
Propylene
18.42
369.9
-1506.2(c)
-
-
Decomposes at 270°C
-
-
-
-5218.2(1)
- 5264.48(g)
-945.6(c)
-
Decomposes at 854°C
8.34
- 38.40(1)
+ 7.82(g)
-851.0(c)
- 2204.0(1)
-2220.0(g)
-2058.4(g)
-2010.4(1)
-2068.6(g)
-1986.6(1)
1390
-
-
-1l26.3(c)
-
-
-1130.9(c)
-411.0(c)
-
-359.4(c)
'"1:l
~
Na2S04
142.05
2.698
890
24.3
-
78.05
1.856
950
6.7
-
-
-1384.S(c)
-
-373.2(c)
-
'<
C/>
(S.
!:'..
Na2S
-
...,'"1:l
0
"0
Na2S03
126.05
2.633 15 '
Decomposes
-
-
-1090.3(c)
...,
(l)
-
'<
~
(continued)
r::r
~
C/>
C1\
Vol
Vol
Q\
~
".
;:l>
"0
"0
<l>
::l
0..
X·
O:l
Table B.l (Continued)
SG
(20 W)
0
Tm(°C)b
6.H m(T m)',j
kllmo!
TbCC)d
Mfv(Tb)',j
kllmo!
Pc(atm)g
(6.H j Ol,j
kllmo!
Compound
Formu!a
Mol. Wt.
Sodium
thiosulfate
Sulfur
(rhombic)
Sulfur
(monoclinic)
Sulfur
dioxide
Sulfur
trioxide
Sulfuric
acid
Toluene
Na2 S2 0 3
158,11
1.667
Sg
256.53
2.07
113
10.04
444.6
83.7
-
SH
256.53
1.96
119
14.17
444.6
83.7
-
-10.02
24.91
430.7
77.8
-296.90(g)
43.3
41.80
491.4
83.8
-395.18(g)
-
-811.32(1)
-907.51(aq)
+ 12.00(1)
+50.00(g)
-285.84(1)
-241.83(g)
-25.42(1)
+ 17.24(g)
-24.44(1)
+ 18.99(g)
-24.43(1)
17.95(g)
O(c)
-
-
-
-75.48
S02
64.07
SO)
80.07
H2SO4
98.08
1.834 18"
C7 H g
92.13
0.866
-94.99
Water
H 2O
18.016
1.004"
0.00
m-Xylene
CgH lO
106.16
0.864
-47.87
o-Xylene
CgH IO
106.16
0.880
-25.18
p-Xylene
CgH IO
106.16
0.861
13.26
Zinc
Zn
65.38
7.140
-
Tc(K)f
7.402
16.84
25.48
10.35
9.87
419.5
Decomposes at 340°C
-
] 10.62
33.47
593.9
40.3
6.0095
100.00
40.650
047.4
218.3
11.509
139.10
36.40
619
34.6
13.598
144.42
36.82
631.5
35.7
17.11
138.35
36.07
618
33,9
907
114.77
-1117.1(c)
O(c)
+0.30(c)
6.619
6.674
(6.H/)i,j
kllmo!
-3909.9(1)
-3947.9(g)
-4551.9(1)
-4594.5(g)
-4552.9(1)
-4596.3(g)
-4552.91(1)
-4595.2(g)
Table B.2 Heat Capacitiesa
•
Form 1: Cp[kJ/(mol'°C)] or [kJ/(mol·K)] = a
Form 2: Cp[kJ/(mol'°C)] or [kJ/(mol'K)] = a
Example: (C,,)lIcclonc(g) = 0.07196
Phvsical Property
database
+ (20.10
X
1O-5)T - (12.78
X
+ bT + cT 2 + dT 3
+ bT + cr 2
1O- H)T 2
+ (34.76
X
1O- 12 )T 3 , where T is in
0c.
Note: The formulas for gases are strictly applicable at pressures low enough for the ideal gas equation of state to apply.
Quickly integrates
tabulated heat
capacities
Compound
Formula
Mol.
Wt.
Acetone
CH 3 COCH 3
58.08
Acetylene
Air
Ammonia
AlIll1loniulIl sulfall:
Benzene
Isobutane
n-Butane
Isobutene
Calcium carbide
Calcium carbonate
Calcium hydroxide
Calcium oxide
Carbon
Carbon dioxide
Carbon monoxide
Carbon tetrachloride
Chlorine
Copper
C2 H 2
NH 3
(NII.,)!SOI
C6 H 6
C 4 HJO
C 4 HjQ
C4 H H
CaC2
CaC0 3
Ca(OH)z
CaO
C
CO 2
CO
CCI 4
CI 2
Cu
26.04
29.0
State
Form
I
g
g
1
1
1
1
I
I
g
g
Temp.
Unit
a X 103
b
°C
°C
°C
°C
K
°C
123.0
71.96
42.43
28.94
28.09
35.15
18.6
20.10
6.053
0.4147
0.1965
2.954
17.03
g
112.1)
C
I
K
78.11
J
I
I
1
1
1
2
2
1
2
2
1
1
1
1
1
°C
°C
°C
°C
°C
K
K
K
K
K
°C
°C
K
°C
K
58.12
58.12
56.10
64.10
100.09
74.10
56.08
12.01
44.01
28.01
153.84
70.91
63.54
g
g
g
g
c
c
c
c
c
g
g
I
g
c
X
105
eX 108
-12.78
-5.033
0.3191
0.4799
0.4421
d
X
10 12
34.76
18.20
-1.965
-1.965
-6.686
21 ).1)
126.5
74.06
89.46
92.30
82.88
68.62
82.34
89.5
41.84
11.18
36.11
28.95
93.39
33.60
22.76
Range
(Units
ofT)
-30-60
0-1200
0-1200
0-1500
273-1800
0-1200
27)J2H
23.4
32.95
30.13
27.88
25.64
1.19
4.975
2.03
1.095
4.233
0.4110
12.98
1.367
0.6117
-25.20
-18.91
-15.47
-17.27
-8.66
-12.87
77.57
49.87
34.98
50.50
X
X
10 10
10 10
-4.52 X 10 10
-4.891 X 10 10
-2.887
0.3548
-1.607
-
7.464
-2.220
6.473
6--67
0-1200
0-1200
0-1200
0-1200
298-720
273-1033
276-373
273-1173
273-1373
0-1500
0-1500
273-343
0-1200
273-1357
'1j
::r
'<
'"
n·
e:.
..,
'1j
0
"d
..,.....
Adapted in part from D. M. Himmelblau, Basic Principles and Calculations in Chemical Engineering, 3rd Edition, © 1974, Table E.1. Adapted by
permission of Prentice-Hall, Inc., Englewood Cliffs, NJ.
'<
(continued)
;j
U
(1)
0-
~
'"
Q\
(.-.I
01
C\
C".I
0'1
>-
"0
"0
(1l
~
0..
Table B.2 (Continued)
~.
Compound
Formula
Cumene
(Isopropyl benzene)
Cyclohexane
Cyclopentane
Ethane
Ethyl alcohol
(Ethanol)
C 9 H 1Z
C6 H 1Z
CsH IO
C zH 6
CzHsOH
Ethylene
Ferric oxide
Formaldehyde
Helium
n-Hexane
C ZH 4
FeZ 0 3
CHzO
He
C6 H I4
Hydrogen
Hydrogen hromide
Hydrogen chloride
Hydrogen cyanide
Hydrogen sulfide
Magnesium chloride
Magnesium oxide
Methane
Hz
HUr
HCI
HCN
HzS
MgCl z
MgO
CH 4
Methyl alcohol
(Methanol)
Methyl cyclohexane
Methyl cyclopentane
Nitric acid
Nitric oxide
CH 3 0H
C 7 H l4
C6 H 1Z
NH0 3
NO
Mol.
Wt.
State
Form
Temp.
