phys. formulae – August 28, 2014 Cylindrical coords dV =rdrdφdz • b ~ ∇t=∂ r + 1 ∂φ [t]φ+∂ b r [t]b z [t]z r b d~ l=dr r b+rdφφ+dz z b SI Base Units 2 [t]+∂ 2 [t] ∇2 t= 1 ∂r [r∂r [t]]+ 12 ∂φ 2 z r r Length L⁄metre: path length of light in vacuum during • ∂z for polar/planar 1 ∂ [rv ]+ 1 ∂ [v ]+∂ [v ] ~ ∇·~ v = r z z dt = 1/299792458s. Mass M⁄kilogram: mass of an interr r r φ φ b φ=atan(y/x) b r −sφφ b y b national prototype. Time T⁄second: dt of 9192631770 x=rcφ • z=z • x=cφb • r=√x·x+y·y • rbb=cφx+sφ b z b 133 b y=sφb b r +cφφ φ=−sφx+cφ b y b Cs (hyperfine split, @ 0 K) ground state oscilla- y=rsφ z= Delta Function/Distrib. tions. Elec. Current I⁄ampere: produces 2E−7 N⁄m R ~ r d between two L = ∞, A = 0 wires 1 m apart in vacδ d (~ r ) = 1 d eik·~ d k (2π) cum. Thermo. Temp. Θ⁄kelvin: 1⁄273.16th the T of N Transforms triple point water. Amount of Substance ⁄mole: as ∞ ∞ R R ~ r d~ ~ r d many entities (atoms, molecules, e− , etc.) as there are f(~ k)eik·~ d k • F(~ r )e−ik·~ d~ r r ) = 1d/2 F(~ k) = 1d/2 f(~ (2π) −∞ (2π) −∞ 12 atoms in 12 g of ground state C. Luminous IntenCombinatorics sity J⁄candela: directional intensity of a monochromatic (remaining possible) N choose n N (f = 5.40E12 Hz) source with directional radiant inten- N P N·(N−1)···(N−n+1) N! N =2N . = n! (N • n n = sity 1⁄683 watt per steradian. n! " −n)! n=0 (order unimportant) Constants & Units Stirling’s Approx. Value(s) Base √ n! ≈ nn e−n √2πn (1 + 1/12n) ⇐⇒ n 1 me− 9.11E−31 kg (5.48E−4) · u M n −n 2πn (sqrt sometimes needed) n! ≈ n e mp− 1.67E−27 kg (1.01) ·u m M m n −n n! ∼ n e =⇒ ln n! ≈ n ln(n) − n mair (29.0) · u ≈ 43 N2 + 14 O2 M m⊗ 5.97E24 kg (3.60E51) · u M Integrals – (a,b > 0) b√ π R R 1.99E30 kg (3.33E5) · m⊗ M m 2n 2m 1 (x−a)(b−x)dx= π (√b−√a)2 1 1 2 • 0sin (x)cos (x)dx=β(n+2,m+2) M L2/T 2 Θ kB 1.38E−23 J⁄K 8.62E−5 eV⁄K ax ∞ 2 R M L2/T 2 ΘN R 8.31 J⁄mol K NA kB Γ((n+1)/2) ∞ R n −bx xne−bx dx= 1 n≥0 x e dx=n!/bn+1 n≥0 2 b(n+1)/2 1⁄N NA 6.02E23 1⁄mol ≈ 279 1⁄mol • 0 0 ∞ M L2/T h 6.23E−34 J·s 4.14E−15 eV·s R xn R 1 dx=Γ(n+1)ζ(n+1) n≥1 dx=−ln(1+e−x) 1 eV IT e 1.60E−19 C ex −1 ex +1 • 0 e2/4π◦ ~c α ≈ 1/137.036 – q ∞ ∞ R 2 R n x e~/2me dx=(1−1/2n)Γ(n+1)ζ(n+1) n≥1 e−ax dx= 1 π µB 5.79E−5 eV/T IL2 2 a ex +1 • −∞ 0 L3/T 2 M G 6.67E−11Nm2/kg2 – q q ∞ ∞ 2 R −ax2−2bx R 2/a σB 5.67E−8J/sm2K4 π2kB/60c2~3 e dx= 1 π eb xe−a(x−b) dx=b π 2 a a • −∞ −∞ M L/T 2 1 N 1kg m/s2 1(P a)m2 ∞ q R 2 −ax2 R 2π R π 1 π 2 2 2 2 x e dx= M L /T 1 J 1kg m /s 1N m,1C V a·b r)(~ b·b r) sin θdθdφ=4π(~ a·~ b)/3 2 a3 0 0 (~ • −∞ M L2/T 3 1J/s,1V A,1ΩA2 1 W 1kg m2/s3 2−z 2 R 2 2 zR cosθ − R R sinθ cosθdθ b√ √ = R 2 T 4 I 2/L2 M 1 F 1s4 A2/m2 kg 1 VJ2 ,1 CJ ,1 sH (R2+z2−2zR cosθ)3/2 z2 R2+z2−2zRcosθ • a2−x2 dx= πa 4 s Js a M L2/T 3 I 2 1 Ω 1kg m2/s3 A2 1V A ,1 C 2 ,1 F ∞ R xm dx Γ(n−q)|b|2(q−n) m+1 M L2/T 3 I 1 V 1kg m2/s3 A 1ΩA,1J/C ,1W/A 2 2 n = π sin(πq)Γ(1−q)Γ(n) q≡ 2 , 2n−m>1, m even. kg −∞(x +b ) M/T 2 I 1 T 1kg/s2 A 1 mJ2 A ,1 C s √ R R 2 dx √x √ dx =ln[x+ z 2+x2] = 1 AJ2 ,1Ωs,1 mAT M L2/T 2 I 2 1 H 1kg m2/s2 A2 (z 2+x2)3/2 z 2 z 2+x2 z 2 +x2 • ∞ q √ Math R −ar bq R b −1dx=b π −arcsin a − a(b−a) e sin(br)dr= 2 b 2 2 b b +a Def. As Circumference Area • 0 Shape a x ∞ R1 x2 +y 2 =r 2 Circle 