IJREAS Volume 1, Issue 4 (December 2011) ISSN: 2294-3905 PHYSICO-CHEMICAL ANALYSIS OF YAMUNA WATER AT MATHURA Suman Yadav* (Research Scholar) Dr. Ajay Kumar Rajawat ABSTRACT Physico-chemical Properties of water of Yamuna River at Mathura, (UP) were studied. The time period of study was July 2009 to June 2010. Three sampling stations were selected for study. The parameters studied were Temperature, Turbidity, pH, DO, BOD, COD, Total Dissolved Solids and Suspended Solids. Almost all the parameters were found above the tolerance limit. Keywords: Pollution, Pollutants, D.O., B.O.D., C.O.D., Turbidity, Effluents, TDS, TSS. *Dept. of Chemistry, CMJ University, Shillong, Meghalaya International Journal of Research in Engineering & Applied Sciences http://www.euroasiapub.org 51 IJREAS Volume 1, Issue 4 (December 2011) ISSN: 2294-3905 INTRODUCTION Pollution is one of the most challenging problems today. The unwanted substances are being regularly added to our environment, making it unsafe to live. Population growth, r apid e conomic de velopment, i ndustrialisation a nd un conscious hum an activities a re s lowly tr ansforming o ur planet into a r otten p lace. T he b alance of nature h as b een so a dversely a ffected t hat w e ar e f acing w ith, f requent f loods i n some areas and severe draught in the others. Mathura (U.P.) is considered to be a historical and holy place, being the birth-place of L ord Krishna, m illions of pi lgrims f rom e very corner vi sit Mathura every year and use to take bath in the holy river Yamuna. Their stay in the city causes a severe sewage a nd garbage disposal pr oblem. T he sew age a long w ith t he g arbage i s disposed off either directly or indirectly into the river Yamuna through a number of wide drains and results in heavy water pollution. Furthermore, Mat hura i s a f ast d eveloping c ity. A n umber o f sm all a nd l arge industries a re w orking he re, w hich us e ve ry f ast, ha rmful a nd no n-biodegradable chemicals like sulphuric ac id, silica powder, h ydrochloric ac id, d etergents including a lkyl be nzene s ulphonate a nd l inear a lkyl s ulphonate and s everal dye s containing c yanides, a rsenic, c admium, m ercury a nd l ed compounds. T heir menacing e ffects ha ve b een m anifested i n the f orm o f t he d eath of t housands of aquatic organisms. MATERIALS AND METHODS The s ampling w as do ne i n second w eek of each m onth i n gl ass bot tles w ith capacity 300 ml. The physico-chemical parameters of the water were determined on the s pots, w ith the he lp of ‘ Portable w ater de tection ki t’ ( Model no. C K-710, manufactured by ‘ Century I nstruments P vt. L td., C handigarh). T he t emperature was measured on the spot by using temperature sensitive electrodes of the portable water d etection ki t. O ther phys ico-chemical p arameters f rom sam ples w ere determined in the l aboratory using t he method suggested by APHA ( 1985) a nd NEERI m anual ( 1986). T he results w ere c ompared w ith s tandard permitting parameters as suggested by WHO and ISI. For digestional and pre concentration of water sa mples, st andard methods were f ollowed ( Chakraborty et.al. 1987 and Subramaniam 1987). International Journal of Research in Engineering & Applied Sciences http://www.euroasiapub.org 52 IJREAS Volume 1, Issue 4 (December 2011) ISSN: 2294-3905 RESULTS AND DISCUSSION Temperature – Temperature is an important physical factor which control the natural processes of the e nvironment. I t was o bserved i n accordance w ith t he seasonal c hanges. I t ranged be tween 16. 