Chemistry For Engineers Lecture Worksheet Prepared by: Engr. Andrew Cesar M. Rimando Chemical Engineer Faculty College of Education and Sciences Lorma Colleges Chemistry for Engineers Worksheet Page 1 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ Significant Figures and Unit Conversion 1. Compute the density of a 5.0 ml computer chip weighing 30 pounds. Express answer in kg/m3 and in g/ml. 2. Compute the volume capacity of a cylinder with an inside diameter of 2.0 cm and an inside length of 1.2 inches. Express answer in cubic centimetre and cubic inch. 3. Going abroad to work as a computer engineer, you are asked to accomplish a form asking for your height in meters. How do you convert your height of 5’ 5” to meters? Express answer in three significant figures. Chemistry for Engineers Worksheet Page 2 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ Significant Figures and Unit Conversion 4. The generally accepted normal body temperature is 37OC. If you are in United Kingdom working in a computer automation company and your body temperature using thermometer there indicates that your temperature is 101 OF, do you have fever or not? 5. Generally people with blood sugar or blood glucose of 4 to 6 mmol/L are considered not diabetic. Those who have much higher are considered diabetic like if your blood glucose level is 10mmol/L specially if you are a computer engineer working without any exercise. If you have an average blood glucose level of 200 mg/dL, are you diabetic? (1mmol/L=18mg/dL) 6. Assuming that blood flows in an aorta near the heart at 1200 mm/s, what is this speed in km per hour and in miles per hour? Chemistry for Engineers Worksheet Page 3 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ Electronic Configuration of Atoms A. As engineers, you should know the basic composition of matter. Write the electronic configuration of the following common atoms (assuming that they are neutral or uncharged) based on their atomic number in the periodic table and indicate their number of valence electrons. 1. Carbon 2. Hydrogen 3. Oxygen 4. Nitrogen 5. Phosphorous 6. Potassium 7. Sulfur 8. Silicon 9. Chlorine 10. Fluorine Chemistry for Engineers Worksheet Page 4 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ Intramolecular Chemical Bonds and Electronegativity A. Draw the Lewis dot structure of the following compounds, indicate if metallic, ionic or covalent bond, determine the difference of electronegativities between bonded atoms and predict their shapes. 1. CO2 2. NaCl 3. CH4 4. Steel 5. HCl Chemistry for Engineers Worksheet Page 5 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ Writing Formula of Inorganic Salts A. Give the formula of the following salts and research one importance of each to our body. 1. potassium phosphate 2. sodium sulphate 3. potassium chloride 4. calcium fluoride 5. magnesium phosphate 6. potassium sulphate 7. ferric phosphate 8. calcium sulphate 9. sodium phosphate 10. calcium phosphate Chemistry for Engineers Worksheet Page 6 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ Naming of Acids and Bases Give the name of the following acids and bases and research on one use each. 1. HSO3F 2. H2SO4 3. Ca(OH)2 4. HCl 5. HNO3 6. NaOH 7. Mg(OH)2 8. H3PO4 9. H2CO3 10. Sr(OH)2 Chemistry for Engineers Worksheet Page 7 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ Writing Structures of Hydrocarbons Write the structural, condense, line and give the molecular formula of the following hydrocarbons and research on one use each: 1. propane 2. butane 3. 