Polymer Terms Shortlist Study online at quizlet.com/_811skn 1. Addition polymerization 5. process where monomer molecules add to a growing polymer chain one at a time (i.e. polyvinyl Chloride -PVC and polytetrafluoroethylene - Teflon) 2. Condensation polymerization process involving the reaction of monomer molecules that produces a polymer chain and chemical by-products that do not form part of the chain structure (i.e. epoxy and phenolic resin) 6. Copolymer Amorphous a polymer whose chemical structure consists of long chains of two chemically different monomers, which repeat at more or less regular intervals in the chain no long-range order in the positions and arrangement of the molecular chains 3. 7. Atactic Crosslinks polymer chain configuration in which the side groups are positioned randomly on one or the other side of the polymer back-bone 4. Block copolymer covalent bonds linking one polymer chain to another chain 8. polymer formed when two different types of monomers are linked in the same polymer chain and occur as alternating sequences of each type Crystalline polymer with a regular order or pattern of molecular arrangement 9. Elastomer 14. Matrix phase of fiber composites a type of polymer with a coiled molecular chains that are crosslinked 10. Glass transition temperature most common use for polymers, accounts for 40-45% of the total volume of the material 15. Molecular weight temperature at which a reversible change occurs in a polymer when it is heated to a certain temperature and undergoes a transition from a hard and glassy to a soft and ductile condition 11. Graft copolymer a number defining how heavy one molecule (or unit) of a chemical is compared with the lightest element, hydrogen, which has a weight of 1 a special type of branched copolymer with the main backbone to the chain composed of one type of monomer while the branches are composed of a chemically different monomer 12. 16. Monomer Homopolymer chemical compound that can undergo polymerization, which is a chemical reaction in which two or more molecules combine to form a larger molecule that contains repeating units polymer which is formed from only one type of monomer 13. 17. Isotactic Polycarbonates polymer chain configuration in which the side groups are all located on the same side of the polymer back-bone thermoplastics that are transparent, tough, and impact resistant, used for cockpit windows and canopies 18. Polymerization 21. Syndiotactic polymer chain configuration in which the side groups are located at alternate positions along the polymer backbone 22. chemical reaction in which small molecules combine to form a larger molecule that contains repeating units of the original molecules. It is a process of reacting monomer molecules together in a chemical reaction to form linear chains or a threedimensional network of polymer chains 19. Tensile strength of polymers is controlled by: Stress rupture increasing degree of polymerization, increasing the size of side groups attached to the main chain, increasing the amount of chain branching, increasing the degree of crosslinking, and increasing the degree of crystallization 23. Thermoplastic the fracture of a material after carrying a sustained load for an extended period of time; it usually involves viscoelastic deformation ad occurs more rapidly at elevated temperature 20. polymer which may be softened by heat and hardened by cooling in a reversible physical process owing to a the lack of crosslinks between the chains Structural adhesive 24. high strength durable glue with high elastic modulus, strength and toughness that bonds together components in a loadbearing structure, epoxy resin is most often used Thermoset polymer obtained by crosslinking of the chains that make it an infusible and insoluble material 25. Van der Waals bond a weak attractive force between atoms or nonpolar molecules caused by a temporary change in dipole moment arising from a brief shift of orbital electrons to one side of an atom or molecule, creating a similar shift in adjacent atoms or molecules 26. Vulcanization chemical reaction whereby the properties of an elastomer are changed by causing it to react with sulfur or another crosslinking agent