2πr πr 2 √ sin(±|b|r)dr=±π/2 2 2 2 2 Ellipse ≈π[3a+3b− (3a+b)(a+3b)] πab n-Vol. n-Area 4πr 3/3 2 4πr √ 2 πhr 2/3 πr 2 [1+ √ 1+(h/r)√] ab[2+ 1+(2h/a)2 + 1+(2h/b)2 ] abh/3 2 π n/2 r n/Γ(1+n/2) 2π n/2 r n−1/Γ(n/2) x /a +y /b =1 Shape 3-sphere cone⊥ pyramid⊥ n-sphere 0 r • cos2(x)=(1+cos(2x))/2 cosh2 (x) − sinh2 (x) = 1 n lim 1+ x =ex n→∞ n n n lim 1+ x = x n n x→∞ ez = ∞ P zn n! n=0 • cos(x±y)=cos(x) cos(y)∓sin(x) sin(y) Series and Sums P∞ (−1)k+1 xk −1<x≤1 k=1 k • ln(1+x) = ln(x)+P∞ (−1)k+1 |x|>1 k=1 kxk N P N−1 if 1 xn = 1−x =⇒ 1−x |x| < 1 1−x n=0 N→∞ Coordinates, Vector Calculus R~ R H R H b (∇ ~ f)·d~ ~ AdV ~ ~ a l=f(~ b)−f(~ a) ~ ~ ~ ~ ∇· = A·d~ ~ a • • ∇×A·d~a= A·dl ~ b/ 2)=4πδ (3)(~) ∇( ∇2 (1/)=−4πδ (3)(~) ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ f) A·(B×C)=B·(C×A)=C·(A×B) ∇·(∇×A) = 0 = ∇×(∇ • ~×(B× ~ C)=( ~ ~ C) ~ B−( ~ ~ B) ~ C ~ ~ ×(∇ ~ ×A ~)=∇ ~ (∇· ~ A ~)−∇2A ~ A A· A· ∇ 1 b b ~ ∇t=∂ r + 1 ∂θ [t]θ+ ∂φ [t]φ r [t]b Spherical coords r r sin θ • b b dV =r 2 sin θdrdθdφ d~ l=dr r b+rdθ θ+r sin θdφφ h i 2 [t] ∇2 t= 12 ∂r r 2 ∂r [t] + 2 1 ∂ [sin θ∂θ [t]]+ 2 1 2 ∂φ r r sin θ θ r sin θ 1 1 1 2 ~ ∇·~ v = 2 ∂r [r vr ]+ ∂ sin θvθ ]+ ∂ [v ] r sin θ θ [ r sin θ φ φ r x=rcφsθ y=rsφsθ z=rcθ φ=atan(y/x) b b x=sθcφb b r +cθcφθ−sφ φ b b r b=sθcφx+sθsφ b y+cθ b z b b z=cθ b r b−sθ √θ θ=atan( x·x+y·y/z) φ=−sφx+cφ b y b √ r= x·x+y·y+z·z b r +cθsφθ+cφφ θ=cθcφx+cθsφ b y−sθ b z b • y=sθsφb •b b β(1, 1)=π β(1, 5)= 3π 2 2 • 23 23 π8 β(1, 3)= π β( , )= 2 2 2 2 2 8 β(x,y)=β(y,x)=Γ(x)Γ(y)/Γ(x+y) • • Classical Mech. Trigonometry Identities sin(x)=(eix−e−ix)/2i sin(2x)=2sin(x)cos(x) sinh(x)=(ex−e−x)/2 • • cos(2x)=1−2sin2(x) cos(x)=(eix+e−ix)/2 cosh(x)=(ex+e−x)/2 sin2(x)=(1−cos(2x))/2 sin(x±y)=sin(x) cos(y)±cos(x) sin(y) Misc Γ(1)=1 Γ(n)=(n−1)! ζ(3)≈1.202 • √ • ζ(2)=π2/6 ζ(4)=π4/90 Γ(1)= π 2 R Γ(x)=(x−1)Γ(x−1)= 0∞tx−1e−tdt r1+m2 ~ r2 mm ~ Gm1 m2 b ~=m1 ~ F= R µ= 1 2 s2=x2+y 2 m1+m2 m1+m2 − 2 • •~ • ds=√1+(∂xy)2 dx ~=∂ ~ ~ r=~ r1−~ r2 L r ×~ p ~ τ=~ r ×F t τ =~ ∂L = d ∂L m r)2−V(~ r ) T=m[(∂t ~ r)2+r 2 (∂t φ)2] ∂qi dt ∂[∂t qi] L=T−V = 2 (∂t ~ 2 • Polar Kinetic. Conserv. F’s., • & Inertial Frm. Pendulum ~g along Tb to cancel Tb ⊥ θb . Now Fnet = Project F −mg sin θ ≈ −mgθ. So ma =p−mgθ. Since sp= Lθ, g solve θ̈=− L θ → θ(t) = A sin( g/Lt) + B cos( g/Lt). p p ω 1 g/L and T = 2π L/g . Then, f = 2π = 2ω Light Interference: A cos(kr+ωt) Double slit: ∼ 2 point sources • Single slit: d = slit width • (I=2A)max: sin θ=nλ/d⇔n=0,±1,±2,.. (I=0)min: sin θ=nλ/2d⇔n=±1,±2,.. (I=0)min: sin θ=nλ/d⇔n=±1,±2,.. General: I(θ)=A(j0(dπ sin(θ)/λ))2 Special Relativity p T = [γ(v)−1]mc2 • γ(v) = 1/ 1−v 2/c2 b b fobs = fstat/(γ(v)(1−~ v · d/c)) with v b · d = cos θ. Scattering 0 Compton: (γ+{→γ +|) Inelastic, but ∼elastic. q hc 1) E-cons.: mc2 + hc m2 c4 + p2m0 c2 . λ = λ0 + 2) P -cons.: p ~γ + p ~ ~γ 0 +~ pm0 . Isolate p ~m0 , square. m =p h Substitute for p ~m0 : λ0−λ = 2 mc sin2 θ2 θ ← p ~γ·~ pγ 0 . Thompson: Compton, Eγ mc2 . (Elastic: {→{). 2 2R dσ = R4 ⇒ σ = R4 sinθdθdφ = πR2. Hard-sphere: dΩ Rutherford: (|+{→|+{). Elastic, Heavy target, Coulomb. dσ dΩ = (q1 q2 )2 (16π◦ T sin2 θ )2 2 T = mc2 (γ −1). (incoming kinetic) Thermo./Stat. Mech. work R V compression (other) 1. ∆U = Q + W • W = V f P (V )dV + Wo heat i ∂S 2. S ≡ kB ln Ω grows. Equilib. ⇒ ∂... = 0 {N,U,V,...