What are Minerals? To meet the definition of "mineral" used by most geologists, a substance must meet five requirements: Naturally occurring Inorganic Solid Definite chemical composition Orderly internal crystal structure Minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various species. All minerals have a unique and specific chemical composition. This is like the DNA of the mineral - it's what makes the mineral different from other minerals. There are over 5,300 known mineral species; as of September 2017, over 5,290 of these had been approved by the International Mineralogical Association (IMA). The silicate minerals compose over 90% of the Earth's crust. Silicon and oxygen constitute approximately 75% of the Earth's crust; which means there are more silicate mineral 1 The properties that can be used to identify minerals are: Luster: this refers to the 'shininess' of the mineral (how light is reflected off the surface) Color: color can vary even within the same mineral, like corundum (it can be white, blue or red), depending on what other elements are present. Hardness: Ability to resist scratching not how easily it breaks. Hardness depends on the bonds within the mineral, so the stronger the bonds, the harder the mineral. Mineral hardness is measured on the Mohs scale of hardness, which compares the hardness of different minerals. Streak: a streak is the color, of the powdered form, of the mineral. (it can be made by scratching a porcelain tile) Cleavage and Fracture: is the way a mineral breaks apart. If it breaks along smooth, flat surfaces or planes, it has cleavage. If it breaks with rough or jagged edges, it has fracture. Transparency: it can be transparent (see through), translucent (shadowy), opaque (non-see through) The Importance and use of Minerals Just about everything like computers, medicines, jewelry, copper wiring, and electronics. 2 Physical Properties – Luster Luster - the character of light reflected from the mineral A mineral’s luster may be metallic or non-metallic. 3 Physical Properties – Color Color - the color of the mineral as it appears to the eye in reflected light. Some minerals may have a range of colors. Example: quartz may be color-less, white, pink, purple, dark brown, green, or blue. 4 Physical Properties - Hardness Hardness - the resistance of a mineral to scratching. Hardness is measured on a scale of 1 - 10 on the Mohs Scale of Hardness. Hardness of minerals can be determined by comparison to several common objects – fingernail, copper object, nail, glass. Note: Pennies are no longer made of pure copper. 5 Physical Properties – Crystal Form Crystal form - some minerals are in the form of crystals. Crystals "grow" through the addition of chemical ions to their surfaces as they crystallize from magma or lava, mineral-rich waters, or gases. Perfect crystals are rare in nature because they typically grow close together in confined spaces, producing a mass of interlocking crystals. A crystal growing in a larger space may develop crystal faces. Crystal shape is related to the structural arrangement of atoms within the mineral. All minerals can be divided into one of six crystal systems based on symmetry. These systems use three or four imaginary lines, called axes, to define the system based on the length of the axis and the angle that the axes intersect. 6 Crystal Forms 7 8 Physical Properties – Mineral Habit Mineral Habit – visible external shape of the mineral Examples include acicular, bladed, prismatic, hexagonal, cubic, rosette, botryoidal, striated, massive, radiating, twinning, & granular. 9 Physical Properties – Cleavage and Fracture Cleavage and Fracture - the way a mineral breaks when stressed Cleavage – breakage in flat surfaces along planes of weakness Several basic forms based on # directions One direction (basal) Two directional Three directional (not at right angles; rhombic) Three directional (right angles or cubic) Octohedral (4 – directions) 10 Fracture - breaks in random directions (no planes of weakness) 11 Mineral Classification Carbonates Native Elements Halides Oxides/Hydroxides Phosphates Sulfates o Gypsum Varieties Sulfides Silicates o Amphibole Group o Feldspar – Plagioclase o Feldspar – Potassium o Garnet Group o Mica Group o Pyroxene Group o Quartz Varieties 12 Mineral Identification 13 14 Carbonates Minerals made of carbon, oxygen, and a metallic element (contain CO3); This group of minerals is soft and easily dissolved by even mild acids. Some of these minerals form by acidic action of air and rain Most fizz in acid. Reaction with HCl - Calcite, dolomite, malachite. 15 Native elements Minerals made of a single element. Ex. copper, gold, graphite, sulfur, silver 16 Halides Form from halogen elements (chlorine, fluorine) with metallic elements. Usually very soft and easily dissolved in water. Ex. Halite (NaCl) and fluorite. 