DVD BONDING USING HIGH ENERGY PULSED UV/VIS LIGHT TAKE THE 0.6-SECOND CURE! XENON’s PULSED UV IS SLASHING CURE TIMES AND CYCLE TIMES WHILE BOOSTING DVD YIELDS 0.6-second cure times —that’s an eye-popping figure. XENON Corporation, the speed leader, has documented cure times as low as 0.6 seconds for DVD-5, and 1.2 seconds for DVD-9. And lightning fast cure times are just one of the many benefits of pulsed UV curing technology. Others include: higher yields, reduced complexity, safe, mercury-free operation, and fast ON/OFF. The leading DVD manufacturers are designing in XENON’s CoolCureXL-DVD®, XENON’s pulsed UV technology because it reduces “shrinkage” through tilt management and through lower temperature rise of the DVD substrate during the curing cycle. Shorter cure times reduce overall cycle times of DVD bonders which means higher DVD output. XENON Corporation’s CoolCureXL-DVD pulsed UV systems are installed in more than 1000 DVD bonders the world over. Vastly improved yields and dramatically reduced cure times that result in low cycle times… these are reasons that the leaders in DVD manufacture are switching to pulsed UV curing technology and to aligning with XENON’s proven history. Pulsed UV curing is less complex than mercury systems, and it is safer for the user too. And finally, instant ON and OFF is a benefit manufacturers appreciate. For more information, request the booklet: DVD Bonding… Using High Energy Pulsed UV/VIS Light. Call or access our website at www.xenoncorp.com/dvd/ XENON’s PULSED UV ... CURES WHILE IT YIELDS www.xenoncorp.com +1 800-936-6695 +1 781-938-3594 Table of Contents TABLE OF CONTENTS Chapter 1: Introduction to Ultraviolet light (UV) ------------------------------------------------------ 4 Comparison: Pulsed Light versus Continuous Wave UV Pulsed Light Properties Chapter 2: Pulsed Light Systems ------------------------------------------------------------------------- 5 Chapter 3: Benefits of Pulsed Light in DVD Bonding ----------------------------------------------- 6 Low heat transfer to substrate Deep penetration of polycarbonate layers Instant on/off control processing Broad Spectrum of Light Flexibility of Lamp Shape Spectrum Tuning Edge curing Tilt management using energy control and dual pulsed lamps Comparing Lacquer CD Curing Requirements with Those of DVD Bonding Ease of System Integration Safety and Environmental Benefits UV-Curing Adhesives and Lacquers Achieving Fast Cure times Chapter 4: Non Contact Surface Treatment Using Pulsed UV/Visible Light ------------------ 11 Chapter 5: Emerging Technologies Using High Energy Pulsed UV/Visible Systems ------ 13 Data Storage Devices Based on Holographic Technology Graphics for the Play Side of Optical Media Chapter 6: Next Generation DVD Systems ------------------------------------------------------------- 14 M2 Pfeiffer Vacuum Chapter 7: Conclusion --------------------------------------------------------------------------------------- 16 References Acknowledgments Chapter 8: Model RC-1002 System Specifications -------------------------------------------------- 17 3 Chapter 1: Introduction 1: Introduction to Ultraviolet Light (UV) UV is unable to penetrate opaque materials and meet low temperature, safety, and flexibility requirements. Advantages of pulsed light include faster processing, little or no substrate temperature buildup, process flexibility, freedom from toxic lamp materials, penetration of opaque solutions, and ease of meeting special lamp configuration requirements. Pulsed light is usually the technology of choice when continuous UV fails to maintain low substrate temperature or to penetrate thick and opaque materials. Electromagnetic radiation is the theory of propagation of all energy, and extends from the extremes of sound to gamma rays, and includes radio waves, microwaves, infrared, visible light, X-rays and ultraviolet light. Ultraviolet light occupies that region of the spectrum between visible light and x-rays. By definition, the wavelengths of ultraviolet radiation extend from 400 nm (nanometers) down to about 100 nm (or 4000Å to 1000Å). Below 180 nm, ultraviolet radiation can only propagate in a vacuum, and is commonly referred to as vacuum UV. The UV spectral region is often divided into bands referred to as: Band Ozone generating Bacterial (germicidal) Erythemal “Black light” Pulsed Light Properties The difference between pulsed UV light and continuous UV light is illustrated in Figure 1 in terms of pulse amplitude and controlled spaced pulses. Peak power levels with pulsed light can be as high as 1 x 106 watts, with pulse widths in the microsecond region. The pulsed-lamp spectrum is also directly dependent on the characteristics of the electrical operating