}. 3. T→0 ⇒ CV →0; dS 0 (S6=0 b/c of ∆E=0 config.s!) P Thermo. Identity. dU = T dS −P dV + i µi dNi . µi 1 ∂S P ∂S ∂S = • = • T ∂U V,N T ∂V U,N T = − ∂N i i U,V i H = U + P V. Enthalpy: Eassemble & put in enviro. Reversible dV ⇒ quasistatic. (Note: H ⇐⇒ H !) • Q 6= 0 ⇒ irreversible. But if ∆T → 0 then ∆S ≈ 0 so “infinitesimal” Q is ∼reversible. • Quasistatic RT C ∆S = T f TV dT . ⇒ dS = Q T ; if dV = dN = 0 then: i RT C If dN = 0 and W = −P dV then: ∆S = T f TP dT . i Degrees of Freedom f [Total at STP]=(trans, rot, spring{-vib, -pot}). Spring DOF are ‘frozen out’ in gases at STP. Monatomic gas [He, Ar] 3 =(3,0,{0,0}). Diatomic gas [O2 , N2 , CO] 5 =(3,2,{1,1}). Polyatomic (>2) gases: linear [CO2 ] 5 =(3,2,{4,4}), nonlinear [NO2 , H2 O] 6 =(3,3,{3,3}). Elemental solids [Al, Pb] 6 =(0,0,{3,3}). Einstein solids 2 =(0,0,{1,1})/osc.. Adiabatic exponent: γ ≡ 1 + 2/f . Equipartition Theorem At temp. T the avg. energy of any quadratic DOF is 1 2 kB T . For N entities with only f quadratic DOF each: Uthermal = N f 12 kB T . Ideal Gas P V = nRT =N kBT (Hard indist. spheres; low ρN ; elastic coll’s) • U = Nf 21kBT • CP = CV +kBN. 3 V 4πmU 2 S(N,V,U) = N kB ln N + 52 monatomic. 3N h2 3 2+mgz µ=−kBT ln V 4πmU 2 N 3h N • 3/2 =V = V Ztr(T,N=1)=V 2πm vQ h2 β l3 Q Z(T,V,N)= 1 [Z1(T,V)]N= 1 [Zint(T)Ztr(T,N=1)]N N! N! mixing gases b&c N N Nc monatomic•Pb=Pc c ∆S=−NkB Nb ln Nb + N N ln N T =T •N +N =N c b c b Free Expansion (Quasistatic+irreversible+vacuum) ∆U = Q+ W = 0. But ∆S = N kB ln Vf Vi (6= 0, 6= Q T ). Isothermal (Quasistatic+slow+thermal equil.) ∆T = = Q+W = 0 • ∂(PNV ) = 0 • ∆S = Q 0 ⇒ ∆U T If ∆N = 0 then Wcomp. = N kB T ln Vi/Vf . h ( (h ∆U = h (h Adiabatic (Fast+( quasistatic) Q+W • ∆S 6= 0 If ∆N = 0 then ∂(V T f/2 ) = 0, ∂(V γ P ) = 0, and Wcomp. = f2 (Pf Vf − Pi Vi ). Isentropic (Adiabatic+Quasistatic) ∆S = Q = 0. Reversible. T p p 3kB T /m from toy piston/P vrms = v2 = wall . q p −V ∂P γkB T /m [Adiabatic; expand csound = = ρm ∂V ∂(P V γ ) = 0, rearrange for bulk modulus.] Heat (Energy) Capacity C≡ Q ∆T CP = = ∆U −W ∆T • c≡ C m • ∂Wo ∂H ∂U ∂V ∂T P = ∂T P+P ∂T P− ∂T P CV = • ∂U ∂T V,N,W L≡ Q m P,W Virial Expansion / Van der Waals P V = nRT (1 + B(T)/(V/n) + C(T)/(V/n)2 + . . .) Qual. OK for gases, dense fluids. a : intermolecular attr., b : occupied V •(P + an2/V2) (V −nb) = nRT 2-State Paramagnet ∼ Spin 1/2 (symmetric!) N • Ω N ~ || z ∼ Coins. • B b • Ω(N, N↑ ) = N total = 2 ↑ N N N (N↑ N↓ ok) 1+N↓/N↑ ↑ 1+N↑/N↓ ↓ eN ↑ √ N↓ N↑ 1 ⇒ Ω≈ N 2πN ↑ h i k S(U,B,N)=−N kB 1−z ln 1−z +1+z ln 1+z • 1 = B ln 1−z 2 2 2 2 T 2µB 1+z Ω≈ U =µB(N↓−N↑) U(T,B)=−N µB tanh(µB/kBT) •z=U/(N µB) • M =µ(N↑−N↓) µB µB 2 /cosh2 CB =N kB kB T kB T U(T,B)=−BM(T,B) Einstein Solid N indep. oscil.’s, q quanta total: N bins & q stars. )( = bin dividers, QQQQQ → (1, 1, 1, 2) QQQQQ → (1, 3, 1, 0) q +(N −1) symbols, choose q to be quanta. ......... 