Health and Safety Executive Measurement of acoustic spectra from liquid leaks Prepared by Health and Safety Laboratory for the Health and Safety Executive 2007 RR568 Research Report Health and Safety Executive Measurement of acoustic spectra from liquid leaks M Royle D Willoughby E Brueck J Patel Health and Safety Laboratory Harpur Hill Buxton Derbyshire SK17 9JN Acoustic leak detection is being used increasingly in the offshore industry as a means of detecting leaks of flammable substances on offshore platforms. Rather than relying solely on human intervention or the uncertain and inefficient dispersion of gas to the detectors, acoustic leak detectors (ALD) detect a leak through the ultrasonic sound produced by the escaping gas jet. These sensors are generally designed to detect leaks of gaseous products and have been shown to perform well under the conditions experienced on offshore platforms. HSE recognises the benefits of using such devices possibly in conjunction with line-of-sight sensors to detect gaseous releases. This report and the work it describes were funded by the Health and Safety Executive (HSE). Its contents, including any opinions and/or conclusions expressed, are those of the authors alone and do not necessarily reflect HSE policy. HSE Books © Crown copyright 2007 First published 2007 All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means (electronic, mechanical, photocopying, recording or otherwise) without the prior written permission of the copyright owner. Applications for reproduction should be made in writing to: Licensing Division, Her Majesty’s Stationery Office, St Clements House, 2-16 Colegate, Norwich NR3 1BQ or by e-mail to hmsolicensing@cabinet-office.x.gsi.gov.uk CONTENTS 1. INTRODUCTION 1 1.1 BACKGROUND 1 1.2 AIMS 1 1.3 THIS REPORT 2 2. TEST FACILITY 3 2.1 TEST LOCATION 3 2.2 TEST FACILITY 3 2.3 RELEASE FACILITY 4 2.4 FLUID PRESSURISATION VESSELS 5 2.5 RELEASE MANIFOLD 5 3. INSTRUMENTATION AND DATA PROCESSING 9 3.1 ATMOSPHERIC MEASUREMENTS 3.1.1 Wind speed and direction 3.1.2 Temperature and humidity 9 9 9 3.2 PRESSURE SENSORS 9 3.3 ACOUSTIC LEAK DETECTORS 9 3.4 SOUND MEASUREMENT 11 3.5 DATA ACQUISITION AND ANALYSIS 12 3.6 VISUAL RECORDS 13 4. WORK PLAN AND OPERATING PROCEDURE 4.1 WORK PLAN 15 4.2 OPERATING PROCEDURE 15 4.3 DATA FILES 16 5. RESULTS 17 ii 15 iii iv 5.1 AIR RELEASES 17 5.2 WATER RELEASES 18 5.3 DIESEL RELEASES 22 5.4 PROPANE RELEASES 25 5.5 DIESEL PROPANE MIXTURE RELEASES 28 6. CONCLUSIONS 31 7. ACKNOWLEDGEMENTS 33 8. REFERENCES 35 9. APPENDICES 36 9.1 Appendix A. Details of Tests undertaken 36 9.2 Appendix B. Frequency spectra 43 9.3 Appendix C Frequency spectra 45 9.4 Appendix D frequency spectra 55 9.5 Appendix E frequency spectra 57 9.6 Appendix F frequency spectra 61 9.7 Appendix G frequency spectra 65 9.8 Appendix H. Details of acoustic equipment used 69 iii EXECUTIVE SUMMARY Since the Piper alpha incident in 1988 fixed gas detection systems have proliferated across the North Sea. However evidence exists to suggest that their contribution to control and mitigation against major hazards is not in proportion to their size and complexity. This assertion is supported by data for hydrocarbon leaks and detection methods in the UK offshore industry over the nine years from 1992 to 2000 (OTO2000/112)(1) The traditional fixed gas detection systems detect only 65% of flammable gas releases. The remaining 35% of releases are mainly detected by personnel. Liquid hydrocarbons are much more difficult to detect than gas. From a total of 793 liquid releases 499 were detected by personnel, i.e. visual sound smell or hand held metering equipment. The major implication of this is that offshore personnel are entering areas where hydrocarbon releases exist and that detection of liquid leaks in particular relies on personnel going into potentially hazardous areas. Acoustic leak detection is being used increasingly in the offshore industry as a means of detecting leaks of flammable substances on offshore platforms. Rather than relying solely on human intervention or the uncertain and inefficient dispersion of gas to the detectors, acoustic leak detectors (ALD) detect a leak through the ultrasonic sound produced by the escaping gas jet. These sensors are generally designed to detect leaks of gaseous products and have been shown to perform well under the conditions experienced on offshore platforms. HSE recognises the benefits of using such devices possibly in conjunction with line-of-sight sensors to detect gaseous releases. There is an increasing desire across the industry to adopt these devices for detection of liquid releases as well as for gaseous releases. The devices have been proven so far only for gaseous releases. Acoustic leak detectors have in some circumstances been shown to be able to respond to the noise generated by liquid releases under pressure. Industry and HSE are however not in a position to accept the use of these devices for detecting liquid releases because their response to such leaks has not been characterised. The aim of this work is to investigate the response of acoustic leak detectors to liquid releases and ultimately to produce guidance for their acceptable use. The objectives are to provide: • • • spectra of the sound produced from pressurised releases of liquids from a variety of realistic release scenarios, details of the response of selected ALD sensors positioned at different locations relative to the point of release and information which can be used to produce guidance on the use, sensitivity and positioning of ALD sensors for protection against liquid releases. The programme of work involved: • • • Initial releases of air at pressures up to 100 bar in order to characterise the release facility and provide a base-line sensitivity for the sensors. Releases of water at pressures up to 100 bar. Hydrocarbon releases including liquid propane, diesel and diesel / propane mixtures. iv v • • • Releases were made using a variety of release scenarios which were intended to simulate realistic leakage conditions Three types of acoustic leak detectors from 2 manufacturers were used for the trials Acoustic spectra from the releases were recorded. The data and some discussion of the results are contained in this report. The data, in Excel format, is given on the accompanying Compact Disc. Conclusions are provided based on an analysis of the data sufficient only to allow it to be accurately reported. A more detailed analysis may reveal additional features. The main conclusions are as follows: vi (a) All releases; air, water, propane, nitrogen padded propane, propane / diesel mixture or diesel alone gave rise to broadband, random noise into the ultrasonic range. There are no unique or distinctive frequency characteristics that would identify either the nature of the opening, the release pressure or the substance released. (b) Ultrasonic leak detectors were most effective detecting the air leaks (c) The sound pressure level arising from the release changes according to the substance, the release pressure and the orifice. (d) Liquid releases produce a lower sound pressure level than a gas release. An air release at 32 bar gives rise to level around 30 dB higher than a corresponding water release. Diesel releases gave levels around 6 dB higher than a water release; mixed phase releases are around 9 dB higher than a water release. (e) Ultrasonic leak detectors will require a higher sensitivity to detect liquid or mixed phase leaks. The ultrasonic leak detectors used in these trials did not always detect liquid leaks, even at 98 bar. (f) The sound pressure level of the releases increases with increasing release pressure, although the rate at which the sound pressure level increases against the release pressure is variable. (g) The nature of the orifice affects the sound pressure level. However, the sound pressure level is not simply related to the orifice size as both increases and decreases in sound pressure level are reported for increases in size. (h) If ultrasonic leak detectors are to be used to detect liquid or mixed phase leaks they will require a higher sensitivity due to the lower ultrasound levels. However increasing the sensitivity will only be of benefit if the sound from the leak exceeds normal background levels. It will not be possible to select any ultrasonic frequency band that characterises any substance, or opening associated with the leak. v 1. 