The building blocks of rocks Seeds of growth Modified from NIGS 2003 Geo11.1 Laboratory Manual Introduction The term “mineral” is used in many different ways. Jewelers recognize minerals as stones to be cut, polished and mounted on different settings. Agriculturists enrich soils with fertilizers containing different minerals to provide plants with nutrients to enhance their growth. Humans also need a certain amount of minerals to supplement their everyday diet. However, in geology, the word “mineral” has a specific connotation. In order for a substance to be considered a mineral, it must meet five requirements. It must be a naturally occurring, inorganically formed homogenous solid that has a definite chemical composition and an ordered internal structure. These characteristics determine the mineral’s physical and chemical properties, which can be used in their identification. In particular, six properties are commonly used in classifying minerals. Color Color is the composite of all visible light reflected back by the mineral. It is usually the most noticeable physical property. For some minerals, color can be used as a diagnostic property, since these minerals always occur in shades of one particular color (idiochromatic color). Examples are the intense azure blue of azurite, the bright green of malachite, and the bright yellow of sulfur. However, most minerals, like quartz, occur in a range of colors, due to impurities caused by chemical substitution and the effects of radiation (allochromatic color). Some minerals have a characteristic iridescence (a lustrous rainbowlike play of color), or have one color on freshly broken surfaces and a different color on tarnished surfaces. The color of a mineral depends on its absorption or reflection of certain wavelengths of light when light is transmitted through or reflected on it. A white mineral appears white because it essentially reflects the entire visible spectrum. A transparent mineral transmits the entire visible light spectrum. A black mineral absorbs all wavelengths of visible light. Colored minerals selectively absorb certain wavelengths of light and transmit or reflect the remaining light that our eyes see. Luster Luster is a description of how the surface of a substance reflects light. The nature of the reflecting surface gives rise to the different kinds of luster, and the amount of reflected light produces varying intensities of luster. • Metallic – opaque and reflective, like the silver, gold, or copper sheen displayed by metals • Submetallic -- intermediate between metallic and nonmetallic; describes materials that are opaque or nearly opaque but reflect light well • Adamantine -- the luster of diamond; displays extraordinary brilliance and shine • Vitreous -- reflects light like glass; exhibited by 70% of all minerals • Resinous – similar to the way amber or clear candy would reflect light • Satiny – reflects light like satin cloth; exhibited by minerals with fibrous habits • Pearly – similar to the luster exhibited by pearls or the inside of mollusk shells • Waxy – reflects light like a wax candle • Greasy – reflects light as if coated with a layer of grease • Dull – nonreflective, like concrete or dirt; usually exhibited by rough, porous surfaces A comparison chart is a simple tool that can be made to compare different kinds of luster properly. Take a piece of folder or illustration board and cut it to a strip of 1.5 in x 6 in. Draw six or seven equal sized squares as shown in Figure 2-1. On the squares, glue or rub materials that have luster types similar to the metal foil (metallic) pencil rub (submetallic) ) oil pastel rub (dull) candle drip (waxy) Figure 2-1 Luster comparison chart silk piece (silky) window glass (vitreous) ones mentioned in the list. You will then be able to compare these materials with the mineral specimens in the exercise. Streak Streak is the color of a substance in its powdered form. It is often called a mineral’s true color, since the streak of a mineral is constant regardless of its body color or clarity. Streak is thus a more diagnostic property than color. Some minerals have streak colors that are similar to their body colors, like those of azurite and malachite. However, most metallic minerals show streaks different from their body color. For example, both hematite and magnetite can have body colors of black or very dark gray. But hematite always shows a red-brown streak similar to the color of dried blood. Magnetite always has a black streak. The usual method for determining this property is by scratching the mineral against a piece of unglazed porcelain tile called a streak plate, as long as the mineral is less hard than the porcelain plate (see Hardness). The color of the powder left on the plate is the streak of the mineral. Other methods of determining streak are by powdering a piece of the mineral with a hammer, or by scraping the mineral with a pocket knife. Hardness Hardness is a measure of the resistance of a mineral to scratching and abrasion, and is usually measured in comparison to other minerals of known hardness. A harder substance will scratch a softer one. In 1812, a German mineralogist named Friedrich Mohs developed a quantitative scale of relative mineral hardness on which the softest Table 2-1 Mohs Scale of Hardness mineral (talc) has a hardness of 1, and the hardest Common Objects Hardness Mineral mineral (diamond) has a hardness of 10 (see Table 2-1). 