conditions. Shifting the current will yield the optimum wavelength for a particular application. The broad Wavelength 180 to 200 nm 220 to 300 nm 280 to 320 nm 320 to 400 nm A more common grouping in radiometric terms is: Band UV-A (phototherapy) UV-B (sunburn) UV-C carcinogenic Wavelength 315 to 400 nm 280 to 315 nm 100 to 280 nm There are several sources of plasma-created UV radiation, the most common being the electric arc, the mercury lamp, and the most efficient of all, the pulsed xenon lamp. Whatever the application, the quest for increased energy in the UV is incessant, as always, and the demand for the efficient UV generator increases constantly with new applications. A primary characteristic of the pulsed xenon lamp is its capability of generating wideband radiation (50 nm to 5 microns) with unequalled high efficiency … especially in the ultraviolet spectral region from 180 nm (air-cutoff) to 400 nm. Figure 1: A comparison of pulsed vs. continuous UV light (pulsed light illustrated in a single pulse and burst mode) spectrum can be tuned to peak in different spectral ranges. Pulsed light is a fast, safe, environmentally benign and flexible technology capable of meeting all the needs of DVD bonding. About 50% to 60% of the input electrical energy is converted to optical energy, with an efficacy in the range of about 150 to 280 lumens/watt when operated at optimum conditions. Generally, a xenon pulsed source can be designed to outperform any other source Comparison: Pulsed Light vs. Continuous Wave UV The two fundamental methods of delivering UV are continuous (CW) and pulsed. Pulsed light is inherently different from continuous UV light such as, fluorescence, halogen, mercury vapor, or microwavegenerated continuous light sources. Pulsed light is particularly useful in applications where continuous 4 Chapter 2 Pulsed Light Systems 2: Pulsed Light Systems Figure 2 illustrates the five functional elements of a high energy pulsed UV/Visible light system. These basic elements are: ➀ HIGH VOLTAGE POWER SUPPLY ➁ STORAGE CAPACITOR ➂ INDUCTOR ➃ FLASHLAMP ➄ TRIGGER CIRCUIT The high-voltage dc power supply, protected by current-limiting, is used to charge the storage capacitor to a voltage below the gas breakdown voltage, or ionization, of the flashlamp. When the capacitor is fully charged to this level, the power supply is momentarily prevented from further charging. A high voltage trigger pulse is then supplied to the flashlamp, typically through a trigger wire wound around the flashlamp. This trigger pulse ionizes the gas in the flashlamp allowing the energy stored in the capacitor to discharge through it. The capacitor and inductor values control the flashlamp peak current, rise time and pulse width, insuring the optimum energy transfer within the flashlamp. The flashlamp discharge converts the capacitor/inductor electrical energy to radiant energy in the form of UV/Visible radiation which in turn is delivered to the intended target. This process is then repeated, typically 10 pulses/second, resulting in a series of controlled, shaped, high energy UV/Visible pulses. Figure 2: Basic Pulsed UV/Visible Light System 5 Chapter 3: Benefits of Pulsed Light 3: Benefits of Pulsed Light in DVD Bonding operate at the same high temperatures required to vaporize the mercury in mercury vapor lamps; The most important reasons for considering pulsed UV/Visible systems for DVD bonding over continuous UV systems are: • The high peak power of the pulses, which eliminates the need for high average power; • The elimination of continuous infrared radiation; flashlamps are turned completely off/on in microseconds. • Safety • Temperature control • Process effectiveness • Process speed • Process flexibility These features result in one or more of the following benefits of pulsed light technology: 1. Low heat transfer 2. High peak power for deep penetration of opaque substances 3. Instant on/off (no warm-up required), for ease of control 4. Broad spectrum Figure 3: Instead of continuously warming the substrate, as does continuous UV, pulsed UV/Visible light provides cooling periods between pulses. 5. Special lamp configurations 6. Spectrum Tuning For manufacturers seeking higher yields and faster production, the important benefit of maintaining the substrate at a lower temperature during the process is the ability to eliminate disc warping. 