See discussions, stats, and author profiles for this publication at: https://www.researchgate.net/publication/281061409 Welding of Duplex Stainless steel Conference Paper · May 2013 CITATION READS 1 1,885 1 author: Hans Astrom ELGA AB 2 PUBLICATIONS 11 CITATIONS SEE PROFILE All content following this page was uploaded by Hans Astrom on 18 August 2015. The user has requested enhancement of the downloaded file. Welding of Duplex Stainless Steel ELGA meeting 16/5-2013 Hans Åström DUPLEX STEELS - Index • Chemical composition • Microstructure • Properties - Mechanical - Corrosion • Welding - Welding procedures and welding methods - Shielding gases - Joint preparation - Set-up and tacking - Welding techniques - Repair welding • Imperfections – how to avoid • Post weld cleaning • Utilizing the strength of duplex steels • Applications How to weld duplex – 2 1 DUPLEX STEELS - History First duplex stainless steel was produced end 1920: Avesta 453 S (26%Cr, 5%Ni, 1.5%Mo) Avesta 453 E (26%Cr, 4%Ni) Modern duplex steels, 1960- (possible to alloy using nitrogen) Sandvik 3RE60 (18.5%Cr, 5%Ni, 2.7%Mo) 2304 (23%Cr, 4.5%Ni, 0.10%N) 2205 (22%Cr, 5.5%Ni, 3%Mo, 0.17%N) SAF 2507® (25%Cr, 7%Ni, 4%Mo, 0.27%N) LDX 2101® (21%Cr, 1,5%Ni, N, Mn) LDX 2404 (24Cr, 3,6Ni, 1,6Mo, 3Mn, 0,27N) How to weld duplex – 3 DUPLEX STEELS - Chemical composition Chemical composition (typical values wt-%) Grade ASTM EN C (max) N Cr Ni Mo Mn S32101 1.4162 0.02 0.22 21.5 1.5 0.3 5 Filler LDX - - 0.03 0.16 23.5 7 <0.5 0.8 2304 S32304 1.4362 0.02 0.10 23 5 <0.3 1.5 Filler 2304 - - 0.02 0.12 24.5 8 <0.3 0.8 2205 S32205 1.4462 0.02 0.17 22 6 3.1 1.5 Filler 2205 E2209 22 9 3 N L 0.02 0.16 23 9.5 3.2 0.8 SAF 2507® S32750 1.4410 0.02 0.27 25 7 4 1.5 Filler 2507 E2594 25 9 4 N L 0.03 0.23 25.5 10 4 1.2 LDX 2101® How to weld duplex – 4 2 DUPLEX STEELS - Microstructure + Austenitic = Duplex Ferritic Duplex steels combine the austenitic and ferritic properties How to weld duplex – 5 DUPLEX STEELS - Microstructure BASE MATERIAL WELD METAL Controlled cooling Cooling rate can vary Ferrite 50% Ferrite 20-70% 3 DUPLEX STEELS - Ferrite content The ferrite content is influenced by several factors: Chemical composition • • Composition of filler Dilution with parent metal (joint preparation/parameters) Cooling time (1200800°C) • • • Heat input (welding procedure) Material thickness (welding procedure) Interpass temperature (welding procedure) Use right filler metal and follow the welding procedure How to weld duplex – 7 DUPLEX STEELS - Ferrite content The ferrite content for duplex steel is best predicted by... • WRC-92 …or measured with... • Ferritescope (Fischer MP-3) • Manual point counting (ASTM E562) Big variations between and within methods. Always use mean values. How to weld duplex – 8 4 DUPLEX STEELS - Physical properties Heat conductivity: Mild steel 47 W/mºC CrNi steel 15 W/mºC Duplex steel 14 W/mºC Thermal expansion: Mild steel 12 x10-6/ºC CrNi steel 17 x10-6/ºC Duplex steel 13 x10-6/ºC How to weld duplex – 9 DUPLEX STEELS – Position Hot coil LDX 2404® 2507 550 LDX 2101® 450 400 Duplex 500 2205 2304 4565 350 4439 300 250 200 Austentic Yield strength, Rp0.2 [MPa], Min. värden 600 4438 4404 254 SMO 904L 4307 4436 150 Bildplacering Bildplacering Corrosion resistance, ASTM G150 CPT How to weld duplex – 10 5 DUPLEX STEELS – Mechanical properties Tensile strength - typical values base metal 700 Rp0.2 (MPa) 600 500 400 300 200 100 0 4404 2304 LDX 2101 2205 2507 How to weld duplex – 11 DUPLEX STEELS – Mechanical properties Impact toughness - typical values base metal 350 300 KV (J) 250 Austenitic Duplex Carbon Steel 200 150 100 50 0 -150 -125 -100 -75 -50 -25 0 25 Temp. (°C) How to weld duplex – 12 6 Welding Duplex Stainless Steels – Properties DUPLEX STEELS – Corrosion resistance Duplex steels has generally