Engineering Structures 28 (2006) 229–239 www.elsevier.com/locate/engstruct Stress–strain curves for stainless steel at elevated temperatures Ju Chen, Ben Young∗ Department of Civil Engineering, The University of Hong Kong, Pokfulam Road, Hong Kong Received 17 February 2005; received in revised form 15 July 2005; accepted 27 July 2005 Available online 19 September 2005 Abstract This paper presents the mechanical properties data of stainless steel at elevated temperatures. Accurate prediction of the material properties of stainless steel at elevated temperatures is necessary for determining the load-carrying capacity of structures under fire conditions. However, full utilization of the special feature of stainless steel has not been possible due to lack of technique data on the fire resistance of stainless steel structural material. Therefore, both steady and transient tensile coupon tests were conducted at different temperatures ranging from approximately 20 to 1000 ◦ C to obtained the material properties of stainless steel types EN 1.4462 (Duplex) and EN 1.4301 (AISI 304) with plate thickness of 2.0 mm. The elastic modulus, yield strength obtained at different strain levels, ultimate strength, ultimate strain and thermal elongation versus different temperatures are also plotted and compared with the prediction from the Australian, British and European standards. The test results obtained from this study are also compared with the test results predicted by other researchers. A unified equation for yield strength, elastic modulus, ultimate strength and ultimate strain of stainless steel at elevated temperatures is proposed in this paper. It is shown that the proposed equation accurately predicted the yield strength, elastic modulus, ultimate strength and ultimate strain compared with the test results. Furthermore, stress–strain curves at different temperatures are plotted and a stress–strain model is also proposed. © 2005 Elsevier Ltd. All rights reserved. Keywords: Elevated temperatures; Experimental investigation; Fire resistance design; Mechanical properties; Stainless steel; Steady state tests; Transient state tests 1. Introduction Stainless steel has high corrosion resistance and aesthetic appearance as well as ease of maintenance and ease of construction. Therefore, stainless steel members have been increasingly used in the construction industry, especially in architectural and structural applications. Specifications for the design of stainless steel structural members are available, such as the American Society of Civil Engineers Specification [1], Australian/New Zealand Standard [2] and European Code 3 Part 1.4 [3]. However, these design specifications are mainly for structures at normal room temperature. Design specifications for steel structures at elevated temperatures are available, such as the Australian Standard AS 4100 [4], British Standard BS 5950 Part 8 [5] and European Code 3 Part 1.2 [6]. The reduction ∗ Corresponding author. Tel.: +852 2859 2674; fax: +852 2559 5337. E-mail address: young@hku.hk (B. Young). 0141-0296/$ - see front matter © 2005 Elsevier Ltd. All rights reserved. doi:10.1016/j.engstruct.2005.07.005 factors for mechanical properties at elevated temperatures are recommended in these design specifications, but they are mainly based on investigation of hot-rolled carbon steel. The material properties of stainless steel are significantly different from those of carbon steel, and the standard for carbon steel cannot be used for stainless steel without modification. For carbon and low-alloy steels, the proportional limit is assumed to be at least 70% of the yield point, but for stainless steel the proportional limit ranges from approximately 36% to 60% of the yield strength [7]. Therefore, the material properties of stainless steel at elevated temperatures should be known for the fire resistant design of stainless steel structures. The material properties of stainless steel, such as the yield strength, elastic modulus, ultimate strength and ultimate strain, can be obtained from the stress–strain curve. These material properties are one of the important factors in the design and numerical modelling of structures. Furthermore, the development of an accurate non-linear numerical 230 J. Chen, B. Young / Engineering Structures 28 (2006) 229–239 Nomenclature The following symbols are used in this paper: a, b, c