Coal Also called black gold. Found in sedimentary strata [layers of soil]. Contains carbon, volatile matter, moisture and ash [in some cases Sulphur and phosphorous] Mostly used for power generation and metallurgy. Coal reserves are six times greater than oil and petroleum reserves. Composition Almost by definition, coal consists mostly of carbon. The plant materials from which coal is derived are largely carbohydrates of various kinds, only the most resistant of which (mainly cellulose and lignin) remain after partial decomposition after death of the plants. The initial plant residues that are buried to become coal therefore consist largely of carbon even at the very beginning. But coals—even lignites—contain appreciable percentages of other constituents as well. Here’s a list: nitrogen: a couple of percent; doesn’t vary much. Probably from the organic matter itself, not from entrapped air. sulfur: small percentages, a couple of percent, but undesirable because of production of sulfuric acid (the main constituent of acid rain) upon combustion. water: varies with rank from a few percent to as much as 90% (conventionally measured after drying at a temperature a little greater than 100 °C, to get rid of liquid water in pore spaces). gases: CO2, O2, N2, CH4, variable percentages. “ash”: the solid residue upon combustion: sand, silt, and clay in variable proportions, either carbonate or siliciclastic (mostly the latter). From fractions of a percent in the cleanest coal to such large values that the rock should be called a carbonaceous shale or a carbonaceous sandstone rather than coal. Very impure coal is called bone coal. Figure 12-3 shows one segment of a composition triangle whose end members are percent of carbon, hydrogen, and oxygen. Only the area nearest the carbon corner is occupied by rocks we would call coal. You can see that the increase in rank is associated with a progressive decrease in the percentages of hydrogen and oxygen, presumably owing to driving off of the volatile constituent water. The plant constituents of coal have been classified both macroscopically and microscopically. The basic idea is that all coal is composed of a small number of kinds of fragments of plant debris called macerals, which are analogous to the minerals of an ordinary sedimentary rock. Macerals represent such things as branches, twigs, leaves, bark, interior tissue of various kinds, and pollen or spores, among many others. Study and classification of coal macerals is highly botanical and can be done only with the aid of a microscope. The macroscopic study and classification of coals, on the other hand, while not as fundamental, is easier to deal with. Coal has long been recognized to consist of just a few macroscopic constituents, usually interlaminated. These constituents form strata that are typically from fractions of a millimeter to tens of millimeters thick. vitrain: brilliant, vitreous (glassy-looking), jetlike coal with conchoidal (shell-like) fracture clarain: coal layers that appear silky from the presence of very delicate internal lamination durain: dull, lusterless, matte layers of coal with a close or dense texture, without internal lamination fusain: friable and highly porous coal, usually appearing as irregular chips and wedges lying along the bedding; often called mineral charcoal. Origin Coal can form wherever growth of vegetation is abundant enough, and accumulation of the sediment is scanty enough, that plant material can accumulate in high concentrations and large quantities before complete decomposition. For this, one has to appeal to extensive swamps, usually termed coal swamps, either fresh water or sea water (probably mainly fresh water) in climatic conditions conducive to lush growth of vegetation and far from sources of siliciclastic sediments. Most coal seems to have formed in place, by gradual accumulation of plant material right where it grew. You can imagine thick accumulations of earlier plant material into which the present crop puts down its roots, only to succumb eventually and form the substrate for yet another crop. Such coal is said to be autochthonous. Some coal, however, seems to consist