1.1 INTRODUCTION BACKGROUND Since the Piper alpha incident in 1988 fixed gas detection systems have proliferated across the North Sea. However evidence exists to suggest that their contribution to control and mitigation against major hazards is not in proportion to their size and complexity. This assertion is supported by data for hydrocarbon leaks and detection methods in the UK offshore industry over the nine years from 1992 to 2000 (OTO2000/112) The traditional fixed gas detection systems detect only 65% of flammable gas releases. The remaining 35% of releases are mainly detected by personnel. Liquid hydrocarbons are much more difficult to detect than gas. From a total of 793 liquid releases 499 were detected by personnel, i.e. visual sound, smell or hand held metering equipment. The major implication of this is that offshore personnel are entering areas where hydrocarbon releases exist and that detection of liquid leaks in particular relies on personnel going into potentially hazardous areas. Acoustic leak detection is being used increasingly in the offshore industry as a means of detecting leaks of flammable substances on offshore platforms. Rather than relying solely on human intervention or the uncertain and inefficient dispersion of gas to the detectors, acoustic leak detectors (ALD) detect a leak through the ultrasonic sound produced by the escaping gas jet. These sensors are generally designed to detect leaks of gaseous products and have been shown to perform well under the conditions experienced on offshore platforms. HSE recognises the benefits of using such devices possibly in conjunction with line-of-sight sensors to detect gaseous releases. There is an increasing desire across the industry to adopt these devices for detection of liquid releases as well as for gaseous releases, for which the devices have been proven. Acoustic leak detectors have in some circumstances been shown to respond to the noise generated by liquid releases under pressure. Industry and HSE are however not in a position to accept the use of these devices for detecting liquid releases because their response to such leaks has not been characterised. 1.2 AIMS This series of experiments was intended to establish whether currently available acoustic leak detectors could be used successfully to detect liquid leaks. At the same time the acoustic spectra produced by the leaks would be measured to characterise the sounds produced by high pressure liquid leaks. This data could then possibly be used to refine sensor performance for liquid leaks. The aims of the work were to: (a) Measure the response of the detectors to leaks of air at pressures up to 100 bar. (b) Measure the response of the detectors to leaks of water at pressures up to 100 bar. (c) Measure the response of the detectors to releases of diesel and diesel / propane mixtures at elevated pressure and determine if any difference exists between the detection of sounds produced by a water leak and those produced by a diesel leak. (d) Measure the response of the detectors to a release of liquid propane. (e) Characterise the sounds produced from the leaks by means of spectral analysis. 1 1.3 THIS REPORT This report is a factual record of the tests undertaken and of the measurements recorded. Data from all the measurements taken are given as Microsoft Excel files on Compact Disk reference number (HSLPS0618) to allow more detailed analysis. 2 2. TEST FACILITY The acoustic leak rig consists of a series of pressure storage vessels and a release rig interconnected by a flexible hose. Next to the storage unit is a shed which houses the compressor intended for charging the storage unit with compressed air to the required pressure. A cylinder of compressed air is used to provide air at 7 bar for the pneumatic valves. Electrical, instrumentation cables run from the edge of the platform along cable tray to the control room (building 13). The release of fluids is performed remotely from the control room and all test parameters can be monitored and logged from the control room. All solenoid and pneumatic valves are connected in such a way that in the event of either an electrical or pneumatic supply failure, the system will ‘fail safe’. In normal operation the area surrounding the rig is observed by video camera. In normal operation there is no necessity to approach the test facility whilst the apparatus is under pressure. This section provides a full description of the acoustic leak release rig. 2.1 TEST LOCATION The test facility was situated at the gas dispersion site at the Health and Safety Laboratory at Buxton (see Figure 1). Gas d Dispersion Fi i Site New building Figure 1. Test location 2.2 TEST FACILITY The main test facility comprised: 3 • An elevated steel chequer plate platform, measuring some 10 m x 10 m supported 930 mm above a concrete pad and edged with 50mm high angle section steel; A three phase multistage air compressor housed next to the platform in a purpose built building to provide compressed air to the release rig at up to 105 bar; Three 250 litre vessels to provide storage of release fluids at up to 100 bar; A buffer vessel and release rig having 5 actuated valves. Support wire gantry to support the acoustic detectors above the platform Local wind speed and direction recording (5m from the release point) Remote control room (100 m from the release point) with data logging equipment, instrument power supplies and remote control board for the actuated valves. • • • • • • In the trials described in this report, releases of various fluids were made at pressures up to 100 bar and the outputs from the detectors recorded. The sound produced by these releases was recorded for later analysis. A schematic representation of the test facility is shown in Figure 2. High pressure fluid vessels X Ultrasonic anemometer X Release manifold Compressor building X Diesel pump Bulk propane storage Diesel storage Concrete block wall X Propane release valve X X Support wires Nitrogen storage X Deck platform Detector positions Figure 2. Schematic representation of the test facility 2.3 RELEASE FACILITY The release facility comprises three discrete items; a Hamworthy high pressure air compressor; a bank of storage vessels for containing the released fluids and compressed air; and a buffer vessel and manifold from which the fluids are released. The release facility is controlled remotely from a building approximately 100 metres distant. This building also houses the instrumentation power supplies and the data collection equipment. 4 P I-1 V--1 V--4 PRV--1 P-12-- AV1 V--2 V--3 Air Water Diesel T-1 T-2 T-3 Water fill Diesel fill V--6 V--5 V--8 V--7 Air or nitrogen in V--9 V--10 Flexible hose to release manifold Figure 3. Piping and instrumentation diagram for storage vessels 2.4 FLUID PRESSURISATION VESSELS The fluids to be released are stored and pressurised in a bank of three 250 litre steel vessels. The vessels are pressure tested to 150 bar and are interconnected to allow filling and discharge of the various fluids. In use the air vessel is pressurised to the required discharge pressure with either air or nitrogen and the valves on the rig are set such that the required release fluid is forced out of its storage vessel by the air pressure. The pressure inside the air vessel is monitored using a pressure transducer. A flexible hose connects the storage vessels to the release manifold. A piping and instrumentation diagram for the fluid pressurisation vessels is shown in figure 3. 