Indian Fuel Cell Activity DST-EPSRC Fuel Cells Initiative Scoping Workshop Sep.15-17, 2010, Chennai , India Organized by Centre for Fuel Cell technology, ARCI Background Major Concerns in the Energy Sector in India For India’s continued growth we need among other things - Provision of reliable distributed power (particularly for remote locations, agricultural sector and urban areas ) - Energy for Transport - Energy security and air pollution • Growing gap between demand and supply of commercial energy: electricity, oil and gas. • Increased oil imports • Indian Government is committed to renewable energy technologies including hydrogen and fuel cells • Several research institutions, educational institutions & industries are involved in implementing various projects on hydrogen energy technologies 2 K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai Sep.15-17, 2010 Major Hydrogen and Fuel cell activities in India MNRE to establish the National Centre for Hydrogen Energy and Fuel Cell 1990’s UoR TU IIT-D,TERI IIP,NPL,ACME, BPCL, IOCL CSMCRI BHU IIT-K Tata/Plugpower CGCRI, Arora Matthey IIT--Kr, BESUS, CMERI, IIT-G AIIST TU,assam IMMT NMRL, IIT-B,NCL,PU, BARC, RIL, Digitronics, Bloom Energy IISc NAL , ISAC, REVA, IE, Bloom Energy Daimler,GE BHEL, IICT,JNTU, UoH,Andhra Uni. , Falcon Ind., Assam Carbon VSSC C-DAT TATA, Sued chemie Present Very few industries •Traders not included 3 K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai IIT-M, CECRI, SSF, MCRC NCCR,, IGCAR, CFCT , Anna Uni,SU, Alagappa Univ., KPas, Alacrity,HEB,TVS, AL, M&M, Sai energy, Ingsman , Nissan Renault, Sep.15-17, 2010 AU Anna University BESUS Bengal Engineering and Science University, Shipur BHU Banares Hindu University IISc Indian Institute of Science IIT-D Indian Institute of Technology-Bombay IIT-G Indian Institute of Technology-Guwahati IIT-K Indian Institute of Technology-Kanpur IIT-Kr Indian Institute of Technology-Karagpur IIT-M Indian Institute of Technology-Madras JNTU Jawaharlal Nehru Technology University PU Pune University SU Satyabhama University TU Thaper University TU-Assam Tezpur University , Assam UoH University of Hyderabad UoR Univeristy of Rajasthan AISST Advanced Institute of sceinec, Assam BARC Bhabha Atomic research Centre C-DAC Centre for advanced computing CECRI Central Electrochemical Research Institute CFCT-ARCI Center fro fuel Cell Technology, ARCI CGCGRI Central Glas and Ceramic Research Institute CMERI Central Mechanical Engineering Research Institute CSMCRI Central Salt and Marine Chemical Research Institute IGCAR Indira Gandhi Centre for Atomic Reaserach ISAC Indian Space Research Organisation ISRO Indian Space Research Organisation NCL National Chemical laboratory NPL National Physical Laboratory TERI The Energy Research Institute VSSC Vikram Sarabhai Space Centre 6 AL Ashok Leylands ACME ACME Power BPCL Bharat Petroleum Corporation Ltd. HEB IOCL M&M RIL High Energy Batteries Indian Oil Corporation Mahindra and Mahindra Reliance Industries TVS TVS Motors K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai Sep.15-17, 2010 Indian Scenario R&D support for Hydrogen Technology Research from Indian Government Agencies UGC AICTE MHRD DNES – MNES – MNRE – NHEB DST- SERC ( academic research ), TIFAC, IRHPA CSIR – Net work programs , NMITLI (from 2001) Strategic sectors - Internal programs The 11th Five plan of various organisations have included Hydrogen research as one of the priority areas. BRNS ( DAE) RESPOND ( ISRO) DRDO Venture funds (!!) – PACER 7 K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai Sep.15-17, 2010 India initiatives in Hydrogen Energy National Hydrogen Energy Board (NHEB ) National Hydrogen Energy Road Map (NHERM) – 2003 - 2006 The NHERM has identified research, development and demonstration efforts to be undertaken in the country for bridging the technological gaps in different areas of hydrogen energy, including its production, storage, transportation and delivery, applications, safety, codes and standards and capacity building for the period up to 2020. Keeping in view the present status of development of hydrogen energy, the NHERM has recommended two major initiatives for promoting the use of hydrogen as a fuel for Green Transportation (Green Initiative for Future Transportation-GIFT) and Green Power Generation (Green Initiative for Power Generation-GIP) 8 K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai Sep.15-17, 2010 India initiatives in Hydrogen Energy By 2020 One Million Hydrogen Fueled Vehicles (mostly two and three wheelers) and 1,000 MW aggregate hydrogen based power generation capacity Projected Investment requirement : Rs.25,000 crores for creating the required hydrogen supply infrastructure R,D&D investment : Rs.1,000 crores . The Road Map is a public-private partnership driven process. 