Biofuel Feedstock Crops Thomas G Chastain CROP 200 Crop Ecology and Morphology Biofuel Feedstock Crops • Feedstock crops provide the source of raw materials used in the production of biofuels. Seed oils serve as the feedstock for biodiesel while starch in seeds or cellulose in crop stems can serve as the feedstock for ethanol. • Feedstock crops also produce valuable by-products that can be used in animal feed or as biopesticides, soil amendments or other products. The crops themselves may also serve as potent agents of pest control. Weed control with mustards and canola compared to chemical control or no treatment (University of Idaho photo) Biofuel Feedstock Crops – Ethanol and Butanol • Starch stored in the endosperm of seeds such as corn is the primary source of ethanol and butanol in the US. • The starch is first converted to sugars and is then fermented to form alcohol. Oregon is not a major producer of corn. Amylose (Starch) Ethanol Butanol Biofuel Feedstock Crops – Ethanol • Ethanol can be made from a variety of feedstock crops. Most often ethanol is made from starches stored in seed but it can also be made from starch stored in potato tubers, or from sugars stored in fruit, sugarcane or sugarbeets. • Ethanol can also be made from cellulose found in the straw of small grain cereal crops or grass seed crops. Biomass from dedicated energy crops such as switchgrass could also be used to make ethanol. Baled grass seed straw (top – TG Chastain photo), switchgrass (bottom – USDA photo) Biofuel Feedstock Crops - Biodiesel Glycerol Transesterification + Methanol Biodiesel + Glycerol Catalyst Fatty Acid Triacylglycerol (oil) Biodiesel is a mono alkyl ester of fatty acids from plant or animal derived oils Biofuel Feedstock Crops - Biodiesel • The oil is extracted from the seed by crushing using a cold-press or by expeller-pressing followed by solvent extraction. • The meal remaining after oil extraction, if edible (low glucosinolates), is a highprotein source of livestock feed. The meal can also be used as a soil amendment, and as a biopesticide. Commercial oil seed crusher at Willamette Biomass Producers at Rickreall (TG Chastain photos) Canola meal after oil extraction by pressing Biodiesel Feedstock Crops World Production Statistics for Oil Seed Crops Crop Seed Production Crop Harvested Seed Yield million metric tons million hectares metric tons/ha Soybean 241.8 105.0 2.30 Canola 65.1 34.0 1.91 Sunflower 37.4 24.8 1.51 Flax 2.1 2.5 0.84 Safflower 0.83 0.99 0.84 Mustard 0.49 0.61 0.80 These oil seed crops can be harvested for either food grade oil or for biodiesel feedstock Source: FAO 2014 Canola • Canola (Brassica napus var. napus, B. rapa) is an oil seed crop in the mustard family. Oil concentration in the seed often exceeds 45%. 19 pounds of canola seed will yield one gallon of oil. • Origin. Canola was bred for human consumption from rapeseed - first released in Canada in the 1970s. Canola is different from rapeseed in that the oil is low in erucic acid and the meal is low in glucosinolates. Winter canola crop in flower near Corvallis (above), and seed (right). TG Chastain photos Canola • Production. Time of planting is important as later plantings give poorer seed yields. • In the Willamette Valley, winter canola will yield 2,500 to 4,800 lbs per acre, spring canola will yield 2,000 lbs per acre. Oil yield ranges from 80 to 200 gallons of oil per acre. • Seed yields are lower in eastern Oregon than in the Willamette Valley as the statewide average is 2,200 lbs/acre. The US average canola yield was 1748 lbs/acre in 2013. Time of planting effects on canola seedlings. TG Chastain photo Canola • Production. Canola seed production is responsive to nitrogen fertilizer in the spring, but lodging of the crop can reduce seed yield when May rainfall is high (Ferguson et al., 2015). Canola • Crop Improvement. Canola was developed by conventional breeding methods, but in recent years, many of cultivars have been developed for herbicide resistance (GMO). • Contrary to popular belief, not all canola is a GMO crop – both GMO and non-GMO canola exists. Non-GMO cultivars are available and have seed yields that are equivalent or better than GMO types. • Canola production can co-exist with production of specialty seed provided that reasonable