2.5 RELEASE MANIFOLD The release manifold is fixed to one edge of an elevated 10 x 10 metre deck platform. The release rig consists of a 22 litre buffer vessel with an inlet and a total of 7 outlets. The outlets comprise a drain with a manual valve, a bleed facility with a manual valve and five outlets with full-bore actuated valves for the controlled releases. Each of the five release outlets is fitted with a pressure transducer immediately upstream of the actuated valve. The outlets from the release rig were orientated such that the fluids sprayed across the platform. A piping and instrumentation diagram for the release manifold is shown in figure 4 and a photograph in figure5. 5 Flexible hose from storage vessels Vent PI V11 V12 Release Manifold / buffer vessel Drain AV5 PI AV6 P AV4 PI P AV3 PI P PI P AV2 P PI Figure 4. Piping and instrumentation diagram for the release manifold. Figure 5. Release manifold The release manifold had 5 valves set up to simulate a number of commonly occurring process fluid leakage scenarios, these are summarised in table 1. 6 Valve Number 1 2 3 4 5 Table 1. Leakage scenarios Description Valve stem packing leak (simulating split packing) Straight hole with varying diameters (3 mm, 12 mm and 24 mm) Straight hole with 6 mm diameter Simulating gasket blow out behind a bolt which splits the jet Simulating gasket blow out between bolts (most common failure) Gasket blow outs were simulated by removing a section of gasket from the required area of a raised face 1.5 inch 1500 lb pipe flange. This gave an orifice having a segment shape and dimensions 31mm x 2mm. 7 3. INSTRUMENTATION AND DATA PROCESSING A brief description of the sensors and their location is given in this section. 3.1 ATMOSPHERIC MEASUREMENTS Atmospheric measurements were necessary in order to correlate differences in acoustic sensor response. 3.1.1 Wind speed and direction The wind speed and direction were recorded approximately 10 m from the release point at a height of 2.5 m using an FT technologies ultrasonic anemometer. Site wind speed and direction were also recorded at a height of 10 metres using a Vector Instruments A100 anemometer and weather vane. 3.1.2 Temperature and humidity The atmospheric humidity was measured at 10 m and 1.5 m using a Vector Instruments atmospheric humidity sensor. The atmospheric temperature was measured at 1.5 3, 6 and 10 metres using Vector Instruments temperature sensors. 3.2 PRESSURE SENSORS The conditions within the pressure vessels were monitored using a Vega Controls 0-250 bar pressure transmitter, similar pressure transmitters were also located upstream of the actuated valves on each of the five release points. These transmitters are of the strain gauge type having a stainless steel diaphragm and integrated signal conditioning electronics which give a 4-20 ma output. 3.3 ACOUSTIC LEAK DETECTORS The acoustic leak detectors used for these trials were prototype units and therefore became available at different times during the course of this work. Therefore different combinations of detectors were used at different times. In initial tests three Innova Gassonic observer detectors were used, these were supported on poles at 2.8 m above the deck platform, (sensor configuration A). The initial tests showed that this method of mounting raised questions as to the levels of ultrasound produced by the jets of fluids impacting the poles and also raised the possibility of acoustic coupling from the deck platform to the sensors. The mounting of the sensors was subsequently changed such that they were suspended above the platform on steel wires. At the same time two additional Innova Gassonic detectors were installed together with a further detector from Groveley Detection, (sensor configuration B). At a later date a further Groveley detector was added and one of the Innova Gassonic observers removed, (sensor configuration C). The first Groveley detector was a broadband unit with an acoustic response extending into the audible range. The second Groveley detector had a response limited to the ultrasound region similar to the response of the Gassonic observer detectors. Details of sensor positions for each configuration are given in table 2 below. 9 Sensor configuration A B C (1) (2) Table 2. Acoustic detector positions Sensor positions ALD1 ALD2 ALD3 ALD4 ALD5 ALD6 Gassonic Gassonic Gassonic Gassonic Gassonic Gassonic Gassonic Groveley(2) Groveley(1) Gassonic Gassonic Gassonic Gassonic Groveley(2) - ultrasonic response detector – wideband response detector All the acoustic leak detectors were installed as set up by the manufacturers. The analogue output from each of the detectors was logged to the data collection system. For both types of detector this gave an output in decibels. The Gassonic detectors have a baseline threshold level of 58 dB, that is with no signal detected they read 58 dB. The Gassonic detectors also periodically produce pulses of ultrasound as an automated self-test, these pulses can be seen on the spectral analyses of some of the recordings made. The Groveley detectors have a lower threshold of 10 dB and were scaled to give a reading of between 10 and 100 dB. No alarm thresholds were set on the detectors as these would, in practice, be set to take account of local environment and conditions, in order to avoid false alarms. A diagram of detector positions is shown at figure 6 and a photograph of the detectors mounted above the decking at figure 7. 2m 5 3 4 2 6 1 Release manifold Release height 0.72 m above deck 2.5 m 10 2.5 m m 2.5 m 2.5 m Figure 6. Detector positions As noted above, due to the availability of sensors different sensor combinations were used for different sets of trials, table 2 gives the detector positions for each configuration used. 10 Figure 7. Photograph of the release facility 3.4 SOUND MEASUREMENT Noise measurements were made between March and November 2005. Weather conditions varied during measurements over this period. Appendix 1 contains details of the equipment used to measure the noise generated during the releases. Figures 7 and 8 show the measurement arrangements. Two ultrasonic gas leak detectors were tested; the details for each are shown in Table 3. Table 3: Acoustic specifications for the ultrasonic gas leak detectors Detector Gassonic Observer Acoustic specifications Detector frequency range: 25 kHz – 70 kHz Dynamic range: 54 – 104 dB Groveley Detection GDU-01 Ultrasonic Leak Detector Groveley Detection wide band leak detector Frequency range: 30 – 80 kHz Frequency range: 3 – 80 kHz Test sound source Test frequency: 40 kHz ± 3 kHz Sound pressure: 100 dB, 60 mm from sound source N/a N/a Early tests were performed with detector configuration A, as shown in figure 8. Microphones (connected to preamplifiers via gooseneck extensions) were taped to the posts on which the 11 detectors were mounted approximately 2.6 m above the platform. The microphone diaphragm was positioned approximately 10 cm from the detector facing the release manifold. Platform X Gassonic detector and measurement position Forward microphone Left microphone 1 3 2 4 5 Right microphone Release manifold Figure 8: Measurement set up for early tests of Gassonics detectors In later tests, Gassonic and Groveley leak detectors were suspended from wires positioned 2.8 m above the platform as shown in Figure 9. Microphones were taped to the wires so that the microphone diaphragm was approximately 10 cm from the detector facing the release manifold, and a third microphone fixed to the release manifold between valves 2 and 3. Platform X Measurement position Groveley detector Gassonic detector X X 1 Left microphone 3 2 4 X 5 Right microphone Release manifold Figure 9: Measurement set up for later tests using Gassonic and Groveley detectors 3.5 DATA ACQUISITION AND ANALYSIS The output from the microphones was input to the TEAC LX-10 data recorder producing a digital recording with a sample rate of 96 kHz. The data was recorded on magneto-optical discs for post-processing. The data files were converted into a suitable format that