9 K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai Sep.15-17, 2010 Indian Scenario Publications - Indian Scenario* Number of fuel-cell papers from different countries, 1983– 2007 [data from Web of Science 1983–2007]. 10 K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai Source:A historiographic analysis of fuel-cell research in Asia – China racing ahead-S Arunachalam and B. Viswanathan,CURRENT SCIENCE, VOL. 95, NO. 1, 36-49, 10 JULY 2008 Sep.15-17, 2010 10 Indian Scenario Knowledge dissemination ,Training Academic Institutions – Course work , Student Projects, Workshop & Conferences Research organizations – Student projects , Ph.D programs SAEST – Intl. Conference on Electrochemical Power Systems – every 2 yrs - National meetings Other meetings/conferences ( e.g., Green Power , Fucetech2009, WHTC 2009, Renewable energy conferences ) 11 K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai Sep.15-17, 2010 Indian Scenario Technology Status – Fuel cells Alkaline Fuel cells Organizations CECRI $ IIT-D, IIT-M BHEL, Birla, Bajaj Nature of work Early 80’s Basic Science ???? $The first Indian paper in this field came from CECRI [R. Pattabhiraman, V. K. Venkatesan and H. V. K. Udupa, 1981] 12 K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai Sep.15-17, 2010 Indian Scenario Technology Status – PEMFC and DMFC Organizations 13 Nature of work IIT-M, NCCR, IIT-B, IIT-G, IIT-K, IIT-Kr ,IISc, BESUS,CECRI, NCL, NPL, Anna University, UoH, and many other univs. • Basic Science , • Catalysts, Membrane • Modeling SSF, BHEL , CECRI, CFCT- ARCI, ISRO Labs & Def. labs, HEB • Stack and System, • Application demonstration ACME ( AFC & PEMFC) , Tatas, Birla , Bajaj , M&M ,TVS, REVA, BPCL, IOCL, NTPC , NMRL, IITs • System integration using bought out stacks for demonstration • Application Simulation studies ARCI, NCL,NPL, Arora Matthey • Materials ( large scale ) K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai Sep.15-17, 2010 Indian Scenario Technology Status – PEMFC and DMFC Materials Organizations Nature of work Catalyst IITM, NCCR IITD, CFCT-ARCI NCL BESUS •Shape dependent electro catalyst •High aspect ratio nano scale multifunctional materials •Development of non-noble metal catalyst for ORR( Ru, Pd) • Metal carbides • Au–MnO2/MWNT and Au–ZnO/MWNT •Cu- Ni-Alloy catalyst, Conducting polymer containing catalyst Catalyst support IIT-M , CFCT-ARCI NCL Modified CNT Metal carbides Ti mesh substrate • Nitrogen doped graphene and hybrid carbon nanostructures • Nitrogen-doped multi-walled carbon nanocoils • Multi Walled Carbon Nano tubular Coils BipolarK S Dhathathreyan CFCT-ARCI, NPL, Fuel NCL,Cells SSFInitiative Resin impregnated, exfoliated graphite, Metal, , DST-EPSRC Sep.15-17, 2010 14plates Scoping Workshop, Chennai resin bonded Indian Scenario Technology Status – PEMFC and DMFC Materials Membrane Organizations CECRI, NCL , UoH, AU CFCT-ARCI, NMRL , CSMCRI CIPET Nature of work High temp. Polymers - PBI, SPEEK Domain Size Manipulation by Sulfonic Acid-Func. MWCNTs Functionalized CNT based Composite Polymer Electrolytes Phosphonated Multiwall Carbon Nanotube-Polybenzimidazole Composites Organic–inorganic composite membranes ( Nafion with silica, MZP and MTP. Membrane with interpenetrating networks between poly (vinyl alcohol) (PVA) and poly (styrene sulfonic acid) (PSSA). Composite membranes with mordenite (MOR) incorporated in PVA– PSSA blend tailored with varying degree of sulfonation Stabilized forms of phosphomolybdic acid, phosphotungstic acid and silicotungstic acid incorporated into PVA crosslinked with sulfosuccinic acid , chitosan (CS)-hydroxy ethyl cellulose to form novel mixed-matrix membranes and variants Novel mixed-matrix membranes sodium alginate (NaAlg) with PVA and