a very good corrosion resistance that increases with the contents of Cr, Mo and N. • • • • General corrosion Pitting and crevice corrosion High resistance to stress corrosion cracking due to high strength High resistance to inter crystalline corrosion CPT (°C) ASTM G150 100 80 60 Base metal 40 Weld metal 20 0 4404 LDX 2101 SAF 2304 2205 SAF 2507 254 SMO How to weld duplex – 13 DUPLEX STEELS – Key to success Five keys for a successful result 1. Use the right filler metal to achieve right structure = right properties 2. Choose “optimal” welding method for each application 3. Right joint preparation, proper fit-up and clean weld zone 4. Let the welders train how to weld duplex and follow the welding procedure 5. Chose right and make the post weld cleaning carefully How to weld duplex – 14 7 DUPLEX STEELS – Shaping Duplex steels are prone to precipitations when subjected to temperatures below app. 900°C. Precipitations lowers both ductility and corrosion resistance. LDX 2101® 2304 2205 SAF 2507TM Hot forming (C°) 900-1100 900-1100 950-1150 1025-1200 Solution heat treatment (C°) 1020-1080 950-1050 1020-1100 1040-1120 Stress relieving (C°) 1020-110 950-1050 1020-1100 1040-1120 How to weld duplex – 15 DUPLEX STEELS – PWHT Duplex steels shall in general not be PWHT. Risk of embrittlement due to intermetallic phases in the temperature range 600-900°C and due to ferrite decomposition at 350-525°C. These temperatures should be avoided. No risk at normal welding operations. Reduction of impact strength to 50% compared to solution annealed condition How to weld duplex – 16 8 DUPLEX STEELS - Properties CONCLUSIONS • Duplex steels combines austenitic and ferritic steels properties • • High mechanical properties High resistance against corrosion • Welds within the ferrite range 30-70% has good mechanical and corrosion properties. • Less expansion and heat conductivity compared to austenitic steels. • Higher forces for cold forming compared to austenitic steels. How to weld duplex – 17 DUPLEX STEELS - Welding All conventional welding methodes can be applied to DSS • • • • • MMA (SMAW) FCW (FCAW) MIG (GMAW) TIG (GTAW) SAW How to weld duplex – 18 9 DUPLEX STEELS - Welding methods MMA Characteristics • Flexibility - all positions • Flexibility - chemical composition • Flexibility – coating composition • Plate thickness – 2 mm and upwards • Suitable for: • Bildplacering Fabrication welding • On site welding • Repair welding How to weld duplex – 19 DUPLEX STEELS - Welding methods MMA How to weld duplex – 20 10 DUPLEX STEELS - Welding methods MIG Characteristics • High productivity • Plate thickness up to 6 mm • Plate thickness below 1,5 mm requires special Bildplacering welding machines (CMT or SuperPulse®) • Best weldability using pulsed arc but spray and short arc also possible • Good weld metal properties i.e. impact toughness • Suitable for: • Mechanised welding • Robot welding How to weld duplex – 21 DUPLEX STEELS - Welding methods TIG Characteristics • High quality weld metals • Superior weld bead appearance • Plate thickness up to 4 mm + root runs • All positions • “Low” productivity • Good weld metal properties i.e. Bildplacering impact toughness • Suitable for: • Single side root runs • Pipes and tubes • Mechanised welding How to weld duplex – 22 11 DUPLEX STEELS - Welding methods SAW Characteristics • High productivity • Good weld bead appearance • Plate thickness 10 mm and upwards • Flat position • High heat input • Suitable for: • Bildplacering Pre fabrication • Welding using a agglomerated flux • Importance with right wire and flux combination How to weld duplex – 23 DUPLEX STEELS - Welding methods FCW Characteristics • High productivity • Good positional weldability • Surface appearance • Plate thickness 2,5 mm and upwards • Wide parameter box / welder