enabled frequency 12 analysis in 94 Hz intervals up to 48 kHz through a MATLAB analysis package. These spectra are shown as a plot of the power spectral density. The data files were also played though a band pass filter and measuring amplifier to obtain the sound pressure level in the one-third-octave band centred at 25 kHz during each release. This result gives an indication of how the overall level of ultrasound changes with release conditions. For longer releases a 3 or 10 s exponential averaging time was chosen. For the very short releases containing diesel the maximum rms level with a fast time constant is reported. Spectra from early recordings contain tonal spikes. These are purely due to pick up in the recording system when recording low level ultrasound against higher level audible sound. These spikes were present both with and without a release and were eliminated in later recordings by careful earthing of the recording system. All other instrumentation used had 4-20 mA outputs; these signals were fed back to the data collection system where they were converted to voltages using precision 250 Ohm resistors. The data collection system comprised three Data Translation 12 bit 330 kHz analogue to digital capture cards fitted into a PC and running Agilent Vee data collection software. Multipliers and offsets were entered into the data collection software to provide an output in engineering units. 3.6 VISUAL RECORDS Video cameras were used to monitor and record the trials. A digital camcorder was located on the platform upwind of the release position as far as was possible in the prevailing weather conditions. A camera was also located on a 10 m mast overlooking the site for general surveillance. 13 4. WORK PLAN AND OPERATING PROCEDURE The work plan and operating procedure are described in this section. 4.1 WORK PLAN The work plan involved performance of: (a) (b) (c) (d) (e) (f) Releases of air through each release orifice at pressures of 32 and 98 bar. Releases of water through each release orifice at pressures of 10, 32 and 98 bar. Releases of liquid propane at its own vapour pressure. Releases of liquid propane at approximately 3 bar above its own vapour pressure in order to ensure it remained liquid at the point of release. Limited releases of diesel fuel oil to determine if release of this fluid is acoustically different to water. Limited releases of diesel fuel oil and propane mixtures containing 5% propane by weight. Details of the tests undertaken are given in Appendix 1. 4.2 OPERATING PROCEDURE The following procedure was used. (a) (b) (c) (d) (e) (f) The valves on the rig were set to the correct position for the type of test to be performed. For liquid releases the requisite vessel was filled with the release fluid. The release manifold was vented such that the release fluid filled the manifold The compressor was started and the air reservoir was pressurised to the required release pressure (for diesel releases this reservoir was pressurised with nitrogen to avoid any possibility of compression ignition of the diesel). After making sure the exclusion zone was clear, the data collection system was started and the required release valve operated. The data from the instrumentation was recorded and then backed up and stored. Releases of propane were made by connecting the 2 inch liquid take-off from a two tonne bulk storage tank to a remotely actuated valve positioned near to the release manifold on the platform. This valve was fitted with different orifice plates in order to vary the release size. The release manifold and pressurisation system was not used for propane releases due to the low temperatures which may have been encountered. Diesel and propane mixtures were made within the storage vessel by weighing the diesel into the storage vessel and then injecting the required amount of liquid propane from a liquid takeoff cylinder positioned on a balance. 15 4.3 DATA FILES Only processed data (i.e. in engineering units), is given in compact disc HSLPS1806. An Excel spreadsheet was produced for each trial. They were labelled as follows and contained the following: Trial name e.g. ALDAIR01.xls The files used for the plots given in this report are shown in the heading to each plot. 16 5. RESULTS The sound pressure level results are given in tables below. In the release details column the release orifice and pressure are given together with any other identifying name and number to enable cross reference to other parts of the report. The file name column refers to the sound recording file name. The value reported for the 25 kHz third octave band is the unweighted rms average sound pressure level during the release; the fast rms maximum sound pressure level is reported for the very short duration releases containing diesel. The corresponding frequency spectrum is referenced in the final column and can be found in Appendices B to G Frequency Spectra. Examples of outputs produced by the ultrasonic leak detectors are also given in this section. The complete data files are supplied on the accompanying Compact Disc (HSLPS1806). 5.1 AIR RELEASES Air releases were performed to check the response of the acoustic sensors to the type of releases they were designed to detect. All the detectors installed for these trials were found to detect air releases at quite small release rates. An example of the output from these devices in response to a simulated gasket failure at a pressure of 10 bar is shown in figure 10. Further air releases were made at various pressures to characterise the response of the devices. A full set of plots for the air releases performed are shown in appendix B. Table 4 gives the sound pressure level from the left microphone during the air releases. Release details Valve 4 32 bar Valve 4 98 bar Valve 5 32 bar Valve 5 98 bar Table 4: Air release analysis results (02/03/2005) 25 kHz one-third File name Frequency spectrum octave band level dB 02-03-2005 Leak12.mat 02-03-2005 Leak14.mat 02-03-2005 Leak10.mat 02-03-2005 Leak13.mat 17 97 Figure B1 Recorder overload Figure B2 Recorder overload Figure B3 Recorder overload Figure B4 Air release at 10bar - file ALDAIR11.xls 100 0_16_ALD 1g 0_17_ALD 2 90 Detector response (dB) 80 0_18_ALD 3 end of release start of release 0_20_ALD 5 0_21_ALD 6g 70 60 50 40 30 20 10 0 0 5 10 15 20 25 30 35 40 Time (s) Figure 10. Detector response to a simulated gasket failure releasing air at 10 bar. 5.2 WATER RELEASES Water releases were performed in order to determine the response of the acoustic detectors to liquid releases. The acoustic spectra produced by the releases in the ultrasound region were also measured. Releases with water were performed at 10, 32 and 98 bar with release orifices of 3, 6, 12 and 25 mm. The acoustic measurements performed showed broadband ultrasound was produced with no unique or distinctive frequency characteristics. The water releases produced ultrasound levels approximately 30 dB lower than the air releases with the result that the water releases were poorly detected. The sensors did produce an output in response to some of the leaks but it would be difficult to use as a reliable alarm trigger. Figure 11 shows the detector response for a 3 mm water release at 10 bar; as can be seen the detectors show no response to this release. Acoustic measurements for this release show a sound pressure level of 64 dB in the 25 kHz third octave band. Figure 12 shows the detector response for a 3 mm water release at 98 bar. Acoustic measurements for this release show a sound pressure level of 71 dB in the 25 kHz third octave band. Table 5 gives the sound pressure levels from the left microphone during the water releases. March and August measurements have been separated as different microphone positions and test rig arrangements were used. Lower than expected values were reported for the last three measurements on 10 March; it is possible that water on the microphone windshield has attenuated the measured sound level. 