7. Edge Curing 8. Tilt Management Benefit # 2 – Deep penetration of polycarbonate layers Each of these benefits will be discussed in detail to more clearly reveal how pulsed UV/Visible light aligns itself to the needs of today’s DVD bonding process. A significant characteristic of a pulsed UV/Visible lamp is the ability to provide deep penetration due to high peak power. The high peak power of the pulsed lamp allows the UV to penetrate the polycarbonate substrate layer with sufficient energy to complete the cure of the adhesive sandwiched in between the twopolycarbonate layers. In comparison, a continuous UV mercury lamp delivers about one third of its energy as heat at or near the surface of the disc, thus requiring significantly more average power and often requiring water cooling. One Xenon customer used pulsed light to reduce the average power from between 5,000 and 6,000 watts with mercury vapor lamps to an average of 400 watts. Benefit # 1 - Low heat transfer to substrate Although some heat enhances polymerization, the process of photo polymerization is designed to occur mainly with light. Lower temperatures achieved with pulsed light can help improve yields. Five key reasons, illustrated in Figure 3, that minimize temperature buildup when using pulsed UV/Visible in a DVD bonding process are: • The short-duration pulses, which are too fast for heat buildup; • The presence of a cooling period between the pulses; Deep penetration of a substrate also depends on another pulse characteristic: pulse width. This same customer tested thermal loading of DVD-10 discs • The fact that pulsed UV lamps do not have to 6 Chapter 3: Benefits of Pulsed Light (dual sided, single layered) using two pulsed UV lamps with different pulse widths, The more energetic pulse lasted 1 ms, with smooth ramp up and drop off. The second pulse contained only 60% as much energy, but presented it in a 0.32 ms pulse with a very sharp onset and a higher peak power. To cure the DVD adhesive, 6 pulses of the more energetic system or 10 pulses of the less energetic system were required. When researchers measured the temperature of the glass pattern underneath the DVDs over a number of cycles, they found that the longer pulses raise the glass temperature considerably more than the shorter pulses. Visible bonding can start, stop and start almost instantly with the simple pressing of a button or sending of a control signal from a programmable logic controller (PLC). The ability to start and stop in microseconds provides longer lamp life. During the time a DVD is being indexed, the lamp can be shut off and instantly flashed when required. Pulsed UV light leads to better quality, higher yields, and lower operating costs. Benefit # 4 - Spectrum Flexibility Pulsed UV/Visible lamps emit a broad spectrum of light with wavelength ranging from 200 nm (2000 angstroms) to 1,000 nm (10,000 angstroms) – from UV region to the visible region and to the IR region. Pulsed light is the only technology which allows the light spectrum to be changed without changing the lamp, as illustrated in Figure 5. Variations in current will result in predetermined changes in the flashlamp spectrum. This is extremely significant because it allows matching the flashlamp wavelengths to the chemistry of the bonding adhesive. Additionally, changes in the heat delivered to smaller and thinner Figure 4: An automated DVD Bonder with Xenon’s Pulsed Light Equipment designed in. Benefit # 3 - Instant on/off control processing In meeting the demands for today’s high volume manufacturing lines, DVD manufacturers are constantly seeking improvements that will lead to savings with shorter process times along with lower system maintenance costs. DVD adhesive curing with conventional mercury vapor lamps requires both a long warm-up period and keeping lamps on continuously during the manufacturing process. The warm-up time and mechanical shielding requirements imposed by mercury lamps during the noncuring phase of the cycle are undesirable. Responding to these problems, pulsed UV lamps provide full curing energy in microseconds instead of minutes of warm-up time necessary for mercury vapor lamps. Figure 5: Pulsed UV lamps provides a wide spectrum, from UV to the visible range substrates can be controlled using this method. Benefit # 5 – Flexibility of Lamp Shape Pulsed UV lamps can be supplied in a variety of shapes to fit demanding requirements. A pulsed UV lamp can be formed to any shape a glassblower can bend quartz as illustrated in figure 6. Such shapes include circular, helical, serpentine and spiral. Using a pulsed UV system affords the user an advantage in controlling the process. Pulsed UV/ 7 Chapter 3: Benefits of Pulsed Light Newly developed formulations for DVD that require both UV and visible light to cure, benefit from pulsed UV/Visible lamps that radiate in both the UV and visible regions of the spectrum. These new adhesives won’t cure when exposed to fluorescent room lighting (like visible curing adhesives), and require less UV light when compared to adhesives that cure with only UV light. Broad