CONTENTS: • • • • • • • • • • • Chemistry Chemical bonding in Elements and Compounds Bonding in the elements Bonding in metals Bonding in non-metals Chemical bonding in compounds Covalent compounds Ionic compounds Physical properties of chemical and covalent compunds Polyatomic (compound) ions Formula of covalent compounds Metals, Alloys and crystals. Chemical bonding in compounds and elements: We have seen many compounds like those we usually see are ammonia, water and methane; these are only formed by chemical bonding between several elements. Bonding in the elements: • Atoms are able to bond to each other to make molecules and compounds. A compound is a molecule with more than one kind of element in it. How do they do it? It has to do with their electrons. • These two opposite ions (metals and non-metals) attract each other and form the ionic bond. Covalent bonding is a form of chemical bonding between two non metallic atoms which is characterized by the sharing of pairs of electrons between atoms and other covalent bonds. Bonding in metals Metallic bonding is a type of chemical bonding that rises from the electrostatic attractive force between conduction electrons and positively charged metal ions. It may be described as the sharing of free electrons among a structure of positively charged ions. In metals, the electrons leave the outer shells of metal atoms, forming positive metal ions and a 'sea' of delocalised electrons. Metals are solids at room temperature, so the structure of a solid metal consists of closely packed metal ions. These ions are arranged in a regular way to form a metallic lattice structure. The lattice has layers of metal ions. Bonding in non-metals A covalent bond is a chemical bond that involves the sharing of electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs, and the stable balance of attractive and repulsive forces between atoms, when they share electrons, is known as covalent bonding. This bonding gives the a stable structure as of elements of 8th group (except hydrogen). Each atom contributes one electron to each bond. Structures formed: Physical properties of ionic and covalent compunds: Properties of typical ionic compounds Properties of simple covalent compounds They are crystalline solids at room temperature They are often liquid or gas at room temperatures They have high melting point They have low melting and boiling points They are often soluble in water (not soluble in organic solutions like Ethanol and Methylbenzene They ate soluble in organic solvents like Ethanol and Methylbenzene (only a few are soluble in water) They conduct electrucity when molten or dissolved in water (not when solid) They do not conduct electricity Metals, alloys and crystals. • Metal crystals: These crystals are typically solid with a • high melting point. An example of an ionic crystal is table salt. Metallic crystals are crystals made of metal elements. These crystals sparkle with the lustrous sheen we think of metals having. The energy is transferred throughout the rest of the metal by the moving electrons. Metalsare described as malleable (can be beaten into sheets) and ductile (can be pulled out into wires). This is because of the ability of the atoms to roll over each other into new positions without breaking the metallic bond. Alloys An alloy is a combination of a metal with at least one other metal or nonmetal. The combination must be part of a solid solution, a compound, or a mixture with another metal or nonmetal in order for it to be considered an alloy. The most common way to combine metals into an alloy is by melting them, mixing them together, and then allowing them to solidify and cool back to room temperature. Alloys give a property of being much harder than the pure elements they were before. Ionic crystals An ionic crystal consists of ions bound together by electrostatic attraction. The arrangement of ions in a regular, geometric structure is called a crystal lattice. Examples of such crystals are the alkali halides, which include: •potassium fluoride (KF) •potassium chloride (KCl) •potassium These solidsbromide tend to (KBr) be quite hard and have high melting points, reflecting the strong forces between oppositely-charged ions. The exact arrangement of ions in a lattice varies according to the size of the ions in the crystal. Giant molecular crystals Giant molecular crystals are those in which a large number of atoms are covalently bonded to each other creating a network. There are four examples of molecules forming giant structures. They are silicon and two forms of carbon called Silicon dioxide called silica) is the main compound found in sand. It is an diamond and(often graphite. example of a substance with a giant covalent structure. It contains many silicon and oxygen atoms. All the atoms in its structure are linked to each other by strong covalent bonds. The atoms are joined to each other in a regular arrangement, forming a giant covalent structure. There is no set number of atoms joined together in this type of structure