Special: aluminium smelting industry power upgrade of isal potlines 1-3 The ‘ap Technology’ smelter of the future History of intensive mixing for carbon paste ABB Novel gas cleaning for anode baking furnace Volume 89 · January / February 2013 International Journal for Industry, Research and Application Five hundred participants at arabal 2012 conference 1/2 Melting Furnaces State-of-the-art scrap and dross remelting Leading technology in the aluminum casthouse here are many benefiTSINONESTOPSHOPPINGOFINDUS T TRIALGOODS!T(ERTWICH%NGINEERINGWEPROVIDECUSTOMER ORIENTEDSERVICETHROUGHOUTTHEPROJECTDURATIONAND SERVICELIFEOFEQUIPMENT7EDESIGNANDBUILDPLANTSTO MEETBOTHOUROWNSTRINGENTSTANDARDSANDINDIVIDUAL CUSTOMERSSPECIfiCATIONS"ASEDONMANYYEARSOFEXPERI ENCEWECOVERTHEFULLRANGEOFEQUIPMENTINAMODERN ALUMINUMCASTHOUSE Major benefits (ERTWICH%NGINEERINGISWELLKNOWNFORLEADINGEDGE TECHNOLOGY/URVALUEDCUSTOMERSDESERVETOGETTHE BESTVALUEFORMONEY#OMMITMENTTOINNOVATIONSOLID ENGINEERINGANDOWN2$AREINSTRUMENTALFORSTAYING AHEADWITHCONTINUOUSIMPROVEMENTSANDNEWPRODUCTS Common features and advantages of Hertwich melting furnaces 2EMELTINGOFCLEANANDCONTAMINATEDSCRAPWITH PAINTPLASTICANDOIL Q Integrated scrap preheating and gasifiCATION OFORGANICCOMPOUNDS Q )NTERNALCOMBUSTIONANDENERGYRECLAMATION OFORGANICSnNOAFTERBURNERREQUIRED Q 6ERYLOWHEATINGFUELCONSUMPTION Q %XTREMELYLOWOXIDATIONLOSSESMETALLOSSES Q &ULLYAUTOMATEDCHARGINGSYSTEMS Q 4URN+EYSOLUTIONSWITHRELIABLEPROVENANDSOPHIS TICATEDPROCESSCONTROL Q HERTWICH ENGINEERING GMBH EINBERGERSTRASSE 7 "RAUNAU!USTRIA HONE 0 &AX MAIL INFO HERTWICHCOM % )NTERNETWWWHERTWICHCOM CONTENTS Volker Karow Chefredakteur Editor in Chief Aluminiumindustrie startet optimistisch ins neue Jahr Optimistic start for the aluminium industry in the new year ALUMINIUM · 1-2/2013 Aktuelle Zahlen zum globalen Wirtschaftswachstum 2012 lagen bei Redaktionsschluss zwar noch nicht vor, doch gehen die meisten Volkswirte von einem Zuwachs um die drei Prozent aus. Ob die Weltkonjunktur 2013 weiter an Fahrt gewinnen wird, darüber gehen die Einschätzungen auseinander. Weitgehende Einigkeit besteht darin, dass Europas Wirtschaft erneut schrumpfen wird, die USA moderat wachsen werden und die Konjunktur in den Schwellenländern wieder anzieht. Für den Aluminiummarkt zeigt sich AlcoaChef Klaus Kleinfeld optimistisch. Die globale Nachfrage nach Aluminium, so seine Einschätzung, werde im laufenden Jahr um sieben Prozent steigen. Das reicht zwar nicht an die Werte von 2010 (+13%) und 2011 (+10%) heran, wäre aber ein Prozentpunkt über dem geschätzten Zuwachs von 2012. Getragen werde diese Entwicklung vor allem von der Nachfrage aus der Luftfahrt- und Bauindustrie. Für den Luftfahrtmarkt rechnet Alcoa mit einem fast zweistelligen Wachstum. Andere Aluminiumkonzerne sind allerdings nicht ganz so optimistisch in ihren Prognosen für das laufende Jahr. Hydro-Chef Svein Richard Brandtzæg bezifferte den Zuwachs der globalen Aluminiumnachfrage auf einer Investorenveranstaltung Ende November bei zwei bis vier Prozent – ohne China. Bei den Aluminiumpreisen zeichnet sich seit einigen Monaten eine leichte Erholung ab. Die 3-Monats-Notierungen haben sich von ihrem Tief im August ($1.831/t) abgesetzt, sie lagen Mitte Januar bei 2.094 Dollar je Tonne. Angesichts hoher weltweiter Lagerbestände und des weiteren Zubaus von Produktionskapazitäten – Beispiel Alcoa Ma’aden: Die neue Hütte in Saudi-Arabien hat im Dezember ihren ersten von 720 Elektrolyseöfen in Betrieb genommen – ist der Spielraum für substanzielle Preissprünge begrenzt. Dies hält den Druck auf die Erlöse hoch; kaum ein Branchenunternehmen, dass nicht Effizienzprogramme fährt, um Kosten zu senken. Stetiger technologischer Fortschritt trägt maßgeblich dazu bei, noch produktiver bzw. kostensparender zu produzieren. Dass die Hüttenbranche und ihre Ausrüster kontinuierlich daran arbeiten, ihre Produktion und Arbeitsabläufe immer effizienter zu gestalten, belegen zahlreiche Beiträge in dieser Ausgabe. Although the latest figures for global economic growth in 2012 were not yet available when we last went to press, most economists anticipate that growth will have amounted to around three percent. Whether world trade will again pick up speed in 2013 is a question on which opinions differ. It is generally agreed, however, that Europe’s economy will again contract, the USA will see moderate growth and trade in the developing countries will continue its upward trend. As regards the aluminium market, Alcoa CEO Klaus Kleinfeld is optimistic. During the presentation of his company’s quarterly results his estimation was that demand for aluminium will rise seven percent this year. Although that does not come up to the values in 2010 (+13%) and 2011 (+11%), it would still be a percentage point higher than the estimated growth in 2012. That development is driven above all by demand from the aviation and building sectors. In the aviation market Alcoa expects growth to reach almost the two-digit level. Other aluminium concerns, however, are not quite so optimistic in their forecasts for this year. At an investor conference in November Svein Richard Brandtzæg, CEO of Hydro, put a figure of two to four percent on the growth of global demand for aluminium – leaving China aside. That would correspond to the level of general expectations regarding world trade. In recent months aluminium prices have shown a slight recovery. From their low-point in August (USD1,831/t), 3-month quotes have improved somewhat and in mid-January stood at USD2,094/t. In light of high aluminium stock levels worldwide and further proliferation of production capacities – for example, Alcoa Ma’aden: in mid-December the new smelter in Saudi Arabia started up the first of its 720 pots cells – the scope for substantial price increases is limited. This maintains the high pressure on profits: almost every aluminium company today is busy implementing efficiency measures to cut costs. Continual technological advances are contributing decisively toward increased productivity and cost-cutting. Many articles in this issue bear witness that the smelter industry and its suppliers are constantly striving to make their production and working procedures ever more efficient. Pro domo: Der besseren Lesbarkeit wegen werden rein englischsprachige Artikel ab dieser Ausgabe schwarz gedruckt. Deutschenglische Beiträge wie in diesem Editorial behalten dagegen ihre farbige Unterscheidung. Editor’s note: As from this issue, articles purely in English will be printed in black to facilitate legibility. Contributions in both German and English, however, such as this editorial, will retain their colour demarcation. 3 I N H A LT EDITORIAL A l umi n i u mi n du st ri e st a rt e t o p t i mi st i s ch i n s n e u e Ja h r O p t i mi st i c st a rt fo r t h e a l u mi n i u m i n du st ry i n t h e n e w ye a r ................ 3 A KT U E L L E S • N E W S I N B R I E F GF Automotive veräußert deutsches Sandgussgeschäft ......................... 6 Aluminium China’s buyer delegations demand 8 for high quality equipment from overseas ......................................... 7 12 th OEA International Aluminium Recycling Congress in Düsseldorf, 25-26 Feb 2013 .............................. 7 Amag errichtet Logistikzentrum in Rekordzeit .................................... 8 14 to 18 May 2013, Milano, Italy: 8 th Aluminium Two Thousand Congress ............................................. 9 WIRTSCHAFT • ECONOMICS Aluminiumpreise ......................................................................... 10 Produktionsdaten der deutschen Aluminiumindustrie .......................... 12 Five hundred participants at Arabal 2012 Conference ......................... 14 Dub a l ’s DX+ t e ch n o l o gy s e l e c t e d b y Al b a ........................................ 15 TM S 2 013 o ffe rs a di ve rs i t y o f l i gh t me t a l s p ro g ra m m i n g a n d n e t wo rk i n g o p p o rt u n i t i e s .................................... 16 A L U M I N I U M S M E LT I N G I N D U S T R Y R e c e n t d eve l o p me n t o f Du b a l a l um i n i um re du c t i o n c e l l t e ch n o l o gi e s ............................................ 18 0 Th e ‘A P Te ch n o l o gy’ s me l t e r o f t h e fu t u re .......................................24 M ö l l e r d ire c t p o t fe e di n g s yst e m fo r g re e n f i e l d a n d b rown fi e l d s me l t e rs ................................................28 Ca r b o n e Savo i e – Ca t h o de p ro du c e r s h ows i t s me t a l .........................32 Fi ve s S o l io s – 3 0 ye a rs o f e x p e ri e n c e i n fu me de s u l p h u ri s a t i o n ...........38 A l umi n a re fi n e ry: O u t o t e c ’s p ro c e s s a n d i mp l e me n t a t i o n s o l u t i on .......33 E i r i ch : Hi st o ry o f i n t e n s i ve mi x i n g fo r c a rb o n p a st e ..........................40 HM R ’s a ut o ma t e d st u d re p a i r l i n e ..................................................44 M a r x : Ch a n n e l -t yp e ve rs u s c o re l e s s i n du c t i o n fu rn a c e .......................46 A l c o a st a rt s u p p o t l i n i n g fa c i l i t y a t Fja rda á l Ic e l a n d s me l t e r ...............49 G a ut s ch i E n gi n e e ri n g – An i n du st ry p ro fi l e ......................................52 Latest News A d va n c e d t e ch n o l o gy fro m Bro ch o t – www.alu-web.de Di f f us i o n a n d c o n ve c t i o n o f a l u mi n a A p rove n s o l u t i o n fo r a n o de s l o t c u t t i n g .........................................56 i n t h e b at h o f a Ha l l -Hé ro u l t c e l l ...................................................58 4 ALUMINIUM ALUMINIUM · 1-2/2013 · 4/2012 CONTENTS Power u pgra de of Is al Po t l i n e s 1 - 3 . . . . . . . . . . . . . . . . ................................. 61 Applyi n g com pu t a t i o n al t h e r mo dy nami cs t o i ndu st r i al al umi n i um al l o ys . . . . . . . . . .................................64 ECL – A pr i v i l eg ed e qui p m e n t s up p l i e r t o t h e a l u mi n i u m i n du st ry .......67 Alsto m Powe r – N ove l g as c l e a n i n g f o r a n o d e b a k i n g fu rn a c e ............70 GNA ca t h ode bl ock s e al i n g p ro c e s s . . . . . . . . . . . . . . . .................................72 T. T. Tom or row – S l o t t i n g a n o d e s an d re c yc l i n g c a rb o n ......................74 52 Testin g a new ‘ STA R p ro b e’ . . . . . . . . . . . . . . . . . . . . . . . . . . . .................................76 Carbo t her m i c redu c t i o n – A n al t e r n a t i ve alumi n i u m produ ct i o n p ro c e s s . . . . . . . . . . . . . . . . . . . . . . .................................76 Recycl i n g of sm el t e r m at e r i a l s t h ro ug h ro tary cr u sh i ng a n d ma t e r i al s e p a rat i o n . . . . . . . . . .................................82 Meeti n g of t h e IS O C o m m i t t e e f o r an a l ys i s o f mater i a l s f or pr i m ar y al umi n i um i n S w i t z e r l an d ................................86 T E CH N O LO G I E • T E CH N O LO GY 82 Chips ver su s br i qu e t t e s : How t h e a l um i n i um ind ust r y ca n e f f ect i ve l y a n d e f f i c i e n t l y re c yc l e s c ra p ..........................87 Bühle r Lost - C ore -Te ch n o l o g i e e rö f f n e t we i t e s An we n du n gs s p e k t ru m Bühle r Lost C ore t e ch n o l o g y o p e n s up a w i d e ra n ge o f a p p l i c a t i o n s ....89 GM we l di n g i n n ovat i o n e n a b l e s i n c re a s e d us e o f a l u mi n i u m ...............90 A P P L I C AT I O N Alumi n i u m : Te sl a’s s e c re t we ap o n i n n e w M o d e l S ........................... 91 Inserenten dieser Ausgabe List of advertisers C O M PA N Y N E W S W O R L D W I D E Alumi n i u m sm e l t i ng i n d ust r y . . . . . . . . . . . . . . . . . . . . . . . . .................................92 Bauxi t e a n d a l u m i n a a c t i vi t i e s . . . . . . . . . . . . . . . . . . . . . .................................92 ABB Switzerland 37 Alteco Aluminiumtechnologie, Austria 22 Buss AG, Switzerland 21 De Winter Engineering, The Netherlands 60 Didion International Inc., USA 17 Alumi n i u m sem i s . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .................................93 Dubai Aluminium Co. Ltd , UAE 13 Fives Solios, France 41 O n the m ove . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .................................93 FLSmidth Hamburg GmbH, Germany 45 Gautschi Engineering, Switzerland 29 Glama Maschinenbau GmbH, Germany 53 Suppl i e r s . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .................................94 Hertwich Engineering GmbH, Austria RESEARCH Inotherm Industrieofen- und Wärmetechnik GmbH, Germany Cathode wea r i n H al l - Hé ro ul t c e l l s . . . . . . . . . . . . . . . . .................................95 Innovatherm Prof. Dr. Leisenberg GmbH & Co. KG, Germany D O C U M E N TAT I O N Impre ssu m • Im pr i n t . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............................... 113 Vo rs cha u • P rev i ew . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............................... 114 87, 91 35 Interall Srl, Italy 31 Precimeter Control AB, Sweden 65 R&D Carbon Ltd, Switzerland Reed Exhibitions China Ltd, PR China Paten t e . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .................................98 2 Reed Exhibitions, UAE Riedhammer GmbH, Germany SMS Siemag AG, Germany 116 11 115 19 50/51 TMS Minerals, Metals & Materials Society, USA 23 T.T. Tomorrow Technology SpA, Italy 25 L I E F E R V E R Z E I C H N I S • S U P P L I E R S D I R E C T O R Y ........... 100 ALUMINIUM · 1-2/2013 4/2012 5 AKTUELLES GF Automotive veräußert deutsches Sandgussgeschäft Künftiger Fokus auf Druckgussgeschäft in Asien und Europa Marktlage in Europa. Daher soll die rasche Expansion in China fortgesetzt werden. Der Anteil des Landes am Umsatz von GF Automotive ist in den letzten sechs Jahren von null auf zehn Prozent gestiegen. Die Produktionskapazitäten der beiden bestehenden Eisenund Aluminiumdruckgießereien sollen in den nächsten zwei Jahren um 40 Prozent erweitert werden. In Europa will sich das Unternehmen auf Aktivitäten konzentrieren, bei denen bereits eine führende Marktposition erreicht wurde oder künftig erreicht werden kann. Dies trifft für das Druckgussgeschäft zu, nicht jedoch für das Aluminiumsandgussgeschäft. Die beiden Werke in Friedrichshafen und Im Werk Friedrichshafen von GF Automotive werden Antriebs- und Fahrwerksteile aus Aluminiumsandguss hergestellt Garching werden an die MWS IndusGeorg Fischer erwartet in naher Zukunft trieholding GmbH veräußert, die damit zum weiteres Wachstum vor allem am asiatischen Technologieführer und größten Anbieter im Automobilmarkt und eine eher verhaltene Bereich Aluminiumsandguss in Europa wird. Yves Serra, CEO von Georg Fischer, erklärte: „Die Integration der Aluminiumsandgussaktivitäten in das Geschäft von MWS hat eine bedeutende Konsolidierung innerhalb dieses Marktsegments zur Folge und erlaubt es GF Automotive, sich auf ihre Kernaktivitäten zu konzentrieren.“ Um die Kontinuität des Geschäfts zu gewährleisten soll das bisherige Sandguss-Management laut MWS an Bord bleiben. Die Gießereien in Friedrichshafen und Garching gehören seit 1999 zum Georg Fischer Konzern und beschäftigen 250 bzw. 180 Mitarbeiter. Sie sind auf Aluminiumsandgussteile für Pkw, Nutzfahrzeuge und Industrieanwendungen spezialisiert. Der Gesamtumsatz der beiden Gießereien belief sich 2011 auf 127 Mio. Schweizer Franken. GF Automotive verzeichnete 2011 einen Umsatz von 1,7 Mrd. Schweizer Franken. Die MWS-Gruppe mit Sitz in KufsteinSchwoich ist ein österreichischer Automobilzulieferer in Privatbesitz. Die Gruppe ist auf Aluminiumguss spezialisiert. MWS wurde 2004 gegründet und verfügt derzeit über drei Niederlassungen in Österreich und ein Produktionswerk in der Slowakei. Das Unternehmen hat insgesamt 320 Beschäftigte und erzielte 2012 einen Umsatz von 32 Millionen Euro. Otto Junker und Can-Eng Furnaces kooperieren beim Service Optimierung mechanischer Kennwerte deutlich erweitert. Damit entstand eine Pilotanlage, die den Wärmebehandlungsprozess in der Praxis realistisch nachbildet und die Kunden in ihrer F&E-Arbeit unterstützt. Der gesamte Wärmebehandlungsprozess – das Zusammenspiel von Temperatur, Zeit und Abschreckung sowie die Planung des gesamten Ablaufes – wird individuell auf das Bauteil des Kunden bezogen und wissenschaftlich dokumentiert. Die Alu.Heat-Kunden können somit Versuche fahren, ohne ihre laufenden Prozesse innerbetrieblich zu stören. Durch gezielte Versuche und die Kombination aller technischen Möglichkeiten können deutliche Gewichtsreduzierungen pro Bauteil erzielt werden. Einhergehend mit der Einsparung von Gewicht und damit Material wird der Energieverbrauch, bspw. eines Fahrzeugs, reduziert, die Langlebigkeit des Bauteils erhöht, seine Belastungsgrenze ausgedehnt und die CO2-Emission reduziert. © Georg Fischer GF Automotive hat sein deutsches Aluminiumsandgussgeschäft mit den Gießereien in Friedrichshafen und Garching veräußert. In Zukunft will sich das zum Industriekonzern Georg Fischer gehörende Unternehmen auf seine Eisen- und Aluminium-Druckgießereien in Europa konz und vor allem seine bestehenden Werke in China weiter ausbauen. Die Otto Junker Gruppe, Simmerath, und Can-Eng Furnaces International Ltd., Niagara Falls / Ontario, kooperieren beim Kundendienst. Eine jüngst abgeschlossene Vereinbarung zielt angesichts der sich wechselseitig ergänzenden Produktpaletten darauf, die Betreiber von Junker- bzw. Can-End-Wärmebehandlungsanlagen in aller Welt besser zu unterstützen. Den Kunden bietet sich damit eine komplette Palette von Schmelz-, Gieß-, Prozesserwärmungs- und Wärmebehandlungsanlagen für thermische Verfahrensanwendungen. Im Rahmen des Kundendienstes können Kunden von Otto Junker und Can-Eng ihre Anfragen zu Produkten der beiden Gruppen jeweils an die geografisch nächstgelegene Ver- 6 triebsniederlassung richten. Hauptansprechpartner sind Tim Donofrio (Vice President, Standard and Aluminium Products, Can-Eng Furnaces, tdonofrio@can-eng.com), und Jan van Treek (Verkauf Thermoprozessanlagen, Otto Junker jvt@otto-junker.de). Alu.Heat baut innovative Pilot-Wärmebehandlungsanlage Die Alu.Heat GmbH hat eine innovative Pilotanlage zur Wärmebehandlung gebaut, die aus einem luftumgewälzten Kammerofen, einer Luft-/Wasserdusche, einem Wasserabschreckbad mit Umwälzung, einer automatischen Beschickungseinrichtung und einer Prozesssteuerung mit entsprechender Dokumentation besteht. Mit der zum Patent angemeldeten Luftabschreckung unter Zugabe einer regelbaren Wassermenge wurden die Möglichkeiten zur ALUMINIUM · 1-2/2013 NEWS IN BRIEF Aluminium China’s buyer delegations demand for high quality equipment from overseas a great platform for us. Although there are numerous trade exhibitions in China every year, we only exhibit at a single aluminium event: this one. We’ll exhibit here again next year.” With its still booming economy, China is set to remain the world’s largest aluminium consumer throughout the next several years, accounting for more than 40% of global aluminium consumption. Carmakers like VW, BMW, Audi and Nissan are set to open new production plants in China within the next two years, and numerous construction projects are planned for the country’s western provinces. China’s main application industry sectors for aluminium are set to More than 14,700 visitors attended the Aluminum China 2012 trade fair drive demand for both Thanks to the success of Reed Exhibition finished and semi-finished products, but also China’s Targeted Attendee Programme for for processing machinery and equipment from Chinese VIP buyers at Aluminium China Japan, Korea and Europe. As a consequence 2012, over 200 exhibitors already booked ex- of rising energy costs an increasing number of hibition space for the 2013 event occupying Chinese aluminium producing and processing 80% of the overall exhibition space. Jiasheng manufacturers have expressed strong intend Wang, managing director of Ebner Industrial to buy modern, energy saving machinery and Furnaces (Taicang), commented on the side- equipment from overseas. The organiser of Aluminium China 2013 lines of the 2012 event: “Aluminium China is will leverage this strong demand and invite an even bigger number of 550 targeted top buyers from China as well as procurement delegations from selected application industry sectors in Asia, for pre-arranged matchmaking sessions with international exhibitors. This combination of the supply and demand side of the aluminium industry will present a number of attractive business opportunities to both parties. Reed Exhibition’s international delegation programme for Aluminium China 2013 includes new partnerships with tour operators and buying associations from countries with increasing demand for equipment and aluminium products: India, South East Asia and Russia. For Aluminium China 2013 the blend of material exhibitions, high profile conferences and the complementary trade exhibitions Copper China 2013 and Magnesium China 2013 will again enhance the show’s success. Additionally, the ‘China Aluminium Fabrication Forum’, organised by the China Metal Information Network, and a new edition of the Lightweight Automotive Forum will give participants a synergetic opportunity to source and display diversified exhibits while learning more about the key issues affecting today’s aluminium industry. 12th OEA International Aluminium Recycling Congress in Düsseldorf, 25-26 Feb 2013 • The political targets in terms of aluminium recycling • Innovations in recycling technologies • Limits of scrap processing • The pros and cons of recycled aluminium content • Markets for recycled aluminium. Who should attend the congress? Refiners and remelters of secondary smelters, scrap collectors and processors, metal merchants, consumers of recycled aluminium, parliamentarians and authorities, national and international associations. There will be a simultaneous translation of the presentations in English and German. © Reed Exhibitions In 2013, ‘Aluminium China’, the leading aluminium sourcing platform in Asia for industry professionals and buyers from the aluminium industry and a wide array of application industries will expand its buyer delegation programmes on further key Asian industry clusters in China, South East Asia and India. What are the latest trends in aluminium recycling, where are the risks and chances? Recycling and its contribution to the raw material supply will run like a golden thread through the presentations and discussions of the 12th OEA Intl Aluminium Recycling Congress. Industry experts will present their view on important recycling matters. The aim of the congress is to show a complete picture of all relevant subjects on the recycling of aluminium. The delegates of the congress who form the ALUMINIUM · 1-2/2013 Who is Who of the aluminium recycling world will get a comprehensive update of the development of aluminium recycling in Europe and the world. Interesting encounters and discussions are guaranteed. Thanks to highly qualified speakers, numerous delegates of the aluminium recycling industry and other industries, as well as the public from Europe and other parts of the world, the 12th OEA Congress in Düsseldorf offers the ideal platform to answer questions, to exchange and discuss information and to look for solutions in order to cope with the challenges the industry is facing. Topics to be discussed include: • The impact of increasing energy prices • The regional and global scrap supply • The role of the metal trade Aluminium China 2013 will be taking place from 2-4 July 2013 at the Shanghai New International Expo Centre. For more details, visit www.aluminiumchina.com/en. Further information and registration details at www.oea-alurecycling.org 7 AKTUELLES Amag errichtet Logistikzentrum in Rekordzeit weist eine Lagerkapazität von 11.000 Tonnen auf. Mit dem Logistikzentrum wurde ein wichtiger Schritt zur Steigerung der Produktionskapazitäten gemacht. „Durch die optimale Planung, Bauvorbereitung und den tat- © Amag Der Werksausbau der Amag Austria Metall AG in Ranshofen liegt im Zeitplan. Anfang Dezember wurde als erster Teil der Großinvestition ein neues Logistikzentrum am Standort Ranshofen fertiggestellt. Die neue Halle Eckdaten des Fertigwarenlagers: Abmessungen: 199 x 56 Meter, Lagerfläche: 9.000 Quadratmeter Ascojet-Trockeneisstrahlen für Motorenteile © Asco Im Werk Untertürkeim setzt Daimler die Trockeneisstrahl-Technologie der Schweizer Asco Kohlensäure AG ein, um Motorenteile wie Kolben, Zylinderköpfe und Kurbelgehäuse schonend von Silikonrückständen, Ölen, Fetten, Verbrennungsrückständen und anderen Verschmutzungen oder Dichtstoffen zu reinigen. Da diese Bauteile in der geometri- schen Messtechnik vor und nach Tests genau ausgemessen werden, ist es wichtig, die Teile nach den Tests so schonend zu reinigen, dass 8 die Messwerte nicht verfälscht werden. Die Trockeneisreinigung stellt sicher, dass die Oberflächen nicht beschädigt werden und die Bauteile nach einmaligem Reinigen sauber sind. Als Alternative kämen nur aufwendige manuelle Reinigungsmethoden oder die Reinigung mit Lösungsmitteln in Frage, was zeitaufwendiger wäre. Noch wichtiger als die Zeitersparnis bei der Reinigung selbst ist für die Messtechnik die Gewissheit, dass das Bauteil nach einmaliger Reinigung vollkommen sauber ist. Jede Doppelmessung und Nachreinigung bedeutet zusätzliche Kosten. Ein spezieller Fall ist die Reinigung von Kolben, deren schmale Ringnut nicht einmal Trockeneis messfähig säubert. Dank eines an der Pistole montierten Lichtkranzes (s. Foto) wurde eine Lösung gefunden, die Ringnut mit Trockeneis soweit vorzureinigen, dass Verschmutzungsreste anschließend im Ultraschallbad entfernt werden können. kräftigen Einsatz der Belegschaft sowie regionaler Zulieferer- und Dienstleistungsbetriebe wurde das Projekt in kürzester Zeit durchgeführt“, erklärte Amag-Generaldirektor Gerhard Falch. Mit einem Volumen in Höhe von 220 Mio. Euro, die über die nächsten Jahre hinweg in den Werksausbau fließen, stellt das Projekt eines der größten Investitionsvorhaben in der europäischen Aluminiumindustrie dar. Der Großteil der Investitionssumme fließt in die Errichtung des neuen Warmwalzwerkes sowie in die Erweiterung der Walzbarrengießerei sowie in eine neue Plattenfertigung. Mit den neuen Anlagen erweitert Amag ihre Produktionskapazität im Walzwerk von derzeit 150.000 Tonnen auf 225.000 Tonnen und weitet das Produktspektrum zu größeren Breiten und Dicken aus. Durch den Ausbau werden mittelfristig rund 200 neue Arbeitsplätze geschaffen. Rösler nimmt Hochregallager in Betrieb Die Rösler Oberflächentechnik GmbH hat am Standort Memmelsdorf ein Hochregallager mit 17 Ebenen errichtet. Zwei neue LasertechnikHallen und ein Kompaktlager sind bereits im Herbst in Betrieb gegangen. Der Spezialist für Strahl- und Gleitschlifftechnik hat zu diesem Zweck 8,5 Mio. Euro investiert. Das neue Hochregallager bietet mit einer Grundfläche von 1.400 Quadratmetern auf 17 Ebenen insgesamt 7.741 Palettenstellplätze, die zum Einlagern von Grundstoffen (Compounds), Schleifkörpern sowie Maschinenund Ersatzteilen dienen. Mit dem Aufbau an Lagerkapazitäten will Rösler noch schneller auf Kundenwünsche reagieren. Das Hochregallager nahm wie geplant in der ersten Januarwoche seinen Dienst auf. Pro Stunde können über die Lkw-Verladestation 100 Paletten aus- und eingelagert werden. Bereits im Herbst des vergangenen Jahres hat Rösler zwei Produktionshallen mit einer Fläche von rund 3.500 Quadratmetern in Betrieb genommen. In diese Neubauten wurde vor allem der komplette Bereich der Laserfertigung verlagert. Dazu gehören die beiden vorhandenen Trumpf-Laserschneidanlagen inklusive Materialkompaktlager. Neu hinzugekommen sind zwei Abkanntpressen mit jeweils 400 Tonnen Presskraft. ALUMINIUM · 1-2/2013 NEWS IN BRIEF 14 to 18 May 2013, Milano, Italy The Aluminium Two Thousand Conferences, since their beginning in 1990, have become not-to-be-missed events for aluminium technology and marketing people all over the world. The highly practical and specialist character of these meetings, organised by Interall, have been attracting more and more attendants to listen to and debate an ever increasing number of presentations from high-level speakers. Two years after the event in Bologna, the international aluminium community – industry experts, scientist and researchers from renowned companies – will gather again: this time in Milano, Italy, from 14 to 18 May 2013. The 8th Aluminium Two Thousand Congress will offer a profound technical programme with a record number of 120 papers on latest technologies in the aluminium industry, especially in the extrusion, rolling, casting and finishing sectors. Representatives from leading suppliers, extruders, anodisers, coaters, fabricators, operators in the casting industry, and from the automotive, electronic and aerospace industries have already confirmed their participation. During the plenary session on the first day, specialists from different areas of the world will speak about the aluminium market and trends for the future. During the opening day, ambassadors of seven of Africa’s most developed countries will illustrate their projects for industrialisation and business opportunities at a forum titled ‘Aluminium for Africa and Africa for Aluminium’. The technical programme comprises four parallel sessions on the following themes: Session 1 will deal with the extrusion process, with emphasis on numerical modelling and automation systems, database and extrusion process monitoring. Further presentations will deal with extrusions and their various applications, such as aluminium for Attendees at the Aluminium Two Thousand Congress in 2011 structural application, deformation of aluminium profiles, and quality techniques (quality management and control, measuring instruments), rolling safety aspects and energy savings. Session 2 is dedicated to aluminium fin- technology (heat transfer, new studies), adishing: anodising and hard anodising (latest vanced forming and welding processes. The ‘Russian Day’ for Russian speaking studies, nanotechnology, acid etching, plasma electrolytic oxidation, studies of electrolysis delegates is another special event: the most baths), coating (pretreatment, chrome-free interesting papers with innovative content will systems, eco-friendly solution for aluminium be repeated by the speakers in a separate full pretreatment, aesthetic surface treatment with session with simultaneous translation. The congress programme includes three high durability, corrosion protection), enviworkshops (full day) on extrusion, anodising ronmental protection and recycling. Session 3 is dedicated to casting and die- and coating, as well as the choice of a technical casting (semi-solid casting for reducing energy, tour out of a total of five. An attractive social methodology for temperature evaluation, mi- programme with a gala dinner, daily tours for cro-porosity in gravity die-casting, self-clean- accompanying persons rounds off the event. Further information at ing effects, casting structural alloys). www.aluminium2000.com Session 4 will deal with measuring, testing © Interall 8th Aluminium Two Thousand Congress Rio Tinto announces huge write-down of aluminium assets Mining giant Rio Tinto has revealed a near USD14 billion (after tax) write-down of its coal and aluminium assets. The write-down of the aluminium assets (mainly related to Rio Tinto Alcan but also to Pacific Aluminium) is in the range of USD10-11 billion; a further USD3 billion write-down relates to Rio Tinto Coal Mozambique. The final figures will be included in Rio Tinto’s 2012 full year results due on 14 February. As a direct consequence of this dramatic cut, Tom Albanese has stepped down as chief executive. Iron Ore chief executive Sam Walsh has been appointed as his successor with immediate effect. ALUMINIUM · 1-2/2013 Chairman Jan du Plessis commented: “The Rio Tinto board fully acknowledges that a write-down of this scale in relation to the relatively recent Mozambique acquisition is unacceptable. We are also deeply disappointed to have to take a further substantial write-down in our aluminium businesses, albeit in an industry that continues to experience significant adverse changes globally.” Mr Plessis said Rio Tinto will implement an “aggressive cost reduction plan” to improve the company’s competitive position. Already at its investor seminar in Sydney at the end of November, Rio Tinto said that the annual year-end review of asset carry- ing values would most likely result in further revisions to the value of assets, notably aluminium. The further deterioration in aluminium market conditions in 2012, together with strong currencies in certain regions and high energy and raw material costs, has had a negative impact on the current market values in the aluminium industry. Rio Tinto acquired Canadian aluminium flagship Alcan in 2007. The takeover price of USD101 a share corresponded to some ten times Rio Tinto’s Ebitda. The mining company has now written down USD28-29 billion or about three quarters of the USD38 billion paid for Alcan. 9 WIRTSCHAFT ! /3"+6:/)+*+6#!#$$ /+43'87348/+693-,B6192/3 /92 /-.-6'*+ 348/+68+ /2 +<+2(+6 ;+/8+6./3 '9, +/3+2 .4.+3 /:+'9 92 */+'60+:43$"411'6#+2546@6 *6+.8+7/).*+6'608/3+<9-'9,*+3 "56+'* '77+43'8+ 096< :46 *+2 *6/88+3 /88;4). '97 +/3+6 438'3-4 "/89'8/43/3*/+.A).78+')0;'6*'8/43 7+/8 ,B3, '.6+3 /+7 .'88+ <96 41-+ *'77*'7+8'11'3*/+4*+6'3936+ -/786/+68+'-+6.@97+6'3-+*/+38;96*+ +7 &+/8+6+3 :+6<+/).3+8+ */+ +/3+378'60+3378/+-2/8+/3+2!+046* .4).:43/11/43+3#433+3(+/*+3 ?)'3)+11+* ;'66'387= /3 *+3 '-+6.@9 7+63+864/893*%1/77/3-+3 ! +8<8+396).7).3/887;+68+ +<+2(+6 4:+2(+6 084(+6 "+58+2(+6 9-978 91/ 964 964 964 964 964 964 50 0 –50 2004 2005 2006 2007 2008 2009 2010 2011 2012 +8<8+396).7).3/887;+68+ 2.500 +<+2(+6 4:+2(+6 084(+6 "+58+2(+6 9-978 91/ 2.000 964 964 964 964 964 964 1.500 2004 2005 2006 2007 2008 2009 2010 2011 2012 1.000 6.000 +8<8+343'87+3*;+68+ +<+2(+6 4:+2(+6 084(+6 "+58+2(+6 9-978 91/ 8 8 8 8 8 8 5.000 4.000 3.000 2.000 1.000 2004 2005 2006 2007 2008 2009 2010 2011 2012 0 11+3-'(+3'9,*/+7+6"+/8+7/3*93:+6(/3*1/). 9+11+#!#$$>'089+11+&+68+938+6;;;86/2+8*+4*+65+6#!#55'9,*'7/.43+ 10 ALUMINIUM · 1-2/2013 WIRTSCHAFT Produktionsdaten der deutschen Aluminiumindustrie Primäraluminium Sekundäraluminium Walzprodukte > 0,2 mm Press- & Ziehprodukte** Produktion (in 1.000 t) +/in % * Produktion (in 1.000 t) +/in % * Produktion (in 1.000 t) +/in % * Produktion (in 1.000 t) +/in % * Nov 35,2 -1,9 57,0 8,5 152,8 -3,5 53,2 4,7 Dez 35,9 -3,5 46,7 12,1 109,2 -11,5 30,2 -3,5 Jan 12 35,3 -4,7 54,1 7,2 145,4 -6,1 46,3 3,3 Feb 32,4 -4,1 55,6 2,6 149,3 -7,3 47,7 0,9 Mär 34,1 -8,0 57,2 -2,2 165,9 -4,5 50,4 -5,1 Apr 33,5 -6,1 53,3 0,2 147,2 -6,0 45,0 -4,9 Mai 34,4 -7,4 54,3 -4,1 160,7 -4,5 48,9 -12,7 Juni 33,0 -8,0 54,6 6,9 161,0 20,6 49,1 -0,3 Juli 34,8 -5,0 56,0 7,1 166,4 0,9 46,9 -7,4 Aug 34,9 -5,8 47,2 2,9 161,4 1,2 44,9 -11,8 Sep 33,6 -4,4 52,5 -4,3 164,5 8,1 44,6 -17,2 Okt 35,2 -2,5 53,3 -0,3 162,5 9,4 46,1 -7,4 Nov 34,2 -2,9 53,4 -6,4 152,9 0,1 42,5 -20,1 * gegenüber dem Vorjahresmonat, ** Stangen, Profile, Rohre; Mitteilung des Gesamtverbandes der Aluminiumindustrie (GDA), Düsseldorf Primäraluminium Walzprodukte > 0,2 mm 12 Sekundäraluminium Press- und Ziehprodukte ALUMINIUM · 1-2/2013 To be world-class itÕs not enough to meet the standards. We believe we have to set them. Dr. Maryam Mohamed Al Jallaf Senior Manager: Process Control Potrooms and Cell Lining Setting the benchmark for production costs, environmental protection and employee safety. Since our inception in 1979 we have dedicated ourselves to establishing DUBAL as a world-class supplier of aluminium to global markets. You might put our success down to an unswerving focus on quality and the unparalleled 99.99% purity of our products. But it is also the restless pursuit of excellence that drives continuous improvements in product quality, operating processes, employee and environmental safety which has helped make us what we are today. Commitment to raising the standards. ThatÕs what sets us apart. And you can quote us on that. Together we shine For more information call: +971 4 884 6666 www.dubal.ae ECONOMICS Five hundred participants at Arabal 2012 Conference Almost 500 participants – a record number – attended the Arabal 2012 Conference in Doha in November last year. In his opening address to the plenary session Mohammad Ali Al Naqi, chairman of the Organising Committee, outlined how things have changed since the first Arab Aluminium Conference in 1983. “Today, as we celebrate the 16th occasion of Arabal, the region has seven primary aluminium smelters with a capacity of up to 15 percent of global production,” he said, adding that this went along with other, supporting projects such as calcined coal and projects that depend on smelters’ products, like aluminium extrusion, cables and car-wheel factories which supply the global automotive industry.1 © Arabal The first day of the conference focused on regional issues, power generation and technology. Abdulrahman Ahmed Al Shaibi, chair- Well attended – the Arabal 2012 Conference man of Qatalum, the organising host of Arabal 2012, took the audience through the steps that the company has taken in Qatar and the achievements realised in the aluminium industry and industrial sector. Despite the current global economic slowdown, he is optimistic about future development in the aluminium industry: “We do not expect low prices to last; unlike many other metals, growth in aluminium demand is positive and we expect it to continue,” he said, being confident that the aluminium price will follow bullish demand forecasts. The industrial sector in Qatar was moving 1 Note from the editor: the 15% figure does not include the Alcoa Ma’aden smelter, which was inaugurated in mid-December 2012. 14 on the right track, he noted, “supported by incentives and industrial benefits that aim to encourage industrial investment and to focus on industrial projects that are based on best available technology”, something which can no longer be considered on a solely national basis. “It is truly an international industry, due to the interdependence between production and raw material hubs, the smelting and refining centres and the manufacturing industries,” he said. Mr Al Shaibi, who also spoke on behalf of Mr Al Sada, Minister of Energy and Industry, pointed out that the aluminium industry was in a state of restructuring. The economic downslide in Europe coupled with escalating power tariffs, lack of local resources, taxation and tightening of ecological regulations had already resulted in the shutdown of European aluminium smelters. “We are seeing a spate of evolution and consolidation within the industry. The focus of the aluminium sector is steadily shifting, often away from those who were considered the traditional leaders. Middle-Eastern manufacturers are now increasingly emerging as serious contenders in the global aluminium market,” he said. Qatalum CEO Tom Petter Johansen ruled out direct involvement in downstream industries but said the company’s focus would be on capacity enhancement. Qatalum smelter tour Attendees of the conference had the opportunity to visit the Qatalum smelter at Mesaieed Industrial City. The 40-minute tour of the facility – which consumes up to one third of Qatar’s total power usage – started at Potline 2, then moved to the baking furnace, paste plant and anode rodding shop and also to the casthouse and power plant and to a building characterised by zero net energy consumption and zero carbon emissions. At the paste plant ingredients are mixed to create new (green) anodes. The baking plant consists of furnaces where green anodes are baked to form the black anodes used in the reduction pots for making liquid aluminium. The 1,350 MW power plant includes the tur- Mr Al Shaibi (left) and Mr Al Naqi bine building, seawater cooling towers, four heat recovery steam generators for recycling exhaust gases and finally the gas insulated switchgear (GIS) – the connection between the power plant and the smelter. The delegates were accompanied by tour guides from Qatalum to answer any questions on the plant, processes and people. The role of China China’s aluminium industry was a major topic on the final day of the Arabal conference. Paul Adkins, director of AZ China Limited, and Eric Zhang, analyst at SMM, spoke about the peculiarities of the Chinese industry, which persists with enormous production despite heavily subsidised losses, at least in certain provinces. According to Adkins, China is in the top quartile of the global cost curve. Its industry consumes scarce energy resources, is forced to import raw materials and jeopardises environmental integrity, yet 10 million tonnes of new capacity are still to come online. “Why on earth do the Chinese persist with making aluminium,” he asked rhetorically. His answer: “As Westerners and as analysts and corporates, we focus on the markets, the industry, equities, P & L (profit & loss), capital flows, ROI, etc. But by doing so, we can miss the key point: for the Chinese Communist Party, aluminium is an important conduit for the development, urbanisation and modernisation of China,” he said. Eric Zhang forecast that domestic aluminium prices will face many uncertainties in 2013 and are subject to LME aluminium prices to a large extent. SMM expects domestic aluminium prices to fluctuate between RMB15,000-17,500/t (USD2,400-2,800/t) in 2013. The role of China was a theme carried into the next session, with a presentation by Jorge ALUMINIUM · 1-2/2013 Vazquez, managing director of Harbor Aluminium Intelligence, who spoke to delegates on who is winning and losing in the global aluminium industry and supply chain today. “Who is getting the value?” he asked. “It is not the producer for sure.” Today, consumers are getting the greatest value ever, with real LME aluminium prices at a cycle bottom below USD2,000/t, compared to the historical average of USD2,650/t and a high of about USD4,700/t. In his view there are two main sources of growth in the next five years: emerging Asia (including the Gulf) and the Americas. Over 16 million tonnes of new aluminium capacity should hit the market by 2015, two thirds of this in China for domestic consumption. The Middle East too is well placed. “We see the Middle East as the leading provider for growing world metal needs ahead and the Americas / Europe / South East Asia as increasing import players,” he said. Outlook of the automobile industry David Cutting, director of J. D. Power Automotive Forecasting, spoke about the Global Light Vehicle Market, which is heavily depend- ent on aluminium. The global light vehicle market is predicted to break through the 100 million barrier by 2015, almost doubling in volume since the end of the 1990s. Emerging markets, led by China, India, Brazil and Russia, have driven much of the recent growth and are expected to remain key motivators of future growth. Qatalum smelter at Mesaieed Industrial City Light vehicle production growth in Asia is expected to significantly than 50% of aluminium used in cars. outpace the other regions (with share of outThe day and the conference as a whole put increasing from 48% in 2011 to 53% by wrapped up with a Culture Night at Skeikh 2016). Faisal Bin Qassim al Thani Museum, with a Shambhu Prasad, senior expert at Gulf tour of the museum followed by a dinner at Organisation for Industrial Consulting, noted Majlis hall, at which delegates could discuss that aluminium usage has increased to 140 kg the connections made, information shared per car in 2011 – predominantly in the drive- and arguments put forward over three days train, chassis and suspension, and body. The of discussion about the aluminium industry at automotive industry is the largest market for national, regional and international level. aluminium castings, which account for more N © Qatalum ECONOMICS Dubal’s DX+ technology selected by Alba ALUMINIUM · 1-2/2013 nology has been fully operational since February 2008, and visited Dubal’s DX+ pilot section. The Alba delegates were also accompanied on a tour of Emal in Al Taweelah, Abu Dhabi, where 756 DX technology cells, arranged in two potlines, have been fully operational at Emal Phase I since the end of December 2010. “Dubal’s reduction technologies have been designed fully-modelled and extensively tested. The results consistently confirm that both DX and DX+ technology operate stably, demonstrating not only the robustness of their design but also the suitability of both to the Gulf climate,” said Abdulla Kalban, president and chief executive of Dubal. “We are delighted that Alba has recognised these qualities as evidenced by the selection of DX+ technology for the Line 6 Bankable Feasibility Study.” economic analysis for the construction of a new Power Station 5. Bechtel has considerable industry-specific experience in the region and was previously the EPCM contractor for the Alba Potline 4 and 5 expansions. The study is expected to be complete by the third quarter of 2013. Bechtel to conduct feasibility study Alba has awarded Bechtel Canada a letter of intent to conduct the feasibility study for Potline 6. The study will include the © Alba Dubai Aluminium has signed an agreement with Aluminium Bahrain whereby the latter will use Dubal’s DX+ technology for Alba’s Potline 6 Bankable Feasibility Study. Tim Murray, chief executive of Alba, pointed out that study would determine the viability of Alba’s sixth potline expansion project, which will boost the company’s aluminium production capacity by approximately 400,000 tpy to 1.280 million tonnes. Dubals’s DX+ technology is an enhanced version of Dubal’s proven DX technology. DX+ is designed to operate at higher amperages and optimised performance levels. Five DX+ cells, built in a pilot line at Dubal’s Jebel Ali site in 2010, initially operated at 420 kA and currently operate stably at 440 kA. At this level, the DX+ cells yield substantially better energy efficiency and specific energy consumption levels than DX cells, and produce 3,37 tonnes of aluminium per pot per day. Ultimately, DX+ cells are expected to operate at 460 kA. While in the UAE, the Alba delegation visited Dubal’s Potline 8 – a dedicated 40-cell potline within the greater smelter operations where Dubal’s proprietary, in-house developed DX tech- View of the Alba site 15 A L U M I N I U M S M E LT I N G I N D U S T R Y TMS2013 offers a diversity of light metals programming and networking opportunities The Minerals, Metals & Materials Society (TMS) 142nd Annual Meeting and Exhibition will take place from 3 to 7 March 2013 in San Antonio, Texas, USA The foundation of TMS2013 is an exceptionally strong technical programme featuring more than 330 sessions built from more than 3,000 abstract submissions. Topics span the continuum of materials science and engineering, from basic research of novel materials to optimisation of manufacturing processes. This breadth of programming offers attendees a unique opportunity to network and learn from colleagues representing other disciplines, facilitating the transition of material innovations from bold idea to successful product. Contributing to the strength of TMS’s annual meeting programming is the ‘globalisation’ of contributing authors in recent years. For TMS2013, nearly half of the abstracts accepted came from outside the United States. “The TMS Annual Meeting has evolved into a truly international event,” he says. “Not only does this build the prestige of the conference, but also greatly enhances the depth and quality of the learning and perspectives that are gained from attending it.” TMS2013 highlights of particular interest to the aluminium industry include: Technical track devoted exclusively to light metals: Representatives from the world’s largest light metals companies and research organisations convene to discuss breaking developments, evolving challenges, and new opportunities. Planned symposia specific to the aluminium industry include: Aluminium Alloys – Fabrication, Characterisation and Applications; Alumina and Bauxite; Aluminium Processing; Aluminium Reduction Technology; Cast Shop for Aluminium Production; Deformation, Damage, and Fracture of Light Metals and Alloys; Electrode Technology for Aluminium Production. Interdisciplinary learning opportunities: Energy management, recycling, and materials 16 processing and production topics pertinent to the aluminium community are incorporated throughout TMS2013’s other technical subject areas. These include: Advanced Characterisation, Modelling, and Performance; High TMS2013 Exhibition: Find the expertise and technology necessary to implement the new concepts and approaches covered in the TMS2013 symposia sessions at the three-day exhibition. TMS will offer a free buffet lunch © TMS “This is where the many facets of TMS meet,” says Wolfgang Schneider, 2012 TMS President and head of the Hydro R&D Centre in Germany, of the TMS2013 Annual Meeting and Exhibition. “It is at the core of what we do as a professional society and showcases the very best of what TMS has to offer – as well as the very best of what materials science and engineering has to offer the world.” View looking into the exhibition hall at TMS2012 Performance Materials; Materials Processing and Production; and REWAS 2013: Enabling Materials Resource and Sustainability. Aluminium Keynote Session: The TMS 2013 Aluminium Keynote Session will assemble experts representing a range of perspectives on managing impurities in the aluminium supply chain. “The primary goal is to bring people together from the bauxite / alumina, reduction, electrode, and casthouse areas to make the point that we need to think about impurities holistically rather than something that affects each area separately,” says Les Edwards, vice president of Technical Services, Rain CII Carbon, and session chair. “Taking this approach can change the way we develop solutions to impurity problems.” Technical papers presented in the session will be published in the 2013 Light Metals proceedings. Light Metals Division Luncheon: This popular networking event will feature John Mitchell, president of Rockwood Lithium North America, as its featured speaker. in the exhibition hall on 5 March, along with the president’s Reception and Happy Hour Tuesday event. Lunch items will also be available on 4 and 6 March, to make exhibition browsing convenient between sessions. Essential Readings in Light Metals: Available for sale at TMS2013 will be the just-released Essential Readings in Light Metals, a comprehensive collection of the most significant papers published in the more than four decades of the Light Metals proceedings. A rigorous review process, based on a specific selection criteria, has compiled about 10-15% of all Light Metals articles into four volumes, which can be purchased individually or as a set. Volume topics are: Alumina and Bauxite; Aluminium Reduction Technology; Cast Shop for Aluminium Production; and Electrode Technology for Aluminium Production. For additional information on TMS2013 and to make registration and housing arrangements, visit the conference website at www.tms.org/tms2013. N ALUMINIUM · 1-2/2013 A L U M I N I U M S M E LT I N G I N D U S T R Y Recent development of Dubal aluminium reduction cell technologies M. Reverdy, Dubal Dubai Aluminium (Dubal) commenced operation in 1979 with a capacity of 90,000 tonnes a year, and it has progressively grown to reach over one million tonnes in 2010, predominantly using its in-house developed D18, D20, CD20, DX, DX+ and D18+ cell technologies. The number of reduction cells and the annual production capacity of these technologies is shown in Table 1. Recent development and results of DX+ and D18+ cell technologies will be described in this paper. DX cell technology started in 2005 with five prototype cells, followed by a 40-cell demonstration potline at Dubal in 2008. The implementation on a large industrial scale was at Emal Phase 1 with two potlines and an initial production capacity of 750 000 tonnes a year DX cells have operated at 385 kA at Dubal since March 2012, and at 380 kA at Emal since September 2012 [1-3]. Five DX+ cells were started in July 2010 at Dubal at 420 kA and are now operating at 440 kA. One potline of 444 DX+ cells is currently under construction at Emal Phase 2. These cells should start production in 2013/14 at 440 kA, and they are designed for a future potential of 460 kA. D18 cells were recently completely redesigned for 210 kA and low energy consumption, resulting in seven D18+ pilot cells. These started up in March 2012 at 200 kA because there is no booster for this group of cells. DX+ cell technology DX+ cell technology is an evolution of the DX technology for high productivity and lower capital cost per installed tonne of capacity [4-5]. Five DX+ Reduction cell technology Amperage (kA) Number of cells Capacity (kt/y) demonstration D18 202 513 284 cells in Dubal D18+ 202 7 4 Eagle Section CD20 250 480 335 are shown in D20 249 528 367 Fig. 1. The key DX 385 40 43 performance inDX+ 440 5 6 dicators (KPIs) Total 1,573 1,039 are given in Table 2. Table 1: Cell technologies at Dubal Fig. 1: Five prototype DX+ cells in the demonstration section at Dubal 18 DX+ cells were designed utilising in-house, commercial software-based mathematical models that were developed in recent years at Dubal. These comprise thermo-electric, magnetohydrodynamics (MHD), mechanical, cell gas exhaust and potroom ventilation models. The models were originally validated on operational DX cells and were re-confirmed on operational DX+ cells [6]. The alignment between the models and measurements is excellent, instilling confidence to use these models for further optimisation and development of Dubal cell technologies. In addition to increased amperage and higher metal production per day, DX+ tech- © Dubal ALUMINIUM · 1-2/2013 ANODE BAKING FACILITIES The Riedhammer anode baking facility is a key component in a modern anode production plant. Our plants offer many advantages such as: Customised design Excellent anode quality WK ² WK 0DUFK %RRWK Extended furnace lifetime Low energy consumption High productivity Flexible equipment supply Safe operation RIEDHAMMER CARBON BAKING TECHNOLOGY RIEDHAMMER GmbH Klingenhofstraße 72 90411 Nürnberg Phone: +49 911 5218 0 Fax: +49 911 5218 231 www.riedhammer.de A L U M I N I U M S M E LT I N G I N D U S T R Y KPI Amperage Current efficiency Metal production Volts per cell DC specific energy Net carbon consumption Fe Si AE frequency AE duration PFC emissions, CO2 equivalent**** Unit Dec 2010 to July 2011 Aug 2011 to Feb 2012 Mar 2012 to Sept 2012 1 Oct 2012 to 21 Nov 2012 kA % kg/pot-day V kWh/kg Al kg/kg Al % % AE/pot-day s 419.6 95.1 3214 4.22* 13.22* 407 0.040 0.028 0.191 9.6 430.2 94.9 3291 4.22** 13.25** 412 0.039 0.029 0.085 10.3 439.7 94.5 3345 4.24*** 13.37*** 404 0.043 0.028 0.071 10.1 440.1 94.9 3366 4.24*** 13.37*** 0.398 0.036 0.026 0.046 10.3 kg/t Al 33 16 13 9 Fig. 2, above: Historical data on HMI 20 Fig. 3, below: Pot voltage trend graph on HMI Table 2: KPIs of Dubal DX+ technology – average of the five cells *Based on 4.35 V actual minus 0.13 V for design changes in the industrial version of DX+ **Based on 4.32 V actual minus 0.10 V for design changes in the industrial version of DX+ ***Based on 4.31 V actual minus 0.07 V for design changes in the industrial version of DX+ ****CO2 equivalent is calculated as in Reference [4], using the Tier 2 method nology has been optimised in many other ways with respect to its sister DX technology. In spite of increased length and width, the mass of the DX+ optimised potshell was reduced by 21% without any reduction in strength, thanks to improved structural characteristics of the design. The cell superstructure height was lowered by more than 400 mm, and in spite of its increased size, its mass was decreased by 12%. The overall volume of the concrete in the potshell and busbar supports was reduced by 35%. Considering the amperage increase to 440 kA, the productivity of potroom in tonnes of aluminium per square metre of covered building has increased by 16% to 7.12 tonnes of aluminium produced per square metre of covered building, calculated for 360 cells and one central passage per potroom. Capex improvement is the result of cell productivity, which is proportional to amperage, and of the higher number of cells per potline corresponding to the higher rectiformer voltage of 2,000 V DC. Further optimisation is under way. The design of DX+ busbars has already been optimised and the results are: decrease of cell centreline distance by approx. 