Emission Spectra and Atomic Models Emission of Energy by Atoms • Ground state: An atom with its electrons in the _______________ possible energy levels (closer to the nucleus) • Excited state: Electrons that _______________ energy and occupy _______________ energy levels (further from the nucleus) • When heated, an electron can absorb energy, become ____________________, and move to a higher energy level • When it loses that energy and falls back to the ____________________ state, the electron emits the same amount of energy as a photon • The energy of the photon _______________ as the electron falls from the excited state back to the ground state corresponds to a specific frequency of light • If the frequency is within the ____________________ spectrum, we can see it • The ___________________ we see is determined by the frequency of the photon Emission Spectra of Elements • Spectrum- a band of colors, produced by separation of the components of light by their different degrees of refraction according to wavelength • When _______________are connected to a voltage source and heated, they glow and emit light • The light that is emitted by the hot gas can be shined through a prism and split into __________ wavelengths which we see as lines against a dark background • The _______________ in the emission spectrum represent the energy released by the photons as the electrons fall from the excited state back to the ground state. • Since light is quantized, the energy levels within the electron cloud of that element correspond to specific photon wavelengths. • Because every element has a ____________________ “light signature”, an emission spectrum can be used to identify the element Emission Spectrum of Hydrogen • The emission spectrum of hydrogen has _______________ spectral lines • The emission spectrum of hydrogen, in conjunction with the photoelectric effect, provided the evidence Bohr needed to develop his model of the atom Bohr’s Model of the Atom • Bohr’s model of the atom involved electrons moving around the nucleus, in fixed, circular orbits, like planets around the sun. • Bohr said that the energy of electrons is quantized; therefore, electrons can occupy only certain orbits or energy levels. • Quantum- amount of energy required to _______________ an electron from one energy level to another energy level • Think about a ladder to understand the concept of quantized electron energy levels: ➢ Lowest rung is lowest energy level (n =1) ➢ You can move from rung to rung, but you cannot step between rungs. ➢ Similarly, an electron can move from energy level to energy level, but it cannot exist between levels ➢ You must have correct amount of energy to move from rung to rung, just as an electron must have correct amount of energy to move from level to level • The Bohr Model is important because it showed us that _____________________________ exist within the atom and that electrons can change energy levels when they absorb (gain) or emit (lose) energy • The _____________________ with Bohr’s model is that it worked only for hydrogen and not atoms with more than one electron. Quantum Mechanical Model s p d f • The quantum mechanical, or _______________________________, model is what we use today • Electrons move unpredictably within ____________________ inside the electron cloud • Orbital-a representation, or ____________________ map, of the space occupied by an electron within an atom