Appendix E
SELECTED THERMODYNAMIC DATA AT 298.15 K
Species
D H f°
(kJ
mol21)
S°
(J mol21
K21)
D G f°
(kJ
mol21)
Aluminum
Al(s)
Species
D H f°
(kJ
mol21)
S°
(J mol21
K21)
D G f°
(kJ
mol21)
Be(OH)2(s)
2907.1
50.2
2817.6
21205.20
77.91
21093.80
0
56.74
0
BeSO4(s)
0
28.3
0
AlCl3(s)
2704.2
110.7
2628.9
Al2O3(s)
21676
50.92
21582
AlPO4(s)
21733.8
90.76
21617.9
Bi(s)
Al2(SO4)3(s)
23440.84
239.3
23099.94
BiCl3(s)
2379.1
177.0
2315.0
Bi2O3(s)
2573.88
151.5
2493.7
Bi2S3(s)
2143.1
200.4
2140.6
0
5.86
0
Antimony
Sb(s)
Bismuth
0
45.69
0
Sb4O6(s)
21417.1
246.0
21253.0
Boron
Sb2O5(s)
2971.9
125.1
2829.2
B(s)
SbCl5(,)
2440.2
301
2350.1
BCl3(,)
2427.2
206.3
2387.4
2259.4
B2H6(g)
35.6
232.11
86.7
BF3(g)
21137.00
254.12
21120.33
H3BO3(s)
21094.33
88.83
2968.92
NaBH4(s)
2183.34
104.68
2119.54
111.8
174.9
82.4
SbCl3(s)
2382.17
184.1
Argon
Ar(g)
0
154.843
0
0
35.1
0
Br(g)
H3As(g)
66.44
222.78
68.93
Br2(,)
0
152.23
0
As2O5(s)
2924.87
105.4
2782.3
Br2(g)
30.91
245.4
3.14
AsCl3(,)
2305.0
216.3
2259.4
Arsenic
As(s)
Bromine
BrF3(g)
2255.6
292.4
2229.5
HBr(g)
236.4
198.59
253.43
Barium
Ba(s)
0
62.8
BaCl2(s)
2860.1
126
0
2810.9
Cd(s)
0
51.76
0
BaCO3(s)
21216.3
112.1
21137.6
CdCl2(s)
2391.50
115.27
2343.93
BaF2(s)
21207.1
96.36
21156.8
CdO(s)
2258.2
54.8
2228.4
Ba(NO3)2(s)
2992.07
213.8
2796.59
CdS(s)
2161.9
64.9
2156.5
BaO(s)
2553.5
70.42
2525.1
BaSO4(s)
21465
132
21353
Beryllium
Cadmium
Calcium
Ca(s)
0
41.6
0
Ca(g)
192.6
154.8
158.9
0
9.54
0
Ca21(aq)
2542.8
253.1
2553.5
BeCl2(s)
2490.4
82.68
2445.6
CaBr2(s)
682.8
130
2663.6
BeF2(s)
21026.8
53.35
2979.4
CaC2(s)
262.8
70.3
267.8
BeO(s)
2609.6
14.14
2580.3
CaCO3(s)
21207
92.9
21129
Be(s)
512
S°
(J mol21
K21)
D G f°
(kJ
mol21)
Species
D H f°
(kJ
mol21)
S°
(J mol21
K21)
Species
D H f°
(kJ
mol21)
D G f°
(kJ
mol21)
CaCl2(s)
2795.0
114
2750.2
CH3NH2(,)
247.3
150.21
35.6
CaF2(s)
21215
68.87
21162
CO(NH2)2(s)
2334
105
2198
CaH2(s)
2189
42
2150
CH3CN(,)
54
150
99
CaO(s)
2635.5
40
2604.2
C3H3N(,)
172.9
188
208.6
CaS(s)
56.5
197.6
2137.2
2477.4
CO(g)
2110.5
2482.4
Ca(NO3)2(s)
2938.39
193.3
2743.07
CO2(g)
2393.5
213.6
2394.4
Ca(OH)2(s)
2986.6
76.1
2896.8
CO2(aq)
2413.80
117.6
2385.98
Ca(OH)2(aq)
21002.8
76.15
2867.6
COCl2(g)
2223.0
289.2
2210.5
Ca3(PO4)2(s)
24120.8
236.0