and prudent safeguards are implemented. Growing non-GMO canola (Brassica napus) in areas isolated from where specialty seed crops are grown will minimize the potential risk of crossing. Winter canola cultivar evaluation trials at Hyslop Farm (TG Chastain photo) Mustard • Mustard (Brassica hirta, B. juncea and Sinapis alba) are oil seed crops in the mustard family. Oil concentration in the seed is 27%. • Origin. Native of Europe, mustards have been in cultivation for more than 4000 years. Yellow mustard (Sinapis alba) crop in flower (top), yellow mustard seed (right). TG Chastain photos Mustard • Production. Mustard is a very competitive crop and has less need for weed control than many other crops. The crop grows quickly and matures about 4 months after planting. • Seed yield for the crop ranges from 1,500 to 2300 lbs./acre in the Willamette Valley. • Sinapis alba will not cross with vegetable seed crops making it a good candidate for production in the Willamette Valley. • High glucosinolate content in meal makes the meal unsuitable for animal feed, but may have a place in the natural pest control market. Mustard seedling (top), closed crop canopy (bottom). TG Chastain photos Sunflower • Sunflower (Helianthus annuus ) is an oil seed crop in the sunflower family. Oil concentration in the seed ranges from 40 to 50%. • Origin. Native to Central America, sunflower has been in cultivation for about 4000 years, and has been grown for oil since the 1700s. • Production. Sunflower oil yields under irrigation range from 90 to 100 gallons per acre. Sunflower head (TG Chastain photo) Safflower • Safflower (Carthamus tinctorius) is an oil seed crop in the sunflower family. Oil concentration in the seed ranges from 30 to 50%. • Origin. Native to Asia and Africa, safflower has been cultivated for dyes since the time of the ancient Egyptians, but production for oil began in the 1950s. • Production. Safflower oil yields under irrigation range from 57 to 94 gallons per acre. Without irrigation, safflower oil yields can drop to 12 gallons per acre. Safflower flower (top) and plants (bottom) TG Chastain photos. Flax • Flax (Linum usitatissimum) is an oil-seed crop in the flax family (Linaceae). Oil concentrations in the seed range from 30 to 45%. Flax seed is the source of linseed oil and used in paints, stains, and linoleum flooring. • Origin. The crop was domesticated about 7000 years ago and was grown by the ancient Egyptians. • Production. Spring and winter annual crops. Spring flax yields range from 600 to 1500 lbs/acre while winter flax can yield up to 2000 lbs/acre. Fiber flax is grown for linen fabrics. Flax flowers near Corvallis (Garbacik photo-above), seed (left). Camelina • Camelina. Originating in Europe, Camelina sativa is a spring annual oil seed crop in the mustard family. Seed is very small, about 1/3 the size of canola. Oil concentration in the seed is 40%. • Production. Seed yields range from 1000 to 1800 lbs./acre in the Willamette Valley. Production of camelina is now underway in several western states including Montana and Oregon. Camelina pods (TG Chastain photos) Camelina • Camelina seed yield increases in response to applied nitrogen fertilizers when there is adequate water available (Wysocki et al., 2013). Camelina seed (TG Chastain photo). Soybean • Soybean (Glycine max) is a summer annual member of the legume family. The most important oil seed crop in the US and world-wide. Oil concentration in the seed is a comparatively low 20%. • Extensive work has been done by OSU to determine the adaptation of soybeans to Oregon conditions. Low oils yields, late maturity, and need for irrigation limit the utilization of soybean in western Oregon, while some production may be possible under irrigation in parts of eastern Oregon. Soybean pods and seed (left – USDA photos). Biofuel Feedstock Crops Biodiesel – Can we grow enough feedstock in Oregon? Oregonians consume 800 million gallons of diesel fuel annually. Biodiesel grade 100 gallons/acre 200 gallons/acre B20 (20%) 1.5 million acres 800,000 acres B5 (5%) 400,000 acres 200,000 acres B2 (2%) 160,000 acres 80,000 acres These estimates do not include production of biodiesel from waste products (WVO = waste vegetable oil). Note – total crop acreage in Oregon is 4.4 million acres.