5%, reduction of busbar mass by 20% and reduction of busbar voltage drop by 26%. Reduced cell-to-cell distance increases the building productivity by 4.6%. In Table 1, the actual voltage and the corresponding specific energy consumption have been corrected with respect to demonstration cells to allow for the expected improvements due to design changes in the industrial DX+ cells to be installed at Emal Potline 3. These improvements include larger cross-sections of busbars and cathode collector bars. A substantial voltage gain has been obtained with the introduction of four-stub anodes at the end of 2011 instead of the threestub anodes previously used. This explains a different voltage correction for DX+ industrial cells for the four periods given in Table 2. Excellent performance has been maintained in conjunction with amperage increase. As per tradition at Dubal, the metal purity is excellent in DX potlines at both Dubal and Emal as well as in DX+ demonstration cells at Dubal: the metal’s low iron and silicon content did not deteriorate with amperage increase. Low anode effect frequency and duration result in very low PFC emissions (expressed in CO2 equivalent kg/t Al in Table 1) which are a benchmark within the industry [7]. ALUMINIUM · 1-2/2013 SPECIAL A L U M I N I U M S M E LT I N G I N D U S T R Y the total number to the current 520. Further significant advances in operating performance are limited mainly by poor magneto- hydrodynamic (MHD) stability, by alumina and AlF3 feeding control and by high anode current density. A new cell design, D18+ has D18 Busbar configuration Al2O3 feeding AlF3 feeding Alumina distribution Number of anodes Anode beam control Number of cathode blocks Collector bar – flexible connection End risers Pseudo point feed converted from dual centre breaking 10 kg bags added manually Via crane hopper 18 Pneumatic 17 Bolted D18+ Four side risers with under cell bus Four point feeders with bath sensing breakers Dedicated AlF3 feeder Dense phase system 20 Electric 19 Welded Table 3: Comparison between D18 and D18+ Dubal has developed its own proprietary cell control system, comprising microcomputer based DCCU (Dubal Cell Control Unit) and cell control software. DCCU has been progressively installed since 2005 in Dubal and also in Dubal-licensed smelters, with 1,276 cells equipped as of November 2012. Recently, a new hardware system, based on standard PLC (Programmable Logic Controller), has been developed and installed on the five DX+ demonstration cells. It has been also chosen for Emal Phase 2. Increased Graphical User Interface (GUI) capabilities provide improved and more complete information to cell operators than the original control systems, which were generally text based and black and white. The new Human Machine Interface (HMI) provides the operators access to all required supervisory controls, data entries and information about the cells in the potroom. Two sample screen shots from HMI are shown in Figs 2 and 3. The HMI can also display various trend graphs for a period of 30 minutes to 8 hours (Fig. 3). The PLC data are sent to the potline server, where they are analysed and displayed in the same way as with DCCU based control system. Detailed pot traces and command interface can be obtained from ‘iPots’ system hosted on a network server. In addition, user specified queries can be used in a new web based Smelter Analytics platform developed in-house to provide data in an exportable format to programs such as MS Excel. The new ‘iRPMS’ reporting system, equipped with a web based interface for ease of navigation, provides information to the user from the potlines, carbon plant, casthouse, etc. as well as presenting various types of summary overviews to the senior management. For over 50 years BUSS KE and CP series Kneaders have been D18+ cell technology the benchmark for reliable, cost-effective compounding of The D18 technology is the result of Dubal development of the P69 technology first installed in 360 cells in Dubal in 1979. Subsequent additions brought anode pastes. Now we go one step further. ALUMINIUM · 1-2/2013 A L U M I N I U M S M E LT I N G I N D U S T R Y KPI Amperage Current efficiency Metal production Volts per cell DC specific energy Fe Si AE frequency AE duration (V > 8 V) PFC emissions, CO2 equivalent [4] Unit D18+, 1 June to 21 Nov 2012 D18 Difference kA % kg/pot-day V kWh/kg Al % % AE/pot-day s 202 96.0 1,562 4.08 12.67 0.05 0.02 0.02 32 202 92.3 1,502 4.69 15.14 0.07 0.03 0.44 31 0 3.7 60 -0.61 -2.47 -0.02 -0.01 -0.42 1 kg/ t Al 12 247 -235 tion from D18 to D18+ cell design. Additionally, the original potshell was modified to accommodate two more cathode blocks. Fig. 3 shows the seven test cells. Table 4 gives key performance indicators. The performance of the D18+ cells has now exceeded the original design targets, resulting in significant improvement over the existing D18 cells. The test cells are currently being fully evaluated before implementing throughout Dubal’s D18 potlines. Conclusions Table 4: D18+ and D18 performance comparison. D18+ is average of 5 middle pots DX+ cell technology continues to give excellent performance with considerable amperage increase to 440 kA in DX+ pilot cells. The new DX+ Pot Control System is based upon standard market PLCs, which give increased HMI capabilities and ensure easy maintenance and future development. The successful test and validation of the D18+ cell technology has proven that it is both technically and practically possible to update and replace the cell technology within an existing operating potline. Study of the feasibility and optimal engineering pathway is currently in progress to enable replacing the remaining 513 D18 cells with the D18+ technology. References Fig. 4: Completed seven D18+ test cells in a D18 potline been developed to modernise the original Dubal D18 potlines and to improve their performance and economic competitiveness [8]. The objectives behind modernising the cells through new technology are to reduce the 22 specific energy consumption to below 12.9 kWh/kg Al, reduce the anode effect frequency to below 0.10 per cell-day and to allow for a possible further amperage in-crease of 40 kA. The constraints were: to maintain the same cell-to-cell centerline distance and the same cell height, to keep the amperage availability limits within the same rectifiers and to use the same gas treatment centre. Seven D18+ cells were constructed and successfully startedup in March 2012. Table 3 gives a list of changes made during the transi- [1] Ali Al Zarouni et al., DX Cell Technology Powers Green Field Expansion, Light Metals 2010, 339343. [2] B.K. Kakkar et al., Commissioning of Emirates Aluminium Smelter Potlines, Light Metals 2012, 721-726. [3] Ali Al Zarouni et al., The Successful Implementation of Dubal DX Technology at Emal, Light Metals 2012, 715-720. [4] Ali Al Zarouni et al., DX+ an Optimized Version of DX Technology, Light Metals 2012, 697-702. [5] M. Reverdy et al., Advancements of Dubal High Amperage Reduction Cell Technologies, Light Metals 2013. [6] Abdalla Zarouni et al., Mathematical Model Validation of Aluminum Electrolysis Cells at Dubal, Light Metals 2013. [7] Abdalla Zarouni et al., Achieving Low Greenhouse Gases Emission with Dubal’s High Amperage Cell Technology, 19th International Symposium ICSOBA, Belem, Brazil, 25 Oct. to 2 Nov. 2012. [8] S. Akhmetov et al, D18+: Potline Modernisation at Dubal, Light Metals 2013. Author Michel Reverdy is Technology Transfer manager at Dubal. ALUMINIUM · 1-2/2013 -ARCHs(ENRY"'ONZALEZ#ONVENTION#ENTERs3AN!NTONIO4EXAS53! REGISTRATION IS NOW OPEN FOR TMS 2013 Register Today and Save $100! -ORETHANSYMPOSIAAREPLANNEDINTHEFOLLOWINGAREAS s !DVANCED#HARACTERIZATION-ODELINGAND0ERFORMANCE s (IGH0ERFORMANCE-ATERIALS s ,IGHT-ETALS!LUMINUM-AGNESIUMAND4ITANIUM s -ATERIALSAND3OCIETY%NERGY4ECHNOLOGY0OLICYAND%DUCATION s -ATERIALS0ROCESSINGAND0RODUCTION s .ANOSCALEAND!MORPHOUS-ATERIALS Also featuring... 2013 Enabling Materials Resource Sustainability -AKETHEMOSTOFYOURTRAVELTO3AN!NTONIO7HENYOUREGISTERFORTHECONFERENCE s 3IGNUPFORA#ONTINUING%DUCATIONCOURSEHELDINCONJUNCTIONWITHBUTNOTINCONmICTWITHOTHERCONFERENCEEVENTS s 2ESERVEYOURSPACEAT3OCIAL%VENTSLIKETHE(ONORS!WARDS"ANQUET s "OOKA(OTEL2OOMTHROUGHTHE4RAVELSECTIONOFTHEWEBSITE 4-3+EYNOTE3ESSION )MPURITIESINTHE!LUMINUM3UPPLY#HAIN 4HIS KEYNOTE SESSION WILL INCLUDE INVITED PRESENTATIONS FROM LEADING INDUSTRY EXPERTS THAT EXAMINE THE ROLE AND OUTLOOK FOR IMPURITIESACROSSTHEALUMINUMSUPPLYCHAIN 3CHEDULEDSPEAKERSFORTHEEVENTINCLUDE s 3TEPHEN,INDSAY!LCOA)NC s *AMES-ETSON5NIVERSITYOF!UCKLAND s +ARL"ARTHOLOMEW+"#!DVANCED4ECHNOLOGIES)NC s *OHN'AVIN24!3EBREE s 3TEWART(AMILTON.EW:EALAND!LUMINIUM3MELTERS s -UHAMMAD!KBAR2HAMDHANI3WINBURNE5NIVERSITY OF4ECHNOLOGY s *OHN'RANDlELD'RANDlELD4ECHNOLOGY Register today at www.tms.org/tms2013 A L U M I N I U M S M E LT I N G I N D U S T R Y The ‘AP Technology’ smelter of the future The economical, energy efficient and environmentally safe solution for primary aluminium production S. Fraysse, J.-M. Jolas, F. Charmier and O. Martin, Rio Tinto Alcan An efficient smelter solution is made up of many technological buildings blocks. The degree of interaction between the blocks is quite high and can be complex. Rio Tinto Alcan has not only continuously developed and optimised these blocks; over the years, it has also developed a global approach to its smelter solution. The global approach, code named Global Smelter Design (GSD), is used to design the smelter of the future, building global and coherent solutions based on a functional and cross-cutting view of the plant. The approach has been made even more relevant by new available technologies and products in fields as varied as automation, robotics, data processing, environmental expertise, innovative civil works and new materials. Global smelter design builds upon the first-in-class AP Technology processes and in particular, reduction cells to optimise global development of the smelter solution. use the same generic cell equipment: • AP6X cell, the benchmark of cell productivity • APXe, operating at low energy consumption and the benchmark environmental performance. These two versions will make it possible to deliver optimal solutions for greenfield projects starting in the next few years. The first APXe cell was started in December 2010 and has already delivered very promising results: after less than one year of operation, the 12.3 kWh/kg target has been achieved with very low fluoride emission and at particularly low gas suction rates [1]. More ambitious targets are already planned for the coming months. Some of the innovative solutions developed on the APXe cell can also be deployed in existing aluminium smelters in order to reduce their energy consumption and environmental footprint. An industrial demonstration of AP6X Platform – Jonquiere, Quebec: The Rio Tinto board of directors approved the AP60 Phase The team which has supplied technologies to a large number of aluminium smelter projects over the last 40 years has had a unique opportunity to develop and industrialise the best cells to meet the greatest constraints and challenges. The technical challenge of low energy: After 125 years of operation, Hall-Héroult process cell productivity has improved dramatically through the development of high-amperage cells. However, improvement in energy efficiency levelled off after the seventies. In the coming decades, the challenge of massive demand for aluminium in an energy-constrained future calls for the development of low-energy cell designs. With the different AP cell platforms, Rio Tinto Alcan proposes a comprehensive suite of solutions able to take up this challenge and to adapt to changing market trends. This offer is based on two platforms, AP6X-APXe and AP4X. AP6X – APXe platform: Rio Tinto Alcan has developed two new cell technologies that 24 © Rio Tinto Alcan Reduction cells to support the existing assets optimisation and the smelters of the future AP Technology cells AP Technology, sites in operation and under construction ALUMINIUM · 1-2/2013 .2./$(.!)#$,0'+($)/%*-/&$($/!')#0./-2 !5 343 4 1# !'#0$"!--!-$+#'/!2/ %7 66663 8 A L U M I N I U M S M E LT I N G I N D U S T R Y AP6X – APXe platform 1 project Notice to Proceed on 14 December 2010 following completion of a comprehensive feasibility and business evaluation study. The Jonquiere project is to be constructed in multiple phases to attain a production level of 460,000 tpy. Phase 1 with a capacity of 60,000 tpy capacity is the industrial and commercial demonstration step. The goal is to demonstrate, with the 38-pot section, a commercial operating AP6X potroom, with all the related logistics and operational challenges. The first metal is planned for February 2013, and full production in May 2013. This platform allows us not only to continuously improve the AP6X pot in an industrial and robust way, but also to develop and validate other major improvements such as equipment capabilities, pot oversuction using the JIBS RTA-patented system, potroom ventilation, industrial hygiene and environment performances, and last but not least automation and improved accuracy of the anode change and positioning (‘best anode change’). AP4X platform: The AP4X platform has been developed according to the two same Jonquiere project, potroom 26 streams: high productivity and low energy. This platform supports the retrofit of existing AP3X potlines, and is also a solution for smaller power blocks. The two development streams provide an optimised solution suited to each client with his specific constraints. The first version of the AP4X Low Energy has been developed in collaboration with the Alouette smelter in Canada and the Saint Jean de Maurienne smelter in France. In Alouette [2] a two-year test period resulted in the validation of a brownfield AP4X Low Energy design capable of world-class environment performance in terms of gas emission and cell life. Rio Tinto Alcan is also currently on its way to validating a 12.4 kWh/kg AP4X technology by the end of 2013 in the Saint Jean de Maurienne boosted section. Global approach to a smelter The conventional way of designing a smelter is to consider the smelter as an assembly of process shops linked by roads and logistics services. This approach has not drastically changed in the past decades, as we can see from the layouts of the plants erected during this period. If we change our outlook on smelters, viewing them as global entities, then there are new opportunities for improvement and cost reduction. In addition to developing units, we can deliver an improved global approach. This new way of working has led not only to disruptive innovations in the global management and layout of smelters, but has also allowed processes to be reviewed from this new viewpoint. Some of the innovative solutions developed using this global approach can also be deployed in existing smelters. From a sequential to an integrated design: New reflections and action plans have been implemented so as to manage a global approach and to develop the required elements accordingly. The construction of a global vision of the smelter with clearly defined goals has allowed us to challenge the conventional ‘silo’ approach and to combat the existing paradigms. ‘Open innovation’ is also a key pillar in our approach, including as far as possible, the technologies and solutions that can be transposed from other industries or applications. Global vision is a medium and long-term vision resulting from the existing goals and constraints, based on the aluminium industry context. It is materialised in a holistic highlevel roadmap, based on an e3 approach: ‘energy efficiency’, ‘environment’ and ‘economy’, with a high standard of health and safety. To support this high level vision together with operational goals and steps, we developed a multi-generation plan, giving us previews of the ‘ideal’ new smelter over the coming decades, and the steps in optimising existing assets. Our conventional view of the smelter and how we work were challenged in a variety of ways. For example, if we compare the cost of a smelter not shop by shop but per discipline (concrete, electrical, structural, equipment, etc.), we can see that the global building and roads aspect is more expensive than all the pots put together. Moreover, as this aspect is not part of specific aluminium know-how, this part can be improved with ‘open innovation’ and existing technologies and can be developed quickly. To take the challenge further, we can also compare some basic smelter data such as the cubic metre of concrete or the tonne of metallic structure to benchmark data in other industries or applications, and then analyse the gap and the reasons for the gap. And finally, ‘open innovation’ starts – internally. Integrated teams need not only development people, but also production, HSE, projects, engineering, business improvement and procurement people. Such a team can give a different approach and allow an efficient challenge, finally leading to a global buy-in of all the stakeholders in the chosen solutions. External ‘open innovation’ can provide not only technical ideas and solutions, but also yield new methodologies and ways of working: ALUMINIUM · 1-2/2013 SPECIAL Lean manufacturing and flows in the smelter: Over and beyond the long-standing tradition of numerical simulation and test programs to optimise and increase the reliability of cells, there is room for optimisation of the various flows (materials, pedestrians, vehicles, fluids) and, consequently, of general layout, safety and the environmental footprint. With upward amperage creep and lower energy consumption, this optimisation becomes a critical factor in running a smelter in a reliable and qualityoriented way, and also economically. Lean manufacturing has given us basic principles such as ‘one piece – one flow’. This forms a good starting point to develop a flow management philosophy that delivers the right quantity at the right place and at the right time. With this concept, we consider flows in the smelter as a key activity, thus generating a virtuous circle. We use the required technologies, such as process automation, simulation or data processing, to bring anodes and liquid metal, for example, in a repeatable and safe way, to the pots and to the casthouse as needed. Consequently, on the one hand, we challenge the size of the different transport systems and make savings in smelter infrastructures, while, on the other hand, we increase process reliability, and show that ‘just on time’ is a key enabler for process quality and thus for the environmental footprint. Moving from environmental solutions considered as a cost to environmental challenges seen as opportunities: The traditional way of thinking is to consider environmental control equipment or features as necessary costs. The global environmental function in the typical smelter accounts for 12% of direct costs. If we switch to a mindset where these costs are seen as creating opportunities, if we are ready to challenge the old paradigms, then some basic questions are raised: • Why should creeping of amperage or size of the cell automatically result in an increase in gas suction rate? • Is a FTC dedicated to baking furnaces the only scrubbing option if we accept to change the typical smelter layout and install the baking furnace much closer to the potrooms? One way to answer the first question is to redesign the cell and the suction system with the goal of reducing specific flowrate by 50%. If expressed this way, the objective leads to innovative solutions which, in turn, open out towards other avenues with respect to energy recovery and capex reduction, while also improving environmental performance. With respect to the second question, existing experience shows that there are no ma- ALUMINIUM · 1-2/2013 A L U M I N I U M S M E LT I N G I N D U S T R Y jor technical barriers when considering mixing the baking furnace gases with cell gases and so combining scrubbing in a conventional GTC, thereby optimising costs compared to the standard layout. These are only examples. Low cost over-suction solutions are now also becoming Global Smelter Design, mindset available on the market [3] and other approaches can be investigated H. Rollant, Jet Induced Boosted Suction System for Roof Vent Emission Control: New Developments to improve this business segment. and Outlooks, Light Metals 2012, pp. 551-556 Conclusion Authors The aluminium industry is currently facing increasingly tougher constraints and challenges, whether we look at energy savings, environmental footprint or, over and above all, economic competitiveness. In the coming years, this industry needs to make tremendous improvements and to seek new optimisation methods. Rio Tinto Alcan is proposing the reference solution to successfully take up this challenge. Not only does it possess the best cell platforms for both new smelters and for existing assets optimisation, but it also boasts the only industrial platform of its kind in the world for testing the most recent cells. Over and beyond this strong position, Rio Tinto Alcan is able to integrate its technological building blocks in a global approach where the whole smelter is studied from completely new viewpoints. The AP Technology smelter of the future is a global and comprehensive answer to both existing and future challenges. Sylvie Fraysse joined the aluminium business ten years ago, in process and engineering projects management. She is currently in charge of the Global Smelter Design project. Jean-Michel Jolas has 30 years of aluminium business experience, half spent in various production and process management responsibilities in smelters, and half dedicated to Reduction and Environmental R&D. In his current position, he is managing the Environmental R&D group and activities for the Rio Tinto Alcan primary metal business. In more than 20 years of aluminum business experience, François Charmier has held various managing positions in Technology, Project Management and Execution, and presently in Technology Sales. In his current position, he is leading the Technology Transfer of AP60 to the AAR-CT AP60 Smelter (‘Aluminerie Arvida – Centre Technologique AP60’). Olivier Martin has 25 years of aluminium business experience including various international operational positions in smelters. Since 2005, he is back in Rio Tinto Alcan Technology group as Senior Technology Advisor, head of the Cell Development group. References [1] O. Martin, B. Allano, E. Barrioz, Y. Caratini, A. Escande and N. Favel, Low Energy Cell Development on AP Technology, Light Metals 2012 pp. 569-574 [2] P. Coursol, J. Coté, F. Laflamme, P. Thibault, A. Blais, D. Lavoie and S. Gosselin, The Transition Strategy at Alouette Towards Higher Productivity with a Lower Energy Consumption, Light Metals 2012, pp. 591-594. [3] J.-N. Maltais, M. Meyer, M. Leduc, G. Girault and A combined fume and gas treatment centre 27 A L U M I N I U M S M E LT I N G I N D U S T R Y C. Duwe and T. Letz, FLSmidth Hamburg FLSmidth is a market-leading supplier of equipment and services to the global minerals and cement industries. With more than 15,000 employees, FLSmidth is a global company with headquarters in Denmark and local presence in more than 50 countries including project and technology centres in Denmark, India, USA and Germany. Over the past 130 years FLSmidth has developed a business culture based on three fundamental values: competence, responsibility and cooperation. For the alumina and bauxite industries the company offers complete bauxite handling, storage, crushing, grinding and settling on the red mud side, as well as conveying and storage systems on the white side. Today’s aluminium smelter industry requires the most economical, reliable and environmentally friendly systems in each part of the smelter. The electrolysis cells (pots) in all modern greenfield smelters are already or will be equipped with closed Fig. 1: Process flow diagram, Möller direct pot feeding system complete with Möller Fluidflow pipe air slides 28 pot feeding systems. Brownfield smelters, which still mainly use the open type crane feeding technology, seem more in need of changes to the closed pot feeding system after examining modernisation projects. The Möller direct pot feeding system is an innovative system that ensures constant and reliable feeding of secondary (fluorinated) alumina to each ore bunker of the electrolysis cell. Since the first installations at Vereinigte Aluminium Werke (VAW) in Hamburg, Germany, and at Aluminij Mostar in Bosnia-Herzegovina, the design has continuously been improved in order to fulfill a wide range of requirements. These improvements include a flexibility for use in both greenfield and brownfield smelters. This paper presents the general design and latest improvements of the Möller direct pot feeding. This system will be installed in the Emirates Aluminium (Emal) Phase 2 greenfield project in Taweelah, Abu Dhabi, and in a brownfield project at Alcasa in Venezuela. General description The vent air from the electrolysis cells is evacuated via gas ducts to the Gas Treatment Centres (GTC) where primary (fresh) alumina absorbs many of the emissions. During this cleaning process the primary alumina becomes secondary alumina and is stored in silos, near the potrooms respective GTCs. From the secondary alumina silos the direct pot feeding system transports the secondary alumina pneumatically to each of the electrolysis cells. The fully automatic and absolutely dust-free feeding process can be either continuous or discontinuous, and it works independently from the potroom cranes. The smooth-working Möller direct pot feeding system combines the ‘Möller Turbuflow’ dense phase and ‘Möller Fluidflow’ pipe air slide transport system to take the secondary alumina from the storage silo to distribution pieces at the electrolysis cells. From there the Möller Fluidflow pipe air slide feeding system takes alumina to each of the ore bunkers of the electrolysis cells. The Möller Turbuflow dense phase conveying and the Möller Fluidflow pipe air slide are both well proven transport technologies which have established itself because of its superior performance record. Highlights of the Möller direct pot feeding system complete with Möller Fluidflow pipe air slides are: • Highest possible performance and reliability of continuous feeding of the electrolysis cells for almost all kinds of secondary © FLSmidth Möller Möller direct pot feeding system for greenfield and brownfield smelters ALUMINIUM · 1-2/2013 SPECIAL • • • • • • • • • • or primary alumina qualities by Möller Fluidflow pipe air slide Gas-tight pot feeding system by Möller Fluidflow pipe air slide (no dust emission from flange connections) No generation of fines, no segregation and no scaling Lowest possible (over-)pressure Self-regulating system by filling level in ore bunkers of cells Works independently of any slight overpressure or slight under-pressure in the ore bunkers of the electrolysis cell Quickest possible (emergency) refilling of the ore bunkers of the electrolysis cells by Möller Fluidflow pipe air slides and high performance fans or blowers (0.1-0.2 bar) Lowest possible emission to GTC gas duct No pulsation in the Möller Fluidflow pipe air slide along the potroom and on top of each cell Independent of the filling level of the buffer silo Minimised energy consumption. Low fluidising air amount and energy A L U M I N I U M S M E LT I N G I N D U S T R Y consumption by use of frequency controlled fans or blowers • Minimised maintenance work as well as minimised amount of spare parts. Functional description and design features Silo discharge including material trap: The secondary alumina is discharged via Möller rotary flow control valve and Möller Fluidflow pipe air slide, generally from the secondary alumina silo at the GTC, and transported to the so-called main bin. A specifically designed material trap is installed to avoid any foreign particles entering the direct pot feeding system. In greenfield aluminium smelters, vibrating screens Fig. 2: Möller rotary flow control valve and material trap A L U M I N I U M S M E LT I N G I N D U S T R Y Fig. 4: Möller distribution pieces and vent dome Fig. 3: Möller Fluidflow pipe air slide from secondary alumina silo to potroom wall; main bin and Möller Fluidflow pipe air slide along potroom (Dubal) in the GTC system already remove most of the coarse material (e. g. from scaling effects). However, in brownfield aluminium smelters the existing installation situation may not have enough space in which to install vibrating screens. To address this, FLSmidth enhanced the design of the material trap in order to include the process function of a vibrating screen. The Möller direct pot feeding system can generally be installed at every brownfield smelter presently operating with a crane feeding system. Main bin: The main bins – normally one main bin is used for each half of a potroom – are located right next to the potroom wall. The main bins are always 100% filled, and the resulting material column ensures a continuous mass flow of secondary alumina to all electrolysis cells, especially to the last cell at the end of the Möller Fluidflow pipe air slide along the potroom. Because of the well-defined height of the main bin, the Möller direct pot feeding system is independent of the filling level of the secondary alumina silo. Whether the secondary alumina silo is full, half full or nearly empty, the conveying capacity of the Möller direct pot Fig. 5: Single-feed design … 30 feeding system stays the same. Given the sufficient height between the outlet flange of an existing secondary alumina silo and the superstructure of the electrolysis cell, then the Möller Fluidflow pipe air slide can also be installed along the potroom with an appropriate declination (downhill slope) without a main bin. Distribution pieces and vent domes: From the main Möller Fluidflow pipe air slide along the potroom the secondary alumina is transported via the distribution pieces into the potroom, and then to the electrolysis cells. According to the design requirements, a sufficient number of vent domes will be installed on top of the distribution pieces. All necessary venting domes are connected to the gas duct of the GTC. Each of the above described distribution pieces can be connected to one (single-feed), two (double-feed) or even more electrolysis cells (multi-feed), as per customer requirements resp. installation situation. Superstructure design requirements: Each superstructure is specially designed as part of the electrolysis cell’s technology. Generally, the state-of-the-art electrolysis cell technologies already ensure sufficient space for a direct pot feeding system. However, clients have different requirements regarding free access for crust breakers, dosing devices and the option for removing the ore bunkers during operation, and these factors influence the final design of the Möller Fluidflow pipe air slide to be installed on top or inside of the superstructure of the electrolysis cell. The self-regulating and continuous filling process of the ore bunkers of an electrolysis cell by the Möller direct pot feeding system is simply ingenious. If the ore bunker is full, then the material cone level has reached the filling spout discharge opening of the Möller Fluidflow pipe air slide, and the mass flow is blocked automatically. As soon as secondary alumina is removed from the ore bunker of the electrolysis cell, the pneumatic transport starts again automatically and ensures a constant and reliable mass feed rate to the pots. The fluidising of the secondary alumina inside the Möller Fluidflow pipe air slide works permanently to ensure a constant bulk density. Fluidisation air equipment: The fluidisation air requirements for the Möller Fluidflow pipe air slide along the potroom and on top of the electrolysis cells are different in regard to the fluidisation air pressure and the specific fluidisation air amount. Therefore, the Möller direct pot feeding system uses two different fluidisation air sources which can either be frequency controlled rotary piston blowers Fig. 6: … and double-feed design of the Möller direct pot feeding system ALUMINIUM · 1-2/2013 SPECIAL A L U M I N I U M S M E LT I N G I N D U S T R Y ered by FLSmidth Hamburg when the Möller direct pot feeding system was introduced at VAW in Hamburg in 1997, and at Aluminij Mostar, Bosnia-Herzegovina in 2001. In particular, the latest contracts for Emal Phase 2, Abu Dhabi (greenfield), and Alcasa, Venezuela (brownfield), have proven the system’s high Conclusion adaptability with great success. This system is designed to ensure a conThe necessary flexibility of a closed pot feeding system to serve greenfield and brownfield stant and a reliable feed into the ore bunkers aluminium smelters had already to be consid- of the electrolysis cells at the highest possible standard. The lowest possible conveying velocities preserve the particle size distribution as well as the flow ability of the secondary alumina without any scaling effects. This most competitive system is superior by minimising wear and maintenance as well as energy consumption, Fig. 7: Variable design of the Möller Fluidflow pipe air slide on top or inside and last but not least of the electrolysis cell or fans. This design allows minimised energy consumption during operation down to the necessary minimum amount as well as minimised fluidisation air vented into the GTC’s gas duct. ALUMINIUM · 1-2/2013 Fig. 8: Self-closed filling spout and filling process of the ore bunker 31 A L U M I N I U M S M E LT I N G I N D U S T R Y 2007 Rusal/Hydro, Boguchany Aluminium Smelter greenfield 672 RA300 pots, 200 kg/h/pot (double-feed), potroom length 1,050 m by its high operating reliability. In close co-operation with clients around the world, FLSmidth Hamburg has offered and contracted various tailor-made solutions for the use of a Möller direct pot feeding system. Please contact the authors for more detailed information or to obtain support regarding specific projects. 2007 Rusal, Taishet Aluminium Smelter greenfield 672 RA400 pots, 200 kg/h/pot (double-feed), potroom length 1.050 m Authors Contract Client Smelter Type 2001 Aluminij Mostar brownfield 2006 Dubal, Potline 8 IMIDRO, Hormozal Aluminium Smelter greenfield 2007 greenfield System description 256 pots, 130 kg/h/pot (double-feed), potroom length 600 m 40 DX pots, 210 kg/h/pot (double-feed) 228 D20 pots, 170 kg/h/pot (double-feed), potroom length 720 m 2012 Emal, Phase 2 greenfield 444 DX+ pots, 480 kg/h/pot (single-feed), potroom length 1,520 m 2012 CVG Alcasa, Potline 3/4 brownfield 400 pots, 480 kg/h/pot (single-feed), potroom length 700 m Tab. 1: Möller direct pot feeding system references in operation or under construction; all secondary alumina Dipl.-Ing. Carsten Duwe is head of Technical Department and Dipl.-Ing. Timo Letz is area sales manager of FLSmidth Hamburg GmbH, based in Pinneberg, Germany. Contact: carsten.duwe@flsmidth. com; timo.letz@flsmidth.com Cathode producer shows its metal © Carbone Savoie M. Casasole, Carbone Savoie Carbone Savoie’s plant in Notre Dame de Briançon Aluminium has been one of the mainstays of industrial production for several decades. It is one of the most plentiful elements on earth, and its lightness and strength makes it ideal for many applications. The production of aluminium involves electrolysis, and creating increasingly better technology for the aluminium producers is the specialty of Carbone Savoie. Carbone Savoie is one of the worldwide leading manufacturers of cathode products, the design and production of cathode blocks, graphitised blocks, sidewall blocks and ramming paste. The company’s unique graphitised block has given it a significant competitive edge over its nearest rivals. Since 2010, Carbone Savoie provides a new generation of ramming paste NeO2. Unlike the previous pastes and unlike all other pastes of the market that contain toxic com- 32 pounds, NeO2 is a 100% clean ramming paste. This first 100% clean ramming paste contributes towards huge progress to the aluminium production, and it guarantees a clean and safe environment for our customers’ and own employees. Despite short terms uncertainties, the basis for aluminium growth remains strong. Ramming paste, sidewalls and cathode blocks will be part of this trend. Success for Carbone Savoie is underpinned by its excellent reputation. A decisive factor is the long life of its cathodes. The concern ploughs a significant part of turnover back into research and development. Carbone Savoie sees its clients more as partners than customers, and so offers consulting and advice throughout the lifetime of the cathodes which it supplies. Naturally, in such a technologically advanced field, R & D is carried out in close co-operation with technical departments of universities and other research organisations. Carbone Savoie’s long-term strategy is to improve sustainability, and to deliver sales commitment, as well as to develop both the organisation itself and to extend the skills of its staff. Steps will be taken to ensure long-term profitability by closely watching aspects like product mix, production costs and pricing mechanisms. It is our vision to let our actions NeO2: the first 100% clean be directed by re- ramming paste spect for the environment at all levels. We strive to remain the commercial and technological leader in our business fields. We aim to remain the most reliable company operating in the market today and to be the manufacturer of the best products that money can buy. Some of our profits will continue to be directed back into research and environmental protection. It is what our customers expect from us in what is a constantly changing world. The company is anticipating and going beyond expected new regulatory requirements and is running a project to study further ways of treating all fumes released by the plant. With its outlook towards technological innovation and environmental sustainability, Carbone Savoie is set for a bright future. Author The end product, a cathode block, ready for delivery Matthieu Casasole is sales and marketing director of Carbone Savoie, based in Vénissieux, France. ALUMINIUM · 1-2/2013 SPECIAL A L U M I N I U M S M E LT I N G I N D U S T R Y Alumina refinery Outotec’s process and implementation solution In retrospect, it is hard to say whether Austrian chemist Karl Josef Bayer knew how significant his two patents – A process for the production of aluminium hydroxide and The pressure leaching of bauxite with NaOH to obtain sodium aluminate solution – would be for the future alumina industry when he filed for them in 1888 and 1892 respectively [1]. However, it is clear that within two years of obtaining his patents, the first industrial alumina plant was commissioned in 1894 in Gardanne, France for Société Française de l’Alumine Pure. The plant’s capacity, 1.5 tonnes per day, was very small compared to current plant capacities: newly implemented alumina refineries range between 1-2 million tonnes of alumina per year. Implementing an entire alumina refinery In addition to the costs for an alumina refinery, investments are also needed for various infrastructures such as railroads, harbours, roads and villages. Most investors usually rely on the traditional front end loading (FEL) methodology for capital project planning. It involves four phases with a decision gate after each phase. The order of magnitude, pre-feasibility and basic engineering phases are commonly known as FEL 1, 2 and 3, and these are generally contracted with a technology-independent engineering contractor. In contrast, FEL 4, or project implementation, is done with an EPCM contractor. At first glance, this appears to be the best implementation model in terms of low capex costs, since it allows to combine a variety of sub-process solutions, and it ensures maximum competition among the technology/equipment suppliers as well as among the engineering/EPCM contractors. However, a quick review of some recent projects utilising the EPCM model shows that many of interfaces in these complex projects – both from a technological and management perspective – have suffered significant delays to implementation schedules as well as tremendous cost overruns. Focussing on separate process units instead of on a comprehensive optimised process solution often creates operational problems, and can transform initially viable ‘solutions’ into a customer’s ‘problem’. With an EPCM contract, the absence of a comprehensive implementation approach and of ALUMINIUM · 1-2/2013 © Outotec M. Missalla, A. Scarsella and A Koschnick, Outotec Fig. 1: A tradition of demonstrating industrial plant expertise over the last century process guarantees leads to problems where customers find themselves having sole liability. Thus, the EPC/turnkey approach for the core process area, where competent technology solution providers are involved at an early project stage, is increasingly favoured by the industry where the first projects in alumina were contracted using this model. Outotec’s mission is to be a leading provider for sustainable process life cycle solutions. Its ability to offer turnkey project implementation with full implementation and process guarantees makes the company a preferred choice for the industry, allowing customers to focus on their core business. Providing life-cycle technology process solutions to the alumina industry With a track record of successful EPC/turnkey project implementations going back several decades, Outotec has a unique value proposition: it offers integrated engineering, project and risk management, which aggregates value to a customer’s investment in terms of • Optimised, sustainable process solutions • Guarantees for implementation within schedule and budget • Guarantees for final product quality, capacity and consumption figures • Best value for investment. Fig. 2 : The Bayer cycle 33 A L U M I N I U M S M E LT I N G I N D U S T R Y Fig. 3: Alumina refinery layout With an EPC contract, customers hand over a significant portion of their investment risks to the contractor. Outotec has structured its organisation to control and cope with these risks: within its technology competence centres, process and engineering disciplines are integrated using the latest design tools available. With a global procurement organisation and a network of approved manufacturers, not only does Outotec have access to the most cost-efficient supply chain, but it also has the flexibility to react to any surprises which suddenly appear on the market. Additionally, Outotec’s project management teams work with the latest management tools and procedures for scheduling, cost control, document control quality and HSE management. But what really brings excellence to this organisation is Outotec’s experienced staff – with an average age of 40+, most of the company’s professionals have at least 15 years of experience in industrial projects. Proof of this technology and project execution excellence is supported by extensive reference lists of successfully implemented LSTK contracts and plants operating with benchmark parameters for productivity and sustainability. The Bayer process Fig. 4: Temperature profile of the Bayer circuit Fig. 5: Autoclave digestion train [2] 34 The Bayer process is a highly integrated grinding, leaching and recovery process. Ground bauxite is dissolved (digested) at a high temperature in a highly concentrated solution of sodium hydroxide more commonly known as ‘caustic’. The next step involves other bauxite components which do not digest and which are separated by a thickening and security filtration step before being washed and then stored as red mud. The alumina-rich solution is cooled and the aluminum tri-hydrate is precipitated from the solution. The alumina-depleted caustic solution next undergoes evaporation, so increasing the caustic concentration, and is recycled back to digestion, thus closing the Bayer cycle. The aluminum tri-hydrate is filtered, washed and finally thermally treated resulting in calcined aluminum oxide as a product (Fig. 2). Estimating a refinery’s correct capital is not restricted to basic tankage, and the budget for major equipment or civil requirements also includes interconnecting piping, conveyors and roads. In addition to the total capital expenditure, the operational expenditure must also be clearly understood and optimised during the designing and implementation of your alumina refinery. This, in turn, helps determine future refinery profitability and the payback period. ALUMINIUM · 1-2/2013 © !& % % $ &$$ $ &$%" !"% #%!&$$& ! % !& $ $ $$$ !!& % %$! ddilisa@innovatherm.de $'!