23884.7
CS2(g)
117.4
237.7
67.15
21433
107
21320
(CH3)2SO(,)
2203
188
299
C6H12O6(s)
(glucose)
21274.5
212.1
2910.56
C12H22O11(s)
(sucrose)
22221.7
360.24
21544.3
0
85.23
0
Cs (aq)
2248
133
2282
CsF(aq)
2568.6
123
2558.5
0
223.0
0
Cl(g)
121.7
165.1
105.7
Cl2(g)
2226
—
—
2
Cl (aq)
2167.29
56.48
2131.26
ClO(g)
101.22
ClO2(g)
104.60
249.4
123.4
CaSO4(s)
Carbon
C(s,graphite)
0
5.740
0
C(s,diamond)
1.897
2.38
2.900
C(g)
716.7
158.0
671.3
CCl4(,)
2135.4
216.4
265.27
CCl4(g)
2103
309.7
260.63
2134.5
202
273.72
CHCl3(,)
CHCl3(g)
2103.1
295.6
270.37
CH2Cl2(g)
2121.46
177.8
267.26
CH3Cl(g)
280.83
234.58
257.37
CF4(g)
2925
261.61
2879
CF2Cl2(g)
2477
301
2440
CH3CF3(,)
2737
280
2668
CH4 (g)
274.81
186.2
250.75
C2H2(g)
226.7
200.8
209.2
C2H4(g)
52.26
219.5
68.12
C2H6(g)
284.86
229.5
232.9
Cesium
Cs(s)
1
Chlorine
Cl2(g)
Cl2O(g)
80
266
98
ClF(g)
254.48
217.89
255.94
ClF3(g)
C3H6(g)
20.41
266.9
62.75
C3H8(g)
2103.8
269.9
223.49
C6H6(,)
49.03
172.8
124.5
C8H18(,)
(n-octane)
2250.3
361.2
16.32
CH3OH(,)
2238.66
126.8
2166.27
C2H5OH(,)
161
Cr(s)
2277.7
2174.9
C2H5OH(g)
2235.1
282.6
2168.6
Cr2O3(s)
HCOOH(aq)
2425.6
92.0
2351
Cr2Cl3(s)
HCOOH(,)
2424.72
128.95
2361.35
(NH4) 2Cr2O7(s)
HCHO(g)
2108.57
218.77
2102.53
Cobalt
CH3CHO(g)
2166.19
250.3
2128.86
Co(s)
CH3COOH(,)
2484.5
159.8
2389.9
CoO(s)
H2C2O4(s)
2828.93
115.6
2697.2
Co3O4(s)
2891
102.5
2774
H2C2O4(aq)
2825.1
45.61
2673.9
CoCl2(s)
2312.5
109.16
2269.8
135.1
201.78
124.7
CoSO4(s)
2888.3
118.0
2782.3
HCN(g)
2163.2
281.61
2123.0
HCl(g)
292.31
186.8
295.30
HCl(aq)
2167.4
55.10
2131.2
0
23.8
0
21139.7
81.2
21058.1
2556.5
123.0
2486.1
21807
—
—
Chromium
0
30.04
0
2237.94
52.97
2214.20
Appendix E
513
D H f°
(kJ
mol21)
S°
(J mol21
K21)
D G f°
(kJ
mol21)
0
33.15
0
CuBr(s)
2104.6
96.11
2100.8
CuCl(s)
2137.2
86.2
2119.86
CuCl2(s)
2220.1
108.07
2175.7
FeCO3(s)
CuI(s)
267.8
96.7
269.5
Fe(CO)5(,)
CuO(s)
2157
42.63
2130
Cu2O(s)
2168.6
93.14
2146.0
CuS(s)
253.1
66.5
253.6
Cu2S(s)
279.5
120.9
286.2
2771.36
109
2661.8
F2(g)
2322
—
—
F2(aq)
2332.6
—
2278.8
F(g)
78.99
158.6
61.92
F2(g)
0
202.7
0
HF(g)
2271
173.7
2273
Lead
HF(aq)
2320.08
88.7
2296.8
Pb(s)
Species
Copper
Cu(s)
CuSO4(s)
Germanium
Ge(s)
0
3
0
GeH4(g)
91
217
113
GeCl4(g)
2496
348
2457
GeO2(s)
2551
55