spectrum pulsed lamps provide a wide range of wavelength selection. As a result, pulsed lamp systems can be used with adhesives from different vendors. Buyers of fully automated multimillion-dollar machines benefit by having more than one formulation choice for their process. Figure 6: Multi-shaped lamps illustrating flexibility of lamp design Benefit # 7 - Edge curing Another advantage for DVD manufacturers when they select a pulsed lamp system is the shape of the pulsed lamp. Traditionally, mercury lamps have been limited to short arc or linear lamp designs, although other lamp shapes may fit the application better. For example, a spiral lamp design can provide better uniformity and enhanced matching of the illumination area for a DVD as shown in figure 8. By including an outer ring, this spiral lamp is designed to meet the DVD edge cure bonding requirements. The outer ring of the spiral lamp proved itself to one Xenon customer when it was first installed more than four years ago. In particular, the spiral lamp shape eliminated the previous problem of “tacky” edge cures that the customer was experiencing prior to using a pulsed lamp system. Benefit # 6 - Spectrum Tuning The spectrum of a single pulse of light is a universe of flexibility unto itself. The spectrum of a single pulse can be controlled to meet unique DVD bonding requirements. When the lamp is triggered and the xenon gas ionizes, the light spectrum initially starts with the shorter wavelengths and moves toward longer wavelengths as the pulse forms, as illustrated in Figure 7. The amount of UV, visible, and IR can be set for each specific application. An example of this is a semiconductor application requiring 100 microseconds of UV, 50 microseconds of visible light and 25 microseconds of IR from a single pulse. This spectrum distribution creates a “super” hard photo-resist capable of withstanding very high ion implant dosages without damage. Prior to using a “tuned” UV pulsed system, the limit of the industry was 700 watts. The goal was to achieve a 10% improvement. The single pulse tuning brought the power handling capability to 2,000 watts, 500 watts higher than the highest power ion implant system could deliver at maximum output. These results provided a significant technical breakthrough for the semiconductor industry. Figure 8: Spiral lamp, designed to match DVD shape, provides superior edge cure Figure 7: A Single pulse of light, illustrating spectral components 8 Chapter 3: Benefits of Pulsed Light Benefit # 8 - Tilt management using energy control and dual pulsed lamps All DVDs’ are layers made from heat sensitive polymers. Further, the trend to thinner DVD materials is making them even more heat sensitive. Processing steps that overheat the plastic can cause changes in the DVD tilt. Excessive tilt can impair the quality and yield. For the DVD manufacturer this is clearly unacceptable. The lower substrate temperature that can be achieved with pulsed UV curing can help prevent excessive tilt. The wavelength of the pulsed light can be tailored to deliver a precise energy with each pulse, thereby providing tilt management. Further tilt management is achieved by the use of top and bottom pulsed light lamps. Each lamp is sequenced under Figure 10: Dual Lamps operated from a single power Programmable Logic Control (PLC) for tilt supply and controller management of batch processing. The full benefits of tilt management using pulsed light operate two lamps from one power source. have been realized in full production.This was achieved with two independently controlled pulsed light systems, Comparing Lacquer CD Curing Requirements as shown in figure 9. with Those of DVD Bonding When curing lacquer coatings on CDs, continuous mercury lamps have traditionally been the selected method. These surface coatings are easily penetrated with continuous UV light unless extremely high production speeds are required. However, the curing requirements for DVD bonding are significantly different. The light must penetrate a 0.6 mm polycarbonate substrate containing one or more information layers on one or both sides to reach the bonding adhesive. Moreover, light needs to penetrate the DVD polycarbonate layer with sufficient energy to affect the adhesive cure at a low temperature and high speed. Further, new developments in DVD (such as DVD18 which are double sided, dual layered) pose even tougher penetration requirements. Because DVDs have shallower Figure 9: Pulsed UV lamp housings (top and bottom) sandwich the DVD for tilt management. and smaller pits, smaller track pitch and tighter tolerances on tilt and jitter than CDs, the effect of temperature on the substrate is In order to reduce the cost of two complete pulsed much more pronounced. DVD further challenges the lamp systems, Xenon Corporation introduced their UV technology with tough edge curing and tilt RC-1002 system, shown in Figure 10, designed to management requirements. 