1 V = 21q k s x2 −1 • E = ~ω(n+ 2 ) • Ω(N, q) = q +N ks N q U = ~ω(q + ) ω = 2 m q N high-T q N ln Ω ≈ ln 1+ N Ω ≈ eq q N 1 q +ln 1+ N +... N q i (1+N/q)q (1+q/N)N eN √ Ω≈ q, N 1 N q 1 Ω≈ q 2πq(q+N )/N low-T µ ≈ −kBT log(1+ q/N). High-T : U ≈ N kB T • CV ≈ N kB 2 • CV ≈ N kB k~ωT e−~ω/kBT Low-T : U ≈ ~ωN e−~ω/kBT Barometric Eqn. Air slab: dz thick, m avg. molecule mass: dP dz = N mg −V ideal gas =⇒ dP dz = −mg kB T P B mgz ⇒ N(z) = No e−kB T Heat Eqn. ∂t T = K∇2 T T (~ r ; t) = mk r ; 0) = g(~ r ). K = ρm T C & T (~ R 0 0 − 2/4Kt g ~ e r d~ r n/2 Rn 1 (4πKt) Partition Functions Bltzmn/Can’cl Gibbs/Grnd can’cl (r,N)→rth state of • • sys. of N particles. P(s)= 1 e−E(s)β P(r,N)= 1 e−(E(r,N)−µN)β Z Z P Z(T) = s e−βE(s) • F(T) = −kBT ln(Z(T)) • hEi = −∂β[ln Z] P P −βE(s) 2 2 1 • σE = ∂β [ln Z] hQi = s PsQ(s)= Z s Q(s)e P βµN P −(E(r,N)−µN)β = Z(T,V,N) Z(T,µ) = N e (r,N) e 3/2 2 mβ −βmv2/2 Maxwell speed: D(v)dv dv q = (4πv ) 2π e p √ 2kBT Most prob’bl: vp = = 2vp/ π •vrms = vp 3/2 m •hvi 3/2 2 Maxwell velocity: D(3)(v)d3~ v = mβ e−βmv /2d3~ v 2π P(i,n)= Ideal quantum gas Zi(T,µ)=Z(i,T,µ) • • P (n)= e−β(i−µ)n Z(T,µ)=Π∞ Zi(T,V,µ) Z( ,T,µ)=P e−β(i−µ)n i i=1 Z(i,T,µ) i n 1 Fermi-Dirac: n=0,1→Z(,T,µ)=1+e−β(−µ) →hni(,T,µ)= e+β(−µ)+1 1 1 Bose-Ein: n=0,1,...→Z(,T,µ)= →hni(,T,µ)= 1−e−β(−µ) e+β(−µ)−1 R P P 2k2 nx L 3 3~ E(~ k)= ~2m ⇒ kx= 2πL • ... = ... → 2π d k... nx,ny,nz ~ One part’cl in a box k R∞ P P P ~ D.O.S’s: f((k)) → 0 g()f()d ~ i f(i) = spin k √ √ 2 3/2 BE: g() = αV /2•FD: g() = αV •α = 4π(2m/h ) R R N = 0∞ hni()g()d•U = 0∞ hni()g()d Fermi gas@T=0:•F = µ(T=0)•kF3 = 3π2n . 3/2 U = 3F/5•P = 2U/3 R n = 2αF /3• N ∞ R PV P 2 L 3 3~ d k → πV Black body • µ = 0 • → 2 2π 2c3 ω dω polariz 0 3 ~ ∞ ∞ k R R 1 ~ω U V = uω(ω,T)dω = u(,T)d• = ~ω•uω(ω,T) = π 2c3 β~ω e −1 0 4σB 4 1 3 • ~ω ≈ 2.82k T • U = VT max B c π 2 (~c)3 eβ−1 16σB 3 S = 3c VT • P V = U/3 • Rad.E-flux: eσB T4 ω phon RD P BZ P k3 T3 6π2Nv3 3 Debye • → 9N dωω 2 ... • ωD = B~3D = V s ω3 polariz~ D 0 k ω TR/T RD~ω3dω 9N(kBT)4TD R/T 9NkBT3 D x3dx x3exdx U= 9N = (k T )3 ex−1 • CV = (ex−1)2 ω3 T3 eβ~ω−1 BD D0 D 0 0 h i3R h i3 h i3 ∞√ T<Tc N xdx Nnorm 2 2πmkBTc 2 √ BEC• N = TTc 2• cond =1− TTc 2 V = π ex−1 • N N h2 0 ∞ ∞ h i3 h i3 R 3/2 R 5γNk x1/2dx U = γNkBT TTc 2•CV = 2 B TTc 2•γ = xex−dx 1 ex−1 ≈0.77 0 0 0 u(,T) = Non-Rel. Quantum Mech. P hf (j)i= j f (j)Prob(j) R hf (x)i= f (x)ρprob (x)dx iλA √ = σ σj −iλA j σj ← std.dev. •↑ var (iλ)2 2 Qe =Q+iλ[A,Q]+ [A,Q] +... 2! • e Schrödinger Eqn. 2 2 = −~ r , t) Ψ(~ r , t) (= H(~ r, p ~, t)Ψ). 2m ∇ +V(~ Time-Indep. Schrödinger Eqn. [AB,C]=A[B,C]+[A,C]B i~ ∂Ψ ∂t • 2≡h(j−hji)2 i=hj 2 i−hji2 " σj If ∂tV = 0, using Ψ(~ r, t) = ψ(~ r )φ(t) (‘sep of vars’) leads to H(~ r, p ~)ψ = Eψ. General sol’n is Ψ = P r, t) with Ψn = ψn φn = ψn (~ r )exp iEnt & n cn Ψn(~ −~ R ∗ (~ r )Ψ(~ r , t = 0)d~ r En∈R, cn∈C. cn = hψn|Ψt=0i = ψn 1. Ψn ← stationary states; only phase evolves in t. 2. If V is symmetric ⇒ each ψn (can be) even or odd. 3. Each En>Vmin . (Else Ψ is not normalizeable.) 4. E > V(−∞) or E > V(∞) ⇒ scatter state(s). 