1 Talc There are a few points to remember when 2 Gypsum 2.5 Fingernail testing for hardness: 3 Calcite 3.5 Copper wire 1) Always test a smooth, fresh surface of the 4 Fluorite mineral. Weathered or corroded surfaces 4.5 Iron nail will be softer than normal. 5 Apatite 5.5 Pocket knife 2) Cross-check the results of your hardness 6 Orthoclase 6.5 Streak plate tests. For example, in addition to using 7 Quartz mineral B to scratch mineral A, also try to 8 Topaz using mineral A to scratch mineral B. Without this cross check you may not be 9 Corundum able to tell which minerals is actually doing 10 Diamond the scratching. Cleavage & Fracture Minerals break along flat surfaces, irregular surfaces, or a combination of both. The flat breaks are called cleavage planes, and the irregular breaks are called fracture surfaces. Cleavage planes are sets of parallel surfaces representing weak chemical bonding between repeating, parallel layers of atoms in a crystal. Each group of parallel cleavage planes has an orientation relative to the crystal structure and is referred to as a cleavage direction. Different minerals have different numbers of cleavage directions, depending on their inherent crystal structures. Minerals like muscovite and biotite have basal cleavage, breaking in one direction into thin sheets like pages of a book. Halite has three cleavage directions developed at right angles to one another, so it breaks either into cubes (cubic cleavage) or fragments that have sides at right angles to each other. Cleavage can be described as excellent, good, poor, or absent, depending on how well the surface reflects light. When cleavage is absent—that is, when the mineral breaks very poorly and irregularly—then the surface of the break is called a fracture. Minerals like quartz have characteristic curved fracture surfaces that are called conchoidal fractures, much like that observed in broken glass. Other Properties Habit denotes the general shape of crystals. All true minerals have a crystalline structure, or an orderly three-dimensional arrangement of atoms or molecules, which is manifested externally by the different geometrical shapes that mineral crystals occur in. Pyrite is commonly found as cubes or intergrown cubes. Muscovite and biotite generally grow as book-like stacks of thin sheets. Specific gravity is the ratio of the weight of a substance to the weight of an equal volume of water. Minerals made up of elements of high atomic weight are denser than minerals made up of elements with low atomic weights. Minerals whose atoms are strongly bonded to each other have closely packed structures, and are denser than minerals having similar chemical compositions but weakly bonded components. The average specific gravity of minerals is about 2.7, but some metallic minerals have a specific gravity many times greater than the average, depending on their purity. Platinum has a specific gravity of about 21.4, while quartz has a specific gravity of 2.65. Magnetism is a characteristic of minerals, such as magnetite, that have a high iron content and are attracted to a magnetic field. Reaction to acid differs among minerals. A drop of dilute hydrochloric acid applied on the fresh surface of a carbonate mineral (a mineral whose chemical composition includes carbonate, CO 3) like calcite will effervesce or “fizz” due to the release of carbon dioxide gas. Over 2,000 minerals have already been discovered and named according to their characteristic chemical composition and physical properties. Of these, only 20 are common and fewer than 10 form the bulk composition of most rocks. Each of these minerals possesses unique properties that serve to identify them from the rest. Figure 2-2 Comparison of cleavage surfaces Excellent cleavage (large even flat surfaces) light rays Good cleavage (small uneven flat surfaces) Poor cleavage (a few small flat surfaces) Fracture surface (no flat surfaces), or absent cleavage SOURCES David, C.P., R.A. Amores, J.A.L. Barretto, R.R.C. Luis, E.J. Marquez, and K.L. Queaño. Geology 11.1 Manual of Exercises. Quezon City: UP Press, 1996. Electrical and Magnetic Properties. <http://www.tmm.utexas.edu/npl/mineralogy/Science_of_Minerals/ electric_magnet_properties.htm>. Hurlbut, C. Jr., and C. Klein. Manual of Mineralogy (after James D. Dana). John Wiley & Sons, 1977. Mechanical Properties. <http://www.tmm.utexas.edu/npl/mineralogy/Science_of_Minerals/ mechanical_properties.htm>. Mineral Properties: Luster. <http://www.minerals.net/resource/property/luster.htm>. Optical Properties. <http://www.tmm.utexas.edu/npl/mineralogy/Science_of_Minerals/ optical_properties.htm>. Tarbuck, E.J., F.K. Lutgens, and K.G. Pinzke. Applications & Investigations in Earth Science. New Jersey, USA: Prentice Hall, 2000. WORLD WIDE WEB LINKS The Science of Minerals. <http://www.tmm.utexas.edu/npl/mineralogy/Science_of_Minerals/index.htm> Exercise 4 The building blocks of rocks Seeds of growth Modified from NIGS 2003 Geo11.1 Laboratory Manual Objectives One of the most basic skills that a student of Geology needs to have is the ability to identify minerals, since they are essentially the building blocks of the different kinds of rocks. To be able to understand the origin, classification, and subsequent alteration of rocks, the student must be able to recognize the minerals that make them up. This exercise is designed to enable students to: • become familiar with the physical properties of minerals. • systematically identify minerals based on their physical properties. Materials To be provided by the students: pencil, eraser, pocket knife or glass plate, magnet, hand lens (10x) To