2497
0
48
0
Gold
Helium
He(g)
0
126.150
0
218.0
H2(g)
D G f°
(kJ
mol21)
0
27.3
0
FeCl2(s)
2340.67
117.9
2302.3
FeCl3(s)
2399.49
142.3
2334.00
Species
114.6
Fe(s)
2741
93
2667
2774.0
338
2705.4
2733.8
445.2
2697.3
2272
—
—
Fe2O3
(s, hematite)
2824.2
87.40
2742.2
Fe3O4
(s, magnetite)
21118
146
21015
Fe(OH)2(s)
2569.0
88
2486.5
Fe(CO)5(g)
FeO(s)
Fe(OH)3(s)
2823.0
106.7
2696.5
FeS2(s)
2177.5
122.2
2166.7
FeSO4(s)
2928.4
107.5
2820.8
0
64.81
0
PbCl2(s)
2359.4
136
2314.1
PbO(s, yellow)
2217.3
68.70
2187.9
PbO2(s)
2277.4
68.6
2217.33
Pb(OH)2(s)
2515.9
88
2420.9
PbS(s)
2100.4
91.2
298.7
PbSO4(s)
2919.94
148.57
2813.14
Lithium
Li(s)
0
28.0
0
LiAlH4(s)
2116.3
78.74
244.7
LiCl(s)
2408.61
59.33
2384.37
LiF(s)
2615.97
35.65
2587.71
LiH(s)
290.54
20.008
268.35
203.3
LiNO3(s)
2483.13
90.0
2381.1
LiOH(s)
2487.23
50
2443.9
LiOH(aq)
2508.4
4
2451.1
Hydrogen
H(g)
S°
(J mol21
K21)
Iron
Fluorine
Au(s)
D H f°
(kJ
mol21)
0
130.6
0
H2O(,)
2285.8
69.91
2237.2
H2O(g)
2241.8
188.7
2228.6
H2O2(,)
2187.8
109.6
2120.4
Magnesium
Mg(s)
Iodine
0
32.5
0
Mg21(aq)
2454.668
2138.1
2455.57
I(g)
106.6
180.66
70.16
MgBr2(s)
2524.3
117.2
2503.8
I2(s)
0
116.1
0
MgCl2(s)
2641.8
89.5
2592.3
I2(g)
62.44
260.6
19.36
MgCO3(s)
21095.8
65.7
21012.1
ICl(g)
17.78
247.4
25.52
MgF2(s)
21123.4
57.24
21070.2
HI(g)
26.5
206.5
1.72
MgI2(s)
2364.0
129.7
2358.2
514
Appendix E
Species
D H f°
(kJ
mol21)
S°
(J mol21
K21)
D G f°
(kJ
mol21)
Mg(NO3)2(s)
2790.65
164.0
MgO(s)
2601.8
27
S°
(J mol21
K21)
Species
D H f°
(kJ
mol21)
D G f°
(kJ
mol21)
2589.4
NH4Cl(aq)
2300.2
—
—
2569.6
NH4HCO3(s)
2847
12.1
2666
Mg(OH)2(s)
2924.7
63.14
2833.7
NH4I(s)
2201.4
117
2113
Mg3(PO4)2(s)
23780.7
189.20
23538.7
NH4NO3(s)
2365.6
151.1
2184.0
MgS(s)
MgSO4(s)
2347
—
—
21284.9
91.6
21170.6
Manganese
Mn(s)
MnCl2(s)
(NH4)2SO4(s)
21180.85
220.1
2901.67
NF3(g)
2125
260.6
283.3
NO(g)
90.25
210.7
86.57
NO2(g)
33.2
240.0
51.30
0
32.01
0
2481.29
118.24
2440.50
N2O(g)
82.05
219.7
104.2
83.72
321.28
139.46
MnO(s)
2385.22
59.71
2362.90
N2O3(g)
MnO2(s)
2520.03
53.05
2465.14
N2O4(g)
9.16
304.2
97.82
2881.1
N2O5(g)
11
356
115
243.1
178
114
Mn2O3(s)
2959.0
110.5
Mn3O4(s)
21387.8
155.6
21283.2
N2O5(s)
MnSO4(s)
21065.25
112.1
2957.36
NOCl(g)
52.59
264
66.36
HNO3(,)
2174.1
155.6
280.79