friendly • Suitable for: • Pre fabrication • On site welding • Horisontal and position wires • Single side welding against ceramic backing Bildplacering How to weld duplex – 24 12 DUPLEX STEELS - Welding methods plasma Characteristics • High energy and focused arc • High welding speed • High quality weld metals with low deformation • Good weld metal properties i.e. • Good penetration using keyhole • Plate thickness up to 8 mm • Suitable for: Bildplacering impact toughness • Automatic and mechanised welding • Longitudinal pipe welding • Root PAW followed by TIG or SAW • Filler wire unless PWHT can be performed How to weld duplex – 25 DUPLEX STEELS - Welding methods laser Characteristics • High energy, high focus arc • High quality weld metals with low deformations • Deep penetration • YAG or CO2 laser • High productivity • Good weld metal properties i.e. Bildplacering impact toughness • Laser: plate thickness up to 4 mm • Laser hybrid: plate thickness up to 10 mm • Suitable for: • Laser hybrid MIG Automatic and mechanised welding How to weld duplex – 26 13 DUPLEX STEELS - Welding methods Choice of welding method • Productivity • Positional welding • Welder friendly • Access How to weld duplex – 27 Deposition rate (kg/h) DUPLEX STEELS - Welding methods 10 FCW (1,20 m m ) 8 MIG (1,20 m m ) 6 TIG (2,40 m m ) SAW (dim 3,20 m m ) 4 SMAW (3,25 m m ) 2 SMAW (4,00 m m ) 0 SMAW (5,00 m m ) 50 100 150 200 250 300 350 400 450 500 Current (A) How to weld duplex – 28 14 Method Plate thickness MMA > 1,5 mm Advantage Flexibility position Flexibility grades Ergonomic Welding speed MIG > 1,5 mm Cost Impact toughness TIG Productivity Slag remains Surface appearance Parameter adjustment 0,3-3 mm Surface appearance Productivity Root runs Impact toughness Shielding and purging gas Productivity SAW Disadvantage > 10 mm Surface appearance No fume and radiation FCAW > 2.5 mm PAW 1-8 mm Laser 1-8 mm Lasertohybride How weld duplex –4-15 29 mm High heat input Only horizontal Productivity Fume emission Wide parameter box Impact strength Welding speed Fit up Surface appearance Expensive equipment Welding speed Surface appearance Fit up Expensive equipment Productivity Expensive equipment Weld metal properties Parameter set up DUPLEX STEELS – Shielding gases Method Grades Shielding gas General guidelines: MIG LDX 2101, 2304, 2205 1. Ar+1-2%CO2 or Ar+1-3%CO2 2. Ar+1-2%CO2 or Ar+2-3%CO2 • Gas flow MIG 12-16 l/min 2507/P100 1. Ar+1-2%CO2 or Ar+1-3%CO2 2. Ar 3. Ar+30%He+1-2%N2+1-2%CO2 •Too a low or too a high flow may result in porosity. TIG LDX 2101, 2304, 2205, 2507/P100 1. Ar+10-30%He+2%N2 2. Ar FCAW LDX 2101, 2304, 2205 1. Ar+16-25%CO2 2. 100%CO2 Plasma LDX 2101, 2304, 2205, 2507/P100 1. Ar* 2. Ar+20-30%He+1-2N2* Laser LDX 2101, 2304, 2205, 2507/P100 1. Ar • Gas flow TIG 8-12 l/min • All methods are sensitive to draughts. • Check housing, couplings etc. * Also as plasma gas How to weld duplex – 30 15 DUPLEX STEELS – Backing gases 40 15 MISONN2He Ar + 3%N2 20 Ar 25 Ar+2%N2 30 Ar (No filler) Temperature,°C 35 An addition of up to 3% nitrogen gives a positive effect on the resistance to pitting corrosion. Autogenous welding of special grades is not advisable. 10 How to weld duplex – 31 DUPLEX STEELS – Backing gases Unless pickling is possible an inert backing must be used when non-fluxing processes (TIG and MIG) are employed for the root run of single side welds. The backing provides protection against oxidation. If no, or inadequate, protection is provided the penetration bead and surrounding metal will be badly oxidized. How to weld duplex – 32 16 DUPLEX STEELS – Backing gases The purging gas is often applied via: • Purge insert • Cardboard or tape The enclosed volume should flushed at least 7 times. The purging gas must be applied to at least 8 mm of weld metal. Oxygen meter