BCLN CHEMISTRY 11 - Rev. July/2014 Unit 3 ~ Learning Guide Name: Instructions: Using a pencil, complete the following notes as you work through the related lessons. Show ALL work as is explained in the lessons. You are required to have this package completed BEFORE you write your unit test. Do your best and ask questions if you don’t understand anything! Combining Capacity and Naming Compounds: 1. Certain groups (columns) on the periodic table have combining capacities (also known as charges) that you should memorize. Understanding that there is a pattern to these charges will help you do that. Fill in the table below to see the pattern. Period Combining Capacity +1 1 +2 2 +3 13 14 Do not usually form ions but if they do the charge is +4 or -4 -3 15 -2 16 -1 17 18 Do not form ions! Page 1 of 10 BCLN CHEMISTRY 11 - Rev. July/2014 2. Determine the combining capacity of iron in the compound FeCl3. Show your work! Fe + 3Cl = 0 Fe + 3 (-1) = 0 Fe + (-3) = 0 Fe = +3 3. Determine the combining capacity of lead in the compound Pb3P2. Show your work! 3Pb + 2P = 0 3Pb + 2 (-3) = 0 3Pb + (-6) = 0 3Pb = 6 Pb = +2 4. Provide names for the following Group 1/2 Ionic Compounds Formula Name Beryllium oxide BeO Barium phosphide Ba3P2 5. Provide names for the following Molecular/Covalent Compounds Formula Name SiO4 Silicon tetroxide Trinitride monoxide N3O Triphosphide octoxide P3O8 Page 2 of 10 BCLN CHEMISTRY 11 - Rev. July/2014 6. There are a number of chemicals which have common names that you should know. Fill in the table below to help you memorize these. Use the internet to find a food that each of these is found in or something they are used for. Formula CH3OH C2H5OH C6H12O6 C12H22O11 H2O H2O2 O3 NH3 Name Food or Use Methanol Used as a pesticide Bear ethanol Glucose Candy sucrose Brown sugar Apple Juice water Hydrogen Peroxide Used for food disinfection ozone Vegetables disinfection Ammonia Used as a fertilizer Writing the Formula of a Compound: 1. Provide formulas for the following Ionic Compounds. Use the work box to show how you balanced the combining capacities. Name Work Formula Mg(+2)+O(-2)=0 Mg + O = 0 MgO magnesium oxide aluminum sulfate Al(+3) + S(-2) =0 2Al + 3S = 0 Al2S3 iron (III) hydroxide Fe(+3) + H(-1) = 0 Fe+ 3H = 0 FeH3 Page 3 of 10 BCLN CHEMISTRY 11 - Rev. July/2014 2. Provide formulas for the following Covalent Compounds. Name Formula fluorine monobromide FBr pentasulfur heptaselenide S5Se7 carbon tetrachloride CCl4 3. If you see H2O at the end of a compound's formula what word must go at the end of the compound's name? hydrate . Multivalent Metals and Polyatomic Ions: 1. Provide names for the following Ionic Compounds which contain multivalent metal. Use the work box to show how you determined the correct Roman Numeral to use. Formula Work Name Cobalt(Ⅱ) sulfide FeS Fe + S = 0 Fe + (-2) = 0 Fe = + 2 Ni2O3 2Ni + 3(-2) = 0 2Ni = 6O Ni = + 3 nickel(Ⅲ) oxide PtO2 Pt + 2O = 0 Pt + 2(-2) = 0 Pt = + 4 Platinum(Ⅳ) oxide Sb3P5 3Sb + 5P = 0 3Sb + 5(-3) = 0 3Sb = 15P Sb = +5 Page 4 of 10 antimony(Ⅴ) phosphide BCLN CHEMISTRY 11 - Rev. July/2014 2. What prefix is used as a replacement for the word hydrogen in some polyatomic ions? Bi 3. Name the following ternary compounds. The easy way to recognize that these are all ternary compounds is that they all contain at least 3 elements which means the formula will have at least 3 capital letters. Remember to use your data table to name the polyatomic ions correctly. Some of these will require roman numerals but some will NOT. If a roman numeral is required show your work. Formula Work Name AuClO Au + ClO(-1) = 0 Au + (-1) = 0 Au = +1 gold(Ⅰ) hypochlorite ( Sr3 PO4)2 Bi(CN)5 Hg3PO4 3Sr + 2 PO4 = 0 3Sr + 2(-3) = 0 3Sr = 6 Sr = +2 Bi + 5 CN = 0 Bi + 5(-1) = 0 Bi = +5 3Hg + PO4 = 0 3Hg + (-3) = 0 3Hg = 3 Hg = +1 strontium phosphate Bismuth(Ⅴ) cyanide Mercury(Ⅰ) phosphate CaSO3 Ca + SO3 = 0 Ca + (-2) = 0 Ca = +2 Calcium sulphite (NH4)2S 2NH4 + s = 0 2(-1)+S = 0 S=+2 Ammonium sulfide Na3BO3 3Na + BO3 = 0 3Na + (-3) = 0 Na = -1 Sodium borate