coefficients for proposed equation; E elastic modulus; E normal elastic modulus at normal room temperature; ET elastic modulus at temperature T ◦ C; elastic modulus at yield strength at temperaE y,T ture T ◦ C; f 0.2 0.2% yield strength; f 0.2,normal 0.2% yield strength at normal room temperature; f 0.2,T 0.2% yield strength at temperature T ◦ C; 0.5% yield strength; f 0.5 f 0.5,normal yield strength corresponding to 0.5% strain level at normal room temperature; yield strength corresponding to 0.5% strain f 0.5,T level at temperature T ◦ C; 1.5% yield strength; f 1.5 f 1.5,normal yield strength corresponding to 1.5% strain level at normal room temperature; yield strength corresponding to 1.5% strain f 1.5,T level at temperature T ◦ C; 2.0% yield strength; f 2.0 f 2.0,normal yield strength corresponding to 2.0% strain level at normal room temperature; yield strength corresponding to 2.0% strain f 2.0,T level at temperature T ◦ C; fT stress at temperature T ◦ C; ultimate strength at temperature T ◦ C f t,u,T obtained from transient state test; f u,normal ultimate strength at normal room temperature obtained from steady state test; f u,T ultimate strength at temperature T ◦ C obtained from steady state test; yield strength at temperature T ◦ C; f y,T n coefficients for proposed equation; coefficient for proposed stress–strain equanT tion; coefficient for proposed stress–strain equamT tion; T value of temperature; ε elongation (tensile strain) at the point of fracture based on gauge length of 25 mm; strain at temperature T ◦ C; εT εu,normal strain corresponding to ultimate strength at normal room temperature; strain corresponding to ultimate strength at εu,T temperature T ◦ C; ε y,T strain corresponding to yield strength at temperature T ◦ C. model requires the stress–strain curve of the material. An investigation on the effect of stress–strain relationships on the fire performance of steel beams indicated that beam behaviour is very sensitive to the stress condition relative to the temperature-reduced proportional limit and yield stress [8]. Hence, the stress–strain relationship of a material is an important piece of data in the non-linear numerical model of structures for both the normal room and elevated temperatures. It is important to investigate the stress–strain relationship of stainless steel at elevated temperatures for the fire resistant design of stainless steel structures. The purpose of this study is to investigate the material properties of stainless steel at different temperatures using both steady and transient tests. In steady state tests, the test specimen is heated up to a specified temperature then a tensile test is carried out, whereas in transient state tests the load remains constant and the temperature is raised until the test specimen fails. Temperature would rise in a real fire; therefore, the transient state test is more realistic in predicting the behaviour of a material under fire than the steady state test. Tensile coupon tests were conducted for stainless steel types EN1.4462 (Duplex) and EN 1.4301 (AISI 304) for temperatures ranging from approximately 20 to 1000 ◦ C. The material properties were obtained from the test results of steady and transient state tests. A unified equation for yield strength, elastic modulus, ultimate strength and ultimate strain for stainless steel at elevated temperatures is proposed in this paper. Furthermore, a stress–strain curve model that accurately describes the stainless steel material at elevated temperatures is also proposed in this paper. 2. Experimental investigation 2.1. Testing device An MTS 810 Universal testing machine of 100 kN capacity was used for tensile coupon tests. The testing machine was calibrated before testing. The installation of the coupon specimen and the testing device used in this study are shown in Fig. 1. The heating device of an MTS Model 653 high temperature furnace with a maximum temperature of 1400 ◦ C was used. The furnace composed of upper and lower heating elements, as shown in Fig. 2. Heat was generated by the heating elements for each heating zone. An MTS model 409.83 temperature controller was used. Two internal thermal couples are located inside the furnace to measure the air temperature. Since there is a distance from the internal thermal couples to the specimen, the temperature detected by the internal thermal couples is higher than the