of plant fragments that were transported far from where they grew, presumably by flowing water, and deposited in some rather different sedimentary environment—but again one without an abundance of “ordinary” siliciclastic sediment. SZCuch coal is said to be allochthonous. The overall association of other sedimentary facies with coals—mainly shallow marine and fluvial sediments—tells us that, broadly, coal accumulates in coastal environments of one kind or other. Perhaps the most common kind of environment of this kind could be termed deltaic. Imagine a broad river carrying mud and sand to the shoreline. The river flow in deltas tends to be well channelized, with strong flows carrying sand to the channel mouths. Mud carried by such channels is either spilled widely over the banks of the channels along the way or disgorged into the sea at the mouths of the channels. In certain settings, in between the channels are low-lying areas that receive little fluvial sediment and are conducive to dense vegetation. Such areas tend to experience slow subsidence, from compaction of earlier-deposited sediments; this subsidence makes room for further accumulation of plant materials. (Keep in mind that there must be great compaction of the plant material as it's buried.) Carboniferous Coal Most of the world’s coal was formed in Carboniferous age [350 million years ago][Best quality coal]. Carboniferous age: In terms of absolute time, the Carboniferous Period began approximately 358.9 million years ago and ended 298.9 million years ago. Its duration is approximately 60 million years. The name Carboniferous refers to coal-bearing strata. Formation of Coal Amount of oxygen, nitrogen and moisture content decreases with time while the proportion of carbon increases [The quantity of carbon doesn’t increase, only its proportion increases due to the loss of other elements]. Capacity of coal to give energy depends upon the percentage or carbon content [Older the coal, much more is its carbon content]. Percentage of carbon in coal depends upon the duration and intensity of heat and pressure on wood. [carbon content also depends on depth of formation. More depth == more pressure and heat == better carbon content]. Coal formed millions of years ago when the earth was covered with huge swampy [marshy] forests where plants – giant ferns and mosses – grew. As the plants grew, some died and fell into the swamp waters. New plants grew up to take their places and when these died still more grew. In time, there was thick layer of dead plants rotting in the swamp. The surface of the earth changed and water and dirt washed in, stopping the decaying process. More plants grew up, but they too died and fell, forming separate layers. After millions of years many layers had formed, one on top of the other. The weight of the top layers and the water and dirt packed down the lower layers of plant matter. Heat and pressure produced chemical and physical changes in the plant layers which forced out oxygen and left rich carbon deposits. In time, material that had been plants became coal. Coals are classified into three main ranks, or types: lignite, bituminous coal, and anthracite. These classifications are based on the amount of carbon, oxygen, and hydrogen present in the coal. Coals other constituents include hydrogen, oxygen, nitrogen, ash, and sulfur. Some of the undesirable chemical constituents include chlorine and sodium. In the process of transformation (coalification), peat is altered to lignite, lignite is altered to sub-bituminous, sub-bituminous coal is altered to bituminous coal, and bituminous coal is altered to anthracite. Types of Coal Peat, Lignite, Bituminous & Anthracite Coal. This division is based on carbon, ash and moisture content. Peat First stage of transformation. Contains less than 40 to 55 per cent carbon == more impurities. Contains sufficient volatile matter and lot of moisture [more smoke and more pollution]. Left to itself, it burns like wood, gives less heat, emits more smoke and leaves a lot of ash. Lignite Brown coal. Lower grade coal. 40 to 55 per cent carbon. Intermediate stage. Dark to black brown. Moisture content is high (over 35 per cent). It undergoes SPONTANEOUS COMBUSTION [Bad. Creates fire accidents in mines] Bituminous Coal Soft coal; most widely available and used coal. Derives its name after a liquid called bitumen. 