certain heteropolyacids (HPAs), such as PMoA, PWA and SWA. Minimally hydrated polymers, replace water with ‘proton mobility 15 facilitator’ K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai Sep.15-17, 2010 Indian Scenario Technology Demonstration – PEMFC and DMFC BHEL - 3 kW PEMFC Source : MNRE website SSF- UPS Source : MNRE website 16 K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai Sep.15-17, 2010 Indian Scenario Technology Status – Fuel cells – Demonstration of PEM Fuel Cell Stacks by Team CSIR 17 K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai Sep.15-17, 2010 Fuel cell program at Centre for Fuel Cell Technology, ARCI Fuel cell – a device which converts the chemical energy of fuel like hydrogen to electricity directly without the Carnot limitation at higher efficiency Development of liquid cooled PEM fuel cell stacks of capacity from 100 watts to 10 kW . 600 PEMFC Technology Development Mini fuel cells 1-3 watts capacity No of cells H2 → 2H+ + 2e1/2O2 + 2H++2e- → H2O CD (mA/sq cm) Voltage(mV) 35 No of cells 30 500 400 300 25 CD and voltage 40 PEM Fuel Cell Products • Large stationary power plants • Small power generators • Stacks for telecom backup • Stacks for transportation systems: • Car, three wheeler 200 20 2003.5 2004.0 2004.5 2005.0 2005.5 2006.0 100 2006.5 Year 3.0 kW prototype Components development Grid Independent Power systems Stack Development Hydrogen sensor System Development Cost Reduction ARCI Fuel Cells – Processes /Products available for commercial exploitation Know how for GDL, Electrodes and MEAs Know how for Bipolar plates Know how for Fuel cell stacks from 100 watts to 10 kW Know how Fuel cell systems from 1000 watts to 5000 watts with inverter, controller, air blower Our OEMS can supply the following : Bipolar plates Controllers , Inverters and Converters GIPS-1000 2004/05 GIPS-2000 2005/06 GIPS-3000 2007/8 GIPS-5000 2008/09 Fuel cell( battery) powered Automobiles Stack weight Reduced by 50% Improved controller, 600 kms With 1st generation stack 1800 kms With 2nd generation stack Indian Scenario Technology Status – Phosphoric Acid Fuel Cells Organizations Nature of work BHEL, NMRL, HEB Stack and System dev. Products developed at NMRL, a DRDO Lab NMRL’sstable700-1000 watt PAFC based UPS / generator with built in compact methanol reformer 19 DRDO –REVA fuel cell vehicle 8 KW Phosphoric Acid Fuel Cell (PAFC) based power pack K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai SHy-Power generator car 10kW fuel cell based mobile generator car Trolley mounted version of Shy Power generator Capacity 10kw continuous Sep.15-17, 2010 Indian Scenario Technology Status – Solid Oxide Fuel Cell Organizations CGCRI, CECRI , BARC, NAL, IMMT, IGCAR, Nature of work Materials development BHEL, IIT-M, IIT-B ,IIT-D ARCI CECRI, Thaper, IMMT, IISc, IIT-M, IIT-D, NIT-R Basic Science CGCRI, NAL , BARC, Stack , System (?) and integration TATA, RIL, BHEL , ARCI ( ??) , VIT (?) > Planar > Tubular > Other configuration s **India operation of foreign companies not included 20 K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai * This is not an exhaustive list Sep.15-17, 2010 Indian Scenario Technology Status – Solid Oxide Fuel Cell Organizations CGCRI ( Planar), Anode supported Nature of work •Electrode materials •Glass-based Sealants •Metallic Stack Components (Crofer 22APU) • Single cells, Scale-up to stack At 800oC and 0.7 V, current density in the range 1.5 – 2.0 A/cm2 is achieved Cathode ~50 µm Anode 1500 µm Electrolyte ~15 µm 10 cm x 10 cm Single Cells 10-cell Stack CECRI Intermediate temp. 21 Cathode materials K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai Demonstration 19 selected perovskite type oxide compositions in the La0.8Sr0.2MnO3 -La0.8Sr0.2CoO3- La0.8Sr0.2FeO3 Sep.15-17, 2010 system. Indian Scenario Technology Status – Solid Oxide Fuel Cell Organizations BARC Obj: Technology Nature of work •Materials •Stack development and demonstration of SOFC tubular cell module for 1kW and 5kW •Different processes for materials synthesis •Dense and impervious coating of YSZ electrolyte on LSM tube •Tube Cell integration works are being carried out in 200 mm long tubes NAL – Tubular IMMT Anode supported SOFC by Electrophoretic deposition (EPD) Thaper Sealants 22 