5. ψn ← an orthonormal set. (Completeness assumed.) R + 6. ψ continuous. ∆(∂xψ) = 2m lim→0 V(x)ψ(x)dx. − ~2 7. ψn+1 has one more zero-crossing than ψn . im [H(t),~ r] 8. i~∂tQ(t) = [Q(t),H(t)] ⇒ p ~= ~ Interpretation, Requirements, Misc. ∗ ~~ ~p p ~ → ~i ∇ r→i~∇ r• ~ ~ • [x,px]=i~ • [f(x),px]=i~∂xf • hg|fi=hf|gi Eigen-funcs: x b: x|ψy(x)i = y|ψy(x)i ⇒ |ψy(x)i = δ(x−y). √ p bx : i~∂x|ψpx(x)i = px|ψpx(x)i ⇒ |ψpx(x)i = eipx x/~/ 2π~. So: Φ(px, t) ≡ hψpx(x)|Ψ(x, t)i and Ψ(y, t) ≡ hψ−px(y)|Φ(px, t)i P hQi = hΨ| [Q|Ψi] = [hΨ|Q†] |Ψi = n qn|cn|2 R ∗ ~ 3 R ~~ ~p hQ(~ r, p ~)i = Ψ Q ~ r, i ∇ r = Φ∗Q i~∇ ~ Φd3 p ~ r Ψd ~ ~, p P Spectral decomp.: Q = nqn Pn if Q|ni = qn |ni R∞ ρprob (x, t) = |Ψ(x, t)|2 ⇐⇒ |Ψ(x, t)|2 dx = 1 −∞ Rb 2 (but a |Ψ(x, t)| dx is time-dep. in general.) prob. prob. cn = hΨn |Ψi =⇒ |cn |2 • c(z) = hΨz |Ψi =⇒ |c(z)|2 dz P P prob. 2 2 |cn |2En En←→|cn | • nR n |cn(t)| = 1P • hHi = P =1 • Pz dz=1 Proj. op.: Pn ≡ |nihn|/|hn|ni|2 • n n Schwarz ineq.: ha|aihb|bi ≥ |ha|bi|2 ≥ ((ha|bi−ha|bi∗)/(2i))2 2 2 1 ~ Uncertainty: σA σB ≥(2i h[A,B]i)2 • σx σpx ≥ ~ 2 • σt σE ≥ 2 Correspondence principle → “classical” limit agrees. Schrö. Pict.: hQ(t)i = hΨ(x, t)|Q|Ψ(x, t)i iHt iHt Heisen. Pict.: hQ(t)i = hΨ(x, 0)|e ~ Qe −~ |Ψ(x, 0)i (no-degen or ψ is a Feyn-Hllmn: ∂λEn = hψn|∂λH|ψni proper lin. comb.) Ehrenfest’s Theorem / Virial Theorem 1 ∂t hQi= i~ h[Q,H]i+h∂t Qi • h...i’s obey classical laws. 1 ~ ~ • ∂thLi=h ~ ~ ~ h~ pi=h~ v i=∂th~ r i • ∂th~ pi=h−∇Vi=h Fi r×(−∇V)i m If V (λ~ r1 , λ~ r2 , ...) = λν V (~ r1 , ~ r2 , ...) for N particles then hn|T |ni = ν2hn|V |ni (& En = hn|T |ni+hn|V |ni). ~ ∂th~ r ·~ pi = 2hT i−h~ r · ∇Vi • ∂thψn|Q|ψni = 0 if ∂t Q = 0 1D Scatter (L−∞ → R+∞ ) • R+T = 1 group v ψL = AeikL x +Be−ikL x |F |2 |B|2 R ikR x −ik x • R ≡ |A|2 • T ≡ v group |A|2 R ψR = F e + Ge L 1D Infinite Square Well n o √ d2 ψ 0, 0 ≤ x ≤ L V (x) = ∞, =⇒ = −k2 ψ k ≡ 2mE . ~ else dx2 q 2 ~2 kn ~2 n2 π 2 2 nπx En = 2m = 2mL2 • ψn = L sin L • n ∈ N>0 hn|x|ni = 2 L 2 hn|p |ni = • hn|x2 |ni = π 2 ~2 n2 L2 • σx,n = L2 3 q 2 − 2πL2 n2 π 2 n2 −6 L 12 πn • σp,n = ~ πn L 1D Harmonic Oscillator / 3D [N,a ] = a • [a,N] = a • N |ni = n|ni • a|ni = n|n−1i q q √ ~ x = 2mω a†+a • p = i mω~ a†−a • a†|ni = n+1|n+1i 2 [H,a†]=~ωa† 1D Free Particle 2 2 2π V (x) = 0 • ∂x ψ = −k2 ψ • p = ~k • λ = |k| • ωk = ~k 2m n o 2 √ ~k k > 0 moves → k ≡ ± 2mE • Ψk ∝ ei kx− 2m t ~ k < 0 moves ← (stationary states) 2 ∞ R ~k packet.” Ψ(x, t) = √12π φ(k)ei kx− 2m t dk ← “Wave General sol’n, −∞ R with ∼weights: φ(k) = √12π −∞ Ψ(x, t = 0)e−ikx dx. ∞ q q (&classical)dω ~|k| ~|k| ω E vphase = |k| = 2m = 2m • vgroup = dk = m = 2E m 1D Delta Well/Barrierbound scatter 2 ψ ≡ κ2 ψ ≡ −k2 ψ. V(x) = −αδ(x) • ∂x ψ = − 2mE ~2 √ 2 mα|x| mα • E = − mα Bound → κ • ψ(x) = ~ exp −~2 2 i h 2~ h 2 i−1 −1 mα2 E • T = 1+ 2~ Scatter → k • R = 1+ 2~ 2E mα2 V(x) = αδ(x) • No bound • Same scatter as δ-well. 1D Double Delta√Well √ V(x) = −α(δ(x+a)+δ(x−a)) • κ ≡ −2mE • k ≡ 2mE ~ ~ ( 2 o Even: e−2κa = ~mακ −1 Sol’n: always Bound: −2κa ~2 κ Sol’n: sometimes Odd: e = 1− mα Scatter: T = 1 (with z=αm/~2k) 1+2z 2 [(1+z 2)+(1−z 2)cos(4ak)−2zsin(4ak)] 1D Finite Square Well / Barrier √ n √ 2m(E+V0) −V • κ ≡ −2mE V(x) = 0,0 , |x| ≤ a • ` ≡ ~ ~ |x| > a p & Even: tan z = q (z/z0)2−1 z ≡ `a, √ Bound: a Odd: tan z = −1/ (z/z0)2−1 z0 ≡ ~ 2mV0 π 2 ~2 Sol’ns: •Even: always, finite# •Odd: iff V0 ≥ 8mα 2. p V02 −1 2 2a Scatter: T = 1+ 4E(E+V ) sin ~ 2m(E+V0) 0 The 1D Finite Square Well, but −V(x). No bound. p V02 −1 2 2a 2m(V0−E) Scatter: TE< V0= 1+ 4E(V0−E) sinh ~ p V02 −1 −1 2 2a 2mE 2 TE= 2m(E−V0) V =1+ ~2 a • TE>V =1+ 4E(E−V ) sin ~ 0 ~ 2 • • [H,x]=im p • [H,p]=i~mω x 2 p 1 mωx 1 mω 4 e −2~ Hn mω En = ~ω(n+ 12) • ψn = √ n ~ x 2 n! π~ 2 (hermite poly’s) 2 n −x ψn = √1 (a†)nψ0 • n ∈ N≥0 • Hn(x) = (−1)nex ∂x e n! p √ √ hn|x|qi = ~/2mω( nδq,n−1 + qδn,q−1 ) • hn|V |ni = 1 En 2 0 0 1D Sudden Step Up / Drop Down n o ≤0 V(x) = V0,, x • Reminder: ∆vgroup |x=0 6= 0. 