17 Oxides Combination of a metal & oxygen Common ore minerals. Ex. Hematite (Fe), corundum (Al) 18 Phosphates: Contain PO4 Not as common. Ex. Apatite 19 Sulfates : Compounds of sulfur with metals and oxygen Contain SO4 ; Often form in evaporative environments. Ex. Gypsum (calcium), barite (barium), celestite (strontium) 20 Sulfates – Gypsum Varieties 21 Sulfides: Compounds of a metal with sulfur Common ore minerals. Ex. Galena (Pb), Sphalerite (Zn), Pyrite (Fe), Chalcopyrite & Bornite (Cu, Fe) 22 Silicates Made from metals combined with silicon and oxygen; Largest group of minerals; they make up over 90% of the weight of the Earth’s crust. Quartz family of minerals are the most recognizable of this class. Silicon tetrahedron structure, most common mineral family, many subgroups; some are very complex. Ex. Quartz, feldspars, micas, olivine, hornblende, tourmaline, garnets, augite, talc, epidote, etc. Slightly changing the different elements that combine with silica greatly changes the mineral that results, or the characteristics of the mineral. 23 24 Silicates – Amphibole Group 25 Silicates –- Feldspar - Plagioclase 26 Silicates –- Feldspar – Potassium 27 Silicates –- Garnet Group 28 Silicates –- Mica Group 29 Silicates –- Pyroxene Group 30 Silicates –- Quartz Varieties 31 Rocks A rock is an aggregate of one or more minerals. Rocks are the building blocks of the Earth's crust. Rocks are classified by how they are formed. There are three basic groups, o igneous, o sedimentary o metamorphic In each group, distinctions are made for texture or grain size and chemical or mineral content. 32 How to classify between Igneous, Sedimentary and Metamorphic 33 ROCK CYCLE 34 Rocks Identification 35 36 Igneous Rocks Igneous rocks get their name from the latin word for fire “igneus” These rocks are born of fire. Molten materials or Magma is hot molten rock and are found below the earth crust; they are normally subjected to extreme pressure and temperatures – up to 1200° Celsius. Magma also contains bits of rock crystals and gas. It ranges in consistency from wet concrete to thick oatmeal. Due to extreme heat levels, igneous rocks do not contain organic matter or fossils. Magma is made up of a fairly uniform mixture of elements. Some of the major elements present are silica, iron, sodium, potassium, aluminum, magnesium, and gasses including water vapor, oxygen, carbon dioxide, nitrogen, hydrogen and sulfur dioxide. Lava is hot, molten rock that has flowed out and onto the surface of the Earth. The rocks may be made up entirely of one mineral or various minerals, and the cooling process determines their sizes. Igneous Rocks make up more than 90% of the Earth’s crust, by volume. 37 Magma and Volcanoes Rock that crystallizes from magma is IGNEOUS ROCK. Factors controlling the behavior of Magma 1. Amount of Water 2. Amount of Silica 3. Temperature Viscosity increases with 1. Increase in SiO2 (silica), because of the strong covalent silicon oxygen bonds. 38 2. Decrease in temperature. 3. Decrease in water. (water has a lubricating effect, breaking bonds, making melting easier) HOWEVER, added water causes explosive eruptions due to the rapid expansion of water into steam (Subduction Zones). Rock melts when the temperature within the earth (geotherm) exceeds the melting point (solidus) of the rock. This happens for different reasons at 1) subduction zone volcanoes 2) midocean ridge volcanoes and 3) hotspot volcanoes. As continents collide, crust is pushed down, and melting begins. The first minerals to melt are “granitic.” They rise up, but often cool, before reaching the top of the mountain. These granitic batholiths become exposed at surface when mountains erode. 39 40 BOWENS REACTION SERIES Minerals crystallize at different temperatures. Some are more stable than others. As magma begins to cool, some minerals crystallize first changing the composition of the magma. The last minerals to crystallize are Quartz, sodium and potassium rich feldspars and amphibole -> granite 41 42 Classification of Igneous Rocks – By Texture and Composition o Texture – Influenced by rate of cooling (fast or slow). Texture of a rock is a description of the grain size. o Composition – of a rock is dependent on the mineral composition. 43 There are two forms of silica o Felsic – Feldspar and Silica – Form in granites and are lighter in weight and color because they have less iron and magnesium. o Mafic – Magnesium and Iron – Usually form in magmas moving up to fill the gap left when tectonic plates are moving away from each other on the sea floor. Basalt and Gabbro are this type. Olivine and Pyroxene are ultramafic as they are relatively dark and dense. 