40 to 80 per cent carbon. Moisture and volatile content (15 to 40 per cent) Dense, compact, and is usually of black colour. Does not have traces of original vegetable material. Calorific value is very high due to high proportion of carbon and low moisture. Used in production of coke and gas. Anthracite Coal Best quality; hard coal. 80 to 95 per cent carbon. Very little volatile matter. Negligibly small proportion of moisture. Semi-metallic lustre. Ignites slowly == less loss of heat == highly efficient. Ignites slowly and burns with a nice short blue flame. [Complete combustion == Flame is BLUE == little or no pollutants. Example: LPG] In India, it is found only in Jammu and Kashmir and that too in small quantity. Distribution of Coal in India Gondwana coal fields [250 million years old] Tertiary coal fields [15 – 60 million years old] Gondwana Coal Gondwana coal makes up to 98 per cent of the total reserves and 99 per cent of the production of coal in India. Satpuras, denudation [weathering + erosion] has exposed coal bearing Gondwana strata. The carbon content in Gondwana coal [250 million years old] is less compared to the Carboniferous coal [350 million years old][Almost Absent in India] because of its much younger age. Gondwana coal forms India’s metallurgical grade as well as superior quality coal. The Damuda series (i.e. Lower Gondwana) possesses the best worked coalfields accounting for 80 per cent of the total coal production in India. 80 out of 113 Indian coalfields are located in the rock systems of the Damuda series [lower Gondwana Age]. Coking as well as non-coking and bituminous as well as sub-bituminous coal are obtained from Gondwana coal fields. Anthracite is generally not found in the Gondwana coal fields. The volatile compounds and ash (usually 13 – 30 per cent) and doesn’t allow Carbon percentage to rise above 55 to 60 per cent. [It requires few million years more if the quality has to get better. Remember Gondwana coal is 100 million years younger than Carboniferous coal]. Gondwana coal is free from moisture, but it contains Sulphur and Phosphorous. These basins occur in the valleys of certain rivers viz., the Damodar (Jharkhand-West Bengal); the Mahanadi (Chhattisgarh-Odisha); the Son (Madhya Pradesh Jharkhand); the Godavari and the Wardha (MaharashtraAndhra Pradesh); the Indravati, the Narmada, the Koel, the Panch, the Kanhan and many more. Distribution of Gondwana Coal in India First coal mine was opened in 1774 at Raniganj in West Bengal. Coal industry was nationalized in 1973-74. [The present government made some serious changes during the last year [2015] by allowing private sector to play a bigger role in coal production]. India is now the third largest coal producer in the world after China and the USA. Coal industry provides employment to nearly seven lakh persons. Gondwana Coalfields == exclusively found in the Peninsular plateau of India. Gondwana Coalfields in Chhattisgarh Coalfield Extent Korba coalfield Korba district. Birampur coalfield Hasdo-Arand coalfield Surguja district. Chirmiri coalfield Lakhanpur coalfield Jhilmili coalfield Shandol district & Koriya district Johilla coalfield Johilla valley Sonhat coalfield Surguja district Tatapani-Ramkota coalfields Surguja district Gondwana Coalfields in Jharkhand 1st in reserves [28%]. 2nd in production [20%]. Most of the coal fields are located in a narrow belt running in east-west direction. Major coalfields are present in Dumka (Santhal Parganas), Hazaribagh, Dhanbad and Palamu. Jharia, Bokaro, Girdih and Karanpura are the major coal fields Jharia coalfield Danbad district Jayanti coalfields One of the oldest and the richest coalfields of India; store house of the best metallurgical coal [coking coal] inferior quality and has high ash content Bokaro coalfield West Bokaro [900 m deep] It is a long but narrow strip in the catchment area of the Bokaro river. East Bokaro [600 m deep] Girdih (Karharbari) coalfield Hazaribagh