&'"& A L U M I N I U M S M E LT I N G I N D U S T R Y Fig. 7: Basic flow chart for seawater neutralisation of red mud [4] Fig. 6: Tube digestion [3] It goes without saying that the aim of every refinery is to become a low-cost producer, and so must examine the major factors influencing the first-quartile costs: • Proximity to the bauxite mine • Proximity to a deepwater harbour • Low energy cost • Low soda cost • Low energy, caustic and lime consumptions. The first four factors depend on the location selected as well as on available infrastructure. The final factor depends on the bauxite mineralogy and on selection of the technology to be applied. Fig. 4 shows the bauxite entering the grinding step at ambient temperature, where it is then mixed with the spent liquor. The ground suspension is heated to its digestion temperature, which is determined by the bauxite’s composition: gibbsitic bauxites need low temperatures, while boemitic bauxites require higher temperatures. The digested slurry is then rapidly cooled and the green liquor (alumina-rich solution) is separated from the red mud. In the same figure, heat recovery is maximised so as to minimise the addition of live steam needed to bring the fresh slurry to the required digestion temperature. A similar principle can be seen when the incoming green liquor is indirectly cooled with outgoing spent liquor prior to precipitating alumina tri-hydrate in the next stage. The hydrate is then fed to the calcination stage. The figure also makes it easy to distinguish between the white and red sides of an alumina refinery production site. venture with Hatch – HOT (Hatch Outotec) – can supply the entire digestion tool box. The joint venture focuses on designing and developing integrated tube digestion and evaporation solutions using single-stream heating in jacketed pipe technology. This allows you to efficiently recover the heat in the digested slurry. Fig. 6 shows the slurry as it is heated to the digestion temperature and then held for a time in tube reactors to meet the reaction requirements. Next, the slurry is flash cooled in stages to near- ambient pressure, while using the heat from vapour to the pre-heat incoming slurry in counterflow. The water vapour transfers its heat to the slurry as it condenses on the outside shell of the jacketed pipes. Red mud disposal: sea water neutralisation The residue from the Bayer process – more commonly known as red mud – still has a high alkaline content and must be neutralised. Fig. 7 illustrates the basic flow chart for neutralisation by magnesium in the sea water. The mud / seawater mixture is held in a reactor so that the caustic is chemically neutralised. The hydrotalcite-rich mud and magnesium-deficient seawater are then decanted using a conventional clarifier. The supernatant magnesium-deficient seawater with the correct permits is now suitable for environmental discharge. The small facility shown in Fig. 8 can treat the entire rate of red mud production from a refinery producing four million tonnes of product per year to environmentally acceptable levels. The magnesium actively reacts with the liquor phase components of red mud; namely aluminum and hydroxide ions. During the neutralisation process, the dissolved magnesium levels drop from approx. 1,200 mg/l to around 300 mg/l and the aluminum level drops to less than 5 mg/l. These net reductions of magnesium and aluminum are the Digestion and evaporation The appropriate equipment for digestion must be selected based on the kinetics of the digestion reactions, bauxite type and target heat recovery. Available technology for the digestion process includes autoclaves and tube digestors, which are selected according to throughput, number and size. Outotec’s joint 36 Fig. 8: Neutralisation facility [4] ALUMINIUM · 1-2/2013 *$&%! !" ( %#%!! %" #"!% ! ! !! ##"" %%! ! !!! % % " ! & ! ' #%# " %!! " %$&%! ! " " ! , #+# & ) ! % A L U M I N I U M S M E LT I N G I N D U S T R Y result of their precipitation as insoluble salts, forming hydrotalcite as a product. performance in terms of separation efficiency and particle breakage, and thus by extension, for the overall performance of the calciner. Calcination References The average energy consumption in the calcination processes for an alumina refinery globally exceeds 3,100 kJ/kg of alumina. Outotec calcination technology has reduced this figure to about 2,800 kJ/kg of alumina. In fact, Outotec was recognised with an honourable mention from the German energy agency Dena in 2010. Additionally, Outotec can provide numerous references for its calcination technology. Cyclones are an integral component of a circulating fluidised bed (CFB) calciner and a key element for efficient heat recovery with a minimal impact on product quality. The typical CFB calciner layout includes five cyclones, each customised to the prevailing process conditions. The cyclone’s geometry is critical its [1] F. Habashi : Bayer’s Process for Alumina Production: A Historical Perspective, Bull. Hist. Chem. 17/18 (1995), p. 15-19 [2] B. Haneman, A. Wang: Optimising Flash Tank Design for the Alumina Industry. 9th Alumina Quality Workshop (2012) p 127-131 [3] A. Wang, B. Haneman, C. Coleman: Pressure Surge Mitigation at High Temperature Tube Digestion Facility of Yarwun Alumina Refinery. 9th Alumina Quality Workshop (2012) p 132-137 [4] A. Scarsella, T. Leong, B. Henriksson: A Novel and Environmentally Friendly Process for the Treatment of Bayer Process Residue. 9th Alumina Quality Workshop (2012) p 171-175 Authors Michael Missalla heads the Light Metals/Fluidised Beds business line at Outotec. He has designed several processes for a variety of metallurgical applications. His PhD topic was ‘Calculation method for highly loaded cyclones’. He also has experience in chemical plant operations, process engineering, R&D, as well as in training and development. Alessio Scarsella heads the Alumina Refinery group at Outotec Germany and has extensive experience in combustion and alumina refining. He has an MBA from Deakin University and a PhD in chemical engineering from the University of Adelaide in fluid mechanics and combustion. Dr. Scarsella has held process and senior project leading positions in the alumina industry, where he developed fundamental and operational expertise in refining alumina from bauxite. He has also executed major greenfield refinery projects. Andreas Koschnick is Outotec’s director for Solution Sales Latin America. He holds a degree in industrial engineering and began his career with Lurgi in project management for the Leuna petrochemical refinery, which was the largest industrial project in Europe. As a former general manager of a construction and engineering company in Brazil, he was responsible for the implementation of major industrial projects in the energy and metallurgical sector. Fives Solios – 30 years of experience in fume desulphurisation A. Courau, Solios Environnement geographic locations. This article reviews all Formerly Procedair, Solios Environnesolutions already considered and exploited for ment has supplied turn-key plants for SO2 treatment without seawater. fume desulphurisation dedicated to many different industrial applications, such as diesel motor production, Application Process paper fabrication, sulphuric acid production, anode baking furnacMethionine production for Wet-scrubber (packing) es, electrolysis reduction gases, animal food industry (France) Reagent: caustic soda or waste incineration. Today, Solios Environnement’s know-how Desulphurisation on two Semi-wet scrubber in desulphurisation processes diesel engines of 5 MW with Reagent: lime milk heavy fuel oil (Spain) mainly applies to electrolysis pot Desulphurisation on two coalgases or to anode baking furnace Enhanced all dry-scrubber fired stoker-type boilers fumes of primary aluminium Reagent: lime (Virginia, USA) smelters. Relying on its long-standing experience, Fives Solios is now a privileged partner for the design of SO2 scrubbers. Indeed, after studying all parameters of a project and evaluating all available technologies, Solios Environnement is able to propose tailor-made solutions in which its efficient SO2 units combine various processes and meet perfectly its customers’ needs. While projects that are located near the sea can benefit from using seawater in wet scrubbers, various other solutions are available in other 38 Aluminium electrolysis potline (USA) Waste incineration (England) Desulphurisation on six diesel engines of 12,5 MW with heavy fuel oil (Philippines) Paper wastes incineration (Australia) Black liquor furnace on ammonium bisulphate process (France) Like many existing technologies, Fives Solios’s desulphurisation treatments commonly use a calcium reagent (limestone, lime, lime milk), Technical data available 78,000 Nm3/h at 320 °C Max inlet value: 3,000 mg SO2 / Nm3 Outlet guaranteed value: 300 mg SO2 / Nm3 Measured values: 30-200 mg SO2 / Nm3 2 x 33,300 Nm3/h at 190 °C Efficiency DeSOx: > 91% 30,000 Nm3/h at 250 °C Efficiency DeSOx: 92% Wet scrubber (pulverisation) Reagent: sodium carbonate (Na2CO3) Dry scrubber Reagent: lime With Conditioning towers 637,000 Nm3/h at 65-93 °C Inlet concentration: 370 mg SO2 / Nm3 Outlet concentration: 15 mg SO2 / Nm3 4 x 125,000 Nm3/h at 165 °C Inlet value: 400 mg SO2 / Nm3 Outlet guaranteed value: 50 mg SO2 / Nm3 Wet-scrubber (pulverisation) Reagent: caustic soda 2 x 215,000 Nm3/h at 380 °C Efficiency DeSOx: > 70% 90 000 Nm3/h at 175 °C Max inlet value: 1,260 mg/Nm3 Outlet guaranteed value: 85 mg/Nm3 Measured values: 26 mg/Nm3 Efficiency DeSOx: 98% 143,000 Nm3/h at 185 °C Wet-scrubber (pulverisation) Inlet value: 10,000 ppm (28 g SO2 / Nm3) Reagent: ammonium Outlet values: 200-400 ppm (560-1,120 mg SO2 /Nm3) bisulfite Efficiency DeSOx: 96% Enhanced all dry-scrubber Reagent: lime and activated carbon Table: Characteristics of various references ALUMINIUM · 1-2/2013 © Fives Solios SPECIAL Fig. 1: Enhanced all-dry scrubbing process Fig. 2: Semi-wet scrubbing process A L U M I N I U M S M E LT I N G I N D U S T R Y based on the following chemical reaction: Ca(OH)2 + SO2 → CaSO3 + H2O. Other compounds such as ammonium bisulfite or activated carbon (which has a valuable adsorption capacity) can also be used. SO2 treatment processes can be classified into four main families : Dry scrubbing: Fives Solios’s all-dry scrubbing process uses the Venturi reactor coupled with a pulse jet fabric filter. The vertical reactor provides intimate contact of gas with a solid reagent. Reagent recirculation maximises pollutant elimination, and therefore reduces spikes at the stack. Acid gas removal is achieved in the filter by reaction in the filter cake with the unspent reagent. This process is operationally simple, easy to maintain and a low energy consumption. Enhanced all-dry scrubbing: The addition of a conditioning drum to the dry scrubbing process enables the reagent to be moisturised before being injected into the reactor. Water evaporation cools the flue gas, creating ideal conditions for SO2 removal – ideal reaction temperature, lowest reagent surface temperature and more humidity at the point of reaction – which results in an increased surface area for chemical adsorption. This process was developed by Procedair in the 1980s, and it is particularly suitable for high efficiency in SO2 removal. Semi-wet scrubbing: Fives Solios’s semiwet scrubbing process treats acid gases in a spray dryer coupled with a pulse jet fabric filter. The reagent (e. g. lime milk) is dispersed into fine droplets to extend its contact area with SO2. Desulphurisation is controlled by the reagent flow, while the water flow enables temperature control of the fumes. This process allows rapid response to variations of inlet pollutant levels and can so control high acid gas concentrations. Wet scrubbing: The reagent is dissolved and put into contact with SO2 either by pulverisation into the gas stream or by spraying water on packing, which has a shape which ensures high contact area between liquid and gas. Pulverisation scrubbing can reach higher efficiency than packing scrubbing in a dusty atmosphere. Packing generally requires to be protected from dust; this is achieved by locating the scrubber downstream of the filter. Solios Environnement has successfully applied these solutions; some references to various projects are listed in the table. Author Fig. 3: Pictures of wet scrubbers (methionine production – catalyst regeneration) ALUMINIUM · 1-2/2013 Alix Courau is a process engineer at Solios Environnement, located at St. Germain en Laye, France. 39 A L U M I N I U M S M E LT I N G I N D U S T R Y History of intensive mixing for carbon paste B. Hohl, Eirich Anodes for primary aluminium smelting The world’s production of primary aluminium reached approximately 44 million tonnes in 2012, of which about 90% (39.6m t) were produced in modern factories with so-called prebaked anodes. The remaining 4.4 million tonnes come from older works with Soederberg technology. The requirement for anode paste is therefore about 21.7 million tonnes for prebaked anodes and 2.5 million tonnes for Soederberg anodes. Due to the high throughput rates together with the constant formulas, continuous preparation systems are used almost exclusively for carbon anode paste preparation. More than every second prebaked anode is produced from partially or completely intensively prepared paste (Eirich remixer-cooler, resp. Eirich Mixing Cascade EMC). So, the use of intensive mixers for the preparation of anode paste has become state-of-the-art in the primary aluminium industry. Remixing and cooling of anode paste 40 Already in the 1970s, individual intensive mixers were used as continuously operating coolers for anode paste. In the Netherlands and in Bahrain for instance, the breakthrough of this technology began around 1990, followed by two more machines in France and Australia. Preceding this were extensive test series at the Pechiney works in Sabart (France). At that time, the customer was looking for a paste cooler of high performance and efficiency. With the continuously operating Eirich intensive mixer, Pechiney found a machine which not only coped reliably with this task definition but additionally achieved excellent homogenisation of the paste. By direct addition of cooling water and its immediate evaporation, the mixer achieved paste cooling capacities never reached before. On top of that is the effect of a more or less ‘cost-free’ homogeniser: the relatively long retention time of 4-5 minutes, with the intensive mixing effect and the additionally introduced mixing energy of approx. 4 kWh/t, together generate a considerably improved paste quality compared to single-step preparation [2]. All these factors are the reason that in the last 15 years hardly any single-step paste preparation lines were built. In the same period, numerous existing plants were retrofitted with Eirich intensive remixer-coolers. The installation of an additional machine into an existing building often posed a great challenge to the engineers. In the end, they always found a solution to integrate the machine. The effect of the Eirich cooler becomes especially apparent when retrofitting into existing lines, because here the improvement in preparation quality is easy to prove. Advantages • Thanks to the cooler operating in a second mixing stage, the hot mixing temperature is freely adjustable independent of the forming temperature • Long retention time and intensive energy input provide excellent mixing of the paste • Thus, essentially more stable paste quality; parameter variations are reduced to less than 50% of previous scatter range • Agglomerate-free paste with constant temperature • Additional mixing energy raises paste quality • Higher green and baked anode density improve anode strength • Lower electric resistivity of the anode improves electrolysis efficiency • Clearly reduced porosity and optimised pore structure improve anode life • Lower chemical reactivity reduces anode burn • Possibility of increasing the performance of the complete preparation system to a certain extent. High-performance remixer-coolers have been installed recently, for instance at Alcoa Mosjoen / Norway, Qingtongxia/China and Emal 1+2 / Abu Dhabi. All-intensive preparation of anode paste The successful use of the intensive mixing principle for paste cooling was the initiation for the development of the Eirich Mixing Cascade (EMC). Two series-connected intensive mixers perform both hot mixing of coke and binder pitch, plus subsequent remixing and cooling. The special advantages of the Eirich intensive mixer, such as low capex and opex, short standstill periods on the occasion of wear-related repairs, long retention time, com- © Eirich Carbon paste is used in many different fields of the heavy industries, for instance, as anode or cathode blocks for primary aluminium smelting, as graphite electrodes for electric arc furnaces, as carbon bricks for refractory linings, as Soederberg electrodes for reduction furnaces, etc. Over many decades, slowly running batch mixers have been the only useful aggregates for the preparation of such products. For anode paste a continuous preparation process became established later which was based on one or two continuous kneaders arranged downstream. In the seventies of the last century, the intensive mixer started on a triumphal march through this industry. Starting with individual machines for continuous remixing and cooling of anode paste as well as batchwise preparation of various carbon bodies, the intensive mixer constantly opened up new fields of application in the carbon sector. Due to its special benefits, such as high efficiency and an attractive cost/performance ratio, the intensive mixer can be found everywhere in the carbon industry today. This paper describes the most important characteristics and applications, from the beginnings until today. Fig 1: Eirich intensive mixing principle Fig 2: Paste quality improvement thanks to the second mixing level ALUMINIUM · 1-2/2013 ! " # $%& '()) * + ' ) ), -.+ % " / ') + A L U M I N I U M S M E LT I N G I N D U S T R Y Anode paste with high coarse and fine porosity (continuous kneader) Anode paste with low porosity and evenly coated coke particles (continuous kneader + Eirich mixing cooler) Fig. 3: Green paste porosity as an indicator of mixing efficiency [1] pensation of short-term variations in paste composition, especially efficient and thus moderate energy input, etc. come into their own. On top of that, the machines are available for a wide range of throughput rates, so that even most modern smelters with more than 600,000 tonnes a year of aluminium production can be supplied from an anode plant with just one single preparation line. After the triumphant start of a pilot system in a Swiss aluminium smelter, and following comprehensive tests in Norway, it took about ten years to commercialise this new idea successfully. After launching a comparatively small plant in Cameroon in 1998 [8, 9], the breakthrough occurred in 2003 with the sale of three plants to several customers in China [3] In the meantime the EMC has gained ground in India as well as in the Persian Gulf. At the Qatalum greenfield smelter the magical limit of 60 t/h was achieved in one single line for the first time. Fig. 4: Conventional two-step paste preparation 42 The concentration on only one preparation line, even for extremely large anode factories, is based on economic reasons, which require a system with maximum reliability and high availability, but in parallel with short downtimes for maintenance work. Thanks to decades of experience, an in-house production of high quality standards, and a worldwide service organisation, the EMC systems reach the same performance as the well-known Eirich remixer-coolers. Meanwhile, there are 14 EMC lines under construction or in operation. products is performed entirely batchwise. Especially the so-called Ultra High Power (UHP) qualities for graphite electrodes with large diameters require an optimally prepared press body. The very fact that up to three months elapse between paste mixing and the quality control of the final product, shows the high cost of uncertain quality in such a process; with the mixer being one of the key elements. A lot of manufacturers are using Eirich highperformance compact systems because they need this reliable quality. Optimisation of the three important process steps In the mid-1980s, Eirich was able for the first time to replace a series of conventional batch mixers of an Austrian graphite electrode manufacturer by one single Eirich high-performance mixer. The new batch preparation system used the following principles: • Separation of dry substance heating and mixing process • Application of a direct electric coke heater of high performance Carbon products for other metallurgical purposes Intensive mixers have been successfully used for manufacturing graphite electrodes for electric arc furnaces, cathode blocks for primary aluminium smelting [4] and carbon blocks for linings of blast furnaces. Based on the given task definition, the paste preparation for these high-quality final Fig. 5: Eirich Mixing Cascade EMC Fig. 6: 35 t/h paste plant at Aostar/China [3] ALUMINIUM · 1-2/2013 SPECIAL Fig. 7: 36 t/h paste plant at Sohar/Oman [5] • Application of an intensive mixer-cooler with only 15 minutes batch processing time • Storage of the prepared paste in a special silo (table feeder) to make the mixing process independent from the press operation. This allowed the customer to replace numerous conventional mixing systems by one single Eirich line. This not only reduced the maintenance effort by about a third, but also significantly improved the mixing effect itself compared to the existing sigma blade kneaders. Advantages • Fully electric coke heating equals the most elegant solution on the market A L U M I N I U M S M E LT I N G I N D U S T R Y Fig. 8: 60 t/h paste plant at Qatalum [6] • Rapid and accurate adjustment of the coke temperature • No HTF heating system required i.e. no risk of fire, self-ignition, leakage, etc. • Mixing energy input easily adjustable via tool speed, tool shape and mixing time • Rapid homogenisation in the intensive mixer • Significantly increased mixing quality • Reduction in pitch consumption of 2-5% • Simple machine design • Wear and spare parts easily exchangeable • Short maintenance standstill periods • Insensitivity to varying operating conditions • One Eirich mixer may replace 8-12 conventional batchwise operated machines • Thus, productivity increases in green production of graphite electrodes are up to 200% • Investment and maintenance costs up to 30% lower • High and freely selectable temperature level of the preparation process, thanks to direct electric heating and evaporative cooling Sample C13, 10 min. Sigma mixing, 19% pitch, high fines, green density 1.646 kg/m3 Fig. 9: Eirich high-performance compact system for batchwise preparation of carbon paste ALUMINIUM · 1-2/2013 • Compact tower system close to the press. Conclusion Thanks to its specific benefits, intensive mixing has become proven technology in the carbon paste preparation sector. Further technical and commercial growth potential is assured. The high efficiency at low investment and operating costs make the Eirich intensive mixer the means of choice also in the future. References [1] P. Stokka., Green paste porosity as an indicator of mixing efficiency, Light Metals (1997), pp. 565568 [2] B. Hohl and L. Gocnik, L. Installation of an anode paste cooling system at Slovalco, Light Metals (2002), pp. 583-586 [3] B. Hohl, and Y. L. Wang, Experience Report – Aostar Aluminium Co. Ltd China, Anode paste preparation by means of a continuously operated intensive mixing cascade, Light Metals (2006), pp. 583-587 [4] B. Hohl and V. V. Burjak, High-performance preparation plant for cathode paste, Light © Sample C11, 10 min. Eirich mixing, 19% pitch, high fines, green density 1.685 kg/m3 Fig. 10: Overview of the green samples mixed with a Sigma or with an Eirich mixer, magnification 160x, polarised light 43 A L U M I N I U M S M E LT I N G I N D U S T R Y Metals (2008), pp. 997-1000 [5] M. Gendre et al., From technology development to successful start-up and operations of Sohar: The potential of the Bi-Eirich mixing line, Light Metals (2010), pp. 963-968 [6] C. Bouché, S. Bhajun and B. Somnard, 60 tph single line green anode plant commissioned at Qatalum, Light Metals (2012), pp. 1153-1157 [7] M. Tkacet al., Effects of variation in production methods on porosity development during anode baking, 12th Arabal Conference, 2006 Others [8] J.-C. Thomas, New concept for a modern paste plant, 7th Australasian Aluminium Smelting Technology Conf. and Workshops, Melbourne, 2001 This paper was presented at the ICSOBA Conference in Belèm-Brazil, 2012 [9] C. Dreyer, C. Ndoumou and J.-L. Faudou, Reconstruction of the mixing line for anode paste production at Alucam, Light Metals (1998), pp. 705710 Author Dipl.-Ing. Berthold Hohl is manager Carbon Technology of Maschinenfabrik Gustav Eirich GmbH & Co KG, based in Hardheim, Germany. HMR’s automated stud repair line I. Dal Porto, HMR Hydeq ting results in damage to the surface which is then needed for welding, whereas it is very important to reduce the electrical resistance of the welded joint. Poor quality cut surfaces can significantly affect the overall current efficiency of the electrolytic process and hence production costs. Automated stud repair line HMR’s Automated Stud Repair Line (ASRL) repairs anode yokes by replacing worn-out studs with the new studs whilst anode yoke and rod is still on the powered and free conveyor in the rodding shop. The repair line is fully automatic and requires only one operator. The operation starts by testing of every anode stud on the anode yoke in accordance with the wear-and-tear specification set up by the customer. Anode studs with wear and tear above the acceptable limits are diverted on a bypass to the ASRL for replacing. The powered and free conveyors bring the anode rod forward, first to the cleaning station, then to the cutting station, where a saw cuts the exhausted stud from the yoke, and finally into the welding station, where fully programmable welding robots perform a perfect weld. After the replacement of worn anode studs, the anode yoke with rod returns to the rodding shop. During the process of cleaning the studs to remove bath, rust, oxide scale, etc., some dust © HMR The consumption of yoke studs is huge in aluminium smelters. Today most of the plants carry out the repair process manually. The operation consists of removing the damaged anode yoke from the overhead conveyor, transport to the repair shop, cutting off damaged studs with a cutting torch, making a seam, adjusting and welding of new parts – all these operations are carried out manually. This traditional manual repair cannot be costeffective and cannot ensure a high quality standard, since it involves handling and transportation of the anode yoke and it relies on the ability of a human operator both for welding and for the cut, which usually employs flame cutting. Flame cut- Automated Stud Repair Line (ASRL) installed in Årdal, Norway, with sawing station on the right. Data from the measuring station is transferred to the sawing station, which performs cutting automatically in accordance with the given information. 44 ALUMINIUM · 1-2/2013 SPECIAL A L U M I N I U M S M E LT I N G I N D U S T R Y is released. Also during the welding process, welding gas appears. In order to effectively contain these impurities, a special cyclone filter has been installed on the ASRL. The advantages of HMR’s ASRL are: • The line is completely automated and requires just one supervising operator • The process is efficient and very safe for the floor personnel • It reduces repair down-time to the minimum • There is no need to remove the anode rods from the conveyor during stud replacement - Fewer anode rods are needed in the plant (estimation 2-4%) • Studs are replaced exactly according to the procedure set up by the customer. Procedure, line of action HMR’s ASRL brings the studs distinctively to the same condition as on the anode yoke Measuring station: All complete anode yokes and rods are transported on the power and free conveyer to HMR’s ASRL measuring station. Each anode stud is checked against the wear and tear limit set by the customer. Anode studs with an acceptable wear-and-tear level are returned to the plant. A bypass on power and free conveyer brings anode studs with wear and tear above the limit to the ASRL for processing. The measurement station collects historical data which later can be used for statistical purposes. ("$ !"#%# # #-*0"#45/ #)*'*"2($/#5.+ $'$3 .$) .$") )"$) -$)"+-*0- ( )/ - /$*))*(($..$*)$)"*!+) 0(/$(/ -$'#)'$)".2./ (.!*-/0-)& 2+-*% /. )*(+*) )/.!*-/# '0($))0./-2*-(*- /#) 2 -./# 4-)#. ./**!*-#$"#,0'$/2./)-.2./ (.1$/#(*- /#) - ! - ) .1*-'1$ ! " #$# -.' ) -/-s $)) -" -()2 's#(0-"6.($/#*( &# ! DUBAL Cleaning station: The HMR’s ASRL system sends a signal to the robot-operated cleaning device and indicates which stud is to be cleaned. In front of the cleaning station there is a conveyor block up. The robot with chain centrifugal blast cleaning device starts to clean A L U M I N I U M S M E LT I N G I N D U S T R Y The specimens show the homogeneous welding attainable and how tight the two parts are pressed together. This improves the electric conductivity, and it transfers heat better then than other joints available on the market today. the saw cutting / welding area. Saw: Thereafter the anode yoke and rod is transported to the automatic saw station. Data from the measuring station is transferred to the cutting station, which performs cutting according to the given information. Welding station: After removal of a stud or studs, the anode yoke and rod is directed to the automatic welding station. If the welding station is occupied, the anode yokes and rod wait at the intermediate storage zone. While one robot handles the new stud, checks and prepares it for a correct replacement and welding, the other two robots execute the welding operation simultaneously from both sides. Then the already repaired anode yoke and rod is returned into the system for rodding. Safety system: The whole of HMR’s ASRL is surrounded by a safety fence. Each robot station has an additional safety fence. If anyone opens a door in the fences, the system stops robot movements momentarily. A separate, moveable safety catch is placed around the chain centrifugal blast cleaning station. Performance, capacity and quality HMR’s ASRL brings the studs distinctively to the same condition as on a new anode yoke. The operation provided by ASRL ensures in a low electrical resistance of the joint thanks to optimised cutting and welding procedures developed by HMR and executed reliably by the automated robotic line. The system has a repeatability of < 0,1 mm (NB. depending on anode rod condition) and a productive capacity of ≤ 6 min. (NB. depends on groove weld design, number of studs per anode rod and on conveyor speed). The welding time is about four minutes per stud. The photo shows two sliced part cut in the exact same cut It is quite important that the before welding. Second cut 10 mm below welding. cutting and welding area is kept Samples of the stud bar cut by the saw. The quality of the cut is very good and can be systematically tested. clean of bath, rust and iron scale contamination. That is why a chain centrifugal blast cleaning is a part of the ASRL system. This device prevents bath, rust and iron scale from interfering with welding, and it prolongs the life of saw blades (40% alumina content in bath causes rapid wear of saw blades). This cleaning allows up to 800-1,000 studs cut to be obtained from recommended saw blades. However, one must bear in mind that the quality of weld provided by ASRL depends also upon external conditions. The most important of these is that joint surfaces must be clean and accurately machined. The studs cut by the saw have a bright steel surface, which is preferred for welding. Author Italo Dal Porto is senior engineer at HMR Hydeq AS, based in Årdal, Norway. Channel-type versus coreless induction furnaces W. Spitz and C. Eckenbach, Marx GmbH & Co. KG The company Marx gives an overview of the different types of induction heating units for melting, holding and holding/ casting furnaces. This paper focuses on coreless inductors and on their advantages over channel type inductors when it comes to holding /casting of special aluminium alloys. It illustrates and explains this comparison for the case of a holding/casting furnace in an aluminium semi-fabrication plant in Europe which was modified from a channel-type furnace to a furnace with coreless inductor 46 technology. The paper gives technical information comparing in detail the new benefits, such as an increased service life of the furnace of up to three years with the crucible inductor. Specifically, this revamp and upgrade of a 28 tonnes holding and casting furnace with a power of 200 kW converted it to 40 tonnes and 450 kW, as demonstrated by construction and field results. Basically two different kinds of induction furnaces are used for melting, holding and cast- ing of metals: the channel-type induction furnace and the coreless type induction furnace. The channel-type induction furnace consists of a refractory lined furnace body made of steel to which one or several channel-type inductors are flanged for heating the metal. Due to effects like thermal conductivity and buoyancy of the hot melt, in most cases the channel-type inductor is flanged at the bottom of the channel type furnace body. This results in the typical design of a small to mediumsized channel-type melting furnace like that shown in Fig. 1. ALUMINIUM · 1-2/2013 Depending on the function of the furnace in the production line other furnace body designs may be appropriate, placing the channel inductor in other positions. Channel-type induction furnaces are used for copper and copper alloy melting, as the copper is sensitive to oxygen pick-up from the air at a turbulent surface. Channel-type furnaces offer a smooth bath surface, but still provide a sufficient turbulence inside the melt to mix it and ensure uniform chemical composition and temperature. These are also the preferred type of furnace for holding and casting of copper and copper alloys (Fig. 2). Another application for the channel inductor is the holding of iron melts in huge storage furnaces or holding / casting furnaces with flanged forehearth, these being used in automatic high-speed sand mould casting lines. Channel-type furnaces have a much higher electrical efficiency than coreless furnaces, but when it comes to iron and steel melting (high power density required) and frequent alloy change, or the need to empty the furnace regularly, the coreless furnace is the preferred choice as melting for holding / casting furnaces. A third version of induction heating is a so called ‘coreless inductor’. Coreless inductors were already being used at the beginning of the 1980s for heating holding furnaces in the aluminium and copper casting industries, typically for holding furnaces in continuous casting lines. Such inductors consume more energy than a channel-type inductor, but they offer much longer lifetime and they allow easy emptying the holding furnace on a regular basis (Fig. 3). Marx has gained an extensive experience in modifying existing holding furnaces from being heated by channel-type inductors to being heated by coreless inductors. Such a refurbishment and modification can increase holding capacity, precision and power efficiency. Changing the old conventional tap switch power cabinet for a more economical IGBT transistor converter cabinet also allows a precise holding / casting temperature regulation of the melt. Such a furnace refurbishment will be illustrated and explained using the example of a 28-tonne holding furnace at a prominent semifabricator plant in the European aluminium slab casting industry. This customer has been operating eleven units with 20- to 30-tonne holding furnaces, these being fed with liquid metal by gas heated melting furnaces, which supply the liquid metal by tilting into a semicontinuous vertical casting line (Fig. 4). The holding furnaces had been equipped ALUMINIUM · 1-2/2013 A L U M I N I U M S M E LT I N G I N D U S T R Y © Marx SPECIAL Fig. 1: Different types of induction furnaces – channel-type furnace Fig. 2: Channel inductor – Aluminium Holding /casting furnace Coreless (crucible) inductor Fig. 3: Different types of induction furnaces – furnace heated by coreless inductor 47 A L U M I N I U M S M E LT I N G I N D U S T R Y 3D-Visualisation Fig. 4: Channel inductor, 28-tonne capacity with 200 kW channel-type inductors, but these required weekly cleaning due to clogging of the channels. Cleaning represents in significant production downtimes as well as difficult and time-consuming maintenance. In addition, the furnaces needed five to six inductor changes per year at one holding furnace, resulting in additional maintenance costs and production downtimes. Converting an existing furnace involves first collecting the furnace’s structural data. It is useful and recommendable to visualise this structure in a 3D image. Then we must decide whether the furnace volume will remain unchanged or whether the furnace casing should Fig. 5: Separation of existing substructure Crucible inductor, 40-tonne capacity be enlarged. For this purpose, we must subject the unit needs to static and dynamic functional testing and check the complete movement (tilting, driving) devices and power input. Calculations have to prove whether these components must be replaced by more powerful ones. On the construction site itself, the disconnection of the old lower furnace body structure is prepared and carried out. The welding area is being mechanically and technically prepared and the new substructure is positioned on the contact surface and then welded onto the furnace (Figs 5 and 6). The new furnace substructure supports the receiving structure for the crucible induc- Fig. 7: 40-tonne holding and casting furnace, ready for production tor that is installed later on. After successful welding and structural support, the furnace is ready to undergo welding analysis and, after approval, needs to be prepared for a new lining. Constructional conditions, such as the furnace pit, are also checked in terms of spatial geometry. The necessary clearance spaces for more expansive tilting movements may require structural changes; this however is normally not the case (Fig. 7). In terms of cost saving and production increase, such conversion is amortised in less than one year. For operating personnel, handling becomes much easier. So far, Gautschi has retrofitted or has prepared for retrofitting some 30 such furnace plants. It is nearly always possible to use the existing furnace ves- For 50 years, the Marx group in Germany with its approximately 100 employees has been working in the furnace industry. The company’s activities include planning and manufacturing of induction furnace plants, engineering, development, remanufacture, modernisation and retrofitting of induction furnace plants, service and customer support. The company has therefore gained extensive experience in working on almost all types of induction furnaces. Nearly every type of furnace has been serviced, repaired, retrofitted or modernised in its facilities. Its German sites in Iserlohn, Hennigsdorf, Donauwörth and in Youngstown, Ohio/USA provide well-aimed proximity to their customers in Europe and the United States. Fig. 6: Mounting prefabricated new substructure 48 ALUMINIUM · 1-2/2013 SPECIAL A L U M I N I U M S M E LT I N G I N D U S T R Y Comparison over the year Furnace with channel inductor Furnace with coreless inductor Cleaning cycles 52 cleaning cycles 3 man-days each (1,248 h) 52 production downtimes due to cleaning 2 x 24 h each (2,496 h) no cleaning cycles no production downtime due to cleaning Inductor change At least 5 inductor changes / shutdowns for repair ⅓ – 1 vessel change / shutdowns for repair 10 man-days each (400 h) (1-3 man days → 8-24 h / 3 staff) 5 production downtimes ⅓ – 1 production downtimes 5 x 24h each (120 h) 10-30 h At least 5 repair deployments ⅓ – 1 repair deployment €10,000/piece each → €50,000 €10,000/piece each → €3,300-10,000 Refractories 5 levelling processes and conditioning work on ⅓ – 1 levelling process and conditioning work rectangular flange on round flange 5 x 3 h (15 h) 1-3 h Table: Comparison over the year sels, to shorten them at the bottom and to fix a new substructure, thereby completing the refit within quite a short time, with good preparation in approximately four weeks. The coreless inductor is simply bolted on to the furnace is surprisingly overwhelmingly clear in favour of the crucible furnace (see Table): As already mentioned, the modification period can be used to change the old conventional-style power supply against a more efficient new converter power supply. Using an infinitely variable power supply via transistor converter in IGBT technology provides for automated and visualised control of the holding and casting process and, at the same time, allows for monitoring the condition of the crucible inductor itself. It is clearly worthwhile to examine existing furnaces and to retrofit them with modern technology. This keeps melting and heating technology one step ahead of the market. Authors lower furnace body. If it wears out, it can be changed within a time frame of 24 to 30 hours maximum from pouring the furnace vessel empty to its restart. The cost-benefit equation in relation to channel furnace versus crucible Dipl.-Wirt. Ing. (FH) Christian Eckenbach is managing director of Marx GmbH & Co. KG, based in Iserlohn, Germany. Dipl-Ing. W. Spitz is sales manager for Induction Furnaces at Marx GmbH & Co. KG. Alcoa starts up potlining facility at Fjardaál Iceland smelter The cost of the new facility amounts to some USD36 million, Alcoa says. Work started in 2010, and overall construction has taken about 18 months with Canadian engineering company Hatch heading up the construction in collaboration with Icelandic firm HRV Engineering. Around 100 people worked on the construction at the peak of the project. Following a bidding process, VHE in Iceland was chosen to operate the new potlining facility in accordance with Alcoa’s stringent demands, in terms of environmental and safety issues. VHE has hired around 60 people to work on potlining and pot repairs, and these operations will be located partly in the new Alcoa potlining facility and partly in VHE’s own facility situated on the smelter site. The new construction consists of three buildings: a spent pot lining facility; a dedicated potlining workshop, and an administration block. Spent pot lining, also known as SPL, con- ALUMINIUM · 1-2/2013 sists of the cathodic block (carbon) and insulation (refractory lining materials) of aluminium smelting pots that have reached the end of their service life. The potlining area is a stateof-the-art facility, purpose-designed and equipped with latest plant and process technologies and also ideal conditions for lining new pots for the smelter operation. Alcoa presents some key figures that reflect the operating performance of the new pot relining facility since its opening last year: Over 40 pots have been relined and the facility has the capacity to reline around 100 pots per year. An average of New potlining workshop 90 tonnes of materials (refractory bricks, cathodes, paste and mortar) are used to line each pot; and interestingly the busy cathode transport crane which traverses between the potroom and the relining facility covers some 6 km each week. Alcoa emphasises that many new jobs have been created by the project overall, culminating in the opening of the potlining facility, and that increased business and revenues are also being generated for the Icelandic economy. The launch of the smelter in Reydarfjördur, the company claims, has proved to be pivotal © Alcoa Alcoa reports that a new potlining facility is now in operation following its formal launch last year at the company’s Fjardaál smelter in Reydarfjördur Iceland. The startup of the new plant marks the overall completion of the integrated smelter on which work initially began in 2004. for East Iceland: the number of residents has increased by 1,000 since Alcoa’s aluminium plant started operations. Ken Stanford, contributing editor 49 The entire steelmaking process chain from a single source. $ ! !"! !"!& !"!! $&!"!"""!"%"$! !&$!! "# ! !!!!$#! ! ! (!"!! ' "!"!!"'!$ & !& "! # 5"! . .*,-048 & ).2,++11+* 6% ).2,++11+.2*, "! 3 " $$$ " -," ++,,"%" )-/,.20*+ 6% )-/,.20*,,*2 "$"!3"$"! $$$"$"! A L U M I N I U M S M E LT I N G I N D U S T R Y Gautschi Engineering – An industry profile O. Moos, Gautschi Engineering you can choose from numerous designs for liquid metal furnaces according to the differing requirements of modern casthouses. Gautschi supplies a wide range of different liquid metal furnaces with capacities between 10 to 140+ tonnes. Melting rates above 40 t/h have been achieved in remelt facilities. As mentioned above, Gautschi started to develop its own technologies early on. This was on the one hand because certain technologies were not available on the market, and on the other hand, because the available technologies are not always suitable From the start, the for specific applicacompany has worked tions. to gain a thorough unOver the many derstanding of its cusdecades in operation, tomers’ needs so that the company develtogether with them it oped a wide range can develop compreof burners with a cahensive solutions to pacity between 500 meet all their requireto 9,500 kW. These ments. This naturally burners either work applied especially to with cold air, or the beginning of its with hot air (using a operation, when the central recuperator) commercial producor they are regention of aluminium had erative, with a heat just been established. Round top charged melting furnace with a melting capacity of 30 tonnes per hour © Gautschi Engineering exchanger module Gautschi’s head office location in Switzerland certainly contributed necessary expertise not only for a specific piece directly attached to the burner head. In adto the success in the aluminium industry, as of equipment, but also for its auxiliary com- dition, the burners can operate with different the first commercially operated smelter was ponents and for equipment/processes adjacent fuels according to the customer’s needs. located just a few kilometres away. In addi- to the equipment within the whole working Gautschi is especially proud having a regention, the first aluminium cold rolling mill was area. For example, a casting machine can only erative combustion system at hand (the Varestablished in a neighbouring town. produce a certain quality if the casting process ega Regenerative Combustion System), bringAs most components required to operate already meets specific requirements. ing the thermal energy consumption down to the equipment were then not easily available, rates as low as 465 kWhth/tAl. Naturally, this Gautschi invested heavily in developing its Liquid metal furnaces depends on a lot of factors, starting with good own technologies. In the early times, even house keeping practices (what kind of charging fuel and air line components were fabricated For many years, liquid metal furnaces for material is available and how is separated and in-house. For a period of time, Gautschi pro- standard applications were seen just as a ne- stored), and including the kind of furnace used duced part of the insulation material in its own cessity in an aluminium casthouse. Main ef- as well as the level of maintenance done on factory. Hydraulic equipment from valves to forts were put into the design of casting ma- the equipment. In addition to being the most cylinders was supplied by Gautschi. In addi- chines (the heart of the casthouse) and the heat efficient combustion system on the market, tion, the control systems are designed and treatment facilities. But in the second half of the Gautschi Varega Regenerative Combusprogrammed in-house up to this day. Further- the last century, the dramatic increase in ener- tion System requires minimal maintenance. more, we still use our own design for blowers, gy cost together with stringent environmental Other systems on the market require costly fans and burners (cold air, hot air and regen- requirements, and the demand for top quality maintenance at intervals of a few weeks to a erative). products, drove furnace suppliers and users couple of months. For example, the ceramic Nowadays, most components for combus- to take a new look at their furnaces. Nowadays balls in the regenerator must be removed and Gautschi Engineering GmbH is one of the world’s leading suppliers of casthouse and heat treatment technology for the aluminium industry since 1922. The wide product range includes all necessary control and automation equipment, and its reliability and efficiency has been a major contribution to the success of the company over all those years. Gautschi has been a supplier to all the large aluminium producers as well as to many smaller, independent companies around the world. 