18 Table 5: Water release analysis results (10/03/2005, 08/08/05 and 09/08/05) 25 kHz one-third octave Frequency spectrum Release details File name band level dB March measurements Valve 1 10 bar 10_3_2005 ALDTEST38 L96k9.mat Valve 1 32 bar 10_3_2005 ALDTEST34 L96k5.mat Valve 1 98 bar 10_3_2005 ALDTEST42 L96k13.mat Valve 2 98 bar 10_3_2005 ALDTEST43 L96k14.mat Valve 3 10 bar 10_3_2005 ALDTEST37 L96k8.mat Valve 3 (6 mm) 32 10_3_2005 bar ALDTEST33 L96k4.mat Valve 3 98 bar 10_3_2005 ALDTEST41 L96k12.mat Valve 4 10 bar 10_3_2005 ALDTEST36 L96k7.mat Valve 4 32 bar 10_3_2005 ALDTEST32 L96k3.mat Valve 4 98 bar 10_3_2005 ALDTEST40 L96k11.mat Valve 5 10 bar 10_3_2005 ALDTEST35 L96k6 .mat Valve 5 32 bar 10_3_2005 ALDTEST30 L96k1.mat Valve 5 32 bar 10_3_2005 ALDTEST31 L96k2 .mat Valve 5 98 bar 10_3_2005 ALDTEST39 L96k10.mat August measurements Valve 2 32 bar 9_8_2005 LEAKTEST08 Leak16.mat 66 Figure C1 64 Figure C2 54 (microphone windshield wet?) Recorder overload Figure C3 Not included 65 Figure C4 67 Figure C5 59 (microphone windshield wet?) 64 Figure C6 67 Figure C8 69 Figure C9 64 Figure C10 67 Figure C11 66 Figure C12 71 Figure C13 66 Figure C14 Figure C7 Valve 3 32 bar LEAKTEST07 9_8_2005 Leak15.mat 67 Figure C15 Valve 3 100 bar LEAKTEST09 9_8_2005 Leak17.mat 72 Figure C16 Valve 3 97 bar LEAKTEST10 Valve 4 32 bar LEAKTEST06 9_8_2005 Leak18.mat 9_8_2005 Leak14.mat 70 Not included 66 Figure C17 19 Valve 4 100 bar LEAKTEST04 Valve 5 32 bar LEAKTEST05 9_8_2005 Leak6.mat 71 Figure C18 9_8_2005 Leak13.mat 59 Figure C19 Valve 5 100 bar LEAKTEST01 Valve 5 100 bar LEAKTEST02 Valve 5 100 bar LEAKTEST03 9_8_2005 Leak3.mat 65 Figure C20 9_8_2005 Leak4.mat 65 Figure C21 9_8_2005 Leak5.mat 65 Figure C22 ALDTEST35.xls. 3mm hole betwween bolts at 10 bar 100 Detector response (dB) 90 ALD1 0_16_ALD 1 ALD2 0_17_ALD 2 80 ALD3 0_18_ALD 3 70 60 50 40 30 20 10 0 0 2 4 6 8 10 12 14 16 Time (s) Figure 11. Detector response to a simulated gasket failure releasing water at 10 bar. 20 ALDTEST39, water 98 bar, 3 mm hole between flange bolts 100 ALD1 0_16_ALD 1 90 ALD2 0_17_ALD 2 80 Detector response (dB) ALD3 0_18_ALD 3 start of release end of release 70 60 50 40 30 20 10 0 0 5 10 15 20 Time (s) Figure 12. Detector response to a simulated gasket failure releasing water at 98 bar. The difference in sound produced and therefore detector response is well illustrated by the release leaktest10 shown in figure 13. In this test water was released through a 6mm orifice at 98 bar, the release was allowed to continue until all the water had been used and air started to come through. When this occurred a step change appeared on the detector outputs. When water was being released the nearest detector gave an output of 62 dB (4dB above its baseline level), when air started to be released the output increased to 91 dB. It should be noted that the detector ALD6g is a wideband response unit, which also responds to audible noise. 21 Leak Test 10 100 Detector response (dB) 90 80 70 60 50 air 40 0_17_ALD 2 0_18_ALD 3 30 0_19_ALD 4 0_20_ALD 5 20 0_21_ALD 6g start of water release 10 0 100 200 300 400 Time (s) Figure 13. Plot showing different response to water and air leaks. 5.3 DIESEL RELEASES Diesel releases were performed in order to determine if the sound produced by this type of fluid was significantly different to that produced by water. The acoustic measurements showed ultrasound levels possibly 6 dB higher than those produced by water but again there were no unique or distinctive frequency characteristics. The diesel releases only produced broadband ultrasound. The duration and size of these releases were kept to a minimum to reduce the environmental impact and clean up required. Figure 14 shows the detector response for a Diesel release from a between bolt simulated gasket failure at 10 bar, the acoustic measurement on this release gave a sound pressure level of 69 dB in the 25 kHz third octave band. Figure 15 shows the detector response for a between bolt diesel release at 98 bar, the acoustic measurement on this release gave a sound pressure level of 72 dB in the 25 kHz third octave band. The plots show that the detector having the greatest response to the releases is ALD1 this is due to the position of this detector – it is nearest to the leak, and is also downwind of the leak source. Table 6 gives the sound pressure levels from the left microphone during the diesel releases. The results are reported for very short releases and are the fast rms maximum sound pressure level. Release details 10 bar valve 5 (between bolts) ALDDIES 09 10 bar valve 4 (behind bolt) ALDDIES 10 Table 6: Diesel release analysis results (01/11/2005) 25 kHz one-third File name octave band level dB Frequency spectrum 01_11_2005 LeakEB16.mat 69 Figure E1 01_11_2005 LeakEB17.mat 69 Figure E2 22 10 bar valve 3 (6mm 01_11_2005 orifice) ALDDIES 11 LeakEB18.mat 68 Figure E3 32 bar valve 5 (between bolts) ALDDIES 01 32 bar valve 4 (behind bolt) ALDDIES 02 32 bar valve 5 (between bolts) ALDDIES 03 32 bar valve 4 (behind bolt) ALDDIES 04 98 bar valve 3 (6mm orifice) ALDDIES 05 01_11_2005 LeakEB8.mat 75 Figure E4 01_11_2005 LeakEB9.mat 74 Figure E5 01_11_2005 LeakEB10.mat 67 Figure E6 01_11_2005 LeakEB11.mat 70 Figure E7 01_11_2005 LeakEB12.mat 74 Figure E8 98 bar valve 5 (between bolts) ALDDIES 06 98 bar valve 4 (behind bolt) ALDDIES 07 98 bar valve 3 (6mm orifice) ALDDIES 08 01_11_2005 LeakEB13.mat 72 Figure E9 01_11_2005 LeakEB14.mat 78 Figure E10 01_11_2005 LeakEB15.mat 79 Figure E11 23 ALDDIES09.xls - diesel 10bar between bolts 100 90 0_16_ALD 1g 0_17_ALD 2 start of release 80 end of release 0_18_ALD 3 0_19_ALD 4 Detector response (dB) 0_20_ALD 5 70 0_21_ALD 6g 60 50 40 30 20 10 0 0 5 10 15 20 25 Time (s) Figure 14. Detector response to a simulated gasket failure releasing Diesel at 10 bar. ALDDIES06.xls - diesel 98bar between bolts 100 0_16_ALD 1g 90 0_17_ALD 2 0_18_ALD 3 Detector response (dB) 80 0_19_ALD 4 end of release start of release 0_20_ALD 5 0_21_ALD 6g 70 60 50 40 30 20 10 0 0 5 10 15 20 25 Time (s) Figure 15. Detector response to a simulated gasket failure releasing Diesel at 98 bar. 24 5.4 PROPANE RELEASES Two sets of propane releases were made; one set with propane under its own vapour pressure and another with the propane vessel pressurised with nitrogen such that the propane would remain liquid in the nozzle and only flash to vapour when released to the atmosphere. It could reasonably be anticipated that flashing propane releases, particularly those without nitrogen, would easily be detected by the acoustic sensors. The spectra obtained by the acoustic measurements again show the releases gave rise to broadband ultrasound, without any unique or distinctive characteristics. Figure 16 shows the detector response for a release of propane through a 3 mm orifice and figure 17 shows the detector response for a release of propane through a 12 mm orifice. The acoustic measurements for these two tests both give a sound pressure level of 77 dB in the 25 kHz third octave band but it is apparent from the graphs that the larger release is more easily detected by the sensors. Figures 18 and 19 show similar releases but with the propane pressurised with nitrogen. Table 7 gives the sound pressure levels from the left microphone during the propane releases. Release details Table 7: Propane release analysis results (11/08/2005) 25 kHz one-third File name Frequency spectrum octave band level dB 3 mm orifice ALDPROP04 6 mm orifice ALDPROP03 12 mm orifice ALDPROP02 Simulated gasket failure ALDPROP05 38mm orifice ALDPROP06 11_08_2005 Leak89.mat 11_08_2005 Leak88.mat 11_08_2005 Leak87.mat 11_08_2005 Leak810.mat 11_08_2005 Leak811.mat 77 Not included 79 Figure D1 77 Figure D2 80 Figure D3 91 Figure D4 Table 8 gives the sound pressure levels measured by the right microphone for each of the Nitrogen padded propane releases. It should be noted that the microphone to the left of the release failed during the day’s measurements and the results have been removed from the corresponding frequency spectra. Table 8: Propane padded nitrogen release analysis results (17/11/2005) 25 kHz one-third Release details File name Frequency spectrum octave band level dB 3 mm orifice ALDPROP08 3 mm orifice ALDPROP09 6 mm orifice ALDPROP10 6 mm orifice ALDPROP11 12 mm orifice ALDPROP14 12 mm orifice ALDPROP15 38 mm orifice 8 bar 17_11_2005Leak910.mat 85 Figure F1 8 bar 17_11_2005Leak911.mat 83 Figure F2 8 bar 17_11_2005Leak912.mat 84 Figure F3 8 bar 17_11_2005Leak913.mat 84 Figure F4 8 bar 17_11_2005Leak916.mat 85 Not included 8 bar 17_11_2005Leak918.mat 85 Figure F5 8 bar 17_11_2005Leak919.mat 81 Figure F6 25 ALDPROP16 Simulated gasket 80 failure ALDPROP12 17_11_2005Leak914.mat Figure F7 Simulated gasket 80 failure ALDPROP13 17_11_2005Leak915.mat Figure F8 ALDPROP04.xls - release of propane through 3mm orifice 100 0_17_ALD 2 90 0_18_ALD 3 0_19_ALD 4 Detector response (dB) 80 0_20_ALD 5 0_21_ALD 6g 70 60 50 40 30 20 10 start of release end of release 0 0 50 100 150 200 Time (s) Figure 16. Detector response to a release of liquid propane through a 3 mm orifice. 