9 Chapter 3: Benefits of Pulsed Light Ease of System Integration UV-Curing Adhesives and Lacquers The integration of a pulsed UV system into a DVD line eliminates the need for demanding water cooling or equipment placement constraints. Because of the low heat feature of a pulsed UV system, with the resulting low average power (400 watts for a pulsed light system versus 5,000 watts for a mercury lamp system) lamp and reflector cooling is reduced to Achieving optimum cure times requires the use of specially formulated, fast curing, bonding adhesives that take advantage of pulsed UV’s emissions in both the UV and visible regions. Typically the adhesive is applied to the disk surface by a spinning or skimming process, requiring the use of low viscosity material. There are many UV-curing adhesives available that are designed to offer fast cure speed, excellent bond integrity and dimensional stability for all disc formats; DVD-5; DVD-9; DVD-18; etc. The table below lists manufacturers who provide pulse UV curable adhesives and lacquers. Web Site Manufacturer www.bordenchem.com Borden Chemical, Inc Dainippon Ink and Chemicals, Inc. www.dic.co.jp Eques Coatings www.eques.nl Sony Chemicals Corporation www.sonychemicals.com Achieving Fast Cure times The overall achievement of applying high energy, pulsed UV curing systems in DVD bonders, is reduced cure time when compared to conventional mercury lamp UV systems. With shorter cure time, overall cycle times of DVD bonders are reduced resulting in the cost of manufacturing dropping due to a higher output of DVDs. Figure 11: Pulsed UV/Visible lamps can be placed at a distance from the controller and power supply. These compact electronic units help minimize the footprint of an automated bonder simple air cooling blowers. Because a pulsed UV light system is modular and compact in design, equipment such as power supply and controller can be located as far as 20 feet away from the lamp. These additional features provide DVD bonder manufacturers with flexibility in placing components within their bonders. Figure 11 illustrates one such DVD bonder where the pulsed light system controller and power supplies were placed at the rear, affording quick and convenient access for maintenance procedures. Examples of pulsed UV curing systems that are currently being employed in over 1000 DVD Bonders Installed worldwide are Xenon Corporation’s models RC-742 and RC-1002. These modular curing systems are designed to provide a broad spectrum of high intensity UV/Visible radiation utilizing a unique spiral flashlamp and lamp housing reflector design. The average power per pulse is 100 w/cm² (measured at 10 pulses/sec, broadband, 1.25 in (31.75 mm) from the face of the lamp housing). Peak power is 1000 w/cm². The table below lists the actual cure times achieved using these systems under actual production conditions. Safety and Environmental Benefits of Pulsed UV/ Visible Systems The pulsed UV process is environmentally benign since it does not create or use volatile organic compounds (VOCs) or create suspended airborne particulates. Pulsed UV lamps do not use microwaves or contain toxic materials, such as mercury, and therefore do not expose personnel to the potential hazards due to lamp breakage. Format DVD-5 DVD-9 DVD-10 DVD-14 DVD-18 Cure Time 0.6 seconds 1.2 seconds 1.4 seconds 1.2 seconds 1.2 seconds Future pulsed UV systems are evolving from work focused on delivering the UV/Visible energy at even higher rates (>10 pulses/sec), resulting in bonding cure times on the order of 40% less than today’s results. 10 Chapter 4: Non-contact Surface Treatment Studies • Thermoplastic polyolefin (TPO) Reactor Grade (RTPO) Mechanical grade (MTPO) • Sheet molding compound (SMC) (EAR) Regular (SMC1) Toughened (SMC2) • Polyphenylene Sulphide (PPS) White (PPS1) Black (PPS2) 4: Non-contact Surface Treatment Studies Using Pulsed UV/Visible Light Pulsed UV can be used as a non-contact polymer surface treatment, as reported by Prof. Lawrence T. Drzal, Composite Materials & Structures Center, Dept. of Chemical Engineering and Materials Science, Michigan State University (USA). Paint and adhesive performance depends on the quality (cleanliness and surface energy) of the substrate (adherent) surface. Disadvantages of existing surface pretreatment methods like plasma, flame, corona, and solvent washing are that they are labor intensive, time consuming, cause damage to the adherent surface, and emit volatile organic compounds. Many polymers used as matrices for