44 Composition of Rocks (Felsic Mafic, Intermediate and Ultramafic) 45 Igneous rocks are of two types, Intrusive and Extrusive. o Intrusive (Plutonic rocks) – formed by slow cooling of the rocks beneath the earth’s surface. Texture is coarse grained. o Extrusive (Volcanic rocks) – formed when rocks are quickly cooled at Earth’s surface. Texture is fine grained. Volcanoes and Lavas o Volcanoes are hills or mountains that form around the vent and consist of cooled magma, rock fragments, and dust from eruptions. o Pieces of rocks that are blown out of volcanoes are called pyroclasts or pyroclastic debris o Pyroclastic flows are dense cloud like mixtures o Crater is a circular depression at the top of the volcano o 3 types of volcanoes Composite Built up over million years, they consist of alternating layers of pyroclastic debris and lava Located along the circum-pacific belt also known as Ring of Fire and Mediterranean belt Shield Shield based volcanoes are broad cone shaped hills or mountains made from cooled lavas A spatter cone is a smaller feature that usually develops on a cooling lava flow from a shield volcano Cinder cone Is composed of pyroclastic material ejected from a vent o Volcanic domes If magma is thick and viscous and does not flow easily, it may form a volcanic dome Volcanic domes are steep sided and form near the vents, creating a plug that trap gases and building internal pressures which can lead to violent explosions Viscosity is the resistance to flow; lava with high viscosity flows slower, lava with low viscosity spreads quickly 46 47 Igneous Rock Identification 48 Igneous Environments of Formation (Show textures) 49 Extrusive Igneous Rocks (also known as Volcanic Rocks) Extrusive rocks are formed from lava, which cool quickly on the Earth's surface. Two main kinds of volcanic eruptions Mafic Lava and Felsic/Andesitic Lava Mafic Lava – Effusive/Gushing lava eruptions 50 Intrusive Igneous Rocks (Also known as Plutonic Rocks) Intrusive igneous rocks are formed when the magma cools off slowly under the earth’s crust and harden into rocks. E.g. Gabbro and Granite Rapid or fast cooling results in smaller crystals while slow cooling results in large crystals. Intrusive rocks are very hard in nature and are often coarse-grained. 51 Sedimentary Rocks Sedimentary Rocks cover about 75% of the world’s land area They are formed when loose sediment (gravel, sand, silt or clay) becomes compacted and or cemented to form rock Every rock grain initially separated from other rocks. After many years the materials finally settle down through the process of Sedimentation. As the materials move they are smoothened and rounded by abrasion. They leave pore spaces as they settle down which makes them achieve their distorted shape. Cementation is gluing of rock pieces together by salt compounds or organic matter. The process of converting sediment to sedimentary rock is called lithification Sediment is deposited in horizontal layers called beds or strata Weathering to Sedimentary Rocks How common are Sedimentary Rocks 52 Distinguishing characteristics of Sedimentary Rocks Layers of sediments Grains cemented together Fossils Textures of Sedimentary Rocks 53 54 Sedimentary Rocks Identification 55 Clastic – Compacted and cemented rock fragments; sediments derived from continents Examples – Shale, sandstone, conglomerate and breccia Organic (Bioclastic) – Examples – Limestone (oolitic, fossil), Coal (bituminous and anthracite) Chemical/Biochemical – Examples – Gypsum, rock salt, dolostone, travertine limestone 56 Clastic – Compacted and cemented rock fragments. Sediments derived from continents. They are Inorganic Composed of clay minerals, quartz, feldspar, other mineral & rock fragments Formed by compaction & cementation of grains Rock fragments Continental Environments include rivers, alluvial fans, desert sand dunes, deltas, beaches, lakes Rock type depends on grain size Fossils may be present, particularly in shale and sandstone E.g. Shale, sandstone, conglomerate and breccia Breccia – Angular fragments mixed pebble size and smaller Sandstone – sand sized; mostly quartz Conglomerate – rounded fragments; mixed pebble size and smaller Shale – clay sized particles 57 58 Organic Sedimentary Rocks Formed from remains of plants or animals Often monominerallic If limestone, fizz in acid Many types of limestones due to various environments May or may not have visible fossils 59 Organic – Coal Composed of carbon Coal forms by compression and carbonization of plant material Bituminous Coal is most common Most coal formed 300 million year ago in swamp environments where vegetation was abundant Anthracite Coal is the most pure form of coal (92-98% carbon) and burns the most efficiently. It formed during mountain building episodes when bituminous coal was under heat and pressure. It is often considered a metamorphic rock, but is still found in sedimentary sequences of sandstone and shale. Bituminous Coal Anthracite Coal 60 Organic – Limestone Composed of calcium carbonate (calcite or aragonite) Most formed in marine environment from skeletal remains (shells, algae, forams) Size of grains & types of fossils indicates environment Types of Limestone Coquina – composed of shell fragments 2mm or larger; forms in high energy, shallow marine environment (beach) Fossil Limestone – any limestone containing fossils; may be fine grained or coarse grained; usually shallow marine Oolitic Limestone – formed from small spherical grains (oolites) with 61 concentric layers; formed in very shallow marine, high energy intertidal environment or sometimes on lakebed by wave action. Right: enlarged view of modern oolites from the Bahamas Chalk and Diatomite Chalk and Diatomite are organic sedimentary