Name----------------------------------------------Date---------------------period--------------- Hess’s Law of Summation 1. B2H6(g) + 6 Cl2(g) BCl3(g) + 3 H2O(l) H3BO3(g) + 3 HCl(g) B2H6(g) + 6 H2O(l) 2 H3BO3(s) + 6 H2(g) 1/2 H2(g) + 1/2 Cl2(g) HCl(g) 2. 2 OF2(g) + 2 S(s) OF2(g) + H2O(l) O2(g) + 2 HF(g) SF4(g) + 2 H2O(l) 4 HF(g) + SO2(g) S(s) + O2(g) SO2(g) 2 BCl3(g) + 6 HCl(g) Ho=? Ho= -112.5 kJ/rx Ho= -493.4 kJ/rx Ho= -92.3 kJ/rx SO2(g) + SF4(g) Ho=? Ho= -276.6 kJ/rx Ho= -827.5 kJ/rx Ho= -296.9 kJ/rx 3. N2H4(l) + 2 H2O2(l) N2(g) + 4 H2O(l) Ho = -622.3 kJ/rx Ho= -285.8 kJ/rx Ho= -187.8 kJ/rx N2H4(l) + O2(g) N2(g) + 2 H2O(l) H2(g) + 1/2 O2(g) H2O(l) H2(g) + O2(g) H2O2(l) 4. P4O10(g) + 6 PCl5(g) 1/4 P4(s) + 3/2 Cl2(g) PCl3(g) P4(s) + 5 O2(g) P4O10(g) PCl3(g) + Cl2(g) PCl5(g) PCl3(g) + 1/2 O2(g) Cl3PO(g) : Ho=? 10 Cl3PO(g) Ho=? Ho= -306.4 kJ/rx Ho= -2967.3 kJ/rx Ho = -84.2 kJ/rx Ho= -285.7 kJ/rx 5. 2 SO2(g) + 2 P(s) + 5 Cl2(g) SOCl2(l) + H2O(l) SO2(g) + 2 HCl(g) PCl3(l) + 1/2 O2(g) POCl3(l) P(s) + 3/2 Cl2(g) PCl3(l) 4 HCl(g) + O2(g) 2 Cl2(g) + 2 H2O(l) 6. C3H8(g) + 5 O2(g) 3 C(s) + 4 H2(g) C3H8(g) C(s) + O2(g) CO2(g) H2(g) + 1/2 O2(g) H2O(g) 2 SOCl2(l) + 2 POCl3(l) DHo = +10.3 kJ/rx Ho= -325.7 kJ/rx DHo = -306.7 kJ/rx Ho= -202.6 kJ/rx 3 CO2(g) + 4 H2O(g) Ho=? Ho= -103.8 kJ/rx Ho= -393.5 kJ/rx Ho = -241.8 kJ/rx 7. 2 N2(g) + 5 O2(g) 2 N2O5(g) Ho= -571.6 kJ/rx Ho= -73.7 kJ/rx Ho= -348.2 kJ/rx 2 H2(g) + O2(g) 2 H2O(l) N2O5(g) + H2O(l) 2 HNO3(l) N2(g) + 3 O2(g) + H2(g) 2 HNO3(l) 8. C(s) + 2 H2(g) C(s) + O2(g) CO2(g) H2(g) + 1/2 O2(g) H2O(l) CO2(g) + 2 H2O(l) CH4(g) + 2 O2(g) Ho=? CH4(g) Ho=? DHo = -393.5 kJ/rx DHo= -285.8 kJ/rx Ho= +890.3 kJ/rx