polymer composites are being investigated. Figures 12a and 12b, obtained at MSU with a wide range of thermoset and thermoplastic polymers, illustrates the significant improvements in surface energy that can be obtained. This has resulted in better wetting of plastic surfaces by adhesives and coatings, and substantial increase in adhesion of UV treated surfaces as measured by a tensile butt test to an epoxy matrix. Polymers investigated have included thermoplastic as well as thermoset matrices. Although this group of polymeric matrices represents some of the materials commonly used in industry (TPO, polypropylene, polyester, polycarbonate, poly phenylene sulfide, poly methylmethacrylate and vinyl ester), the breadth of applicability of this pulsed UV surface treatment method indicates that it has a high potential of being very useful with other materials as well. • Polypropylene (PP) • Polybutylene terephthalate (PBT) • Bulk Molding Compound (BMC) • Diene rubber (DR) • Ethylene Acrylic Rubber • Polymethyl methacrylate (PMMA) • Vinyl Ester (VE) • Polycarbonate (PC) • Bexloy (lonomer) Composite Figure 12b: Samples treated with pulsed UV (Figure provided by Prof. Lawrence T. Drzal) A model including the important parameters of this UV surface treatment and comparison of methods are shown in Figures 13 and 14 respectively. The flexibility of pulse light delivery to the substrate (i.e., pulse recurrence frequency, pulse duration, and spectrum) brings “tuning” possibilities to various substrates. Pulsed UV meets the need for a continuous, environmentally benign, fast, cost effective and non-contact surface preparation process. Lamp intensity Ozone concentration Humidity Substrate temperature Nature of gas flow Exposure time Pulse frequency (UV flashlamps) Nature of the substrate UV UV photons Polymer Figure 12a: Improvements in surface energy when treated with pulsed UV (Figure provided by Prof. Lawrence T. Drzal) Oxygen Carbon Ozone Oxygen radical Figure 13: Parameters for surface treatment process model. (Figure provided by Prof Lawrence T. Drzal) 11 Chapter 4: Non-contact Surface Treatment Studies Conventional Surface Treatments (Flame, Corona, Plasma, Chemical) UV Surface Treatment Current Status Flame, Corona and Chemical Wash are mainstream surface treatment technologies. Plasma - limited acceptance. Developing technology Equipment manufacturing base exists. Environmental Impact Chemical – VOC emission, waste disposal. Corona – High levels of ozone produced. Flame – Greenhouse gases, organic fuels. Very low levels of ozone produced in contained environment. Ability to Treat Flame, Corona and Plasma Treatments have Complex Geometries severe limitations in treating complex geometries. Line-of-sight treatment. Potential to treat complex geometries is excellent. Treatment Time Corona, Flame – Very fast treatment times Chemical, Plasma – Moderate treatment times Fast treatment times (Time scales inversely with lamp power) Hazards Chemical – human exposure, waste disposal Corona – very efficient Ozone production UV protection for humans Cost Corona, Flame, Chemical – Inexpensive Plasma – Expensive Inexpensive Suitability in Manufacturing Environment Corona, Flame – Web treatment applications. Removal of process gases required. Chemical – Adverse environmental impact, hazardous. Plasma – Unsuitable for large scales. Excellent suitability for all applications – flat, complex geometries, large scale. Minimal hazards – UV protection, Removal of low levels of ozone required. Figure 14: Comparison of conventional surface treatment and pulsed UV. (Figure provided by Prof. Lawrence T. Drzal) 12 Chapter 5: Emerging Technologies 5: Emerging Technologies using High Energy Pulsed UV/Visible Systems materials,” said Dr. Parag Mehta, VP Aprilis Corp. “Xenon is regarded as the supplier of choice for their lighting systems in DVD manufacturing.” The Optical Disc market is achieving ever increasing growth by demonstrating its ability to provide new and innovative products. High energy pulsed UV/Visible systems are providing a key tool in the development of new systems. Companies such as Aprilis Corp and Spectra Systems Corporation are utilizing pulsed UV technology to offer products that are truly exciting. Data Storage Devices Based on Holographic Technology Graphics for the Play Side of Optical Media Aprilis Aprilis is developing the first data storage devices based on holographic data storage technology. Holographic data storage records data as twodimensional optical “pages”, instead of as a serial stream of bits as occurs in conventional magnetic or optical storage. Many holographic pages can be independently written and retrieved from any given location in the media, so data density are