district Gives out of the finest coking coal in India for metallurgical purposes. Karanpura and Ramgarh coalfields Auranga coalfield Hutar coalfield Palamu district inferior quality; used in cement furnaces and brick kilns Deltenganj coalfield Devgarh coalfields Dumka district inferior quality Rajmahal coalfield Rajmahal hills inferior quality Coalfield locations can be asked in Prelims. Gondwana Coalfields in Odisha Ranks second in reserves (24,374 million tonnes) after Raniganj; Talcher field Talcher town to Rairkhol in Dhenkanal and Sambalpur districts Coal from this field is most suitable for steam and gas production. Most of the coal is utilised in thermal power and fertilizer plants at Talcher. Rampur-Himgir coalfields Sambalpur and Sundargarh Coal occurs here in middle and lower Barakar seams. inferior quality Ib river coalfield Sambalpur and Jharsuguda district Much of the coal is of inferior quality. Gondwana Coalfields in Madhya Pradesh largest coalfield of Madhya Pradesh Singrauli (Waidhian) coalfield Sidhi and Shandol districts Jhingurda, Panipahari, Khadia, Purewa and Turra are important coal seams Jhingurda with a total thickness of 131 m is the richest coal seam of the country. thermal power plants at Singrauli and Obra Pench-Kanhan- Chhindwara district Ghoravari seam in Kanhan field is 4.6 m thick and Tawa contains coking coal Sohagpur coalfield Shandol district Umaria coalfield Umaria district inferior quality with high percentage of moisture and ash. Gondwana Coalfields in Andhra Pradesh 6th in reserves [7.07 %]. 5th in production [9.69 %]. Most of the coal reserves are in the Godavari valley. Adilabad, Karimnagar, Warangal, Khammam, East Godavari, and West Godavari. The actual workable collieries are situated at Singareni and Kothagudam. Almost the entire coal is of non-coking variety. These are the southern most coalfields of India and a source of coal supply to most of south India. Gondwana Coalfields in Maharashtra 3 per cent reserves. 7 per cent of the production. Gondwana Coalfields in West Bengal 4 % of India’s coal. 11 % of the coal reserves. Darjeeling and Jalpaiguri are the chief producing districts. RANIGANJ is the largest coalfield of West Bengal. Raniganj == Barddhaman, Bankura and Purulia districts; Small part of this field is in Jharkhand state. The coal here is non-coking steam coal. Dalingkot coalfield == Darjeeling district. Gondwana Coalfields in Uttar Pradesh Do not possess coal reserves. A small portion of the Singrauli field of Madhya Pradesh falls within Mirzapur district. A high grade coal seam, about 1 to 1.5 m thick occurs near Kotah. Tertiary Coal Tertiary coal 15 to 60 million years old. Carbon content is very low. Mainly confined to the extra-Peninsula [Jammu and Kashmir, Himachal Pradesh, Assam, Arunachal Pradesh etc.] Coal generally has low carbon and high percentage of moisture and Sulphur.[It takes few hundred million years for the carbon content to improve]. Important areas of Tertiary coal include parts of Assam, Meghalaya, Arunachal Pradesh, Nagaland, Himalayan foothills of Darjeeling in West Bengal, Jammu and Kashmir, Uttar Pradesh, Rajasthan, Kerala, Tamil Nadu and the union territory of Pondicherry also bear tertiary coal reserves [exceptions]. Tertiary Coalfields in Assam Makum, Nazira, Mikir Hills, Dilli-Jeypore and Lakhuni. Makum coalfield in Sibsagar district is the most developed field. Assam coals contain very low ash and high coking qualities but the sulphur content is high, as a result of which this coal is not suitable for metallurgical purposes. But these coals are best suited for hydrogenation process and are used for making liquid fuels. Tertiary Coalfields in Arunachal Pradesh Upper Assam Coal belt extends eastwards as Namchick-Namrup coalfield. High in volatiles and in sulphur. Tertiary Coalfields in Meghalaya Garo, Khasi and Jaintia hills. Darrangiri field == Garo hills. Siju, Cherrapunji, Liotryngew, Maolong and Langrin coalfields == Khasi and Jaintia hills. Tertiary Coalfields in Jammu and Kashmir, Himachal Pradesh Kalakot and surrounding regions in Jammu, south of Pirpanjal. Himachal Pradesh == Chamba district. Tertiary Coal – Lignite Tamil Nadu, Gujarat, Jammu and Kashmir, Kerala, Rajasthan, West Bengal and Puducherry. Tamil Nadu excels all other states regarding reserves and production of lignite. Lignite in Tamil Nadu 90 per cent of the reserves. 