1-butyne 4. propene 5. octane Chemistry for Engineers Worksheet Page 8 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ Sigma and Pi Covalent Bonds Indicate if the statement described or is referring to a sigma bond or pi bond with a carbon atom by writing the word sigma or pi. _____________1. The first bond made with any other atom. _____________2. The second or third bond made with any other atom. _____________3. This is the only bond present between carbon atoms of alkanes. _____________4. This bond is present in alkenes and alkynes but not in alkanes. _____________5. This is the bond between carbon and hydrogen in hydrocarbons. _____________6. The weaker bond. _____________7. The stronger bond. _____________8. This bond is made from leftover p orbitals or carbon. _____________9. This bond is made from hybridized orbitals of 2s and 2p orbitals of carbon. _____________10. This is present in double and triple bonds but not in single bond of carbon. _____________11. This is the only bond present in single bonds of carbon. _____________12. This bond is present ONLY when a carbon atom has sp2 or sp hybrid orbitals. _____________13. This bond is the only bond when a carbon atom has only sp 3 hybrid orbitals. _____________14. This bond is not present in methane. _____________15. This bond is represented by the 18th letter of Greek alphabet. Chemistry for Engineers Worksheet Page 9 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ Writing Structures of Organic Functional Groups (alcohol and aldehyde) Write the structural, condense, line and give the molecular formula of the following organic compounds and research on one use each: 1. 2-propanol (isopropyl alcohol) 2. glycerol (glycerine, triol) 3. butanal (butyraldehyde) 4. propanal 5. ethylene glycol Chemistry for Engineers Worksheet Page 10 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ Intermolecular Forces Indicate whether the statement is describing the following intermolecular forces, hydrogen bonding, dipole-dipole, ion-dipole, ion-induced dipole, London dispersion forces. Note: The van der Waals’ forces like hydrogen bonds and London dispersion forces is a general term for intermolecular interactions that do not involve covalent bonds or ions. _____________1. The force of attraction between the lone pair of an electronegative atom and a hydrogen atom that is bonded to nitrogen, oxygen or fluorine. _____________2. This bond maybe described as a strong electrostatic dipole-dipole interaction involving hydrogen. _____________3. This bonding is the reason why water has a high boiling point. _____________4. This bond is also the one that connects the two strands of DNA, between adenine and thymine and between guanine and cytosine. _____________5. This is between the positive end of one polar molecule and the negative end of another polar molecule. _____________6. The partially positive end of a polar molecule is attracted to the partially negative end of another. _____________7. An example of this is the attractive forces between HCl molecules. _____________8. This force is an attractive force that results from the electrostatic attraction between an ion and a neutral molecule that has a dipole (polar molecule). _____________9. An example of this is the force generated between polar water molecule and a sodium ion. _____________10. This force consists of an ion and a non-polar molecule interacting. _____________11. An example of this is a phosphide ion interacting with oxygen molecule in water. _____________12. This is considered the weakest intermolecular force. _____________13. These forces are found between noble gases and between non-polar molecules. _____________14. This results when the electrons in two adjacent atoms of different molecules occupy positions that make the atoms form temporary dipoles. _____________15. This force is sometimes called induced dipole-induced dipole attraction. Chemistry for Engineers Worksheet Page 11 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ Writing Structures of Organic Functional Groups (ketones and carboxylic acid) Write the structural, condense, line and give the molecular formula of the following organic compounds and research on one use each: 1. 