significantly higher than conventional magnetic storage and an order of magnitude higher than optical storage such as CD and DVD. Since writing and reading of the data consists of transferring large digital arrays from each storage location, the data transfer rates can be hundreds of megabytes/second compared to ~5 MB/ sec. for DVDs. Furthermore, the data arrays can be searched by optical correlation methods, greatly reducing the dependence of the search on processor speed, and leading to a significant improvement in the performance of database applications. Spectra Systems has introduced a breakthrough technology in DVD/CD coating and in optical disc manufacturing. Called MediaCoatTM, the technology allows graphics, alpha-numerics and barcodes to be applied on the play sides of optical discs; this means targeted advertising messages can receive greater notice on motion picture, music and software discs. The technology is compatible with all pre-recorded optical media formats. Two Xenon flashlamps are used to cure MediaCoat on a disc, Spectra Systems R&D explains. “For the color coating (first coating applied), we use a xenon lamp because it is a true blackbody radiator in the UV and provides UV power that is independent of the discrete, narrow radiation lines of a conventional lamp. We select the wavelength cutoff with filters or reflectors. For the protective over-coating (second coating applied), it is important to use as little power as possible to overcome oxygen inhibition. Using the Xenon’s high peak power pulsed lamps accomplishes this while allowing us to use less total power.” When Aprilis designed their new manufacturing equipment for DHDTM media, it required a unique light source that provided precise spectral output, very uniform fluence and a high degree of reproducibility. Aprilis, indeed, could not have wished for a better partner than Xenon in development of this light source. Aprilis engineers worked with the Xenon team which designed and delivered the light source in record time. Spectra Systems has made an agreement with Singulus Technologies AG, to develop and commercialize customized equipment for applying Media Coat. Singulus will manufacture and sell MediaCoat equipment and Spectra will sell its proprietary lacquer formulation and provide licensing opportunities to replicators. “From our perspective, Xenon was an obvious choice because of the depth of industry experience Xenon has in providing the light source for photo curable 13 Chapter 6: Next Generation DVD Systems 6: Next Generation DVD Systems M2 is one of the world's leading manufacturers of optical disc production systems and equipment for CD, CD-ROM, CD-R, DVD and DVD-R/DVD+R. M2's equipment includes the heralded SQ1 for CD and equipment like the SQ2 for CD and all DVD formats, and the SQ3 for recordable formats. The SQ3 can handle both CD-R and DVD-R production. The SQ1 and SQ2 are the world's first fully integrated modular optical disc replicating machines. Engineered in single units (with the world's smallest footprint), SQ1 and SQ2 features integration of all components for buffering, sputtering, spin coating, curing, inspection and restacking of CD and DVD discs in one machine. Both the SQ2 and the SQ3 also features M2's unique CenterBond™ technology, which allows for bonding all the way to the center of the disc. The SpinCure™ technology creates uniform bonding layers. The acceptance of Xenon Corporation’s high energy pulsed UV/Visible systems in high volume DVD and CD manufacturing started over four years ago. At that time, one Xenon Corporation customer completed an extensive evaluation of Xenon’s pulsed light technology, confirming their ability to achieve higher production speeds with improved yields due to tilt management and lower substrate temperature. Since that time, the customer has converted over 150 installations to incorporate the Xenon Corporation Model RC-742 CoolCureXL-DVD® pulsed light system. Acceptance of pulsed UV/Visible light as the industry standard for DVD bonding has spread since this conversion was started. Examples of new bonders that are now coming to the market, incorporating Xenon’s pulsed high energy UV/Visible equipment are systems from M2 Engineering AB (Model SQ2) and Pfeiffer Vacuum Technology AG. Brief descriptions of their new systems are shown below. The SQ2 system, incorporating Xenon Corporation's Twin-XL Pulsed UV/Visible System, offers one of the fastest and most productive DVD-9 production lines on the market with a cycle time below 3.5 seconds. The bonding of the DVD discs is the most crucial process in DVD-9 production. The SQ2 system offers the revolutionary CenterBond™ and SpinCure™ technology taking DVD bonding into a new dimension. The SpinCure™ technology enables up to 25% lower adhesive costs than other bonding techniques, resulting in savings of at least $20,000 per year and line. The size of the machine means fewer parts, less maintenance and less electrical power consumption. The SQ2 consumes only 40% electrical power compared to other systems, resulting in a savings of more than $13,000 per year per system. 