52 tion, hydraulic, pneumatic and electric systems are sourced from leading suppliers. However, the profound experience from the past allows Gautschi to understand basic principles when designing the equipment supplied, and to judge what components are most suitable for a specific application. Its history and wide product range allows a system supplier such as Gautschi to offer all ALUMINIUM · 1-2/2013 SPECIAL washed, and damaged balls must be replaced. Gautschi’s systems offers maintenance cycles of more than 12 months between the regenerator cleaning. In addition, our system uses honeycomb modules, of which only a small proportion (generally only the top layer) must be replaced during the maintenance, so keeping cost to an absolute minimum. In order to meet customers’ requirements, we offer reverberatory melting and holding furnaces, round top charged melting furnaces, tower melting furnaces, and oval shaped holding furnaces in its portfolio. However, due to its huge technical data base, Gautschi is also in a position to meet any special requirements customers might have for a specific application. Gautschi can be seen as the leading supplier of round top charged melting furnace technology, having supplied many such furnaces in the course of its history. It is not uncommon for such a furnace to remain in operation for 50+ years. Capital well invested! This type of furnace is normally used in larger remelt facilities (e.g. rolling mills) to optimise the production capacities. A typical A L U M I N I U M S M E LT I N G I N D U S T R Y installation might have a 120-tonne casting line consisting of one RTC melting furnace, one holding furnace and one VDC casting machine for rolling slabs and produce more than 140,000 tonnes a year. Output depends not only on the melting furnace but also on the material used to charge the furnace, and on the size or format changes of the rolling slabs. Besides having expertise both for the liquid metal furnaces and for its auxiliary equipment, the company also supplies complete casting lines, from the melting furnace up to the casting machine. Complete lines have the advantage that all battery limits / communication interfaces are designed and supplied by one company. Casting systems Gautschi’s casting machines are known for their accurate and robust design as well as for their high level of automation. The Gautschi family of casting machines produce high quality products such as rolling slabs, extrusion billets, forging stock and foundry ingots around the globe. Vertical DC casting machines have been on our agenda for more than six decades. These machines have been constantly developed over the years, and they feature Gautschi’s Airglide mould technology for billets. Just recently a newly developed billet mould gas control system for a vertical DC casting machine has been successfully commissioned at one of our long-term partners. This mould system offers a superb pit recovery, with billets showing excellent surface qualities while having minimised shell and segregations zones. Compared to similar systems available, the Gautschi Airglide mould technology requires very low maintenance. This mould system is mainly used for billet diameters between 5 to 10”. However, moulds as small as 2” and as large as 16” have been supplied to different customers. All commonly used alloys can be processed. Gautschi has been one of the pioneers in the design of horizontal DC machines to cast billets and ingots, a technology which is still commonly referred to as the Gautschi-Ugine casting process. High versatility combined GLAMA Maschinenbau GmbH Hornstraße 19 D- 45964 Gladbeck / Germany phone + 49 (0) 2043 9738 0 fax + 49 (0) 2043 9738 50 email: info@glama.de web: www.glama.de A L U M I N I U M S M E LT I N G I N D U S T R Y with the low investment costs makes this technology ideal for small scale production of foundry ingot, forging rod or extrusion billet. The technology is especially useful when producing rods/billets of smaller diameters (normally less than 3”) as no undesired bending effects can occur, as opposed to such risks in a vertical casting process. On the other hand, casting larger diameters (normally more than 8”) can result in segregation zones within the billet, because heavier alloying elements tend to sink to the bottom of the billet. Recently, Gautschi has designed the so called smart caster. This casting system is designed to offer very low investment costs and short lead times. It is basically shop-assembled and shipped in one unit. Thus it does not need extensive installation on site, and this further minimises time and cost. It is designed as a dual strand standard caster for rod and billet in a diameter range of 2 to 6”. Both the primary and the secondary aluminium industry have always counted on Gautschi for the supply of reliable ingot casting and stacking machines. A wide variety of production lines allow the production of ingots from 6 to 23 kg, with a maximum output of 28 t/h. The latest development in this field is an improved, partially submerged pouring system. A plug and spout system, in combination with a casting wheel, successfully avoids turbulence and reduces the generation of oxides. Automatic speed control has been a standard feature of Gautschi casting lines for years. It ensures excellent weight consistency of the ingots (which is necessary to ensure compact stacks). Variation in the metal level of the feed launder is compensated by the speed control system, which ensures uniform filling of the moulds. Heavy-duty industrial robots have been used in Gautschi ingot stacking lines for over ten years. They can build rigid ingot stacks weighing between 500 and 1,000 kg, depending on customer requirements. Recent installations have been equipped with a special sensor measuring the distance between the ingot layer in the robots handling system and the previous layer of the stack. This allows the robot release the ingots at a minimal fall height, which increases the integrity of the stacks. Heat treatment technology The pre-heating and annealing processes are some of the major steps in the production of aluminium products, and they are of critical importance for the quality of the final product. Based on its long tradition of engineering, Gautschi designs and supplies the full range of equipment in the field of heat treatment. These includes single and multi coil furnaces, chamber homogenising furnaces as well as pit type furnaces. Gautschi is also one of the leading suppliers of pusher type furnaces, having been involved in this technology for more than 60 years. This success is based on continuous product development to improve productivity, temperature uniformity and energy efficiency. As a result, all components are carefully evaluated and chosen to perfectly match each other. This applies to the combustion systems, air guidance and nozzle systems, recirculation fans, insulation materials and temperature control. It also applies to the complete handling system, allowing short cycle times. In 2007, Gautschi designed a new ingot travel car for pusher type furnaces. As commonly done, several pusher furnaces are installed at the entry side of a hot rolling mill. The ingot travel car allows for the installation of some of the handling systems which often serve more than one furnace. This car needs just one unit for the up-ender and rail bridges on the entry side, as well as single extraction Gautschi pusher furnace 54 ALUMINIUM · 1-2/2013 SPECIAL device, rail bridges and down-ender on the exit side to serve several existing pusher-type furnaces. Just recently, the company has been awarded the contract to revamp one of its pushertype furnaces which had been supplied in the mid-1950s. This long life underlines the high quality, robustness, durability and reliability of Gautschi equipment. We will supply a new state-of-the-art combustion system for heavy oil firing on this furnace. The furnace will also get a new insulation lining in order to further enhance its efficiency, allowing it to continue production well into its second half century. Besides the modernisation of older installation to meet low-energy requirements, Gautschi will continue with its efforts to further improve all aspects of productivity and energy consumption. This is the driving force behind design enhancements and improvements in the operation of these furnaces. We stay in contact with our customers to work together on practical solutions to create the most suitable and efficient equipment for the heat treatment in the aluminium industry. Controls and automation Throughout its history, Gautschi’s Controls and Automation department has always been one of the backbones of the company. Not only are all the switchgear and control devices designed in-house, but also the software is written by competent team members. The optimised hardware and software engineering is only possible by constant training of all members of the department. Industrial robot in the process of creating an ingot stack ALUMINIUM · 1-2/2013 A L U M I N I U M S M E LT I N G I N D U S T R Y A state-of-the-art remote service centre rounds up Gautschi support for its customers. If required and desired, a remote service connection links the equipment installed with Gautschi headquarters in Switzerland, enabling the Gautschi experts to consult its customers on aspects of furnace operation / function and maintenance. Summary Gautschi Airglide mould It is common practice for personnel from our Controls and Automation department to be present during commissioning and start-up of the equipment. This helps them to understand and also optimise required processes, and in cooperation with the customer to optimise the process steps. In a global environment, Gautschi can offer other international brands besides its own standard control systems based on Siemens PLCs. Alternatives include Allen-Bradley, Télémécanique and others to meet specific customer requirements. To facilitate the human-machine interface, Gautschi uses software packages such as InTouch Wonderware, WinCC and WinCCflexible, but can also accommodate special requests by customers if desired. In recent years, Gautschi is focussing especially on the development and implementation of control systems up to level 2 (and/or 3), and works in cooperation with its customers on the development of ERP systems. Besides an optimised control system to operate equipment supplied by Gautschi, preventative maintenance programmes are becoming a standard feature. This begins with timers running and telling the operator to take a specific action (e.g. to lubricate a gear box motor, change hydraulic fluid, filters) In addition, preventative maintenance can be incorporated into equipment supplied by Gautschi, so allowing customers to determine the ‘right’ time to maintain or exchange components. This applies, for example, to vibration detectors mounted on blower bearings. A warning will appear on the HMI once elevated vibrations are detected, allowing the customer to react before a catastrophic failure of the bearing occurs. Furthermore, modern HMI systems allow the service personnel to find specific information about components used on the equipment. The system stores key data (such as location of instruments and sensors, component numbers, spare part references) to facilitate spare part handling by customers. Gautschi has been a reliable partner and expert advisor for high quality facilities for the aluminium industry for more than 90 years. As a global supplier of complete melt shop and heat treatment facilities, the company has decades of experience and a worldwide network of qualified experts. These ensure high production efficiency and long-term success thanks to Swiss precision engineering. We assemble a thorough understanding of our customers’ needs so as to develop together comprehensive solutions to meet all requirements. Product developments cover both current and future market requirements. With worldwide professional services Gautschi guarantees the long-term operation of the facilities it supplies. The customers profit from the operator friendliness, easy servicing, long service life, high quality and resource / energy saving technology of the products. Author Dr. Oliver Moos is managing director of Gautschi Engineering GmbH, based in Tägerwilen, Switzerland. Electrical control system 55 A L U M I N I U M S M E LT I N G I N D U S T R Y Advanced technology from Brochot – A proven solution for anode slot cutting P. Dunabin, Brochot © Brochot The French-based company Brochot is a well-established supplier of production process equipment to the non-ferrous metals industry. The company is represented on a worldwide basis with offices in Canada, China, Russia and the Middle-East and with three workshops in Quebec, France and China. The company’s portfolio is extensive and increasing, in particular with the addition of recent equipment supply to the copper and zinc industries by the Brochot Hydromet division. However, Brochot’s principal activity remains the design, development, manufacturing and supply of equipment for the primary aluminium sector. In this sector the company is well known for the supply of individual machines as well as for complete turnkey projects for anode rodding shops and anode handling installations. Brochot anode slot cutting machine during workshop testing A recent successful installation is an anode slot cutting machine at the Nalco plant in Angul, India. This machine is part of Brochot’s on-going development of anode slot cutting concept which seeks to improve and adapt the design to the varying criteria of individual smelter sites. Brochot continues to invest in development of new and revised designs for its slot cutting machine, and future orders will incorporate a number of improvements to improve cycle times and to adapt to client slotting requirements. cell resistance. The distance and time for a gas bubble to escape from the underside of the anode are determining factors of the thickness of the bubble layer: basically, the shorter the escape distance the lower will be the extra resistance created by the gas layer. As anode sizes grow, so the problem of the gas layer increases. Thus the slots in the anode, for as long as they exist, stimulate the shorter escape path for gas bubbles formed on the underside of a smaller anode. Advantages of slotted anodes Slot configurations The use of slotted anodes is now well established in aluminium smelter potlines. The slotting of anodes is known to give improvements in pot efficiency by reducing the formation of bubble films (which create higher electrical resistance), by reducing anode cracking and by allowing increased pot currents. The cost of aluminium production depends critically on the cost of energy used in the reduction process, and so efficiency gains from slotted anodes have a direct cost benefit. Studies have shown that the gases (mostly carbon dioxide and carbon monoxide) generated by the reduction process form mainly on the underside of the anode block, where they build up of a layer of gas which increases the Anode slotting arrangements have existed in two configurations – lengthwise slots and transverse slots. These slots can be formed in two ways: either by moulding during the formation of green anodes, or by machining the slots in baked anodes. It is accepted that the longitudinal slot configuration delivers the greatest benefit, and the Brochot slot cutting machine produces slots in this direction. The use of moulded slots has a number of disadvantages compared to machined slots. Slot forming plates introduced in green anode moulds can affect the paste distribution and compaction around the slots. The slots are wider than machined slots, and they can become clogged with packing coke at the anode baking stage. The wider slots also reduce the overall mass of carbon, consequently reducing the life of an anode. Slots make the green anodes more fragile and so increase rejection rates during the green anode forming, cooling and transportation stages. These problems are exacerbated with increases in the slot depth, although deeper slots would be potentially useful to maintain their function through a greater part of the anode life. Machine installation and construction 56 The Brochot slot cutting machine is intended to be used as an integral part of the anode handling system. The machine is integrated into the anode conveying lines, receiving anodes from the baked anode storage areas, and cutting the slots in them before they proceed to the anode rodding shop. At Nalco the Brochot machine was integrated as a retrofit into the existing conveyor line just before feeding the anode rodding station. The machine installation was adapted to the existing slope of the conveyor, and the design also allows the possibility of configuring it for a ‘pass through’ process without slotting. Space restrictions in this plant do not allow the use of a separate by-pass conveyor. The basic elements of the machine are: a ALUMINIUM · 1-2/2013 SPECIAL Anode slot cutting in progress strong, rigid frame which supports an anode transport carriage and anode lifts; a powerful gearmotor which directly drives the shaft mounted cutting tool discs; entry and exit roller conveyors; and a fully enveloping enclosure to retain carbon dust within the machine whilst assuring operator safety. Slot parameters The machine delivered to Nalco can cut a variety of slot configurations including horizontal slot depth, as well as sloped slots up to 450 mm deep. In this machine the slot cutting unit is in a fixed mounting configuration. Brochot, as mentioned below, can deliver other slots Brochot slot cutting unit dimension as well. This simple and robust solution is well adapted to the client’s needs. Brochot can also offer machine configurations with mobile slot cutting unit mountings, where the cutting discs can be raised or lowered. The position of the slots in the anode is normally predefined by the client, but nevertheless the distance between the slots may be modified by changing the disc mounting spacers. To help the gas bubbles to leave the slots more quickly, the slot depth is often inclined. This parameter can be quickly and easily ALUMINIUM · 1-2/2013 A L U M I N I U M S M E LT I N G I N D U S T R Y Brochot slot cutting machine during installation at Nalco changed in the Brochot machine by adding or removing spacers on the anode support pads of the transport carriage. This operation inclines the anode relative to the machine chassis, so that the depth of cut is greater at one end of the anode than at the other. We emphasise that Brochot is manufacturing in-house its own blade which is designed for the specific application of each customer. The stability of the slot cutting discs is very important for reliable operation of the slot cutting machine. Disc diameters for deep slots become very large compared to the disc thickness. One of the objectives of slot cutting is to create a significantly narrower slot than in a moulded anode. The disc stability is related to its thickness, materials, detail design and fixing arrangements. Any deformation of the cutting discs will cause premature wear to cutting tools, with localised tool heating, and will create slots that are wider than desired. The design of the Brochot disc ensures excellent shape stability despite the mechanical loads and the thermal variations caused by cutting anodes which are still hot, particularly in their cores. For Nalco Brochot has produced tooling which produces an 11.5 mm wide inclined slot with two slots per anode. Brochot can also offer machines with slot depth up to 450 mm with small slot widths. Brochot offers a fully automated process machine adapted to the products defined by a particular smelter or anode production unit. Within the limitations of the machine size determined at the outset, the machine can be adapted to accommodate changes in slot dimensions (depth, length, slope, fully traversing or partially traversing slots, distance between slots) when production parameters change. Tooling life Operating costs of slot cutting machines depend largely on the life of the cutting tools. Brochot has worked over a number of years to choose and refine the specification of the cutting tools in order to achieve long life and reliability. A single set of tool tips can reliably achieve a life of 40,000 anodes (Customer reports having achieved 45,000 anodes), and by indexing the tool tips, the life of the tools can be doubled. The Brochot tooling design uses special tool holders carrying diamond tip tools which are mounted alternately on either side of our tool carrying discs. Brochot supplies the complete machine and tooling package with after-sales service, giving full support for supply of consumables and replacement parts. In any slotting operation the rigid mounting of the anode is essential to avoid problems of vibration during the machining operation. The Brochot machine has a rigid anode transfer carriage equipped with strong pneumatic anode clamps. A motorised roller conveyor delivers the anodes to the machine and places above an anode lift. The lift raises the anode, allowing the transfer carriage to position itself around the anode. The lift retracts, lowering the anode onto the anode support pads, and then the carriage anode clamps fix the anode securely in place. The carrier advances the anode so that the discs cut the slots in the anode as the carriage advances. After exiting the cutting zone, the anode clamps release the anode and the exit lift lowers it onto the outlet roller conveyor. During this stage, the next cutting anode is loaded and lifted, ready for the re- 57 A L U M I N I U M S M E LT I N G I N D U S T R Y turn of the anode carriage. The slot inclination and the orientation of the slot are determined by the height of the anode support pads, the anode being inclined in the carriage during the slotting operation. The quality of the cutting operation and the control of vibration are well understood by Brochot, allowing reliable calculation of the optimum for disc rotation speed and anode advance. This ensures good prediction of slotting cycle times in new projects, which is essential for correct sizing of equipment in new and existing installations. Dust control One drawback of slot cutting in baked anodes is that the process creates carbon dust. To control the dust, Brochot supplies a complete dust extraction and filtration system along with the slot cutting machine, and works together with its clients to create the best package for the site installation. A fully enclosing housing supplied with the machine provides dust control and safety protection. The housing is in two parts, which are retractable to allow maintenance access into the machine. The lower part of the machine forms a dust collection hopper which feeds a screw conveyor. During cutting, the larger carbon particles fall into the hopper from where a screw conveyor extracts them to a collection bin. Periodically this bin is emptied to the carbon recycling system. Ongoing developments Capitalising on our experience at Nalco and at other sites, current design developments at Brochot focus on providing cost optimised designs with higher capacity, so reducing cycle times, whilst simultaneously increasing the depth of slot. New designs optimise the use of the cutting unit (discs and drive system) to allow multiple anode slotting with a single cutting unit. Other improve- Brochot anode transport carriage ments include: new dust collection and extraction systems, tool life of around 60 anodes/hour. Backed up by its commercial and engineeroptimisation, and automation of pass-through systems to facilitate anode transfer without ing resources across several continents, Broslotting. The reliability of the equipment is of chot is already replying to client requests for primary importance, since downtime of the the next generation of slot cutting machines slot cutting machine can quickly interrupt and intends to remain a leading player in this supply to the rodding shop. The current Bro- market. chot slot cutting ma-chine delivers a reliable performance at around 45 anodes/hour, de- Author pending on anode dimensions. The next generation of equipment will maintain current Philip Dunabin is manager of Brochot’s engineering reliability levels while increasing this to a rate department, based in Tremblay en France. Diffusion and convection of alumina in the bath of a Hall-Héroult cell R. von Kaenel and J. Antille, Kan-nak The alumina concentration in the bath plays a fundamental role in cell operation. Local depletion may lead to an anode effect. This paper presents a mathematical model describing the alumina convection-diffusion process in the bath coupled to the cell magneto-hydrodynamic (MHD), and discusses the relative importance of the velocity field and the alumina diffusion coefficient on the alumina concentration in the bath. The aluminium industry is continuously increasing the productivity of electrolysis cells by increasing the line current. In order to keep an acceptable anode current density, smelters then almost systematically increase the an- 58 ode length. This reduces the central channel width (distance between the anodes along the centre line of the cell) and the side channel width (distance between the anodes to the side lining). The channel geometry, Lorentz force fields and bubbles have an important impact on the bath velocity field. In order to keep an acceptable energy input when increasing the current, the anode to cathode distance (ACD) is reduced as much as possible before reaching the magneto-hydrodynamic (MHD) instability constraints. This further reduces the active bath volume. Thus the increased current imposes an increase of alumina feeding rate simultaneously with a reduction of bath volume. Therefore, the question of dissolution, diffusion and alumina transport becomes an important element for avoiding underfeeding, which would lead to more frequent anode effects (AE). Alumina dissolution is a very complex phenomena in which the bath chemical composition, bath temperature, alumina temperature and alumina properties play an important role [1-3]. In this paper we assume that the dissolution is instantaneous when the alumina reaches the bath surface, and so we concentrate this study on the diffusion and transport by stirring processes. The purpose of the study is to optimise the feeding quantities (feeding frequency) as well as the number and location of alumina feeders so as to minimise the number of AE and to avoid sludge. ALUMINIUM · 1-2/2013 SPECIAL A L U M I N I U M S M E LT I N G I N D U S T R Y The theory is described in a more detailed manner in reference [4]. Let us briefly mention that the alumina distribution in the bath is determined by the following partial differential equation: c: Alumina concentration in the bath D: Alumina diffusion coefficient u: Bath velocity field generated by MHD Lorentz force and by the release of bubbles If we consider fluctuations around the stationary state: (2) The velocity field is generated by Lorentz force field and by the bubbles. When the number of bubbles produced, per m2 and per second, is too large, we cannot use a numerical approach describing the motion of each bubble separately. There are essentially two standard ways to overcome this difficulty. The first consists of performing some kind of averaging over the equations and over the corresponding fields. The second bypasses the averaging and directly postulates the flow equations for each phase. One of the main difficulties encountered when performing an averaging process is related to the possible jumps that fields can suffer at the boundaries between the two phases. One way to overcome this problem consists in extending the domain of definition of each motion equation to the domain occupied by the two phases. This is achieved by multiplying each equation by the characteristic function corresponding to its domain of definition. Derivatives are then performed in the sense of distributions which allows us to keep track of these discontinuities in the averaging process. Whatever choice we make, the resulting equations will contain terms which reflect the interaction between the two phases. The exact shapes of these terms are not known; they have to be defined through constitutive equations. (3) Taking into account the first law of Fick, eq. ALUMINIUM · 1-2/2013 (4) An estimation shows that Dturb is of the order of 0.2 m2/s. Industrial cell in Fig. 3. From the two figures, the alumina concentration field appears as only slightly modified by the velocity field. However, when considering the concentration evolution, the time needed for reaching the stationary state is reduced by a factor 2 when the velocity field is acting. Therefore the velocity field plays an important role in the feeding process (alumina dumps). To highlight the role of the velocity field, Fig. 4 shows the difference between the alumina concentration field due only to the diffusion compared with that in presence of the velocity field. The greatest differences are observed at the ends of the cell, due essentially to the MHD effects. High negative values re- The problem has been solved for a 180 kA cell using two point feeders. On the feeders, the alumina concentration is set to 5% of the bath weight. When presenting a stationary solution, this assumes continuous feeding. But we can easily analyse the impact of dump feeding. Fig. 1 corresponds to the stationary alumina distribution, when the velocity is neglected. The concentration is shown under the anodes. The two Fig. 1: Alumina concentration at the anode surface assuming no velocity field feeder locations appear clearly in the figure. The asymmetry of the diffusion pattern reflects the larger channel width at the feeders. A difference of close to 2.5% alumina concentration can Fig. 2: Velocity field in the bath of the cell be observed at the surface of the anodes. The vertical variation of alumina is 0.5% under the feeders, but it is negligible away from the feeders. Fig. 2 shows the velocity field Fig. 3: Alumina concentration at the anode surface in presence of the velocity field generated by the bubbles and Lorentz force in this particular cell. The impact of the velocity field on the stationary solution of the alumina concentration is shown Fig. 4: Alumina concentration variation due to the velocity field 59 © Kan-nak 3 becomes: Theory A L U M I N I U M S M E LT I N G I N D U S T R Y pendent on the diffusion coefficient, the distribution itself is not affected in its shape. Obviously, a higher alumina diffusion coefficient leads to a lower difference of concentration in the bath. Conversely, greater distances from the feeders lead to higher differences in concentration. Moreover, the situation must be analysed as function of time and of the mass of Fig. 5: Lowest alumina concentration function of the alumina diffusion coefficient alumina fed at each veal large differences in alumina concentra- dump. The software allows us to determine tion. The velocity field helps to homogenise the highest difference of alumina concentration in the bath for any type of cell design and the alumina concentration. The above results depend strongly on the feeding strategy. It also considers the current alumina diffusion coefficient that was con- load in the cell, since Faraday’s law is satisfied sidered to be 0.5 m2/s from the Reynolds at the anode and cathode. stress tensor. When the diffusion coefficient is reduced, the velocity field becomes more Conclusions important. Fig. 5 shows how reducing the diffusion coefficient impacts on the lowest A model for the velocity field in presence of local alumina concentration in the bath. The MHD and bubbles has been developed. The velocity field becomes more important, but velocity field is used to determine the evoluthe global alumina concentration distribu- tion of the alumina concentration using a nontion remains mainly defined by the diffusion stationary convection-diffusion model. This coefficient. Bubbles and Lorentz force field equation takes into account the feeding and act to produce much the same effect as an in- the Faraday law at the anodes and cathode. crease in the alumina diffusion coefficient. The application to an existing cell with two They play a key role due to the much faster dif- point feeders demonstrates the following: fusion (the feeding in a cell is not continuous). • The local alumina concentration can vary Although the maximum difference of alu- by up to 2-5% (depends on the bath composimina concentration in the bath is clearly de- tion) • The pattern of the alumina distribution is not significantly affected by the velocity field, but is mainly determined by the Revamping solutions diffusion process and tailor made • The velocity reduces the time aluminium melting needed to reach the stationary and holding furnaces state for the alumina concentraExample: mobile gas treatment system and furnace covers with gas exhaust tion by a factor of two when compared to diffusion 60 only, and it therefore plays an important role in the cell • It would be of great interest to perform measurements to validate the macroscopic alumina diffusion coefficient References [1] O. Kobbeltvedt, S. Rolseth and J. Thonstad: The dissolution behaviour of alumina in cryolite bath on a laboratory scale and in point fed industrial cells. Department of Electrochemistry, Norwegian Institute of Technology, Trondheim, Norway [2] R. G. Haverkamp. PhD Thesis, University of Auckland (1992). [3] O. Kobbeltvedt, S. Rolseth and J. Thonstad: On the Mechanisms of Alumina Dissolution with relevance to Point Feeding Aluminium Cell, Light Metals, TMS, 1996, pp.421-427 [4] R. von Kaenel, J. Antille, M. V.Romerio and O. Besson, Impact of magnetohydrodynamic and bubble driving forces on the alumina concentration in the bath of a Hall-Héroult cell, to be published in Light Metals, TMS, 2013. Acknowledgement The authors would like to thank Prof. Olivier Besson from University of Neuchâtel and Prof. Michel Romerio from The Swiss Institute of Technology who developed the theory and software. Authors René von Kaenel received his diploma of physicist from The Swiss Federal Institute of Technology Lausanne (EPFL) with a specialisation in plasma physics before working for ICL in London and specialising in computer science. In 1981 he joined Alusuisse and became the head of the modelling activities for smelting technology. In 2000, he received the title of Electrolysis director in the new Alcan organisation and further supervised Alcan’s modelling activities. Since 1981 he has participated in many smelter modernisation projects all over the world, leading to large productivity increases. He has published many articles on electrolysis cells, casting processes and inert anode technology. In 2004 he created Kan-nak Ltd., a specialised company for the optimisation of processes, in particular of the Hall-Héroult process. Dr. Jacques Antille obtained a degree in Physics at the University of Lausanne in 1978 and his PhD at the European Centre of Nuclear Research (CERN) in 1984. Soon after he joined Alusuisse Technology and Management Ltd and worked on modelling projects of the Hall-Héroult process and casting processes. In 2004 he joined Kan-nak S.A. where he leads the magnetohydrodynamic studies to optimise the electrolysis process as well as all measurement techniques. ALUMINIUM · 1-2/2013 SPECIAL A L U M I N I U M S M E LT I N G I N D U S T R Y Power upgrade of Isal Potlines 1-3 B. Jonsson, RTA; M. Wiestner, ABB In the period 1959 to 1971 the Government of Iceland was keen to develop power intensive industry to utilise the hydro power resources of Iceland, of which at least 30 TWh/a are considered economically harnessable and not of major conservation value. In the early 1960s contacts between Alusuisse and the Ministry of Industry soon became formal negotiations, which in 1966 concluded with a master agreement on the engineering and construction of the facilities in Straumsvik for the production of aluminium. A power contract was also concluded between the National Power Co., Landsvirkjun, and the Icelandic Aluminium Co. Ltd (Isal), a sole subsidiary of Alusuisse. The Isal Smelter was constructed in several steps, from part of Potline 1 inaugurated in mid-1969 to Potline 3 entering into operation by mid-1997. In the middle of the 1980s the electrolysis pots of both elder potrooms were replaced by a then recently developed new type, so called cradle pots, which had more thermal expansion capability than their predecessors. The purpose of this development by Alusuisse was to raise the current intensity of the potlines from then 104 kA to some 120 kA, which is the rated current for each of the rectifier stations A and B for the Potlines 1 and 2, to which totally eight rectifier units are assigned. Rectifier unit B4 was modified to serve as a booster rectifier for test purposes and connected to 20 pots in Potline 2 for current tests up to 20 kA around 1990. By the middle of the 1990s, the rated current, 120 kA, was already achieved for 320 pots in Potlines 1 and 2. Back then, Alusuisse looked for further investments and pursued the option of a new potline with identical pots but with bigger and magnetically optimised DC-busbars. The rated current intensity of Potline 3 is 135 kA with four rectifier units. In 2000 the filter system for rectifier C was extended to enable current intensity above 140 kA and in 2004 the fifth ALUMINIUM · 1-2/2013 © ABB The most challenging and advanced power upgrade ever has been realised in an aluminium smelter. In 2012 Rio Tinto Alcan Iceland (Isal) accepted delivery from ABB Switzerland of four new rectiformers which now feed from a new 220 kV AIS step down substation all three potlines at Isal. The project history and technical challenges will be described. RTA Isal at Straumsvik, Iceland rectifier was added to maintain (n-1) operability of the rectifiers. By 2004, the current intensity in Potlines 1 and 2 had reached 125 kA. Then the filter system for rectifier B, whose reactive power demand is higher than that of A, was extended and the current intensity raised gradually to its present value of 133 kA. The present value of the current intensity in Potline 3 is 168 kA, and since November 2011 there is a 20 kA, 100 V DC, booster rectifier operated to achieve 181 kA on ten test pots in Potline 3. The substation and rectifier equipment serving Potline 1 is from the Swiss company Oerlikon, and that for Potline 2 is from the Swiss company BBC. Both companies are predecessors to ABB, a consortium composed of the Swedish Asea and the Swiss BBC. ABB was in 1995 the successful bidder for the power system in the substation extension and new Rectifier Station C for Potline 3 in Straumsvik. There are three different current control systems for the potlines of Isal. Rectifier A comprises diodes, rectifier transformers and regulating transformers with On-Load Tap Changers (OLTCs) from Maschinenfabrik Reinhausen (MR) in Regensburg, Bavaria, extremely reliable equipment. The Potline 1 current fluctuates, but is kept constant with an accuracy of ± 0,1 kA within a 24 hours interval. Rectifier B comprises diodes, rectifier transformers with saturable reactors of voltage range ± 30 V DC, and regulating transformers with OLTCs from MR. This equipment provides for constant current control for Potline 2. Rectifier C comprises thyristors and rectifier transformers with constant current control and fast load-shedding capability, and with a very big range of load gradients for Potline 3. Each rectifier station has its own current control system with their pros and cons. In Potline 1 the current is fluctuating. The control algorithm optimises the number of steps so as to simultaneously minimise both the number of diverter switch operations and the longterm current deviation from the setpoint. Rectifier stations B and C provide for constant current with regulating transformers. These are rectifier transformers with saturable reactors and diode rectifiers in B, respectively rectifier transformers and thyristor rectifiers in C. Each system has its advantages and disadvantages, but the superior controllability of a thyristor rectifier is unquestionable. This is advantageous to achieve quick and modulated load shedding. On the other hand, this feature is not useful for multiphase voltage dips deeper than 50%, because we then need to release the thyristors from the grid to avoid wrong triggering damage to the thyristors. In an island grid like the Icelandic one, such dips tend to occur about once a year. The introduction of programmable logic controllers at Isal in 1990 gave rise to optimised potline current control and to enhanced open circuit protection. This has supported the search for higher current and energy effi- 61 A L U M I N I U M S M E LT I N G I N D U S T R Y Largest transformer in Iceland ciency, as well as for fewer anode effects, thus reducing the release of greenhouse gases. The merit of Isal in this context is high on a world wide scale. The modern control technique has also served to enhance safety in the potrooms. Huge power will be concentrated in a pot in which the potline circuit is broken at high current. Such an event is catastrophic to personnel in the vicinity, to the superstructure of the pot and to equipment in the vicinity. In 1991, Isal, supported by an entrepreneurial mechanical engineer and software expert from Berkeley University, Hafliði Loftsson, started data collection to develop a protective algorithm in an empirical manner. This software development proved itself soon successful in Potroom 1, in which arc prediction and protection has avoided any arc flash across pots since its introduction. This scheme was then adapted to the different dynamic of Potroom 2, and soon after start-up of Potroom 3, it was adapted to the much more dynamic control characteristic of Potroom 3. This protection scheme has to be adopted by the parallel operating old and new rectifiers. 220 kV AIS (Air Insulated Substation) Scope background On 19 June 2006 ferroresonance struck the voltage measurement transformers on the secondary busbar of the stepdown transformers for Rectifier Station C, feeding Potline 3. Subharmonic oscillations occurred between the inductances of these VTs and the capacitances of the 33 kV cables feeding the five rectifier transformers. This caused excessive voltage across the VTs and huge overloading. Floating power systems are prone to this phenomenon under raised voltage conditions, as was the case here at midnight during midsummer. What triggered the ferroresonance was a change in the active and reactive load, when Potline 3 was being taken to zero current due to a certain pot-tending need. Voltage measurement on the delta busbar of the fixed ratio 220/33 kV, 51 MVA, Single Phase Stepdown transformers serves mainly to provide a reference signal to the gate control of the thyristors. When this input measurement disappeared, the rectifiers became inoperable, which resulted in freezing of the pots. In spite of successful cold restarting of the 160 frozen pots in the period 16 July through 31 August 2006, this event cost at least USD30 million. Therefore Isal undertook a number of minor improvements from June 2006 to January 2007 to avoid a reoccurrence of this rare phenomenon. However the major risk mitigation still remained to be realised. In December 2006 the then owner of Isal, Alcan, carried out a 132 kV GIS (Gas Insulated Switchgear) operated at 60 kV 62 due diligence analysis on site Straumsvik with experts of Isal to evaluate the power supply availability to the three potlines. This Hazop Risk Analysis revealed severe weaknesses in the design of the main power supply, when confronted by a number of common mode failure scenarios. It was obvious that these weaknessess could only be corrected by major strengthening of the power system. The concept chosen in a specification made by Isal and Alesa, an engineering company of Alcan and now of Rio Tinto Alcan (RTA), was to design a new 220 kV bay feeding 2 x 75 kA, 900 V DC, swing rectifier units of thyristors, thus virtually bypassing the existing power supply system. The swing rectifiers can be operated in parallel with each of the rectifier stations A, B and C, serving all three potlines. The rated power capability of this enhanced reliability system is 200 MVA on the 220 kV side and 150 kA, 900 V on the DC side. The normal operating voltage of the potlines is only 720 V DC, while the high voltage capability allows for restarting a potline on the verge of freezing, e.g. after a grid failure, as there is then no reserve power supply for the Isal smelter. In March 2007 a referendum was held in the nearby municipality of Hafnarfjördur, a few kilometres from the existing smelter in which the public rejected a new smelter for Isal. Then Isal proposed a plan B of enlarged production capability of the existing smelter from 190 to 230 kt/a with a potential for further creep. This was approved by the new owner, RTA. The concept is to add a stepdown transformer, 200 MVA, and two thyristor rectifiers, 75 kA, 900 V DC, dedicated to Potlines 1 and 2 for the creep concept. The idea is to continue operation of the four old rectifier units for each of the Potlines 1 and 2 as the most valuable part of this equipment has a remaining lifetime of some 30 years. Then normal ALUMINIUM · 1-2/2013 SPECIAL operation will constitute four old units at some 112 kA and a new unit at some 74 kA (in total 186 kA) in Potlines 1 and 2. This can also be accomplished in (n-1) operation. Two out of three plant power transformers were upgraded from 15 to 30 MVA. One of them was needed to cope with higher load of the gas treatment centres for the pot fumes, and the upgrade to cope with an electric furnace in the casthouse to homogenise extrusion billets. Billets are a new product type of Isal, replacing the hot rolling slabs. The feeder of the plant power transformer supplying auxiliaries of Potline 3 was relocated from 33 kV busbars to the new 60 kV GIS-busbars. The latter are equipped with sectionalisers enabling load transfer between stepdowns on each 220 kV line without affecting the potline operation, which is a step forward for Isal. The reason for preferring GIS to AIS was lack of land at the seaside of the substation. The benefit of the feeder relocation is not only for higher reliability of the power supply. It also means that the 15 MW power formerly allocated for plant power can now be transferred to the rectifier station, thus yielding 180-185 kA permissible current intensity from rectifier station C, instead of 168 kA previously. The new power contract with the National Power Co. and the transmission agreement with the TSO, Landsnet, is for delivery of 425 MW at power factor over at least 0,98 for a calendar month. In addition to this high reactive power compensation, the TSO also requested thorough filtering of harmonics, keeping each voltage harmonic under 1,0% and the total voltage distortion factor below 1,5% at the Isal 220 kV intake. This demanded a sophisticated engineering of 2x85 MVA filters connected to the 60 kV busbars. Immediately useful Overhaul of transformers and rectifiers was postponed under the IPU Construction Period to avoid a crowded construction area and to reduce production loss and disturbances to the electrolysis. This would have inflicted considerable losses to Isal, as it was not possible to weld busbars on full potline current intensity. This is the main explanation for the higher than expected fault rate of equipment under the commissioning period. One regulating transformer failed in each of the rectifier stations A and B, and then, at short notice, the new rectifier sections A5 and B5 had to be temporarily put into operation in order to ALUMINIUM · 1-2/2013 A L U M I N I U M S M E LT I N G I N D U S T R Y keep full potline current, 133 kA. The transformers tap changers were repaired on site. While leakage in a rectifier transformer in station B was being repaired, the damping units for one of the rectifiers B took fire. Then only two old units were available for Potline 2. This would not have been a sustainable situation for this Busbar system with FOCS (Fibre Optic Current Sensor) potline, i.e. its current intensity would have been 80 kA only out control system for Potline 1 in Straumsvik of 133 kAm or 60%. The electrolyte tem- until the commissioning of the 4 x 75 kA rectiperature would have approached its freez- fier units and their power supplies in autumn ing point while repair of the damping unit 2012. This cooperation has been beneficial to took place. It is likely that some pots would both parties. have been lost, and the operational stabilIcelandic companies have never played so ity and efficiency of others would have been big a role in realisation of an ABB project in adversely affected. The electrolysis costs and Straumsvik as in the IPU Project. Orkuvirki lost revenue due to such a serious situation can has erected all the equipment and has engibe estimated to USD1,5 million. As new units neered and assembled a number of switchgear were made available to the Isal operation by and controlgear units. Staki has developed the ABB, full current intensity could be kept in the software of the master controller of each potpotline during this critical situation. line as well as the software of the supermaster All this delayed the hot commissioning and of the SCADA. All this has been accomand disturbed the schedule of ABB; however, plished in good relationship with the owner of ABB, its subcontractors and Isal gained valu- the systems, Isal, which has been closely conable experience. sulted at each stage and made contributions to Spooky damage to control equipment like the technical developments as well. coils and control valves was observed during The technical infrastructure delivered to this period. We identified the origin by ana- Isal is in accordance with the technical specilysing the voltage quality on the 60 kV bus- fication made jointly by Alesa, an engineering bar feeding the new plant power transformer, company of RTA in Zürich, Switzerland, and which supplies the auxiliary voltage to the new Isal, prior to the bidding process of the IPU system, S, and the existing system C. With project. new rectifier units in operation without any The power and control system of the subfilter ON, the voltage contains a lot of har- station of Isal is a state-of-the-art solution for monics with Total Voltage Distortion Factor, the complicated task of extending a power TVDF = 10. It was therefore decided to mod- distribution system of an over 40 years old ify the control concept of the filters. Instead aluminium smelter in full production. This was of being switched on when the reactive power accomplished without any injury and without demand is about 30 MVAr, the first part of any major damage to the smelter’s equipment. the filter is switched on after switching on Isal looks ahead to a prosperous future of the first rectifier transformer, but before it is an ever increasing production capacity, higher loaded. With the filter of the third harmonic productivity and improved reliability of power on, the voltage is a true sinus curve, and the supply to the electrolysis pot lines and to the voltage quality is even higher when switch- plant as a whole. ing on the filter for the fifth and eleventh harmonic as the first part. Authors Conclusion The fruitful cooperation between ABB Switzerland and Isal has now lasted for about 45 years from the engineering of the power and Bjarni Jonsson is leader of Electrical Services of Rio Tinto Alcan, based at Icelandic Aluminium Ltd, Straumsvik, Iceland. Max Wiestner is manager of the business group Primary Aluminium which is part of the ABB Global Product Group, based in Dättwil, Switzerland. 63 A L U M I N I U M S M E LT I N G I N D U S T R Y Applying computational thermodynamics to industrial aluminium alloys P. Mason and H.