57 per cent of the production. Neyveli Lignite fields of Cuddalore district. These are the largest deposits of lignite in south – east Asia. Neyveli mines suffer from the artesian structure [mining goes deep and deep]. Mining in Lignite coalfields is risky due to SPONTANEOUS COMBUSTION of lignite. Lignite in Gujarat and Rajasthan Kachchh district and Dharuch district; poor quality. Rajasthan == Palana in Bikaner district; The 250 MW thermal plant at Bikaner wholly depends upon lignite as the basic fuel. Tertiary Coal – Peat Confined to a few areas only. Occurs in Nilgiri hills. Kashmir valley, peat occurs in the alluvium of the Jhelum. In West Bengal peat beds are noted in Kolkata and its suburbs. In the Ganga delta, there are layers of peat which are composed of forest and rice plants. Problems of Coal Mining in India The distribution of coal is uneven. High ash content and low caloric value. Large percentage of coal is taken out from underground mines. [Very few open cast mines] Heavy losses due to fires in the mines. Pilferage at several stages also adds to losses – bad transportation infrastructure. Serious problem of environmental pollution. High ash, moisture == more smoke. Safety measures against environmental pollution are very costly. Clean coal technology == Complex technology. Misuse of good quality coal for burning into transport and industries. Short life of metallurgical coal. Selective mining leading to large scale wastage of raw coal Unscientific method of extraction of coal. Measures to be taken Coking coal should be used for metallurgical industry only. Low grade coal should be washed and blended with superior quality coal in requisite proportion and used in industries. [Clean Coal Technology] Selective mining should be discouraged and all possible coal from the mines should be taken out. New reserves should be discovered and new techniques should be adopted. Alternative energy sources should be encouraged. Coking Coal vs. Non-Coking Coal Coking Coal or Metallurgical Coal Thermal Coal or Non-Coking Coal or Steaming coal High carbon content, less moisture, less Sulphur content is high and hence cannot be used in iron and steel sulphur, less ash. industry. Sulphur is very bad for iron and steel industry. Used to create coke. Creating coke using this coal is not Coke is produced by heating bituminous economical. coal without air to extremely high temperatures. Moreover traces of sulphur will remain even after coking. Coking == flushing out impurities and improving the concentration of carbon. Coking coal is an essential ingredient in steel production. Major producers: Australia, Canada, United States. Major exporters: Australia, Canada, United States. China imports huge amount of coking coal from Australia. India also imports coking coal. Coal Reserves in India by State Thermal coal is used to generate power. Major producers: China, Australia, USA, Russia. Major exporters: Australia, South Africa. Name of the state Reserves in billion tonne % of total reserves 1. JHARKHAND 80.71 26.76 2. ODISHA 75.07 24.89 3. CHATTISHGARH 52.53 17.42 4. WEST BENGAL 31.31 10.38 5. MADHYA PRADESH 25.67 8.51 6. ANDHRA PRADESH 22.48 7.45 7. MAHARASTRA 10.98 3.64 8. OTHERS 2.81 0.95 Coal Production in India by State All data from 2013-2014. For latest data you must follow newspapers or Reports published by Ministry of Coal. Remember top 3 positions in all data below. Coking Coal Production by State Jharkhand [More than 90% of India’s Coking coal comes from Jharkhand] West Bengal Madhya Pradesh Non Coking Coal Production By State Chhattisgarh Odisha Madhya Pradesh Jharkhand Andhra Pradesh Total Coal Production By State Chhattisgarh Jharkhand Odisha Madhya Pradesh Andhra Pradesh India’s Coal Imports and Exports Major Coalfields in India Major Coalfields in India 1. Singrauli 2. Karanpura Bokaro 3. Jharia 4. Raniganj 5. Ib & Talcher 6. Pench & Kanhan 7. Singareni – Godavari Velley 8. Lignite: TN, Gujrat And Rajasthan