is best used to measure the content. How to weld duplex – 33 DUPLEX STEELS – Backing gases Acceptance criteria A straw yellow colour can normally be accepted. This requires a oxygen content of max 50-60 ppm. How to weld duplex – 34 17 DUPLEX STEELS – Key to success Five keys for a successful result 1. Use the right filler metal to achieve right structure = right properties 2. Choose “optimal” welding method for each application 3. Right joint preparation, proper fit-up and clean weld zone 4. Let the welders train how to weld duplex and follow the welding procedure 5. Chose right and make the post weld cleaning carefully How to weld duplex – 35 DUPLEX STEELS - Joint preparation • Avoid small joint angels • Root gap is essential for full penetration • Edge preparation: 1. Milling 2. Plasma cutting followed by smooth grinding 3. Grinding the joint shall be avoided • Cleaning of the joint after preparation: • Edge burs • Degreasing Keep the joint and plate clean before welding How to weld duplex – 36 18 DUPLEX STEELS - Joint preparation FCW, MIG, MMA, TIG I-joint, t = 2-4 mm D = 2-2,5 mm V-joint, t = 4-16 mm = 60-70° C = 1,5-2 mm D = 2-3,5 mm FCW welding can be performed using ceramic backing (round type) D = 4-6 mm How to weld duplex – 37 DUPLEX STEELS - Joint preparation FCW, MMA, SAW X-joint, t = 14-30 mm = 60-70° (SAW 80-90°) D = 2-2,5 mm (SAW 0 mm) C = 2-2,5 mm (SAW 3-8 mm) B C By choosing X-joint instead of V-joint the consumption of consumables can decrease be app. 10% and the distortion will be minimised How to weld duplex – 38 19 DUPLEX STEELS - Joint preparation Root face 8 mm 16 mm plate Bevel angel 45 Example SAW 2205, t=16 mm How to weld duplex – 39 DUPLEX STEELS – Fit-up • Greater distortion then mild steel but less than for austenitic steel • Careful fit-up - keep the root gap! • Tack welds should be “removed” before welding • Avoid misalignment 150-200 mm How to weld duplex – 40 20 DUPLEX STEELS – Fit-up • Bridges, bullets or horses can be used when fitting-up the joint. Keep the root gap!! • Tacking of the bridge must be performed using suitable duplex filler metal. • All tacks outside the joint must be removed by removed properly. • Disalignment should be avoided Good tacking is essential for a proper result Good relation between ”tackers” and welders How to weld duplex – 41 DUPLEX STEELS – Key to success Five keys for a successful result 1. Use the right filler metal to achieve right structure = right properties 2. Choose “optimal” welding method for each application 3. Right joint preparation, proper fit-up and clean weld zone 4. Let the welders train how to weld duplex and follow the welding procedure 5. Chose right and make the post weld cleaning carefully How to weld duplex – 42 21 DUPLEX STEELS - Temperatures • Pre-heating not necessary. Welding outside in humid and cold weather condition requires a slight pre-heating (max 40°C) to avid moist in the joint • Interpass temperature max 150°C • Heat input 2205, 2304 LDX 2101, 2507 0.5 – 3.0 kJ/mm 0.3 – 1.5 kJ/mm • No post weld heat treatment should be carried out • Hot forming using flame should be avoided due to risk of carbon pick-up How to weld duplex – 43 DUPLEX STEELS - Welding techniques • Two side welding is easier than one side unless FCW against ceramic backing is used • Visual inspection between each run • Grinding should be performed between runs to “open” up the joint (be careful with the plate surface) • Grinding of start and stops • Stringer beads (horizontal) • Weaving (vertical-up) • Avoid to thin runs (porosity) • Protect the weld area from wind and draught How to weld duplex – 44 22 DUPLEX STEELS - Welding sequence Root run • Sound weld metal • Full penetration • Single side runs using MMA or TIG • TIG requires root protection Filler runs • High deposition rate