26 ALDPROP01.xls - Release of propane through 12 mm orifice 100 0_17_ALD 2 0_18_ALD 3 90 Detector response (dB) 0_19_ALD 4 80 0_20_ALD 5 70 0_21_ALD 6g end of release start of release 60 50 40 30 20 10 0 0 20 40 60 80 100 120 140 Time (s) Figure 17. Detector response to a release of liquid propane through a 12 mm orifice. ALDPROP09.xls - propane release through a 3mm hole 100 Detector response (dB) 90 80 70 60 50 40 30 0_16_ALD 1g 0_17_ALD 2 20 0_18_ALD 3 0_19_ALD 4 start of release 10 0_20_ALD 5 0_21_ALD 6g 0 0 5 10 15 20 25 30 35 Time (s) Figure 18. Detector response to a release of nitrogen padded liquid propane through a 3 mm orifice. 27 ALDPROP15.xls - propane release through a 12mm hole 100 Detector response (dB) 90 start of release end of release 80 70 60 50 40 0_16_ALD 1g 0_17_ALD 2 30 0_18_ALD 3 0_19_ALD 4 20 0_20_ALD 5 0_21_ALD 6g 10 0 0 5 10 15 20 25 30 35 Time (s) Figure 19. Detector response to a release of nitrogen padded liquid propane through a 12mm orifice. 5.5 DIESEL PROPANE MIXTURE RELEASES Releases were made using a mixture of diesel and propane; the mixture contained approximately 5% propane by mass. This mixture was intended to be representative of a ‘dead’ condensate. The mixture was prepared in the diesel storage tank and forced out of the release manifold under nitrogen pressure. Figure 20 shows detector response to a release of diesel / propane mixture at 66 bar through a simulated gasket failure. It can be seen that there is very little difference between detection of this release and that of diesel alone, although acoustic measurements suggest that these releases may produce slightly more sound than those for diesel alone. In addition the acoustic spectra for the diesel propane mixture show only broadband ultrasound arising from the release. There are no unique or distinctive frequency characteristics. Table 9 gives the sound pressure levels measured by the right microphone for each of the diesel + 5% propane releases. It should be noted that the microphone to the left of the release failed during the day’s measurements and the results have been removed from the frequency spectra. The sound pressure levels reported below are for very short releases and are the fast rms maximum sound pressure level. Table 9: Diesel + 5% propane mix release analysis results (17/11/2005) 25 kHz one-third Release details File name Frequency spectrum octave band level dB Valve 3 (6 mm orifice) 32 bar ALDCONDS11 Valve 3 (6 mm orifice) 65 bar ALDCONDS05 17_11_2005Leak930.mat 75 Figure G1 17_11_2005Leak924.mat 85 Figure G2 28 Valve 3 65 bar ALDCONDS06 Valve 4 31 bar ALDCONDS09 Valve 4 65 bar ALDCONDS03 Valve 4 65 bar ALDCONDS04 Valve 5 34 bar ALDCONDS10 Valve 5 48 bar ALDCONDS07 Valve 5 48 bar ALDCONDS08 Valve 5 66 bar ALDCONDS01 Valve 5 66 bar ALDCONDS02 17_11_2005Leak925.mat 84 Figure G3 17_11_2005Leak928.mat 76 Figure G4 17_11_2005Leak922.mat 81 (recorder overload when valve closed) 17_11_2005Leak923.mat 81 Not included 17_11_2005Leak929.mat 75 Figure G6 17_11_2005Leak926.mat 77 Figure G7 17_11_2005Leak927.mat 77 Figure G8 17_11_2005Leak920.mat 78 Figure G9 17_11_2005Leak921.mat 78 Figure G10 Figure G5 ALDCONDS01.xls - 66 bar diesel/propane release between bolts 90 0_16_ALD 1g 80 0_17_ALD 2 Detector response (dB) 0_18_ALD 3 0_19_ALD 4 70 0_20_ALD 5 0_21_ALD 6g 60 50 40 30 20 start of release 10 end of release 0 0 2 4 6 8 10 12 14 Time (s) Figure 20. Detector response to a release of diesel / propane mixture. 29 16 6. CONCLUSIONS Conclusions are provided based on an analysis of the data sufficient only to allow it to be accurately reported. A more detailed analysis may reveal additional features. The main conclusions are as follows: 1. All releases; air, water, propane, nitrogen padded propane, propane / diesel mixture or diesel alone gave rise to broadband, random noise into the ultrasonic range. There are no unique or distinctive frequency characteristics that would identify either the nature of the opening, the release pressure or the substance released. Note - Spikes at ultrasonic frequencies in early water release recordings proved to be due to pick up in the recording system. They were apparent with and without the release, and on unused channels of the recorder. Careful earthing of the recording equipment later eliminated the spikes. 2. The sound pressure level arising from the release depends on the substance, the release pressure, and the orifice. 3. Ultrasonic leak detectors were effective detectors of the air leaks. The sound pressure level from liquid leaks was often insufficient to enable detection. 4. Within the 25 kHz third octave band an air release at 32 bar is likely to give rise to a level around 30 dB higher than a water release. The results suggest diesel releases are giving levels around 6 dB higher than a water release, mixed phase diesel and propane releases are possibly 9 dB higher than a water release. It is clear from these results that ultrasonic leak detectors will require a higher sensitivity to detect liquid or mixed phase leaks. 5. The sound pressure level of the releases increases with increasing release pressure, although the rate at which the sound pressure level increases against the release pressure is variable. 6. The nature of the orifice affects the sound pressure level. However the orifice size alone is not a simple effect as both increases and decreases in sound pressure level are reported for increases in the orifice size. 7. If ultrasonic leak detectors are to be used to detect liquid or mixed phase leaks they will require a higher sensitivity due to the lower ultrasound levels. It will not be possible to select any ultrasonic frequency band that characterises any substance, or opening associated with the leak. 31 7. ACKNOWLEDGEMENTS HSL gratefully acknowledge the assistance received from: Gassonic A/S CBISS Ltd Groveley Detection Ltd Wormald Fire and Safety Ltd Shell UK Ltd Exploration and Production. 33 8. REFERENCES 1.) Health and Safety Executive, Offshore Technology Report OTO 2000 112. Offshore Hydrocarbon Releases Statistics 2000. 35 9. 9.1 APPENDICES APPENDIX A. DETAILS OF TESTS UNDERTAKEN Test ALDtest04 ALDtest05 ALDtest06 ALDtest07 ALDAIR01 ALDAIR02 ALDAIR03 ALDAIR04 ALDAIR05 ALDAIR06 ALDAIR07 ALDAIR08 ALDAIR09 ALDAIR10 ALDAIR11 ALDAIR12 Table A1. Details of air release trials Pressure Leak type (bar) Valve 5 (3mm hole between bolts) Valve 4 (3mm hole behind bolts) Valve 5 (3mm hole between bolts) Valve 4 (3mm hole behind bolts) Valve 3 (6mm orifice) Valve 2 (12mm orifice) Valve 3 (6mm orifice) Valve 2 (12mm orifice) Valve 3 (6mm orifice) Valve 2 (12mm orifice) Valve 5 (between bolt gasket failure) Valve 4 (behind bolt gasket failure) Valve 5 (between bolt gasket failure) Valve 4 (behind bolt gasket failure) Valve 5 (between bolt gasket failure) Valve 4 (behind bolt gasket failure) Sensor config. Data Appendix 32 A B 32 A B 98 A B 98 A B 10 14 32 32 98 98 98 C C C C C C C B B B B B B B 98 C B 32 C B 32 C B 10 C B 10 C B Tests ALDAIR01 to 12 were not recorded for spectrum analysis because the levels of ultrasound produced by air releases was very high and the releases were easily detected. 