be provided by the teacher: mineral specimens, streak plates, dilute HCl Procedure To properly identify a mineral, one must first determine as many of its physical properties as possible, employing the available tools. Remember that the goal of this exercise is for the student to learn the systematic procedure of identifying minerals through observation and not simply to name them based on gut feel or good luck. List down as many identifiable physical properties as possible for each mineral in Table 2-3. Additional observations are encouraged. Then, using the Mineral Identification Key (Table 2-2), narrow down the choices and arrive at a mineral name. Answer concisely the questions preceding Table 2-3 regarding minerals. Light colored Dark colored Dark colored Table 2-2. Mineral Identification Key Adapted from Tarbuck, Lutgens & Pinzke (2000) H=hardness, SP=specific gravity Metallic Minerals Name Hardness Streak Other Diagnostic Properties (Chemical Composition) Black; magnetic; H=6; SP=5.2; often Magnetite, Black granular Fe3O4 Brass yellow; H = 6; SP=5.2; GreenishPyrite, Harder than pocket knife generally an aggregate of cubic black FeS2 crystals Gray or reddish brown; H=5-6; SP=5; Hematite, Red-brown platy appearance Fe2O3 Greenish- Golden yellow; H=4; SP=4.2; Chalcopyrite, Softer than pocket knife black massive CuFeS2 but harder than a Silvery gray; H=2.5; SP=7.6 (very Galena, fingernail Gray-black heavy); good cubic cleavage PbS Silvery gray; H=1 (very soft); SP=2.2; Graphite, Softer than a fingernail Dark gray massive C Nonmetallic Minerals Name Hardness Cleavage Other Diagnostic Properties (Chemical Composition) Black to greenish black; H=5-6; Augite (Pyroxene), SP=3.4; fair cleavage, 2 directions at (Ca,Na)(Mg,Fe,Al,Ti)(Si, Al)2O6 nearly 90 Present Hornblende Black to greenish black; H=5-6; (Amphibole), SP=3.2; fair cleavage, 2 directions at Ca2(Mg,Fe)4Al(Si7Al)O22 Harder than nearly 60 and 120 (OH,F)2 pocket knife Gray to brown; H=9; SP=4; Corundum, hexagonal crystals common Al2O3 Dark brown to black; H=7; Smoky quartz, Not prominent conchoidal fracture; glassy luster SiO2 Olive green; H=6.5-7; small glassy Olivine, grains (Mg,Fe)2SiO4 Dark brown to black; H=2.5-3; Biotite, Present excellent cleavage in 1 direction; K, Mg, Fe, OH, Al elastic in thin sheets; black mica silicate Softer than pocket knife but harder Bright green; H=3.5-4; green streak; Malachite, than a fingernail effervesces in HCl; Cu2CO3(OH)2 Deep azure blue; H=3.5-4; pale blue Azurite, Not prominent streak; Cu3(CO3)2(OH)2 Softer than a Reddish brown; H=1-5; SP=4-5; red Hematite, fingernail streak; earthy appearance Fe2O3 Potassium feldspar, Pink to white H=6; SP=2.6; 2 KAlSi3O8 directions of Present Plagioclase feldspar, cleavage at White to gray NaAlSi3O8 to Harder than nearly 90 CaAl2Si2O8 pocket knife Any color; H=7; SP=2.65; conchoidal fracture; glassy appearance; Quartz, Present varieties: milky, rose, smoky, SiO2 amethyst, citrine Nonmetallic Minerals (continuation) Light colored Hardness Cleavage Other Diagnostic Properties White, yellowish to colorless; H=3; 3 directions of cleavage at 75 (rhombohedral); effervesces in HCl; often transparent Softer than pocket White to colorless; H=2.5; 3 knife but harder Present directions of cleavage at 90 (cubic); than a fingernail salty taste Yellow, purple, green, colorless; H=4; white streak; translucent to transparent; 4 directions of cleavage Colorless; H=2-2.5; transparent and elastic in thin sheets; excellent cleavage in one direction; lightcolored mica White to transparent; H=2; when in Present sheets, is flexible but not elastic; varieties: selenite (transparent, 3 directions of cleavage), satin spar (fibrous, silky luster), alabaster (aggregate of small crystals) Softer than a White, pink, green; H=1-2; forms in fingernail thin sheets; soapy feel; pearly luster Yellow; H=1-2.5; smells like rotten eggs White; H=2; smooth feel; earthy Not prominent odor; when moistened, has a typical clay texture Pale to dark reddish brown; H=1-3; dull luster; earthy; often contains spheroidal-shaped particles; not a true mineral Name (Chemical Composition) Calcite, CaCO3 Halite, NaCl Fluorite, CaF2 Muscovite, KAl2(Si3Al)O10(OH,F) Gypsum, CaSO4·2H2O Talc, Mg3Si4O10(OH)2 Sulfur, S Kaolinite, Al2Si2O5(OH)4 Bauxite, FeO(OH) + Al2O32H2 Name ________________________________ Student Number ____________ Section __________ Answer Sheet The building blocks of rocks Questions 1. What determines the hardness of a mineral? ________________________________________________________________________________ ________________________________________________________________________________ ________________________________________________________________________________ ________________________________________________________________________________ 2. Why do some minerals cleave and others fracture? ________________________________________________________________________________ ________________________________________________________________________________ ________________________________________________________________________________ ________________________________________________________________________________ 3. List five minerals and give their economic uses. Mineral name Economic use a. b. c. d. e. References _____________________________________________________________ _____________________________________________________________ Specimen Number Luster Hardness Color Streak Fracture/Cleavage (# dirs., angle of intersection Other Properties Mineral Name