-L. Chen, Thermo-Calc Software Even more than GPS and Google Earth have changed our view and navigation of the world, so computational thermodynamics is changing the way metallurgists see what goes on inside alloys during solidification and heat treatment. This tool gives us new and more detailed views of the phase diagrams of almost all the commercial aluminium alloys. But it also lets us explore the phases in new alloys which have never yet been made. Thus we can now study phases in virtual alloys without using real materials or laboratory instruments and equipment. Compared with actually casting and heat treating alloys for metallurgical studies, and then preparing and interpreting the samples, computational thermodynamics represents huge savings in time and expense. Computational thermodynamics has been used in the aluminium industry for more than two decades in order to understand and model the behaviour of existing alloys, to accelerate the development of new alloys, and also to give insight into improvements in the areas of process optimisation and the simulation of casting and heat treatment. During this time, the CALPHAD (CALculation of PHAse Diagrams) approach [1] and related software packages and databases have made significant contributions in this area. This trend has gained added momentum in recent years with the publication by the National Academies report on Integrated Computational Materials Engineering (ICME) in 2008 [2], and with the announcement by President Obama of the Materials Genome Initiative (MGI) in June 2011 [3]. ICME is an emerging discipline that can accelerate materials development and unify design and manufacturing. To quote from Wikipedia: “Integrated Computational Materials Engineering (ICME) is an approach to design products, the materials that comprise them, and their associated materials processing methods by linking materials models at multiple length scales.” This is similarly linked to the goals of the MGI which aims to double the speed with which new materials are developed, manufactured and bought to market, thus increasing innovation and competitiveness while also reducing cost and time. 64 Computational thermodynamics is a foundational component of ICME since it fundamentally links the phases that form, and hence their microstructure, to the chemical composition of an alloy, and also the temperature variation that a material may be subjected to. It is also essentially the driving force for many of the phase transformation reactions that take place during materials processing. The CALPHAD approach such as DICTRA and TC-PRISMA. These are respectively computer programs for simulating diffusion-controlled phase transformations and for simulating multi-particle precipitation kinetics in multicomponent alloy systems. Through the use of such simulations it is possible to optimise alloy compositions and to predict optimal solidification processes and solution heat treatment temperature ranges all this without performing many time-consuming and costly practical experiments. CALPHAD technique uses all available ther- Thermodynamic and kinetic databases mochemical information, both thermodynamic and phase equilibria data, to fit model pa- The quality of the predictions depends rameters used to describe the Gibbs energy strongly on the quality of the thermodynamic of individual crystallographic phases. The ob- and atomic mobility databases that are used. jective is to obtain a consistent set of model TCAL1 is a new thermodynamic database deparameters that can describe the thermody- veloped by Thermo-Calc Software which connamic properties of the system in a realistic tains all the important Al-based alloy phases way. The Gibbs energy of each phase is de- within a 26-element framework [Al, Cu, Fe, scribed by an appropriate thermodynamic model which depends on its physical and chemical properties, for example, crystallography, type of bonding, order-disorder transitions, and magnetic properties. These Gibbs energy functions, which take into consideration chemical composition and temperature dependence, are obtained by the critical evaluation of binary and ternary system and then through the use of software, such as ThermoCalc, multicomponent calculations can be made for alloys of industrial Fig. 1: Equilibrium solidification and Scheil solidification simulations of alimportance, based on the loy AA7075, compared with experimental results from Bäckerud et al [8] constraints of compositon, temperature and pressure for the system as a Mg, Mn, Ni, Si, Zn, B, C, Cr, Ge, Sn, Sr, Ti, V, whole. Zr, Ag, Ca, H, Hf, K, La, Li, Na, Sc]. This inAdditionally, the CALPHAD method can cludes in total 346 solution and intermetalalso be extended to model atomic mobilities lic phases are included. Developed using the and diffusivities in a similar way. By combin- CALPHAD approach, TCAL1 is based on ing the thermodynamic and mobility data- critical evaluations of binary, ternary and even bases, it is possible to simulate kinetic reac- higher order systems which enable making tions during solidification and subsequent heat predictions for multicomponent systems and treatment processes by using other software alloys of industrial importance. A hybrid ap- ALUMINIUM · 1-2/2013 SPECIAL proach of experiments, first-principles calculations and CALPHAD modelling have been used to obtain thermodynamic descriptions of the constituent binary and ternary systems. In total, 147 of the binary systems in this 26-element framework have been assessed to their full range of composition. TCAL1 also contains assessments of 58 ternaries in the Al-Cu-Fe-Mg-Mn-Ni-Si-Zn system. In addition, twelve quaternaries and one quinary system have been assessed. MOBAL2 is a kinetic database containing mobility data for the liquid and fcc phases in Al-based alloys within a 23-element framework [Al, Cu, Fe, Mg, Mn, Ni, Si, Zn, Cr, Ge, Sn, Sr, Ti, V, Zr, Ag, Ca, Hf, K, La, Li, Na, Sc]. For the FCC phase, the database contains assessed impurity diffusion data in Al for all included elements. It also includes complete and critical assessments in some important binary systems. As for liquid, there are also assessed data for diffusion in liquid Al for Al, Cr, Cu, Fe, Ge, Mg, Mn, Ni, Si, Ti, V, and Zn. The TCAL1 and MOBAL2 databases are the result of a longterm collaboration with academia that has involved extensive experimental work, as well as critical assessments of the published literature. Both databases have also been validated where possible against higher order systems, such as data published for industrial alloys. Such validation highlights the key systems which are the basis of many of the commercial aluminium alloys to which care of special practical importance. Take for example, the AA-7000 series alloys, which are high strength, high toughness alloys often used in high performance applications such as aircraft, aerospace and competitive sporting equipment: these alloys are based around the AlCu-Mg-Zn system. In spite of the addition of other minor elements like Mn and Si etc., the main hardening elements Zn, Mg and Cu play a dominant role in the formation of the main precipitate phases such as C14 (MgZn2, the η phase), S (Al2CuMg) and T (which is stable in the Al-Cu-Mg, Al-Mg-Zn and Al-Cu-Mg-Zn ternary systems). In some cases, the formation of the Al7Cu2Fe phase may also be important. These phases dominate the balance of the properties, and their amounts are closely related to the composition and to the heat treatment conditions. In TCAL1, the thermodynamic description of the Al-Zn-Mg-Cu-Fe core system has been systematically refined and validated in order to give more accurate predictions for these commercial Al-based alloys. More specifically, crucial corrections or modifications have been made for the following related ternary systems: Al-Cu-Fe, Al-Cu-Mg, Al-Cu-Zn, and Al-Mg-Zn. A L U M I N I U M S M E LT I N G I N D U S T R Y tion during solidification. For example Onda et al [5] investigated the solidification of alloy AC2A. The authors noted: “Prediction of the solidification model by thermodynamic calculations is useful from a practical point of view.” However, equilibrium thermodynamic calculations, while useful, do not consider the dynamic effects of time. DICTRA is a software tool used for detailed simulations of diffusion-controlled phase transformations for multi-component alloys where time diffusion is a parameter. Example applications include the simulation of microsegregation during solidification, heat treatment, growth and dissolution of precipitates, and coarsening. Senaneuch et al [6], for example, used DICTRA to look at diffusion modelling in brazed aluminium alloy components; and Samaras et al [7] simulated the evolution of the as-cast microstructure during the homogenisation heat treatment of alloy AA6061. In the latter paper, the alloy microsegregation, which results after casting, was calculated with the Scheil module using Thermo-Calc, and the microstructure evolution during homogenisation was then simulated with DICTRA. The composition profiles of the alloying elements, and the volume fraction of the secondary phases, were calculated as a function of homogenisation time. Comparison with experimental work concluded: “The model reproduces the homogenisation kinetics reasonably, and it is capable for the prediction of the homogenisation heat treatment completion times.” Two examples in the areas of casting and heat treatment using Thermo-Calc in conjunction with TCAL1 are illustrated below. © Molten Metal Level Control Thermodynamic and kinetic simulations Predictions for multicomponent systems are useful, since they show what phases could form at different temperatures during processing and operation, for different alloy compositions, both under equilibrium and under non-equilibrium conditions. Phase diagrams make it possible to see how an element is influencing the phase stabilities and solubilities of different elements at varying temperatures. For example, Thermo-Calc can be used to predict second phase particles that are formed during casting, homogenisation, downstream rolling and annealing. Gupta et al [4] performed such a study to validate calculations of phase stability made using Thermo-Calc against experimental observations for automotive alloy AA6111, which is a commercial body sheet alloy. The paper concluded: “The type of particles, and the temperature regime in which they are formed, are consistent with the predictions made by the Thermo-Calc software.” The Scheil model in Thermo-Calc can also be used to predict non-equilibrium solidification behaviour and micro-segrega- ALUMINIUM · 1-2/2013 7KH3UR+'LJLWDO&DPHUD6HQVRUFRPELQHV KLJKSHUIRUPDQFHWULDQJXODWLRQWHFKQRORJ\ ZLWKDOOWKHFRQWUROIXQFWLRQV\RXQHHGWR PDLQWDLQDQDFFXUDWHPROWHQPHWDOOHYHO 7KH3UHFLPHWHU*URXSGHYHORSVSURGXFHVDQG VHOOVVROXWLRQVIRUPROWHQPHWDOOHYHOFRQWURO :HRIIHUDZLGHUDQJHRI HTXLSPHQWLQWKLVLQGXVWU\ 3OHDVHYLVLWRXUKRPHSDJHIRUPRUHLQIR ZZZSUHFLPHWHUFRP 35(&,0(7(5&21752/$% gVWUD+DPQHQ6(+|Q|6( 3KRQH)D[ PDUNHWLQJ#SUHFLPHWHUFRP 65 A L U M I N I U M S M E LT I N G I N D U S T R Y alloys allows the metallurgist to optimise, control and generate a reproducible and predictFor fabricating aluminium alloys, it is useful able change in the microstructure of the alto understanding solidification during cast- loy. This serves to influence properties such as ing and to predict the phases that are likely strength, ductility, fracture toughness, thermal to precipitate during cooling. A Scheil solidi- stability, residual stress, dimensional stability fication calculation of the alloy AA7075 was and resistance to corrosion and stress corroperformed by using the real alloy composition sion cracking [9]. The main heat treatment (Al, 0.11 Si, 0.28 Fe, 1.36 Cu, 2.49 Mg, 0.19 procedures for aluminium alloys are homogenisation and annealing, as well as precipitation hardening, which involves the three steps of solution heat treatment, quenching and aging. Computational modelling tools, such as those described here, can give insight into each of these stages. For example, the purpose of solution heat treatment of aluminium alloys is to put the maximum practical amount of the hardening solutes, such as Cu, Mg, Si, Zn or other elements, into a state of solid solution in the Al matrix. Multicomponent phase diagrams calculated using Thermo-Calc can aid this type of analysis without the need to perform timeFig. 2: Calculated isothermal section of the Al-Cu-Mg-Zn quaternary system at 600 °C and 6 wt.% Zn compared with experimental work of consuming experiments. Strawbridge [10] The 7000-series alloys Cr, 5.72 Zn, wt.%). The calculation predicts are heat-treatable wrought aluminium alloys, that Al45Cr7 solidifies primarily before the and it is useful to perform equilibrium calcuformation of (Al) although it had not been lations at solution treating temperatures and experimentally observed. Considering that it at aging temperatures in order to predict the is probably the only Cr-bearing phase in this phase formations in these alloys. As an examalloy, its formation would be almost certain. ple, Fig. 2 shows a calculated isothermal secDue to its small amount, however, its forma- tion of the Al-Cu-Mg-Zn quaternary system tion can hardly be observed in the DTA trace at the typical solution treating temperature of or in the solidified microstructures. The for- 460 °C, and at a Zn content of 6 wt.%; the calmation of (Al) was followed by the Al13Fe4, culation was in very good agreement with the Mg2Si, T and V (MgZn2) phases, which agrees experimental data from Strawbridge et al [10]. well with the experimental results. Imposed This diagram can be used to generally account on the diagram shown in Fig. 1 (see previous for the phase constitution at the solution tempage) are the accumulated solid phase frac- perature for a number of 7000 series alloys, tions at different temperatures, which have e. g. AA7010, AA7050, AA7075, AA7175, been evaluated from the experimental DTA AA7475 and AA7178, etc. Andreatta [11] retrace obtained by Bäckerud et al [8]. It should ported that Al7Cu2Fe and Al23CuFe4 are the be noted that DTA can only allow a qualitative most abundant of the intermetallics in AA7075 evaluation. Nevertheless, it is suggested by and AA7475, together with traces of Mg2Si, the comparison that the real solidification sig- Al6Fe, S, T and Al12(Fe,Mn)3Si, after being nificantly deviates from the equilibrium solid- solution treated. In such cases, it is necessary ifi-cation, but can be reasonably approximated to perform equilibrium calculations using real by a Scheil solidification simulation. alloy compositions by including other minor elements. Because of the high Fe content, the calculation using TCAL1 shows that Al7Cu2Fe Heat treatment forms in alloy AA7075 with an amount up to The controlled heat treatment of aluminium 1%, and Al13Fe4 coexists in a small amount. Casting and solidification 66 However, for alloy AA7475, Al7Cu2Fe is calculated to be the only main intermetallic. Summary The materials community is increasingly using computational modelling tools, and is applying them more widely to material design and process optimisation. For more than two decades, CALPHAD- based software and databases have been employed within the aluminium industry and they have served to improve the understanding of existing alloys, to accelerate the development of new alloys and also to model and understand better materials processing routes. The quality of the predictions depends on the quality of the thermodynamic and kinetic databases that they use. Some examples have been given here to illustrate how these tools are being used within the aluminium industry in the areas of casting and solidification as well as heat treatment. References [1] N. Saunders, A.P. Miodownik, Calphad (Calculations of Phase Diagrams): A Comprehensive guide, Pergamon Materials Series, vol. 1, ed. R.W. Cahn (Oxford, OX: Elsevier Science Ltd, 1998). [2] National Research Council, Integrated Computational Materials Engineering: A Transformational Discipline for Improved Competitiveness and National Security. Washington, DC: The National Academies Press, 2008. [3] http://www.whitehouse.gov/sites/default/files/ microsites/ostp/materials_genome_initiative-final. pdf [4] A.K. Gupta et al., 2006, Materials Science Forum, 519-521, 177 [5] H. Onda et al., 2007, Materials Science Forum, 561-565, 1967 [6] J. Senaneuch et al., 2002, Materials Science Forum, 396-402, 1697 [7] S.N. Samaras, G.N. Haidemenopoulos, 2007, Journal of Materials Processing Technology, 63-73, 194 [8] L. Bäckerud, G.C. Chai, J. Tamminen, Solidification Characteristics of Aluminium Alloys, Vol. 1 and 2. Sweden (1990) [9] H. Moller, 2011, Heat Treatment of Al-7Si-Mg casting alloys, Aluminium International Today, 1618, Vol 23, No 6 [10] D.J. Strawbridge, W. Hume-Rothery, A.T. Little, The constitution of aluminium-copper-magnesium-zinc alloys at 460 °C. J. Inst. Metals (London) 74 (1947) 191-225 [11] F. Andreatta, Local electrochemical behaviour of 7xxx aluminium alloys, PhD thesis, 2004 Authors Paul Mason is president of Thermo-Calc Software Inc., based in McMurray, PA, USA. Hai-Lin Chen is with Thermo-Calc Software AB, based in Stockholm, Sweden. ALUMINIUM · 1-2/2013 SPECIAL A L U M I N I U M S M E LT I N G I N D U S T R Y ECL – A privileged equipment supplier to the primary aluminium industry A.-G. Hequet, ECL Created in 1947 and based in Ronchin, a suburb of Lille, ECL entered the aluminium business in 1955. In 1962 it commissioned the world’s first pot tending machine. By the 1970s the company concentrated mainly on the aluminium industry and has become a key partner of most smelters around the world. It is now part of the Rio Tinto Alcan group and its products are used in the reduction, carbon and casthouse areas of the smelter. The product range includes pot tending machines, cranes and transfer equipment for the potlines, as well as a wide range of products and services for the carbon sector. These include green and baked anode handling equipment and specialised cranes, complete anode rodding shop, and metal and bath handling systems. The involvement of ECL does not end with the conception, production, erection and commissioning of its products. The company offers a wide range of supporting services including training, technical assistance, spare parts, on-site maintenance management, equipment audits, refurbishment and upgrades. The machines are adaptable to all the potline technologies used in today’s smelters. To better serve its customers around the world on a 24/7 basis, ECL has a network of seven subsidiaries around the world. © ECL Solutions for all sectors of the aluminium smelter ECL Pot Tending Machine ALUMINIUM · 1-2/2013 Reduction: Pot equipment is a significant part of what ECL offers to the reduction sector, with more than 15,000 pots equipped by the company worldwide. However, ECL’s flagship product is doubtless the Pot Tending Machine (PTM). Adaptable to all the reduction technologies, each crane is designed to each smelter’s specification. The ECL PTM is still evolving: safer, more efficient, more reliable and more compact, while also being cheaper to commission and to operate. The potline offer also includes anode beam raising mechanisms, anode jacking frames, crust breaking and feeding devices, J hooks and fixings, anode clamps and sealing jaws. Carbon: ECL offers equipment for the whole carbon sector, from single machines to turnkey rodding shops for all types of anodes, including the building. The company also delivers furnace 67 A L U M I N I U M S M E LT I N G I N D U S T R Y tending assembly and fully automated anode handling shops: green and baked anode handling cranes, transfer cranes, conveyors, cooling tunnel and anode hole cleaning machine. Services: As mentioned above, ECL provides an exhaustive range of services, either from the main base in Ronchin, France, or through its subsidiaries. Innovation: ECL is also a driving force when it comes to innovation. The ECL R&D department is constantly working on new ways to make aluminium production safer, easier, more productive, and to make sure the equipment meets the ever increasing environmental and safety requirements. 30,000 hours are dedicated yearly to R&D. Research focuses on HSE innovations, equipment cost reduction, operational cost reduction, and on automated equipment, through a combination of theory, experiment and computational simulation. Recent technological advance – the ‘New Concept Furnace Tending Assembly’ Since ECL commissioned the first anode baking Furnace Tending Assembly (FTA) in 1963 in Slatina, Romania, the designs and tasks of ECL Furnace Tending Assembly this machine have evolved. For the first time in the industry’s history, ECL has performed a total rethink of the FTA, based on: • A modular structure providing higher per- 68 formance in terms of: safety, shorter commissioning time, productivity, quality as well as operational cost savings • A streamlined architecture, giving significant weight and height reductions • The possibility to have one or two grabs and / or one or two filling pipes on the crane • Better, faster and more efficient coke suction flow rates, speed of movement of the tools • An evolutionary design greatly improving maintenance access and costs and ergonomics. Consequently, the ECL New Concept FTA is lighter and more compact and has improved performance. Its new design has been conceived to make human intervention easier and safer: operators benefit from an ergonomic cabin and from easy access for maintenance. The ECL New Concept FTA is based on a modular structure that offers several advantages over conventional designs. First, it is lighter than a regular crane. As the FTA is the main piece of equipment supported by the anode baking furnace building’s rails, this weight reduction has a direct impact on the design and cost. The modular concept leads to a simplification of the FTA’s overall structure. Each of the crane’s constituent elements and the links between them (pneumatic, electric and optical) have gone through a total rethink that makes them individual modules rather than imbricated elements. The result is a crane that is faster to commission and easier to maintain. Furthermore, the FTA tools dedicated to work on the pits have been located differently, which greatly improves the operator’s view. Consequently he can more accurately control the tools’ movements and can reduce damage to the tools and flue wall. The modularity of the cranes also allows flexibility in implementing upgrades. A second grab and or a second filling pipe can be installed on a machine to match any later increase in anode production. Whereas the design of all FTAs is made according to the customer’s requirements, the ECL New Concept FTA, ensures that it keeps room for later improvement and development. In such a harsh environment of heat, gas, and dust, it is essential to prioritise environ- ment, health and safety for the smelter but above all for the operators. The ECL R&D department focused especially on providing an ergonomic cabin, and they paid special attention to air quality and temperature control, visibility, safety and reliability. To minimise the safety risks (falling, pinching, crushing, suffocation) ECL equipped its crane with safety features: • A retractable step ladder with guardrail provides to access the crane • An emergency evacuation access is available whatever the position of the main trolley, in case of a power cut or damage to tools in the furnace • Many more emergency stop push buttons surround the workplace • Relocating floodlights improves lighting and avoids shadows • Stairs instead of ladders between the different platforms on the crane provide a much easier way to transport a maintenance tool box. The cabin has been also subject to many changes and turned into a shell around the operator. The cabin is more spacious: its size increased by 75%, which brings many advantages. The operator benefits from a 70% wider window area, thereby bringing a brighter environment and better visibility. With a 10 metres visibility under the cabin, the operator is now able to see into the bottom of the pit, which greatly eases the operation of coke filling and sucking. Now two to three people can fit in the cabin at the same time, providing good conditions for training and management purposes. Seats have been rethought and are now motorised, enabling cross travel movements to facilitate and ensure seat position accuracy perfectly in front of the tools. The seat includes height adjustment as well as air and mechanical suspension, arm support and body fixation for greater ease and flexibility. As an option, cameras can be installed on the suction pipe to improve the overall operator’s safety observation without back bending. The operator can also adapt the control units (joystick) according to his morphology. All these features facilitate the driving of the FTA and considerably reduce fatigue of the driver. Easier maintenance, safer and cheaper By redesigning its FTA, ECL has greatly improved the operator’s working environment, but has also facilitated maintenance work, for which access was difficult to some key areas. The New Concept FTA is now equipped with several onboard platforms which include: ALUMINIUM · 1-2/2013 SPECIAL A L U M I N I U M S M E LT I N G I N D U S T R Y • A complete upper platform gives full access to the grab hoist unit, to the top of the storage hopper (sucking pipe elbow), and to the top of the filter hopper to perform filter bags changing • A maintenance platform provides access to the valve situated between the cyclone and the filter hopper, and to the valve used to control the de-dusting sucking during the pit filling phase • A platform is situated at the top of the sucking pipe • The 25-tonne hoist is now directly accessible from a platform above the main trolley • A platform links the top of the FTA girder to the long travel maintenance platform • Lifting points and lifting rails installed directly on the crane facilitate the dismantling of heavy components not directly accessible (moto-reducer, air condition unit, hoist unit). No effort has been spared in ensuring safety of both the operator and the maintenance staff. The large number of on-board platforms makes obsolete any external mobile platform which was often unavailable when needed, and always cumbersome. A New Concept FTA combining reliability and greater performance A double filling pipe: The new architecture of the FTA is based on a double filling pipe assembly; these pipes can be used individually or simultaneously. Compared with a conventional FTA (1 filling pipe, 1 grab and 1 sucking pipe) this system of double filling pipe increases by almost 10% the FTA utilisation rate and therefore productivity. The utilisation rate is carefully computed by ECL engineers to match the customer’s production needs, while keeping a capacity back-up of at least 25%. This approach ensures that the FTA is not oversized (therefore not over-priced) and reliably meets the anode production requirement. ECL engineers also worked to make the filling pipe more resistant to shocks, to variations of coke temperature, and to the risks of pipe blocking and falling. The pipe has therefore become wider and shorter. Reduc- can reach a suitable level of dexterity both ing the pressure drop and consequently the through PTM and FTA driving exercises. The abrasion and maintenance costs for the suc- programme grades trainees after each exertion circuit. Stronger bumpers have been installed. The nozzle of the filling pipe has been modified in order to ease conical flow and to decrease the time of filling. Regarding the flexible de-dusting pipe located on the filling pipe, it has been replaced by an outside mechanical pipe. This solution eliminates all risk of friction between lifting cable and de-dusting system as well as any risk of tearing the de-dusting pipe. A powerful sucking pipe, from 65 to 110 m3/h: this new Training in a simulator capacity of the sucking pipe set up in the FTA almost doubles the suction cise in the simulator. Thus the trainer and the rate. Moreover, the sucking pipe is equipped trainee have a global view of the progress with a new shock absorption system, so avoid- achieved and of what competences still need improvement. ing the risk of crushing the pipes. In the second technical container the Towards a fully automated FTA: What about a crane in a few years time operating trainees can practice on real devices (compreson its own in this harsh environment? The sors, etc.). Training is crucial for success, and FTA is already equipped with some automatic is fruitful for both employers and employees sequences, such as automatic positioning of a smelter. When well trained, the operator over the pits, to assist the operator in his daily will become more efficient, productive and tasks. The ECL R&D department is never at a valuable asset to the smelter, needing less rest, and is always looking for more automa- supervision. This will lead to fewer accidents, less equipment damage and consequently tion processes to include in the FTA. costs, better productivity and better quality. Technicians and operators from different ECL Training Academy smelters can share their experience and learn ECL has recently launched a customised train- from each other’s know-how. A first session was organised in Dubai in ing programme dedicated to operators and maintenance technicians. This programme is a 2011 to meet with ECL customers from the unique opportunity to improve skills, capabili- Middle East, and a second session in Canada ties and knowledge on crane operations and in 2012. Here is the reality: produce more, faster, maintenance of ECL equipment sub-assemblies (hydraulic, pneumatic, mechanical and at a lower cost and in a safer way. ECL is electrical). The programme consists of five full constantly innovating, and both The New days of training session right on the doorstep Concept FTA and the ECL Training Academy greatly help to achieve all this. of our customers. Two special technical containers allow trainees to practice right after theory. The Author first container is equipped with a multipurpose driving crane simulator. In it trainees can Anne-Gaëlle Hequet is External Communication improve their accuracy and rapidity, and manager at ECL, based in Ronchin, France. Suppliers Directory – for your benefit On pages 100 to 113, leading equipment suppliers to the aluminium industry present their product portfolios and ranges of services. Take advantage of this useful information. ALUMINIUM · 1-2/2013 69 A L U M I N I U M S M E LT I N G I N D U S T R Y Novel gas cleaning for anode baking furnace B. Herrlander, Alstom Power © Alstom Power In November 2011 Alstom started the novel gas cleaning plant for the anode baking furnace at Alcoa Mosjøen, Norway. This Fume Treatment Centre (FTC) comprises a new gas cooling principle that replaces the conventional conditioning tower with a heat exchanger. The AHEX heat exchanger has the dual purpose of cooling the flue gas while it simultaneously works as a reactor for capturing tar and HF on alumina. The heat exchanger is integrated into the filter, which thus constitutes a very compact FTC design. The Årdal DDS The novel FTC concept Even though improved state-of-the-art firing technologies on today’s open anode baking furnaces have significantly reduced the emissions, there is still a need for further gas cleaning to meet regulations. The main furnace emissions are compounds in the flue gas such as PAH (Polycyclic Aromatic Hydrocarbons), HF, SO2 and carbon particles. HF emissions originate from the recycled butts used in the anode production and PAH from the green anode material. A number of PAHs are known for their carcinogenic, mutagenic and teratogenic properties. These include benz[a]anthracene*, chrysene*, benzo[b, j, k]fluoranthene*, benzo[a]-pyrene*, The integrated Alstom AHEX FTC 70 benzo[ghi]perylene, dibenz(a,h)anthracene* and indeno(1,2,3-cd)-pyrene* (*classified by the US EPA as probable human carcinogens). Some of these compounds are subject to emission limits set by government authorities. These are typically expressed as subsets of the various PAHs such as PAH-16 and OSPAR 11, which are subsets including 16 or 11 different PAHs. The abatement of PAH is temperature-dependent in such a way that the removal efficiency increases by lowering the flue gas temperature. The novel FTC with AHEX solves a number of problematic issues related to the traditional conditioning tower filter combination. The conditioning tower evaporative cooling principle increases the flue gas moisture content, typically by some 6-7%, to reach the acceptable operation temperature levels around 100-110 °C. However, a drawback of this method is that the increased moisture content may cause corrosion in the conditioning tower and hydrolysis of the bag polyester material in the fabric filter. By contrast, the gas cooled in the AHEX avoids this humidity increase, and thus prevents the above problems. Now, as the temperature is lowered in the AHEX, various tars (including PAH) start to condense. In order to prevent these from fouling the AHEX tubes, we inject alumina upstream. This measure ensures there is a controlled condensation of tar on the alumina. The alumina also adsorbs HF and to some extent SO2. Since the tar will end up on the alumina for the potlines, there is no need for disposal of hazardous material. Conventional conditioning tower cooling may occasionally cause wet bottom with tar-rich effluents, and it will inevitably result in tar deposits in the ducts connecting to the filters, from where it must be removed and safely disposed of as hazardous material. With AHEX no such ducts are required as AHEX is integrated in the fabric filter unit. This novel FTC with AHEX is built on Alstom’s DDS (Distributed Dedicated Scrubber) concept. The DDS is based on the well-proven Abart dry scrubbing technology, which features a two-stage counter-current gas cleaning process. It was designed for greenfield as well as for retrofit / modernisation projects, for applications where space is limited, or where the customer needs to minimise the resources used for site installation / erection. The DDS invention has been granted patents in all major aluminium producing countries. The DDS integrates fresh alumina storage, and it is equipped with an internal alumina handling system powered by one high pressure fan. Enriched alumina from the DDS is distributed back to the pots via Alstom’s Alfeed system. There is one exhaust fan per filter compartment, which operates on medium voltage (440 V). This allows full flexibility for tuning the DDS for optimal performance. The DDS is supplied in modules, which makes it easy to transport and install. The DDS can be fully shop-manufactured, as the size of a DDS compartment meets road transportation requirements. Shop fabrication ensures a uniformly high quality of work. Several DDS can ALUMINIUM · 1-2/2013 SPECIAL be erected simultaneously and independently. The DDS system may integrate a SO2 scrubber on the top, which enables it to comply with more stringent emission limit values. The available reagent choice is between an alkaline solution or seawater. This DDS / SO2 technology will be in operation around the middle of 2013 at a smelter in Europe. The AHEX is integrated to the DDS, upstream of the filter stage. The hot gas, containing the condensable fumes, is cooled inside multiple water-cooled steel tubes in the AHEX, where it enters the cooling tubes from the top. The fumes are mixed with alumina in the plenum upstream of the tubes inlets. The hot fumes include condensable tar components, which during the gas cooling condense on the alumina surface. Simultaneously HF and to some extent SO2 is adsorbed. Due to the efficient mixing of alumina and gas inside the heat exchanger tubes, the AHEX FTC absorbs more than 95% of the HF and tar on the alumina. The efficient collection of tar aerosols on the alumina particles reduces the risk of tar depositing on the heat exchanger surfaces. In addition the injected abrasive alumina particles will clean the surfaces of possible deposits, as demonstrated in the earlier trials in the ME, which were the basis for this patented design. Control or elimination of fouling of heat exchanger surfaces has been the main driver behind Alstom’s development of this new fire tube heat exchanger. Alstom has long-term experience with fire tube heat exchangers on similar or more difficult flue gases, such as from Fe/Si- and Si-metal furnaces. Over the last three years this technology has also been proven for potgas in full-size demonstration units (EHEX, MHEX, IHEX) at Alcoa Mosjøen in Norway. The adsorption process is enhanced by the even gas / particle distribution, relatively long retention time and short mixing length within the confined space of the multiple parallel tubes. The dry process of the novel AHEX FTC, allows the gas to be cooled to temperatures below 105 °C, possibly even below 80 °C. This allows for further condensation of PAH and improved cleaning efficiency. After leaving the heat exchanger the cooled gas enters directly into the dry scrubber, where the main part of the injected alumina is separated into the filter hopper and re-circulated directly back to the heat exchanger inlet. Primary alumina is injected into the filter compartment and collects on the bags in a final polishing stage to adsorb any trace components of tar fumes and HF. Through an overflow device in the filter hopper the re-circulated or spent ALUMINIUM · 1-2/2013 A L U M I N I U M S M E LT I N G I N D U S T R Y alumina leaves the system to be sent to the pots. The new AHEX FTC can efficiently handle a larger variation of the flue gas flow than today’s systems. There is no need to re-circulate the gas, as is common for the conditioning tower-based FTC. The heat energy recovered in the AHEX may be used or disposed to the environment. One example of efficient use is in district heating, another to use it for seawater desalination. Electricity production is also possible by deploying an Organic Rankine Cycle (ORC) machine. For the AHEX plant at Mosjøen, the hot water will be used for both district heating and for driving an ORC for electricity production. During the cold season, an extension from the plant’s (and thus also the town’s) district heating system to the AHEX is planned. for the higher gas flow to the AHEX compartment is the lower pressure drop across the AHEX compared to the conditioning tower. The gas flow is estimated within ± 10% accuracy assuming a gas specific heat value Validation of the AHEX FTC concept The full scale AHEX concept is demonstrated at the existing Alcoa Mosjøen FTC, which Alstom delivered. This includes six filter compartments downstream of the conditioning tower. One compartment is retrofitted with the AHEX heat exchanger. Thus the gas bypasses the existing conditioning tower and flows directly into the top of the heat exchanger and further on to one filter compartment, which operates on gas from the heat exchanger only. This compartment is therefore conveniently benchmarked with the other five compartments which run on flue gas from the conditioning tower. The measurements on the gas from these compartments are references in the full-scale validation of the AHEX performance. The ingoing water temperature to the AHEX is usually 60 °C and the outgoing is 80-90 °C. The inlet gas temperature normally varies between 160 and 190 °C and the corresponding outlet gas temperature reads 90-100 °C. The heat recovered in the AHEX heats up the 50% glycol water mixture to about 90 °C. This fluid flows in a closed loop between the AHEX and the heat delivering heat exchanger. Here it is normally cooled down to about 60 °C. The heat flow is calculated from measuring the fluid mass flow and corresponding temperatures in and out of the AHEX, deploying a specific heat value of approx. 3,300 kJ/kgK for the heat transfer fluid. The heat transferred to the fluid is in the range of 0.8 to 1 MW. This indicates a total heat recovery potential of about 5 MW for the complete anode bake plant at Alcoa Mosjøen. A 50% higher gas flow is estimated to flow through the AHEX compartment, compared to the remaining compartments. The reason The installed full scale demo AHEX FTC at Alcoa Mosjøen of about 0,37 Wh/Nm3. This is based on the fact that the heat absorbed in the fluid will be equal to the heat recovered from the gas (neglecting the small heat loss to the environment). The total gas flow to the remaining compartments is measured in a venturi duct. To validate that there is no excessive dust deposits on the AHEX tubes, a heat transfer coefficient is calculated from the measured data and divided by a theoretically calculated heat transfer coefficient from the literature. The stable quota curve indicates that the heat transfer coefficient is not degrading due to e. g. excessive dust de- Schematic diagram of AHEX, the combined heat exchanger and tar condensation system 71 A L U M I N I U M S M E LT I N G I N D U S T R Y posits. Even if there are some fluctuations in the measured pressure drop, it is evident that the pressure drop is not increasing over time. This is also verified by several visual inspections of the heat exchanger surfaces. It demonstrates that the heat exchanger is clean and not fouled by tar residue. Extractive PAH samples from the flue gas were collected with standard methods from the inlet to the conditioning tower and from the AHEX compartment outlet, as well as from the outlet of the other compartments. These measurements let us calculate the removal efficiency. During the measurements the outlet gas temperature from the AHEX was raised so as to be identical to that of conditioning tower outlet, so as to simplify the comparison of the AHEX concept with a conventional filter compartment. The measured removal efficiency of the AHEX can therefore be considered conservative, since it would collect more PAH on an AHEX FTC, when operated at the lower gas temperatures typical for AHEX. An external laboratory analysed the samples for the different PAH compounds (gas chromatography – mass spectrometry method). It is evident that the AHEX compartment has similar or better removal efficiency compared to the reference compartment. Overall the removal efficiency for the PAH-16 gas compounds was 18% higher for the AHEX compartment. As the gas flow through the AHEX compartment is in the order of 50% higher compared with the reference compartment, the AHEX compartment collects about 70% more PAH (kg/h) than the reference compartment. A visual inspection of the enriched alumina from the AHEX compartment revealed it to have a much darker colour compared with alumina from the reference compartment. As the primary alumina flow to all of the compartments is identical, this supports the higher collection efficiency. HF emissions from the filter compartments were measured by portable HF analyser. It showed that the HF emission from the AHEX compartment is significantly lower than from the reference compartment. For further details see [1]. Conclusion A novel Fume Treatment Centre (FTC) concept has been developed. The core of this concept is the integrated heat exchanger reactor which simultaneously combines cooling the flue gas with adsorbing PAH, condensed tars and HF on alumina. This novel FTC concept is a further development of the Alstom’s DDS (Decentralised Dedicated Scrubber) technology. This new AHEX concept integrated into the filter eliminates the need for a conditioning tower with water injection. All the operational challenges related to the conditioning tower (corrosion, tar deposits, bag hydrolysis) are reduced or eliminated. The fumes flow directly into the filter without the need for a duct from the conditioning tower to the filter. The AHEX concept allows cooling the gas to below 100 °C without the risk of corrosion of the duct and the filter. The improved cooling of the gas will allow for even higher removal efficiency. The AHEX offers recovery of approx. 1 MWth heat per compartment. The concept has been validated on a full scale demo-plant at Alcoa Mosjøen, which has been in operation since November 2011. The performance of the compartment with AHEX has been compared with another compartment running on a conditioning tower at the same gas temperature. The emission measurements show that the AHEX has a much higher emissions removal efficiency compared to the compartment with conditioning tower. This higher efficiency is achieved even though the AHEX compartment handles 50% more gas compared with the compartment downstream of the conditioning tower. The novel AHEX FTC is more compact compared with a conditioning tower cooled FTC, and it allows for improved removal efficiency, thus reducing emission of carcinogenic tars and gaseous fluorides. It recovers heat which when used reduces the smelter’s carbon footprint. It eliminates handling of carcinogenic residues from tar drop outs in conditioning towers and ducts, and it adds ‘renewable’ energy to the smelter. It secures lower operational and capital costs compared with the conventional conditioning tower-cooled FTC. AHEX is flexible, it allows integration in existing FTCs, and it will add many benefits both to greenfield and brownfield smelter projects. References [1] A. Sorhuus, S. Ose and G. Wedde, AHEXA New, Combined Waste Heat Recovery and Emission Control System for Anode Bake Furnaces, TMS 2013, San Antonio, Texas, USA. Author Bo Herrlander is global marketing manager Industry & Power of Alstom Power, based in Växjö, Sweden. GNA cathode block sealing process T. Phenix, GNA alutech GNA alutech inc. of Montreal, Canada, is recognised as a leader in the supply of cathode sealing equipment and of control systems to primary aluminium smelters worldwide. Having worked for some 29 years with major aluminium smelters around the globe, the company has improved the cathode sealing process with equipment designs that are more productive yet more efficient. The equipment is also diverse, being easily adaptable to seal blocks and bars from various smelter technology providers and brought together in a single production line. We 72 have provided systems for different potroom technology suppliers, including AP 30, 35, 37 and 40, Hydro, Montecatini, Sumitomo and others. Cathode blocks are among the materials necessary to line a typical reduction cell. These blocks vary in dimensions and configuration, and must be mated to steel bars before being installed in the cells. For many years, this cathode assembly process was typically done by hand using rudimentary tools and basic handling equipment. Now that has all changed, and different approaches with vari- ous levels of mechanisation and automation have been developed to streamline this process. They make it more efficient and improve the electrical conductivity and the lifetime of the fin-ished product, the cathode bar and block assembly. System overview Today’s cathode block sealing system groups together a number of machines and heating sources to clean and heat the steel bars as well as to heat the carbon-graphite blocks prior to reaching the point of assembly. At ALUMINIUM · 1-2/2013 SPECIAL this stage, operators are involved to continue the process, and they usually perform a quick check of the block and bar temperatures prior to pouring the sealing medium, which typically A L U M I N I U M S M E LT I N G I N D U S T R Y iron during the mating procedure. The GNA steel bar furnaces are typically heated using SCR controlled electrical elements to achieve the required temperature. Electrical energy for the various motions and movements is regulated through a comprehensive electrical control scheme with an operating programme containing several hundred I/O’s. Feedback and data are continually available to the operators and to the smelter Scada system to create a data base, to do trending and to manage inventories. © GNA System performance and reliability Block oven and feed conveyor consists of molten iron from a local induction furnace. In addition to this mating and sealing process using the molten iron, operators must feed the system with the basic raw materials that include the blocks and steel bars. Following that, where the initial cooling process is completed they remove the final assemblies to a dedicated storage area. The assembly tolerances are specified and need to be within a few millimetres. Also, the correct temperatures are critical to the success of the sealing process, with minimal temperature variation across the blocks and bars, not only as they exit their respective heaters, but also just prior to the pouring of the molten Motor control centre ALUMINIUM · 1-2/2013 This is also the case for the block ovens; however, recirculation fans are also incorporated into the latter to ensure adequate heat transfer to meet the production cycle time requirements. Specific design strategies are used in zoning the heating equipment to achieve and main-tain optimum temperatures, while also consuming as little energy as possible. The PLC program strategy regulates energy usage for heating, and it also controls all system movements in order to respect the temperature variance which is specific to the applicable bar-block combination. A GNA cathode assembly line can store enough materials to meet the requirements for several hours of production, thereby freeing up the operator for other tasks. In the cathode assembly line, the material handling requirements are multi-dimensional with the bars flowing through the assembly chain, changing direction, being shot-blasted to clean the surface of rust and mill scale, and then heated. In parallel, the blocks are heated to their respective temperature and are then automatically assembled with the bars using an automated crane and special handling system of GNA design and fabrication; all under the watchful eye of an operator. Here is where the repeatability and reliability pay off. The mechanical system and its controls must continually produce block and bar assemblies within the specified tolerances and temperature limits. This is vital so that primary producers can prepare and store the multitude of cathode blocks required for a new smelter start up or for on-going pot maintenance. Rejects are both costly and time-consuming. New smelters typically start producing sealed cathode blocks one year prior to actual potroom construction. They often work two shifts per day, six or seven days a week to meet their cathode block sealing target so as to guarantee start-up of the smelter and the production of molten metal. The quality and precision of the block assembly is particularly important as the cell amperage is ever-increasing, causing more aggressive service conditions. This can affect the cathode service life, emphasising the benefits of a reliable quality. Also, the costs associated with pot ‘patching’ or ‘relining’ due to premature failure of the pot lining are a significant part of the costs of producing aluminium. Managed by a logical, user-friendly control system, and supported by a knowledgeable staff with a stock of critical spare parts, the GNA system will return many years of quality operation to the smelter for their sealed cathode requirements. Having demonstrated proven reliability for more than 20 years, GNA consistently strives to refine and improve their equipment to meet the client’s most stringent requirements and expectations. Illustrated in the diagram (next page) are the cathode block oven, the bar furnace and the assembly area. There a gantry crane automatically retrieves the hot bars and aligns and positions them in the hot block during the mating process. Client relations For each client, GNA analyses his specific needs and produces a system overview to determine the guaranteed performance for a particular assembly line. We design and adapt our systems for both greenfield and brown- 73 A L U M I N I U M S M E LT I N G I N D U S T R Y the resulting findings to our design, and this is a major part of our continual improvement process. Guards and fences are used to protect personnel from moving machinery that starts automatically. Electronic aids are also strategically located that will stop any piece of equipment or the complete system, should a specific area be breached. Operator comfort is also in the forefront, with noise abatement equipment and dust collection provided for specific components of the system. Sustainability, the final word Schematic diagram of cathode block oven, bar furnace and assembly area field sites, providing detailed layout and foundation drawings. These drawings include the utility requirements necessary for the client to construct or modify a building to install the new equipment. In the course of our engineering study, the assembly line production target is only one aspect of the project. The system design, which incorporates