Unit
120.19
g
1
°C
139.2
53.76
-39.79
84.16
70.13
30.07
46.07
g
g
g
I
I
g
g
c
g
g
I
g
g
g
g
g
g
c
c
g
g
I
g
g
g
I
g
1
1
1
1
1
1
°C
°C
°C
°C
94.140
73.39
49.37
103.1
158.8
61.34
+40.75
103.4
34.28
20.8
216.3
137.44
28.84
29.10
29.13
35.3
33.51
72.4
45.44
34.31
19.87
75.86
42.93
121.3
98.83
IIO.ll
29.50
49.62
39.28
13.92
-31.90
-25.54
-5.816
80.63
68.66
7.280
15.72
11.47
6.711
4.268
-8.749
-6.891
-17.72 X 10 10
0.0000
19.83
17.66
28.05
159.70
30.03
4.00
86.17
2.016
80.lJ2
36.47
27.03
34.08
95.23
40.32
16.04
32.04
98.18
84.16
63.02
30.01
I
2
1
1
1
1
1
1
1
1
1
DC
°C
°C
K
DC
°C
°C
°C
°C
°C
DC
°C
°C
I
K
2
1
K
°C
I
K
1
°C
°C
°C
°C
°C
°C
I
I
1
1
1
a
X
103
b X 10s
eX
108
40.85
0.00765
-(J.()227
-0.1341
2.908
1.547
1.58
0.5008
5.469
5.021
16.83
8.301
56.53
45.857
-23.92
0.3288
0.9887
0.9715
1.092
0.3012
0.8188
-0.2925
-8.732 X 10 10
0.3661
1.268
-1.87
-37.72
-30.44
d X 10 1Z
120.5
-
-8.694
57.66
-0.8698
-4.858
-4.335
-3.292
-11.00
-11.00
-8.03
100.8
83.81
0.3652
Range
(Units
ofT)
0-1200
0-1200
0-1200
0-1200
0
100
0-1200
0-1200
273-1097
0--1200
0-1200
20-100
0-1200
0-1500
0-1200
0-1200
0-1200
0-1500
273-991
273-2073
0-1200
273-150ll
0-65
0-700
0-1200
0-1200
25
0-3500
ttl
Nitrogen
Nitrogen dioxide
Nitrogen tetraoxide
Nitrous oxide
Oxygen
n-Pentane
N2
N0 2
N 20 4
N 20
O2
Cs H 12
Propane
Propylene
Sodium carbonate
Sodium carbonate
decahydrate
Sulfur
C3 H s
C3 H6
Na2C03
Na2CO.\
'10H 2O
S
28.02
46.01
92.02
44.02
32.00
72.15
44.09
42.08
105.99
286.15
g
g
g
g
g
I
g
g
g
c
c
Sulfuric acid
Sulfur dioxide
Sulfur trioxide
Toluene
H 2SO 4
S02
SO]
C7H g
32.07
c
(Rhombic)
c
(Monoclinic)
98.08
I
64.07
g
80.07
g
92.13
I
Water
I-hO
18.016
g
1
g
0-150()
0-1200
0-300
0-12()O
0-1500
0-36
0-1200
0-1200
0-1200
288-371
298
1
I
I
1
1
1
1
1
1
I
I
°C
°C
DC
°C
°C
°C
°C
°C
°C
K
K
29.00
36.07
75.7
37.66
29.10
155.4
114.8
68.032
59.580
121
535.6
0.2199
3.97
12.5
4.151
1.158
43.68
34.09
22.59
17.71
I
K
15.2
2.68
273-368
1
K
18.3
1.84
368-392
1
1
I
1
1
I
I
°C
°C
°C
DC
°C
°C
°C
139.1
38.91
48.50
148.8
94.18
75.4
33.46
15.59
3.904
9.188
32.4
38.00
0.68RO
0.5723
-2.88
-11.3
-2.694
-0.6076
-2.871
7.87
-18.99
-13.11
-10.17
42.26
31.71
24.60
-3.104
-8.540
-27.86
0.7604
10.57
1.311
8.606
32AO
80.33
-3.593
10--45
0-1500
0-1000
0-110
0-1200
0-100
0-1500
""0
;:r
'-<
C/l
(i'
e
""0
...,
0
"0
I'D
...,
.-+
'<
p;i
cr"
(D
C/l
0'\
W
-..J
638
Appendix B
Table B.3 Vapor Pressure of Water"
pv(mm Hg) versus T(°C)
Example: The vapor pressure of liquid water at 4.3°C is 6.230 mm Hg
~
Ice
T(°C)
0.0
0.1
0.2
0.3
0,4
0.5
0.6
0.7
0.8
0.9
-14
-13
-12
-11
-10
1.361
1.490
1.632
1.785
1.950
1.348
1.477
1.617
1.769
1.934
1.336
1.464
1..602
1.753
1.916
1.324
1.450
1.588
1.737
1.899
1.312
1.437
1.574
1.722
1.883
1.300
1.424
1.559
1.707
1.866
1.288
1.411
1.546
1.691
1.849
1.276
1.399
1.532
1.676
1.833
1.264
1.386
1.518
1.661
1.817
1.253
1.373
1.504
1.646
1.800
-9
-8
-7
-5
2.131
2.326
2.537
2.765
3.013
2.122
2.306
2.515
2.742
2.987
2.093
2.285
2.493
2.718
2.962
2.075
2.266
2.472
2.695
2.937
2.057
2.246
2,450
2.672
2.912
2.039
2.226
2.429
2.649
2.887
2.021
2.207
2.408
2.626
2.862
2.003
2.187
2.387
2.603
2.838
1.985
2.168
2.367
2.581
2.813
1.968
2.149
2.346
2.559
2.790
-4
-3
-2
-1
-0
3.280
3.568
3.880
4.217
4.579
3.252
3.539
3.848
4.182
4.542
3.225
3.509
3.816
4.147
4.504
3.198
3.480
3.785
4.113
4.467
3.171
3,451
3.753
4.079
4,431
3.144
3,422
3.722
4.045
4.395
3.117
3.393
3.691
4.012
4.359
3.091
3.364
3.660
3.979
4.323
3.065
3.336
3.630
3.946
4.287
3.039
3.308
3.599
3.913
4.252
0
1
2
3
4
4.579
4.926
5.294
5.685
6.101
4.613
4.962
5.332
5.725
6.144
4.647
4.998
5.370
5.766
6.187
4.681
5.034
5.408
5.807
6.230
4.715
5.070
5.447
5.848
6.274
4.750
5.107
5,486
5.889
6.318
4.785
5.144
5.525
5.931
6.363
4.820
5.181
5.565
5.973
6.408
4.855
5.219
5.605
6.015
6.453
4.890
5.256
5.645
6.058
6.498
5
6
7
8
9
6.543
7.013
7.513
8.045
8.609
6.589
7.062
7.565
8.100
8.668
6.635
7.111
7.617
8.155
8.727
6.681
7.160
7.669
8.211
8.786
6.728
7.209
7.722
8.267
8.845
6.775
7.259
7.775
8.323
8.905
6.822
7.309
7.828
8.380
8.965
6.869
7.360
7.882
8.437
9.025
6.917
7.411
7.936
8,494
9.086
6.965
7.462
7.990
8.551
9.147
10
11
12
13
14
9.209
9.844
10.518
11.231
11.987
9.271
9.910
10.588
11.305
12.065
9.333
9.976
10.658
11.379
12.144
9.395
10.042
10.728
11.453
12.223
9.458
10.109
10.799
11.528
12.302
9.521
10.176
10.870
11.604
12.382
9.585
10.244
10.941
11.680
12.462
9.649
10.312
11.013
11.756
12.543
9.714
10.380
11.085
11.833
12.624
9.779
10.449
11.158
11.910
12.706
15
16
17
18
19
12.788
13.634
14.530
15.477
16.477
12.870
13.721
14.622
15.575
16.581
12.953
13.809
14.715
15.673
16.685
13.037 13.121
13.898 13.987
14.809 14.903
15.871
15.772
16.789 . 16.894
13.205
14.076
14.997
15.971
16.999
13.290
14.166
15.092
16.771
17.105
13.375
14.256
15.188
16.171
17.212
13.461
14.347
15.284
16.272
17.319
13.547
14.438
15.380
16.374
17.427
20
21
22
23
24
17.535
18.650
19.827
21.068
22.377
17.644
18.765
19.948
21.196
22.512
17.753
18.880
20.070
21.324
22.648
17.863
18.996
20.193
21.453
22.785
18.085
19.231
20.440
21.714
23.060
18.197
19.349
20.565
21.845
23.198
18.309
19.468
20.690
21.977
23.337
18.422
19.587
20.815
22.110
23.476
18.536
19.707
20.941
22.243
23.616
-6
~
Liquid
water
17.974
19.113
20.316
21.583
22.922
"From R. H. Perry and C. H. Chilton, Eds.. Chemical Engineers' Handbook, 5th Edition. McGraw-Hill, New York, 1973,
Tables 3-3 and 3-5. Reprinted by permission of McGraw·Hill Book Co.