surface temperature of the specimen. Therefore, an external thermal couple was used to measure the surface temperature of the specimen, and the measured temperature was considered as the real temperature of the specimen in this paper. The differences between the temperatures detected by the internal and external thermal couples were in the range from 3% to 28%. The temperature accuracy of the internal and the external thermal couples was 1.0 ◦ C J. Chen, B. Young / Engineering Structures 28 (2006) 229–239 231 (a) Stainless steel section. Fig. 1. Testing device. (b) Coupon test specimen dimension. Fig. 3. Test specimen. A total of 45 tests (29 steady state tests and 16 transient state tests) was conducted in this study. The actual dimensions of the cross sectional areas of the coupon specimens within the gauge length were measured using a micrometer. The measured dimensions were used to determine the cross sectional area of each coupon. 2.3. Testing procedure Fig. 2. High temperature furnace (MTS Model 653). and ±0.1 ◦ C. The heating rate of the furnace is 100 ◦ C/min. The fast heating rate resulted in the temperatures overshooting slightly, but the overshoot stabilizes within a minute. The maximum overshoot was approximately 40 ◦ C at low temperatures and it decreases at higher temperatures. When the temperature was beyond 700 ◦ C, the overshoot was less than 20 ◦ C. An MTS Model 632.53F-11 of axial extensometer was used to measure the strain of the middle part of the coupon specimen. The gauge length of the extensometer was 25 mm with the range limitation of ±2.5 mm. The extensometer was also calibrated before testing. The extensometer was reset when it approached the range limit during testing; hence a complete strain of coupon specimen could be obtained. 2.2. Test specimen The coupon test specimens were taken from stainless steel sections cold-rolled from structural steel sheets, as shown in Fig. 3(a). The tensile coupon specimens were taken from the centre of the face at 90◦ angle from the weld in the longitudinal direction of the stainless steel sections. The test specimens were prepared in accordance with the ASTM Standard E21-92 [9] and Australian Standard AS 2291 [10], as shown in Fig. 3(b). Stainless steel of types EN 1.4462 and EN 1.4301 with plate thickness of 2.0 mm was used. 2.3.1. Steady state test In the steady state tests, the specimen was heated up to a specified temperature then loaded until it failed while maintaining the same temperature. In this study, thermal expansion of specimen was allowed by maintaining zero tension load during the heating process. After reaching the pre-selected temperature, it needed approximately 2 min for the temperature to be stabilized, and after another 7 min the tensile load was applied to the specimen. This would allow the heat to transfer into the specimen. The external thermal couple indicated that the variation of the specimen temperature within the gauge length was less than 6 ◦ C (±3 ◦ C) during the tests. In the steady state tests, the strain control was used in the tensile testing machine. A constant tensile loading rate of 0.2 mm/min was used and the strain rate obtained from the extensometer was approximately 0.006/min, which is within the range 0.005 ± 0.002/min as specified by the ASTM Standard E21-92 [9]. 2.3.2. Transient state test In the transient state tests, the specimen was under a constant tensile stress level while the temperature was raised. The stress levels selected in the tests were 2, 50, 100, 150, 200, 250, 300, 350, 400, 450, 500, 550, 600, 650, 700 and 750 MPa. In the transient state tests, the load control was used in the tensile testing machine. The temperatures specified in the temperature controller ranged from 100 to 232 J. Chen, B. Young / Engineering Structures 28 (2006) 229–239 Fig. 4. Definition of symbols. Fig. 5. Stress–strain curves of stainless steel type EN 1.4462 at different temperatures obtained from transient state test results. 900 ◦ C at intervals of 100 ◦ C. The strain of the specimen at a given temperature was recorded using the extensometer 6 min after the temperature reached the specified value. The ultimate strength of the specimen was defined as the point at which strain kept increasing at a given value of temperature. In the tests, there are two reasons for the temperature to rise step by step. Firstly, there is a rapid loss of strength for the loaded specimen and the loading machine could not follow the sudden load drop under load control. Secondly, the strain data for different specified temperatures should be obtained, because the results of the transient state tests need to be converted to stress–strain curves. 