without imperfections • MMA, FCW, MIG, SAW Cap runs • Surface appearance • Minimum of post weld cleaning How to weld duplex – 45 DUPLEX STEELS - Welding procedures Welding Procedure Specification ELGA AB Issued by: Hans Åström Charge: Basematerial: A: B: Welding position: 10 mm 10 mm PA (1G) Preheat: B C A C 1 2-3 4-5 Run 1 2-3 4-5 80° 1,5-2,5 mm Gro up: B 0,5-1,5 mm PWHT N.A. Backing: No Joint prep. Milled Filler material ELGA 2205 ELGA 2205 2205 Dia. 1,6 2,4 3,25 Batch No. Polarity Current Speed Energy kJ/mm 0,6-0,8 0,5-0,6 1,4-2,1 Voltage Ampere Volt mm/s 10-12 10-12 20-25 0,8-1,5 1,5-2,5 6-9 1(1) Date: 2006-05-11 Establish a proper welding procedure and follow it! P ipe Ø: No °C Max.150° °C °C h Notes: Welding from one side. Purging gas: Ar (10-15 l/min). Purging applied for all runs. Process GTAW GTAW SMAW 60-80 80-110 100-120 Side: ø400-1000 mm ø400-1000 mm Interpass temp. A Run Thickness: 2205 (EN 1.4462) 2205 (EN 1.4462) WPS No: HÅ155 Gas/Flux Ar +2% N2 (5-8 l/min) Pulsed arc Wire feed Note: m/min How to weld duplex – 46 23 DUPLEX STEELS – Overlay welding Duplex filler metals can be used for all types of overlay welding of carbon steel. The duplex overlay is resistant to both corrosion and wear resistance. The dilution with the carbon steel should be minimised and MMA and TIG gives generally the lowest dilution. SAW gives generally a very high dilution and should be avoided. The dilution can be heavily affected with the welding technique and parameter set-up. 309L or 309MoL is an cost efficient alternative as first layer. How to weld duplex – 47 DUPLEX STEELS – Key to success Five keys for a successful result 1. Use the right filler metal to achieve right structure = right properties 2. Choose “optimal” welding method for each application 3. Right joint preparation, proper fit-up and clean weld zone 4. Let the welders train how to weld duplex and follow the welding procedure 5. Chose right and make the post weld cleaning carefully How to weld duplex – 48 24 DUPLEX STEELS – Dissimilar welds ? X Z How to weld duplex – 49 DUPLEX STEELS – Dissimilar welds SAF 2507 2205 2507 2304 2304 2304 2205 2507 2205 2205 2101 2205 2205 2507 SAF 2507 2507 2507 2507 2507 2101 309MoL 309L 2304 309MoL 309L 2205 309MoL 309L 2507 309MoL 309L 2101 309MoL 625 2304 309MoL 625 2205 309MoL 625 2507 309MoL 625 Carbon Steel 2205 2304 254 SMO 2304 2101 316 LDX 2101 LDX 2101 304 Grade 2101 309MoL 309L 2304 309MoL 309L 2205 309MoL 309L 2507 309MoL 309L How to weld duplex – 50 25 Weld defects in DSSDSS • Solidification cracking • Porosity • Slag inclusions • Spatter • Weld oxides • Precipitates • • Sigma phase Nitrides Field experience next ….. How to weld duplex – 51 5 How to weld duplex – 52 26 How to weld duplex – 53 How to weld duplex – 54 27 How to weld duplex – 55 How to weld duplex – 56 28 How to weld duplex – 57 DUPLEX STEELS - Be aware of… The penetration into base material is less for duplex steels than f ex 1.4301 (304) and 1.4401 (316). Risk for incomplete penetration. Full penetration essential for structural integrity and good properties 2 - 2,5 mm root gap + 30° bevel angle How to weld duplex – 58 29 DUPLEX STEELS - Be aware of… The high nitrogen content in base material and consumable increase the sensitivity for porosity formation compare to 1.4301 (304) and 1.4401 (316). To thin or thick beads increase the risk How to weld duplex – 59 DUPLEX STEELS - Be aware of… Striking scars, grinding scars, surface oxides, crevice all decreases the corrosion resistance repair welding must be performed using filler How to weld duplex – 60 30 DUPLEX STEELS - Be aware of… Too low energy gives high cooling rate a high ferrite content and nitrides decreased corrosion resistance and toughness Too high energy gives low cooling rate risk for precipitation's of inter metallic