(continued)
Physical Property Tables
Table B.3 (Continued)
0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
25
26
27
28
29
23.756
25.209
26.739
28.349
30.043
23.897
25.359
26.897
28.514
30.217
24.039
25.509
27.055
28.680
30.392
24.182
25.660
27.214
28.847
30.568
24.326
25.812
27.374
29.015
30.745
24.471
25.964
27.535
29.184
30.923
24.617
26.117
27.696
29.354
31.102
24.764
26.271
27.858
29.525
31.281
24.912
26.426
28.021
29.697
31.461
25.060
26.582
28.185
29.870
31.642
30
31
32
33
34
31.824
33.695
35.663
37.729
39.898
32.007
33.888
35.865
37.942
40.121
32.191
34.082
36.068
38.155
40.344
32.376
34.276
36.272
38.369
40.569
32.561
34.471
36.477
33.584
40.796
32.747
34.667
36.683
38.801
41.023
32.934
34.864
36.891
38.018
41.251
33.122
35.062
37.099
39.237
41.480
33.312
35.261
37.308
39.457
41.710
33.503
35.462
37.518
39.677
41.942
35
36
37
38
39
42.175
44.563
47.067
49.692
52.442
42.409
44.808
47.324
49.961
52.725
42.644
45.054
47.582
50.231
53.009
42.880
45.301
47.841
50.502
53.294
43.117
45.549
48.102
50.774
53.580
43.355
45.799
48.364
51.048
53.867
43.595
46.050
48.627
51.323
54.156
43.836
46.302
48.891
51.600
54.446
44.078
46.556
49.157
51.879
54.737
44.320
46.811
49.424
52.160
55.030
40
41
42
43
44
55.324
58.34
61.50
64.80
68.26
55.61
58.65
61.82
65.14
68.61
55.91
58.96
62.14
65.48
68.97
56.21
59.27
62.47
65.82
69.33
56.51
59.58
62.80
66.16
69.69
56.81
59.90
63.13
66.51
70.05
57.11
60.22
63.46
66.86
70.41
57.41
60.54
63.79
67.21
70.77
57.72
60.86
64.12
67.56
71.14
58.03
61.18
64.46
67.91
71.51
45
46
47
48
49
71.88
75.65
79.60
83.71
88.02
72.25
76.04
80.00
84.13
88.46
72.62
76.43
80.41
84.56
88.90
72.99
76.82
80.82
84.99
89.34
73.36
77.21
81.23
85.42
89.79
73.74
77.60
81.64
85.85
90.24
74.12
78.00
82.05
86.28
90.69
74.50
78.40
82.46
86.71
91.14
74.88
78.80
82.87
87.14
91.59
75.26
79.20
83.29
87.58
92.05
0
1
2
3
4
5
6
7
8
9
92.51
149.38
233.7
355.1
97.20
156.43
243.9
369.7
102.09
163.77
254.6
384.9
107.20
171.38
265.7
400.6
112.51
179.31
277.2
416.8
118.04
187.54
289.1
433.6
123.80
196.09
301.4
450.9
129.82
204.96
314.1
468.7
136.08
214.17
327.3
487.1
142.60
223.73
3<!1.0
506.1
0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
90
91
92
93
94
525.76
546.05
566.99
588.60
610.90
527.76
548.11
569.12
590.80
613.17
529.77
550.18
571.26
593.00
615.44
531.78
552.26
573.40
595.21
617.72
533.80
554.35
575.55
597.43
620.01
535.82
556.44
577.71
599.66
622.31
537.86
558.53
579.87
601.89
624.61
539.90
560.64
582.04
604.13
626.92
541.95
562.75
584.22
606.38
629.24
544.00
564.87
586.41
608.64
631.57
95
96
97
98
99
100
101
633.90
657.62
682.07
707.27
733.24
760.00
787.57
636.24
660.03
684.55
709.83
735.88
762.72
790.37
938.59
662.45
687.04
712.40
738.53
765.45
793.18
640.94
664.88
689.54
714.98
741.18
768.19
796.00
643.30
667.31
692.05
717.56
743.85
770.93
798.82
645.67
669.75
694.57
720.15
746.52
773.68
801.66
648.05
672.20
697.10
722.75
749.20
776.44
804.50
650.43
674.66
699.63
725.36
751.89
779.22
807.35
652.82
677.12
702.17
727.98
754.58
782.00
810.21
655.22
679.69
704.71
730.61
757.29
784.78
813.08
T(°C)
TeC)
50
60
70
80
TeC)
639
640
Appendix B
Table 8.4 Antoine Equation Constants a
IoglO P*
0=
A - T
B
+
C
•
p in mm Hg,
T in °C
Example: The vapor pressure of acetaldehyde at 25°C is determined as follows:
IOglO
p~
o(2SOC)
H
2
0=
8.00552 -
4
===>
P~2H~O(25°C)
0=
1600.017
25 + 291.809
Formula
Range Cc)
Acetaldehyde
Acetic acid
Acetic acid*
Acetic anhydride
Acetone
Acrylic acid
Ammonia*
Aniline
Benzene
n-Butane
i-Butane
I-Butanol
2-Butanol
I-Butene
Butyric acid
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chlorobenzene*
Chlorobenzene*
Chloroform
Chloroform*
Cyclohexane
Cyclohexanol
n-Decane
1-Decene
1,1-Dichloroethane
1,2-Dichloroethane
Dichloromethane
Diethyl ether
Diethyl ketone
Diethylene glycol
Dimethyl ether
Dimethylamine
N,N-Dimethylformamide
l,4-Dioxane
Ethanol
Ethanolamine
Ethyl acetate
Ethyl acetate*
Ethyl chloride
Ethylbenzene
CZH4 0
CZH4 0 Z
-0.2 to 34.4
29.8 to 126.5
oto 36
62.8 to 139.4
-12.9 to 55.3
20.0 to 70.0
-83 to 60
102.6 to 185.2
14.5 to 80.9
-78.0 to -0.3
-85.1 to -11.6
89.2 to 125.7
72.4 to 107.1
-77.5 to -3.7
20.0 to 150.0
3.6 to 79.9
14.1 to 76.0
62.0 to 131.7
oto 42
42 to 230
-10.4 to 60.3
-30 to 150
19.9 to 81.6
93.7 to 160.7
94.5 to 175.1
86.8 to 171.6
-38.8 to 17.6
-30.8 to 99.4
-40.0 to 40
-60.8 to 19.9
56.5 to 111.3
130.0 to 243.0
-78.2 to -24.9
-71.8 to 6.9
30.0 to 90.0
20.0 to 105.0
19.6 to 93.4
65.4 to 170.9
15.6 to 75.8
-20 to 150
-55.9 to 12.5
56.5 to 137.1
CZHdO:
NH3
C6H7 N
C6 H 6
n-C 4 H lO
i -C4 H lO
C4 H lO O
C4 H lO O
C4 H s
C4 HSO z
CS z
CCl 4
C6 H s Cl
C6 H sCl
C6 H sCl
CHCh
CHCh
C6 H 12
C6 H 12 0
n-ClOH n
ClOH zo
CzH 4 Clz
C:H 4 CI
CHzClz
C4 H lO O
CSHlOO
C4H lO O Z
CZH60
CZH7 N
C 3 H 7 NO
C 4 H sO z
CzH~O
C ZH 7 NO
C4 H sO z
C4 Hg Oz
CzHsCl
CSH lO
2.9551
1OZ.9SS1 = 902 mm Hg
Compound
C4 H6 0 3
C3 H6 0
C3 H4 0 Z
0=
A
B
c
8.00552
7.38782
7.18807
7.14948
7.11714
5.65204
7.55466
7.32010
6.89272
6.82485
6.78866
7.36366
7.20131
6.53101
8.71019
6.94279
6.87926
6.97808
7.10690
6.94504
6.95465
6.90328
6.84941
6.25530
6.95707
6.95433
6.97702
7.02530
7.40916
6.92032
7.02529
7.63666
6.97603
7.08212
6.92796
7.43155
8.11220
7.45680
7.10179
7.09808
6.98647
6.95650
1600.017
1533.313
1416.7
1444.718
1210.595
648.629
1002.711
1731.515
1203.531
943.453
899.617
1305.198
1157.000
810.261
2433.014
1169.110
1212.021
1431.053
1500.0
1413.12
1170.966
1163.03
1206.001
912.866
1503.568
1497.527
1174.022
1271.254
1325.938
1064.066
1310.281
1939.359
889.264
960.242
1400.869
1554.679
1592.864
1577.670
1244.951
1238.710
1030.007
1423.543
291.809
222.309
225
199.817
229.664
154.683
247.885
206.049
219.888
239.711
241.942
173.427
168.279
228.066
255.189
241.593
226.409
217.550
224.0
216.0
226.232
227.4
223.148
109.126
194.738
197.056
229.060
222.927
252.616
228.799
214.192
162.714
241.957
221.667
196.434
240.337
226.184
173.368
217.881
217.0
238.612
213.091
Adapted from T. Boublik, V. Fried, and E. Hala, The Vapour Pressures of Pure Substances, Elsevier,
Amsterdam, 1973. If marked with an asterisk (*), constants are from Lange's Handbook ofChemistry,
9th Edition, Handbook Publishers, Inc., Sandusky, OH, 1956.