2-butanone (ethyl methyl ketone) 2. diacetyl (butanedione) 3. butanoic acid (butyric acid) 4. hexanoic acid (caproic acid) 5. lauric acid (dodecanoic acid) Chemistry for Engineers Worksheet Page 12 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ Writing Structures of Organic Functional Groups (ethers and esters) Write the structural, line and give the molecular formula of the following organic compounds and research on one use each: 1. diethyl ether 2. dimethyl ether 3. ethyl hexanoate 4. butyl propanoate 5. ethyl heptanoate Chemistry for Engineers Worksheet Page 13 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ Writing Structures of Organic Functional Groups (amine and amide) Write the structural and line formula then give the molecular formula of the following organic compounds and research on one use each: 1. ethylamine 2. diethylamine 3. dimethylamine 4. propanamide 5. ethanamide Chemistry for Engineers Worksheet Page 14 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ Writing Structures of Organic Functional Groups (alkyl halide) Write the structural formula and give the molecular formula of the following organic compounds and research on one use each: 1. dichloromethane 2. carbon tetrachloride 3. CFC-11 or R-11 or Freon-11 4. chloroform 5. R134A or 1,1,1,2-tetrafluoroethane Chemistry for Engineers Worksheet Page 15 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ Give the name of the following organic compounds: 1. 2. 3. 4. 5. Chemistry for Engineers Worksheet Page 16 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ 6. 7. 8. 9. 10. Chemistry for Engineers Worksheet Page 17 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ 11. 12. 13. 14. 15. Chemistry for Engineers Worksheet Page 18 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ Molar Mass Calculate the molar mass of the following compounds. 1. Aspirin 2. Amphetamine 3. isopropyl alcohol 4. ethanoic acid 5. guanine Chemistry for Engineers Worksheet Page 19 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ Moles and Molar Mass Calculate the moles of the following: 1) 50 grams of butane 2) 100 grams of hydrochloric acid 3) 150 grams of water 4) 200 grams of carbon dioxide 5) 250 grams of ethanol Chemistry for Engineers Worksheet Page 20 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ Mass and Molar Mass Calculate the mass of the following: 1. 50 moles of glucose 2. 5 moles of sucrose C12H22O11 3. 20 moles of sodium chloride 4. 5 moles of nitric acid 5. 6 moles of carbonic acid Chemistry for Engineers Worksheet Page 21 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ Chemical Reaction and Balancing Write the chemical reaction equation of the following then balance them. 1. Pentane is burned with oxygen gas to produce carbon dioxide and water. 2. During photosynthesis carbon dioxide reacts with water to produce glucose and oxygen gas. 3. Iron reacts with silver chloride in an aqueous solution to form silver metal and ferric chloride. 4. Ethyl alcohol is oxidized in our stomach to produce ethanal. 5. Barium sulphate is precipitated when barium chloride reacts with sodium sulphate. Chemistry for Engineers Worksheet Page 22 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ 6. Calcium carbonate is decomposed in high heat to calcium oxide and carbon dioxide. 7. Magnesium metal reacts with oxygen gas to form magnesium oxide. 8. Propanoic acid reacts with ethanol to produce ethyl propanoate and water 9. Hydrogen peroxide is decomposed to water and oxygen gas. 10. Nitric acid reacts with copper to produce copper(II) nitrate, nitrogen dioxide and water. Chemistry for Engineers Worksheet Page 23 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ Molarity, Molality and Normality 1. What is the molarity of a 2 L solution containing 5 moles of solute? 2. What is the molality of a solution containing 20 moles of solute dissolved in 5 kg of solvent? 3. What is the normality of a 5 Liter solution that contains 5 moles of calcium hydroxide? 4. How many moles solute are there in 2 Liters of 5M solutions? 5. What is the volume of a 5M solution containing 2 moles of solute? Chemistry for Engineers Worksheet Page 24 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ 6. What is the final concentration of a 5M solution with a volume of 2 L if 3 L of water is added? 