phases decreased corrosion resistance and toughness DUPLEX 2304, 2205 max 3 kJ/mm DUPLEX LDX 2101, 2507 max 1,5 kJ/mm How to weld duplex – 61 DUPLEX STEELS - Repair Imperfections must be removed and repair • Grinding or plasma gauging to sound metal (use stainless tools) • Protect the surrounding area from spatter (cardboard or choke paint) • Consider the width and depth • Penetrant testing • Welding with suitable method • Inspection • Repair can be performed several times without harming the base metal Establish repair procedure!! How to weld duplex – 62 31 DUPLEX STEELS - Repair How to weld duplex – 63 Post weld cleaning - Applications How to weld duplex – 64 32 DUPLEX STEELS – Key to success Five keys for a successful result 1. Use the right filler metal to achieve right structure = right properties 2. Choose “optimal” welding method for each application 3. Right joint preparation, proper fit-up and clean weld zone 4. Let the welders train how to weld duplex and follow the welding procedure 5. Chose right and make the post weld cleaning carefully How to weld duplex – 65 DUPLEX STEELS - Storage & handling • Covered electrodes and FCW are sensitive to moist • • Porosity Bad weld bead apperance • Product should be stored in original packaging in a moist and heat controlled room (80%/20°C) • After use back to package and storage room. No electrodes/FCW/Flux ”over night” • Re-drying at 250-280º for 3 hours (SMAW and Flux) How to weld duplex – 66 33 DUPLEX STEELS - Applications 2205 Civil Engineering Bridges, crash barriers, rebars, lamp-posts, aerial masts, flood-gates, beams 2205 LDX 2101 2205 LDX 2101 2304 How to weld duplex – 67 DUPLEX STEELS - Applications Pressure vessels Process vessels, heat exchangers, domestic heaters Process vessel Domestic Heat exchanger heater How to weld duplex – 68 34 DUPLEX STEELS - Applications Transportation Bus frames, car bodies, mobile vessels Barge tank Trailer chassis Chassi How to weld duplex – 69 DUPLEX STEELS - Applications Heavy Industry Pipe systems Continuous digester Petro chemical Sulphuric acid production Batch digesters Flue gas cleaning Papper machine How to weld duplex – 70 35 DUPLEX STEELS - Applications Cargo tanks How to weld duplex – 71 DUPLEX STEELS - Applications Storage tanks Caustic liquor, petroleum products, wine, water, etc. Marble slurry tanks, Norway Palm oil tanks, Netherlands White liquor tank, Finland How to weld duplex – 72 36 DUPLEX STEELS - Utilizing strength Mechanical and physical properties, RT, minimum values Grade Rp0.2 [MPa] Rm [MPa] E [GPa] [x103 kg/m3] [x10-6/°C] 304L 210 520 200 7.9 16.0 460 640 200 7.8 13.0 450 650 200 7.7 13.0 2205 (S32205) LDX 2101 (S32101) Factors influencing how the strength can be utilized: • Function – e.g. cylinder with internal pressure • Constraints: Shape (diameter, height etc.) Loading condition (wind loads – instability etc.) Material standards and design codes (design stresses etc.) How to weld duplex – 73 DUPLEX STEELS - Cost advantage tank 1.4301 LDX LDX2101 2101 64.9 tons 36.6 tons m 14 12 Required gauge 1.4301 Required gauge LDX 2101 Min gauge (stability) = 6 mm 10 8 6 4 2 [mm] Ø 17 m 16 12 8 4 0 How to weld duplex – 74 37 DUPLEX STEELS - Conclusions • Chose the right filler for the duplex type • Chose right welding method • Importance of right joint preparation • Full penetration • Slag control • Control of the melt pool • Be careful with fit-up and tacking • Controlled heat input • Protect the weld area from wind and draught • Clean weld area • No pre-heating • Handling and storage (stainless is sensitive) • Repair procedures • Post weld cleaning Use right filler and follow the welding procedure How to weld duplex – 75 Welding Duplex Stainless Steels is not difficult just different How to weld duplex – 76 38 View publication stats