a
(continued)
Physical Property Tables
Table 8.4 (Continued)
Compound
Formula
Range (0C)
Ethylene glycol
Ethylene oxide
1,2-Ethylenediamine
Formaldehvde
Formic acid
Glvcerol
n-Heptane
i-Heptane
I-Heptene
n-Hexane
i-Hexane
I-Hexene
Hydrogen Cyanide
Methanol
Methanol*
Methyl acetate
Methyl bromide
Methyl chloride
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl methacrylate
Methylamine
Methylcyclohexane
Naphthalene
Nitrobenzene
Nitromethane
n-Nonane
I-Nonene
n-Octane
i-Octane
1-0ctene
n-Pentane
i-Pentane
I-Pentanol
I-Pentene
Phenol
I-Propanol
2-Propanol
Propionic acid
Propylene oxide
Pyridine
Styrene
Toluene
1.1,1-Trichloroethane
1.1,2-Trichloroethane
Trichloroethylene
Vinyl acetate
Water*
Water*
til-Xylene
o-Xylene
p-Xylene
C ZH 6 0 Z
C ZH 40
CzHsN z
HCHO
CHzO z
C 3H H0 3
n-C 7 H!6
i -C7 H 16
C 7 H 14
n-C 6 H 14
i -C6 H!4
C 6H 1Z
HCN
CH,OH
CH 3 0H
C 3H 6O Z
CH 3 Br
CH3 Cl
C 4H s O
C 6H 12 O
CsHsO z
CHsN
C 7 H 14
CIOHs
C6 H s NO z
CH 3 NO z
n-CqH zo
C9 H 1S
n-CSH 1S
i -CSH 1S
C SH 16
n-C SH 12
i -CSH 12
CSHlZO
CSH IO
C6 H 6O
C3 H s O
C 3 H sO
C3H 6 O Z
C 3H 6 O
CsHsN
CsH s
C7 H s
C 2H 3 Ch
C 2H 3 Cl3
C zHCl 3
C4H 6O Z
H 2O
H2O
m-CSH IO
o-C SH lO
p-C S H lO
50.0 to 200.0
0.3 to 31.8
26.5 to 117.4
-109.4 to - 22.3
37.4 to 100.7
183.3 to 260.4
25.9 to 99.3
18.5 to 90.9
21.6 to 94.5
13.0 to 69.5
12.8 to 61.1
15.9 to 64.3
-16.4 to 46.2
14.9 to 83.7
-20 to 140
1.8 to 55.8
-70.0 to 3.6
-75.0 to 5.0
42.8 to 88.4
21.7 to 116.2
39.2 to 89.2
-83.1 to -6.2
25.6 to 101.8
80.3 to 179.5
134.1 to 210.6
55.7 to 136.4
70.3 to 151.8
66.6 to 147.9
52.9 to 126.6
41.7 to 118.5
44.9 to 122.2
13.3 to 36.8
16.3 to 28.6
74.7 to 156.0
12.8 to 30.7
107.2 to 181.8
60.2 to 104.6
52.3 to 89.3
72.4 to 128.3
- 24.2 to 34.8
67.3 to 152.9
29.9 to 144.8
35.3 to 111.5
-5.4 to 16.9
50.0 to 113.7
17.8 to 86.5
21.8 to 72.0
o to 60
60 to L50
59.2 to 140.0
63.5 to 145.4
58.3 to 139.3
A
B
C
8.09083
8.69016
7.16871
7.19578
7.58178
6.16501
6.90253
6.87689
6.91381
6.88555
6.86839
6.86880
7.52823
8.08097
7.87863
7.06524
7.09084
7.09349
7.06356
6.67272
8.40919
7.33690
6.82827
7.03358
7.11562
7.28166
6.93764
6.95777
6.91874
6.88814
6.93637
6.84471
6.73457
7.18246
6.84268
7.13301
7.74416
7.74021
7.71423
7.01443
7.04115
7.06623
6.95805
8.64344
6.95185
6.51827
7.21010
8.10765
7.96681
7.00646
7.00154
6.98820
2088.936
2005.779
1336.235
970.595
1699.173
1036.056
1267.828
1238.122
1265.120
1175.817
1151.401
1154.646
1329.49
1582.271
1473.11
1157.630
1046.066
948.582
1261.339
1168.408
2050.467
1011.532
1273.673
1756.328
1746.586
1446.937
1430.459
1437.862
1351.756
1319.529
1355.779
1060.793
992.019
1287.625
1043.206
1516.790
1437.686
1359.517
1733.418
1086.369
1373.799
1507.434
1346.773
2136.621
1314.410
1018.603
1296.130
1750.286
1668.210
1460.183
1476.393
1451.792
203.454
334.765
194.366
244.124
260.714
28.097
216.823
219.783
220.051
224.867
228.477
226.046
260.418
239.726
230.0
219.726
244.914
249.336
221.969
191.944
274.369
233.286
221.723
204.842
201.783
227.600
201.808
205.814
209.100
211.625
213.022
231.541
229.564
161.330
233.344
174.954
198.463
197.527
217.724
228.594
214.979
214.985
219.693
302.769
209.197
192.731
226.655
235.000
228.000
214.827
213.872
215.111
641
642
Appendix B
Table B.5 Properties of Saturated Steam: Temperature Table a
V(m 3 /kg)
T(°C)
P(bar)
Water
0.01
2
4
6
8
0.00611
0.00705
0.00813
0.00935
0.01072
0.001000
0.001000
0.001000
0.001000
0.001000
10
12
14
16
18
0.01227
0.01401
0.01597
0.01817
0.02062
20
22
24
25
26
28
Steam
O(kJ/kg)
H(kJ/kg)
Water
Steam
Water
Evaporation
Steam
206.2
179.9
157.3
137.8
121.0
zero
8.4
16.8
25.2
33.6
2375.6
2378.3
2381.1
2383.8
2386.6
+0.0
8.4
16.8
25.2
33.6
2501.6
2496.8
2492.1
2487.4
2482.6
2501.6
2505.2
2508.9
2512.6
2516.2
0.001000
0.001000
0.001001
0.001001
0.001001
106.4
93.8
82.9
73.4
65.1
42.0
50.4
58.8
67.1
75.5
2389.3
2392.1
2394.8
2397.6
2400.3
42.0
50.4
58.8
67.1
75.5
2477.9
2473.2
2468.5
2463.8
2459.0
2519.9
2523.6
2527.2
2530.9
2534.5
0.0234
0.0264
0.0298
0.0317
0.0336
0.0378
0.001002
0.001002
0.001003
0.001003
0.001003
0.001004
57.8
51.5
45.9
43.4
41.0
36.7
83.9
92.2
100.6
104.8
108.9
117.3
2403.0
2405.8
2408.5
2409.9
2411.2
2414.0
83.9
92.2
100.6
104.8
108.9
117.3
2454.3
2449.6
2444.9
2442.5
2440.2
2435.4
2538.2
2541.8
2545.5
2547.3
2549.1
2552.7
30
32
34
36
38
0.0424
0.0475
0.0532
0.0594
0.0662
0.001004
0.001005
0.001006
0.001006
0.001007
32.9
29.6
26.6
24.0
21.6
125.7
134.0
142.4
150.7
159.1
2416.7
2419.4
2422.1
2424.8
2427.5
125.7
134.0
142.4
150.7
159.1
2430.7
2425.9
2421.2
2416.4
2411.7
2556.4
2560.0
2563.6
2567.2
2570.8
40
42
44
46
48
0.0738
0.0820
0.0910
0.1009
0.1116
0.001008
0.001009
0.001009
0.001010
0.001011
19.55
17.69
16.04
14.56
13.23
167.4
175.8
184.2
192.5
200.9
2430.2
2432.9
2435.6
2438.3
2440.9
167.5
175.8
184.2
192.5
200.9
2406.9
2402.1
2397.3
2392.5
2387.7
2574.4
2577.9
2581.5
2585.1
2588.6
50
52
54
56
58
0.1234
0.1361
0.1500
0.1651
0.1815
0.001012
0.001013
0.001014
0.001015
0.001016
12.05
10.98
10.02
9.158
8.380
209.2
217.7
226.0
234.4
242.8
2443.6
2446
2449
2451
2454
209.3
217.7
226.0
234.4
242.8
2382.9
2377
2373
2368
2363
2592.2
2595
2599
2602
2606
60
62
64
66
68
0.1992
0.2184
0.2391
0.2615
0.2856
0.001017
0.001018
0.001019
0.001020
0.001022
7.678
7.043
6.468
5.947
5.475
251.1
259.5
267.9
276.2
284.6
2456
2459
2461
2464
2467
251.1
259.5
267.9
276.2
284.6
2358
2353
2348
2343
2338
2609
2613
2616
2619
2623
"From R. W. Haywood, Thermodynamic Tables in Sf (Metric) Units, Cambridge University Press,
London, 1968. V = specific volume, 0 = specific internal energy, and f1 = specific enthalpy. Note:
kJ/kg X 0.4303 = Btu/Ibm'
(continued)
Physical Property Tables
Table 8.S (Continued)
V(m 3 /kg)
B(kJ/kg)
U(kJ/kg)
P(bar)
Water
Steam
Water
Steam
Water
Evaporation
Steam
70
72
74
76
78
0.3117
0.3396
0.3696
0.4019
0.4365
0.001023
0.001024
0.001025
0.001026
0.001028
5.045
4.655
4.299
3.975
3.679
293.0
301.4
309.8
318.2
326.4
24fi9
2472
2474
2476
2479
293.0
301.4
309.8
318.2
326.4
2333
2329
2323
2318
2313
2626
2630
2633
2636
2639
80
82
84
86
88
0.4736
0.5133
0.5558
0.6011
0.6495
0.001029
0.001030
0.001032
0.001033
0.001034
3.408
3.161
2.934
2.727
2.536
334.8
343.2
351.6
360.0
368.4
24iQ
2484
2487
2489
2491
334.9
343.3
351.7
360.1
368.5
2308
2303
2298
2293
2288
2643
2646
2650
2653
2656
90
92
94
96
98
100
102
0.7011
0.7560
0.8145
0.8767
0.9429
1.0131
1.0876
0.001036
0.001037
0.001039
0.001040
0.001042
0.001044
0.001045
2.361
2.200
2.052
1.915
1.789
1.673
1.566
376.9
385.3
393.7
402.1
410.6
419.0
427.1
2493
2496
2499
2501
2504
2507
2509
377.0
385.4
393.8
402.2
410.7
419.1
427.5
2282
2659
2662
2666
2669
2673
2676
2679
TCC)
2277
2272
2267
2262
2257
2251
643
0'1
t
?