3. Test results Fig. 6. Comparison of thermal elongation predicted by BS 5950-8 and EC31.2 with test results of stainless steel type EN 1.4462. 3.1. Determination of strength and elastic modulus The yield strengths at strain levels of 0.2%, 0.5%, 1.5% and 2.0% were obtained for the purpose of comparison since these strain levels are widely accepted. The 0.2% yield strength ( f 0.2 ) is the intersection point of the stress–strain curve and the proportional line off-set by 0.2% strain. Meanwhile, the yield strengths of f 0.5 , f 1.5 and f 2.0 at the strain levels of 0.5%, 1.5% and 2.0%, respectively, are those values corresponding to the intersection points of the stress–strain curve and the non-proportional vertical line specified at a given strain level, as shown in Fig. 4. Serration of the stress–strain curve was observed at high temperatures and the intersection point was the mean value determined from the serration. The elastic modulus was determined from the stress–strain curve based on the tangent modulus of the initial elastic linear curve. For transient state tests, the results are firstly converted into stress–strain curves, as shown in Fig. 5. The specimen was loaded to a given stress level, and the elastic modulus at different temperatures of each specimen can be determined from the stress–strain curves obtained from the transient state tests. The data of the specimen at each temperature are normalized with respect to the initial elastic modulus at normal room temperature of each specimen, so that the influence of elastic modulus variation can be eliminated. Some repeat tests were conducted and the deviations between these tests results were quite small, with a maximum difference of 3%. 3.2. Thermal elongation in transient state test Thermal elongation of the specimens was determined at a tensile stress level of 2 MPa, which is close to free thermal expansion, and compared with the thermal elongation calculated according to British Standard 5950-8 [5] and European Code 3 Part 1.2 [6] in Fig. 6. The thermal elongation of the strain in percentage (%) is plotted in the vertical axis of the graph and the horizontal axis is plotted against different temperatures. The comparison indicates that the test values of thermal elongation of stainless steel type EN 1.4462 are less than the values predicted by the BS 5950-8 [5] and EC3-1.2 [6] at temperatures lower than or equal to 660 ◦ C, and the test values are higher than the predicted values for temperatures higher than 660 ◦ C. Although the 2 MPa tensile stress was almost negligible at normal room temperature for determining the thermal elongation, it slightly affected the elongation when the temperature increases. Since the thermal elongation was J. Chen, B. Young / Engineering Structures 28 (2006) 229–239 233 Table 1 Material properties of stainless steel types EN 1.4462 and EN 1.4301 at normal room temperature Stainless steel f 0.2,normal (MPa) f 0.5,normal (MPa) f 1.5,normal (MPa) f 2.0,normal (MPa) f u,normal (MPa) εu,normal (%) E normal (GPa) EN 1.4462 (Duplex) EN 1.4301 (AISI 304) 731 398 729 409 817 443 824 452 870 709 15.8 60.6 227 187 Table 2 Reduction factors of yield strength and elastic modulus of stainless steel types EN 1.4462 and EN 1.4301 EN 1.4462 (Duplex) Temperature (◦ C) f 0.2,T / f 0.2,normal f 0.5,T / f 0.5,normal f 1.5,T / f 1.5,normal f 2.0,T / f 2.0,normal E T /E normal 22 1.000 1.000 1.000 1.000 1.000 80 0.943, 0.923a 0.936, 0.920a 0.949, 0.919a 0.947, 0.922a 0.947, 0.949a 180 0.834 0.834 0.834 0.836 0.863 320 0.758 0.742 0.802 0.814 0.714 450 0.728 0.717 0.752 0.765 0.696 550 0.683 0.678 0.718 0.729 0.690 660 0.528 0.539 0.542 0.541 0.643 760 0.354 0.351 0.324 0.325 0.409 870 0.170 0.177 0.163 0.161 0.300 960 0.031, 0.038a 0.033, 0.041a 0.031, 0.037a 0.032, 0.036a 0.060, 0.063a EN 1.4301 (AISI 304) Temperature (◦ C) f 0.2,T / f 0.2,normal f 0.5,T / f 0.5,normal f 1.5,T / f 1.5,normal f 2.0,T / f 2.0,normal E T /E normal 22 1.000 1.000 1.000 1.000 1.000 80 0.839 0.848 0.860 0.863 1.045 180 0.764 0.773 0.786 0.788 0.939 320 0.698 0.704 0.720 0.730 1.036 450 0.678 0.687 0.693 0.704 0.951 550 0.595 0.599 0.619 0.635 0.900 660 0.523 0.543 0.562 0.577 0.862 760 0.357 0.359 0.357 0.347 0.574 870 0.181 0.176 0.163 0.159 0.452 960 0.116, 0.101a 0.115, 0.098a 0.106, 0.088a 0.104, 0.089a 0.340, 0.351a a Second test. determined for specimens loaded at a stress level of 2 MPa, the elastic modulus obtained from the transient state tests were slightly underestimated. 