7. If 100 grams of sucrose is added to water to form a 500 ml solution, what is its molarity? 8. What is the mass of carbon dioxide that is dissolved in 200 ml of 2M solution? 9. How much water should you add to a 10M solution with a volume of 500 ml to reduce its concentration to 8M? 10. If you mix 500 ml of 2M solution to 300 ml 5M solution, what will be the final concentration? Chemistry for Engineers Worksheet Page 25 Score: ___________ Surname: _________________________________ Date Submitted: _____________________ First Name: ________________________________ Course, Year and Section: ______________ Electrochemistry 1. Lithium battery is now being used in most computer power storage application because it lasts longer and has lesser maintenance cost. Write the half cell reactions, potentials and the complete reaction of a lithium ion battery. 2. Write the chemical reactions and electric potentials of an alkaline battery. 3. Write the half cell reactions, potentials and the complete reaction of car lead battery. Inorganic and Organic Chemistry Worksheet Appendix Page 26 SI BASE UNITS 1. Meter (m) is the length of the path traveled by light in vacuum during a time interval of 1/299,792,458 of a second. 2. Kilogram (kg) is the unit of mass; it is equal to the mass of the international prototype of the kilogram –a platinum iridium cylinder kept in France. 3. Second (s) is the duration of 9,192,631,770 periods of the radiation corresponding to the transition between the two hyperfine levels of the ground state of the cesium 133 atom. 4. Ampere (A) is that constant electric current which, if maintained in two straight parallel conductors of infinite length, of negligible circular cross-section, and placed 1 meter apart in vacuum, would produce between these conductors a force equal to 2 x 10-7 Newton per meter of length. 5. Kelvin (K), unit of thermodynamic temperature, is the fraction 1/273.16 of the thermodynamic temperature of the triple point of water. 6. Mole (mol) is the amount of substance of a system which contains as many elementary entities as there are atoms in 0.012 kilogram of carbon 12; its symbol is "mol." When the mole is used, the elementary entities must be specified and may be atoms, molecules, ions, electrons, other particles, or specified groups of such particles. 7. Candela (cd) is the luminous intensity, in a given direction, of a source that emits monochromatic radiation of frequency 540 x 1012 hertz and that has a radiant intensity in that direction of 1/683 watt per steradian. Prefixes in the SI System Prefix Symbol Multiple anton yotta zetta exa peta tera giga mega kilo hecto deca deci centi milli micro nano pico femto atto zepto yocto A Y Z E P T G M k h da d c m µ n p f a z y (10100)100 (1010)100 10100 1024 1021 1018 1015 1012 109 106 103 102 101 10-1 10-2 10-3 10-6 10-9 10-12 10-15 10-18 10-21 10-24 English and SI Converstion Factors Common Name antonplex googolplex googol heptillion hexillion quintillion quadrillion trillion billion million thousand hundred ten tenth hundreth thousandth millionth billionth trillionth quadrillionth quintillionth hexillionth heptillionth Inorganic and Organic Chemistry Worksheet Appendix Length: 1 in = 2.54 cm 1 mi = 1.6093 km 1 m = 3.2808 ft Volume: 1 gal = 3.7854 L 1 fluid ounce (fl oz) = 29.574 ml 1 teaspoon = 5 ml (approximate) 1 tablespoon = 15 ml (approximate) 1 cup = 250 ml (approximate) 1 gallon = 4 quarts 1 quart = 2 pints 1 pint = 2 cups 1 cup = 48 teaspoon 1 cup = 16 tablespoon 1 tablespoon = 3 teaspoon Mass: 1 kg = 2.2046 lb 1 oz = 28.35 g 1 MT = 1000 kg Temperature: o F = 1.8oC + 32 o C = (oF – 32)/1.8 K = 273.15 + oC o R = 460 + oF Scientific Notation – used to simplify the handling of cumbersome values - expressed in the form N = a x 10n Derived Units: volume, density Page 27 Inorganic and Organic Chemistry Worksheet Appendix Page 28 SIGNIFICANT FIGURES Definition: The digits that indicate the precision with which a measurement is used All digits of a measured quantity are significant, including the last digit, which is uncertain Guidelines applied to determine