'U
'U
~
::l
0-
x·
Table B.6 Properties of Saturated Steam: Pressure Table"
V(mJ/kg)
P(bar)
0.00611
0.008
OJ
O(kJ/kg)
H(kJ/kg)
TCCC)
Water
Steam
Water
Steam
Water
Evaporation
Steam
0.01
3.8
O.OOlOOO
206.2
159.7
zero
15.8
2375.6
2380.7
+O,()
0.001000
15.8
2501.6
2492.6
2501.6
2508.5
0.010
0.012
0.014
0.016
0.018
7.0
9.7
12.0
14.0
15.9
0.001000
0.001000
0.001000
0.001001
0.001001
129.2
108.7
93.9
82.8
74.0
29.3
40.6
50.3
58.9
66.5
2385.2
2388.9
2392.0
2394.8
2397.4
29.3
40.6
50.3
58.9
66.5
2485.0
2478.7
2473.2
2468.4
2464.1
2514.4
2519.3
2523.5
2527.3
2530.6
0.020
0.022
0.024
0.026
0.028
17.5
19.0
20.4
21.7
23.0
0.001001
0.001 002
0.001002
0.001002
0.001002
67.0
61.2
56.4
52.3
48.7
73.5
79.8
85.7
91.1
96.2
2399.6
2401.7
2403.6
2405.4
2407.1
73.5
79.8
85.7
91.1
96.2
2460.2
2456.6
2453.3
2450.2
2447.3
2533.6
2536.4
2539.0
2541.3
2543.6
0.030
0.035
0.040
0.045
0.050
24.1
26.7
29.0
31.0
32.9
0.001 003
0.001003
0.001004
0.001005
0.001005
45.7
39.5
34.8
31.1
28.2
101.0
111.8
121.4
130.0
137.8
2408.6
2412.2
2415.3
2418.1
2420.6
1010
111.8
121.4
130.0
137.8
2444.6
2438.5
2433.1
2428.2
2423.8
2545.6
2550.4
2554.5
2558.2
2561.6
0.060
0.070
0.080
0.090
0.10
36.2
39.0
41.5
43.8
45.8
0.001006
0.001007
O.Om008
0.001009
0.001010
23.74
20.53
18.10
16.20
14.67
151.5
163.4
173.9
183.3
191.8
2425.1
2428.9
2432.3
2435.3
2438.0
151.5
163.4
173.9
183.3
191.8
2416.0
2409.2
2403.2
2397.9
2392.9
2567.5
2572.6
2577.1
2581.1
2584.8
0.11
0.12
0.13
0.14
47.7
49.4
51.1
52.6
1l.()0 10 I I
0.001012
0.001013
0.001013
13.42
12.36
11.47
10.69
109.7
206.9
213.7
220.0
2440.5
2442.8
2445.0
2447.0
100.7
206.9
213.7
220.0
2388.4
2384.3
2380.4
2376.7
2588.1
2591.2
2594.0
2596.7
8045
8.03
226.0
231.6
236.9
242.0
246.8
2448.9
2450.6
2452.3
2453.9
245504
226.0
231.6
236.9
242.0
246.8
2373.2
2370.0
2366.9
2363.9
2361.1
2599.2
2601.6
2603.8
2605.9
2607.9
0.00 I0 17
o.O() 10 I8
0.00 I0 IlJ
0.001020
0.001021
7.65
7.00
6.45
5.98
5.58
251.5
200. I
268.2
275.6
282.7
2456.9
2459.6
2462.1
2464.4
2466.5
251.5
260.1
268.2
275.7
282.7
2358.4
2353.3
2348.6
2344.2
2340.0
2609.9
2613.5
2616.8
2619.9
2622.7
0.45
0.50
69.1
72.7
75.9
78.7
81.3
OJl01022
0.001025
0.001027
0.001028
O.OO1OJO
5.23
4.53
3.99
3.58
3.24
289.3
304.3
317.6
329.6
340.5
2468.6
2473.1
2477.1
2480.7
2484.0
289.3
304.3
317.7
329.6
340.6
2336.1
2327.2
2319.2
2312.0
2305.4
2625.4
2631.5
2636.9
2641.7
2646.0
0.55
0.60
0.65
0.70
0.75
83.7
86.0
88.0
90.0
91.8
0.001032
0.001OJ3
0.001OJ5
0.001036
0.001OJ7
2.96
2.73
2.53
2.36
2.22
350.6
359.9
368.5
376.7
38404
2486.9
2489.7
2492.2
2494.5
2496.7
350.6
359.9
368.6
376.8
384.5
2299.3
2293.6
2288.3
2283.3
2278.6
2649.9
2653.6
2656.9
2660.1
2663.0
0.80
0.85
0.90
0.95
1.00
1.01325
(1 atm)
93.5
95.2
96.7
98.2
99.6
100.0
0.001039
0.001040
0.001041
0.001042
0.001043
0.001044
2.087
1.972
1.869
1.777
1.694
1.673
391.6
398.5
405.1
411.4
417.4
419.0
2498.8
2500.8
2502.6
2504.4
2506.1
2506.5
391.7
398.6
405.2
411.5
417.5
419.1
2274.1
2269.8
2265.6
2261.7
2257.9
2256.9
2665.8
2668.4
2670.9
2673.2
2675.4
2676.0
0.15
0.16
0.17
0.18
0.19
54.0
55.3
56.6
57.8
59.0
0.001014
0.001015
OJJOlO15
0.001016
0.001017
10.02
0.20
0.22
0.24
0.26
0.28
60.1
02.2
64.1
65.9
67.5
0.30
0.35
0040
9043
8.91
'"0
::r-
'-<:
(fl
D'
"From R. W. Haywood, Thermodynamic Tables in SI (Metric) Unitj; Cambridge University Press, London, 1968.
internal energy, and fl = specific enthalpy. Note: kJ/kg X 0.4303 = Btu/Ibm'
V
= specific volume,
l! = specific
(continued)
2-
'"0
'"1
0
'U
(1)
'"1
....
'<
p;1
0"
~
(fl
.,.
Q'I
VI
0'1
~
;p
'0
'0
~
Table B.6 (Continued)
::l
0-
~.