3.3. Yield strength The material properties obtained from the tests for stainless steel types EN 1.4462 and EN 1.4301 at normal room temperature are presented in Table 1. The reduction factors ( f 0.2,T / f 0.2,normal , f 0.5,T / f 0.5,normal, f 1.5,T / f 1.5,normal , f 2.0,T / f 2.0,normal) determined from the ratio of different yield strengths to normal room temperature (22 ◦ C) at different temperatures for the four strain levels of 0.2%, 0.5%, 1.5% and 2.0%, respectively, are presented in Table 2. The test results of 0.2% yield strength of stainless steel types EN 1.4462 and EN 1.4301 are plotted in Fig. 7. The vertical axis of the graph plotted the reduction factor f 0.2,T / f 0.2,normal and the horizontal axis plotted against different temperatures. It is shown that the test results of stainless steel types EN 1.4462 and EN 1.4301 obtained from the steady state and transient state tests are similar. The reduction factor of 0.2% yield strengths obtained from the tests were compared with the Australian Standard AS 4100 [4] prediction and also compared with the test results conducted by Ala-Outinen [11], Sakumoto et al. [12] and Ala-Outinen et al. [13], as shown in Fig. 7. The comparison shows that AS 4100 provides a conservative prediction for the test results of stainless steel types EN 1.4462, EN 1.4301 and EN 1.4571 from 400 to 900 ◦ C, but an unconservative prediction for temperatures less than 400 ◦ C. The AS 4100 conservatively predicted the stainless steel type SUS 304 for temperatures in the range from 600 to Fig. 7. Comparison of reduction factor of 0.2% yield strength predicted by AS 4100 and proposed equation with test results. 900 ◦ C, but unconservatively predicted for temperature less than 600 ◦ C. It can be seen that the test results obtained from this study are generally close to the test results conducted by Ala-Outinen [11], Sakumoto et al. [12] and Ala-Outinen et al. [13]. Since the reduction factors of 0.2% yield strength predicted by AS 4100 are unconservative for temperatures in the range from 80 to 500 ◦ C, a new equation is needed for the prediction of reduction factor of 0.2% yield strength. The unified equation for the prediction of yield strength proposed by Chen and Young [14] for cold-formed carbon steel at elevated temperatures is used in this study for stainless steel. The coefficients a, b, c and n of the equation are calibrated with all the stainless steel test results, and the coefficients are presented in Table 3, where T is the temperature in degrees Celsius (◦ C). 234 J. Chen, B. Young / Engineering Structures 28 (2006) 229–239 Table 3 Coefficients of the proposed equation for yield strength and elastic modulus of stainless steel types EN 1.4462 and EN 1.4301 Yield strength Eq. (1) Temperature (◦ C) a b c n Elastic modulus Eq. (2) Temperature (◦ C) a b c n 22 ≤ T < 300 1.0 22 45 0.5 300 ≤ T < 850 0.63 300 5.7 × 105 2 850 ≤ T < 1000 0.1 850 600 0.8 22 ≤ T < 922 1.0 22 900 1 Fig. 8. Comparison of reduction factor of 0.5% strength predicted by BS5950-8 with test results. Fig. 9. Comparison of reduction factor of 1.5% strength predicted by BS5950-8 with test results. Proposed equation for yield strength: f 0.2,T f 0.2,normal =a− (T − b)n c (1) It is demonstrated that the values of reduction factor f 0.2,T / f 0.2,normal predicted by the proposed Eq. (1) compared well with all of the stainless steel test results, as shown in Fig. 7. The reduction factors of yield strength for the strain levels of 0.5%, 1.5% and 2.0% are compared with the EC3-1.2 [6] and BS 5950-8 [5] prediction for hotfinished steel and cold-formed steel, as shown in Figs. 8–10. The reduction factors of 0.5%, 1.5% and 2.0% yield strength predicted by the BS 5950-8 for hot-finished steel are conservative for both stainless steel types EN 1.4462 and EN 1.4301 for temperatures in the range from 550 to 960 ◦ C, but unconservatively predicted for temperatures less than 550 ◦ C. The reduction factors of 0.5%, 1.5% and 2.0% yield strength predicted by the BS 5950-8 for cold-formed steel are conservative for both stainless steel types EN 1.4462 and EN 1.4301 for temperatures in the range from 450 to 960 ◦ C, but unconservatively predicted for temperatures less than 450 ◦ C. The reduction factor of 2.0% yield strength predicted by EC3-1.2 is conservative for temperatures in the range from 550 to 960 ◦ C, but unconservatively predicted for temperatures less than 550 ◦ C. Fig. 10. Comparison of reduction factor of 2.0% strength predicted by BS5950-8 and EC3-1.2 with test results. 