0 x>0 q 2 √ E−V0 4E √ TE<V0= 0 • TE>V0= E − E −V0 2 E V0 p p = 4( 1+V0/E)/(1+ 1+V0/E)2 Like Step Up, but −V(x) • T 3D Spherical Symmetry & ∂t V = 0 ψ ≡ R(r)Y(θ, φ) • u(r) ≡ rR(r) • Yl −m = (−1)m(Ylm)∗ R∞ 2 2 R 2πR π m∗ m0 |R| r dr = 1 • (Y ) Yl0 sinθdθdφ = δl,l0 δm,m0 0 0 0 l q n (2l+1) (l−|m|)! imφ m <0, m Yl (θ, φ) = 4π (l+|m|)! e Pl (cosθ) = 1(−1if)mmelse. |m| m| l l!2l • ∂ hLi ~ =0 Plm(x) =(1−x2)2 ∂|x Pl(x) • Pl(x) = ∂xl(x2−1)/ t i h [H,L2]=[H,Lz]=0 −~2 2 ~2 l(l+1) • 2m ∂r u+ V + 2m r 2 u = Eu m∈−l,...0,1,...l • hn|p|ni = 0 1 1 V(x) = 12kx2 = 12mω 2 x2 • H = ~ω(a†a+ 2) = ~ω(N+ 2) pmω ip ip † pmω † a = 2~ x+ mω • a = 2~ x− mω • [a, a ] = 1 √ † † [H,a]=−~ωa p √ √ hn|p|qi = i mω~/2( nδq,n−1 − qδn,q−1 ) • hn|T |ni = 1 En 2 p p hn|x2 |qi = (~/2mω) (2q+1)δn,q + n(q+1)δn,q+2 + q(n+1)δn,q−2 p p hn|p2 |qi = (mω~/2) (2q+1)δn,q − n(q+1)δn,q+2 − q(n+1)δn,q−2 3 ψ = ψa(x)ψb(y)ψc(z) • En=~ω(n+ 2) • dn=(n+1)(n+2)/2 N 3D Rigid ing Circle with N Masses ~ = aM v about ~ r◦ at r=a • H = T+ V = 12M v 2 • |L| L2 2a2M ~2l(l+1) 2a2M ⇒ El = • ψlm = Ylm • m∈−l,..0,1,..l l∈0,1,2,... 3D Inf. Spherical Well n i o h √ 0, r ≤ a =⇒ ∂ 2 u = l(l+1) −k2 u k ≡ 2mE . V (x) = ∞, r ~ else r2 1 u(r) = Arjl(kr)+Brnl(kr) jl(x) = (−x)l x ∂x l sinx x • x x 1 j0 = sin • n0 = − cos nl(x) = −(−x)l x ∂x l cosx x x x H= 2l l!xl 1 jl(x) ≈ x cos(x− π (2l+1)! 2 (l+1)) x1 • 1 π −(2l)! x1 n (x) ≈ l nl(x) ≈ l l+1 x sin(x− 2 (l+1)) 2 l!x ∂x jl(x) = xl jl(x)−jl+1(x) • ∂x nl(x) = xl nl(x)−nl+1(x) 2 ~2βnl jl(βnl)=0 (n roots/l) Enl = 2ma2 E →(2l+1)-degen. • ψnlm = jl(βnl r/a)Ylm nl jl(x) ≈ Hydrogen Atom – Bound States √ −2mE −e2 1 −m e2 2 n∈N>0 , • En = 2~ 2n2 4π◦ 4π◦ r • κ ≡ ~ n2 -deg. 2 m∈−l,..0,1,..l 4π◦~ ~ 1 a◦ = αm ≈ 0.529Å • = = 2 c nκ l∈0,1,..,( n−1) e n mee r h i3 il −rh ( 2l + 1 ) (n−l−1)! m 2r 2 2r ψnlm= na◦ 2n[(n+l)!]3 ena◦ na◦ L(n+l)−(2l+1) na◦ Yl (θ, φ) V(r) = p q −x q e−r/na◦ Lqp−p(x) = (−1)p∂x Lq(x) • Lq(x) = ex∂x e x • ψn00= √ π(na◦)3 2 hVi=2E |nlmi ⇒ hTi=−En • hr1i = a 1n2 • hr12 i= a2n3(1l+1/2) • hp2i= a◦~n n ◦ ◦ s+1hrsi−(2s+1)a hrs−1i+ s[(2l+1)2−s2 ]a2hrs−2i=0 ◦ ◦ 2 4 • n q q (1+(−1)q)(q+2)!a◦ hz 2i=a2 (q+2)!a◦ q Most q ◦ hz i= hr i= q+1 hzi=0 (q+1)2q+2 2 |100i ⇒ • • prob r=a◦ • a hri= ◦ [3n2−l(l+1)] 2 Angular Momentum, Intrinsic Spin ~ r ×~ L=~ p ~ ~~ S= σ 2 ~,r2]=0 [L ~,p2]=0 [L ~ L ~ L2=L· •S 2=S· ~ S ~ • [L ,L ]=i~L • [Sx,Sy]=i~S z x y z ~,S]=0 ~ [L ~ [L2,S]=0 • ~ [L2,L]=0 ~ [S2,S]=0 • [L ,L ]=i~L • [Sy,Sz]=i~S x y z x L± ≡Lx±iLy S± ≡Sx±iSy • [L ,L ]=i~L • [Sz,Sx]=i~S y z x y [Lz,L±]=±~L± [Sz,S±]=±~S± ~·S, ~ L]=i~ ~ ~×S ~ [L ~·S, ~ J]=0 ~ [Lz,x]=i~y [Lz,y]=−i~x [Lz,z]=0 [L L • • •~~ ~ •~~ 2 ~ L ~ [L [Lz,px]=i~py [Lz,py]=−i~px [Lz,pz]=0 [L ·S,S]=i~S× ·S,L ]=0 √ m±1 L± Ylm=~ (l∓m)(l±m+1)Y ~·S,S ~ 2 ]=0 L2 Y m=~2 l(l+1)Ylm [L l √ • 2l • ~·S,J ~ 2 ]=0 S |smi=~2s(s+1)|smi [L S±|smi=~ (s∓m)(s±m+1)|sm±1i Lz=−i~∂φ Lz Ylm=~mYlm s=0,1/2,1,... • (Ym)∗ xyY • ms =−s,..,0,1,..,s m =0 Sz|smi=~m|smi l l h i P (123) 1 1 ~ σ = 01 10 , 0i −0i , 10 −01 → ±1 , ±i , 10 / 01 • σjσk= δjk+i njknσn P j1j2j |j1m1i|j2m2i= Cm |jmi 1m2m j Jz →m≡m1 +m2 If s1= 1/2 then: (with s = s2 ±1/2) • P j1j2j |jmi= Cm m m |j1m1i|j2m2i m1,m2 1 2 2 J →j∈|j1−j2|,..