ERAMET RESEARCH 40 years in R&D serving extractive metallurgy of non-ferrous metals DES ALLIAGES, DES MINERAIS ET DES HOMMES. contact.ErametResearch@erametgroup.com ERAMET GROUP: TARGETED STRATEGIC POSITIONNING A specialist in alloying metals used for up range metallurgy and steelmaking. An integrated Group from ore through to finished parts and recycling, with key strengths: World-class deposits High-tech metallurgical production capacities Strategy centered on world-class R&D. Developments in progress or under study in new, high-potential metals, e.g. zircon, titanium dioxide, lithium, niobium, rare earths… Businesses and skills that position the Group as the mining and metallurgical partner for strategic industries and new business sectors. A specialist in alloying metals on the leading edge of mining and conversion technologies ERAMET RESEARCH in a few words Fully owned subsidiary of ERAMET (main R&D Centre of the Group) Our integration within the Group as an important role player in the fields of mining and metallurgy is a gauge for the strength of the research center. 40 years experience in R&D Successful R&D followed by industrial implementations in mining , beneficiation and metal producing plants, either in continuous improvement or in breakthrough innovation. 170 scientists and technicians gathered in one site just 20 minutes outside of Paris Documentation, test laboratories, pilot installations, analytical equipment, mineralogical and computational modeling facilities ; all competencies and means to carry out projects are present in Trappes. Proximity with ERAMET INGENEERING also based in Trappes Exchange between R&D and mining engineering to plan and design the best adapted solutions An advantage when the projects evolve from the research into the industrialization phase, including a complete network of service providers. An organization serving performance and innovation Our missions To develop and to optimize the processes and the products of our clients In mines In metallurgical factories By running for them R&D programs By helping them during commissioning and ramp-up phases Taking into account safety and sustainable development aspects To conduct technical assistance missions Audits during and after installation of equipment. Expert missions in metallurgical factories. To guaranty a permanant pool of scientific expertise A high level of academic requirements in selecting staff Partnerships with the best engineering schools and universities. An integration and education of young engineers and researchers in mineral processing An active participation in the international science and technology network We carry out studies from laboratory to industrial scale Documentation, bibliography Numerical and Physical Modelling Analysis and Physico-chemical characterizations Laboratory tests Internal/external pilot tests Plant tests Support to engineering teams NiCl2 dihydrate compacting-grinding pilot Support to industrial ramp up and further optimization A R&D center structured around various poles of competencies … Mineralogy, Geology and Product Applications Ore dressing Development of products adapted to client needs Preparation and Beneficiation Mining and extractive Metallurgy Pyrometallurgy Hydrometallurgy Treatment of minerals by elevated heat Treatment of minerals by means of liquid agents … with the expert assistance of transversal departments Chemical Analysis HSE Design and construction of pilots Computer Modelling and Simulation ORE BENEFICATION - Expertise Laboratory studies and pilot plants to valorize raw materials to develop innovative beneficiation processes or to optimize existing industrial units (technical assistance). Specialized on all levels of process mineralogy : Comminution: attrition, crushing and grinding Particle size classification : scrubbing / screening /sieving/ cycloning ….. Concentration : density separation/flotation/magnetic separation Solid/liquid separation : flocculation/filtration Process characterization: sample preparation/mass balance/process simulations and optimization All studies are performed with chemical analyses and mineralogical characterizations performed at ERAMET RESEARCH. 9 qualified persons including 4 graduate engineers ORE DRESSING - Equipment 3 laboratories and 2 pilots allow to perform classification and beneficiation tests on a large variety of minerals or recycled materials at different scales ranging from a few grams to several tons Crushing : Cone and jaw crushers, MMD … Milling : Rod mills and ball mills, attritioning cells , SMD… Densimetric separation : shaking tables, jigs, spiral classifier and dense liquor . Flotation : 5 flotation cells including newest Outotec lab cell. Magnetic separation : high and low intensity magnetic separators (dry and wet). Sample preparation : Sampling tower to obtain representative test material to perform representative chemical analyses (tons to grams). HYDROMETALLURGY – Expertise and competencies Lab and pilot studies to treat ores, metallic concentrates or recycled materials, including: Chemistry of inorganic and organic solutions : Leaching in chloride, sulfate, ammoniacal, basic medium, solvent extraction and ion exchange resin, purification or metal recovery by precipitation, cementation, crystallization Solid-liquid