5–35.9 oC. I t w as hi gher i n M ay, J une a nd J uly a nd l ower during winter months i.e. December and January. Turbidity – Turbidity i s ge nerally c aused by unt reated a nd unde composed organic m atter, sewage a nd industrial w aste. I t w as ve ry high i n J uly and August be cause of t he ‘Janmashtami’ and Shravan Maas’ when t here i s a mass g athering in the city and millions of peoples take bath in Yamuna river. It was noted minimum 64 NTU and maximum 131 NTU. pH – pH sh ows t he a cidic or al kaline n ature o f water. T he w ater o f r iver Y amuna w as found s lightly a lkaline. I t r anged be tween 7.1 – 8.6. I t s howed s imilar t rend w ith Mathur e t.al. ( 1987), Dakshini e t.al ( 1979), K umar and S harma (2005) a nd Singh et. al (1988). TABLE -1 PHYSICO-CHEMICAL PARAMETERS OF RIVER YAMUNA FROM JULY 2009 TO JUNE 2010 (Average value of three sites) Rains Parameters Winters Summers Units Jul Sep Oct Nov Dec Jan 30.8 30.4 23.4 22.7 22.4 19.1 16.5 21.1 23.9 NTU 121 125 99 111 83 104 64 87 … 7.1 7.2 7.6 8.4 8.5 7.9 8.6 D.O. Mg/lit. 2.2 2.4 4.7 6.6 3.9 9.8 B.O.D. Mg/lit. 35.1 34.2 7.8 8.9 17.6 C.O.D. Mg/lit. 44.1 22.5 15.3 19.4 T.D.S. Mg/lit. 501 421 412 T.S.S. Mg/lit. 419 387 412 Temperature Turbidity pH oC Aug Feb Mar Apr May Jun 28.0 33.4 35.9 81 79 89 131 7.7 7.6 8.5 8.4 7.5 8.7 4.6 11.8 6.5 2.8 1.8 5.8 5.4 19.8 12.0 22.1 44.8 47.0 32.1 17.9 12.3 33.5 17.2 59.4 44.4 60.5 506 622 455 413 512 648 605 606 698 401 446 521 346 421 458 401 502 512 International Journal of Research in Engineering & Applied Sciences http://www.euroasiapub.org 53 IJREAS Volume 1, Issue 4 (December 2011) ISSN: 2294-3905 Dissolved Oxygen :Dissolved oxyge n i s e ssential f or t he de composition of c hemical w aste a nd de ad organic matter. It show variable trend. It was maximum in winter but lower in summer. It ranged between 1.8 -11.8 mg/l. (Kumar & Sharma, 2004). BOD :BOD i s t he a mount of oxy gen required by l iving a quatic or ganisms f or t heir physiological process. It was found very high in summer and comparatively low in winter. I t r anged be tween 5. 4-47.0 mg /l. T he f indings w ere similar to th ose observed by Kumar & Sharma (2005). COD :It i s t he a mount of oxyge n r equired for t he de composition of c hemical w aste. A high value of C OD s hows a hi gher a ccumulation of organic waste in t he pond. It was found higher during summer (60.5 mg/l) and lower during winter (12.3 mg/l). Which w as i n a ccordance w ith t he o bservations m ade b y S hankar et . al ( 1986), Reddy et. al (1985) and Sangu et. al. (1983). TDS :Total dissolved s olids also serve a s indicator of pol lution. T rend w as found t o be highly f luctuating. I t ranged be tween 41 2 - 698 mg/l. ( Saxena et. a l. , 1993 a nd Siddiqui et. al, 1994). TSS :Total s uspended s olids w ere f ound ve ry f luctuating. T SS w ere hi gher i n s ummer and lower in winter and ranged between 346 - 521 mg/l. The findings were similar to t hose obs erved by Mathur et. a l ( 1987), Saxena et. a l ( 1991) and S hahji e t. a l (1993). Summary & Conclusion – From the above observations it was concluded that Yamuna river is highly polluted and t he us e of i ts p olluted w ater m ay c ause v arious d iseases. R emedial m easures are required to sustain the good quality of water and also to save the life of people. REFERENCES 1. APHA (1992), “AWWA. WFCW in Standard Method for the examination of water and waste water. American Public Health Association, New York. International Journal of Research in Engineering & Applied Sciences http://www.euroasiapub.org 54 IJREAS Volume 1, Issue 4 (December 2011) ISSN: 2294-3905 2. Bhaumik B.M. and Singh A.K. (1985), ‘Phytoplankton population in relation to physico-chemical factor of river Ganga at Patna’. Ind. J. Eco. 12(2) : 360364. 3. Dakshini K.M.M. and Soni J .K. ( 1979), ‘Water quality of sewage drains entering Yamuna at Dehli’. Ind. J. Env. Hlth., Vol. 21, No. 4, 354-360. 4. Kumar P raveen a nd S harma H .B. 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Yadav and L.Singh (1988), ‘Pollution status on Sangam and its a djoining river before t he K umbh M ela at Allahabad’. I.J.E.P., 8( 11): 839-842. 16. WHO (1984), ‘International Standard for water.’ Third ed. Geneva. International Journal of Research in Engineering & Applied Sciences http://www.euroasiapub.org 56