CHAPTER 1: MINERALS: DEFINITION, PROPERTIES AND OCCURRENCES Sarah Lambart CONTENT OF CHAPTER 1 Goal: learn how to describe and classify minerals 3 elements of classification: chemistry, structure and environment Outline: Occurrences of minerals Classification of minerals Physical properties of minerals Definitions: A mineral is always (1) inorganic, (2) naturally occurring, (3) with a structure and a composition that give it defined macroscopic properties. A mineral is most of the time a (1) crystal and (2) a solid. A crystal is a homogeneous chemical compound with a regular and periodic arrangement of atoms. These arrangements present symmetries. A crystal is not always a mineral. It can be synthetic or organic (e.g., proteins) MINERAL OCCURRENCES AND ENVIRONMENTS Igneous Half dome, Yosemite (granite) Sedimentary Montaña de Oro State Beach (shales) Metamorphic Sequoia National Forest California (marble, schist and gneiss) COMMON MINERALS & MINERAL ASSOCIATIONS Metamorphic Omphacite Jadeite (amphibole) (pyroxene) Epidote, chlorite Sedimentary Carbonates Salts (calcite, dolomite,…) (halite) Gypsum Igneous: Olivine + pyroxenes Plagioclases + pyroxenes ADDITIONAL SLIDE Minerals in igneous rock Acid (SiO2>63 wt. %) Rhyolite, granite Rock names (intrusive, extrusive) Common minerals Quartz, alkali feldspar (plagioclase, hornblende, micas) Intermediate (52<SiO2<63 wt. %) Andesite, dacite, diorite, tonalite, Sodic plagioclase (hornblende, biotite, quartz, pyroxene). Basic (45<SiO2<52 wt. %) Basalt, gabbro, pyroxenites pyroxene, plagioclase, (Olivine, iron oxide, titanium oxide, quartz, amphibole, micas) Ultrabasic (SiO2<45 wt. %) Peridotite, kimberlite Olivine, pyroxene (plagioclase garnet, amphibole, spinel, micas) ADDITIONAL SLIDE Minerals in sedimentary rocks Clastic sedimentary rocks Conglomerates and breccias (>2mm) Sandstones (0.06-2mm) Mudrocks (<0.06mm) Chemical sedimentary rocks Siliceous rocks (silex) Evaporite Limestone, dolostone Organic sedimentary rocks Carbonate rocks (guano, coal) quartz, gold, diamond, apatite, calcite, and clays calcite, gypsum, anhydrite, halite and sylvite, borate minerals phosphates, graphite, calcite, fossils ADDITIONAL SLIDE Minerals in metamorphic rocks Basic rock (basalt, gabbro) Metabasite Amphiboles +epidote for LMG +plagioclase for HMG Clay-rich sedimentary rock (shale, mudstone) Metapelite Muscovite + Quartz +chlorite, biotite garnet for LMG +sillimanite, opx, cordierite for HMG Limestone Marble Calcite or dolomite +micas, quartz, clay, pyrite CLASSIFICATION AND NAMING >4000 mineral species Classification: based on the dominant anion Sulfates: with SO42- Gypsum (CaSO4 2H2O). Oxide: Cation + oxygen hematite (Fe2O3) Ex.: magnetite (Fe3O4) Phosphates: with PO43-, (or AsO43-,VO43-) Apatite Ca5(PO4)3(OH) Hydroxides: with OH- Brucite Mg(OH)2 Ex.: gibbsite Al(OH)3 Borates: with BO32- (or BO45-) Borax Na2BIII2BIV2O5(OH)4 8H2O Carbonates & nitrates : with CO32- (or NO3-) Calcite CaCO3 Ex.: Nitratite NaNO3 Native: no anion Gold (Au) Sulfide: with S2-, (or As, Te) pyrite(FeS2) Ex.: Pt, Ag, Cu, Ex.: galena (PbS2), C(graphite or diamond) sphalerite (ZnS) Silicates: with SiO44- Halides: contained halogens (F, Cl, Br, I) “table-salt”(NaCl) Ex.: Fluorite (CaF2) SILICATES Orthosilicates Olivine (Fe,Mg)2SiO4 Ex.: pyrope Mg3Al2Si3O12 Chain silicates Amphibole Sorosilicates Epidote Ca2Al2FeO(OH)SiO4 Si2O7 Sheet silicates Muscovite Cyclosilicates Tourmaline Framework silicates (or tectosilicates) Quartz SiO2 Ex.: Feldspar NaAlSi3O8 DIAGNOSTIC PROPERTIES - Habit - Morphology - Transparency - Luster - Color - Streak - Tenacity - Cleavage and fractures - Density - Hardness - Others PHYSICAL PROPERTIES Habit Euhedral Subhedral Anhedral Tabular/platy Prismatic, acidular, fibrous Morphologies: Granular Transparency Transparent (quartz) Translucent (garnet) opaque (lapis-lazuli) Luster Metallic (pyrite) Submetallic (rutile) Adamantine (diamond) Resinous (amber) Vitreous (amethyst quartz) Earthy (desert flower) ADDITIONAL SLIDE Luster examples Color Smithsonian collection (D.C.) Tenacity Streak Credits: http:// depthome.brooklyn.cuny.edu/ geology/core332/minerals.htm the ability of a mineral to deform plastically under stress: Brittle > Sectile > Ductile Definition: Cleavage Fracture Definition: Cleavage = plane of weakness. Conchoidal fractures (obsidian) Density (or specific gravity) Most silicates have a density between 2.6 and 3.5 g/cm3 Hardness Mohs scale Moh’s scale 1 Talc 2 Gypsum 3 Calcite 4 Fluorite 5 Apatite 6 Orthoclase 7 Quartz 8 Topaz 9 Corundum 10 Diamond Fingernail: 2.5 Copper penny: 3 Window glass: 5.5 Steel nail: 6.5 Other properties Taste Magnetism: (MnO2) Acid-test: magnetite (Fe3O4)> ilmenite (FeTiO3) > pyrolusite Calcite Fluorescence (Fluorite (CaF2), calcite (CaCO3), nepheline) Radioactivity (uraninite (UO2), thorite (ThSiO4), carnotite) Pleochroism Electrical conductivity