Page 5 of 10 BCLN CHEMISTRY 11 - Rev. July/2014 Names and Formulas of Acids 1. Name the following acids. Remember to use the prefix hydro if the acid contains a simple element. If the acid contains a polyatomic ion you change an ate ending to ic and you change an ite ending to ous. Formula Name H2S Hydrosulfuric acid H2SO4 Sulfuric Acid H2SO3 Sulfurous acid 2. Provide formulas for the following acids. Be sure to use the correct number of hydrogen atoms to match the charge on the negative ion. Name Formula hydroiodic acid HClO hydrophosphoric acid HOCl phosphoric acid H3PO4 nitrous acid HNO2 3. Acids formulas usually start with H. Organic acids however will END with an H. What is the name and formula of the polyatomic ion that you will always find at the end of a base? Page 6 of 10 BCLN CHEMISTRY 11 - Rev. July/2014 Overall Unit 3 Review: 1. Name or write the formula & state whether the substance is Ionic (M), Ionic (I), Acid (A), Element (E). Note that (aq) simply means the compound dissolves in water and will not affect the name 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. Type M, I, A or E Chemical Name Chemical Formula M sodium chloride NaCl M Calcium Carbonate CaCO3 I nickel (III) bisulfate NiS2 A sodium hydroxide NaOH M Calcium oxide CaO M Magnesium Sulfate heptahydrate MgSO4•7H2O M carbon dioxide CO2 A acetic acid CH3COOH E carbon C M calcium sulfate CaSO4 M Sodium silicate Na2SiO3 M Calcium bicarbonate Ca(HCO3)2 Page 7 of 10 BCLN CHEMISTRY 11 - Rev. July/2014 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. M magnesium hydroxide Mg(OH)2 M potassium chloride KCl M sodium thiosulphate pentahydrate NaS2O3 5H2O M sodium hypochlorite NaClO M Sodium carbonate Na2CO3 A Hydrogen chloride HCl (aq) M potassium nitrate KNO2 M Copper sulphate pentahydrate CuSO4•5H2O E magnesium Mg M magnesium oxide MgO M Potassium iodide KI A Sulfuric acid H(aq) M silicon monocarbide SiC E Iron Fe M Ammonium chloride NH4Cl Page 8 of 10 BCLN CHEMISTRY 11 - Rev. July/2014 It is important that you are able to count the number of each type of atom in a formula. Each atom will have as many as 3 numbers that "belong" to it. If a number comes directly after the atom then it belongs to that atom. If an atom is inside a bracket then the number after the bracket belongs to that atom. Finally if there is a number in front of the compound (known as a coefficient) then that number belongs to all of the atoms. Here is an example: 3 Fe2(SO4)3 Fe: Fe has its own number 2 and the 3 at the front. Therefore we have 3 x 2 = 6 Fe atoms S: S does not have its own number which means you start with 1. However it is inside the bracket and you have a 3 out front. Therefore we have 1 x 3 x 3 = 9 S atoms O: O has its own number 4, the 3 after the bracket and the 3 in front. Therefore we have 4 x 3 x 3 = 36 O atoms 2. Determine the number of each type of atom in the following compounds. Show your work where appropriate (which numbers you multiplied to get each atom) Formula Atoms CuBr2 1 Cu atom, 2 Br atoms Ca(MnO4)2 1 Ca atom, 2 Mn atoms, 8 O atoms 2 CH3COOH 4 Hf(HPO4)2 4 C atoms, 4 O atoms, 8 H atoms 4 Hf atoms, 8 H atoms, 8 P atoms, 32 O atoms 2. A sample of Zr(H2PO4)4 that contains 6 000 oxygen atoms must also contain how many hydrogen atoms? Hint use a unit conversion to convert from O atoms to H atoms Each Zr(H2PO4)4 has 16 oxygen atoms 375 numbers of Zr(H2PO4)4 have 6000 oxygen atoms 375 × 4 × 2 = 3000 Answer is 3000 hydrogen atoms Page 9 of 10 BCLN CHEMISTRY 11 - Rev. July/2014 Answers: Combining Capacity and Naming Compounds: 1. +1, +2, +3, None, -3, -2, -1 2. +3 3. +2 Multivalent Metals and Polyatomic Ions: 1. These are the correct Roman Numerals: II, III, IV, and V 3. Three of the formulas require Roman Numerals. They are I, V and I Overall Unit 3 Review: 1. 20) Roman Numeral is II 2. Formula Atoms CuBr2 1 Cu atom, 2 Br atoms Ca(MnO4)2 1 Ca atom, 2 Mn atoms, 8 O atoms 2 CH3COOH 4 C atoms, 4 O atoms, 8 H atoms 4 Hf atoms, 8 H atoms, 8 P atoms, 32 O atoms 4 Hf(HPO4)2 3. 3000 H atoms Page 10 of 10