several pieces of material handling equipment as well as heating systems, hydraulic and pneumatic systems, is all engineered to exacting standards that reflect the smelter’s immediate and long-term objectives. Typically, a single master control station is located so as to provide the operator with a clear view of where the bars and blocks are assembled and sealed in the critical mating and sealing process. Safety As stated above, system reliability is of primary importance, but not more important than safety and ergonomics for the operators. The GNA cathode sealing system is the result of many years’ experience in designing and building such equipment for aluminium smelters, and this is reflected in the safety aspect of day-to-day operations. Having performed risk analysis studies on cathode systems for several clients, we routinely apply To ensure optimum performance and the ongoing production capability of the GNA assembly line, comprehensive manuals and training are provided, both for the system operators as well as the maintenance personnel. The training consists of classroom sessions and also a hands-on experience directly on the assembly line. Continuous technical support and spare parts are made available to the client long after we have left their site, thus ensuring the plant can maintain a stable supply of sealed cathode block assemblies for the life of the smelter. Author Ted Phenix is CEO of GNA alutech inc, based in Saint-Laurent, Quebec, Canada.v Slotting anodes and recycling carbon Slots cut in the bottom surface of the anodes are an effective way to evacuate the gas continuously formed during the aluminium reduction process, thus reducing the accumulation of gas bubbles underneath the anodes. Major benefits commonly achieved by the use of slots in the anodes are the reduced cell resistance and the improved cell stability. Depth of slot is important to ensure these benefits last for the entire anode life (full life slot); slot shapes are important to achieve other benefits in the pots management thanks to the control of the gas exit direction and related area of influence. T. T. Tomorrow Technology, based in Italy close to the city of Padua, has achieved particular knowledge in anodes cutting and slotting technology. Internal R & D as well as long experience in the design and manufacture of dedicated equipment 74 for anodes cutting and slotting, as well as for the carbon area, have been the basis to develop the patented Automatic Slots Cutting Machine. The most recent of the anodes slotting machines manufactured by T. T. is incorporated in the automatic anodes slotting line delivered to Trimet Aluminium in Hamburg, Germany, which is now in operation to feed the slotted anodes to the potrooms. This line manages in fully automatic mode to cut one or two slots in the bottom of two completely different anodes types. The line in Hamburg has been supplied with a dedicated carbon material recovery system and aspiration and filtration unit, which allow 100% recycling of carbon material produced while slots are cut. The accurate value of recycling rate is at 99,995%, far above the expectations of the customer. An air filtration unit was designed to meet the severe requirements of the local authorities. Noise reduction, capture of all the dust and carbon material emissions and discharges together with the proprietary design of critical parts of the line to reduce pollution impacts contribute to have the highest environmental protection while the anodes are slotted. Recycling of the carbon material recovered from the slotted anodes is achieved through collecting, transporting, sizing, buffering and returning to the raw material silos the carbon material which is reprocessed in the mixer to form new anodes. Recycling benefits to the smelter and the environment are: reduced amount of raw materials used to produce anodes, reduced wastes, conserving natural resources, and saving money. The equipment manufactured by the company is furthermore particularly designed to minimise operator exposure to any potential hazards during operation as well as during ALUMINIUM · 1-2/2013 © T.T. Tomorrow Technology SPECIAL Two slots being cut simultaneously maintenance, resulting in a healthy and safe working environment for the operators. The slots cutting machine is supplied with a sound and dust proof cabin, complete with complementary items as hydraulic power unit, electrical panel / MCC with necessary controls and HMI for the friendly operations. The ability to access the machine control and software at any time from anywhere via special programs is a huge advantage that T. T. Tomorrow Technology customers value highly. The fact that both planned maintenance and unplanned machine downtime costs are expensive is well known to T. T., whose design and construction criteria for this reason are: • Simplicity of design • Robust construction • Reliable operation • Easy and low cost operation and maintenance • Safety operation and maintenance. While the slots cut in the baked anodes have proved to solve a lot of the problems suffered when slots are formed by the conventional way in the vibrocompactor (last but not least the lack of homogeneity in the anode due to the blades in the forming press preventing uniform material distribution and forming pressure) the slots cut with the technology proposed by T. T. have reached the target of depth required to ensure that the benefit of the slots last for the full anode life. The economic and production benefits that are so achieved in the potroom management are bigger than those achieved with the deeper of the shorter slots that can be produced with ALUMINIUM · 1-2/2013 A L U M I N I U M S M E LT I N G I N D U S T R Y of the anode; position where the blades are removed from the slot is selectable from operator panel. T. T. Tomorrow Technology has recently been awarded of a new contract for a highly customised automatic anodes slotting machine by a major aluminium smelter in Australia. Construction is in progress; and its commissioning is scheduled for the beginning of the second half of 2013. Other projects for automatic anodes slotting machines, says T. T., are under discussion with smelters around the world, which are positively evaluating the capability of the slotting machine to cut one or two deep longitudinal slots in the bottom surface of the baked anodes even of different dimensions, whether they are to be cut with straight slot/ slots or with (variable) slope or interrupted before the end of the anode. The carbon material recovery system and the combined air filtration, developed by T. T. and reaching almost 100% recovery and recycling rate, is complementary to the anodes slotting machine. Energy savings, increased productivity, reduced greenhouse gas emissions, money saving for raw material purchase and prevention of pollution caused by the recycling of process wastes are key factors matching the short-term ROI of the anodes slotting equipment. N conventional methods in the green anodes. With T. T.’s anodes slotting machines the depth and the inclination of the slots can be furthermore managed and adjusted at any time during production: the slot configuration and the slot shape are therefore flexible. Another big and important advantage is the possibility to cut interrupted slots, which allow to control the gas flow direction toward the centre of the pots. Particularly the automatic slots cutting machines are manufactured to perform three profiles of slots: • Straight slots (passing thought the anode at the same depth); the actual slot depth is anyway adjustable (pre-selectable) from the operator panel • Inclined slots: starting from a pre-selectable slot depth, ending to a smaller one with a constant inclination; the value of the inclination angle is anyway adjustable (pre-selectable) from the operator panel • Interrupted slots: where while slots are cut the blades are quickly removed from the slots before reaching the end View of an air filtration and carbon recycling system 75 A L U M I N I U M S M E LT I N G I N D U S T R Y Testing a new ‘STARprobe’ M. Dupuis, GeniSim; J.-P. Gagné, Stas Taking into consideration the neutralisation of some of the fluoride absorbed by the fresh alumina in the scrubber by the sodium already present in it, we can assume that the equivalent of 3.6 kg/hr of AlF3 is fed back to the cell by the secondary alumina (on average or at the nominal 100% alumina feeding rate). This leaves 1.1 kg/hr of AlF3 that must be directly fed using a point breaker feeder (PBF) under the supervision of the cell controller. However, this hourly dose is only about 0.14% of the excess AlF3 in the bath, since the cell contains close to eight tonnes of bath and hence about 800 kg of excess AlF3. This means that if the direct AlF3 feed were to be completely stopped for some reason, it would take about 72 hours for the excess AlF3 concentration to drop by 1 to 9%. In view of this relatively slow response time of the cell, it should be quite easy to keep the excess AlF3 concentration under tight control. But such control is clearly lacking in the great majority of smelters, so some other factors must be complicating things. How daily operations influence the bath ratio: In the above mass balance calculation, about 75% of the AlF3 is fed back to the cell as part of the alumina feeding. However, in © GeniSim In addition to the two main tasks an aluminium reduction cell controller has to perform, namely to keep both the dissolved alumina concentration in the bath and the anode cathode distance (ACD) under tight control [1], modern cell controllers are also in charge of keeping the bath ratio (or excess AlF3) concentration under control. This task has proven to be quite challenging despite the fact that, at first glance at least, it looks quite straightforward. Fluoride evolves out of the cell in the off-gas; a big fraction of that fluoride is captured by the fresh alumina in the scrubber and returns to the cell as part of the secondary alumina feed to it. The part that does not return to the cell must be compensated by direct AlF3 feeding in order to maintain a constant bath ratio in the cell. The cell controller performs that task using feedback control algorithms based on regular measurements performed by cell operators. Recently Alcoa has develop a revolutionary new technology to measure bath ratio in the potroom almost as quickly as you can measure bath temperature [2, 3]. Furthermore, in addition to the excess AlF3 concentration, the new STARprobe also measure the bath temperature, the dissolved alumina concentration, and the cell superheat. That last information can be used as part of the cell control logic, as previously presented in [4] for example. GeniSim’s Dyna/Marc dynamic aluminium reduction cell simulator has been used to model and evaluate the efficiency of the traditional combined bath sample/XRD analysis and bath temperature measurement bath ratio control logic, and to compare it with a new control algorithm based on STARprobes excess AlF3 concentration and superheat measurements. Fig. 1: Daily excess AlF3 concentration variation modelled without control and any mass imbalance as generated by Dyna/Marc cell simulator Performing the AlF3 mass balance Using a 300 kA cell as an example, the fluoride mass balance can be performed as follows. Fluoride evolved out of the cell at a rate dictated by many factors, like the bath ratio and temperature and the state of the anode cover [5]. In the current example, the fluoride evolution rate is calculated to be 33.6 kg F/t Al with the cell conditions selected, namely 10% excess AlF3, 970 °C, and a good anode cover. For a 300 kA cell producing 94.7 kg Al / hr, this represents the equivalent of 4.7 kg of AlF3 that evolves out of the cell and hence must be replaced each hour. 76 Fig. 2: 20 days excess AlF3 concentration variation modelled without control and any mass imbalance ALUMINIUM · 1-2/2013 SPECIAL A L U M I N I U M S M E LT I N G I N D U S T R Y Fig. 3: Corresponding 20 days of excess AlF3 concentration sampling results modelled assuming no bath sampling noise modern continuous tracking control logic, the alumina is never fed constantly at the nominal 100% rate to the cell. As a result, the excess AlF3 concentration swings up and down according to the alumina feeding cycle. The direct AlF3 additions are also performed in discrete events, for example 2 kg every 110 minutes, in order to average 1.1 kg/hr. Those discrete additions also influence the short term variation of the excess AlF3 concentration. As well as the irregular AlF3 addition, several thermal events also affect the AlF3 evolution, such as the bath temperature, but more importantly the ledge thickness variation: as ledge is mostly pure cryolite, ledge formation concentrates the excess AlF3 in the molten bath. Ledge formation occurs after anode change events, for example. Fig. 1 shows the calculated daily variation of the concentration of AlF3 in the modeled bath in the absence of Fig. 4: Corresponding 20 days of excess AlF3 concentration sampling results modelled assuming 0.5% standard deviation white sampling noise control additions and of any AlF3 mass imbalance. The standard deviation on the average value is about 0.1%. Sampling frequency and delayed XRD results: The next factor complicating things is the long delay in evaluating the bath chemistry through manual interventions. The traditional way of proceeding requires manual bath sampling, manual processing of the bath samples, at best semi-automatic analysis of the bath samples by a XRD instrument, and manual input of the results in a database accessible to cell controllers. Considering the cost of a XRD analysis, it is typical to take bath sample every second day and to get results at 8 to 24 hours after the actual bath sampling. Fig. 2 shows the calculated variation of the AlF3 for a period of 20 days, again in a model without control additions or any mass imbalance. Fig. 3 shows the results of the bath Fig. 5: Simulation of the process without perturbation; top without control, bottom with feedback control, 10% target concentration (XRD results, once per day, 1 day delay, 0.5 kg/hr% proportional band and -0.1 kg/hr°C proportional band) ALUMINIUM · 1-2/2013 sampling performed once a day, always at the same time of the day. The delay between taking the sample and receiving the results of the analysis is clearly not an issue when the concentration is drifting very slowly. Yet any delay in the feedback response can cause instability, depending on the controller setup. So far, despite the daily events ‘process noise’, the sparse sampling frequency, and the delay in getting the sampling analysis results, should make it easy to stabilise the bath ratio. So there is no obvious explanation for why it is so difficult to control the bath ratio. Bath sampling noise problem: But a new problem affecting bath ratio control has recently been identified: it is the bath sampling noise due to the bath composition being far from homogeneous [6]. The standard deviation of that bath sampling noise has been evaluated to be around 0.5%, which is five times greater than the process noise generated by daily events. That bath sampling noise, contrary to the daily events noise, is completely unpredictable. Fig. 4 shows the simulated results of bath sampling performed on the 20 days period presented in Fig. 2, but when 0.5% white noise is added to the noise-free results presented in Fig. 3. The fluctuations are about seven times greater. Simulated process response using standard control without any process perturbation: Now, we want to test a typical control logic where both the delayed XRD analysis from bath samples and measured bath temperature are used to correct the direct AlF3 feeding rate as it is commonly done in the industry these days. The proportional band was set to 0.5 kg/hr% for the 24 hours delayed bath XRD analysis results, and to -0.1 kg/hr °C for the bath temperature measurement. The bath sampling and the temperature measurement for the model are done simultaneously every 24 hours. © 77 A L U M I N I U M S M E LT I N G I N D U S T R Y A bath sampling noise having a standard deviation of 0.5% has been added to the XRD analysis results following observation recently reported [6]. For the temperature measurement, a bath sampling noise having a standard deviation of 2.5 °C has been added as reported in [6]. Fig. 5 presents the modeled results in the dynamic cell simulator for a period of 100 days. The top graph presents the results obtained without any control and in the absence of process perturbation. The initial bump is an indication that the steady state conditions used as initial transient conditions are not 100% representative of the long term pseudo steady state conditions. The bottom graph presents the results ob- tained with feedback control active. Unfortunately, it is not as good as the results without control. This shows that the bath sampling noise, combined with the 24 delay in the bath sampling analysis result, is destabilising this feedback control loop. Simulated process response using standard control with a significant process perturbation: In order to more seriously test the stability of the feedback control loop, we added a major perturbation to the simulation. On day 14, we simulated removal of about half of the cover material from the anodes. This increases the anode panel heat loss by about 30 kW from 230 to 260 kW. As we can see in Fig. 6, as a natural response, the cell must reduce its cathode heat loss by the same amount. It does this by reducing its superheat by about 1 °C and by increasing its ledge thickness by about 5 cm. This extra ledge formation concentrates the excess AlF3 in the molten bath by about 2%, where it remains close to 12% if the direct AlF3 additions remain unchanged. This is clearly a case where some feedback control is required. Fig. 7 presents the model results obtained using the standard control described above. After the change of superheat, the 970 °C temperature target is no longer compatible with the 10% excess AlF3 target. Combined with the 1 day offset between the AlF3 feedback and the temperature feedback, this generates a cyclic response characteristic of somewhat unstable feedback control. This type of oscillation with a wave length of about 20 days and an amplitude of about 2.5% is very often seen in real smelters. Those undesired oscillations occur despite careful selection of the values of the proportional constants in an unsuccessful attempt to avoid feedback loop instabilities. The new STARprobe Fig. 6: Simulation of 100 days natural response (no control) to a significant reduction of the anode cover material thickness resulting in an increase of the anode panel heat loss by 30 kW Fig. 7: Simulation of the process with a significant perturbation; feedback control, 10% target concentration (XRD results, once per day, 1 day delay, 0.5 kg/hr% proportional band and -0.1 kg/hr°C proportional band) 78 The STARprobe is a portable device that takes real-time measurements of bath properties in electrolysis cells, such as Superheat, Temperature, Alumina concentration and bath Ratio or acidity (STAR). This synchronicity of measurements is a most important step forward in improving the control and efficiency of electrolysis cells. It unites the conventional processes of temperature measurement and bath sampling analysis into one online measurement. This simplifies and greatly shortens the process and time delay from measurement/sampling to pot control decision. The pot control decision can therefore be based on the real-time cell conditions rather than on conditions from few hours ago, or even from as long as 24 hours ago. This integrated real-time measurement system consists of four major components: • Reusable probe tip • Portable stand to fit various pot configurations • Electronics for data acquisition and analysis, and wireless communications for data transfer • Tablet PC with programs to perform all necessary tasks during measurements. Considering the great advantages of the STARprobe, Alcoa has decided to share the technology with the rest of the aluminium industry starting from 2012. In this regard, Alcoa has just appointed STAS, a well recognised leader in the aluminium industry, to commercialise the new STARprobe analysing system. ALUMINIUM · 1-2/2013 SPECIAL Simulated process response of STARprobe to a significant process perturbation: Exactly the same major perturbation was used to test the efficiency of the feedback control loop using STARprobe measurements. The same day measurement frequency is used and the same 0.5 kg/hr% proportional constant for the AlF3 feedback loop. Obviously in this case however, the measurement results are available without delay. In addition, the measured superheat was also used to activate a separate feedback loop which adjusts the target cell resistance based on the offset between the target and the measured superheat. The measured superheat is also affected by a very significant bath sampling noise. That bath sampling noise was estimated to have a A L U M I N I U M S M E LT I N G I N D U S T R Y standard deviation of about 2 °C in [6], so we added a 2 °C standard deviation white sampling noise to the simulation. The obtained results are shown in Fig. 8. In this case the response to the perturbation is slower than in the previous case, because there is no longer a correction based on the temperature offset, and because a ± 1 °C deadband was imposed on the superheat target in order to inhibit wrong responses to the noise in the superheat measurements. Yet after a 25 days transient response to the perturbation, the excess AlF3 concentration goes back to its target value and remains on target without oscillations after that. Fig. 9 shows the evolution of the target cell resistance. After a delay of 6 days, a 0.01 μΩ Fig. 8: Simulation of the process with a significant perturbation; feedback control, 10% target concentration (STARprobe measurements once per day, 0.5 kg/hr% proportional band and daily 0.1 μΩ target resistance correction due to superheat offset from target) Fig. 9: Evolution of the cell target resistance (there is a 0.4 μΩ change of target resistance each day during the anode change event) ALUMINIUM · 1-2/2013 correction to the target cell resistance was applied each day for 15 days giving a total 0.15 μΩ correction. This 0.15 μΩ ‘permanent’ correction ensures that the superheat remains within the 3.5 to 5.5 °C range, despite the fact that the anode panel now dissipates an extra 30 kW of heat loss. Conclusions This study demonstrates the value of using a dynamic cell simulator to optimise existing cell controller algorithms and to test new ones without putting real cells at risk. The Dyna/ Marc cell simulator used in this study is available to the whole aluminium industry through GeniSim Inc. Version 14 supports adding the simulated bath sampling noise at the level seen in the AlF3 measurements. The model can also use STARprobe measurements instead of bath samples/XRD analysis to perform bath ratio control. The revolutionary new STARprobe measurement tool makes possible a new control logic scheme based on independent control of the excess AlF3 and of the cell superheat. Modelling proves this to be superior to the standard single feedback control loop, which uses two target variables (namely the excess AlF3 and the operating temperature) to control a single control action, namely the direct AlF3 additions. The STARprobe developed by Alcoa [2, 3] is now available to the whole aluminium industry through STAS (http://www.stas.com/ en/starprobetm.html). References [1] M. Dupuis, Testing cell controller algorithms using a dynamic cell simulator, ALUMINIUM 88 (2012)1-2, 50-55. [2] X. Wang, B. Hosler and G. Tarcy, Alcoa STARprobeTM, Light Metals, (2011), pp 483-489 [3] X. Wang, G. Tarcy, E. Batista, and G. Wood, Active pot control using Alcoa STARprobeTM, Light Metals, (2011), pp 491-496 [4] T. Rieck, M. Iffert, P.White, R. Rodrigo and R. Kelchtermans, Increased Current Efficiency and Reduced Energy Consumption at the Trimet Smelter Essen using 9 Box Matrix Control, Light Metals, (2003), pp 449-456. [5] W. Haupin and H. Kvande, Mathematical Model of Fluoride Evolution from Hall-Héroult Cells, Proceedings from the International Jomar Thonstad Symposium, ed. by A. Solheim and G. M. Haarberg, Trondheim, Norway, October 16-18, (2002), 53-65. [6] M. Dupuis, P. Bouchard and J. P. Gagné, Measuring bath properties using the STARprobeTM, 19th International ICSOBA Symposium (2012), to be © published. 79 A L U M I N I U M S M E LT I N G I N D U S T R Y Author Dr. Marc Dupuis is a consultant specialised in the applications of mathematical modelling for the aluminium industry since 1994, the year when he founded his own consulting company GeniSim Inc. (www.genisim.com). Before that, he graduated with a Ph.D. in chemical engineering from Laval University in Quebec City in 1984, and then worked ten years as a research engineer for Alcan International. His main research interests are the development of mathematical models of the Hall-Héroult cell, dealing with the thermo-electric, thermo-mechanic, electro-magnetic and hydrodynamic aspects of the problem. He was also involved in the design of experimental high amperage cells, and in the retrofit of many existing cell technologies. Jean-Pierre Gagné is specialist for elecrolysis products of Stas, based in Chicoutimi, Canada. Stas designs and manufactures equipment for the primary and secondary aluminium industry. Carbothermic reduction – An alternative aluminium production process H. Kvande, NTNU About twenty years ago the present author co-authored a paper [1] with the title Carbothermal production of aluminium – technically possible, but today economically impossible? Since then significant resources have been spent on the study of this process and much experimental work has been done. So, it is time to ask again if such a carbothermic process for production of aluminium really is still economically impossible. The present paper reviews the published literature of the last two decades to try to evaluate the current status of carbothermic aluminium production. The standard industrial aluminium electrolysis process (Hall-Héroult) has several weaknesses, as we know: very high capital investment, a complex anode change operation, high energy consumption, pollution of the environment and emissions of greenhouse gases. That is why the search for alternative methods for production of aluminium will probably never stop. In 2000 Alcoa announced that it had started to develop a process based on carbothermic reduction of alumina. Since then little published information has emerged about the progress of Alcoa’s work. This is quite understandable in view of the importance which a successful result would have. So let us here first take a look at the present status of carbothermic aluminium production. Carbothermic production of aluminium – its history The idea of carbothermic reduction of alumina to aluminium is indeed an old dream. Aluminium-copper alloys with about 15% Al were produced industrially already in 1886 [2], the same year as the present industrial electrolysis process was invented. In the 1920s Al-Si alloys with 40-60% Al were produced in Germany, and about 10,000 tonnes of these alloys were produced annually in the period up to 1945. 80 The first attempt to produce pure aluminium by carbothermic reduction of alumina was performed around 1955. Pechiney worked on the process from 1955 to 1967, but terminated the programme for technical reasons. Reynolds worked on an electric arc furnace to produce aluminium from 1971 to 1984. Alcan acquired information from Pechiney and continued their research, but stopped in the early 1980s. Alcoa tried to develop the process to produce Al-Si alloys from 1977 to 1982. However, in 1998 Alcoa started the carbothermic production project again, together with Elkem R&D in Norway. They changed their focus from an open arc furnace (with high generation of volatile aluminium-containing gases) to a submerged arc process. Elkem already had a long experience with modern silicon furnace technology, and so came up with the idea for a new type of high-temperature electric reduction reactor tailor-made for carbothermic production of aluminium. Alcoa had a good understanding of the fundamental chemistry and a long experience with carbothermic production of aluminium from the work in the 1960s until the 1980s. Together Alcoa and Elkem then agreed to try this again. Carbothermic aluminium production: the three main steps in the process As the name says, the purpose of the carbothermic method is to use carbon and heat to reduce alumina to aluminium, according to the overall reaction: Al2O3(s) + 3 C(s) + heat = 2 Al(l) + 3 CO(g) The reaction proceeds close to and above 2 000 °C, and it produces CO as the primary gas. The gaseous by-product is therefore different from that of the Hall-Héroult process, which produces CO2. The carbothermic process can be divided into three steps, as shown in the flow chart: • Production of a slag, which contains a molten mixture of alumina and aluminium carbide • Production of a molten aluminiumcarbon-(carbide)-alloy • Production of pure aluminium (refining) from the aluminium-carbon-(carbide)containing alloy. The two most difficult steps here are steps 2 and 3; the production of the molten aluminium alloy and the subsequent refining of this alloy. In addition the process needs a gas scrubber to collect the aluminium-containing gases that evaporate from the furnace at these high temperatures. This is an engineering challenge. The main reactions are: Overall carbothermic reduction: Al2O3 (l) + 3 C (s) = 2 Al (l) + 3 CO (g) E°theoretical = 7.9 kWh/kg Al Stage 1 (T > 1 900 °C): 2 Al2O3 (s) + 9 C (s) => (Al4C3 + Al2O3) (slag) + 6 CO (g) Stage 2 (T > 2 000 °C): (Al4C3 + Al2O3) (slag) => (6 Al as metal alloy with Al4C3) + 3 CO (g) The latter two chemical equations are not stoichiometrically correct here, because both the slag and metal phases will have varying compositions. The molten aluminium phase will always contain some dissolved carbon, and therefore it can be considered chemically as an Al-C alloy. There are two molten phases here and they will not mix. The molten alloy has the lower density and will float on top of the molten slag phase. The carbothermic reduction process produces poisonous CO, which has to be captured. If the CO were later burnt as fuel it would produce CO2. To avoid releasing this greenhouse gas this should then either be used as a chemical or captured and stored (CCS). Information published after year 2000 Here is a list of expected potential gains from carbothermic aluminium production, as published by Alcoa in 2000 [3]: ALUMINIUM · 1-2/2013 SPECIAL was underway in Norway. More interestingly here, Alcoa wrote that it was then planning to move from a pilot scale of 1.5 MW to an 8.0 MW scale-up, and suggested this might later be developed in Québec when the furnaces could reach that stage. The plan to move the carbothermic work away from Norway was probably a consequence of the attempt to buy Alcan. Furthermore, working with Elkem AS in Norway, Alcoa had so far invested more than USD37 million on this project. The annual budget for this research was at that time USD14.8 million, with a 35-person development team [7]. This information clearly shows that Alcoa was using significant effort, money and resources on the project. The target then was industrial aluminium production by this process in 2020. © Kvande • Lower production costs by 25%, and reduced capital costs by 50%. This may give lower total cost by up to 35%. • Less need for workforce. • Lower electrical energy consumption by more than 30%. About 10.0 kWh/kg Al is expected and about 8.5 kWh/kg Al can be obtained with energy recovery from the gases. The theoretical minimum energy consumption for this reaction is 7.9 kWh/kg Al, so the energy efficiency will be much higher than for the existing electrolysis process, where typically about 50% of the energy now is lost as heat given off to the surroundings. • Better environmental protection. There will be no gaseous fluoride emissions by vaporisation from the electrolyte, and of course no emissions of perfluorocarbon gases (CF4), which now are formed during anode effects in A L U M I N I U M S M E LT I N G I N D U S T R Y Flow chart of the aluminum carbothermic technology – advanced reactor process concept of Alcoa and Elkem the electrolysis cells. The process will eliminate volatile organic carbon-containing fumes (PAH) from tar used in the anode production step, and there will be no solid waste from spent pot lining (SPL). In 2003 Bruno et al. [4, 5] gave an excellent overview of Alcoa’s work so far on carbothermic aluminium production. Later Bruno [6] documented the non-proprietary R&D work conducted on the Aluminium Carbothermic Technology (ACT) project from the contract inception on 1 July 2000 to its termination at the end of 2004. The objective of the programme was to demonstrate the technical and economic feasibility of a new carbothermic process for producing commercial grade aluminium, designated by Alcoa as the Advanced Reactor Process (ARP). In connection with Alcoa’s attempt to buy Alcan in 2007, some interesting information was published [7]. This confirmed that research on carbothermic reduction of alumina ALUMINIUM · 1-2/2013 Alcoa and Elkem continued to hold joint ownership in the carbothermic process technology that was being developed. It claimed that the carbothermic process technology holds the potential to produce aluminium at a lower cost, driven by reduced conversion costs, lower energy requirements and lower emissions, and that it also promises a lower capital cost than traditional aluminium smelting. The technology was claimed also to hold potential for significant cost improvement in the production of other metals. These are very similar to the claims that were published in 2000 [3]. In an article in the Norwegian technical journal Teknisk Ukeblad [8] in 2008 Alcoa and Elkem Research confirmed that they had worked on this process for nearly ten years. Here are some of the statements given in this article: • “We can produce aluminium with 30% lower energy” (from 13 down towards 9 kWh/ kg Al). • “We have developed good adaptive regulation algorithms that can control the process very accurately.” • “We think that we have solved several of the big challenges in the carbothermic process. The main challenge is to develop process equipment that can withstand these high temperatures (above 2 000 °C). Today’s situation is that there are still a couple of problems that remain to be solved.” • “If successful, the world’s first carbothermic aluminium plant can be in operation in Norway before 2020.” The most recent publication on carbothermic aluminium production At the 2012 TMS Annual Meeting, a paper [9] was presented which contained a lot of interesting information about the progress of this work. It claimed that the cooperation between Alcoa and Elkem has been highly successful and that process development has advanced. Several test campaigns had been done at Elkem’s research facility in Kristiansand. In 2011 Alcoa decided to continue the development of the carbothermic process on its own and established the Alcoa Norway Carbothermic group. The test reactor with auxiliary systems was then moved to the Alcoa Lista aluminium smelter in Southern Norway. While the initial process had used separate compartments for the two stages of the process (first production of the molten alumina-carbide slag and then the molten aluminium-carbon alloy), the current concept uses a single reactor compartment to continuously produce aluminium. The process generates significant amounts of aluminium-containing vapours. This has always been a major challenge with this process, and much effort has gone into dealing with this issue. Vapour recovery concepts continue to be major development areas. The condensation of the vapours needs control to keep the off-gas port open so that the off-gas generated in the process, i. e. CO(g), can leave the reactor. This has led to the development of advanced cooled off-gas pipes [9]. The technical achievements together with improved process understanding have now resulted in a reactor design that is able to continuously operate the process for several weeks at the time. Each tap then generates several hundred kilograms of metal, so that a campaign thus yields many tonnes [9]. So what are the main technological and engineering problems that remain to be solved? The authors [9] claim that the process now faces only few challenges. They mention spe- 81 A L U M I N I U M S M E LT I N G I N D U S T R Y cifically: determination of optimal furnace shape, electrode configuration, and operating conditions for a scaled-up reactor. They also need to find the optimal operating conditions. The plans are now to continue working towards establishing a commercial plant for producing carbothermic aluminium. Concluding remarks The carbothermic reduction technology for production of aluminium has previously been considered to have a high risk for failure, although it is now seemingly closer than ever to commercialisation. If successful, then for cost, energy and environmental reasons this technology would probably have to be licensed to other aluminium producers. Very few, if any, other aluminium producers can compete with Alcoa in this field of technology, and so the rest of the world’s aluminium producers will have to wait and see what happens. References [1]. H. Kvande, R. Huglen and K. Grjotheim, Carbothermal production of aluminium – Technically possible, but today economically impossible?, Proceedings of the International Symposium arranged in honour of Professor Ketil Motzfeldt, edited by H. Kvande, NTH, Trondheim, Norway, 1991, pp. 75-102. [2]. P. T. Stroup, Carbothermic smelting of aluminium. The 1964 Extractive Metallurgy Lecture, Trans. Met. Soc. AIME, 230 (1964), pp. 356-372. [3]. Aluminum Carbothermic Technology Advanced Reactor Process (ACT-ARP), Office of Industrial Technologies, Energy Efficiency and Renewable Energy, US Department of Energy, Washington, D.C. 20585, IT, Oct. 2000. [4]. M. J. Bruno, Aluminum Carbothermic Technology Comparison to Hall-Héroult Process, Light Metals 2003, Edited by P. N. Crepeau, TMS (The Minerals, Metals & Materials Society), 2003, pp. 395-400. [5]. K. Johansen, J. A. Aune, M. Bruno and A. Schei, Aluminum Carbothermic Technology Alcoa - Elkem Advanced Reactor Process, Light Metals 2003, Edited by P. N. Crepeau, TMS, 2003, pp. 401-406. [6]. M. J. Bruno, Aluminum Carbothermic Technol- ogy, Final Technical Progress Report for the Period 2000 July through 2004 December, Submitted to US Department of Energy on 31 Dec. 2004. [7]. Information given in a press release: Alcoa sends letter to Alcan board outlining commitments to Québec will meet requirements of agreement between Alcan and Québec government, Montréal, Québec and New York, New York, 17 May 2007. [8]. Article in Teknisk Ukeblad (Technical Weekly Magazine), No. 16, May 2008 (in Norwegian). [9]. C. V. White, Ø. Mikkelsen and D. Roha, Status of the Alcoa Carbothermic Aluminum Project, International Smelting Technology Symposium (Incorporating the 6th Advances in Sulfide Smelting Symposium), Edited by J. P. Downey, T. P. Battle and J. F. White, TMS, 2012, pp. 81-88. Author Dr. Halvor Kvande recently retired from his position as chief engineer at Norsk Hydro in Oslo, Norway, where he worked for 32 years. From 2009 to 2011 he was Professor and Qatalum chair in the department of Chemical Engineering at Qatar University in Doha, Qatar. He is presently Professor at the Norwegian University of Science and Technology (NTNU) in Trondheim, Norway. Recycling of smelter materials through rotary crushing and material separation D. J. Roth and B. Best, GPS Global Solutions These flexible systems can perform surface scrubbing, crushing, screening and sizing in one single piece of equipment. The Didion systems take up far less space than conven- 82 achieved through the patented double liner configurations. The system requires very low levels of manpower. The equipment was originally designed for automotive foundry production applications and was required to run 24 hours a day, seven days a week with minimal maintenance. This operating philosophy makes the Didion Fig. 1: Model RT 84-2100 Didion scrubber, crusher and separator systems perfect for pritional crushing and screening process facilities, mary aluminium smelters, whose focus is on while at the same time requiring less mainte- making aluminium and not on problems with nance and manpower to operate. The RT/RS ancillary equipment. There are four basic features of the Didion Tumbler systems significantly improve the aluminium industry’s potential impact on the RT Rotary Processing Systems: first, their abilenvironment by this basic approach to process- ity to process very large pieces of feed, up to ing bath, carbon, thimble, dross and salt cake. 1,750 mm blocks, in the same processing step The RT/RS Tumbler is a single process- as fines separation; second, their ability to ing unit that can perform multiple processing crush with controlled fines generation; third, steps within one piece of equipment. This is their ability to ‘scrub’ a surface, so removing © GPS There are many areas in the aluminium smelter operation that can benefit from efficient recycling of materials through low-cost, simple rotary processing operations. Didion International Inc. has the most widely developed uses and applications for rotary crushing and separation systems, being especially suited to recycling and recovery of dissimilar materials that are often mechanically bonded together. This technology developed in the foundry industry in the early 1970s, initially to separate metal castings from the sand mould pieces in which they were cast. These hot, heavy castings required the development of a very durable machine. The continued improvement of the Didion RT/RS Tumblers has made mechanical processing of mixed materials a very cost-effective and low-maintenance alternative to other processing systems. ALUMINIUM · 1-2/2013 SPECIAL A L U M I N I U M S M E LT I N G I N D U S T R Y thimbles in the anode rodding shop, thereby saving consumables and floor space compared with traditional shot belts methods • Separation of metallics from oxides and salts in dross and salt cake processing, significantly improving the environmental impact by eliminating or reducing the landfill residues • burner balls • Separation of spent pot liner material. Fig. 2: Primary crushing chamber Fig. 3: Typical large blocks materials that are foreign to the base structure, and allowing for valuable base structure materials to be recycled and reused; fourth, their ability to classify several sizes of material from bag house dust to 1,750 mm in the same single piece of equipment. Summary of primary plant applications for the RT tumbler processing system: • Rotary bath crusher and size separator in a single process, with the ability to remove the tramp aluminium from this electrolyte in the same step • Carbon reclaimer and cleaner, to scrub the bath off used carbon blocks before crushing, recycling and then crushing them to the required size, all this in the same piece of equipment • Removal of carbon and bath from cast Crushing of large blocks of material Handling large blocks of material can be particularly difficult for most processing systems. However, these must be reduced in size if they are going to be recycled. Most systems either use a primary jaw crusher or a mobile hydraulic hammer / crusher for this first breaking step. The RT systems handle this in the first section of the drum, taking this time-consuming and often dangerous manual labour step out of the procedure. The material is normally charged by end loader into a large hooded vibratory feed hopper that loads the drum. Large, cast steel teeth lift the blocks and then crash them down on hardened spikes for an impact and autogenous milling step that can handle any material used or produced in the smelter. For example, solid aluminium sows can be inadvertently charged into this section of the drum when processing dross, and they will not cause any damage to the Didion unit. Large uncrushable pieces, such as large slabs of aluminium, can be removed from the machine simply by backing out the feeder and reversing the rotation of the drum, discharging these large pieces into a waiting tub. This practice causes no damage to the equipment, as is often the case with impacting systems. This is a valuable feature in bath, pot cleanings and dross processing applications. This one piece of equipment is unique in being able to handle these large pieces without significantly disrupting the process flow. Crushing with controlled fines generation Fig. 4: Autogenous section with impact zone cast liners ALUMINIUM · 1-2/2013 The impact action of the material falling on the cast steel flights in the prebreaking and autogenous chambers, combined with the action of the muller roller, allows for severe crushing, while also immediately removing the fines; this is a key process feature in achieving success. The key technical challenge that the RT unit solves is that it can both preserve the preferred crushed material sizing that was chosen to go through the liners, and also remove finer materials that would form a cushioning bed, so lowering the efficiency of autogenous impacting. This characteristic becomes valuable when processing recycled carbon anode pieces for the downstream processes. Preselecting the correct liner opening and screen size determines the distinctiveness of materials, generating appropriately sized fines for further processing in the green carbon plant. This normally multiple step process is simpler with the RT/RS system. The unique size control abilities of the RT can reduce the large blocks to the exact fraction sizes needed in recycling these materials. The impact breaking action of the system on the particles gives sharp fracture angles which are preferred for the green carbon recycling process. The system’s impact crushing characteristics also work for recycled bath processing, allowing for product sizing and for the removal of tramp ferrous metals and aluminium. The RT system provides a uniform product to put back on top of the pot cells. ‘Scrubbing’ surfaces remove materials that are foreign to the base structure The interior design of the Didion RT systems can combine multiple sections to accomplish a variety of processing goals. The scrubbing or removal of foreign material from the base material is a standard application for Didion rotary equipment. In the original foundry applications for the units, this served to remove sand from the base casting. There are three areas where this feature of the systems have applications in the primary aluminium plant: to remove bath from the spent anodes, to remove of carbon from the thimble castings after separa- Fig. 5: Heavy duty rotary separator / thimble cleaners – RS 83 A L U M I N I U M S M E LT I N G I N D U S T R Y Fig. 6: Spent anode with bath ity within the smelter. There is currently no widely used method for cleaning and recycling of the balls used in the aluminium filter beds. They typically go out with the dross and are destroyed to recover the small amounts of aluminium attached to them. This aluminium, although valuable, is worth less than the high-cost alumina balls. These alumina balls are also used in regenerative burner systems. They typically are cleaned on a regular basis by washing them with water in a separate process, dissolving any contaminants that may be stuck to the surface. The contaminated waste water from the process must be dealt with and is often a water discharge problem. The RS processing of these balls produces a clean, reusable ball, along with easily disposable fines. This is a minor generation area of waste, but when looking at overall recyclability, reductions of landfill and reuse of materials, every opportunity can be an important gain for the environment. Classify several sizes of material in the same processing step Fig. 7: Clean RS processed thimbles tion from the rod, and finally to remove metal and oxides off alumina filter balls. The system works by using the bits and pieces of materials to clean each other, relying on the size differences of individual pieces of the material to clean even in the pockets where small amount of bath or carbon may be trapped. To remove bath from the anodes, or carbon from the thimbles, the standard practice of shot blasting is inefficient and time consuming. The steel shot is an expensive consumable that risks being carried over to contaminate other aspects of the process. Its cleaning efficiency is not perfect, so that significant amounts of sodium/bath can contaminate the next phase of the process. These salt contaminants typically cause problems with the refractories in the carbon baking furnaces and in the thimble casting furnaces. The RT/RS processing technique prevents most of the bath and carbon carry-over into the next part of the production process, improving quality, or event eliminating the furnace refractory problems. An additional unique application for the rotary separator is the ‘cleaning’ of alumina balls that are used in aluminium filter applications and in regenerative burner applications. These unique materials are an expensive consumable in the aluminium casting facil- 84 Fig. 8: Spent balls from aluminium filter Fig. 9: Rotary processed alumina balls aluminium to be processed, cleaned and discharged into tubs after retraction of the entry feeder. Typical block size here is + 250 mm. • The coarse and fine particle removal is the next stag. This can be the key to recovering the value of the materials in processing dross and to the efficiency of the process with the autogenous impact designs. The screens in this area can have any opening size smaller than the liner holes. This hooded area is designed for two screens that allow for different opening sizes in each panel. These screens can quickly be removed and changed for other sizes, for instance if downstream processes need changed size fractions. A typical fines screen selection will range from -10 mm to + 3 mm. • An important option is the ability to select recirculation or direct discharge from the machine of the intermediate materials classified by the liner holes, which guarantees processing flexibility. In bath carbon processing it This equipment has the ability to simultaneously separate up to eight different size fractions in the same processing unit, from bag house dust up to 1,750 mm blocks. It achieves this with the appropriate selection of the crushing chamber dam ring openings, liner openings and screen sizes. The numerous Didion patents for this unique piece of equipment explain this very significant trait of the RT & RS processing units. There are significant advantages from both a process view point and from a general economics view point of being able to accomplish many processing steps in one unit has major advantages as seen from the viewpoints both of technical process and of general economics The process advantages that are the key bonus of this unit are that it can separate all material sizes as follows: • The ability to take almost any size of initial feed, the only restriction being the selection of the overall diameter of the unit. Systems are available in diameters up to 4.5 metres. The unique reversing feature of the system, with the units incorporating the primary impact chamber, allow for solid Fig. 10: Particle size control ALUMINIUM · 1-2/2013 SPECIAL A L U M I N I U M S M E LT I N G I N D U S T R Y with a 200 kW drive motor, the smallest with a 22 kW drive motor. Processing cost per tonne will vary with the size of the unit, with the largest unit processing 20 tph at an operating cost of USD0.75/t. This cost includes all monthly maintenance, capital costs, and a cast liner replacement after seven years of operation. This processing cost / tonne is exclusive of local labour cost. Certainly, even with all labour included, pro-cessing through these large units is less than USD10/t. Custom sizes, throughputs and processing configurations are part of the Didion philosophy of equipment design, and variants can always be evaluated and normally accomplished. Fig. 11: Material flow diagram and fines separation – RT can control the size and characteristics of the particles moving forward to the next process step. When processing materials that contain metallic aluminium, this element allows for high concentration of metallics that can be either efficiently melted in-house or sold for high metal contents. The liner holes / slot sizes typically range from 10 to 50 mm. • The autogenous milling section will reduce friable materials down to the size of the liner openings. No friable or metallic materials can then exit the back end of the drum. These materials will usually be in the size range of -250 mm to +50 mm. They can be further sized with a rotary classifier attached to the end of the drum to sort them into three additional cuts, depending on customer requirements. • The air flow of the bag house system provides the final product sizing possibilities. The pollution control device normally removes -0.5 mm materials. This fraction can be subdivided by use of a cyclone separator before the bag house. All of these sizing steps occur inside the Didion system to provide products that can be recycled as they are, or else moved on further for carbon re-use in the green carbon plant, or bath to be reused in the potlines. Dust emissions to the environment are strictly controlled by the bag house / pollution control system, which is either installed with the unit or attached to the plant system. General comments The RT/RS systems can be designed such that they can act as an aggressive crushing unit or as a gentler ‘scrubbing’ unit. They can also be designed to have both features in one unit. ALUMINIUM · 1-2/2013 This type of design flexibility is an advantage when removing bath from the spent anodes before crushing them to the appropriate size in the same piece of equipment. The installation space requirement for the largest unit is an envelope of approx. 