Worksheet Chapter 1 1. Identify each of the following statements as being most similar to a hypothesis, a law, or a theory. Explain your reasoning. (a) The pressure of a sample of gas is directly proportional to the temperature of the gas. Law: it is the Temperature-Volume Law. It is a consistently observed phenomenon. (b) Matter consists of tiny particles that can combine in specific ratios to form substances with specific properties. Theory: theory of matter atoms and elements is widely accepted by the science community. It is consistent compared to a law. (c) At a higher temperature, solids (such as salt or sugar) will dissolve better in water. Hypothesis: it is a prediction of the outcome of an experiment. It can be tested experimentally. 2. Classify each of the following as an element, a compound, or a mixture: (a) iron Element (b) oxygen Element (c) mercury oxide Compound (d) pancake syrup Mixture (e) carbon dioxide Compound (f) a substance composed of molecules each of which contains one hydrogen atom and one chlorine atom Compound (g) baking soda Compound (h) baking powder Mixture 3. Classify each of the following changes as physical or chemical: (a) coal burning Chemical (b) ice melting Physical (c) mixing chocolate syrup with milk Physical (d) explosion of a firecracker Chemical (e) magnetizing of a screwdriver Physical 4. The volume of a sample of oxygen gas changed from 10 mL to 11 mL as the temperature changed. Is this a chemical or physical change? Physical change 5. Explain the difference between extensive properties and intensive properties. An extensive property depends on the amount of matter while an intensive property depends on the type of matter. 6. Identify the following properties as either extensive or intensive. (a) volume Extensive (b) temperature Intensive (c) humidity Extensive (d) heat Extensive (e) boiling point Intensive 7. The density (d) of a substance is an intensive property that is defined as the ratio of its mass (m) to its volume (V). mass m density = d = volume V Considering that mass and volume are both extensive properties, explain why their ratio, density, is intensive. Dividing one extensive property by another will cancel the properties dependence on the amount of matter which results in density being dependent of the amount, which is the intensive property. 8. Indicate the SI base units or derived units that are appropriate for the following measurements: (a) the mass of the moon Kilogram (b) the distance from Dallas to Oklahoma City Meter (c) the speed of sound Meters per second (d) the density of air Kilogram per cubic meter (e) the temperature at which alcohol boils Square meters (f) the area of the state of Delaware Cubic meters (g) the volume of a flu shot or a measles vaccination Mililiters 9. Give the name of the prefix and the quantity indicated by the following symbols that are used with SI base units. (a) c centi (10-2) (b) d deci (10-1) (c) G giga (109) (d) k kilo (103) (e) m milli (10-3) (f) n nano (10-9) (g) p pico (10-12) (h) T Tera (1012) 10. Express each of the following numbers in scientific notation with correct significant figures: (a) 711.0 -> 7.110 x 102 (b) 0.239 –> 2.39 x 10-1 (c) 90743 -> 9.0743 x 104 (d) 134.2 -> 1.342 x 102 (e) 0.05499 -> 5.499 x 10-2 (f) 10000.0 ->1.00000 x 104 (g) 0.000000738592 -> 7.38593 x 10-7 11. Indicate whether each of the following can be determined exactly or must be measured with some degree of uncertainty: (a) the number of seconds in an hour = measured exactly (b) the number of pages in this book = measured exactly (c) the number of grams in your weight = measured with uncertainty (d) the number of grams in 3 kilograms= measured exactly (e) the volume of water you drink in one day = measured with uncertainty (f) the distance from San Francisco to Kansas City = measured with uncertainty 12. The following quantities were reported on the labels of commercial products. Determine the number of significant figures in each. (a) 0.0055 g active ingredients = 2 (b) 12 tablets = 2 (c) 3% hydrogen peroxide = 1 (d) 5.5 ounces = 2 (e) 473 mL = 3 (f) 1.75% bismuth = 3 (g) 0.001% phosphoric acid = 1 (h) 99.80% inert ingredients = 4 13. Round off each of the following numbers to two significant figures: (a) 517 -> 5.2 x 102 (b) 86.3 -> 8.6 x 101 (c) 6.382 -> 6.4 x 103 (d) 5.0008 -> 5.0 x 104 (e) 22.497 -> 2.3 x 104 (f) 0.885 -> 8.9 x 10-1 14. Perform the following calculations and report each answer with the correct number of significant figures. (a) 62.8 34 = 2.1 x 103 (b) 0.147 + 0.0066 + 0.012 = 0.166 (c) 38 95 1.792 = 6500 (d) 15 – 0.15 – 0.6155 = 14 0.0500 (e) 8.78 = 0.918 0.478 (f) 140 + 7.68 + 0.014 = 148 (g) 28.7 – 0.0483 = 28.7 (88.5 − 87.57) (h) = 0.02 45.13 15. Consider the results of the archery contest shown in this figure. (a) Which archer is most precise? Archer X (b) Which archer is most accurate? Archer W (c) Who is both least precise and least accurate? Archer Y 16. Complete the following conversions between SI units. (a) 612 g = 612000 mg (b) 8.160 m = 816 cm (c) 3779 μg = 3.779 x 10-7 g (d) 781 mL = 0.781L (e) 4.18 kg = 4180g (f) 27.8 m = 0.0278km (g) 0.13 mL = 1.3 x 10-4 L (h) 1738 km = 1738000m (i) 1.9 Gg = 1900000000 g 17. Make the conversion indicated in each of the following: (a) the length of a soccer field, 120 m (three significant figures), to feet 1m = 3.28084 feet 120m = 120 x 3.3 feet = 396 feet (b) the height of Mt. Kilimanjaro, at 19,565 ft the highest mountain in Africa, to kilometers 1 feet = 0.0003048 km 19,565 feet=19,565 x 0.0003048 km = 5.963412 km (c) the area of an 8.5 11-inch sheet of paper in cm2 Area of the sheet = 8.5 inches x 11 inches = 93.5 inches2 1 inch=2.54 cm 93.5 inches2 = 93.5 x (2.54)2cm2 = 603.2246 cm2 (d) the displacement volume of an automobile engine, 161 in. 3, to liters 1 inch3 = 0.0163871L 161inches3 = 161 x 0.0163871L = 2.63832L (e) the estimated mass of the atmosphere, 5.6 1015 tons, to kilograms 1 ton = 907.185 kg 5.6 x 105tons = 5.6 x 1015 x 907.185kg =5.08023 x 1018kg (f) the mass of a bushel of rye, 32.0 lb, to kilograms’ 1 lb = 0.453592 kg 32.0lb – 32 x 0.453592 kg = 14.515kg (g) the mass of a 5.00-grain aspirin tablet to milligrams (1 grain = 0.00229 oz) Mass of 5 grains = 5 × 0.00229 oz = 0.01145 oz 1 oz = 28349.5 mg 0.01145 oz = 0.01145 x 28349.5 mg = 342.601775mg 18. Osmium is one of the densest elements known. What is its density if 2.72 g has a volume of 0.121 cm3 2.72g/0.121 cm3 = 22.479 =22.5g/cm3 19. Calculate these masses. (a) What is the mass of 4.00 cm3 of sodium, density = 0.97 g/cm? Mass = density x Volume = 0.97g/cm3 x 4.00cm3 =3.9g (b) What is the mass of 125 mL gaseous chlorine, density = 3.16 g/L? Mass = density x Volume = 3.16g/L x 0.125L = 0.395g 20. Calculate these volumes. (a) What is the volume of 11.3 g graphite, density = 2.25 g/cm 3? Mass/volume = density 11.3g/V = 2.25g/cm3 11.3g=2.25g/cm3 x V 11.3g/2.25g/cm3 =V 5.02cm3 = V (b) What is the volume of 39.657 g bromine, density = 2.928 g/cm 3 V = mass/density V= 39.657g/(2.98g/cm3) V=13.54cm3 21. Convert the temperature of dry ice, –77 C, into degrees Fahrenheit and kelvin. Temperature in Kelvin = -77 degrees Celsius + 273 = 196 K Temperature in degree Fahrenheit = (-77 degrees Celsius x (9/5)) +32 = (-693/5) +32 =106.6 degrees Fahrenheit