K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai EVD Setup for YSZ electrolyte film coating LSM cathode tubes developed in BARC Sep.15-17, 2010 Indian Scenario Technology Status – Other Fuel Cells Type of Fuel cell MCFC MbFC $ DBFC,DAFC etc., Organizations CECRI , TERI NTPC Nature of work Materials ( Discont.?) (?) IIT-Kar, Satyabama univ. Basic Science and many other Univ. & colleges, IIT-D, IIT-G, IIT-K,IIT-B, Basic Science IIT-M, IISc, CECRI and many other Univ. & colleges, $ Girijesh Govil (TIFR) was the next to write a paper in this field. He wrote two papers on biochemical fuel cells, one in 1982 (Journal of the Indian Chemical Society) and the other in 1983 (International Journal of Quantum Chemistry). **India operation of foreign companies not included 23 K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai * This is not an exhaustive list Sep.15-17, 2010 Indian Scenario Technology Status – Hydrogen Generation Method Electrolytic water splitting** Reformation *** Bio hydrogen Organizations Nature of work BARC, CECRI ( Alkaline) in 90’s Stack and system SSF,CECRI , IIT-D( PEM) Stack and system Academic institutions ?????? NCL, IICT, Sued Chemie , Filtra, ACME , Defence lab. Catalyst ,System MCRC Large scale fermentation Many colleges and Univ., Basic Science , lab scale Many universities/colleges, Basic Science , lab scale ARCI , Many labs. Materials development Photo electrochemical demonstrations demonstrations Thermal water splitting BARC Chemical hydride splitting ARCI , ACME, NMRL Lab scale Recycling ???? Other Methods TERI, Some colleges Gasifier route ??? Strategic sectors ???? 24 K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai Sep.15-17, 2010 MCRC, Source ; MNRE website IIT-D CECRI , Source ; MNRE website SSF , Source ; MNRE website Source ; MNRE website 25 K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai Sep.15-17, 2010 Indian Scenario Technology Status – Hydrogen Generation 26 K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai Sep.15-17, 2010 Indian Scenario Technology Status – Hydrogen Generation 27 K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai Sep.15-17, 2010 Indian Scenario Technology Status – Hydrogen Generation High Temperature Steam Electrolysis (HTSE) The High Temperature Steam Electrolyser forms an integral part of the Nuclear Hydrogen Scheme with a Compact High Temperature Reactor (CHTR) to supply high grade heat at 1000 C. 1 Nm3/hr of H2 HT Steam electrolyser of Tubular cell design is under de4velopment for hydrogen production technology demonstration. HTSE cell components are similar to tubular SOFC cells with LSM oxygen anode & NI-YSZ hydrogen cathode and thin YSZ electrolyte for hydrogen production. The 5 kW SOFC system being developed in BARC will facilitate steam electrolyser design and construction. EVD Setup for YSZ electrolyte film coating 28 K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative 1 Sep.15-17, 2010 LSM cathode tubes developed in BARC Electrical characterization facility for SOFC Scoping Workshop, Chennai Indian Scenario Technology Status – Hydrogen Generation – Reformer Catalysts – NCL Novel supports and co-precipitation techniques developed to yield good SR catalysts containing nano-particles of NiO. Common catalyst for SR of EtOH, LPG, CH4 and MeOH. 100% conversions are achieved at reasonable temperatures. These catalysts have capability to handle high space velocities. Presence of olefins do not affect the performance. Variations in LPG composition has no bearing on the performance. NCL’s SR catalysts show sulfur tolerance to some extent. As a result, desulfurisation of the feed is not a must during the steam reforming of agroethanol. NCL’s PROX catalyst works in the temperature window of 135-150 oC and at O2/CO = 1. These less severe conditions help in saving of valuable H2. Scale up and evaluation of these catalysts at Kg level has been successfully completed. A Fuel processor using complete train of these catalysts is operational at NCL Source : Dr C V V Sathayanarayana National Seminar on “Creating Infrastructure for Adoption of Fuel cell Technology”, NTPC, Noida 29 K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai Sep.15-17, 2010 Indian Scenario Technology Status – Hydrogen Storage* Organizations Nature of