separation : Flocculation, thickening, centrifugation, filtration (vacuum, pressure) Electrochemistry : Electrowinning, electrorefining, membranes technology, electro dialysis Environment : Gaseous emission treatment, Wastewater treatment, solid residue neutralization Modelling : Mass balance (USIMPAC), Solvent extraction 25 graduate engineers including 5 experts and 21 technicians HYDROMETALLURGY- Equipment 5 Laboratories Fume hoods(5) : acid or basic, toxic gas (SO2, Cl2), with a vent gas washing tower of 4500 m3/h Leaching hoods(16) Specific solvent hoods(4) Solid/liquid separation equipment: Centrifugation, Filtration, Flocculation – decantation Roasting furnace up to 200 L 2 piloting halls From 1L to 5 m3 tanks Continuous pilot facilities at 50 L/h flow rate including 50 various reactors, pumps, thickeners, belt filter and filter press, mixer-settlers, instrumentation and control system (flow meters, pH, redox, temperature,..) Electrolysis and electrodialysis cells HYDROMETALLURGY– Some historical achievements Projects Zn hydrometallurgy: calcine leaching, jarosite, goethite precipitation, purification by cementation, increase of current efficiency Mixed Cu-Zn-Pb ore: sulfide leaching in chloride medium, solvent extraction, Pb electrolysis Specialty metals: recovery and purification of In, Ge, Ga from concentrates by leaching, distillation, cementation, electrowinning and electrorefining Spent catalysts: recovery of Mo, V, Ni, Co, Rare Earth Ni hydrometallurgy: complete treatment of Ni-Co laterite ore Recovery of Nb, Ta, U, Rare Earth from a mixed ore Lithium recovery from brine Environment: cyanide removal from effluent, standard leaching tests on solid residues PYROMETALLURGY- Expertise et competencies Running of electric furnaces Charge preparation : pelletizing, sintering, … Process simulation and furnace applications Thermal and materials flows – reactions kinetics – interface reactions – pre reduction Process control Technologies: refractories – insulated/freeze lining , electrodes and power supply, off-gas cleaning …/… Tapping and casting systems – granulation Refining MOR – Bessemer – Pierce-Smith – AOD …/… 11 graduate engineers of which 3 experts and and 6 experienced technicians PYROMETALLURGY - Equipment Laboratory 9 laboratory furnaces (1200°C to 1750°C) allowing a wide range of tests: Electric resistivity of slags, slag viscosity, formation of crowns in rotary kilns , corrosion of refractories, smelting and reduction of ores by means of anthracite or coke, injection of reactants into the metal, studies on the formation of freeze linings, calcination of ores, studies on the pre reduction of ores …/… Continuous analysis of process gases (CO, CO2, O2, H2) ATD/ATG/DSC – enthalpy, entropy, reaction kinetics Piloting hall 2 rotary kilns - 220 KW et 1 MW – drying and calcination – designed for co/counter current operations Vertical sintering station – reducing or oxidizing conditions BZ test Station: low impedance - 36kA, 1.3MW Electric arc furnace, AC, high grade ore HZ test Station - 12kA, 0.7MW Electric arc furnace , AC, low grade ore FCE furnace - 6kA, 200kW Can be quenched - examination of in-situ metallurgical evolutions Induction furnace – 150 kW, 3KHz – general tool for studies on slags or metals PRODUCTS / APPLICATIONS - Expertise and competencies Missions Guidance of clients in the development and improvement of commercial products Evaluation of market needs , in conjunction with commercial and marketing units Studies on product production paths to fulfill the product requirements Improvement of existing products or development of new products Competences Chemical engineering (low and medium temperatures), electrochemistry Production of samples of a representative size Integration of new or improvement of existing processes in production sites 3 graduate engineers of which 1 expert and 2 experienced technicians MINERAL AND MATERIAL CHARACTERIZATION Competences and expertise in various domains Geology, Mineralogy and Petrology Petrography and Crystallography Ore reserve evaluation and mineral processing orientation Geochemistry of natural rocks Material sciences Metallography (steel and alloys) Characterization bring essential information for R&D projects with pertinent industrial results Identification of ore minerals and concentrations is essential for ore resources evaluation Determine mineral association and liberation facilities to model mineral processing Identify and localize penalizing elements to maximize its elimination and add value to the final product Observation of microstructures and textural orientations able to determine metal defects and prevent failures 5 graduate engineers including 2 experts and 3 experienced technicians MINERALOGICAL CHARACTERIZATION - Equipement X-ray diffraction (XRD) Scanning electron microscopy (SEM with field emission gun) for high resolution imaging in secondary electrons (SE) and back-scattered electrons (BSE) Energy dispersive spectroscopy analyses (EDS) for elementary mapping Energy Back Scattered Diffraction (EBSD) for crystallographic orientation and detection of metal defects in tools Qemscan automated mineralogy system for statistical grain counting, shape of particles, mineral proportions and liberation ratios Electron Microprobe Analyses (EMPA) to determine quantitative mineral composition and trace element research (spot size resolution 1µm and very low detection limits <0.1wt%) Environmental SEM with low vacuum system under water-pressure control for life and hydrated material studies Laser Particle Sizer CHEMICAL ANALYSIS – Competencies and Expertise Competencies Element analysis of liquid and solid samples (major, minor, traces) of ores, slags and sinters, metals, residues, salts, hydrometallurgical samples, …. Mercury analyses Carbon sulfur analysis in ores slags and metals Diverse titration tests (pHmetry, potentiometry, volumetry,…) Gravimetry, colorimetry, distillations, analysis of anions…. 