If a photons have momenta… do particles have wavelengths? Yes! de Broglie wavelength: h h or p p electrons can only exist in orbitals where the circumference was is equal to whole number multiples of wavelengths of the electrons. http://www.walter-fendt.de/ph11e/bohrh.htm Only small, high speed particles will show noticeable wave characteristics (diffraction, interference) the wavelengths of elementary particles are the size of nuclei or smaller This particle-wave duality of matter makes it impossible to develop a set of equations that tells us both exactly where an electron is and what its momentum might be. Davisson and Germer reflected a beam of electrons off a crystal and obtained a series of maxima and minima patterns (just like a beam of light would give a series of light and dark bands when it passed through a diffraction grating) Interference Movie Electron diffraction pattern sand electrons sand electrons sand Two overlapping piles of sand electrons Not just two overlapping “piles” of electrons sand Two overlapping piles of sand electrons Interference pattern Photons (particles!) water droplet trapped atoms G.P. Thomson detected electron diffraction patterns by passing a beam of electrons through a metal foil and obtaining an interference pattern Example 1 Find the de Broglie wavelength for an electron moving at 7.30 x 106 m/s. Example 2 An electron is accelerated from rest by a potential difference of 1.50 kV. Determine the de Broglie wavelength of the electron.