work BHU Materials, system , demo programs ( 2,3,4 wheelers) , Basic studies CECRI Materials, Battery IIT-M , NCCR, IIT-G Materials, Lab demo., Modeling , Other applications IIT-B Materials, Modeling ARCI, BARC, IIT-Kharagpur, NEERI, Materials NIT-Durgapur , Rajasthan Univ, JNCSR,RRCAT Basic Science CFCT-ARCI, SSF Fuel cell application –System integration Kinetic , Bajaj , Birla Applications ?? * This is not an exhaustive list > MNRE has sponsored a Mission mode program on Hydrogen Storage last year 30 K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai Liquid Hydrogen not considered High pressure gas storage –issues Sep.15-17, 2010 Indian Scenario Technology Status – Hydrogen Storage BHU Source : MNRE website IIT-M 31 •Hydrogen storage properties of Zr & Mm based alloys •Hydrogen storage properties of Mg based composite materials •Design & Development of hydrogen storage device •Development of alloy hydride catalyst •Kinetics, thermodynamics of hydrogen in alloy hydrides • Alloys for Ni-MH battery applications, sensor applications • Hydrogen storage properties of Pd decorated nitrogen doped graphite nanoplatelets • Hydrogen storage in Carbon materials •MH in air conditioning , refrigeration , Heat pumps , Modeling K S Dhathathreyan , DST-EPSRC Fuel Cells Initiative Scoping Workshop, Chennai Sep.15-17, 2010 Indian Scenario - Indian Industries pathway = Indian Oil Corporation Limited ( IOCL) with the support of Ministry of New and Renewable Energy (MNRE) has set up the first Hydrogen Dispensing Station at a petrol pump in New Delhi in 2009. -The station dispenses neat hydrogen and H-CNG blends as fuel for automotive vehicles. = Bharat Petroleum Corporation (BPCL) is planning to generate up to 1,000 MW of power through fuel cell technology over the next three to five years, and is in talks with Japan’s Nippon Oil Corporation for polymer electrolyte fuel cell (PEFC) technology. BPCL has not divulged the investment details, but a Delhi-based analyst said it could range between Rs 4,000 crore and Rs 8,000 crore for a 500-1,000 MW capacity. - Business Standard, July, 14,2010 = ACME Telepower Group has tied up with Canada based M/s Ballard Power systems and M/S Idatech for Fuel cell installation in telecom sector = Tata teleservices has tied up with US based M/S Plugpower for a fuel cell back-up power supply for a rural base station in Bijnour, Uttar Pradesh. The other partner is Hindustan Petroleum Corporation Limited (HPCL). K S Dhathathreyan , DST-EPSRC Fuel cells Initiative Scoping work shop , Chennai , India Sep.15-17,2010 Indian Scenario - Indian Industries pathway Tata Motors has now developed a range of hydrogen fuel cell-powered buses and light trucks. The fuel cell-powered commercial vehicles, developed at Tata Motors’ European Technical Centre, are undergoing trial run. TATA and ISRO are partnering a fuel cell bus demonstration program in India using Ballard Fuel cell stacks. REVA electric Car company has demonstrated fuel cell powered passenger car using Ballard stacks. • Mahindra and Mahindra is working with ARCI to develop Fuel cell powered 3 wheelers. Reliance Industries has initiated some work in fuel cell development and is in negotiations with many foreign suppliers. They are looking to develop large stationary fuel cells running on natural gas for their large portfolio of property, including shopping malls, luxury hotels and private hospitals. K S Dhathathreyan , DST-EPSRC Fuel cells Initiative Scoping work shop , Chennai , India Sep.15-17,2010 Indian Scenario The majority of organizations in India involved with fuel cells in India are R&D orientated with major thrust in materials research with a smaller number involved with manufacture and distribution. Key Challenges – Indian perspective Key Challenges – Indian perspective Key Challenges – Indian perspective Key Challenges – Indian perspective Key Challenges – Indian perspective Key Challenges – Indian perspective Thank you What needs to be done? Besides materials development , process scale –up , Manufacturing R&D for repeat components fabrication More impetus to hydrogen generation technologies Standard protocols for testing and reporting with duration of tests Field trials at user site Increase industry participation Increase public awareness