CHAPTER – I I CRYSTALS,MINERALS AND ROCKS 2.1 Crystals and their characteristic features ❑ Crystal means simply it is a word came to be applied to any solid body that grown with planar surface. ❑ Crystalline structure is arrangement of atoms in regular, repeating patterns of minerals. These patterns may not be apparent to the naked eye (they are microscopic) and their structures are studied using X-rays. Glass and plastic are non crystalline solids, hence they are not minerals. Figure (a and b) The orderly arrangement of sodium and chlorine ions in halite.(c) Halite crystals. 2.2 Minerals and physical properties in mineral identification The make-up of solid matter on Earth: Atoms → Elements → Compounds → Minerals → Rocks (smallest) What are minerals? (largest) ❖ There are approximately 3,500 minerals, but only a few (about 30) make up about 99 per cent of the volume of the Earth’s crust. Silicate minerals are the most abundant rock-forming minerals in the Earth’s crust, and oxide minerals are the second most abundant. Other common mineral families are the carbonates, phosphates, sulfates and sulfides. Mineral Properties • Minerals are analyzed for these common properties – Color – Crystal Form - reaction with acid – Luster - magnetism – Hardness - striations – Streak - specific gravity – Cleavage - Density – Fracture • Be able to identify minerals in hand sample on the basis of their properties Rock Forming Minerals All the minerals of the earths crust occur in and among the rocks, they are an integral part of the rock. • Silicate minerals are the most common rock forming minerals; they constitute about 95% of the earths crust. •The important silicate minerals are; • Feldspars, Feldspathoids, Quartz,Pyroxenes, Amphiboles, Micas, and Olvines 2.3 ROCKS Rocks are the essential building materials of which the earth is constructed. • The geologist’s definition of rock; - Any mass of mineral matter, whether consolidated or not, which is forming part of the earth’s crust. • Rocks may have only one mineral species, in which case they are known as monomineralic but they usually have an aggregate of mineral species. The rocks are broadly classified into three groups; 1. Igneous Rocks 2. Sedimentary Rocks 3. Metamorphic Rocks Rock cycle Rocks are always changing in a pattern called the rock cycle. Over time, they break down. The minerals in them get recycled to form new rocks. These processes can take millions of years. 1. Igneous Rocks ❖ Igneous rocks are formed by cooling and solidification of magma. ❖ Magma is a hot viscous, siliceous melt containing water vapor and gasses. -It is composed mainly of O, Si, Al, Fe, Ca, Mg, Na, and K When a magma comes out upon the earths surface it looses its gasses such a magma is called lava Origin of Magma ❖ At certain distance below the surface ,the temperature is such that all rocks would be molten ❖ A number of possible sources of heat creating the magma are described below; I. Original heat II. Compaction and contraction III. Radioactivity Original Heat - rocks are very conductors of heat, and the loss of heat from the earth’s is extremely small. - If the earth was one time an incandescent (glowing) ball of fire, a molten sphere, or even a hot solid sphere, some of the original heat may still remain . Compaction and Contraction- If the earth would develop considerable internal heat through the slow compaction of the material (under the pressure of gravity) and contraction of the cooling planet, - Also contraction associated with the folding of layers of rocks would generate large quantities of heat. Radioactivity- Certain unstable chemical elements break down spontaneously, providing energy that is a likely source of all the heat necessary to explain the phenomena of volcanism Occurrence of igneous rocks Magma is produced deep in the earths crust where temperature is 900-1600oC -Based on consolidation or cooling process there are two major types of igneous rocks; - I. Extrusive II. Intrusive I. Extrusive - The rocks formed due to solidification of lava are called extrusive rocks. - When magma reaches the earth’s surface, it causes a volcanic eruption. • As the lava tend to cool and crystallize rapidly, the texture of the volcanic rocks are generally fine grained . Pyroclastic material- volcanic ejected rock fragments. fine dust-sized particles erupted during volcanism referred as volcanic ash. II. Intrusive Rocks – are formed when magma crystallizes beneath the earths surface. Depending on the depth of formation, intrusive rocks are divided in to two groups; I. Plutonic rocks II. Hypabyssal rocks Sedimentary Rocks The total amount of sedimentary rocks that exists in the upper 16 km of the earths crust is estimated to be only about 5%. ❑ sedimentary rock are found chiefly as an extensive cover over the continents ❑ Sedimentary rocks are formed by consolidation and cementation of sediments deposited under water. ❑ Sedimentary rocks also include the rocks formed by accumulation of chemically precipitated or organically derived material . ❑ sedimentary rocks occur in layers and frequently contain fossils ❑ Sedimentary rock The formation of sedimentary rocks takes place in three ways: I. Weathering and erosion - weathering and erosion sediments are produced transported (water or wind) deposited II. Sedimentation - The process of accumulation of sediments at a site of deposition is called sedimentation. The material carried in solution precipitates and accumulates III. Lithification and diagenesis - It is a process by which soft and loose sediments are converted in to hard and firm rocks. During this process many physical and chemical processes take place with in the sediment, such changes are called the diagenetic changes and the process is described as diagenesis. The three diagenesis processes are; • Compaction- in which the rock or mineral particles are brought closer together by the pressure of overlying materials. • Cementation- in which porous materials are bound together by minerals precipitated from water solution such as silicon dioxide (quartz), calcium carbonate (calcite), and the iron oxides(limonite and hematite) • Recrystallization- in which a rock with an interlocking crystalline fabric or grain, such as crystalline limestone, is developed by the continued growth of the mineral grains in a sediment. • The sediments from which sedimentary rocks are formed may be divided into two major groups; -Clastic sediments -Nonclastic sediments -Clastic sediments - are broken fragments of preexisting rocks ranging in size from minute clay particles to very large boulders Conglomerate -Non-clastic Sediments- include those sedimentary rocks which are formed by chemical precipitation of minerals from water or by accumulation of remains of animals and plants. Kaolinite clay Metamorphic Rocks ❖ Metamorphic rocks are formed from older rocks when they are subjected to increased temperature, pressure and shearing stress at considerable depth in the earth’s crust. ❖ During metamorphism recrystalization takes place essentially in the solid state and new minerals and new textures are produced Agents of Metamorphism a) Heat b) Uniform pressure c) Directed pressure or stress d) Chemically active fluids and gases a) Heat - when the earth temperature increases with depth, as a result appreciably high temperature exists at great depths. b) Uniform Pressure- The pressure is due to the weight of the overlying rocks c) Directed Pressure - Directed pressure or stress operates during folding movements that accompany mountain building. d) Chemically Active Fluids and Gases - chemically active fluids and gases when pass through the pores of the rocks, they bring changes in their original composition. Process of Metamorphism a. Granulation b. Plastic deformation c. Recrystalization d. Metamorphism Granulation - pressure shatters the rocks and the pressure is so great that the rocks are partially melted. This process where crushing of the rocks takes place with out loss of coherence is called granulation. Plastic Deformation - when a solid is subjected to stresses, it shape changes. on the removal of stresses if the solid does not regain its original shape, it is said to be plastically deformed Recrystalization - Recrystalization the process of formation of either new minerals or the formation of new crystals of the preexisting minerals Recrystalization causes mineralogical and textural changes in rocks during metamorphism