Profile on Acetic acid 1. 2. 3. 4. PRODUCT OVERVIEW ............................................................................................................................ 2 1.1. General details .............................................................................................................................. 2 1.2. Product application ....................................................................................................................... 2 INDIAN TRADE STATISTICS .................................................................................................................... 4 2.1. Import ........................................................................................................................................... 4 2.2. Export ............................................................................................................................................ 5 INDIAN SUPPLY SCENARIO .................................................................................................................... 6 3.1. Indian Manufacturers and their production level – April 2012 to March 2013 ........................... 6 3.2. New Project ................................................................................................................................... 6 INDIAN DEMAND SUPPLY SCENARIO .................................................................................................... 8 4.1. Indian demand supply scenario– Period Apr 2012 to Mar 2015 .................................................. 8 4.2. Sectorwise Indian domestic demand – Period April 2012-2013 ................................................... 8 4.3. Pattern of sectorwise demand – April 2012 to March 2013......................................................... 9 1 Profile on Acetic acid 1. PRODUCT OVERVIEW 1.1. General details Chemical formula CH3COOH CAS number 64-19-7 Appearance Colourless, water like liquid 1.2. Product application Sectorwise application Sector Pharmaceuticals Textiles Acidulant & Preservative Chemical synthesis Acetates Pesticides Diketene & its derivatives Tanning / dyes Solvents Pickling Application details Eg. In the preparation of ibuprofen, Sulphamethoxazole, Chloroquin, Metronidazole etc In making Purified telepthalic acid (PTA) Eg: Vinegar, Jams, Pickles, Ketchups etc. For eg. Monochloroacetic acid (MCA), Vinyl Acetate Monomer (VAM) Eg. Cellulose acetate, Ethyl Acetate, Zinc acetate, Amyl acetate etc. Eg. Chlorpyriphos, Acephate Eg. Monomethyl acetoacetamide, ethyl acetoacetamide, MAA Laundry sour, printing calico & dyeing For gums, resins & volatile oils Acetic acid / citric acid / oxalic acid or formic acid can be used to acidify a skin to kill bacteria makes the skin easier to flesh and creates a positive ionic charge in the skin fibres to attract tannins. Derivative products Acetic anhydride Diketene and its derivatives (Monomethyl acetoacetamide, ethyl acetoacetamide, methyl acetoacetate) Acetate esters (Cellulose acetate, ethyl acetate, zinc acetate, amyl acetate etc) Vinyl acetate monomer (VAM) Monochloro acetic acid (MCA) Purified terephthalic acid (PTA) 2 Profile on Acetic acid Usage of acetic acid in textile sector ‘Fabric softeners’ is added at the end of the washing process is to neutralise the very small amounts of detergents left in the textiles and thus prevent static electricity. The simplest way to inactivate any detergents left in the fabric is to neutralise the pH to between 6.5 and 7.5 through addition of a small amount of acetic acid. Through this method, the activity of the alkali and surfactants is eliminated. Acetic acid is not a fabric softener in principle but is often used for this purpose in professional laundries. Acetic acid is a weak organic acid which is readily degradable and has no adverse effects in the environment except for the use of oxygen for degradation. It is also readily degradable under anaerobic conditions. Role of acetic acid in various industry Industry Role of acetic acid pH modifier / preservative Raw material Raw material Raw material Raw material Curing agent Bleaching agent Coagulant Coagulant Food Pharma Agro Dyestuff Chemical (VAM/PTA/AA etc) Textile Cotton / polyester / wool Rubber / latex Casein 3 Profile on Acetic acid 2. INDIAN TRADE STATISTICS 2.1. Import Annual import Quantity in tonnes 800000 700000 600000 500000 400000 300000 200000 100000 0 Quantity in tonnes 2008-2009 2009-2010 2010-2011 2011-2012 285036 389650 466096 748970 Countrywise import – Apr 2011 to Mar 12 Uruguay 1% Indonesia 1% France 1% Ukraine 1% Spain 1% U S A 2% Russia 1% U Arab Emts 2% Netherland 3% China P Rp 27% Saudi Arab 6% Iran 7% Singapore 24% Malaysia 21% 4 Profile on Acetic acid 2.2. Export Annual export Quantity in tonnes 25000 20000 15000 10000 5000 0 Quantity in tonnes 2008-2009 2009-2010 2010-2011 2011-2012 12589 13022 8367 23418 Countrywise export Others 11% Netherland 4% Bangladesh Pr 5% Egypt A Rp 6% Belgium 56% U Arab Emts 18% 5 Profile on Acetic acid 3. INDIAN SUPPLY SCENARIO 3.1. Indian Manufacturers and their production level – April 2012 to March 2013 In tonnes Name of the organisation Installed capacity Production GNFC, Gujarat Industrial Organics, Ludhiana 150000 75000 170500 11500 Trichy Distrilleries, Trichy 24000 18000 249000 200000 Total Most of the units including Jubilant Organosys and Somaiya Organics confirmed that they stopped production of acetic acid. They imported acetic acid for captive consumption as well as for supply to other consumers in India. 3.2. New Project Company Indian Oil Corp (IOC) JV with BP Project capacity One million tonnes per annum of acetic acid Project location Gujarat Process BP's Cativa XL technology Schedule 2015 The Indian market is sufficiently large to accommodate one worldscale plant. But Reliance Industries has talked about building plants for acetic acid and derivatives at Jamnagar, Gujarat. This project too has been in the pipeline for a few years and it remains to be seen if the company will be interested in pursuing it after the BP-IOC announcement. It is also interesting that BP which has joined hands with Reliance in the gas value chain has decided to partner IOC for acetic acid. 6 Profile on Acetic acid Assam Petrochemicals Limited (APL) Project capacity 72000 tonnes per annum of acetic acid 150,000 tonnes per annum of methanol Project cost Rs. 3.5 billion (for acetic acid) Rs. 11 billion (for both combined plant of methanol and acetic acid) Plant location Namrup, assam Project schedule Q III, 2015 7 Profile on Acetic acid 4. INDIAN DEMAND SUPPLY SCENARIO 4.1. Indian demand supply scenario– Period Apr 2012 to Mar 2015) In tonnes Period (Apr to Mar) 2012-2013 Domestic demand 950000 Export demand Total demand 974000 *Indian production 200000 Gap in supply to be met import 774000 24000 2014-2015 1067500 25500 1093000 200000 893000 It is considered that the Indian production would remain at present level till 2014-2015. Growth rate considered 4.2. 6% per annum for domestic demand 3% per annum for export demand Sectorwise Indian domestic demand – Period April 2012-2013 Sector PTA Acetate and acetic anhydride MCA Pharmaceuticals Pesticides Tanning, dyes and dye intermediate Textile processing Food and other miscellaneous sectors Total Demand in tonnes 332500 294500 57000 76000 57000 47500 28500 57000 950000 8 Profile on Acetic acid 4.3. Pattern of sectorwise demand – April 2012 to March 2013 Tanning, dyes and dye intermediate 5% Food and other miscellaneous sectors 6% Textile processing 3% Pesticides 6% PTA 35% Pharmaceuticals 8% MCA 6% Acetate and acetic anhydride 31% 9 Profile on Acetic acid 10