3.4. Elastic modulus The reduction factor of the elastic modulus of stainless steel types EN 1.4462 and EN 1.4301 was compared with the AS 4100 [4], EC3-1.2 [6] and EN 10088-1 [15] predictions, as shown in Fig. 11. It can be seen that the reduction factor of the elastic modulus of stainless steel type EN 1.4462 obtained from the steady state tests generally agree well with the results obtained from the transient state tests, except J. Chen, B. Young / Engineering Structures 28 (2006) 229–239 Fig. 11. Comparison of elastic modulus predicted by AS 4100, EC3-1.2 and EN 10088-1 with test results. for temperatures 300 and 660 ◦ C. The reduction factor of the elastic modulus of stainless steel type EN 1.4301 is higher than those of type EN 1.4462. It is shown that the reduction factors predicted by EC3-1.2 are generally conservative, except for stainless steel type EN 1.4462 for temperatures in the range from 80 to 320 ◦ C. The AS 4100 [4] predictions of the elastic modulus are generally conservative, except for stainless steel type EN 1.4462 for temperatures in the range from 80 to 450 ◦ C. The EN 100881 [15] predictions are conservative for stainless steel type EN 1.4301, but unconservative for stainless steel type EN 1.4462 for temperatures in the range from 80 to 450 ◦ C, as shown in Fig. 11. The reduction factors of the elastic modulus obtained from the tests are also compared with the test results conducted by Ala-Outinen [11], Sakumoto et al. [12] and Ala-Outinen et al. [13], as shown in Fig. 12. It can be seen that the results are significantly different from each other. Chen and Young [14] also proposed a unified equation for the prediction of the elastic modulus for cold-formed carbon steel at elevated temperatures that is used in this study for stainless steel, as shown in Eq. (2). The coefficients a, b, c and n of the equation are calibrated with all of the stainless steel test results, and the coefficients are presented in Table 3. Eq. (2) for elastic modulus prediction is identical to Eq. (1) for yield strength prediction, except for the different values of the coefficients. Proposed equation for elastic modulus: ET E normal =a− (T − b)n c (2) It is shown that the prediction of the reduction factor of the elastic modulus using Eq. (2) is generally conservative compared with the test results obtained from this study for stainless steel types EN 1.4462 and EN 1.4301, and the test results obtained by other researchers, as shown in Fig. 12. 235 Fig. 12. Comparison of elastic modulus obtained using the proposed equation with test results. Fig. 13. Comparison of ultimate strength obtained using the proposed equation with test results. 3.5. Ultimate strength The reduction factor of the ultimate strength to normal room temperature ( fu,T / f u,normal ) obtained from the steady state tests at different temperatures are plotted in Fig. 13. The vertical axis of the graph plotted the reduction factor f u,T / f u,normal and the horizontal axis plotted against different temperatures. The values of the reduction factor of the ultimate strength of stainless steel type EN 1.4462 are generally higher than those of stainless steel type EN 1.4301 for all temperatures. A unified equation for the prediction of ultimate strength is proposed, as shown in Eq. (3). The coefficients a, b, c and n of the equation are calibrated with the stainless steel test results, and the coefficients are presented in Table 4. Eq. (3) for ultimate strength prediction is identical to Eqs. (1) and (2) for yield strength and elastic modulus prediction, respectively, except for the different values of the coefficients. It is shown that the predictions of the reduction factor of the ultimate strength using Eq. (3) agree well with the test results obtained from this study for stainless steel types EN 1.4462 and EN 1.4301, as shown in Fig. 13. Proposed equation