Possible STEM Chemistry Challenges Which of the following elements are metals: P S Na Cu Sn I W Answer Key Which of the following elements are metals: P S Na Cu Sn I W Align atoms, based on their atomic size, from smallest to largest: Cs K Ca H He Li C Answer Key Align atoms, based on their atomic size, from smallest to largest: He H Li C Ca K Cs Which of the following elements exist as gases at normal conditions (0 oC, 1 atm) Na O Au Cl Ar I N Answer Key Which of the following elements exist as gases at normal conditions (0 oC, 1 atm) Na O Au Cl Ar I N Place elements in order of their discovery year, from ancient times to most recent: Tc O Na Ds Ne Fe Al Answer Key Place elements in order of their discovery year, from ancient times to most recent: Fe O Na Al Ne Tc Ds Which 6 elements compose most of the human body (by mass): Answer Key Which 6 elements compose most of the human body (by mass): O (65%) C (18.5%) H (9.5%) N (3.2%) Ca (1.5%) P (1.0%) Which 6 elements compose most of the Earth crust (by mass): Answer Key Which 5 elements compose most of the Earth crust (by mass): O Si Al Fe Ca Which 7 non-radioactive elements are diatomic at normal conditions (0 oC, 1 atm) Answer Key Which 7 non-radioactive elements are diatomic at normal conditions (0 oC, 1 atm) H N O F Cl Br I Which of the elements don’t exist (without looking at a periodic table) Hf Fu Ba Uh Cd Tx Oh Answer Key Which of the elements don’t exist (without looking at a periodic table) Hf Fu Ba Uh Cd Tx Oh Element Names Match an element with the meaning of its name Acid-forming Am Moon Ar Violet Ca America Cl Lime He Stone I Bringer of Light Li Idle O Sun Po Poland P Earth Se Greenish-Yellow Te Answer Key Match an element with the meaning of its name Acid-forming O Moon Se Violet I America Am Lime Ca Stone Li Bringer of Light P Idle Ar Sun He Poland Po Earth Te Greenish-Yellow Cl Juggling the Gas Law Using PV = nRT (ideal gas law) and other fundamental equations, derive equation for density of gas (depends on pressure, temperature, and molecular weight). Answer Key Using PV = nRT (ideal gas law) and other fundamental equations, derive equation for density of gas (depends on pressure, temperature, and molecular weight). d = (PMw)/(RT) Making Up Elements Write up all possible elements using letters in the word CHEMISTRY (letters can be reused). Answer Key Write up all possible elements using letters in the word CHEMISTRY (letters can be reused). C, H, He, I, S, Y, Er, Ce, Ir, and many more… Salt formulas. Rules of “the game”: • Total positive charge must cancel total negative charge in salts • Common charges (more commonly referred to as oxidation states) are listed here. Compose a stable derivative between: a) Ca and Br b) H and S c) Si and O (Si is +4) d) Al and O e) Na, one C, O f) Ba, O, H g) Ca, one Si, O Answer Key: CaBr2, H2S, SiO2, Al2O3, Na2CO3, Ba(OH)2, CaSiO3. Separating Mixtures Puzzle How would you separate a mixture of: a) sand, table salt b) sand, table salt, iron fillings, vegetable oil c) sand, table salt, iron fillings, ZnO, vegetable oil, gasoline Answer Key: a) sand, table salt. Add water (salt will dissolve), filter sand, evaporate water, salt will be left over. b) sand, table salt, iron fillings, vegetable oil. Use magnet to get iron out. Add water (salt will dissolve), collect oil (will float on top), filter sand, evaporate water, salt will be left over. c) sand, table salt, iron fillings, ZnO, vegetable oil, gasoline. Use magnet to get iron out. Add water (salt will dissolve), filter sand and ZnO through a filter paper. Using a separatory funnel, separate water (with salt) from oil (dissolved in gasoline). Distill gasoline – oil will remain. Evaporate water – salt will remain. Add HCl to the mixture of sand and ZnO – ZnO will dissolve, sand can be filtered then. Draw a sketch of an apparatus (design your own if you’ve never seen one before) that: a) Can filter precipitate from a solution b) Can separate two liquids that boil at two different temperatures c) Can separate three liquids that boil at three different temperatures d) Can separate two liquids that do not mix with one another e) Can heat a liquid in a flask at its boiling point. Points to consider: the flask cannot be left open (because the liquid will boil away) and the flask cannot be capped (pressure created by the vapor will have the flask explode). Answer Key (consult with Dr. D ahead of time if solutions are not clear): a) Can filter precipitate from a solution. (use filtering funnel and flask) b) Can separate