(++1)..,(j1+j2) |smi=A|1 1i|s2 (m−1)i+B|1 −1i|s2 (m+1)i 22 2 2 r r2 2 s2 ±m+1/2 s2 ∓m+1/2 A= •B=± 2s2 +1 2s2 +1 • Corrections to hydrogen En∼α2 4 5 4 struc.∼α ∼α Hyperfine∼α me/mp • Fine • Lamb∆ ~ ~ •µ ~ ⇒µ ~p γ(v)6=1 & S↔ quant’zd E ~p →B ~e ↔B 0 Fine struc: E0 4 2 n 0 +H 0 = −p + ~α S· ~L ~ 1+ α Enj = 2 −3 H 0=Hrel n j+1/2 4 s−o 8m3c2 n 2m2 r 3 • ~ L=( ~ J 2−L2−S 2)/2•p2 ψ=2m(E−V)ψ Good #’s: n,l,s,j,mj S· e ~ ~ ~ ~ Zeeman: H 0=−(µ ~ l+µ ~ s)·B ext=2m(L+2S)·Bext •conflicts w/ fs If: Bext Bint ⇒fine struc domn8’s⇒E 1 =hnljmj|H 0|nljmji 2 2 2 1 ~ ~~ ~ 2 ~ ~ use: S t-avgd =J(S·J)/J •S·J=(J −L +S )/2•Egs ∼±µB Bext . If: Bext Bint ⇒zeeman domn8’s⇒non-pert with|nlml msi 1 =µ B align ||z⇒E b B ext (ml+2ms).(note: can also pert the fs, ~L ~i=hSxihLxi+hSyihLyi+hSzihLzi=~2 m ms if including H 0 .) use: hS· l fs If: Bext ∼Bint ⇒use full-blown degen pert (→ W eigenprob) ~ ~ ~ b then H 0=ezE Linear Stark: H 0=E pe . If E ext ·~ ext =|E|z ext= eEext r cos θ. Use degen pert. Most integrals→0. 0 1 3 ~ p ⇒E =Ah[3(S ~p·b ~e·b ~p·S ~e ]/r i+ Hyperfine: H =−~ µe·B r)(S r)−S ~p·S ~ei • C=µ◦ gp e2/3mp me =8πA/3 • S ~p·S ~e=(S 2−S 2−S 2)/2 C|ψ(0)|2hS e p 2 4 If: l = 0 ⇒ A term→0 ⇒ E 1 =(S2−3~2/2)2gp ~2/3mp m2 e c a◦ . Breaks spin degen of the gs: S2 = 0 for singlet, 2~2 triplet. − Stationary e ~ µ ~ =γ S ~ ~ τ =~ µ ×B • ~ H=T−µ ~ ·B ~ if B=B b ◦z • in Magnetic Field E± =∓γB◦~/2 hSzi= ~ cos α 2 • hSxi∝cos ω hSyi∝sin ω • ω=γB◦ Larmor ~ ~ ∇(~ ~ µ ·B)6 ~ =0 e− Stern-Gerlach: B(x,y,z)→ F= b ~ −αxb B= i+(B◦+αz)k ~ t∈[0,T] µ ~ ·B H(t)= 0 else • E±=∓γ(B◦+αz)~/2 • pz=αγ~/2 • q≡iγB◦/2 i aχ+ +bχ− t<0 χ(t)= ae(qT+ipzz)(χ+) + be−(qT+ipzz)(χ−)t>T T.I. Perturbation Theory: H ≡ H +λH 0 0 0 0 0 P hψ0 H 0|ψ0 m|H |ψni|ψ0 i ni=En|ψni |ψ1 ni= m 0−E 0 1 =hψ0 |H 0|ψ0 i En En m = 6 n m n n • 0 0 0 0 2 2 = P |hψm|H |ψni| En 0−E 0 En m = 6 n m • We need to determine the α, β that will 0 0 If: H 0|ψ0 ai=E |ψai split the degen. ψ’s into distinct e-val’s 0 0 0 0 0 and H |ψ i=E |ψ i cleanly when H is applied. There are two b b and maybe more... ways. [1] find A =A† s.t. [A,H 0] = [A,H 0] = 0 • so H 0|ψ0i=E 0|ψ0i which are NOT degen. for the ψ’s in E0 s © © 0 sub-space (ψ0 w/ |ψ0i=α|ψ0 a,ψb, ...) and use non-degen. ai+ © 0 [2] solve W eigenprob for α, β and E 1 (s). +β|ψ i+... b You hopefully get N E’s and req’d α, β. h i h i W =hψ0|H 0|ψ0i Waa Wab α ij i j Solve N×N: 1α = E ⇒ det( β 0 Wba Wbb β W−λ)=0 |ψ0i=α|ψ0 ai+β|ψbi+... © Variational Principle Egs ≤ hψ|H|ψi for any normalized |ψi. Simply minimize! 