the number of significant figures in a measured quantity 1. All non-zero digits are significant 2. Zeroes between non-zero digits are significant 3. Zeroes to the right of the decimal point but to the left of the first non-zero digit are not significant 4. Zeroes to the right of a non-zero digit and to the right of a decimal point are significant 5. When a number ends in zero but contains no decimal point, the zeroes may or may not be significant. Exponential notation is used to avoid potential ambiguity of whether the zeroes are significant or not. 6. Always carry one or two additional significant figures through a multi-step calculation and round off to the desired number of significant figures the final answer only. Conversion Factor – fraction whose numerator and denominator are the same quantity expressed in different units Dimensional Analysis - approach in problem-solving in which the units or dimensions of the quantities are examined to see what conversions are required - uses conversion factor to change one unit to another Inorganic and Organic Chemistry Worksheet Appendix Electronic Configuration, Orbitals and Quantum Numbers Naming of Ionic Compounds or Salts Page 29 Inorganic and Organic Chemistry Worksheet Appendix Page 30 Ionic Compounds are composed of cation and anion joined together by an ionic bond due to the attraction of positive to negative charges. The cation (positively charged ion, normally metal) name retains the same name as the element. The anion (negatively charged ion, normally non-metal) name is similar to the name of the element but the ending is replaced by “-ide” like chloride, oxide, fluoride, carbide, sulphide, etc. For polyatomic ions (composed of two or more atoms covalently bonded/molecular ion), they retain the same names like ammonium hydroxide, potassium chromate, etc. Following are some common polyatomic ions. If a metallic element has cations of different charges (or different oxidation states), the Stock System can be used by including the Roman Numeral (representing its charge) in parentheses after its name like copper(II) chloride. An older method uses the Latin name and suffix “ic” for higher charge and “ous” for lower charge like the following. Inorganic and Organic Chemistry Worksheet Appendix Page 31 Naming Inorganic Acids and Bases The cation of an inorganic acid is the hydrogen ion. In binary acids (with one anion), the prefix is “hydro” plus the name of the ion whose ending becomes a suffix “ic” plus the word acid. For acids with polyatomic anions, the suffix “ate” is replaced with “ic” and those with suffix “ite” with “ous”. Those with one extra oxygen have the prefix “per” and suffix “ic”. Those with one fewer oxygen have the prefix “hypo” and the suffix “ous”. The anion for inorganic bases is the hydroxide, a polyatomic ion. The naming is the same as the rules in naming ionic compounds. For example Mg(OH)2 is named magnesium hydroxide Inorganic and Organic Chemistry Worksheet Appendix Page 32 Naming of Molecular Inorganic Compounds Molecular compounds are composed of two or more atoms of elements that are covalently bonded by sharing valence electrons. Normally it is between atoms of non-metals. When naming molecular compounds, prefixes are used to indicate the number of a given element present in the compound. ” mono-” indicates one, “di-” is two, “tri-” is three, “tetra-” is four, “penta-” is five, and “hexa-” is six, “hepta-” is seven, “octo-” is eight, “nona-” is nine, and “deca” is ten. For example, N2O is called dinitrogen monoxide. If the first element has only one atom, the prefix “mono” does not have to be included or may be dropped. For example NO2 is called nitrogen dioxide and NOT mononitrogen dioxide. If the second element is one atom of oxygen or any atom beginning with a vowel, instead of naming it monooxide, it is named monoxide. One of the “o” is dropped. Normally, the less electronegative atom is written first before the more electronegative ion. Following are other examples. Naming Inorganic Hydrates Hydrates