20 qualified chemists (scientists, engineers and technicians) CHEMICAL ANALYSIS – Equipment Analytical technics for mono element analyses AAS – Atomic absorption spectrometry AA220 EAAS – Electro-thermic absorption spectrometry AA220Z Mercury analyzer - CETAC M6100 Analytical techniques for multi elements analyses ICP AES – Atomic emission spectrometry ICP (3 units: VistaPro, 720 ES et 730 ES) ICP MS – Mass spectrometry ICP 820 MS XRF – X-ray fluorescence spectrometry – AXIOS Minerals equipped for diverse applications (glass beets) with special software OMNIAN (semi-quantitative analyses) Others C,S analyzer - EMIA 320V Spectrophotometry UV-Vis - Cary 50 Ionic Chromatography - Metrohm 881 Compact IC Pro Potentiometric titration, ph-metry Sample preparation technologies jaw crusher, vibration crusher, centrifugal crusher, blade crusher, and various sample dividers,….) NUMERICAL MODELLING – Expertise and Competencies Dynamic simulation of reactors Thermodynamics Procédés Fluid mechanics and heat tranfer Process simulation Model Simulation Software development €↓ COMPUTATIONAL MODELLING - Equipment 3D work-stations + CRAY super-computer World class modelling softwares Software Version Developer / Vendor Applications FLUENT V13 ANSYS, Inc. (USA) GAMBIT 2.4.6 ANSYS, Inc. (USA) Geometry – Meshing MTDATA 4.81 National Physical Laboratory (UK) Thermodynamics MATLAB R2013 Mathworks (USA) Scientific Computing SCILAB 5.4.1 Scilab Enterprises (France) Scientific Computing THERMO-CALC S Thermo-Calc Software AB (Sweden) Thermodynamics Fluid Dynamics (CFD) Transport phenomena Model Simulation €↓ MAINTENANCE department– Competencies et Expertise Missions Preparation of piloting facilities Development and technical improvement of equipment Technical support to metallurgical projects Design and commissioning of: special machines, test stations, laboratories Competencies Mechanics/ piping, / Plastics, …/… Electricity, Automation, Instrumentation / Thermography Reliability studies (FMEA) and maintenance plans for equipment Project management for new plant facilities 2 engineers and 13 technicians MAINTENANCE department – Equipment Software Autocad LT Solidworks (2014) Caneco Step 7 Supervision iFix Mechanical workshop and electricity TIG welding Various type of machining equipment … ERAMET INGENIERIE – Missions and services Our proximity to the engineering teams is complementary to your R&D projects. ENGINEERING SERVICES (for investments up to 150 M€) Scoping studies Preliminary Feasibility Studies Feasibility Studies (sometimes referred to as Bankable Feasibility Studies) Engineering Procurement and Construction Management services (EPCM) ASSISTANCE Assistance to Owner, i.e. Project Management Consulting Technical audits Process General engineering disciplines Technical assistance 56 employees, project managers, specialists engineers and engineering technicians . ERAMET'S SUSTAINABLE DEVELOPMENT POLICY IS BASED ON FOUR PILLARS 1 Protecting ERAMET employees and involving them in our actions Preserving the health and safety of our employees Promoting professional development and encouraging social dialogue Making our employees active players in terms of sustainable development 2 Managing the risks and impacts on health and the Environment Controlling the impacts of industrial activities on health and on the environment Reducing energy consumption and combating climate change Improving the use of natural resources and increasing recycling 3 Seizing the opportunities offered by Sustainable Development Integrating SD into our innovation policy and the group's diversification Highlighting the environmental benefits associated with the use of our products and reducing risks to humans and the Environment Including SD in procurement practices 4 Maintaining a relationship of trust with stakeholders Developing consultation and meeting the expectations of Stakeholders Contributing to economic and social development of the communities Ensuring good governance of the group's companies Sharing our challenges and achievements Conclusion - ERAMET Research’s strengthes : Unique place grouping experts in all areas from mine to metallurgy and recycling R&D oriented toward search of industrial solutions adapted to customers’ needs Closed relationships with our industrial customers Strong international networking Universities International R&D centers (FFF-SINTEF, CSIRO, MINTEK, MEFOS, GTK) Equipment suppliers Flexibility and ability to respond to many needs regardless of budget or studied phenomena Ability to perform tests on all scales (laboratory, continuous pilot) World class characterization equipment