2017 chemistry external exam report

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Chemistry
2017 Senior External Examination: Assessment report
Statistics
Year
Number of
candidates
Level of achievement
VHA
HA
SA
LA
VLA
2017
20
3
6
6
3
2
2016
12
0
0
4
4
4
2015
22
2
0
4
7
9
2014
21
3
1
2
7
8
2013
27
4
2
4
11
6
General comments
Paper One Part A assessed Knowledge and simple application and consisted of 10 multiplechoice questions and eight short-response items covering all eight syllabus topics. Marks were
allocated in proportion to syllabus topic weightings.
Paper One Part B assessed Scientific processes and contained five questions assessed against
specific criteria. Candidates were required to respond to any four of the five questions.
Paper Two assessed Complex reasoning processes and contained five questions assessed
against specific criteria. Candidates were required to respond to any four of the five questions.
Paper One
Part A — Knowledge and simple application
Short-response questions
This part of the examination required candidates to demonstrate their knowledge and ability in
simple application of the eight syllabus topics.
Question 11
a. The majority of candidates successfully identified the chemical term associated with the
supplied definitions.
b. Most candidates could distinguish between the two materials.
180120
c. Most candidates could write some correct chemical formulas.
d. Most candidates could identify the structure of a covalent bond.
e. The numbers of neutrons and electrons were easily identified.
f.
Shapes and polarities of molecules were not well understood.
g. Bonding within and between molecules is still challenging for many candidates.
Question 12
a.
It was evident that many candidates had used the terms interchangeably and failed to
appreciate any difference.
b.
Most candidates were familiar with molarity.
c.
Many candidates successfully calculated the mass present.
d.
Conversion of mass to moles to volume was challenging for many candidates.
e.
Most candidates experienced difficulty with empirical formula determination.
Question 13
a.
Most candidates determined the required oxidation number.
b.
Most candidates successfully calculated the cell potential.
c.
Many candidates used Faraday’s laws to calculate the mass deposited.
d.
The diagram of the electrochemical cell often contained incorrect locations of anode and
cathode and consequently incorrect electron flow.
Question 14
a.
Most candidates could select the appropriate chemical terms.
b.
Very few candidates could correctly name the given alcohol.
c.
Many candidates could make substantial progress in determining the structural formulas.
Question 15
a.
Most candidates correctly stated the electron configurations.
b.
Some candidates could link ionisation energies with element location in the periodic table.
c.
Almost all candidates could link electron configuration to periodic table group.
d.
Many candidates understood the factors determining differences in chemical bonding.
Question 16
a.
Many candidates could not list the importance of nitrogen gas.
b.
Many candidates could list the assumptions of kinetic theory.
c.
Real gases were not understood by most.
d.
Most candidates could recall the general gas equation but were then unable to calculate the
moles of the gas.
Question 17
a.
Most candidates could identify the change in energy.
b.
Most candidates had some knowledge of reaction rates.
c.
Most candidates could not identify the need for the activation energy to be achieved.
Chemistry
2017 Senior External Examination: Assessment report
Queensland Curriculum & Assessment Authority
March 2018
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d.
Many candidates were able to successfully calculate the energies associated with bond
breaking and bond formation but then confused the direction of energy flow.
e.
Many candidates made substantial progress once the required equation was identified.
Question 18
a.
Many candidates understood the concept of ‘weak acid’.
b.
Some candidates could appreciate that forward and reverse reactions were proceeding at
equal rates even though macroscopic properties were constant.
c.
Many candidates could write the required equations.
d.
Most candidates did not understand the meaning of an equilibrium constant.
e.
Most candidates could link stresses to the subsequent changes to equilibrium
concentrations.
f.
Most candidates could not apply knowledge of acids and bases to determine the required
pH.
Candidates are encouraged to make use of prior examination papers (and their worked solutions)
in order to gain a greater appreciation of the range and depth of tasks appropriate to the various
syllabus topics.
Part B — Scientific processes
Candidates were directed to respond to four of the five questions. All candidates complied with
this directive. It was evident that most candidates devoted enough time to this section.
Question 1
The novel presentation of the fundamental concept of half-cell reduction potentials was not
attempted by many candidates.
Question 2
Many candidates were able to make substantial progress in the analysis of data based on a
Charles Law experiment.
Question 3
Many candidates were able to successfully analyse and evaluate the information relating to
materials, their bonding and their properties.
Question 4
Many candidates attempted this question and could successfully plot the given data. The
concepts of limiting and excess reagents were understood by most.
Question 5
Candidates were familiar with factors affecting reaction rates and many could provide
explanations that demonstrated understanding.
Scientific processes is one of the three Chemistry criteria and it is important that candidates
demonstrate an ability to successfully engage in simple scientific process tasks by processing
Chemistry
2017 Senior External Examination: Assessment report
Queensland Curriculum & Assessment Authority
March 2018
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information, making simple judgments and communicating information in various forms
throughout their course of study.
Paper Two — Complex reasoning
processes
In responses to Complex reasoning processes questions, candidates must demonstrate logical
reasoning and critical thinking with reference to the chemistry applicable to the task. Credit
cannot be given for recall of knowledge or simple application of that knowledge.
Question 1
Candidates were often able to reduce the given information to a series of steps, each involving a
calculation of moles of either product or reactant.
Question 2
Candidates often were unable to use half reactions to generate the balanced equation for the
redox process.
Question 3
Only two candidates made substantial progress in matching the trial Ksp with the actual Ksp.
Question 4
Candidates were often able to calculate the moles of carbon and hydrogen, but then experienced
difficulty in the calculation of the molar mass and subsequent molecular formula. Naming of the
unfamiliar carboxylic acids was uncertain.
Question 5
Candidates were provided with an equilibrium dissociation position rather than a standard
equilibrium constant. This challenged candidates in their calculations of moles present at
equilibrium and subsequent volume of gas mixture.
Candidates are encouraged to develop an understanding of chemical principles and processes,
rather than attempting to commit huge amounts of factual information to memory. Only then will
they be able to successfully use complex reasoning in challenging and often unfamiliar situations.
Marker responses
The sample solutions on the following pages show possible ways of successfully responding to
the questions. It must be stressed that they do not provide the only valid responses. Other
approaches and problem-solving strategies may be equally valid.
In Complex reasoning processes, the valid response from a candidate must include the
demonstration of logical reasoning and critical thinking, with reference to the chemistry applicable
to the task. No credit was given to recall of knowledge or simple application of that knowledge.
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March 2018
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Paper One
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Paper Two
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