Molecular Models EXPERIMENT#3 Name of Members: Ryv Gabor, Ian Mauro, Orlino Salvacion Date Performed: September 26, 2018 I. Date Submitted: October 2,2018 Objective 1. See the different shapes that molecules have. 2. Understand that polar bonds could be nonpolar. 3. See how different molecules’ bond angles vary. 4. Understand why the bond angles of different molecules vary. II. Material 1. small balls made of modeling clay 2. one box of multicolored toothpick 3. ruler 4. scissors 5. protractor 6. tape 7. sheet of notebook paper 8. sheet of construction paper III. IV. Data & Results Toothpicks Red and Blue Red and Green Red and Yellow Blue and Green Blue and Yellow Green and Yellow Distance Bold Angle 11 cm 109° 11 cm 109° 11 cm 109° 11 cm 109° 11 cm 109° 11 cm 109° Answers to Questions 1. For methane, compare the bond angles in your model to those in the actual molecule. The actual methane molecule has a tetrahedral shape, which has 4 electron bonds, which has a central atom is located at the center with four substituents that are located at the corners of a tetrahedron. The bond angle is equal 109.4712206...° ≈ 109.5° when all four substituents are the same, nearly the same as the molecular model we made. 2. Compare your models of methane, ammonia and water. Should the bond angles in these models be equal? Why or why not? In water (H2O), ammonia (NH3) and methane (CH4), we have four electron pairs on the central atom. Four electron pairs should get as far apart as possible giving a pyramidal shape, with a bold angle of 109.5°. This should correspond with sp3 hybridization. However, in ammonia there is one lone pair and in water two lone pairs. This creates variations in the geometry of the molecule. This gives water a bent shape with the bond angle of 105°, and ammonia a pyramidal shape, with the bond angle of 107°. 3. In part B, which are the polar molecules and which are nonpolar molecules? Can a molecule with polar bonds be nonpolar? Explain. Ammonia (NH3), Water (H2O) are polar, while Carbon Dioxide (CO2), Oxygen (O2) and Boron Trichloride (BCl3) are. A molecule can possess polar bonds and still be nonpolar. If the polar bonds are evenly (or symmetrically) distributed, the bond dipoles cancel and do not create a molecular dipole. For example, the three bonds in a molecule of BF3 are significantly polar, but they are symmetrically arranged around the central boron atom. No side of the molecule has more negative or positive charge than another side, and so the molecule is nonpolar. V. Conclusion Although Valence Shell Electron Pair Repulsion (VSEPR) allows us to predict the shape of a molecule, it should still be verified by conducting experiments. This can be proven in the 3rd question because a molecule with polar bonds can still be a non-polar molecule.