V(m 3 /kg)
U(kJ/kg)
H(kJ/kg)
ttl
P(bar)
T(°C)
Water
Steam
Water
Steam
Water
Evaporation
Steam
1.1
1.2
1.3
1.4
102.3
104.8
107.1
109.3
0.001046
0.001048
0.001049
0.001051
1.549
1.428
1.325
1.236
428.7
439.2
449.1
458.3
2509.2
2512.1
2514.7
2517.2
428.8
439.4
449.2
45k.4
2250.8
2244.1
2237.8
2231.9
2679.6
2683.4
2687.0
2690.3
1.5
1.6
1.7
1.8
1.9
111.4
113.3
115.2
116.9
118.6
0.001053
0.001055
0.001056
0.001058
0.001059
1.159
1.091
1.031
0.977
0.929
467.0
475.2
483.0
490.5
497.6
2519.5
2521.7
2523.7
2525.6
2527.5
467.1
475.4
483.2
490.7
497.8
2226.2
2220.9
2215.7
2210.8
2206.1
2693.4
2696.2
2699.0
2701.5
2704.0
2.0
2.2
2.4
2.6
2.8
120.2
123.3
126.1
128.7
131.2
0.001061
0.001064
0.001066
0.001069
0.001071
0.885
0.810
0.746
0.693
0.646
504.5
517.4
529.4
540.6
551.1
2529.2
2532.4
2535.4
2538.1
2540.6
504.7
517.6
529.6
540.9
551.4
2201.6
2193.0
2184.9
2177.3
2170.1
2706.3
2710.6
2714.5
2718.2
2721.5
3.0
3.2
3.4
3.6
3.8
133.5
135.8
137.9
139.9
141.8
0.001 074
0.001076
0.001078
0.001080
0.001082
0.606
0.570
0.538
0.510
0.485
561.1
570.6
579.6
588.1
596.4
2543.0
2545.2
2547.2
2549.2
2551.0
561.4
570.9
579.9
588.5
596.8
2163.2
2156.7
2150.4
2144.4
2138.6
2724.7
2727.6
2730.3
2732.9
2735.3
4.0
4.2
4.4
4.6
4.8
143.6
145.4
147.1
148.7
150.3
0.001084
0.001086
0.001088
0.001089
0.001091
0.462
0.442
0.423
0.405
0.389
604.2
611.8
619.1
626.2
633.0
2552.7
2554.4
2555.9
2557.4
2558.8
604.7
612.3
619.6
626.7
633.5
2133.0
2127.5
2122.3
2117.2
2112.2
2737.6
2739.8
2741.9
2743.9
2745.7
5.0
5.5
6.0
6.5
7.0
151.8
155.5
158.8
162.0
165.0
0.001093
0.001097
0.001101
0.001105
0.001108
0.375
0.342
0.315
0.292
0.273
639.6
655.2
669.8
683.4
696.3
2560.2
2563.3
2566.2
2568.7
2571.1
MO. 1
655.8
670.4
684.1
697.1
2107.4
2095.9
2085.0
2074.7
2064.9
2747.5
2751.7
2755.5
2758.9
2762.0
7.5
8.0
8.5
9.0
9.5
10.0
167.8
170.4
172.9
175.4
177.7
179.9
0.001112
0.001115
0.001118
0.001 121
(1.001124
0.f)D1127
0.2554
0.2403
D.2268
D.2148
D.2040
0.1943
708.5
720.0
731.1
741.6
751.8
761.5
2573.3
2575.5
2577.1
2578.8
2580.4
2581.9
709.3
720.9
732.0
742.6
752.8
762.6
2055.5
2046.5
2037.9
2029.5
2021.4
2013.6
2764.8
2767.5
2769.9
2772.1
2774.2
2776.2
10.5
11.0
11.5
12.0
12.5
13.D
182.0
184.1
186.0
188.0
189.8
191.6
0.001 130
0.001133
0.001136
0.001 139
0.001 141
D.OOl 144
0.1855
0.1774
0.1700
0.1632
0.1569
D. I511
770.8
779.9
788.6
797.1
805.3
813.2
2583.3
2584.5
2585.8
2586.9
2588.0
2589.0
772.0
781.1
789.9
798.4
806.7
814.7
2005.9
1998.5
1991.3
1984.3
1977.4
I")7D.7
2778.0
2779.7
2781.3
2782.7
2784.1
2785.4
14
15
16
17
18
19
tlJ5.n
198.3
201.4
204.3
207.1
209.8
O.OO1141J
0.001 154
0.001159
0.001163
0.001 168
0.001172
0.1407
0.1317
0.1237
D.1166
0.1103
0.1047
828.5
842.9
856.7
869.9
882.5
894.6
251JO.8
2592.4
2593.8
2595.1
2596.3
2597.3
830.1
844.7
858.6
871.8
884.6
896.8
11J57.7
1945.2
1933.2
1921.5
1910.3
1899.3
2787.8
2789.9
2791.7
2793.4
2794.1)
2796.1
20
21
22
23
24
212.4
214.9
217.2
219.6
221.8
0.001 177
D.001l81
0.D01l85
0.001189
0.001193
0.0995
0.0949
0.0907
O.OK68
0.0832
906.2
917.5
928.3
938.9
9491
2598.2
2598.9
2599.6
2600.2
2600.7
9D8.6
920.0
931.0
941.6
951.9
1888.6
1878.2
1868.1
1858.2
1848.5
2797.2
2798.2
2799.1
2799.8
2800.4
25
26
27
28
29
223.9
226.0
228.1
230.n
232.0
0.001 197
(U101201
0.001205
O.OOI20l)
0.001213
0.0799
0.0769
0.0740
0.0714
0.0689
959.0
968.6
978.0
l)87. I
996.0
2601.2
2601.5
2601.8
2602.1
2602.3
962.0
971.7
981.2
9l)O.5
9l)9.5
1839.0
1829.6
1820.5
1811.5
1802.6
2800.9
2801.4
2801.7
2802.0
2802.2
30
32
34
36
38
233.8
237.4
240.9
244.2
247.3
0.001216
0.001224
0.001231
0.001238
OJl01245
0.0666
0.0624
0.0587
0.0554
OJ)524
1004.7
1021.5
1037.6
1053.1
1068.0
2602.4
2602.5
2602.5
2602.2
2601.9
1008.4
1025.4
1041.8
1057.6
1072.7
1793.9
1776.9
1760.3
1744.2
1728.4
2802.3
2802.3
2802.1
2801.7
2801.1
'"0
;:r
'-<
'"
(i
e:..
'"0
....
0
'0
(l)
....
.....
'-<
(continued)
p;l
cr-
(b
'"
0'1
~
-..I
C"I
~
>-
"0
"0
~
::l
0-
Table B.6 (Continued)
:;;;.
V(m 3 /kg)
ttl
H(kJ/kg)
U(kJ/kg)
P(bar)
TeC)
Water
Steam
Water
Steam
Walcr
Evaporation
Steam
40
42
44
46
48
250.3
253.2
256.0
258.8
201.4
0.001252
lI.lIlI 12)\)
lI.OO 1266
0.001272
0.001279
0.()4l)7
lI.lI471
0.0451
(l.O430
(1.0412
IOR2.4
IlI!J().3
1109.X
1122.9
1135.6
2001.3
2()lIlI. 7
259lJ.lJ
2599.1
25lJ8.1
101-:7.4
11150'1
1121-:.8
1141.8
1712.9
1()I)7.X
161-:2.lJ
1608.3
1053.9
21-:00,}
27 1)1).4
27lJX.3
27lJ7.1
2795.7
50
52
54
56
58
203.9
266.4
268.8
271.1
273.3
0.001286
0.001292
0.001299
0.001306
0.001312
0.03<)4
0.0378
0.0363
0.0349
0.0337
1148.0
1160.l
1171.9
1183.5
1194.7
25<)7.0
2595.9
2594.6
2593.3
2591.9
1154.5
1100.8
1178.<)
11 <)0.8
1202.3
1039.7
1625.7
1611.9
1598.2
1584.7
2794.2
2792.6
2790.8
2789.0
2787.0
60
62
64
66
68
275.6
277.7
279.8
281.8
283.8
0.001319
0.001325
0.001332
0.001338
0.001345
0.0324
0.0313
0.0302
0.0292
0.0283
1205.8
1216.6
1227.2
1237.6
1247.9
2590.4
2588.8
2587.2
2585.5
2583.7
1213.7
1224.8
1235.7
1246.5
1257.0
1571.3
1558.0
1544.9
1531.9
1518.9
2785.0
2782.9
2780.6
2778.3
2775.9
70
72
74
76
78
285.8
2R7.7
289.6
291.4
293.2
0,(101351
0.001358
0.001364
0.001371
0.001378
0.0274
0.0265
0.0257
0.0249
0.0242
1258.0
1267.9
1277.6
1287.2
1296.7
2581.8
2579.9
2578.0
2575.9
2573.8
1207.4
1277.6
1287.7
1297.0
1307.4
1506.0
1493.3
1480.5
1467.9
1455.3
2773.5
2770.9
2768.3
2765.5
2762.8
80
82
84
86
88
90
92
94
295.0
296.7
298.4
300.1
301.7
303.3
304.9
306.4
0.001384
0.001391
0.001398
0.001404
0.001411
0.001418
0.001425
0.001432
0.0235
0.0229
0.0222
0.0216
0.0210
0.02050
0.01996
0.01945
1306.0
1315.2
1324.3
1333.3
1342.2
1351.0
1359.7
1368.2
2571.7
2569.5
2567.2
2564.9
2562.6
2560.1
2557.7
2555.2
1317.1
1326.6
1336.1
1345.4
1354.6
1363.7
1372.8
1381.7
1442.8
1430.3
1417.9
1405.5
1393.2
1380.9
1368.6
1356.3
2759.9
2757.0
2754.0
2750.9
2747.8
2744.6
2741.4
2738.0
I III I .(l
96
98
308.0
309.5
0.001439
0.001446
0.01897
0.01849
1376.7
1385.2
2552.6
2550.0
1390.6
1399.3
1344.1
1331.9
2734.7
2731.2
100
105
ItO
115
120
311.0
314.6
318.0
321.4
324.6
0.001453
0.001470
0.001489
0.001507
0.001527
0.())804
0.01698
0.01601
0.01511
0.01428
1393.5
1414.1
1434.2
1454.0
1473.4
2547.3
2540.4
2533.2
2525.7
2517.8
1408.0
1429.5
1450.6
1471.3
1491.8
1319.7
1289.2
1258.7
1228.2
1197.4
2727.7
2718.7
2709.3
2699.5
2689.2
125
130
135
140
145
327.8
330.8
333.8
330.0
339.4
0.001547
0.001567
0.001588
O.flOlo11
0.001034
0.01351
O.(1I280
0.01213
(1.(11150
0.0 I090
1492.7
1511.6
1530.4
1549.1
1507.5
2509.4
2500.6
2491.3
2471.0
1512.0
1532.0
1551.9
1571.0
1591.3
1166.4
1135.0
1103.1
1070.7
1037.7
2678.4
2667.0
2655.0
2042.4
2029.1
ISO
155
160
165
170
342.1
344.8
347.3
349.8
352.3
0.00 I058
0.001683
O.(1017lO
0.001739
0.001770
0.01034
0.00981
0.00931
0.00883
0.00837
1580.1
1004.6
1023.2
1641.8
1661.6
2459.9
2448.2
2436.0
2423.1
2409.3
1611.0
1630.7
1650.5
1670.5
1691.7
1004.0
969.6
934.3
898.3
859.9
2615.0
2600.3
2584.9
2568.8
2551.6
175
180
185
190
195
354.6
357.0
359.2
361.4
363.6
0.001803
0.001840
0.001881
0.001926
0.001977
0.00793
0.00750
0.00708
0.00668
0.00628
16HI.H
1701.7
1721.7
1742.1
1763.2
2394.6
2378.9
2362.1
2343.8
2323.6
1713.3
1734.8
1756.5
1778.7
1801.8
820.0
779.1
736.6
692.0
644.2
2533.3
2513.9
2493.1
2470.6
2446.0
200
205
210
215
220
221.2
(Critical point)
365.7
367.8
369.8
371.8
373.7
374.15
0.00204
0.002l!