for ultimate strength: (T − b)n fu,T (3) =a− f u,normal c 236 J. Chen, B. Young / Engineering Structures 28 (2006) 229–239 Table 4 Coefficients of the proposed equation for ultimate strength EN 1.4462 (Duplex) Temperature (◦ C) a b c n 22 ≤ T < 450 0.85 450 9.6 × 1013 5 450 ≤ T < 660 0.85 450 1.3 × 105 2 660 ≤ T ≤ 960 0.51 660 200 0.8 EN 1.4301 (AISI 304) Temperature (◦ C) a b c n 22 ≤ T < 450 0.7 450 4.8 × 1013 5 450 ≤ T < 660 0.7 450 1.92 × 105 2 660 ≤ T ≤ 960 0.06 960 −2.2 × 105 2 Ultimate strength Eq. (3) Table 5 Comparison of ultimate strength of stainless steel type EN 1.4462 obtained from transient state and steady state tests Temperature (◦ C) 22 80 140 220 320 450 550 660 760 870 960 f t,u,T (MPa) (Transient) >750 >750 700–750 700–750 700–750 650–700 600–650 400–450 50–100 2–50 2–50 f u,T (MPa) (Steady) 870 847 804a – – 765 754 692 453 277 136 26 30a a Second test. The ultimate strength of the specimen in transient state tests is defined at a specified load when the temperature reaches a certain value and the specimen undergoes a continuous elongation at an appreciable rate. This specified load was considered as the ultimate strength of the specimen at that particular temperature in the transient state tests. In Table 5, the ultimate strength obtained from the transient state tests ( f t,u,T ) is compared with the ultimate strength obtained from the steady state tests ( fu,T ). The results of ultimate strength obtained from the steady state tests are generally higher than the results obtained from the transient state tests, as shown in Table 5. 3.6. Ultimate strain The ultimate strain is defined as the strain corresponding to the ultimate strength. The reduction factors of the ultimate strain to normal room temperature (εu,T /εu,normal ) obtained from the steady state tests at different temperatures are plotted in Fig. 14. The vertical axis of the graph plotted the reduction factor εu,T /εu,normal and the horizontal axis plotted against different temperatures. The values of the reduction factor of ultimate strain of the stainless steel type EN 1.4462 are higher than those of the stainless steel type EN 1.4301 for all temperatures. The proposed unified Eq. (4) for ultimate strain is identical to the unified equation for yield strength, elastic modulus and ultimate strength, except for the different values of the coefficients. The coefficients a, b, c and n of the equation are calibrated with the stainless steel test results in this study, and the coefficients are presented in Table 6. It is shown that the predictions of the reduction factor of ultimate strain using Eq. (4) generally agree with the test results obtained from Fig. 14. Comparison of ultimate strain obtained using the proposed equation with test results. this study for stainless steel types EN 1.4462 and EN 1.4301, as shown in Fig. 14. Proposed equation for ultimate strain: εu,T εu,normal =a− (T − b)n c (4) 4. Stress–strain curve The stress–strain relationship of stainless steel material at elevated temperatures is necessary in the analysis and simulation of stainless steel structures under fire. However, most stress–strain curve models are based on hot-rolled steel, and very few stress–strain curve models based on stainless steel have been reported. Therefore, a stress–strain curve model for stainless steel at elevated temperatures is proposed in this paper. Chen and Young [16] proposed an accurate stress–strain curve model for cold-formed carbon J. Chen, B. Young / Engineering Structures 28 (2006) 229–239 237 Table 6 Coefficients of the proposed equation for ultimate strain EN 1.4462 (Duplex) Temperature (◦ C) a b c n 22 ≤ T < 180 1.0 22 480 1 180 ≤ T < 660 0.67 180 5.42 × 1021 8 660 ≤ T ≤ 960 0.15 660 5000 1 EN 1.4301 (AISI 304) Temperature (◦ C) a b c n 22 ≤ T < 180 1.0 22 247 1 180 ≤ T < 660 0.36 180 6.1 × 1016 6 660 ≤ T ≤ 960 0.16 660 2000 1 Ultimate strain Eq. (4) steel material at elevated temperatures. This model is used and calibrated with the steady state test results of stainless steel types EN 1.4462 and EN 1.4301. The model is based on the stress–strain curve model for stainless steel at normal room temperature proposed by Mirambell and Real [17] and Rasmussen [18], which is originally based on the Ramberg–Osgood [19] equation. The proposed stress–strain curve model is as follows: fT fT nT + 0.002 ET f y,T εT = f T − f y,T m T f T − f y,T + εu,T + ε