rocks composed of the shells of microscopic one celled photosynthetic protists Both rocks are light colored and powdery Chalk is a type of limestone, formed from forams and coccoliths Chalk is composed of calcite and will bubble with acid Diatomite is composed of the remains of diatoms Diatom skeletons are composed of opal (silica); diatomite is less dense than chalk and will not bubble with acid Chalk formed in moderately deep marine environments Diatomite formed in lake or marine environments Chalk is composed of coccoliths Chalk is composed of coccoliths 62 Diatomite is composed of Diatoms Travertine Limestone formed from precipitation of calcite or aragonite in springs or caverns Often appears as layers of crystals It is a chemical/crystalline form of limestone Often used as building material 63 Chemical Sedimentary Rocks Crystalline rocks composed of one mineral Rock salt (Halite) and Gypsum form by the evaporation of water (usually seawater) and the precipitation of dissolved minerals. Chemical sedimentary rocks that form by the evaporation of water are called evaporites. Rock Salt (Halite) Rock Gypsum(Alabaster) Chert and Dolostone Chert is a fine-grained silica rich microcrystalline sedimentary rock. It is composed of quartz (SiO2). It often occurs as nodules in limestone or chalk where it is believed to be a replacement mineral. It occurs in layers as a primary deposit in some areas. The banded iron formations of Precambrian age are composed of alternating layers of red chert (jasper) with hematite. Chert comes in many colors, and the dark grey to black form is often called flint. Dolostone is composed of the mineral dolomite and is often described as a “non-descript” rock; looks like driveway gravel. Most dolostone formed when magnesium replaced calcium in limestone or lime mud before lithification. Often has vugs with dolomite crystals 64 Flint nodule in Chalk Banded iron with red chert (jasper) and iron oxide Dolostone – Looks fine grained and non-descript. Vug in dolostone with dolomite crystals 65 Sedimentary Environments 66 Environments in which Sedimentary Rocks are formed 67 Sedimentary Texture Classification 68 Metamorphic Rocks Metamorphic rocks form when pre- existing rocks (igneous, sedimentary, or metamorphic) are exposed to high temperatures and pressures under the Earth's surface. The word metamorphic means "changed form.” Metamorphic rocks can form from sedimentary, igneous, or metamorphic rocks Metamorphism causes changes in the texture and mineralogy of other rocks. Metamorphism results from: o High temperatures, o High pressures o Chemical reactions 69 How to Distinguish Metamorphic Rocks The main thing about metamorphic rocks is that they are shaped by great heat and pressure. The following traits are all related to that. Because their mineral grains grew together tightly during metamorphism, they're generally strong rocks. They're made of different minerals than other kinds of rocks and have a wide range of color and luster. They often show signs of stretching or squeezing, giving them a striped appearance. There are two types of Metamorphism - Regional Metamorphism and Contact Metamorphism Regional Metamorphism – occurs when large areas of rocks are exposed to intense pressure. This occurs most often during mountain building events, so metamorphic rocks are found near mountain ranges 70 Four agents of Regional Metamorphism Heat and Pressure - At high temperatures and pressures, the minerals in most rocks break down and change into a different set of minerals that are stable in the new conditions. Fluids – Most rocks contain some water, but Sedimentary rocks holds the most o Metasomatism – Process which changes rock’s chemistry as well as its mineral assemblage. Sedimentary rocks hold the most water, when they change back to feldspar and mica, water is liberated by clay minerals. This water can become so charged with dissolved materials that the resulting fluid is, in essence, a liquid mineral may be acidic or alkaline, full of silica (forming chalcedony) or full of sulfides or carbonates or metal compounds, in endless varieties. Fluids tend to wander away from their birthplaces, interacting with rocks elsewhere. Strain – Change in shape of rocks due to force of stress Foliation and Non-Foliation Foliation is a property of metamorphic rocks that have parallel wavy layers. Sometimes the parallel layers form alternating bands of light and dark colors, this is called banding. 71 Foliation is a property of Metamorphic rocks that have parallel wavy lines Banding is a property of Metamorphic rocks that have wavy layers that alternate between light and dark colors Contact Metamorphism – occurs when hot magma forces its way up into the crust. When this happens the heat cooks the rocks nearby causing metamorphism Eventually the magma will cool and become a layer of igneous rock that cuts into the rocks around it. This is called an igneous intrusion. Contact metamorphism rarely reaches more than 100m from the igneous intrusion. 72 Metamorphic Rocks Identification 73 Metamorphic Rock Classification 74