are compounds that contain loosely bonded water. An example is CuSO4 · 5H2O which is a blue colored compound. Anhydride is a hydrate that has lost water through many means like heating. Anhydrous is a substance that does not contain or not linked to any water. Hydrates are named by naming first the compound where the water is attached then followed by numerical Latin prefix that indicates the number of water molecules attached and the suffix “hydrate”. For example CuSO4 · 5H2O is named of copper(II) sulphate pentahydrate. Inorganic and Organic Chemistry Worksheet Appendix Page 33 Naming Organic Compounds Organic compounds are generally named based on the number of carbons in its longest chain and on its branches. The IUPAC (International Union of Pure and Applied Chemistry) is the internationally acceptable system of organic nomenclature. However, many chemists still use common names which are shorter sometimes. The prefixes based on the number of carbons are as follows: 1 2 3 4 5 6 7 meth eth prop but pent hex hept 8 9 10 11 12 13 14 oct non dec undec dodec tridec tetradec 15 16 17 18 19 20 30 pentadec hexadec hepta octadec nondec eicos triacont Naming is also based on the following functional groups. 40 50 60 70 80 90 100 tetracont pentacont hexacont heptacont octacont nonacont hect Inorganic and Organic Chemistry Worksheet Appendix Many organic compounds have also branches as follows: Below are examples of aromatic organic compounds. Page 34 Inorganic and Organic Chemistry Worksheet Appendix Page 35 Activity Series of Metals Lithium Potassium Strontium Barium Calcium Sodium Li K Sr Ba Ca Na Magnesium Aluminum Manganese Zinc Chromium Mg Al Mn Zn Cr reacts with steam and acids and forms hydroxides and hydrogen gas Iron Cadmium Cobalt Nickel Tin Lead Fe Cd Co Ni Sn Pb reacts with acids only and forms hydroxides and hydrogen gas reacts with liquid water, steam and acids and forms hydroxides and hydrogen gas Hydrogen gas H2 Antimony Arsenic Bismuth Copper Sb As Bi Cu forms oxides with air Mercury Silver Palladium Platinum Gold Hg Ag Pd Pt Au found free in nature, when heated its oxides decompose Solubility Rules Soluble Compounds Salts of of Group IA, ammonium, chlorate, perchlorate, acetate and nitrate Salts of Cl-, Br- and ICompounds containing F- Exceptions Ag+, Hg2 + and Pb2+ Mg 2+, Ca 2+, Sr 2+, Ba 2+, Pb 2+ Salts of sulfate, SO4 2- Sulfates of Sr 2+, Ba 2+, Pb 2+, slightly soluble are Ca 2+ and Ag 1+ Insoluble Compounds All salts of : carbonate, phosphate, oxalate, chromate, sulfide hydroxide Exceptions Salts of NH4 +, and alkali metal ions Ba 2+, Ca2+(slightly soluble) Inorganic and Organic Chemistry Worksheet Appendix Page 36 Easily Oxidized – Anode-More Reactive Negative Electrode – electrons are lost Easily Reduced – Cathode – Less Reactive Positive Electrode – electrons are gained Standard Reduction Potentials Acidic Solution F2(g) + 2e- → 2 F-(aq) O3(g) + 2H+(aq) + 2e- → O2(g) + H2O(l) S2O82-(aq) + 2e- → 2SO42-(aq) H2O2(aq) + 2H+(aq) +2e- → 2H2O(l) MnO4-(aq) + 8H+(aq) + 5e- → Mn2+(aq) + 4H2O(l) PbO2(s) + 4H+(aq) + 2e- → Pb2+(aq) + 4H2O(l) Cl2(g) + 2e- → 2Cl-(aq) Cr2O72-(aq) + 14H+(aq) + 6e- → 2Cr3+(aq) + 7H2O(l) MnO2(s) + 4H+(aq) +2e- -> Mn2+(aq) + 2H2O(l) O2(g) + 4H+(aq) + 4e- → 2H2O(l) 2IO3-(aq) + 12H+(aq) + 10e- → I2(s) + 6H2O(l) Br2(l) + 2e- → 2Br-(aq) NO3-(aq) + 4H+(aq) + 3e- → NO(g) + 2 H2O(l) Ag+(aq) + e- → Ag(s) Fe3+(aq) + e- → Fe2+(aq) O2(g) + 2H+(ag) + 2e- → H2O2(aq) I2(s) + 2e- → 2I-(aq) Cu2+(aq) + 2e- → Cu(s) SO42-(aq) + 4H+(aq) + 2e- → 2H2O(l) + SO2(g) Sn4+(aq) + 2e- → Sn2+(aq) S(s) + 2H+(aq) + 2e- → H2S(g) 2H+(aq) + 2e- → H2(g) Pb2+(aq) + 2e- → Pb Sn2+(aq) + 2e- → Sn(s) Fe2+(aq) + 2e- → Fe(s) Zn2+ + 2e- → Zn(s) Al3+(aq) + 3e- → Al(s) Mg2+(aq) + 2e- → Mg(s) Na+(aq) + e- → Na(s) Ca2+(aq) + 2e- → Ca(s) K+(aq) + + e- → K(s) Li+(aq) + e- → Li(s) Basic Solution O3(aq) + H2O(l) + 2e- → O2(g) + 2OH-(aq) OCl-(aq) + H2O(l) + 2e- → Cl-(aq) + 2OH-(aq) O2(g) + 2H2O(l) +4e- → 4OH-(aq) 2H2O(l) + + 2e- → H2(aq) + 2OH-(aq) 2.866 2.075 2.01 1.763 1.51 1.455 1.358 1.33 1.23 1.229 1.2 