6 x 30 metres. This layout would assume product discharge into tubs. Conveyors can be added to the system for continuous removal of the products. These conveyors can be set up in many configurations for additional separation steps, such as eddy current processing, magnetic separation and / or product bulk bagging. Stand-alone systems that are used for dross or salt slag processing typically require two people per shift to operate the entire system. The systems are very reliable. They were designed to be part of manufacturing lines in high-production automotive foundries that run 24 hours a day, seven days a week. Any unscheduled downtime is unacceptable to this industry. This reliable performance results from using simple, dependable parts and extremely heavy duty components. Operational costs are very low. The largest unit operates Fig. 12: RT system charging Summary The flexibility of the design configurations of the Didion rotary processing equipment offers many potential applications in the aluminium smelter environment. These dynamic systems can lower overall processing cost by reducing manpower, maintenance and energy consumption as well as reducing the plant area required for the above-mentioned materials processing practices. The additional benefits of better recyclability of the dross and other aluminiumcontaining materials will also reduce landfill cost and reduce greenhouse gas emissions. Authors David J. Roth is president and Brian Best is product manager of GPS Global Solutions, based at Downingtown, PA., USA. 85 A L U M I N I U M S M E LT I N G I N D U S T R Y Meeting of the ISO Committee for analysis of materials for primary aluminium in Switzerland L. P. Lossius, Norsk Hydro; J.-C. Fischer, R&D Carbon The Swiss standardisation authority SNV and R&D Carbon Ltd hosted the 6th Plenary Meeting of ISO Technical Committee 226 ‘Materials for the production of primary aluminium’ in Sierre early in October 2012. The participation was good, with 16 delegates and eight of the twelve P-member countries attending. Highlights of the meeting were the progress on four new alumina standards and the harmonisation of three anode / cathode standards on mechanical strength; details for each material type below are given below. Two new convenors were confirmed: Mr Wu Lin of Do-Fluorides (China) for smelter grade fluorides and Mr Jean-Claude Fischer of R&D Carbon (Switzerland) for petroleum coke. The Technical Committee 226 is responsible for 110 ISO standards on the sampling and analysis of materials for the electrolytic production of aluminium, covering the material groups Smelter grade alumina, Smelter Smelter grade alumina • Wu Lin of Do-Fluoride Chemicals Co., Ltd, China; WG4 on Smelter grade fluorides • Jean-Claude Fischer, R&D Carbon Ltd, Switzerland; WG6 on Petroleum coke. The Plenary Meeting reconfirmed 17 standards and confirmed the development of 11 new standards. This makes a fairly large number of standards, but current development work mostly replaces out-of-date methods with new and improved methods, and aims to later withdraw the out-of-date standards. For Smelter grade alumina there are four standards in development, based on the muchused Australian standards: elemental analysis by XRF, bulk density, flow time, and α-alumina content. In addition to the informal work in WG3, the following ISO technical experts are nominated for this work: Ray Brown (Alcoa Australia, SA), Flor Campa (Alcoa, for AENOR), Kjell Hamberg (Hydro, for SN) and Josef Lovcican (Slovalco, for SUTN). For Smelter grade fluorides the new standard ISO 12926 for elemental analysis by XRF From the tour of the R&D Carbon facilities in Sierre, from the left: Ray Brown (Alcoa, Convenor alumina), in front Erwin Smits (Aluchemie), Petter Lossius (Hydro, Committee Chair), Nigel Turner (Koppers EU, Convenor Pitch), Ma Cunzhen (SAC), Yu Yiru (JN Carbon), Xue Xujin (Do-Fluorides) and Jean-Claude Fischer (R&D Carbon, Convenor Petroleum coke). grade fluorides, Pitch, Petroleum coke and Carbon electrodes. The main work is maintenance and development of standards, with a dedicated work group (WG) for each material. After the Sierre meeting, the Work Group Convenors are: • Nigel Turner of Koppers EU, UK; WG1 on Pitch • Professor Harald A. Øye of NTNU, Norway; WG2 on Carbon electrodes • Ray Brown of Alcoa, Australia; WG3 on 86 will be ready for publication in 2013. Work is also on-going in the fluoride field to review or replace several old fluoride methods; ISO technical experts are Xujin Xue (Do-Fluorides, for SAC); Wu Lin (Do-Fluorides, for SAC); Oscar Pérez (Derivados del Flúor, for AENOR) and L.P. Lossius (Hydro, for SN). For Pitch, a critical issue today is the determination of Quinoline insoluble. TC 226 expresses high concern for the continued availability of Quinoline because REACH regula- tions could ban it, but Quinoline is vital and critical to an important raw materials test. The committee therefore recommends interested organisations, if they are surveyed, to state that they wish to retain Quinoline. In the Solid carbon bodies the next published standard will be the dynamic modulus of elasticity by the resonance method, which goes to the final vote this autumn. Work is also on-going to harmonise existing standards, and Andreas Schnittker (SGL Carbon, for DIN) has harmonised the existing standards for 3-and 4-point flexural strength, as well as the crushing strength standard; these will be republished in 2013. ISO technical experts are Harald A. Øye (NTNU, for SN), Jean-Claude Fischer (R&D Carbon, for SNV), Erwin Smits (Aluchemie, for NEN), Yu Yiru (JN Carbon, for SAC) and Nigel Turner (Koppers EU, for BSI). For Petroleum coke there is a revision to specific electrical resistivity to add measurement of the 1.4-1.0 mm fraction, harmonising the sample preparation for the routine coke analysis. For information on the work in TC226, please contact the Secretary Knut Aune at kau@standard.no or the Committee Chair Lorentz Petter Lossius, Hydro Aluminium, Norway at lorentz.petter.lossius@hydro.com. Stéphane Sauvage is the Technical Programme manager for TC226 on behalf of the ISO Central Secretariat, Geneva. Note that the standards in the TC226 programme are available in the ISO Store as a CD made specifically for ‘Materials for the production of primary aluminium’. The Committee thanks R&D Carbon, Hydro Aluminium and Sør-Norge Aluminium for sponsoring the 2012 Plenary Meeting and TC226. The plenary meetings are held every 18 months, and the next plenary meeting will be hosted by DIN and SGL Carbon, in Wiesbaden, Germany, on 8-9 May 2014. In September 2015, a plenary meeting will be hosted by SAC and Do-Fluorides Chemicals, in China. Authors Dr.-Ing. Lorentz Petter Lossius is principal engineer for primary metal technology at Norsk Hydro ASA, based in Øvre Årdal, Norway. Jean-Claude Fischer is director of R&D Carbon Ltd, based in Chalais, Switzerland. ALUMINIUM · 1-2/2013 SPECIAL A L U M I N I U M S M E L T I NTGE CI H NN DO US T RGYY LO Chips versus briquettes: How the aluminium industry can effectively and efficiently recycle scrap For the aluminium industry, there has long been an issue of how to recycle, transport and / or dispose of scrap metal and swarf (machining chips). Many in the aluminium industry recycle their scrap aluminium in the form of chips. These chips can provide additional revenue through recycling. However, there are some challenges with recycling aluminium chips as chips are bulky and tend to be difficult to transport. Also, it is difficult, if not impossible, to remove the machining coolant or lubricant, which leaves manufacturers with wet and oily chips. Recyclers often will not accept wet chips, or will charge a fine. Companies throughout Europe, and now in North America, have discovered a new way to process aluminium scrap: briquetting. Briquetting offers an efficient and effective way to recycle aluminium scrap, and it also solves many of the common problems that arise from recycling aluminium in the form of chips. Briquettes are consistent in shape, size and weight, and so they are easy to stack and transport, besides having other advantages that will be addressed later in this article. What is briquetting? At its most basic level, briquetting is a process that compresses metal scrap and swarf into compact, easy-to-manage round blocks (briquettes) with densities and resale values that rival those of massive metals. Briquet- ()##!)#$* ! &#$# !"!#$ % '''%!#$ % ALUMINIUM · 1-2/2013 © Ruf G. Tucholski, Ruf US Aluminium briquette and chips ting has been used for more than 50 years, but its technology and benefits have evolved greatly over the years. For example, old-style briquetting machines were big, loud and had high-maintenance costs. Today, briquetting systems made by companies like Ruf are just the opposite. Our briquetting systems are engineered specifically to run reliably and efficiently, and to deliver the same or better production rates while using less horsepower. ditional revenue and / or savings (especially when it is mostly oil), or it can be disposed of safely and more easily. There are two big advantages to being able to remove the coolant or oil: First, it allows the manufacturer to do the recycling in-house instead of having to go through a third party, which reduces costs. Second, when a manufacturer sells chips that still have coolant and oil on them, the manufacturer will be penalised. Transporting wet chips also creates a potential problem – it is The benefits for the aluminium industry As the technology and performance of briquetting have advanced, so have the potential benefits that it holds for the aluminium industry. Briquetting boosts the bottom lines by adding value to the waste stream. There are three main advantages of briquetting for manufacturers: The melting factor: The biggest advantage of briquetting aluminium is that briquettes melt better than loose chips. Comparing the same weight of briquettes versus chips, briquettes will produce more aluminium after being melted. Chips tend to burn, whereas briquettes melt more like a solid. This is the main reason smelters use briquettes instead of chips – they are going to get more metal out of their bath than if they were using chips. When the process is complete, more material is recovered with briquettes, which means more revenue. Removing coolant or oil: Through the briquetting process, coolant or oil lubricant that saturates aluminium drains out more easily. This liquid can then either be recycled for ad- Briquettes are consistent in shape, size and weight, therefore easy to stack and transport hazardous if the oil or coolant drips onto the road during transport, so extra precautions and steps must be taken. This penalty, along with the liability of transporting wet chips, can really add up. Space, transportation and storage: When dealing with chips, there have always been issues with storage and transportation because chips are loose, take up much more space and cannot be stacked or contained neatly. Briquetting solves all of these problems. Briquettes are stackable, which makes them easy 87 TECHNOLOGY to transport and store. Additionally, the density of briquettes helps during transport. Briquettes weigh about 120 pounds per cubic foot (about 2,000 kg/m3) whereas chips weigh only about 15 pounds per cubic foot (about 250 kg/m3). The cost savings for transporting briquettes alone tends to justify manufacturers’ purchase of a briquetter. Briquetting in action: how briquetting helps global manufacturer of training ammunition to squeeze value from its scrap Ultimate Training Munitions (UTM) makes high-performance training ammunition and safety systems that allow armed forces and law enforcement agencies in the US and around the world to conduct safe and effective Close Quarter Battle (CQB) training Ruf briquetter exercises. Headquartered in the United Kingdom, UTM also has production find the right briquetting solution for its opfacilities in the United States as well as a global erations. sales network operating in 45 countries. According to Wagner, this included briIn UTM’s US factory, ten machines work quetting test batches of UTM’s scrap, and then in 60,000 square feet of space to create train- sending the briquettes to an independent lab ing ammunition, weapon conversion kits, and to test their moisture content to ensure that safety system equipment. During production, Ruf’s technology would meet the company’s tonnes of turnings are created as the precision needs. “Our moisture content threshold for munitions and system components are turned getting optimum return for our chips is 2%. and finished using a high-speed aluminium With Ruf briquettes, our chips contain only 1.1 turning processes. Because copious amounts to 1.8% moisture. This drastically improves of oil are required to keep the aluminium lu- our chip resale revenues – by about 50 cents bricated as it is turned, the turnings produced per pound.” Since deploying its Ruf briquetter, UTM are so saturated with oil that they are practically worthless. This created a problem for has grown scrap revenue by 250% and is also UTM because it was forced to dispose of these able to filter and reuse the processing oil it oily, messy turnings as best it could – tempo- reclaims as the scrap is compressed during rarily storing them as waste in hoppers, where the briquetting process. Wagner says that his oil could be partially drained before the turn- company’s Ruf briquetter paid for itself in ings were sold for next to nothing to scrap less than six months. Overall, the efficiency of UTM’s operations has risen with streamlined processors. Coming across Ruf Briquetting at an in- scrap processing, and because scrap drainage ternational manufacturing technology trade hoppers are no longer needed, UTM was able show, UTM’s plant manager saw the potential to save 20% of its valuable floor space. Its for briquetting as a way to tackle his plant’s factory is cleaner, and as a result its employees chip disposal problem. After making a visit are safer. As illustrated by UTM’s results, briquetting to Ruf’s German production facility to gain a ground-up understanding of its innovative solves many potential problems and increases briquetting technology and systems, UTM be- revenue for manufacturers dealing with alugan working with Ruf’s team in the US. UTM’s minium. Briquettes melt at a higher yield than Ralf Wagner says that Ruf was a pleasure to chips. Chips are less dense and have a relawork with every step of the way, and was tively larger surface area, so that they tend to willing to do “whatever it took” to help UTM burn or oxidise during the melting process. 88 Briquettes melt more like compact metal, so the manufacturer sees a recycling price closer to that of recycling compact aluminium. Additionally, the coolant or oil recovery during the briquetting process cuts costs. Wet chips are too dangerous to mix with molten metal. If a manufacturer is using oil as a lubricant, the oil savings and recovery alone will usually pay for a briquetter. Thirdly, briquetting saves time and space for manufacturers, while also making transportation easier and more cost efficient. As briquetting becomes more common throughout North America and beyond, its benefits to manufacturers will continue to grow as well. About Ruf Located near Cleveland in North Olmstead, Ohio, Ruf is the North American subsidiary of Ruf GmbH & Co. KG in Germany – a global pioneer of advanced briquetting systems for more than 40 years. The quality and performance of its briquetting systems are proven worldwide with more than 3,000 machines currently in operation. Author Greg Tucholski is with Ruf US, based in North Olmstead, Ohio, USA. ALUMINIUM · 1-2/2013 TECHNOLOGY Bühler Lost-CoreTechnologie eröffnet weites Anwendungsspektrum Aktuelle Trends wie der Leichtbau in der Automobilbranche oder der Druck, immer bessere Produkte zu geringeren Kosten zu produzieren, verlangen nach kreativen Lösungen im Druckguss. Eine innovative Antwort darauf ist die LostCore-Technologie (Salzkerntechnik), die vielfältige Anwendungen erlaubt. Auf einem Symposium der Bühler AG Mitte November in Uzwil, Schweiz, ließen sich über hundert Entwickler und Anwender aus aller Welt darüber ins Bild setzen. Gut besuchtes Symposium Das große Interesse an der neuen Technologie zeigte sich am gut besuchten Symposium von Bühler Mitte November. Die über hundert Teilnehmer, vor allem von Vertretern der Automobilbranche und ihren Zulieferern, konnten sich von den Vorteilen des Lost-CoreProzesses persönlich überzeugen. Zum besseren Verständnis wurde ein konkretes Projekt in allen Schritten simuliert. Auch der Wirtschaftlichkeitsaspekt kam nicht zu kurz und wurde von Andreas Hennings und Georg Habel vom Gießereiunternehmen Bocar unterstrichen. Als weiteren Höhepunkt konnten die Teilnehmer die verschiedenen Prozessphasen live miterleben. Prof. Dr. Lothar Kallien von der Hochschule Aalen präsentierte ergänzend die Ergebnisse eines 3D-Freiformflächenprojekts, bei dem die Lost-Core-Technologie angewandt wurde. N Bühler Lost Core technology opens up a wide range of applications Current trends such as lightweight construction in the automotive industry or the pressure to manufacture increasingly better products at lower cost require creative die casting solutions. An innovative answer to this is the ‘Lost Core’ technology (salt core technology), which allows for a diverse range of applications. More than 100 developers and users from around the globe listened to these multifaceted opportunities at a symposium in mid-November at the Bühler headquarters in Uzwil, Switzerland. What the automotive industry is calling for is cost reduction, integral design (reduction in the number of components) and higher productivity. The Lost Core technology opens up diverse opportunities for this. With this technology certain parts of the component to be cast are recessed with a salt core which is then rinsed out again. This allows to replace permanent mould cast and sand cast components by die castings, with the benefits of material savings, shorter cycle times and reduced post-processing. Lost Core also enables the development of completely new components. The internal shaping can comprise complex designs; the combination of multiple components into one single unit enables high function integration and the increased design freedom allows for a completely new component design. The Bühler Lost Core process begins with the component design for the salt core application, followed by the mould, aluminium part and salt core concepts. The behaviour of the liquid salt and aluminium in the mould as well as the quality of the component can be simulated by software. This eliminates the need for subsequent costly adaptations of the mould. In the creation of the salt core which deter- © Bühler Namentlich die Automobilindustrie ruft nach Kostenreduktion, integralem Design (Verringerung der Anzahl an Bauteilen) und höherer Produktivität. Die Lost-Core-Technologie eröffnet dazu vielfältige Möglichkeiten. Bei diesem Verfahren werden gewisse Partien des zu gießenden Bauteils mit einem Salzkern ausgespart, der dann wieder ausgespült wird. Auf diese Weise lassen sich Bauteile aus dem Kokillen- und Sandguss substituieren; zugleich kommen die Vorteile des Druckgießens – Materialeinsparung, kürzere Zykluszeiten, weniger Nachbearbeitung – voll zum Tragen. Zusätzlich erlaubt Lost Core die Entwicklung ganz neuer Bauteile. So kann die innere Formgebung komplexer gestaltet werden. Die Zusammenfassung mehrerer Bauteile zu einem einzigen ermöglicht eine höhere Funktionsintegration und die erhöhte Gestaltungsfreiheit erlaubt ein komplett neues Teiledesign. Am Anfang des Bühler Lost-Core-Verfahrens steht das Teiledesign für die Salzkern- applikation, gefolgt vom Form-, Aluminiumteil- und Salzkern-Konzept. Das Verhalten des flüssigen Salzes und des Aluminiums in der Form sowie die Qualität des Bauteils können heute mit Software simuliert werden. Dadurch entfallen nachträgliche, kostentreibende Anpassungen der Form. Bei der Herstellung des Salzkerns, der die innere Formgebung des Bauteils bestimmt, spielt die optimale Salzlösung eine zentrale Rolle, um die Stabilität des Kerns zu garantieren und die anschließende Entkernung zu ermöglichen. Produziert werden Salzkern und Aluminiumbauteil auf einer Druckgießmaschine mit Echtzeitregelung. Diese stellt sicher, dass der Kern während des Umgießens nicht beschädigt wird. Entfernt wird der Kern mit Wasserhochdruck. Bühler verfügt über die Ausrüstung für die erfolgreiche Anwendung der Lost-CoreTechnologie und kann den gesamten Prozess von der ersten Idee bis zur Produktionsreife unterstützen. Fotos: a) Aluteil, b) Salzkern, c) Aluteil mit Kern ALUMINIUM · 1-2/2013 Photos: a) Aluminium component, b) Salt core, c) Component with salt core 89 TECHNOLOGY mines the internal shaping, the optimal salt solution plays a crucial role in ensuring the stability of the core while simultaneously enabling its subsequent removal. The salt core and the aluminium component are produced on a die casting machine with real-time control. This prevents damage to the core during recasting. The core is removed by pressurised water. Bühler has the necessary know-how and equipment for the successful application of Lost Core technology and is in a position to support the complete process from the initial idea to the production stage. A well-attended symposium The great interest in the new technology was demonstrated by the well-attended Bühler symposium in mid-November. A concrete project was simulated over all stages to pro- mote better understanding. The economic aspects were also discussed by Andreas Hennings and Georg Habel from the Bocar die casting company. The participants were also able to experience the various process phases live. Prof. Lothar Kallien from the University of Aalen supplemented the programme by presenting the results of a 3D free-form surface project which was implemented using the Lost Core technology. N GM welding innovation enables increased use of aluminium 90 © General Motors tures and closures in such a robust fashion will give GM a unique manufacturing advantage,” said Jon Lauckner, GM chief technology officer and vice president of Global R&D. “This new technology solves the long-standing problem of spot welding Essentially a novel development of resistance aluminium, which is how Concentric rings on the domed electrode tip shown on the right, are key spot welding, GM’s process innovation uses a all manufacturers have to the effectiveness of the aluminium resistance-welding technology. GM’s patented process centres on three concepts: the electrode design, patented multi-ring domed electrode in joining welded steel parts together the controls for the electrical current and the technology for dressing the aluminium to aluminium, which overcomes for decades,” he adds. “It is tip intermittently. the unreliability of traditionally used smooth an important step forward tip electrodes. By using this process GM ex- that will grow in importance as we increase the parts containing rivets is more complex. “No other automaker is spot-welding alupects to eliminate nearly 2 lb (0.907 kg) of riv- amount of aluminium used in our cars, trucks minium body structures to the extent to which ets from aluminium vehicle body parts such and crossovers over the next several years.” as doors, bonnets and tailgates. GM already Spot welding uses two opposing electrode we are planning, and this technology will allow uses this patented process on the bonnets of pincers to compress and fuse metal parts to- us to do so at low cost,” according to Blair the Cadillac CTS-V and the tailgate of the hy- gether, using an electrical current to create Carlson, GM manufacturing systems research brid versions of Chevrolet Tahoe and GMC intense heat to form a weld. The basic process lab group manager. Notably, he adds that the Yukon. The company says it plans to exploit is inexpensive, fast and reliable, but until now, company is to consider licensing the technolthis technology more extensively starting in not sufficiently robust for use with aluminium ogy for non-GM production in wider areas of in the present manufacturing environment. automotive, heavy truck, rail and aerospace 2013. “The ability to weld aluminium body struc- GM’s new welding technique is said to work applications. According to Ducker Worldwide, a Michion sheet, extruded and cast aluminium with the use of gan-based market research firm, aluminium a result of a proprietary use in vehicles is expected to double by 2025, multi-ring, domed elec- reflecting the many advantages the metal oftrode head that penetrates fers compared with steel. One kilogram of the surface metal oxide to aluminium can replace 2 kg of steel. Its corrosion-resistance and excellent blend of strength produce a stronger weld. Historically, carmakers and low mass can help improve fuel economy have used self-piercing riv- and performance. Further highlighting these ets to join aluminium body application benefits AluminumTransportaparts, due to the variabil- tion.org adds that a 5 to 7% fuel saving can ity in production with con- be realised for every 10% weight reduction, ventional resistance spot and substituting lightweight aluminium for a welding. However, use of heavier material is one way to achieve this rivets adds cost and riv- goal. Cars made lighter with aluminium also eting guns have a limited can accelerate faster and brake quicker than 2013 GM Chevrolet Tahoe hybrid SUV: The two-mode power system is state-of-the-art engineering, but the battery pack adds more than 300 lb range of joint configura- their heavier counterparts. (136 kg) to the vehicle. Weight is a fuel economy killer – and to compentions. In addition, end-ofsate, the bonnet and tailgate are aluminium. The lighter-weight metal is also used for the wheels, which are low mass, aero-efficient forged parts. Ken Stanford, contributing editor life recycling of aluminium In the USA, General Motors Research & Development, headquartered in Warren, Michigan, has developed what it claims to be an industry-first aluminium welding technology expected to enable more use of the metal in future vehicles, in which its lightweighting advantage can help improve both fuel economy and driving performance. ALUMINIUM · 1-2/2013 APPLICATION Aluminium: Tesla’s secret weapon in new Model S The Palo Alto, California-based car manufacturer announced three years ago that it planned to build an aluminium-bodied saloon, and the company scheduled a production run of 5,000 cars for 2012, ramping up to 20,000 for this year. To date, Tesla had released only its acclaimed ‘Roadster’, which combined an extruded aluminium chassis with carbon fibre composite body panels. Now notably, for the larger Model S saloon, aluminium components have been substituted for composites. Tesla’s design director, Franz von Holzhausen, explains: “For limited or lowvolume production cars like the Roadster, carbon fibre is a material to reduce weight, but not a solution for higher-volume production due to costs and manufacturing time. For Model S, we are using aluminium for the body panels and chassis, realising that it is as strong as steel but lighter in weight, and has similar manufacturing capabilities. Weight is the enemy of fuel economy – and in the case of Model S, battery life and lighter weight translate directly to efficiency.” Tesla has robustly emphasised that the Model S is the first all-electric luxury saloon to be built “from the ground up” – with the aim of creating a vehicle with optimal rigidity, light weight, aerodynamics, and interior space: Tesla engineers fit the vehicle’s slimline battery pack below the floor in a perfectly flat array to provide the Model S with the under-car airflow and aerodynamics more commonly associated with a race vehicle – while maximising the occupancy space above (the vehicle can seat up to seven passengers). Advertisement The battery pack – a high-performance aluminium structure in its own right – when married to the state-of-the-art aluminium body structure, according to Tesla engineers, becomes three times stiffer. ALUMINIUM · 1-2/2013 © Tesla USA Tesla Motors’ Model S electric performance prestige saloon car, already well underway shipping to buyers worldwide, is one of the latest fine examples of aluminium-intensive vehicle design and construction. Tesla Motors’ new aluminium intensive Model S saloon … … pioneers performance, economy and safety The body shell itself is aluminium space frame architecture comprising castings, extrusions and stampings. Cast cross members and aluminium extrusions in the front-end crumple zone, unhindered by the presence of a gasoline engine, are designed to maximise impact absorption in the event of a crash. (Model S is engineered with the intent of achieving 2012 five-star NHTSA safety ratings.) Tesla’s rear multilink suspension – unique to the Model S – is made from lightweight but exceptionally rigid extruded aluminium, helping the vehicle to achieve sportscar-like ride and handling performance, including acceleration to 96 km/hr (60 mph) in a swift and silent 4.4 sec. Tesla Motors has purchased the former NUMMI factory in Fremont, California, where it will build the Model S sedan and future Tesla vehicles. As recently as April 2010, this factory was used by Toyota to produce the Corolla and Tacoma vehicles using the industry-leading Toyota production system. It is claimed to be one of the largest, most advanced and cleanest automotive production plants in the world. The factory is located in the city of Fremont near Northern California’s Silicon Valley, very close to Tesla’s Palo Alto headquarters. The company claims best-inclass engineers can be recruited in the high tech area and the short distance also ensures a tight feedback loop between engineering, manufacturing and other Tesla divisions. Ken Stanford, contributing editor 91 CO M PA N Y N E W S W O R L D W I D E Aluminium smelting industry © Dubal The upgrade was made possible with the successful installation of the first 1,600 mm long anode in Potline 5. Alba’s production process will receive further boost with additional modifications from the reduction side on anode reference gauges, PTA shovel size, simulations on start-up pots, etc. Alba produced 890,217 tonnes of primary aluminium in 2012 – a production record on the previous year (881,310 tonnes). The record in metal production was achieved without incurring any significant additional capital expenditures, says CEO Tim Murray. N Aluminium S.A. signs USD200m contract with Glencore Aluminium S.A., part of the Mytilineos group, has signed a USD200m contract with Swissbased multinational Glencore for the sale of 75,000 tonnes of aluminium billets and slabs. These quantities will be exported to the European and US markets from January 2013 to June 2014. This contract confirms the group’s strong export orientation and stresses the important role of the aluminium industry in Greece, where it contributes more than 80% of the added value of Greek finished products that are exported abroad. concrete: “Today we see the first aluminium produced in Saudi Arabia and the launch of a new industry,” he said. Abdullah Busfar, chairman of the Ma’aden Alcoa joint venture, commented: “It is just 29 months since the joint venture issued Bechtel with a notice to proceed with construction.” He congratulated Bechtel and its team of 46 different sub-contracting companies that employed the labour and expertise of about 14,000 people from 25 different nationalities to reach this milestone. “They have worked almost 60 million hours with worldclass safety performance. More than 700 Saudi Arabian citizens have completed their initial intensive training and are ready to take their place as skilled operators within this smelter,” he said. RTA evaluates offers for French smelter Metal Bulletin reports that Rio Tinto Alcan is evaluating several offers for its Saint-Jeande-Maurienne aluminium smelter in the French Alps as part of a process to find a buyer for the plant. The smelter could close once its energy contract expires in 2013 if a buyer is not found. Production curtailments began at Saint-Jean-de-Maurienne after the 2008 downturn. Ma’aden Alcoa joint venture celebrates first hot metal On 12 December Ma’aden and Alcoa commissioned the first of 720 pot cells at their joint venture smelter at Ras al Khair in Saudi Arabia. At the smelter ceremony, Ma’aden president and CEO Khalid Al Mudaifer highlighted the achievement of first hot metal in only 25 months from the pouring of first 92 Disinvestment of Nalco delayed The Indian government has delayed the sale of its 12.5% stake in National Aluminium Co. (Nalco), saying that the company’s latest quarterly financial performance did not reflect its true financial position. The divestment will now happen in the first quarter 2013. Further talks about the Nalco disinvestment will take place early in January. The Indian government is offloading stakes in metals companies Hindustan, such as Copper Ltd, in Metals and Minerals Trading Corp. of India Ltd and in Nalco in an effort to pump revenue into its slowing economy. Alba upgrade to improve productivity Aluminium Bahrain (Alba) has upgraded its Potline 5 from AP30 to AP36 technology. Bauxite and alumina activities CBG and Mubadala sign bauxite deal Compagnie des Bauxites de Guinée (CBG), one of the world’s largest bauxite explorers, has signed a long-term supply agreement with Abu Dhabi’s Mubadala Development Company. CBG is 49% owned by the government of Guinea and 51% by Halco Mining, a consortium composed of Alcoa, Rio Tinto Alcan and Dadco. The new agreement is expected to boost Guinea’s GDP by about USD500m a year and provide a significant increase in fiscal revenues. Mubadala owns 50% of Emal, with the remaining 50% owned by Dubal. Mubadala revealed in Q2 2012 that it was performing a feasibility study regarding the construction of an alumina refinery. Global Alumina acquires BHP interest in Guinea project Global Alumina, a corporation participating in a joint venture to develop an alumina refinery, mine and associated infrastructure in the bauxite-rich region of the Republic of Guinea, has announced that the joint venture partners Dubal and MCD Industry Holding (Mubadala) have waived their pre-emptive rights to purchase their pro rata share of BHP Billiton interests in the project. Therefore, Global Alumina will acquire all of BHP’s one third interest in the project, increasing its stake in the project from 33.3 to 66.7%. The joint venture wants to develop a 10m-tpy bauxite mine, with a refinery that would have a capacity of more than 3.3m tpy. N ALUMINIUM · 1-2/2013 CO M PA N Y N E W S W O R L D W I D E Chalco plans to build alumina plant in Indonesia Aluminum Corp. of China plans to build an alumina facility with a production capacity of 1m tpy in Indonesia. A feasibility study is under way; the earliest date for completion of the plant will be 2014/15. This is what President Luo Jianchuan said in an interview in November. In August last year, Chalco signed an agreement with PT Indonusa Dwitama to form a joint venture destined to develop Indonesia’s biggest bauxite mine. China imports over 60% of its bauxite, of which about 80% (2011: 36m t) comes from Indonesia. However, bauxite imports from Indonesia fell 55% in October from a year ago to 1.1m tonnes. N Aluminium semis fuel-efficient commercial truck, trailer and bus wheels. This is the first wheel manufacturing facility Alcoa has opened in China, adding to the list of existing wheel facilities in North America, Europe and Japan. AWTP has had a presence in China since 2004, when it began selling wheels out of Shanghai. Since then, the business has grown to include an employee base in Guangzhou, Beijing, Jinan and Suzhou. Through additions to its distribution network earlier in 2012, Alcoa has built a robust sales and service presence capable of supporting all of China. N © Hydro On the move Ground-breaking ceremony for aluminium rolling mill In mid-December, Alcoa and Ma’aden broke ground for the construction of expanded rolling mill capabilities at Ras Al Khair. The new capabilities will enable the facility to supply aluminium automotive, building and construction sheet, and foil stock to the Kingdom’s developing new industry and other global markets beginning in 2014. Brazil world leader in aluminium beverage can recycling The Brazilian Aluminium Association (Abal’)and the Brazilian Association of Cans of High Recyclability (Abralatas) have reported that the country has recycled 248,700 tonnes of aluminium beverage cans of a total of 253,100 tonnes available on the market in 2011. This corresponds to a recycling rate of 98.3%, keeping Brazil ahead in the world leadership since 2001. The beverage can manufacturing industry has been investing continuously to meet the demand. In 2012, the industry increased its production capacity from 21 to 23 billion units ALUMINIUM · 1-2/2013 a year (+9.5%); growth in the consumption of cans is expected to rise 7%. Alcoa will curtail Indiana extrusion plant in 2013 Alcoa will lay off employees at its extrusion plant in Auburn, Indiana, and curtail the facility by the end of March due to weak market conditions. The plant is part of Alcoa’s Wheel and Transportation division, and produces automotive components and extrusions. Cutting costs has been cited as a priority for Alcoa, as weak aluminium prices combined with high energy costs have put pressure on producers in recent years. Alcoa opens aluminium wheel facility in Suzhou, China Alcoa Wheel and Transportation (AWTP) has opened a production facility in Suzhou marking an expansion that creates a full wheel manufacturing, distribution, sales and service network in China. This facility brings to China Alcoa’s forged aluminium wheel technology that manufactures lighter, stronger and more Aleris has appointed Ralf Zimmermann senior vice president and general manager of Rolled Products Europe. K. Alan Dick, executive vice president and CEO of Aleris Global Recycling, is leaving the company. In future, the company’s recycling business will be led by Terrence J. Hogan, senior vice president and general manager of Recycling and Specification Alloys Americas, and Russell Barr, vice president and general manager of Recycling Europe. Roeland Baan, executive vice president and CEO of Global Rolled & Extruded Products at Aleris, is new chairman of the European Aluminium Association (EAA) for the period 2013-2015. He succeeds Tadeu Nardocci (Novelis). Gerd Götz, formerly global head of Public Affairs with Philips, has been appointed EAA’s new director general. He succeeds Patrick de Schrynmakers, who has left the association after 12 years of commitment. Eric Roegner, 42, has been named COO of Alcoa Investment Castings, Forgings and Extrusions, a new position. He has been president of Alcoa Forgings and Extrusions since 2009 and has led Alcoa Defence since June 2012. Marian Daniel Nastase has been appointed Vimetco’s president of the board of directors; Frank Mueller was appointed vicepresident of the board of directors. Eivind Kallevik has been appointed executive vice-president and CFO of Norsk Hydro. The appointment of Kallevik, currently head of finance in Hydro’s Bauxite & Alumina business area, will become effective from 15 February. He will replace Jørgen C. Arentz Rostrup. Executive vice president of Extruded Products, Hans-Joachim Kock, succeeds Mr Kallevik as head of Finance in Hydro’s Bauxite & Alumina business area. 93 CO M PA N Y N E W S W O R L D W I D E Suppliers Danieli Fröhling supplies slitting and trimming line to Novelis Nachterstedt After having received orders for various Novelis plants, e. g. in Brazil and Korea, Danieli Fröhling has been granted another contract to supply a slitting and trimming line, this time to Novelis Nachterstedt, located in Saxony Anhalt, Germany. The Nachterstedt plant supplies customers of industrial, packaging, building and automotive applications in Europe. It is equipped with the latest cold rolling technology and features a robot workshop dedicated to the laser-cutting of shaped body blanks for the automotive industry. The new edge trimming and slitting line will handle material up to 3.5 mm thickness and a strip width of 850 mm up to 2,250 mm. Line speed is up to 800 m/min. The incoming coil weight will be as much as 25 tonnes. One of several highlights of this line is the full automatic positioning slitting shear with centre cut. Cutting width, cutting gap and cutting depth adjustment will be positioned automatically after input of incoming strip data within seconds. The first coil is to be processed on this line in early 2014. Seco/Warwick acquires Nespi International Seco/Warwick GmbH, located in Stuttgart, Germany, has acquired 100% of Nespi International, Bedburg-Hau, Germany. Nespi is a furnace engineering company specialised in retrofits, repairs, service and spare parts supplies for many types of furnaces. This is a fur- ther step in the growth strategy of the Seco/ Warwick group, which is one of the major heat processing equipment manufacturers worldwide. The acquisition will strengthen Seco/ Warwick’s business, especially on the German and Western European markets, such as Austria, Switzerland and the Netherlands. Group CEO Pawel Wyrzykowski stated: “After our successful development in some key world markets we would like to put emphasis on our offer to our German speaking customers now.” Nespi has been renamed Seco/Warwick Service GmbH. At the end of November Seco/Warwick SA, Swiebodzin / Poland, dissolved the joint venture with Winfor GbR, Stuttgart, that both companies held in Seco/Warwick GmbH. Seco/Warwick SA acquired the Winfor shares in Seco/Warwick GmbH. The managing directors Thomas Wingens and Karol Forycki left Seco/Warwick GmbH on 30 November. Thomas Kreuzaler has temporarily taken over as managing director beside his other group functions. Novelis scrap melting furnace under commissioning In January 2013 commissioning of the new melting furnace supplied by Hertwich Engineering, Austria, was well in progress at Novelis Italia SpA in Pieve, Italy. This Ecomelt PS-80 multi-chamber furnace is aimed to recycle clean and contaminated aluminium scrap for a new casting line at Pieve, as part of Novelis’ effort to raise the recycling content in its various rolling operations around the world from 34 to 80% by 2020. The Ecomelt PS-80 is designed for processing 80 tonnes per day. The Ecomelt furnaces operate particularly economically when melting scraps which contain combustible organic substances, so reducing gas consumption to 400 kWh/t, significantly below that of conventional melting furnaces. That saves energy costs and lowers the CO2 emissions. In addition, the immersion melting process reduces metal loss to below 3%. Hertwich Ecomelt furnaces combine high flexibility in terms of scrap types with low metal loss and low environmental impact. The Ecomelt concept of scrap recycling will be the central topic of a presentation to be held at OEA Aluminium Recycling Congress in Düsseldorf, Germany (25./26. February 2013). Otto Junker and Can-Eng Furnaces co-operate on services The Otto Junker Group, Simmerath/Germany, and Can-Eng Furnaces International Ltd, Niagara Falls / Ontario, have recently signed an agreement to co-operate on customers services. The companies’ complimentary product range will enhance each other’s ability to service worldwide users of thermal processing equipment. Global customers will find a complete range of ferrous and non-ferrous melting, pouring, process heating and heat treating equipment for complex thermal processing applications. To support customers, both Otto Junker and Can-Eng would invite inquires for either groups products be forwarded to the nearest geographical sales office. Key contacts are Tim Donofrio (vice president, Standard and Aluminium Products, Can-Eng Furnaces, tdonofrio@can-eng.com) and Jan van Treek (sales manager Thermoprocessing Plants, Otto Junker, jvt@otto-junker.de). N The Author © Hertwich The author, Dipl.