L. Knight 2010 Name ____________________________ date ___________ Hot Pack/Cold Pack Lab Background Heat of Solution is the energy involved when a salt is dissolved into water. The heat of solution is different for each different salt that is dissolved. In this lab you will determine the heat of solution for four unknown salts (labeled A, B, C, D). From this data you will determine which substance is the best cold pack chemical and which is the best hot pack chemical. The substance with the largest increase in temperature per gram of salt will make the best hot pack. The substance with the largest decrease in temperature per gram of salt will make the best cold pack. Procedure HINT: Precision in measuring is IMPORTANT!! Make sure you record your data to the correct number of digits! 1) Add 50.0 mL of deionized water to the calorimeter. 2) Put a weighing boat on the balance, then zero the balance and put approximately 3.0g of a salt into the boat. 3) Transfer the salt to a clean and dry mortar and pestle and crush to a powder. 4) Put your original weighing boat back on the balance, zero the balance, then transfer the salt back to the boat to record the mass. 5) Record the initial temperature of the water in the calorimeter. 6) Pour the salt from the weighing boat into the calorimeter water. 7) Use the thermometer to stir the solution. You want to dissolve the salt as quickly as possible. You may have to use a stirring rod to break up clumps. YOU MAY USE THE THERMOMETER TO STIR, BUT NOT TO BREAK UP CLUMPS!! 8) While you are stirring, keep the cup on the bench and be sure to hold the cup from the top (so your hands do not influence the temperature of the solution). 9) Record the highest (or lowest) temperature that is reached after the salt is completely dissolved. (NOTE: You may have to keep stirring and watching the thermometer for a few minutes after the salt is dissolved.) 10)Rinse out the calorimeter. Waste may go down the drain for this lab. 11)Repeat the procedure for the other 3 salts. You may test the salts in any order. L. Knight 2010 Data Salt A Salt B Salt C Salt D mass of salt (after crushing) (g) temp. of water before (ºC) temp. of water after (ºC) Calculations 1) For each salt, determine the effectiveness of each salt in terms of change in ºC per gram of salt. (initial temp. - final temp.) Be sure to show all work, circle your final answer and include units in your final answer! Salt A change in temp. change in temp./gram of salt Salt B: change in temp. change in temp./gram of salt L. Knight 2010 Salt C: change in temp. change in temp./gram of salt Salt D: change in temp. change in temp./gram of salt Questions 1) Which salt would make the most effective hot pack? _________ Why? 2) Which salt would make the most effective cold pack? Why? _________ L. Knight 2010 3) For the most effective hot pack, was the change in energy positive or negative? __________________________________________ Therefore, which had more energy? (circle one) reactants products How do you know? This reaction was (circle one) exothermic endothermic 4) For the most effective cold pack, was the change in energy positive or negative? __________________________________________ Therefore, which had more energy? (circle one) reactants products How do you know? This reaction was (circle one) exothermic endothermic 5) In your own words what are two differences between exothermic and endothermic reactions? a) ___________________________________________________________ __________________________________________________________________ __________________________________________________________________ b) ___________________________________________________________ __________________________________________________________________ __________________________________________________________________