y,T E y,T f u,T − f y,T for f T ≤ f y,T (5) for f T > f y,T (a) Initial part of stress–strain curves. and ET (6) 1 + 0.002 n T E T / f y,T √ n T = 6 + 0.2 T (7) T 5.6 − for stainless steel type EN 1.4462 200 (8) mT = T 2.3 − for stainless steel type EN 1.4301 1000 E y,T = where f T is the stress, f u,T is the ultimate strength, f y,T is the yield strength, E T is the elastic modulus at temperature T in degrees Celsius (◦ C), E y,T is the elastic modulus at yield strength at temperature T ◦ C, εT is the strain, εu,T is the strain corresponding to ultimate strength and ε y,T is the strain corresponding to yield strength at temperature T ◦ C. The comparisons of the stress–strain curves obtained using Eq. (5) with the test results for stainless steel types EN 1.4462 and EN 1.4301 at different temperatures are shown in Figs. 15 and 16, respectively. The proposed stress–strain curves plotted using Eq. (5) were based on the material properties obtained from the test results for the full strain range up to the ultimate tensile strain. Generally, the proposed stress–strain curve model accurately predicted the stainless steel type EN 1.4462 and conservatively predicted the stainless steel type EN 1.4301 for the temperature in the range from 22 to 960 ◦ C. In order to plot a stress–strain curve for stainless steel at a given temperature, the yield strength ( f y,T ), elastic modulus (E T ), ultimate strength ( f u,T ), and ultimate strain (εu,T ) are needed. The equations for f y,T (b) Complete stress–strain curves. (c) Complete stress–strain curves. Fig. 15. Comparison of stress–strain curves predicted using the proposed stress–strain model with test results for stainless steel type EN 1.4462. and E T , f u,T , and εu,T have been proposed in this study as shown in Eqs. (1), (2), (3) and (4), respectively. 238 J. Chen, B. Young / Engineering Structures 28 (2006) 229–239 (a) Initial part of stress–strain curves. modulus predicted by the Australian standard and European standards are generally unconservative for temperatures in the range from 80 to 450 ◦ C, but conservatively predicted for higher temperatures up to approximately 1000 ◦ C. Hence, the standards provide unconservative predictions for relatively low temperatures. A unified equation to determine the yield strength, elastic modulus, ultimate strength and ultimate strain of stainless steel types EN 1.4462, EN 1.4301 and EN 1.4571 for temperatures ranging from approximately 20 to 1000 ◦ C has been proposed in this paper. It is shown that the proposed equation conservatively predicted the yield strength, elastic modulus, ultimate strength and ultimate strain of stainless steel material at elevated temperatures. In addition, a stress–strain curve model for stainless steel at elevated temperatures has been proposed in this paper. The proposed model covers the full strain range up to the ultimate tensile strain for temperature in the range from 22 to 960 ◦ C. Generally, it is shown that the proposed stress–strain curve model accurately predicted the stainless steel test results. Acknowledgment (b) Complete stress–strain curves. The authors are grateful to STALA Tube Finland for supplying the test specimens. References (c) Complete stress–strain curves. Fig. 16. Comparison of stress–strain curves predicted using the proposed stress–strain model with test results for stainless steel type EN 1.4301. 5. Conclusions A test program on the material properties of stainless steel at elevated temperatures has been presented. The test program included two types of stainless steel, EN 1.4462 (Duplex) and EN 1.4301 (AISI 304), with plate thickness of 2.0 mm. Steady and transient state tests were conducted at different temperatures. The yield strengths, elastic modulus and thermal elongation obtained from the tests were compared with the Australian, British and European predictions. Generally, it is shown that the yield strengths predicted by the Australian, Britain and European standards are unconservative for temperatures in the range from 80 to 450 ◦ C, but conservatively predicted for higher temperatures up to approximately 1000 ◦ C. It is also shown that the elastic [1] ASCE. Specification for the design of cold-formed stainless steel structural members. SEI/ASCE-8-02. Reston (Virginia): American Society of Civil Engineers; 2002. [2] AS/NZS 4673:2001. 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