2 V∝x: ∂x ψ = α3xψ → ψ = CAi(x)+DBi(x) (Airy’s) √ 3 / 2 2 − x √ Ai(x0)∼sin 2(−x)3/2+π /( π(−x)1/4) Ai(x0)∼e 3 /(2 πx1/4) 4 3 • √ 2 2 π 3 / 2 +2x3/√ Bi(x0)∼cos (−x) + /( π(−x)1/4) 3 4 Bi(x0)∼e 3 /( πx1/4) 0 T.D. Perturbation Theory: H ≡ H +λH 0(t>0) P 0=E 0 ψ 0 H 0 ψn Ψ(t)= cn(t)ψn e−iEn t/~ • ∆mn ≡Em−En n n 0 ≡hψ 0 |H 0 |ψ 0i • ∂ c n 1P −i∆mnt/~ (exact) 0 Hm n m n t m = i~ cn Hmn e n Rt 0 Rt 0 0 0 −i∆mnt0/~dt0 0 1 cm6=n(t)≈ 1 Hm (F.O.) cn(t)≈1+ Hnn(t )dt n(t )e i~ i~ • 0 0 0 ∂t H 0 =0: sin2(∆ t/2~) H =V cosωt: sin2((∆ ±ω~)t/2~) nm nm Pn→m = Pn→m = 2 /(4|H 0 |2) ∆n m mn • iff ∆nm =±~ω (∆nm±ω~)2/(|Vmn|2) 3 |P|2 ω0 Spon. emiA= ssion rate: 3π◦ ~c3 Life- τ = 1 r |ψai A1+A2+... • P=qhψb|~ • time: WKB(J) – (Classical endpoints a, b; L → R) R √ b p(x0)dx0 / p(x) ψ(x)≈C exp ±i a Assume ψ=A(x)eiφ(x) ~ √ • 2 2 2 2 & ∂x [A]/A((∂xφ) & p /~ ) p(x)= 2m(E−V◦) “classical” p. Rb√ 2 2 −2γ • γ~≡ a |p(x)|2 dx Rb Rb no |walls: a p(x)dx=(n−1)π~ 2 |walls: a p(x)dx=nπ~ 2 • w/n=1,2,.. • Best when: Rb 1 n1 1 |wall @a: a p(x)dx=(n− )π~ 4 (semi-classical regime) 1 1 hT i= ∂n[En](n− ) when there are no |walls. 2 2 Tunneling a → b: T =|F| /|A| ≈e Scattering: Partial wave, Born ikr D(θ)= dσ =|f(θ)|2 ψ(r,θ)≈A[eikz+f(θ)e ] u(r)=Arj (kr)+Brn (kr) r l l R dΩ • Use u near • (1) ix (1) origin, σ= D(θ)dΩ h0 = e •h ≡jl(x)+inl(x) match with expansion. ix l P P∞ l 2 eikz = ∞ i=0 i (2l+1)jl(kr)Pl(cosθ) • σ=4π i=0(2l+1)|al| P∞ (1) l ψ(r,θ)=A i (2l+1)[jl(kr)+ikal h (kr)]Pl(cosθ) ←impose b.c.’s. i=0 l 1. V(~ r0) is localized about ~ r0 2. incoming wave ∼ not altered. R ik|~ r−~ r0| ψ(~ r )=ψ0(~ r )− m2 e V(~ r0)ψ(~ r0)d3~ r0 s.t. (∇2+k2)ψ0 =0 |~ r−~ r0| 2π~ R i(~ k0−~ k)·~ r 0 V(~ 0)d3~ 0 s.t. ~ Born→f(θ,φ)≈ −m e r r k=kr b,~ k0 =kz b 2π~2 Spherical sym: κ=2k sin(θ/2) Low-E: −m R R V(~ r 0)d3~ r0 • f(θ)≈ −2m rV(r)sin(κr)dr f(θ,φ)≈ 2π~2 κ~2 1. V(~ r0) is localized about ~ r0 2. incoming wave ∼ not altered. Electrodynamics General ~ ·E=ρ/ ~ Gauss’ ∇ ◦ ~ ×E=−∂ ~ ~ Faraday’s ∇ tB • ~ ·B=0 ~ No monopoles ∇ ~ ~ ~ ~ Ampere’s ∇×B=µ◦(J+◦∂tE) In matter ~ ·D=ρ ~ ∇ f ~ ×E=−∂ ~ ~ ∇ tB ~ ·B=0 ~ ∇ ~ ~ ~ ~ ∇×H=Jf +∂t D Aux. & Pot.s ~ ~ P ~ D= ◦ E+ 1 B− ~ ~ M ~ H= µ◦ ~ ~ V−∂ A ~ E=− ∇ t ~ ∇× ~ A ~ B= • 1 B. ~ =◦ χe E ~ so D= ~ ~ & M ~ =χm H ~ so H= ~ ~ Linear media: P E µ R 1 (E× ~ ~ B) ~ Enrg: U = 1 (◦E 2+ 1 B 2)dV Poynting: S= C≡Q/V 2 µ◦ µ◦ R • • µ ~ =◦ (E× ~ B) ~ dV W=CV 2/2 Larmor: P = ◦ q 2 a2 Momntm: P 6πc ~ =q(E+~ ~ v ×B) ~ ~ nσ F W=Q[V(~ r )−V(O)] F= b 2/2◦ • P =E 2 ◦/2 • • R −σ =n· ~V W= 1 V dq b∇ 2 surf. press. ◦ @surf 0 Spherical image: |rq|=a→q =−qR/a & |r 0|=R2/a•V(~ r )=k((q/)+(q0/ 0)) q 2 X=C→B.c.’s! −∇2V=ρ/◦ solve via sep.vars: V≡X(x)Y(y)Z(z)→ 1 ∂x X (Laplace) N H r R~ Pqi b ~ a= Qenc E·d~ ~ ~ ~ ~ dq={λdl, E( r )= 1 V( ~ r )=− E·d l 2 4π◦ ~ ~V ◦ σda,ρdV}, E=− i i ∇ O • • R 1 R1 0 1 1 ( ∞ ~ ~=~ r −~ r , b bdq E(~ r )= V(~ r )= dq ~ σn E= 2 4π◦ 4π◦ 2◦ plane) q at ~ r0 . V V ~~ Geometry – 4π◦V(~ r )•4π◦E( r) 1D wire. ||b x. Len: L ⊥ above cent. 2D ring. x−b b y. ⊥ above cent. 2D disk. x−b b y. • ⊥ above cent. 3D sph. shell. At origin. • q λ ln L + 1+(L/z)2 z • q(λL) z b z z2+L2/4 (λ2πR) z(λ2πR) • z b (R2+z 2)1/2 (R2+z 2)3/2 q 2 (σπR ) −|z| q 2 2 z +R −|z| • 2 1+ q z b R2 R2 z 2+R2 • q q (out), (in) r R • • (σ4πR2) r>R, r b 0else r2 Magnetic Dipoles (~ µ – proton, electron) gp e ~ 2µ ~e • B ~µ = µ0 [3(~ Sp • µ ~e = −eS µ ·b r)b r −~ µ]+ 0 µ ~ δ 3(~ r) µ ~p = 2mp me 4πr3 3 ~ Electric Dipoles (±|q| sep. by d~ ⇒ p ~e = −q d) R 0 0 3 0 V ~ ~·b r E 1 4π 3 p ~e= ~ rρ(~ r )d ~ r • k = q− q ≈ p • = [3(~ p ·b r )b r −~ p ]− ~δ (~ r) k 3p r2 r3 + −