-Ing. R. P. Pawlek is founder of TS+C, Technical Info Services and Consulting, Sierre (Switzerland), a service for the primary aluminium industry. He is also the publisher of the standard works Alumina Refineries and Producers of the World and Primary Aluminium Smelters and Producers of the World. These reference works are continually updated, and contain useful technical and economic information on all alumina refineries and primary aluminium smelters of the world. They are available as loose-leaf files and / or CD-ROMs from Beuth-Verlag GmbH in Berlin. Hertwich Ecomelt PS furnace 94 ALUMINIUM · 1-2/2013 RESEARCH Cathode wear in Hall-Héroult cells K. Tschöpe, E. Skybakmoen, A. Solheim, SINTEF Materials and Chemistry; T. Grande, NTNU Laboratory tests for cathode wear identify some variables as important, and eliminate others. These results are compared with models and with industrial potline experience. Introduction The research team Electrolysis in SINTEF Materials and Chemistry offers a high level of competence in the field of light metals production, molten salt chemistry, and particularly, the process of aluminium electrolysis. The activities cover fundamental as well as applied research in close collaboration with the industry and NTNU (Norwegian University of Science and Technology). This paper reviews the recent activities in the Durable Materials in Primary Aluminium Production (DuraMat) project on cathode wear, a phenomenon that is of great interest for all primary aluminium producers. The Hall-Héroult process has for more than 125 years been the only commercial method for primary aluminium production. To date, this process has survived the attempts to replace it by alternative methods such as carbothermal reduction, electrochemical reduction of anhydrous aluminium chloride, and electrolysis based on inert electrodes. Tremendous scientific and technological efforts have been made to improve the efficiency of the process; e. g. the potline amperage has been increased from 50 kA in 1940 to currently 400-500 kA [1]. Modern cells may operate at specific energy consumptions as low as 12.5 kWh/kg Al, and the current efficiency is typically in the range of 92-96%. Careful choice of new lining materials, and in particular, the increase of the graphite content in cathode blocks, is one of the factors that made this possible. Anthracitic carbon has been gradually replaced by the now state-ofthe-art graphitised cathode blocks. While this has allowed additional energy savings and increased productivity through the increased electrical conductivity, these benefits need to be weighed against higher material costs and lower wear resistance. eventually leads to direct contact between the metal and the collector bar. Consequently, cathode wear is usually the limiting factor for the service life of aluminium reduction cells. The cross sectional view of cathode blocks often reveals a W-shaped wear pattern, and even a WW-pattern has been observed, as shown in Fig. 1 [3]. Typical wear rates are in the range of 2-6 cm/year [4]. The cell service life is a crucial economic parameter, which makes it important to understand the wear Fig. 1: Visualisation of the wear profile. Cathode surface of a shutdown cell after 2,088 days in operation (a); plotted image using the laser scanmechanism(s). ning method, the blue colour corresponds to less wear and the red colour It is generally agreed indicates the highest wear (b); longitudinal wear profile of all 19 cathodes that formation, disso- showing the WW-shaped wear pattern (c) [3]. lution and transport of aluminium carbide are important factors and (2), respectively. However, the underlythat influence the cathode wear. Aluminium ing mechanism(s) suggested are mainly based carbide can be formed chemically as well as on theoretical considerations and are still a © electrochemically, according to reaction (1) matter of discussion [5-10]. Characteristics of cathode wear a) Wear is generally defined as net removal of material from a surface [2]. Carbon blocks wear excessively along their periphery, which ALUMINIUM · 1-2/2013 b) Fig. 2: Schematic drawing of the experimental set-up with a quartz glass tube and position of the sample (a) as well as the sample appearance and its exposed cross section after embedding and polishing (b) 95 RESEARCH 4 Al(l) + 3 C(s) → Al4C3(s) (1) 3 C (cathode) + 4 AlF3 (diss) + 12 e- → Al4C3 (s) + 12 F- (diss) (2) To improve the physical understanding and to build competence concerning this branch of materials performance, we need to combine data from chemical and electrochemical experiments with fundamental studies on diffusion and thermodynamics, and with computer modelling of transport processes. This paper aims to give an insight to the wear mechanisms of the carbon cathode by summarising the procedures and some of the main results from our experiments. A more detailed description can be found in a series of publications in the corresponding literature [11-18]. Fundamental studies To understand the formation mechanism(s) of aluminium carbide it is necessary to examine possible influencing factors. As stated above, the formation of aluminium carbide could be of either chemical or electrochemical nature. The simplest system to start with is molten aluminium and carbon in direct contact (case 1) using the so called Al-C diffusion couple test. In the further course of the work, we intend to include stepwise other parameters such as presence of cryolite (case 2) and polarisation (case 3), so as to build up an experiment that mimics real potline conditions. The test setup for case 1 and 2 experiments is shown in Fig. 2. More detailed descriptions can be found elsewhere [11, 12]. Case 1 experiments revealed that aluminium carbide indeed forms by a purely chemical reaction at the Al-C interface. Temperatures above 1 100 °C were needed for carbide formation, probably because the reaction was impeded by a protective Al2O3 layer initially present at the aluminium surface due to exposure to air. This oxide layer had to evaporate and/or disintegrate mechanically by thermal a) b) c) d) expansion to ensure appropriate contact between aluminium and carbon, leading to the formation of a dense layer of small Al4C3 crystallites. A possible reaction mechanism for the first stage of carbide formation was discussed [11]. Introduction of synthetic cryolite at the Al-C interface changed the morphology of the aluminium carbide layer to a more needle-like structure, and reduced the reaction temperature to 1 030 °C [12]. This confirms that cryolite acts as a wetting agent by dissolving the oxide layer [5, 7]. This is ongoing work, and studies currently focus mainly on cases 2 (cryolite) and 3 (polarisation). The authors used the case 1 set-up in a side study to compare different types of carbon materials and their influence on aluminium carbide formation. Sample treatment, temperature, duration, and argon pressure in the glass tube were kept constant throughout the experiments. Afterwards, the quartz tube shown in Fig. 2a) was quenched in water and the sample was removed. The spent samples were embedded in epoxy and wet cut with 100 % ethanol in a precision diamond saw. Afterwards, the samples were wet-ground and polished using 100% ethanol as lubricant to avoid reactions of the aluminium carbide in the sample with the moisture in air. Optical microscopy using a polarising filter revealed the Al-C interface and aluminium carbide formation. Some of the initial results are presented in Fig. 3. As can be observed, all types of carbon produced aluminium carbide layers with similar appearance, which leads to the preliminary conclusion that the carbide formation is independent of the type of carbon material. Even though the Al-C diffusion tests are long-term tests and involved only small amounts of carbide formation, the authors would like to point out that this result is in accordance with observations made during the wear test studies, which will be described in the following. Experimental cathode wear investigations Fig. 3: Comparison of polished cross sections of different carbon materials: electrode graphite (a), graphitised carbon of two different types (b, c) and vitreous carbon (d) after the experiments performed at 1 200 °C, 0.8 bar argon atmosphere and 10 days duration. The Al4C3 layer is clearly visible at the aluminium carbon interfaces as indicated in Fig. 2. 96 Several authors have described laboratory test methods for studying the wear mechanism(s) and to reveal the influence of different experimental conditions on the wear rate [5, 13-16, 19-26]. Recent attempts have focused on predicting the behaviour and performance of commercial cathode materials in industrial cells. Ranking or comparing cathode materials requires defining a standardised test with consistent test parameters. Several types of laboratory set-ups to ‘accelerate’ the wear have been tested. The most promising one is ALUMINIUM · 1-2/2013 RESEARCH based on the ‘inverted’ cell design by Patel et al. and Sato at al. [23, 24] and is described here. A schematic drawing of the setup is shown in Fig. 4 a); more detailed descriptions have been published elsewhere [13-15]. The present laboratory study kept all parameters constant, and compared three different commercial cathode materials. The test proved that it can accelerate the observed wear rate compared with the conditions in industrial cells, and it provides reproducible results for each material. Nevertheless, the wear rate was in the same range for all three tested cathode materials, showing that the wear is not material dependent [15]. Hence, the same test set-up was used to identify what actually influences the wear rate [14, 16]. The surface morphology of the cathode samples was changed by introducing slots. By superimposing polished cross sections of spent and virgin samples as depicted in Fig. 4b), we could directly visualise the worn area. The results demonstrated the significant influence of current density and of hydrodynamic conditions. Increased speed of rotation increases the mass transfer when the speed exceeds the threshold where forced convection dominates over natural convection. They also showed that without polarisation there was no indication of wear [16]. Thus our test cell cannot rank carbon cathode materials under the presented standard conditions, because the wear does not depend on the type of material. Electric current is necessary to initiate the aluminium carbide formation. The test shows that a rotation speed of 50 rpm (equivalent to 8 cm/s, about the linear speed of typical industrial metal pad and bath movements) is too low to significantly increase the dissolution rate of aluminium carbide. Increasing the speed to 125 rpm (approx. 20 cm/ s in industry), however, significantly increased the wear rate. Published data on similar test cells stated that parameters like bath chemistry, granulometry, current density, and physical wear in general influence the wear rate [5, 14, 19, 25-26]. However, the question of why the industry observes different wear rates for different cathode qualities still remains. Usually, the wear resistance of the cathode blocks is ranked as follows: anthracitic > graphitic > high density graphitised > graphitised. It is to be noted that this ranking is made without consideration of the conditions the different materials are subjected to under operation. Anthracitic materials normally operate with a lower average current density and also with a much more uniform current distribution, as compared with graphitised cathode blocks. ALUMINIUM · 1-2/2013 a) b) Fig. 4. Schematic drawing of the experimental set-up with a vertical rotating cathode (a). The dimension of the graphite crucible (mm) is given in parentheses. 1 – Rotating cathode connecting rod, 2 – lid of sintered alumina, 3 – thermocouple, 4 – Si3N4 linings covering both ends, 5 a/b – cathode samples: two surface morphologies: a) for ranking tests; b) for parameter studies, 6 – electrolyte, 7 – aluminium metal (100 g), 8 – graphite crucible/anode, 9 – graphite support, 10 – anode lead. Subfigure (b) shows the sampling position and preparation of worn cathode cross sections for both cathode types [13-16]. Our research has shown that the cathode wear may not depend directly on the chemistry of carbide formation and cathode quality as such; rather, the wear rate is indirectly affected, since the modern materials experience higher current densities which enhance the carbide formation and thus increase the wear rate. In addition, higher rotation speeds (physical wear component) above a threshold speed promote mass transfer and dissolution of aluminium carbide. This further increases the wear rate by exposing more unreacted cathode surface area to form aluminium carbide. Therefore, industrial observations made in cells operated under different conditions might be misleading when compared to laboratory tests, which are performed under standard conditions [15]. Computational support It needs to be pointed out that the reason for the preferential wear along the periphery of the cell is not well understood, and it seems Fig. 5: Schematic representation of electrochemical formation and dissolution of aluminium carbide in a pore [17, 18]. 97 PAT E N T E obvious that more than one mechanism must be involved. Solheim presented and discussed three models concerning cathode wear [17]. Only one model, the so-called ‘carbon pump’hypothesis, provides a direct link between local current densities at the cathode surface and the wear rate [17, 18]. It is based on the assumption that a solid aluminium carbide layer covers the cathode surface during cell operation, at least in spots or intermittently. This carbide layer contains pores filled with electrolyte which originates either from sludge or from a bath film present between aluminium pad and cathode. A possible pathway for the current is then either through metal-filled areas/pores, or more likely, around the carbide spots, leaving a high local current density at the edges and a smaller density above and below the centre of the ‘islands’. This current-shielding effect generates a potential gradient along electrolyte-filled pores, which might lead to electrochemical crystallisation of Al4C3 at the bottom of the pore and dissolution of Al4C3 at the top of the pore. The scenario is sketched in Fig. 5 [18] and can explain rapid wear leading to a Wshaped cross-section of a used cathode. However, other mechanisms exist that may increase the wear rate; e.g. the metal flow velocity and / or abrasion caused by the movement of alumina particles. This has not yet been considered in the modelling context described here. More work is certainly needed to clarify these issues. As a helpful tool, the commercial FEM simulation software COMSOL Multiphysics version 4.3 was used in the present work in order to evaluate and support experimental findings [14, 16, 18]. Conclusions Laboratory tests indicate similar wear for all tested carbon cathode grades under standardised conditions, showing the independency on Patentblatt Oktober 2012 Fortsetzung aus ALUMINIUM 12/2012 Verfahren zum waagerechten Gießen und Schneiden von Metallknüppeln. Novelis, Inc., Toronto, Ontario, CA. (B22D 11/126, EP 2 286 940, AT: 09.12.2004, EP-AT: 09.12.2004) Gussaluminiumlegierung und Zylinderkopf eines Verbrennungsmotors. Nippon Light Metal Co. Ltd., Tokio, JP; Nissan Motor Co., Ltd., Yokohama-shi, Kanagawa-ken, JP. (C22C 21/04, PS 60 2008 009 916, EP 2014780, AT: 04.07.2008, EP-AT: 04.07.2008) 98 the material type, but a strong effect of local current density and metal flow velocity was identified. Acknowledgement The present work was carried out in the competence-building project ‘Durable Materials in Primary Aluminium Production’ (KMB, DuraMat), financed by the Research Council of Norway, Hydro Primary Metal Technology, Sør-Norge Aluminium, and Elkem Carbon. The authors gratefully acknowledge permission to publish the results. References [1] A. Tabereaux, JOM 52 (2000)2, pp. 23-29. [2] H.A. Øye and B.J Welch, JOM 50(1998)2, pp. 18-23. [3] E. Skybakmoen, S. Rørvik, A. Solheim, K. R. Holm, P. Tiefenbach, and Ø. Østrem, Light Metals 2011, pp. 1061-1066. [4] D. Lombard, T. Béhérégaray, B. Fève, and J. M. Jolas, Light Metals 1998, pp. 653-658. [5] M. Sørlie and H.A. Øye, Cathodes in Aluminum Electrolysis, Düsseldorf, Germany: Aluminum Verlag, 2nd ed., 1994. [6] M.A. Coulombe, M. Lebeuf, P. Chartrand, B. Allard and G. Soucy, Light Metals 2010, pp. 811-816. [7] R.C. Dorward, Met. Trans 4(1973), pp. 386388. [8] P. Reny and S. Wilkening, Light Metals 2000, pp. 399-404. [9] J. Rødseth, B. Rasch, Ole Lund, and J. Thonstad, Light Metals 2002, pp. 883-887. [10] R. Ødegård, Å. Sterten, and J. Thonstad, Light Metals 1987, pp. 295-302. [11] B. Novak, K. Tschöpe, A.P. Ratvik and T. Grande, Light Metals 2012, pp. 1343-1348. [12] B. Novak, K. Tschöpe, A.P. Ratvik and T. Grande, to be published in Light Metals 2013. [13] K. Tschöpe, A. Støre, S. Rørvik, A. Solheim, T. Grande, and A. P. Ratvik, Light Metals (COM) 2011, pp. 143-153 [14] K. Tschöpe, A. Støre, S. Rørvik, A. Solheim, E. Skybakmoen, T. Grande, and A. P. Ratvik, Light Metals 2012, pp. 1349-1354. Verfahren zur Herstellung eines Titanschweißdrahtes. Norsk Titanium Components AS, 0255 Oslo, NO. (C22C 14/00, EPA 2491155, WO 2011/049465, EP-AT: 21.10.2010, WO-AT: 21.10.2010) Aluminiummaterial für eine Elektrode eines elektrolytischen Kondensators, Verfahren zur Herstellung von Elektrodenmaterial für einen elektrolyt. Kondensator, Anodenmaterial für einen elektrolyt. Aluminiumkondensator und elektrolyt. Aluminiumkondensator. Showa Denko K.K., Tokio, JP. (C22C 21/00, EP 1 841 892, WO 2006/068300, AT: 21.12.2005, EP-AT: 21.12.2005, WO-AT: 21.12.2005) [15] K. Tschöpe, A. Støre, E. Skybakmoen, A. Solheim, T. Grande, and A. P. Ratvik, to be published in Light Metals 2013. [16] K. Tschöpe, A. Støre, A. Solheim, E. Skybakmoen, T. Grande and A.P. Ratvik, to be published in JOM. [17] A. Solheim, Loght Metals (COM ) 2011, pp. 135-142. [18] A. Solheim and K. Tschöpe, to be published in Light Metals 2013 [19] E. Skybakmoen, A. P. Ratvik, A. Solheim, S. Rolseth, and H. Gudbrandsen, Light Metals 2007, pp. 815-820. [20] P. Rafiei, F. Hiltmann, M. Hyland, B. James, and B. Welch, Light Metals 2001, pp. 747-752. [21] P. Patel, M. Hyland, and F. Hiltmann, Light Metals 2005, pp. 757-762. [22] P. Patel, M. Hyland, and F. Hiltmann, Light Metals 2006, pp. 633-638. [23] Y. Sato, P. Patel, and P. Lavoie, Light Metals 2010, pp. 817-822. [24] P. Patel. Y. Sato, and P. Lavoie, Light Metals 2011, pp. 1073-1078. [25] K. Vasshaug, T. Foosnæs, G. M. Haarberg, A. P. Ratvik, and E. Skybakmoen, Light Metals 2007, pp. 821-826. [26] K. Vasshaug, T. Foosnæs, G. M. Haarberg, A. P. Ratvik, and E. Skybakmoen, Light Metals 2009, pp. 1111-1115. Authors Dr. Kati Tschöpe is research scientist at the electrolysis research team at SINTEF Materials and Chemistry since 2012. She has been working on cathode wear and degradation of bottom linings during her PhD and Postdoc position at the Norwegian University of Science and Technology (NTNU). Egil Skybakmoen is research manager at the electrolysis research team since 2004. He has 28 years of experience within aluminium electrolysis and his main fields of research have been fluoride bath chemistry and lining materials. Asbjørn Solheim, chief scientist, has conducted research within aluminium electrolysis at SINTEF for more than 30 years, particularly within bath chemistry and modelling. Dr. Tor Grande has been a professor at NTNU since 1997 and has a broad experience in materials science and engineering with focus on both oxide and none-oxide materials. Aluminiumbandmaterial für lithographische Druckplatten. Fujifilm Corp., Tokio, JP; Sumitomo Light Metal Industries, Ltd., Tokio, JP. (C22B 9/02, EP 2 284 288, AT: 24.07.2010, EP-AT: 24.07.2010) Magnesiumlegierungsplatte und Verfahren zur Herstellung derselben. Sumitomo Electric Industries, Ltd., Osaka, JP. (B21B 3/00, PS 603 08 023, EP 1510265, WO 2003/103868, AT: 03.06. 2003, EP-AT: 03.06.2003, WO-AT: 03.06.2003) Verfahren zum Druckgießen von gegliederten Metallgussstücken. Trimet Aluminium AG, 45356 Essen, DE. (B22D 17/22, EP 2 008 740, AT: 21.06.2008, EP-AT: 21.06.2008) ALUMINIUM · 1-2/2013 PAT E N T E Patentblatt November 2012 Feuerverzinkte Gussaluminiumlegierung mit Al-Zn-Si-Mg-Re-Ti-Ni sowie Herstellungsverfahren dafür. Jiangsu Linlong New Materials Co., Ltd., Jiangsu 214183, CN. 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Flora Rd. Spokane, WA 99216 USA +1 509 922 1404 phone +1 509 924 0241 fax E-Mail: info@wagstaff.com Internet: www.wagstaff.com 1.8 Electrolysis cell (pot) Elektrolyseofen HERTWICH ENGINEERING GmbH see Casthouse (foundry) 1.5 Bulk materials Handling from Ship to Cell Anodenwechselmaschine Anode transport equipment Anoden Transporteinrichtungen GLAMA Maschinenbau GmbH see Anode rodding 1.4 Crustbreakers / Krustenbrecher Could not find your „keywords“? Please ask for our complete „Supply sources for the aluminium industry“. E-Mail: anzeigen@giesel.de Dry absorption units for electrolysis exhaust gases www.coperion.com mailto: info.cc-mh@coperion.com Tel. 0821 / 31 98 80-34 Dennis Ross Calcium silicate boards Gautschi Engineering GmbH see Casting equipment 3.1 Anode changing machine Bulk materials Handling from Ship to Cell Hier könnte Ihr Bezugsquellen-Eintrag stehen. Rufen Sie an: Sawing / Sägen T.T. Tomorrow Technology S.p.A. Via dell’Artigianato 18 Due Carrare, Padova 35020, Italy Telefon +39 049 912 8800 Telefax +39 049 912 8888 E-Mail: gmagarotto@tomorrowtechnology.it Contact: Giovanni Magarotto GLAMA Maschinenbau GmbH see Anode rodding 1.4 HERTWICH ENGINEERING GmbH see Casthouse (foundry) 1.5 Elektrolysehalle GLAMA Maschinenbau GmbH see Anode rodding 1.4 Horizontales Stranggießen Gautschi Engineering GmbH see Casting equipment 3.1 1.9 Potroom Trockenabsorptionsanlage für Elektrolyseofenabgase Solios Environnement www.fivesgroup.com Calciumsilikatplatten Promat GmbH High Performance Insulation Scheifenkamp 16, D-40878 Ratingen Tel. +49 (0) 2102 / 493-0, Fax -493 115 verkauf3@promat.de, www.promat.de Pot ramming Machine Exhaust gas treatment www.brochot.fr Abgasbehandlung Solios Environnement www.fivesgroup.com HERTWICH ENGINEERING GmbH see Casthouse (foundry) 1.5 sermas@sermas.com 102 www.alu-web.de Pot feeding systems Beschickungseinrichtungen für Elektrolysezellen FLSmidth MÖLLER GmbH www.flsmidthmoeller.com see Storage facilities for smelting 1.2 Tapping vehicles/Schöpffahrzeuge GLAMA Maschinenbau GmbH see Anode rodding 1.4 $/80,1,80³ SUPPLIERS DIRECTORY 1.12 Cathode repair shop KathodenreparaturWerkstatt 1.15 Storage and transport Lager und Transport Billet heating furnaces Öfen zur Bolzenerwärmung Cathode Sealing Bench Eingießen von Kathodenbarren INDUKTIONS-ANLAGEN + SERVICE GmbH & Co. KG www.brochot.fr Sermas Industrie sermas@sermas.com see Smelting technology 1.6 SMS Siemag AG see Rolling mill technology 3.0 Am großen Teich 16+27 D-58640 Iserlohn Tel. +49 (0) 2371 / 4346-0 Fax +49 (0) 2371 / 4346-43 E-Mail: verkauf@ias-gmbh.de Internet: www.ias-gmbh.de 1.14 Aluminium Alloys Aluminiumlegierungen RHEINFELDEN ALLOYS GmbH & Co. KG A member of ALUMINIUM RHEINFELDEN Group Postfach 1703, 79607 Rheinfelden Tel.: +49 7623 93-490 Fax: +49 7623 93-546 E-Mail: alloys@rheinfelden-alloys.eu Internet: www.rheinfelden-alloys.eu 2 Hier könnte Ihr Bezugsquellen-Eintrag stehen. Rufen Sie an: Tel. 0821 / 31 98 80-34 Dennis Ross Extrusion Could not find your „keywords“? Please ask for our complete „Supply sources for the aluminium industry“. E-Mail: anzeigen@giesel.de 2.2 Extrusion equipment Strangpressen 2.1 Extrusion billet preparation Pressbolzenbereitstellung 2.1.1 Extrusion billet production Pressbolzenherstellung 2.2 Extrusion equipment Strangpresseinrichtungen 2.3 Section handling Profilhandling see Casthouse (foundry) 1.5 Strangpresseinrichtungen 2.4 Heat treatment Wärmebehandlung 2.5 Measurement and control equipment Mess- und Regeleinrichtungen 2.6 Die preparation and care Werkzeugbereitstellung und -pflege 2.7 Second-hand extrusion plant Gebrauchte Strangpressanlagen 2.8 Consultancy, expert opinion Beratung, Gutachten 2.9 Surface finishing of sections Oberflächenveredlung von Profilen 2.10 Machining of sections Profilbearbeitung 2.11 Equipment and accessories Ausrüstungen und Hilfsmittel 2.12 Services Dienstleistungen www.mechatherm.com see Smelting technology 1.5 Oilgear Towler GmbH Im Gotthelf 8 D 65795 Hattersheim Tel. +49 (0) 6145 3770 Fax +49 (0) 6145 30770 E-Mail: info@oilgear.de Internet: www.oilgear.de www.alu-web.de Press control systems Pressensteuersysteme Oilgear Towler GmbH see Extrusion Equipment 2.2 Heating and control equipment for intelligent billet containers 2.1 Extrusion billet preparation Pressbolzenbereitstellung mfw-maschinenbau.com s,OG"OLZENLAGER(ANDLING s"OLZENSËGE"OLZENFàGEN Heizungs- und Kontrollausrüstung für intelligente Blockaufnehmer extrutec GmbH Fritz-Reichle Ring 2 D-78315 Radolfzell Tel. +49 7732 939 1390 Fax +49 7732 939 1399 E-Mail: info@extrutec-gmbh.de Internet: www.extrutec-gmbh.de $/80,1,80³ Hier könnte Ihr Bezugsquellen-Eintrag stehen. Rufen Sie an: Tel. 0821 / 31 98 80-34 Dennis Ross MARX GmbH & Co. KG www.marx-gmbh.de see Melt operations 4.13 103 LIEFERVERZEICHNIS 2.3 Section handling 2.4 Heat treatment Profilhandling CTI Systems S.A. Z.I. Eselborn-Lentzweiler 12, op der Sang | L- 9779 Lentzweiler Tel. +352 2685 2000 | Fax +352 2685 3000 cti@ctisystems.com | www.ctisystems.com H+H HERRMANN + HIEBER GMBH Rechbergstraße 46 D-73770 Denkendorf/Stuttgart Tel. +49 711 93467-0, Fax +49 711 34609-11 E-Mail: info@herrmannhieber.de Internet: www.herrmannhieber.de Wärmebehandlung KASTO Maschinenbau GmbH & Co. KG Industriestr. 14, D-77855 Achern Tel.: +49 (0) 7841 61-0 / Fax: +49 (0) 7841 61 300 kasto@kasto.de / www.kasto.de Hersteller von Band- und Kreissägemaschinen sowie Langgut- und Blechlagersystemen see Section handling 2.3 BSN Thermprozesstechnik GmbH Kammerbruchstraße 64 D-52152 Simmerath Tel. 02473-9277-0 · Fax: 02473-9277-111 info@bsn-therm.de · www.bsn-therm.de Ofenanlagen zum Wärmebehandeln von Aluminiumlegierungen, Buntmetallen und Stählen Section transport equipment Profiltransporteinrichtungen INSERTEC-INGENIERÍA Y SERVICIOS TÉCNICOS, S.A Vollert Anlagenbau GmbH Stadtseestraße 12, D-74189 Weinsberg Tel. +49 7134 52 220 l Fax +49 7134 52 222 E-Mail intralogistik@vollert.de Internet www.vollert.de Nijverheidsweg 3 NL-7071 CH Ulft Netherlands Tel.: +31 315 641352 Fax: +31 315 641852 E-Mail: info@unifour.nl Internet: www.unifour.nl Sales Contact: Paul Overmans Packaging equipment Stackers / Destackers Verpackungseinrichtungen Avenida Cervantes Nº6 48970 – Basauri – Bizkaia – Spain Tel: +34 944 409 420 E-mail: Insertec@insertec.biz Internet: www.insertec.biz see Equipment and accessories 3.1 Stapler / Entstapler www.mechatherm.com see Smelting technology 1.5 mfw-maschinenbau.com s!UTOMATIK6ERPACKUNG s0ACKTISCHE0ROFILPAKETHEBER s3PACERHANDLINGUND+ONZEPTE mfw-maschinenbau.com sUNDM$EU3TACKER s+OMBIANLAGEN Transport equipment for extruded sections Transporteinrichtungen für Profilabschnitte SECO/WARWICK EUROPE S.A. ul. Šwierczewskiego 76 66-200 Šwiebodzin, POLAND Tel: +48 68 38 19 800 E-mail: europe@secowarwick.com.pl Internet: www.secowarwick.com Heat treatment furnaces see Section handling 2.3 Wärmebehandlungsöfen HOFMANN Wärmetechnik GmbH Section saws Profilsägen Gewerbezeile 7 www.ctisystems.com see Section handling 2.3 Profil-Lagereinrichtungen www.ctisystems.com see Section handling 2.3 104 Tel. +43(0)7215/3601 E-Mail: office@hofmann-waermetechnik.at Internet: www.hofmann-waermetechnik.at INOTHERM INDUSTRIEOFENUND WÄRMETECHNIK GMBH see Casthouse (foundry) 1.5 mfw-maschinenbau.com s+URZLËNGENSËGEAUTOMATISIERT Section store equipment A - 4202 Helmonsödt mfw-maschinenbau.com s3KIP(ANDLING3PACER s+ETTENFÚRDERER Homogenising furnaces Homogenisieröfen HERTWICH ENGINEERING GmbH see Section handling 2.3 see Casthouse (foundry) 1.5 $/80,1,80³ SUPPLIERS DIRECTORY 2.10 Machining of sections Profilbearbeitung Ageing furnace for extrusions Auslagerungsöfen für Strangpressprofile Billet saw Bolzensägen Sermas Industrie sermas@sermas.com see Smelting technology 1.6 see Casthouse (foundry) 1.5 2.11 Equipment and accessories Ausrüstungen und Hilfsmittel Hier könnte Ihr Bezugsquellen-Eintrag see Extrusion billet preparation 2.1 Inductiv heating equipment Induktiv beheizte Erwärmungseinrichtungen see Casthouse (foundry) 1.5 Could not find your „keywords“? Please ask for our complete „Supply sources for the aluminium industry“. E-Mail: anzeigen@giesel.de stehen. Rufen Sie an: Tel. 0821 / 31 98 80-34 Dennis Ross 2.6 Die preparation and care Werkzeugbereitstellung und -pflege Die heating furnaces INDUKTIONS-ANLAGEN + SERVICE GmbH & Co. KG Am großen Teich 16+27 D-58640 Iserlohn Tel. +49 (0) 2371 / 4346-0 Fax +49 (0) 2371 / 4346-43 E-Mail: verkauf@ias-gmbh.de Internet: www.ias-gmbh.de 3 Rolling mill technology Walzwerktechnik Werkzeuganwärmöfen see Extrusion billet preparation 2.1 schwartz GmbH see Heat treatment 2.4 Nijverheidsweg 3 NL-7071 CH Ulft Netherlands Tel.: +31 315 641352 Fax: +31 315 641852 E-Mail: info@unifour.nl Internet: www.unifour.nl Sales Contact: Paul Overmans 2.9 Surface finishing of sections Oberflächenveredlung von Profilen Nijverheidsweg 3 NL-7071 CH Ulft Netherlands Tel.: +31 315 641352 Fax: +31 315 641852 E-Mail: info@unifour.nl Internet: www.unifour.nl Sales Contact: Paul Overmans 3.1 Casting equipment Gießanlagen 3.2 Rolling bar machining Walzbarrenbearbeitung 3.3 Rolling bar furnaces Walzbarrenvorbereitung 3.4 Hot rolling equipment Warmwalzanlagen 3.5 Strip casting units and accessories Bandgießanlagen und Zubehör 3.6 Cold rolling equipment Kaltwalzanlagen 3.7 Thin strip / foil rolling plant Feinband-/Folienwalzwerke 3.8 Auxiliary equipment Nebeneinrichtungen 3.9 Adjustment devices Adjustageeinrichtungen 3.10 Process technology / Automation technology Prozesstechnik / Automatisierungstechnik 3.11 Coolant / lubricant preparation Kühl-/Schmiermittel-Aufbereitung 3.12 Air extraction systems Abluftsysteme 3.13 Fire extinguishing units Feuerlöschanlagen 3.14 Storage and dispatch Lagerung und Versand 3.15 Second-hand rolling equipment Gebrauchtanlagen 3.16 Coil storage systems Coil storage systems 3.17 Strip Processing Lines Bandprozesslinien 3.18 Productions Management Sytems Produktions Management Systeme 3.0 Rolling mill technology Walzwerktechnik mfw-maschinenbau.com s3TRAHLANLAGEN $/80,1,80³ www.alu-web.de see Cold rolling units / complete plants 3.6 105 LIEFERVERZEICHNIS Melting and holding furnaces Schmelz- und Warmhalteöfen SMS Siemag Aktiengesellschaft Eduard-Schloemann-Straße 4 40237 Düsseldorf, Germany Telefon: +49 (0) 211 881-0 Telefax: +49 (0) 211 881-4902 E-Mail: communications@sms-siemag.com Internet: www.sms-siemag.com Geschäftsbereiche: Warmflach- und Kaltwalzwerke Wiesenstraße 30 57271 Hilchenbach-Dahlbruch, Germany Telefon: +49 (0) 2733 29-0 Telefax: +49 (0) 2733 29-2852 Bandanlagen Walder Straße 51-53 40724 Hilden, Germany Telefon: +49 (0) 211 881-5100 Telefax: +49 (0) 211 881-5200 Elektrik + Automation Ivo-Beucker-Straße 43 40237 Düsseldorf, Germany Telefon: +49 (0) 211 881-5895 Telefax: +49 (0) 211 881-775895 Graf-Recke-Straße 82 40239 Düsseldorf, Germany Telefon: +49 (0) 211 881-0 Telefax: +49 (0) 211 881-4902 3.1 Casting equipment Gautschi Engineering GmbH Konstanzer Straße 37 CH 8274 Tägerwilen Telefon +41 71 666 66 66 Telefax +41 71 666 66 77 E-Mail: info@gautschi.cc Internet: www.gautschi.cc Kontakt: Sales Departement LOI Thermprocess GmbH Am Lichtbogen 29 D-45141 Essen Germany Telefon +49 (0) 201 / 18 91-1 Telefax +49 (0) 201 / 18 91-321 E-Mail: info@loi-italimpianti.de Internet: www.loi-italimpianti.com Solios Thermal UK www.fivesgroup.com www.mechatherm.com see Smelting technology 1.5 Electromagnetic Stirrer Elektromagnetische Rührer Solios Thermal UK www.fivesgroup.com www.alu-web.de Metal filters / Metallfilter Gautschi Engineering GmbH see Casting equipment 3.1 www.alu-web.de Füllstandsanzeiger und -regler Gautschi Engineering GmbH see Casting equipment 3.1 Plate saw 106 schwartz GmbH see Heat treatment 2.4 Solios Thermal UK www.fivesgroup.com Bar heating furnaces Barrenanwärmanlagen EBNER Industrieofenbau Ges.m.b.H. see Annealing furnaces 3.3 Gautschi Engineering GmbH see Casting equipment 3.1 Homogenising furnaces Homogenisieröfen Gautschi Engineering GmbH see Casting equipment 3.1 HERTWICH ENGINEERING GmbH see Casthouse (foundry) 1.5 Plattensägen Sermas Industrie sermas@sermas.com see Smelting technology 1.6 schwartz GmbH see Heat treatment 2.4 Solios Thermal UK www.fivesgroup.com Barrensägen Sermas Industrie sermas@sermas.com see Smelting technology 1.6 Walzbarrenvorbereitung see Casting machines 1.6 see Equipment and accessories 3.1 Walzenbarrenbearbeitung 3.3 Rolling bar furnaces Wagstaff, Inc. Gautschi Engineering GmbH see Casting equipment 3.1 3.2 Rolling bar machining Slab saw Filling level indicators and controls EBNER Industrieofenbau Ges.m.b.H. Ebner-Platz 1, 4060 Leonding/Austria Tel. +43 / 732 / 6868-0 E-Mail: sales@ebner.cc Internet: www.ebner.cc Schmelzereinigungsanlagen Gautschi Engineering GmbH see Casting equipment 3.1 Avenida Cervantes Nº6 48970 – Basauri – Bizkaia – Spain Tel: +34 944 409 420 E-mail: Insertec@insertec.biz Internet: www.insertec.biz Glühöfen Melt purification units Gießanlagen INSERTEC-INGENIERÍA Y SERVICIOS TÉCNICOS, S.A Annealing furnaces BSN Thermprozesstechnik GmbH see Heat Treatment 2.4 www.alu-web.de Roller tracks Rollengänge Gautschi Engineering GmbH see Casting equipment 3.1 $/80,1,80³ SUPPLIERS DIRECTORY 3.4 Hot rolling equipment Warmwalzanlagen Hot rolling units / complete plants Warmwalzanlagen/Komplettanlagen see Section handling 2.3 Achenbach Buschhütten GmbH & Co. KG Siegener Str. 152, D-57223 Kreuztal Tel. +49 (0) 2732/7990, info@achenbach.de Internet: www.achenbach.de see Cold rolling units / complete plants 3.6 Coil transport systems Bundtransportsysteme MINO S.p.A. Via Torino, 1 – San Michele 15122 ALESSANDRIA – ITALY Telefon: +39 0131 363636 Telefax: +39 0 131 3 61611 E-Mail: sales@mino.it Internet: www.mino.it Sales contact: Mr. Luciano Ceccopieri see Rolling mill technology 3.0 Kaltwalzanlagen www.ctisystems.com see Section handling 2.3 Hier könnte Ihr Bezugsquellen-Eintrag stehen. Rufen Sie an: Tel. 0821 / 31 98 80-34 Dennis Ross Achenbach Buschhütten GmbH & Co. KG Siegener Str. 152, D-57223 Kreuztal Tel. +49 (0) 2732/7990, info@achenbach.de Internet: www.achenbach.de BSN Thermprozesstechnik GmbH see Heat Treatment 2.4 Coil annealing furnaces Bundglühöfen Gautschi Engineering GmbH see Casting equipment 3.1 see Rolling mill technology 3.0 see Equipment and accessories 3.1 Rolling mill modernisation see Rolling mill technology 3.0 www.alu-web.de Drive systems / Antriebe SMS Siemag AG see Rolling mill technology 3.0 Gautschi Engineering GmbH see Casting equipment 3.1 Process optimisation systems Prozessoptimierungssysteme Walzwerksmodernisierung www.alu-web.de SMS Siemag AG SMS Siemag AG schwartz GmbH see Heat treatment 2.4 MINO S.p.A. Via Torino, 1 – San Michele 15122 ALESSANDRIA – ITALY Telefon: +39 0131 363636 Telefax: +39 0 131 3 61611 E-Mail: sales@mino.it Internet: www.mino.it Sales contact: Mr. Luciano Ceccopieri MINO S.p.A. Via Torino, 1 – San Michele 15122 ALESSANDRIA – ITALY Telefon: +39 0131 363636 Telefax: +39 0 131 3 61611 E-Mail: sales@mino.it Internet: www.mino.it Sales contact: Mr. Luciano Ceccopieri Heating furnaces / Anwärmöfen Drive systems / Antriebe SMS Siemag AG Kaltwalzanlagen/Komplettanlagen SMS Siemag AG 3.6 Cold rolling equipment see Section handling 2.3 Cold rolling units / complete plants Coil transport systems Bundtransportsysteme Gautschi Engineering GmbH see Casting equipment 3.1 Process simulation Prozesssimulation Gautschi Engineering GmbH see Casting equipment 3.1 www.ctisystems.com see Section handling 2.3 SMS Siemag AG see Rolling mill technology 3.0 see Rolling mill technology 3.0 Spools / Haspel SMS Siemag AG see Rolling mill technology 3.0 $/80,1,80³ H+H HERRMANN + HIEBER GMBH Rechbergstraße 46 D-73770 Denkendorf/Stuttgart Tel. +49 711 93467-0, Fax +49 711 34609-11 E-Mail: info@herrmannhieber.de Internet: www.herrmannhieber.de Roll exchange equipment Walzenwechseleinrichtungen SMS Siemag AG see Rolling mill technology 3.0 107 LIEFERVERZEICHNIS Rolling mill modernization Walzwerkmodernisierung 3.7 Thin strip / foil rolling plant Rolling mill modernization Walzwerkmodernisierung Feinband-/Folienwalzwerke Achenbach Buschhütten GmbH & Co. KG Siegener Str. 152, D-57223 Kreuztal Tel. +49 (0) 2732/7990, info@achenbach.de Internet: www.achenbach.de Achenbach Buschhütten GmbH & Co. KG Siegener Str. 152, D-57223 Kreuztal Tel. +49 (0) 2732/7990, info@achenbach.de Internet: www.achenbach.de see Cold rolling units / complete plants 3.6 see Cold rolling units / complete plants 3.6 MINO S.p.A. Via Torino, 1 – San Michele 15122 ALESSANDRIA – ITALY Telefon: +39 0131 363636 Telefax: +39 0 131 3 61611 E-Mail: sales@mino.it Internet: www.mino.it Sales contact: Mr. Luciano Ceccopieri Coil annealing furnaces see Cold rolling units / complete plants 3.6 MINO S.p.A. Via Torino, 1 – San Michele 15122 ALESSANDRIA – ITALY Telefon: +39 0131 363636 Telefax: +39 0 131 3 61611 E-Mail: sales@mino.it Internet: www.mino.it Sales contact: Mr. Luciano Ceccopieri Bundglühöfen Gautschi Engineering GmbH see Casting equipment 3.1 3.10 Process technology / Automation technology Prozesstechnik / Automatisierungstechnik Slitting lines-CTL Längs- und Querteilanlagen Achenbach Buschhütten GmbH & Co. KG Siegener Str. 152, D-57223 Kreuztal Tel. +49 (0) 2732/7990, info@achenbach.de Internet: www.achenbach.de Process control technology see Equipment and accessories 3.1 schwartz GmbH see Cold colling equipment 3.6 Prozessleittechnik SMS Siemag AG see Rolling mill technology 3.0 Strip shears/Bandscheren see Cold rolling units / complete plants 3.6 www.alu-web.de Wagstaff, Inc. see Casting machines 1.6 SMS Siemag AG see Rolling mill technology 3.0 Heating furnaces Trimming equipment Besäumeinrichtungen see Cold rolling units / complete plants 3.6 SMS Siemag AG see Rolling mill technology 3.0 www.alu-web.de Anwärmöfen Gautschi Engineering GmbH see Casting equipment 3.1 INOTHERM INDUSTRIEOFENUND WÄRMETECHNIK GMBH see Casthouse (foundry) 1.5 Strip flatness measurement and control equipment Bandplanheitsmess- und -regeleinrichtungen schwartz GmbH see Heat treatment 2.4 Hier könnte Ihr BezugsquellenEintrag stehen. Rufen Sie an: Tel. 0821 / 31 98 80-34 Dennis Ross Thin strip / foil rolling mills / complete plant Feinband- / Folienwalzwerke / Komplettanlagen MINO S.p.A. Via Torino, 1 – San Michele 15122 ALESSANDRIA – ITALY Telefon: +39 0131 363636 Telefax: +39 0 131 3 61611 E-Mail: sales@mino.it Internet: www.mino.it Sales contact: Mr. Luciano Ceccopieri Achenbach Buschhütten GmbH & Co. KG Siegener Str. 152, D-57223 Kreuztal Tel. +49 (0) 2732/7990, info@achenbach.de Internet: www.achenbach.de SMS Siemag AG SMS Siemag AG see Rolling mill technology 3.0 108 ABB Automation Force Measurement S-72159 Västeras, Sweden Phone: +46 21 325 000 Fax: +46 21 340 005 E-Mail: pressductor@se.abb.com Internet: www.abb.com/pressductor see Rolling mill technology 3.0 $/80,1,80³ SUPPLIERS DIRECTORY Strip thickness measurement and control equipment Banddickenmess- und -regeleinrichtungen ABB Automation Force Measurement S-72159 Västeras, Sweden Phone: +46 21 325 000 Fax: +46 21 340 005 E-Mail: pressductor@se.abb.com Internet: www.abb.com/pressductor Strip Width & Position Measurement equipment Bandbreiten- und Bandlaufmesseinrichtungen ABB Automation Force Measurement S-72159 Västeras, Sweden Phone: +46 21 325 000 Fax: +46 21 340 005 E-Mail: pressductor@se.abb.com Internet: www.abb.com/pressductor Exhaust air purification systems (active) Abluft-Reinigungssysteme (aktiv) Achenbach Buschhütten GmbH & Co. KG Siegener Str. 152, D-57223 Kreuztal Tel. +49 (0) 2732/7990, info@achenbach.de Internet: www.achenbach.de SMS Siemag AG see Rolling mill technology 3.0 3.14 Storage and dispatch 3.11 Coolant / lubricant preparation Achenbach Buschhütten GmbH & Co. KG Siegener Str. 152, D-57223 Kreuztal Tel. +49 (0) 2732/7990, info@achenbach.de Internet: www.achenbach.de Kühl-/SchmiermittelAufbereitung see Cold rolling units / complete plants 3.6 SMS Siemag AG see Rolling mill technology 3.0 Lagerung und Versand SMS Siemag AG see Rolling mill technology 3.0 3.16 Coil storage systems Bundlagersysteme Rolling oil recovery and treatment units Walzöl-Wiederaufbereitungsanlagen Could not find your „keywords“? Please ask for our complete „Supply sources for the aluminium industry“. E-Mail: anzeigen@giesel.de Strip Tension Measurement equipment Bandzugmesseinrichtungen SMS Siemag AG see Rolling mill technology 3.0 Filter for rolling oils and emulsions Filter für Walzöle und Emulsionen Achenbach Buschhütten GmbH & Co. KG Siegener Str. 152, D-57223 Kreuztal Tel. +49 (0) 2732/7990, info@achenbach.de Internet: www.achenbach.de www.ctisystems.com see Section handling 2.3 H+H HERRMANN + HIEBER GMBH Rechbergstraße 46 D-73770 Denkendorf/Stuttgart Tel. +49 711 93467-0, Fax +49 711 34609-11 E-Mail: info@herrmannhieber.de Internet: www.herrmannhieber.de SMS Siemag AG see Rolling mill technology 3.0 www.alu-web.de ABB Automation Force Measurement S-72159 Västeras, Sweden Phone: +46 21 325 000 Fax: +46 21 340 005 E-Mail: pressductor@se.abb.com Internet: www.abb.com/pressductor Roll Force Measurement equipment Walzkraftmesseinrichtungen see Section handling 2.3 Rolling oil rectification units Walzölrektifikationsanlagen Bandprozesslinien Achenbach Buschhütten GmbH & Co. KG Siegener Str. 152, D-57223 Kreuztal Tel. +49 (0) 2732/7990, info@achenbach.de Internet: www.achenbach.de SMS Siemag AG see Rolling mill technology 3.0 ABB Automation Force Measurement S-72159 Västeras, Sweden Phone: +46 21 325 000 Fax: +46 21 340 005 E-Mail: pressductor@se.abb.com Internet: www.abb.com/pressductor $/80,1,80³ 3.17 Strip Processing Lines 3.12 Air extraction systems Abluft-Systeme REDEX Zone Industrielle F-45210 Ferrieres Telefon +33 (2) 38 94 42 00 E-mail: info@redex-group.com Internet: www.tension-leveling.com Anodizing Lines Anodisier-Linien SMS Siemag AG see Cold rolling units / complete plants 3.6 see Rolling mill technology 3.0 109 LIEFERVERZEICHNIS Colour Coating Lines Bandlackierlinien 4 Foundry Gießerei www.bwg-online.com see Strip Processing Lines 3.17 SMS Siemag AG see Rolling mill technology 3.0 Lithographic Sheet Lines Lithografielinien www.bwg-online.com see Strip Processing Lines 3.17 see Cold rolling units / complete plants 3.6 Stretch Levelling Lines Streckrichtanlagen www.bwg-online.com see Strip Processing Lines 3.17 Strip Annealing Lines Bandglühlinien www.bwg-online.com see Strip Processing Lines 3.17 SMS Siemag AG 4.1 Work protection and ergonomics Arbeitsschutz und Ergonomie 4.2 Heat-resistant technology Feuerfesttechnik 4.3 Conveyor and storage technology Förder- und Lagertechnik 4.4 Mould and core production Form- und Kernherstellung 4.5 Mould accessories and accessory materials Formzubehör, Hilfsmittel 4.6 Foundry equipment Gießereianlagen 4.7 Casting machines and equipment Gießmaschinen und Gießeinrichtungen 4.8 Handling technology Handhabungstechnik 4.9 Construction and design Konstruktion und Design 4.10 Measurement technology and materials testing Messtechnik und Materialprüfung 4.11 Metallic charge materials Metallische Einsatzstoffe 4.12 Finishing of raw castings Rohgussnachbehandlung 4.13 Melt operations Schmelzbetrieb 4.14 Melt preparation Schmelzvorbereitung 4.15 Melt treatment devices Schmelzebehandlungseinrichtungen 4.16 Control and regulation technology Steuerungs- und Regelungstechnik 4.17 Environment protection and disposal Umweltschutz und Entsorgung 4.18 Dross recovery Schlackenrückgewinnung 4.19 Cast parts Gussteile see Rolling mill technology 3.0 Strip Processing Lines Bandprozesslinien 4.2 Heat-resistent technology Feuerfesttechnik Refractories / Feuerfeststoffe BWG Bergwerk- und WalzwerkMaschinenbau GmbH Mercatorstraße 74 – 78 D-47051 Duisburg Tel.: +49 (0) 203-9929-0 Fax: +49 (0) 203-9929-400 E-Mail: bwg@bwg-online.de Internet: www.bwg-online.com Calderys Deutschland GmbH In der Sohl 122 56564 Neuwied E-mail: germany@calderys.com Internet: www.calderys.de Refratechnik Steel GmbH Schiessstrasse 58 40549 Düsseldorf / Germany Phone +49 211 5858 0 Fax +49 211 5858 46 Internet: www.refra.com 4.3 Conveyor and storage technology Förder- und Lagertechnik INSERTEC-INGENIERÍA Y SERVICIOS TÉCNICOS, S.A 3.18 Production Management systems Produktions Management Systeme Avenida Cervantes Nº6 48970 – Basauri – Bizkaia – Spain Tel: +34 944 409 420 E-mail: Insertec@insertec.biz Internet: www.insertec.biz Promat GmbH High Performance Insulation Scheifenkamp 16, D-40878 Ratingen Tel. +49 (0) 2102 / 493-0, Fax -493 115 verkauf3@promat.de, www.promat.de PSI Metals Non Ferrous GmbH Software Excellence in Metals Carlo-Schmid-Str. 12, D-52146 Würselen Tel.: +49 (0) 2405 4135-0 info@psimetals.de, www.psimetals.com 110 www.alu-web.de www.ctisystems.com see Section handling 2.3 H+H HERRMANN + HIEBER GMBH Rechbergstraße 46 D-73770 Denkendorf/Stuttgart Tel. +49 711 93467-0, Fax +49 711 34609-11 E-Mail: info@herrmannhieber.de Internet: www.herrmannhieber.de $/80,1,80³ SUPPLIERS DIRECTORY 4.7 Casting machines and equipment see Section handling 2.3 4.5 Mold accessories and accessory materials Formzubehör, Hilfmittel Fluxes Flussmittel Solvay Fluor GmbH Hans-Böckler-Allee 20 D-30173 Hannover Telefon +49 (0) 511 / 857-0 Telefax +49 (0) 511 / 857-2146 Internet: www.solvay-fluor.de Hier könnte Ihr Bezugsquellen-Eintrag stehen. Rufen Sie an: Tel. 0821 / 31 98 80-34 Dennis Ross Gießereimaschinen und Gießeinrichtungen GAPCast TM: the Swiss casting solution Casting Technology / Automation Tel.: +41 27 455 57 14 E-Mail: info@gap-engineering.ch Internet: www.gap-engineering.ch Mould parting agents Kokillentrennmittel Schröder KG Schmierstofftechnik Postfach 1170 D-57251 Freudenberg Tel. 02734/7071 Fax 02734/20784 www.schroeder-schmierstoffe.de 4.8 Handling technology Handhabungstechnik www.mechatherm.com see Smelting technology 1.5 Precimeter Control AB Ostra Hamnen 7 SE-475 42 Hono / Sweden Tel.: +46 31 764 5520, Fax: +46 31 764 5529 E-Mail: marketing@precimeter.com Internet: www.precimeter.com Sales contact: Jonatan Lindstrand www.ctisystems.com see Section handling 2.3 Ein Eintrag (s/w) in diesem Format kostet pro Ausgabe + Stichwort 110,00 € + MwSt. 4.6 Foundry equipment Gießereianlagen Competence in EMC and ASC casting RIHS ENGINEERING SA Tel.: +41 27 455 54 41 E-Mail: info@maschko.ch Internet: www.maschko.ch www.mechatherm.com see Smelting technology 1.5 Casting machines Weitere Informationen unter Tel. +49 (0) 821 / 31 98 80 - 0 4.10 Measurement technology and materials testin Wagstaff, Inc. see Casting machines 1.6 Gießmaschinen Messtechnik und Materialprüfung ratioTEC Prüfsysteme GmbH HERTWICH ENGINEERING GmbH see Casthouse (foundry) 1.5 Could not find your „keywords“? Please ask for our complete „Supply sources for the aluminium industry“. E-Mail: anzeigen@giesel.de www.alu-web.de see Equipment and accessories 3.1 Heat treatment furnaces Wärmebehandlungsöfen Continuous ingot casting lines and aluminium rod lines Kokillengieß- und Aluminiumdraht-Anlagen HOFMANN Wärmetechnik GmbH Recycling / Recycling Tel. +43(0)7215/3601 E-Mail: office@hofmann-waermetechnik.at Internet: www.hofmann-waermetechnik.at $/80,1,80³ 4.11 Metallic charge materials Metallische Einsatzstoffe Gewerbezeile 7 A - 4202 Helmonsödt see Casthouse (foundry) 1.5 In der Au 17 D-88515 Langenenslingen Tel.: +49 (0)7376/9622-0 Fax: +49 (0)7376/9622-22 E-Mail: info@ratiotec.com Internet: www.ratiotec.com Via Emilia Km 310 26858 Sordio-LO Italy Tel. +39.02.988492-1 . hq@properzi.it Fax +39.02.9810358 . www.properzi.com Chr. Otto Pape GmbH Aluminiumgranulate Berliner Allee 34 D-30855 Langenhagen Tel:+49(0)511 786 32-0 Fax: -32 Internet: www.papemetals.com E-Mail: info@papemetals.com 111 LIEFERVERZEICHNIS 4.13 Melt operations Schmelzbetrieb Melting furnaces Schmelzöfen 4.18 Dross recovery Schlackenrückgewinnung Gautschi Engineering GmbH see Casting equipment 3.1 www.mechatherm.com see Smelting technology 1.5 HERTWICH ENGINEERING GmbH see Extrusion 2.4. see Casthouse (foundry) 1.5 Burner System Brennertechnik Büttgenbachstraße 14 D-40549 Düsseldorf/Germany Tel.: +49 (0) 211 / 5 00 91-0 Fax: +49 (0) 211 / 5 00 91-14 E-Mail: info@bloomeng.de Internet: www.bloomeng.de Hier könnte Ihr Bezugsquellen-Eintrag stehen. Rufen Sie an: Tel. 0821 / 31 98 80-34 Dennis Ross Heat treatment furnaces Wärmebehandlungsanlagen Gautschi Engineering GmbH see Casting equipment 3.1 see Equipment and accessories 3.1 MARX GmbH & Co. KG Lilienthalstr. 6-18 D-58638 Iserhohn Tel.: +49 (0) 2371 / 2105-0, Fax: -11 E-Mail: info@marx-gmbh.de Internet: www.marx-gmbh.de 4.14 Melt preparation Schmelzvorbereitung Degassing, filtration Entgasung, Filtration Drache Umwelttechnik GmbH Werner-v.-Siemens-Straße 9/24-26 D 65582 Diez/Lahn Telefon 06432/607-0 Telefax 06432/607-52 Internet: http://www.drache-gmbh.de Schmelzbehandlungseinrichtungen see Casthouse (foundry) 1.5 see Equipment and accessories 3.1 Holding furnaces Warmhalteöfen Gautschi Engineering GmbH see Casting equipment 3.1 see Equipment and accessories 3.1 112 5 Materials and Recycling Werkstoffe und Recycling 4.15 Melt treatment devices HERTWICH ENGINEERING GmbH ALTEK EUROPE LTD Lakeside House, Burley Close Chesterfield, Derbyshire. S40 2UB UNITED KINGDOM Tel: UK: +44 (0)1246 383737 Tel: USA: +1 484 713 0070 Internet: www.altek-al.com Metaullics Systems Europe B.V. Ebweg 14 NL-2991 LT Barendrecht Tel. +31-180/590890 Fax +31-180/551040 E-Mail: info@metaullics.nl Internet: www.metaullics.com 4.17 Environment protection and disposal Umweltschutz und Entsorgung Dust removal Entstaubung NEOTECHNIK GmbH Entstaubungsanlagen Postfach 110261, D-33662 Bielefeld Tel. 05205/7503-0, Fax 05205/7503-77 info@neotechnik.com, www.neotechnik.com Granulated aluminium Aluminiumgranulate Chr. Otto Pape GmbH Aluminiumgranulate Berliner Allee 34 D-30855 Langenhagen Tel:+49(0)511 786 32-0 Fax: -32 Internet: www.papemetals.com E-Mail: info@papemetals.com 6 Machining + Application Bearbeitung + Anwendung 6.1 Equipment to produce castplate Ausrüstungen für Gussplattenproduktion Slicing saw & Milling machines Folienschneidmaschinen Fräsmaschinen Sermas Industrie sermas@sermas.com see Smelting technology 1.6 6.2 Semi products Halbzeuge Wires / Drähte DRAHTWERK ELISENTAL W. Erdmann GmbH & Co. Werdohler Str. 40, D-58809 Neuenrade Postfach 12 60, D-58804 Neuenrade Tel. +49(0)2392/697-0, Fax 49(0)2392/62044 E-Mail: info@elisental.de Internet: www.elisental.de $/80,1,80³ SUPPLIERS DIRECTORY 8 6.3 Equipment for forging and impact extrusion Ausrüstung für Schmiedeund Fließpresstechnik Literature Fachzeitschriften Literatur Technical literature Hydraulic Presses Fachliteratur Hydraulische Pressen Taschenbuch des Metallhandels Fundamentals of Extrusion Technology Giesel Verlag GmbH Hans-Böckler-Allee 9, 30173 Hannover Tel. 0511/8550-2638 · Fax 0511/8550-2405 Giesel Verlag GmbH Hans-Böckler-Allee 9, 30173 Hannover Tel. 0511 / 73 04-125 · Fax 0511 / 73 04-233 Internet: www.alu-bookshop.de LASCO Umformtechnik GmbH Hahnweg 139, D-96450 Coburg Tel. +49 (0) 9561 642-0 Fax +49 (0) 9561 642-333 E-Mail: lasco@lasco.de Internet: www.lasco.com Could not find your „keywords“? Please ask for our complete „Supply sources for the aluminium industry“. E-Mail: anzeigen@giesel.de www.alu-web.de International ALUMINIUM Journal 89. Jahrgang 1. 1. 2013 Verlag / Publishing house Giesel Verlag GmbH Postfach 5420, 30054 Hannover Hans-Böckler-Allee 9, 30173 Hannover Tel. +49(0)511 7304-0, Fax +49(0)511 7304-157 info@giesel.de, www.giesel-verlag.de Postbank / postal cheque account Hannover, BLZ / routing code: 25010030; Kto.-Nr. / account no. 90898-306, Bankkonto/bank account Commerzbank AG, BLZ/routing code: 25040066, Kto.-Nr./account no. 1500222 Geschäftsleitung / Managing Director Klaus Krause Redaktion / Editorial office Dipl.-Vw. Volker Karow Chefredakteur, Editor in Chief Franz-Meyers-Str. 16, 53340 Meckenheim Tel. +49(0)2225 8359643 Fax +49(0)2225 18458 vkarow@online.de Dipl.-Ing. Rudolf P. Pawlek Hüttenindustrie und Recycling rudolf.pawlek@span.ch Dipl.-Ing. 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In view of the ALUMINIUM MIDDLE EAST 2013 trade fair in Dubai from 23 to 25 April we will be reporting on the aluminium industry in the Gulf region – on the companies located there and their equipment partners, current projects and market developments. Weitere Themen Other topics • Energieoptimiert vom Aluminiumschrott zum stranggepressten Halbzeug • Tragbare Metallanalysatoren für Recyclingbetriebe • Urban Mining – Rohstoffquelle der Zukunft • Energy optimised – from aluminium scrap to extruded semi-finished products • Portable metal analysers support recycling operations • Low-energy air-cooled electromagnetic stirring systems • Controlling high temperatures in smelting using technical textiles • Urban mining – raw material source for the future Research • Einfluss der Biegeüberlagerung auf die Grenzformänderung von Aluminiumfeinblech Erscheinungstermin: Anzeigenschluss: Redaktionsschluss: 11. März 2013 25. Februar 2013 11. Februar 2013 Date of publication: Advertisement deadline: Editorial deadline: 11 March 2013 25 February 2013 11 February 2013 Abonnement-Bestellung Subscription-Order U Ja, wir möchten die Zeitschrift ALUMINIUM ab sofort zum Jahresbezugspreis von EUR 297,- (Inland inkl. Mehrwertsteuer und Versandkosten) abonnieren. Das Magazin erscheint zehn Mal pro Jahr. Das Abonnement kann mit einer sechswöchigen Frist zum Bezugsjahresende gekündigt werden. U Yes, we want to subscribe to ALUMINIUM. The rate is EUR 297.00 per year incl. postage. Outside Europe US$ 393.00 incl. surface mail, air mail plus US$ 82.00. The magazine is published ten times a year. Cancellations six weeks prior to the end of a subscription year. Name / name Firma / company Anschrift / address Umsatzsteuer-Ident.-Nr. / VAT Reg.-No. Datum / date Unterschrift/Signature 82 114 ALUMINIUM ALUMINIUM · 1-2/2013 · 5/2012 www.aluminium-middleeast.com Forging Connections. Building Possibilities. ALUMINIUM MIDDLE EAST 2013 23-25 April 2013 I Sheikh Saeed Hall Dubai International Convention & Exhibition Centre (DICEC) Register online for your fast track access DQGHQMR\WKHEHQH¿WVRIWKHEXVLQHVVPDWFKLQJVHUYLFH visit: www.aluminium-middleeast.com Book your stand today contact: info@aluminium-middleeast.com Organised by THE ULTIMATE SERVICE... FOR CARBON PRODUCT DEVELOPMENT AND APPLICATIONS Contact us and profit from twenty-five years 0f expertise in... Innovation is our strength... www.rd-carbon.com Research and Development Laboratory Test Equipment Bake Furnace Firing System Audits and Process Optimization Quality Control and Certification Technology Development Training and Workshops R&D Carbon Ltd. • P. O. Box 362 • CH-3960 Sierre • Switzerland Phone: + 41 27 459 29 29 • Fax: + 41 27 459 29 25 • e-mail: rdc@rd-carbon.com