0.00220
0.00234
0.00267
0.00317
0.00588
0.00546
0.00502
0.00451
0.00373
0,(10317
1785.7
1810.7
1840.0
1878.6
1952
2038
2300.8
2274.4
2242.1
2198.1
2114
2038
1826.5
]853.9
1886.3
192K9
2011
2108
591.9
532.5
461.3
366.2
185
0
2418.4
2386.4
2347.6
2295.2
2196
2108
24~1.4
'l:l
::r
'<
'"C:;.
~
'l:l
'"1
0
"0
~
'"1
~
~
cr"
(D
'"
...
<:7\
~
650
Appendix B
Table B.7 Properties of Superheated Steama
P(bar)
Sat'd
Water
(Tsal.°C)
0.0
(-)
0.1
(45.8)
1.0
(99.6)
20
(212.4)
80
(295.0)
250
300
350
-
2642
2481
-
2689
2517
-
2784
2589
2880
2662
2978
2736
3077
2812
-
3177
2890
-
-
Ii
-
-
-
fl
191.8
191.8
0.00101
2584.8
2438.0
14.7
2593
2444
14.8
2640
2480
16.0
2688
2516
17.2
2783
2588
19.5
2880
2661
21.8
2977
2736
24.2
3077
2812
26.5
3177
2890
28.7
3406
340.6
0.00103
2646.0
2484.0
3.24
209.3
209.2
0.00101
313.9
313.9
0.00103
2683
2512
3.41
2780
2586
3.89
2878
2660
435
2979
2735
4.83
3076
2811
5.29
3177
2889
5.75
417.5
4175
0.00104
2675.4
2506.1
1.69
2093
209.2
0.00101
314.0
313.9
0.00103
2676
2507
1.69
2776
2583
1.94
2875
2658
2.17
2975
2734
2.40
3074
2811
2.64
3176
2889
2.87
640.1
639.6
0.00109
2747.5
2560.2
0.375
209.7
209.2
0.00101
3143
313.8
0.00103
419.4
418.8
0.00104
632.2
631.6
0.00109
2855
2643
0.425
2961
2724
0.474
3065
2803
0.522
3168
2883
0.571
762.6
761.5
0.00113
2776.2
2582
0.194
210.1
209.1
0.00101
314.7
313.7
0.00103
419.7
418.7
0.00104
632.5
631.4
0.00109
2827
2621
0.206
2943
2710
0.233
3052
2794
0.258
3159
2876
0.282
908.6
906.2
0.00118
2797.2
2598.2
0.09950
211.0
209.0
0.00101
315.5
313.5
0.00102
4205
418.4
0.00104
633.1
603.9
0.00109
852.6
850.2
0.00116
2902
2679
0.111
3025
2774
0.125
3139
2862
0.139
1087.4
1082.4
0.00125
28003
2601.3
0.04975
212.7
208.6
0.00101
317.1
313.0
0.00102
422.0
417.8
0.00104
634.3
630.0
0.00109
853.4
848.8
0.00115
1085.8
1080.8
0.00125
2962
2727
0.0588
3095
2829
0.0665
1213.7
1205.8
0.00132
2785.0
2590.4
0.0325
214.4
208.3
0.00101
318.7
312.6
0.00103
423.5
417.3
0.00104
635.6
629.1
0.00109
854.2
847.3
0.00115
1085.8
1078.3
0.00125
2885
2668
0.0361
3046
2792
0.0422
1317.1
13060
0.00139
2759.9
2571.7
0.0235
216.1
208.1
0.00101
3203
312.3
0.00102
425.0
416.7
0.00104
636.8
628.2
0.00109
855.1
845.9
0.00115
1085.8
1075.8
0.00124
2787
2593
0.0243
2990
2750
0.0299
1408.0
1393.5
0.00145
2727.7
2547.3
0.0181
217.8
207.8
0.00101
322.9
311.7
0.00102
426.5
416.1
0.00104
638.1
627.3
0.00109
855.9
W.4
0.00115
1085.8
1073.4
0.00124
1343.4
1329.4
0.00140
2926
2702
0.0224
1611.0
1586.1
0.00166
26150
24599
0.0103
222.1
207.0
0.00101
326.0
310.7
0.00102
430.3
414.7
0.00104
641.3
625.0
0.00108
858.1
841.0
0.00114
1086.2
1067.7
0.00123
1338.2
1317.6
0.00138
2695
2523
0.0115
1826.5
1785.7
0.00204
2418.4
2300.8
0.005875
226.4
206.3
0.00100
330.0
309.7
0.00102
434.0
413.2
0.00103
644.5
622.9
0.00108
860.4
837.7
0.00114
1086.7
1062.2
0.00122
1334.3
1307.1
0.00136
1647.1
1613.7
0.00167
2108
2037.8
0.00317
2108
2037.8
0.00317
228.2
206.0
0.00100
331.7
309.2
0.00102
435.7
412.8
0.00103
645.8
622.0
0.00108
861.4
8363
0.00114
1087.0
1060.0
0.00122
1332.8
1302.9
000135
1635.5
1600.3
0.00163
230.7
205.7
0.00100
334.0
308.7
0.00101
437.8
412.1
0.00103
647.7
620.8
0.00108
862.8
834.4
0.00113
1087.5
1057.0
0.00122
1331.1
1297.5
0.00135
1625.0
1585.0
0.00160
235.0
205.0
0.0009990
338.1
307.7
0.00101
441.6
410.8
0.00103
650.9
618.7
0.00107
865.2
831.3
0.00113
1088.4
1052.1
0.00121
1328.7
12887
0.00133
1609.9
1563.3
0.00155
251.9
202.4
0.0009911
354.2
304.0
0.00100
456.8
405.8
0.00102
664.1
611.0
0.00106
875.4
819.7
0.00111
1093.6
1034.3
0.00119
1323.7
1259.3
0.00129
1576.3
1504.1
0.00144
293.9
1965
0.0009737
394.3
295.7
0.0009852
495.1
395.1
0.001000
698.0
594.4
0.00104
903.5
7953
0.00108
1113.0
9990
0.00114
1328.7
1207.1
0.00122
15505
1419.0
0.00131
(;
If
(;
Ii
If
(;
fl
(;
If
(;
Ii
fi
(;
fl
(;
Ii
60
(275.6)
200
-
Ii
40
(250.3)
150
-
Ii
10
(179.9)
100
(;
Ii
5.0
(151.8)
Temperature CC)--->
75
50
If
Ii
0.5
(81.3)
Sat'd
Steam
If
(;
Ii
If
(;
Ii
100
(3110)
If
150
(342.1)
If
200
(365.7)
If
221.2(Pc )
(374.15)(T c )
If
250
If
(-)
(;
300
(-)
If
500
(-)
If
1000
(-)
If
(;
Ii
(;
Ii
(;
Ii
(;
Ii
Ii
(;
Ii
(;
Ii
(;
Ii
2595
2446
-
-
-
Adapted from R. W. Haywood, Thermodynamic Tables in Sf (Metric) Units, Cambridge University Press, London, 1968.
Water is a liquid in the enclosed region between 50°C and 350°C. fI = specific enthalpy (kJ/kg), 0 = specific internal energy
(kJ/kg), II = specific volume (mJ/kg). Note: kJ/kg x 0.4303 = Btu/Ibm'
(continued)
a
Physical Property Tables
Table 8.7 (Continued)
Temperature (OC)_
P(bar)
0.0
f!
(-)
0
0.1
(45.8)
0.5
(81.3)
1.0
(99.6)
5.0
(151.8)
10
(179.9)
20
(212.4)
40
(250.3)
60
(275.6)
Ii
f!