36 Test Table A2. Details of water release trials Pressure Sensor config. Leak type Data Appendix (bar) ALDtest30 ALDtest31 ALDtest32 ALDtest33 ALDtest34 ALDtest35 ALDtest36 ALDtest37 ALDtest38 ALDtest39 ALDtest40 ALDtest41 ALDtest42 ALDtest43 Leaktest01 Leaktest02 Leaktest03 Leaktest04 Leaktest05 Leaktest06 Leaktest07 Leaktest08 Leaktest09 Leaktest10 (note 1) Valve 5 (3mm hole between bolts) Valve 5 (3mm hole between bolts) Valve 4 (3mm hole behind bolts) Valve 3 (6mm orifice) Valve 1 (valve Packing removed) Valve 5 (3mm hole between bolts) Valve 4 (3mm hole behind bolts) Valve 3 (6mm orifice) Valve 1 (valve Packing removed) Valve 5 (3mm hole between bolts) Valve 4 (3mm hole behind bolts) Valve 3 (6mm orifice) Valve 1 (valve Packing removed) Valve 2 (24mm orifice) Valve 5 (between bolt gasket failure) Valve 5 (between bolt gasket failure) Valve 5 (between bolt gasket failure) Valve 4 (behind bolt gasket failure) Valve 5 (between bolt gasket failure) Valve 4 (behind bolt gasket failure) Valve 3 (6mm orifice) Valve 2 (12mm orifice) Valve 3 (6mm orifice) Valve 3 (6mm orifice) 32 A C 32 A C 32 A C 32 32 A A C C 10 A C 10 A C 10 10 A A C C 98 A C 98 A C 98 98 A A C C 98 A C 98 B C 98 B C 98 B C 98 B C 32 B C 98 B C 32 32 B B C C 98 98 B B C C Note 1: For leaktest10 the release of water was continued until the water in the reservoir was exhausted and air came through. 37 Test Aldprop01 Aldprop02 Aldprop03 Aldprop04 Aldprop05 Aldprop06 Table A3. Details of liquid propane releases under vapour pressure Pressure Sensor config. Data Appendix Leak type (bar) 12mm orifice 7.7 B D 12mm orifice 7.7 B D 6mm orifice 7.7 B D 3mm orifice 7.7 B D Simulated failure 7.7 B D of 2mm gasket 38mm orifice 7.7 B D 38 Test ALDDIES01 ALDDIES02 ALDDIES03 ALDDIES04 ALDDIES05 ALDDIES06 ALDDIES07 ALDDIES08 ALDDIES09 ALDDIES10 ALDDIES11 Table A4. Details of Diesel releases Pressure Sensor config. (bar) Leak type Valve 5 (between bolt gasket failure) Valve 4 (behind bolt gasket failure) Valve 5 (between bolt gasket failure) Valve 4 (behind bolt gasket failure) Valve 3 (6mm orifice) Valve 5 (between bolt gasket failure) Valve 4 (behind bolt gasket failure) Valve 3 (6mm orifice) Valve 5 (between bolt gasket failure) Valve 4 (behind bolt gasket failure) Valve 3 (6mm orifice) Data Appendix 32 C E 32 C E 32 C E 32 C E 98 C E 98 C E 32 C E 98 C E 10 C E 10 C E 10 C E 39 Test ALDPROP08 ALDPROP09 ALDPROP10 ALDPROP11 ALDPROP12 ALDPROP13 ALDPROP14 ALDPROP15 ALDPROP16 Table A5. Details of nitrogen padded propane releases Pressure Sensor config. Leak type (bar) 3mm orifice 8.4 C 3mm orifice 6.9 C 6mm orifice 7.2 C 6mm orifice 7.2 C 2mm gasket 7.5 C failure 2mm gasket 7.4 C failure 12mm orifice 7.5 C 12mm orifice 6.8 C 38mm orifice 7.0 C 40 Data Appendix F F F F F F F F F Test ALDCONDS01 ALDCONDS02 ALDCONDS03 ALDCONDS04 ALDCONDS05 ALDCONDS06 ALDCONDS07 ALDCONDS08 ALDCONDS09 ALDCONDS10 ALDCONDS011 Table A6. Details of Diesel + 5% propane releases Pressure Sensor config. Leak type (bar) 66 C Valve 5 (between bolt gasket failure) Valve 5 (between bolt gasket failure) Valve 4 (behind bolt gasket failure) Valve 4 (behind bolt gasket failure) Valve 3 (6mm orifice) Valve 3 (6mm orifice) Valve 5 (between bolt gasket failure) Valve 5 (between bolt gasket failure) Valve 4 (behind bolt gasket failure) Valve 5 (between bolt gasket failure) Valve 3 (6mm orifice) Data Appendix G 66 C G 65 C G 65 C G 65 C G 65 C G 48 C G 48 C G 31 C G 34 C G 34 C G 41 9.2 APPENDIX B. FREQUENCY SPECTRA Air releases 2/3/05 It should be noted that the recorder overloaded during the measurements reported in Figures B2, B3, and B4. The resultant levels shown are therefore an underestimate of the actual values. Figure B1 Valve 4 32bar 1 0.1 forward 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 02_03_2005 Leak12.mat 0 to 30s Figure B2 Valve 4 98bar 1 0.1 forward 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 03_03_2005 Leak14.mat 0 to 45s 43 30000 35000 40000 45000 50000 Figure B3 Valve 5 32bar 1 0.1 forward 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 02_03_2005 Leak10.mat 0 to 46s Figure B4 Valve 5 98bar 1 0.1 forward 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 02_03_2005 Leak13.mat 0 to 107s 44 30000 35000 40000 45000 50000 9.3 APPENDIX C FREQUENCY SPECTRA Water releases 10/3/05 The spikes shown in the frequency analysis are due to pick up in the recording system. The peaks around 40kHz are the sound of the self-test of the leak detectors. Figure C1 Valve 1 10bar 1 0.1 centre 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 10_03_2005 L96k9.mat 0 to 10s Figure C2 Valve 1 32 bar 1 0.1 centre 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 10_03_2005 L96k5.mat 0 to 15s 45 30000 35000 40000 45000 50000 Figure C3 valve 1 98 bar 1 0.1 centre 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 10_03_2005 L96k13.mat 0 to 40s Figure C4 Valve 3 10 bar 1 0.1 centre 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 10_03_2005 L96k8.mat 0 to 16s Figure C5 Valve 3 (6mm) 32 bar 1 0.1 centre 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 10_03_2005 L96k4.mat 0 to 15s 46 30000 35000 40000 45000 50000 Figure C6 Valve 3 98 bar 1 0.1 centre 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 10_03_2005 L96k12.mat 0 to 14s Figure C7 Valve 4 10 bar 1 0.1 centre 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 10_03_2005 L96k7.mat 0 to 17s Figure C8 Valve 4 32 bar 1 0.1 centre 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 10_03_2005 L96k3.mat 0 to 20s 47 30000 35000 40000 45000 50000 Figure C9 Valve 4 98 bar 1 0.1 centre 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 10_03_2005 L96k11.mat 0 to 20s Figure C10 Valve 5 10 bar 1 0.1 centre 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 10_03_2005 L96k6.mat 0 to 18s Figure C11 Valve 5 32 bar 1 0.1 centre 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 10_03_2005 L96k1.mat 0 to 13s 48 30000 35000 40000 45000 50000 Figure C12 Valve 5 32 bar 1 0.1 centre 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 10_03_2005 L96k2.mat 0 to 16s Figure C13 Valve 5 98 bar 1 0.1 centre 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 10_03_2005 L96k10.mat 0 to 17s 49 30000 35000 40000 45000 50000 Water releases 8 and 9/8/05 Spikes shown on the frequency response are due to pick up on the recording system. The peaks around 40kHz are the sound of the leak detectors self test. Figure C14 Valve 2 32 bar release 08 1 0.1 behind valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 09_08_2005 Leak16.mat 0 to 27s Figure C15 Valve 3 32 bar release 07 1 0.1 behind valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 09_08_2005 Leak15.mat 0 to 56s 50 30000 35000 40000 45000 50000 Figure C16 Valve 3 100 bar release 09 1 0.1 behind valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 09_08_2005 Leak17.mat 0 to 53s Figure C17 Valve 4 32 bar release 06 1 0.1 behind valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 09_08_2005 Leak14.mat 0 to 38s Figure C18 Valve 4 100 bar release 04 1 0.1 behind valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 09_08_2005 Leak6.mat 0 to 59s 51 30000 35000 40000 45000 50000 Figure C19 Valve 5 32 bar release 05 1 0.1 behind valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 09_08_2005 Leak13.mat 0 to 66s Figure C20 Valve 5 100 bar release 01 1 0.1 behind valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 09_08_2005 Leak3.mat 0 to 59s Figure C21 Valve 5 100 bar release 02 1 0.1 behind valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 09_08_2005 Leak4.mat 0 to 49s 52 30000 35000 40000 45000 50000 Figure C22 Valve 5 100 bar release 03 1 0.1 behind valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 09_08_2005 Leak5.mat 0 to 46s 53 30000 35000 40000 45000 50000 9.4 APPENDIX D FREQUENCY