HNO3(g)
2135.1
266.2
274.77
HNO3 (aq)
2206.6
146
2110.5
Mercury
Hg(,)
Hg(g)
0
76.02
0
61.32
174.96
31.82
HgCl2(s)
2224.3
146
2178.6
Hg2Cl2(s)
2224
146
2179
O2(g)
0
205.0
0
249.2
161.0
231.8
Oxygen
HgO(s, red)
290.83
70.29
258.56
O(g)
HgS(s, red)
28.2
82.4
250.6
O3(g)
143
238.8
163
OF2(g)
23
246.6
41
314.6
163.1
278.3
0
177
0
Neon
Ne(g)
0
146.328
0
Phosphorus
P(g)
P4(s, white)
Nickel
Ni(s)
NiCl2(s)
Ni(CO)4(g)
NiO(s)
NiS(g)
NiSO4(s)
0
30.1
0
282.0
52.97
279.5
2602.9
410.4
2587.3
2244
38.6
2216
282.0
52.97
279.5
2872.91
92
2759.7
Nitrogen
P4(s, red)
273.6
91.2
248.5
P4(g)
58.91
279.98
24.44
PCl3(g)
2306.4
311.7
2286.3
PCl5(g)
2398.9
353
2324.6
PF3(g)
2918.8
273.24
2897.5
PH3(g)
5.4
210.1
13
P4O10(s)
22984
228.9
22698
H3PO4(s)
21281
110.5
21119
N2(g)
0
191.5
0
N(g)
472.704
153.19
455.579
NH3(g)
246.11
192.3
216.5
K(s)
0
63.6
0
NH3(aq)
280.29
111.3
226.50
KBr(s)
2393.798
95.90
2380.66
NH41(aq)
2132.51
113.4
279.31
KCl(s)
2436.5
82.6
2408.8
N2H4(,)
50.63
121.2
149.2
KClO3(s)
2391.2
143.1
2289.9
(NH4)3AsO4(aq)
21268
—
—
KClO4(s)
2432.747
82.59
2409.14
2270.83
113
2175.2
K2CO3(s)
21151.02
155.52
21063.5
2314.4
94.6
2201.5
K2Cr2O4(s)
21403.7
200.12
21295.7
NH4Br(s)
NH4Cl(s)
Potassium
Appendix E
515
Species
D H f°
(kJ
mol21)
S°
(J mol21
K21)
D G f°
(kJ
mol21)
Species
K2Cr2O7(s)
22061.5
291.2
21881.8
Sodium
KF(s)
2567.27
66.57
2537.75
Na(s)
0
51.0
0
108.7
153.6
78.11
D H f°
(kJ
mol21)
S°
(J mol21
K21)
D G f°
(kJ
mol21)
KI(s)
2327.9
106.4
2323.0
Na(g)
KMnO4(s)
2837.2
171.71
2737.6
Na1(g)
601
—
—
2240.2
59.0
2261.9
KNO3(s)
KO2(s)
2494.63
133.05
2394.86
Na1(aq)
284.93
116.7
2239.4
NaBr(s)
2359.9
86.82
2348.98
2411.0
72.38
2384
K2O2(s)
2494.1
102.1
2425.1
NaCl(s)
KOH(s)
2424.7
78.91
2378.9
NaCl(aq)
2407.1
115.5
2393.0
2254.85
KOH(aq)
2481.2
92.0
2439.6
NaClO4(s)
2383.30
142.3
K2SO4(s)
21437.79
175.56
21321.37
NaCN(s)
287.49
118.49
276.4
NaCH3COO(s)
2708.80
123.0
2607.18
21131
136
21048
Rubidium
Rb(s)
RbOH(aq)
Na2CO3(s)
0
76.78
0
NaF(s)
2573.647
51.46
2543.494
2481.16
110.75
2441.24
NaH(s)
256.275
40.016
233.46
Selenium
Se(s)
H2Se(g)
0
42.442
0
29.7
219.02
15.9
NaHCO3(s)
2950.81
101.7
2851.0
NaHSO4(s)
21125.5
113.0
2992.8
NaH2PO4(s)
21538
128
21387
Na2HPO4(s)
21749
151
21609
Silicon
NaI(s)
2287.78