0
Ii
f!
r)
Ii
f!
r)
Ii
f!
r)
Ii
f!
r)
Ii
f!
r)
Ii
f!
r)
Ii
f!
r)
Ii
80
(295.0)
H
r)
Ii
100
(311.0)
H
r)
Ii
150
(342.1)
H
0
Ii
200
(365.7)
450
3384
3050
500
3497
3132
550
3597
3217
600
3706
3303
650
700
3280
2969
3816
3390
3929
3480
750
4043
3591
3280
2969
21.1
3279
2969
6.21
3384
3050
33.3
3383
3049
6.67
3489
3132
35.7
3596
3217
38.0
3706
3303
40.3
3816
3390
42.6
3929
3480
44.8
4043
3571
47.2
3489
3132
7.14
3596
3216
7.58
3705
3302
8.06
3i';16
3390
8.55
3929
3480
9.01
3278
2968
3.11
327:'
2964
0.617
3382
3049
3.33
3488
3132
3.57
3596
3216
3.80
3705
3302
4.03
3816
3390
4.26
3928
3479
4.48
3379
3045
0.664
3484
3128
0.711
3478
3124
0.353
3592
3213
0.758
3702
3300
0.804
3813
3388
0.850
3926
3477
0.897
3587
3210
0.377
3697
3296
0.402
3809
3385
0.424
3467
3115
0.175
3578
3202
0.188
3445
3100
0.0864
3422
3083
0.0566
3559
3188
0.0926
3539
3174
0.0609
3689
3290
0.200
3673
3278
0.0987
3657
3265
0.0652
3802
3379
0.211
3788
3368
0.105
3774
3357
0.0693
3923
3475
0.448
3916
3470
0.223
4043
3571
9.43
4042
3570
472
4040
3569
0.943
4038
3567
0.472
4032
3562
0.235
4021
3554
0.117
3399
3065
0.0417
3640
3252
0.0483
3375
3047
0.0328
3311
2999
0.D208
3241
2946
0.0148
3520
3159
0.0450
3500
3144
0.0356
3448
3105
0.0229
3394
3063
0.0166
3580
3207
0.0249
3210
2922
0.0130
3370
3045
0.0147
3166
2888
0.0111
3337
3019
0.0127
3516
3157
0.0162
3490
3137
0.0141
3759
3346
0.0515
3745
3335
0.0410
3708
3307
0.0267
3671
3278
0.197
3655
3265
0.0176
3085
2825
0.008680
2723
2529
0.003882
2316
2127
0.001893
3277
2972
0.0102
3021
2765
0.005112
2594
2369
0.002246
400
(Tsal.'C)
H
r)
221.2(P c )
Ii
f!
(374.15)(T c )
0
250
Ii
f!
(-)
0
300
Ii
f!
(-)
0
Ii
500
f!
(-)
r)
1000
Ii
f!
(-)
r)
Ii
3249
2946
0.151
3371
3041
0.330
3358
3031
0.163
3216
2922
0.0734
3331
3011
0.0799
3180
2896
0.0474
3303
2991
0.0521
3142
2867
0.0344
3274
2969
0.0382
3244
2946
0.0298
3160
2883
0.0185
3264
2958
0.307
3100
2836
0.0264
2975
2744
0.0157
2733
2553
0.008157
3064
2810
0.0127
3020
2776
0.0110
2582
2432
0.006013
2162
2077
0.002830
2954
2725
0.009174
2826
2623
0.006734
1878
1791
0.001726
2293
2169
0.002491
1798
1653
0.001446
2051
1888
0.001628
2820
2622
0.009950
3904
3460
0.111
3892
3451
0.0735
3879
3441
0.0547
3867
3431
0.0435
3835
3407
0.0286
4011
3545
0.0776
4000
3537
0.0578
3989
. 3528
0.0461
3804
3382
0.211
3935
3485
0.0225
3790
3371
0.0190
3923
3476
0.0202
3633
3248
0.0143
3772
3356
0.0166
3908
3463
0.0178
3443
3100
0.0114
3595
3218
0.0126
3740
3330
0.0136
3880
3441
0.0147
3248
2946
0.006112
3439
3091
0.007000
3610
3224
0.007722
3771
3350
0.008418
2857
2591
0.002668
3105
2795
0.003106
3324
3526
313t
0.003953
3623
3240
0.0383
3536
3172
0.0182
2971
0.003536
3962
3507
0.0304
651
652
Appendix B
Table B.8 Specific Enthalpies of Selected Gases: SI Units
H(kJ/mol)
Reference state: Gas, P ref = 1 atm, Tref = 25°C
T
Air
O2
N2
H2
CO
CO 2
H2 O
0
25
100
200
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
-0.72
0.00
2.19
5.15
8.17
11.24
14.37
17.55
20.80
24.10
27.46
30.86
34.31
37.81
41.34
44.89
48.45
-0.73
0.00
2.24
5.31
8.47
11.72
15.03
18.41
21.86
25.35
28.89
32.47
36.07
39.70
43.38
47.07
50.77
-0.73
0.00
2.19
5.13
8.12
11.15
14.24
17.39
20.59
23.86
27.19
30.56
33.99
37.46
40.97
44.51
48.06
-0.72
0.00
2.16
5.06
7.96
10.89
13.83
16.81
19.81
22.85
25.93
29.04
32.19
35.39
38.62
41.90
45.22
-0.73
0.00
2.19
5.16
8.17
11.25
14.38
17.57
20.82
24.13
27.49
30.91
34.37
37.87
41.40
44.95
48.51
-0.92
0.00
2.90
7.08
11.58
16.35
21.34
26.53
31.88
37.36
42.94
48.60
54.33
60.14
65.98
71.89
77.84
-0.84
0.00
....
1':;-1
~
..,..
6.01
9.57
13.23
17.01
20.91
24.92
29.05
33.32
37.69
42.18
46.78
51.47
56.25
61.09
Table B.9 Specific Enthalpies of Selected Gases:
American Engineering Units
H(B tu/lb-mole)
Reference state: Gas, Pret
=
1 atm, Tret
=
77°P
T
Air
O2
N2
H2
CO
CO 2
H 2O
32
77
100
200
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
-312
0
160
858
1563
2275
2993
3719
4451
5192
5940
6695
7459
8230
9010
9797
10590
11392
12200
13016
13837
14663
-315
0
162
875
1602
2342
3094
3858
4633
5418
6212
7015
7826
8645
9471
10304
11142
11988
12836
13691
14551
15415
-312
0
160
857
1558
2265
2976
3694
4418
5150
5889
6635
7399
8151
8922
9699
10485
11278
12080
12888
13702
14524
-310
0
159
848
1539
2231
2925
3621
4319
5021
5725
6433
7145
7861
8581
9306
10035
10769
11509
12254
13003
13759
-312
0
160
859
1564
2276
2994
3720
4454
5195
5945
6702
7467
8239
9021
9809
10606
11409
12220
13036
13858
14688
-394
0
206
1132
2108
3129
4192
5293
6429
7599
8790
10015
11263
12533
13820
15122
16436
17773
19119
20469
21840
23211
-361
0
185
996
1818
2652
3499
4359
5233
6122
7025
7944
8880
9831
10799
11783
12783
13798
14831
15877
16941
lR019
Physical Property Tables
Table B.10 Atomic Heat Capacities
for Kopp's Rule"
C"afl/(g-atom'°C)]
Element
Solids
Liquids
C
H
B
Si
0
F
P
S
All Others
7.5
9.6
12
18
20
24
25
29
31
31
33
11
16
17
21
23
26
26
"D. M. Himmelblau. Basic Principles and
Calculations in Chemical Engineering, 3rd
Edition. Prentice-Hall. Englewood Cliffs,
NJ, 1974. p. 270.
Table B.ll Integral Heats of Solution and Mixing at 25°C
r(mol H 2 0/mol solute)
0.5
1
1.5
2
3
4
5
10
20
25
30
40
50
100
200
500
1000
2000
5000
10000
50000
100000
500000
00
(i.lH')HCI(g)
( i.lHs)NaOH(s)
(.lH m )H 2 S0 4
kl/mol HCI
kllmol NaOH
kllmol H 2SO 4
-26.22
-48.82
-56.85
-61.20
-6·+.05
-69.49
-71.78
-28.87
-34.43
-37.74
-42.51
-42.84
-15.73
-28.07
-36.90
-41.92
-48.99
-54.06
-58.03
-67.03
-72.30
-72.59
-73.00
-73.26
-73.85
-74.20
-74.52
-74.68
-74.82
-74.93
-74.9lJ
-75.0X
-75.10
-42.72
-42.59
-42.51
-42.34
-42.26
-42.38
-42.47
-42.55
-42.68
-42.72
-42.80
-75.14
-42.89
-73.34
-73.97
-76.73
-78.57
-84.43
-87.07
-93.64
-95.31
-96.19
"From 1. C. Whitwell and R. K. Toner, COl/serl'ation of Mass and Energy. pp. 344-346.
Copyright © 1969 by McGraw-Hill, Inc. Used with permission of McGraw-Hili.
653