SPECTRA Propane releases (11/08/2005) Figure D1 6mm orifice 1 0.1 at valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 11_08_2005 Leak88.mat 0 to 74s Figure D2 12mm orifice 1 0.1 at valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 11_08_2005 Leak87.mat 0 to 67s 55 30000 35000 40000 45000 50000 Figure D3 Simulated gasket failure 1 0.1 at valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 11_08_2005 Leak810.mat 0 to 59s Figure D4 1.5 inch orifice 1 0.1 at valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 11_08_2005 Leak811.mat 0 to 44s 56 30000 35000 40000 45000 50000 9.5 APPENDIX E FREQUENCY SPECTRA Diesel Releases – 1/11/05 As only short releases were made the frequency spectra have been taken from analysis of a recording segment containing the release. The note below the spectra details the file and period analysed. Figure E1 10 bar valve 5 (between bolts) ALDDIES 09 1 0.1 at valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 01_11_2005 LeakEB16.mat 19 to 20s Figure E2 10 bar valve 4 (behind bolt) ALDDIES 10 1 0.1 at valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 01_11_2005 LeakEB17.mat 24 to 25s 57 30000 35000 40000 45000 50000 Figure E3 10 bar valve 3 (6mm orifice) ALDDIES 11 1 0.1 at valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 01_11_2005 LeakEB18.mat 25 to 29s Figure E4 32 bar valve 5 (between bolts) ALDDIES 01 1 0.1 at valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 01_11_2005 LeakEB8.mat 0 to 52s Figure E5 32 bar valve 4 (behind bolt) ALDDIES 02 1 0.1 at valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 01_11_2005 LeakEB9.mat 27 to 29s 58 30000 35000 40000 45000 50000 Figure E6 32 bar valve 5 (between bolts) ALDDIES 03 1 0.1 at valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 01_11_2005 LeakEB10.mat 23 to 25s Figure E7 32 bar valve 4 (behind bolt) ALDDIES 04 1 0.1 at valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 01_11_2005 LeakEB11.mat 16 to 19s Figure E8 98 bar valve 3 (6mm orifice) ALDDIES 05 1 0.1 at valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 01_11_2005 LeakEB12.mat 19 to 22s 59 30000 35000 40000 45000 50000 Figure E9 98 bar valve 5 (between bolts) ALDDIES 06 1 0.1 at valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 01_11_2005 LeakEB13.mat 15 to 16s Figure E10 98 bar valve 4 (behind bolt) ALDDIES 07 1 0.1 at valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 01_11_2005 LeakEB14.mat 35 to 38s Figure E11 98 bar valve 3 (6mm orifice) ALDDIES 08 1 0.1 at valves 0.01 right left PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 01_11_2005 LeakEB15.mat 22 to 25s 60 30000 35000 40000 45000 50000 9.6 APPENDIX F FREQUENCY SPECTRA Propane padded nitrogen releases 17/11/05 The results from the left microphone have been removed because of drifting of the microphone sensitivity over the day. Figure F1 3mm orifice 8 bar ALDPROP08 1 0.1 at valves 0.01 right PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 17_11_2005 Leak910.mat 0 to 49s Figure F2 3mm orifice 8 bar ALDPROP09 1 0.1 at valves 0.01 right PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 17_11_2005 Leak911.mat 0 to 49s Figure F3 6mm orifice 8 bar ALDPROP10 1 0.1 at valves 0.01 right PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 61 25000 Frequency (Hz) TEAC data 17_11_2005 Leak912.mat 0 to 39s 30000 35000 40000 45000 50000 Figure F4 6mm orifice 8 bar ALDPROP11 1 0.1 at valves 0.01 right PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 17_11_2005 Leak913.mat 0 to 35s Figure F5 12mm orifice 8 bar ALDPROP15 1 0.1 at valves 0.01 right PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 17_11_2005 Leak918.mat 0 to 34s Figure F6 38mm orifice 8 bar ALDPROP16 1 0.1 at valves 0.01 right PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 17_11_2005 Leak919.mat 0 to 42s 62 30000 35000 40000 45000 50000 Figure F7 Simulated gasket failure 8 bar ALDPROP12 1 0.1 at valves 0.01 right PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 17_11_2005 Leak914.mat 0 to 47s Figure F8 Simulated gasket failure 8 bar ALDPROP13 1 0.1 at valves 0.01 right PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 17_11_2005 Leak915.mat 0 to 51s 63 30000 35000 40000 45000 50000 9.7 APPENDIX G FREQUENCY SPECTRA Diesel plus 5% propane releases 17/11/05 The results from the left microphone have been removed because of drifting of the microphone sensitivity over the day. The background level is shown in Figure G11. Figure G1 Valve 3 (6mm orifice) 32 bar ALDCONDS11 1 0.1 at valves 0.01 right PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 17_11_2005 Leak930.mat 6 to 7s Figure G2 Valve 3 (6mm orifice) 32 bar ALDCONDS05 1 0.1 at valves 0.01 right PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 17_11_2005 Leak924.mat 49 to 51s 65 30000 35000 40000 45000 50000 Figure G3 Valve 3 65 bar ALDCONDS06 1 0.1 at valves 0.01 right PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 17_11_2005 Leak925.mat 9 to 13s Figure G4 Valve 4 31 bar ALDCONDS09 1 0.1 at valves 0.01 right PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 17_11_2005 Leak928.mat 9 to 11s Figure G5 Valve 4 65 bar ALDCONDS04 1 0.1 at valves 0.01 right PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 17_11_2005 Leak923.mat 8 to 10s 66 30000 35000 40000 45000 50000 Figure G6 Valve 5 34 bar ALDCONDS10 1 0.1 at valves 0.01 right PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 17_11_2005 Leak929.mat 11 to 12s Figure G7 Valve 5 48 bar ALDCONDS07 1 0.1 at valves 0.01 right PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 17_11_2005 Leak926.mat 18 to 20s Figure G8 Valve 5 48 bar ALDCONDS08 1 0.1 at valves 0.01 right PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 17_11_2005 Leak927.mat 6 to 7s 67 30000 35000 40000 45000 50000 Figure G9 Valve 5 66 bar ALDCONDS01 1 0.1 at valves 0.01 right PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 17_11_2005 Leak920.mat 8 to 10s Figure G10 Valve 5 66 bar ALDCONDS02 1 0.1 at valves 0.01 right PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 30000 35000 40000 45000 50000 Frequency (Hz) TEAC data 17_11_2005 Leak921.mat 34 to 36s Figure G11 Background level 1 0.1 at valves 0.01 right PSD (Pa²/Hz)² 0.001 0.0001 1E-05 ` 1E-06 1E-07 1E-08 1E-09 1E-10 1E-11 0 5000 10000 15000 20000 25000 Frequency (Hz) TEAC data 17_11_2005 Leak920.mat 2 to 4s 68 30000 35000 40000 45000 50000 9.8 APPENDIX H. DETAILS OF ACOUSTIC EQUIPMENT USED Equipment TEAC LX1-10 (MI P8IO) data recorder B&K 4226 multifunction acoustic calibrator Serial Number 107564 B&K 4136 microphone B&K 2169 preamplifier B&K 2804 power supply 873753 0990257 761775 B&K 4136 microphone B&K 2169 preamplifier B&K 2804 power supply 1252964 761505 761755 B&K 4135 microphone B&K 2169 preamplifier B&K 2804 power supply 1890291 418630 684344 B&K 4135 microphone B&K 2169 preamplifier B&K 2804 power supply 962448 0990252 684342 B&K 2169 preamplifier 608004 B&K 1617 filter set B&K 2636 measuring amplifier 69 Published by the Health and Safety Executive 06/07 Health and Safety Executive Measurement of acoustic spectra from liquid leaks Acoustic leak detection is being used increasingly in the offshore industry as a means of detecting leaks of flammable substances on offshore platforms. Rather than relying solely on human intervention or the uncertain and inefficient dispersion of gas to the detectors, acoustic leak detectors (ALD) detect a leak through the ultrasonic sound produced by the escaping gas jet. These sensors are generally designed to detect leaks of gaseous products and have been shown to perform well under the conditions experienced on offshore platforms. HSE recognises the benefits of using such devices possibly in conjunction with line-of-sight sensors to detect gaseous releases. This report and the work it describes were funded by the Health and Safety Executive (HSE). Its contents, including any opinions and/or conclusions expressed, are those of the authors alone and do not necessarily reflect HSE policy. RR568 www.hse.gov.uk