two liquids that boil at two different temperatures (use distillation apparatus) c) Can separate three liquids that boil at three different temperatures (use distillation apparatus with a distillation spider) d) Can separate two liquids that do not mix with one another (use separatory funnel) e) Can heat a liquid in a flask at its boiling point. Points to consider: the flask cannot be left open (because the liquid will boil away) and the flask cannot be capped (pressure created by the vapor will have the flask explode). (use reflux apparatus) Matching Puzzles Match a formula with its name (level 1) CaCO3, Cu2SO4, CuS, CuSO3, CuSO4, Fe(NO2)3, Fe(NO3)2, H2S, HCl, HClO4, HCN, NH3, SO2, SO3 Answer key is shown. Before showing to team, delete the second column. Dihydrogen sulfide H 2S Sulfur dioxide SO2 Sulfur trioxide SO3 Hydrogen chloride HCl Hydrogen cyanide Perchloric acid Ammonia Iron(II) nitrate Iron(III) nitrite Limestone Copper(II) sulfite Cupric sulfate Cuprous sulfate Copper(II) sulfide HCN HClO4 NH3 Fe(NO3)2 Fe(NO2)3 CaCO3 CuSO3 CuSO4 Cu2SO4 CuS Match a formula with its description/application (level 2) C20H42, CaCO3, CaSO4•2H2O, H2S, H2SO4, He, HF, Hg, Mg(OH)2, N2, N2O, NaOH, O3, SiO2 Answer key is shown. Before showing to team, delete the second column. Component of air N2 Laughing gas N2O Sulfuric acid H2SO4 Smell of rotten eggs H 2S Only liquid metal at room temperature Hg Air is enriched in this gas after lightning O3 Acid that dissolves glass HF Lye NaOH Milk of magnesia Mg(OH)2 Element identified in the sun but only He later found on Earth Chalk CaCO3 Crayons C20H42 Sand SiO2 Gypsum CaSO4•2H2O Match a formula with its description/application (level 3) As, CH4, Cl2, Fe2O3•H2O, H2SO4, HCl, Hg, Mg(OH)2, MgSO4, NaF, NaHCO3, NaI, P4S3, UF6 Answer key is shown. Before showing to team, delete the second column. Used in tooth fillings Hg Is contained in car batteries H2SO4 Our stomach has this acid HCl Common additive in a table salt NaI Epsom Salt MgSO4 Matches have this P4S3 Poison that might have killed Napoleon As Common ingredient of antacids Mg(OH)2 Used during preparation of a nuclear UF6 bomb Commonly used in toothpaste, to NaF prevent cavities Chemical Weapon during WWI Used quite a bit in baking Natural gas Rust Cl2 NaHCO3 CH4 Fe2O3•H2O Fill an empty Periodic Table. Look at a periodic table for 90 sec. Fill an empty periodic table. Each incorrect answer cancels out a correct answer. (Empty Periodic Table provided) Find 9 first elements. Look the file attached. Periodic Table of mistakes. Look the file attached. Balancing equations using M&Ms. Description (great find, Joel!): R – red, B – blue, G – green. R2B means two reds and one blue and cannot be broken down when balancing. The goal is to make number of M&Ms on both sides of the reaction to match one another. Easy: R2 + B2 = R2B (Answer Key: 2R2 + B2 = 2R2B) Intermediate: R2B + G = GBR + R2 (Answer Key: 2R2B + 2G = 2GBR + R2) Difficult: RG4 + B2 = RB2 + G2B (Answer Key: RG4 + 2B2 = RB2 + 2G2B) Be in Mendeleev’s Shoes (See a related pdf file, from Flinn Scientific, actually). 1) Print copies. Cut all the 9 cards and take one card (any one) away. Remember order before cutting the cards, this is your answer key. 2) Students’ goal is to put together a table 3x3, identify a missing element, and predict its properties (should be an average of nearby elements). 3) Info to help: each element has molecular weight (top left), oxidation states (top right), density (below molecular weight), boiling and melting point (further down). Drawing Lewis Structures – Puzzle. Description: In order for molecules to be stable, elements that compose them need to have a certain number of bonds (lines) surrounding them. Group # 1 2 3 4 5 6 7 # of 1 2 3 4 3 2 1 bonds Element can have a single, double, or triple connection to a different element. Draw stable structures: Easy: N2, CO2, H2O2, C2H2, N2H4 Medium: Na2CO3, K3PO4 (here, P has 5 bonds), H2SO4 (here, S has 6 bonds). In all of these examples, Na, K, and H are connected to O atoms. Hard: C4H2, P4, C4O4, B3N3 Answer Key: ask Dr. D if needed. Isomers Puzzle - Isomers are made from same atoms but arranged differently - For example, isomers of C4H10 (feel free to build a model using the provided kit): - note how it's possible to rotate around single bonds - note that all other possibilities will be duplicates of the two structures above Assignment: Predict all isomers of: C5H12 (3 isomers) C4H8 (6 isomers) C4H6 (9 isomers) Answer key (only carbon-carbon bonds are shown):