1.065 0.956 0.8 0.771 0.695 0.535 0.34 0.17 0.154 0.14 0 -0.125 -0.137 -0.44 -0.763 -1.676 -2.356 -2.713 -2.84 -2.924 -3.04 1.246 0.89 0.401 -0.0828 Inorganic and Organic Chemistry Worksheet Appendix Solute HF HCl HClO4 HClO4 · H2O HBr HI HIO3 HNO3 HCOOH CH3COOH NH3 NH4Cl NH4ClO4 NH4Br NH4I NH4IO3 NH4NO2 NH4NO3 NH4C2H3O2 NH4CN NH4CNS CH3NH3Cl (CH3)3NHCl N(CH3)4Cl N(CH3)4Br N(CH3)4I AgClO4 AgNO2 AgNO3 LiOH LiOH · H2O LiF LiCl LiCl · H2O LiClO4 LiClO4 · 3H2O LiBr LiBr · H2O g g l c g g c l l l g c c c c c c c c c c c c c c c c c c c c c c c c c c c ∆sol H° kJ/mol -61.50 -74.84 -88.76 -32.95 -85.14 -81.67 8.79 -33.28 -0.86 -1.51 -30.50 14.78 33.47 16.78 13.72 31.80 19.25 25.69 -2.38 17.57 22.59 5.77 1.46 4.08 24.27 42.07 7.36 36.94 22.59 -23.56 -6.69 4.73 -37.03 -19.08 -26.55 32.61 -48.83 -23.26 Enthalpy of Solutions of Electrolytes ∆sol H° Solute kJ/mol LiBr · 2H2O c -9.41 LiBrO3 c 1.42 LiI c -63.30 LiI · H2O c -29.66 LiI · 2H2O c -14.77 LiI · 3H2O c 0.59 LiNO2 c -11.00 LiNO2 · H2O c 7.03 LiNO3 c -2.51 NaOH c -44.51 NaOH · H2O c -21.41 NaF c 0.91 NaCl c 3.88 NaClO2 c 0.33 NaClO2 · 3H2O c 28.58 NaClO3 c 21.72 NaClO4 c 13.88 NaClO4 · H2O c 22.51 NaBr c -0.60 NaBr · 2H2O c 18.64 NaBrO3 c 26.90 NaI c -7.53 NaI · 2H2O c 16.13 NaIO3 c 20.29 NaNO2 c 13.89 NaNO3 c 20.50 NaC2H3O2 c -17.32 NaC2H3O2 · 3H2O c 19.66 NaCN c 1.21 NaCN · 0.5H2O c 3.31 NaCN · 2H2O c 18.58 NaCNO c 19.20 NaCNS c 6.83 KOH c -57.61 KOH · H2O c -14.64 KOH · 1.5H2O c -10.46 KF c -17.73 KF · 2H2O c 6.97 KCl c 17.22 Page 37 Solute KClO3 KClO4 KBr KBrO3 KI KIO3 KNO2 KNO3 KC2H3O2 KCN KCNO KCNS KMnO4 RbOH RbOH · H2O RbOH · 2H2O RbF RbF · H2O RbF · 1.5H2O RbCl RbClO3 RbClO4 RbBr RbBrO3 RbI RbNO3 CsOH CsOH · H2O CsF CsF · H2O CsF · 1.5H2O CsCl CsClO4 CsBr CsBrO3 CsI CsNO3 c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c ∆sol H° kJ/mol 41.38 51.04 19.87 41.13 20.33 27.74 13.35 34.89 -15.33 11.72 20.25 24.23 43.56 -62.34 -17.99 0.88 -26.11 -0.42 1.34 17.28 47.74 56.74 21.88 48.95 25.10 36.48 -71.55 -20.50 -36.86 -10.46 -5.44 17.78 55.44 25.98 50.46 33.35 40.00 Inorganic and Organic Chemistry Worksheet Appendix Name Aluminum Antimony Argon Arsenic Astatine Barium Beryllium Bismuth Boron Bromine Cadmium Calcium Carbon Cerium Cesium Chlorine Chromium Cobalt Copper Dysprosium Erbium Europium Fluorine Francium Gadolinium Gallium Germanium Gold Hafnium Helium Holmium Hydrogen Indium Iodine Iridium Iron Krypton Lanthanum Lead Lithium Lutetium Magnesium Manganese Mercury Symbol Al Sb Ar As At Ba Be Bi B Br Cd Ca C Ce Cs Cl Cr Co Cu Dy Er Eu F Fr Gd Ga Ge Au Hf He Ho H In I Ir Fe Kr La Pb Li Lu Mg Mn Hg Atomic Mass 26.9815 121.76 39.948 74.9216 210 137.327 9.0122 208.9804 10.811 79.904 112.411 40.078 12.0107 140.116 132.9055 35.453 51.9961 58.9332 63.546 162.5 167.259 151.964 18.9984 223 157.25 69.723 72.64 196.9665 178.49 4.0026 164.9303 1.0079 114.818 126.9045 192.217 55.845 83.8 138.9055 207.2 6.941 174.967 24.305 54.938 200.59 Atomic number 13 51 18 33 85 56 4 83 5 35 48 20 6 58 55 17 24 27 29 66 68 63 9 87 64 31 32 79 72 2 67 1 49 53 77 26 36 57 82 3 71 12 25 80 Name Molybdenum Neodymium Neon Nickel Niobium Nitrogen Osmium Oxygen Palladium Phosphorus Platinum Polonium Potassium Praseodymium Promethium Radium Radon Rhenium Rhodium Rubidium Ruthenium Samarium Scandium Selenium Silicon Silver Sodium Strontium Sulfur Tantalum Technetium Tellurium Terbium Thallium Thulium Tin Titanium Tungsten Vanadium Xenon Ytterbium Yttrium Zinc Zirconium Page 38 Symbol Mo Nd Ne Ni Nb N Os O Pd P Pt Po K Pr Pm Ra Rn Re Rh Rb Ru Sm Sc Se Si Ag Na Sr S Ta Tc Te Tb Tl Tm Sn Ti W V Xe Yb Y Zn Zr Atomic Mass 95.94 144.24 20.1797 58.6934 92.9064 14.0067 190.23 15.9994 106.42 30.9738 195.078 209 39.0983 140.9077 145 226 222 186.207 102.9055 85.4678 101.07 150.36 44.9559 78.96 28.0855 107.8682 22.9897 87.62 32.065 180.9479 98 127.6 158.9253 204.3833 168.9342 118.71 47.867 183.84 50.9415 131.293 173.04 88.9059 65.39 91.224 Atomic number 42 60 10 28 41 7 76 8 46 15 78 84 19 59 61 88 86 75 45 37 44 62 21 34 14 47 11 38 16 73 43 52 65 81 69 50 22 74 23 54 70 39 30 40