98.53
2286.06
Si(s)
NaNO3(s)
2467.85
116.52
2367.00
0
18.8
0
2457.3
277.8
2443.9
Na2O(s)
2414.22
75.06
2375.46
SiC(s)
265.3
16.6
262.8
Na2O2(s)
2510.87
95.0
2447.7
SiCl4(g)
2657.0
330.6
2617.0
NaOH(s)
2426.7
64.45
2379.49
NaOH(aq)
2469.6
49.8
2419.2
Na3PO4(s)
21917.40
173.80
21788.80
2364.8
83.7
2349.8
SiBr4(,)
SiCl4(,)
2687.0
239.7
2619.84
SiH4(g)
56.9
34.3
204.5
SiF4(g)
21615
282.4
21573
SiI4(g)
2132
—
—
Na2SO4(s)
21387.08
149.58
21270.16
Na2S2O3(s)
21123.0
155
21028.0
0
52.3
0
Na2S(s)
SiO2(s)
2910.9
41.84
2856.7
H2SiO3(s)
21189
134
21092
H4SiO4(s)
21481.1
192
21332.9
Na2SiO3(s)
21079
—
—
Sr(s)
H2SiF6(aq)
22331
—
—
SrCl2(s)
2828.9
114.85
2781.1
SrCO3(s)
21220.1
97.1
21140.1
SrO(s)
2592.0
54.4
2561.9
Silver
Ag(s)
Strontium
0
42.55
Ag1(aq)
105.79
73.86
77.12
AgBr(s)
2100.37
107.1
296.90
S(s, rhombic)
0
31.8
0
278.8
167.8
238.3
102.30
430.98
49.63
218
331
231.8
21209
291.7
21105
AgCl(s)
AgI(s)
0
Sulfur
2126.904
96.085
2109.8
S(g)
261.84
115.5
266.19
S8(g)
AgNO3(s)
2124.39
140.92
233.41
S2Cl2(g)
Ag2O(s)
231.05
121.3
211.20
SF6(g)
AgS(s)
232.59
144.01
240.67
H2S(g)
220.6
205.7
233.6
AgSCN(s)
87.9
131.0
101.36
H2SO4(,)
2814.0
156.9
2690.1
Ag2SO4(s)
2715.88
200.4
2618.41
H2SO4(aq)
2907.5
17
2742.0
516
Appendix E
Species
D H f°
(kJ
mol21)
S°
(J mol21
K21)
D G f°
(kJ
mol21)
Species
SO2(g)
2296.8
248.1
2300.2
Uranium
SO3(g)
2395.6
256.6
2371.1
U(s)
SOCl2(,)
2206
—
—
UF6(s)
SO2Cl2(,)
2389
—
—
UO2(s)
UO3(s)
D H f°
(kJ
mol21)
S°
(J mol21
K21)
D G f°
(kJ
mol21)
0
50.21
0
22147.4
377.9
22063.7
21084.9
77.03
21031.7
21223.8
96.11
21145.9
Tellurium
Te(s)
TeO2(s)
0
49.71
0
Xenon
2322.6
79.5
2270.3
Xe(g)
Tin
0
169.683
0
XeF2(g)
2130
260
296
Sn(s, white)
0
51.55
0
XeF4(g)
2215
316
2138
Sn(s, gray)
22.09
44.1
0.13
XeO3(g)
502
287
561
SnCl2(s)
2350
—
—
Zinc
SnCl4(,)
2511.3
258.6
2440.2
Zn(s)
0
41.63
0
SnCl4(g)
2471.5
366
2432.2
ZnCl2(s)
2415.05
111.46
2369.398
SnO(s)
2285.8
56.5
2256.9
ZnCO3(s)
2812.78
82.4
2731.52
SnO2(s)
2580.7
52.3
2519.7
ZnO(s)
2348.3
43.64
2318.3
Zn(OH)2(s)
2643.25
81.6
2555.07
ZnS(s)
2205.6
57.7
2201.3
ZnSO4(s)
2982.8
110.5
2871.5
Titanium
Ti(s)
0
30.6
0
TiCl4(,)
2804.2
252.3
2737.2
TiCl4(g)
2763.2
354.8
2726.8
0
32.6
0
2842.9
75.90
2764.1
Tungsten
W(s)
WO3(s)
Appendix E
517