14 Chapter 6: Next Generation DVD Systems A specially designed, simple conveyor delivers DVD half discs in vertical orientation from molding to metallization. Two separate integrated Pfeiffer Vacuum Single Layer Metalizer apply the L0 and L1 metal layers respectively. All metals including silicon and silver alloys are optional. Attention to uniform cooling of all discs throughout the process is a key feature of the system. DVD Line The new replication system for production of DVD discs. This fully integrated system is designed to produce DVD bonded discs at 3-second cycle times and accommodates all models of injection molding machines currently employed in the industry. Servo controlled stepper motors and Siemens PLC support a smooth handling of discs with a minimum number of transport stations during the critical steps of bonding and curing. Close attention to temperature control and management are key elements of the systems overall design. Achieving stable, ambient disc temperature of all discs during production addresses and compensates for the inherent stresses of DVD inline production. Dual spin stations provide consistently high cycle times with precise bond layer uniformity. Xenon flashlamp curing from two sides enables thorough curing with tilt control. Subsequent cooling prior to in-line inspection ensures that newly bonded discs are optimally evaluated for all physical parameters prior to placement on an 8-spindles turntable. The ability to sort fff rejects into specific categories on three separate spindles provides additional control in production. 15 Chapter 7: Conclusions 7: Conclusion References: Pulsed UV can solve a variety of challenging problems for DVD manufacturers. Key attributes of this technology when applied in DVD adhesive bonding are: 1. Panico, L.R., Pulsed UV Curing for DVD Production, REPLItech, May, 2000 (1) Elimination of heat-induced damage to the disc, 3. Panico, L.R., Pulsed UV Curing for Heat Sensitive Medical Devices, October 1997 2. Panico, L.R., Pulsed UV Curing Provides User-Friendly Solutions to Tough Problems , Adhesive Age, January 1997 (2) Deep penetration through opaque materials for complete bonding at high speeds, 4. O’Hora, D.E., Beuschel, Pulsed Light Exposure Eliminates Oxygen Effect in Negative Photoresists, Technical Communications, IBM RadCure, 1978 (3) Proven technology offering higher yields and lower costs. 5. Capobianco, Robert A., Chief Scientist, Xenon Corporation, UV Curing Equipment for Assembly Applications, Xenon Application Note AN-103, May 2002 Pulsed UV curing systems lend themselves to DVD production because the lamp geometry, spectrum, and pulse shapes can be designed to match the DVD substrate and adhesive requirements. Pulsed lamp systems offer ease of integration into complete bonding systems by virtue of their ability to be switched on and off without warm-up and cool-down periods. These systems do not require water cooling, do not need rotation of the disc, provide tilt management and have longer lamp lifetimes. Pulsed UV lamp systems are mercury free and environmentally benign since they do not create or use volatile organic compounds (VOCs) or create suspended airborne particulates. 6. Panico, L.R., Flash Polymerization, 1976 Radiation Conf. Proceedings, SME, Dearborn, MI. 7. Panico, L.R., Xenon Rapid Curing Process, 1975 Radiation Curing, SME, Dearborn, MI. 8. Miller, B., Executive Editor, Pulsed Light Systems Cures Thick Thermosets in a Flash, Plastic World, Cahners Publishing Co., Inc., February 17, 1975 9. Panico, L.R., Simulating the Sun with Pulsed Light, 6th Space Simulation Conference, May 1972. 10. L. P. Haack, A. M. Straccia, J. W. Holubka, A. Bhurke, M. Xie, L. T. Drzal, Chemistry Of Surface Modification With UV/ Ozone For Improved Intercoat Adhesion In Multilayered Coating Systems, Surf. Intrf. Anal., 29, No. 12, pages 829-836, (2000) 11. Lawrence T. Drzal, R. Schalek, P. Askeland, M. Rich, A. Bhurke And P. Tummala, Ultraviolet Light Surface Treatment Of Polymers, Composite And Metals As An Environmentally Benign Surface Preparation, International Technical Conference, Seattle, WA, November 4-8, 2001 Acknowledgment Professor Lawrence T. Drzal Composite Materials and Structures Center Department of Chemical Engineering and Materials Science Michigan State University East Lansing, MI USA 16 Chapter 8: RC-1002 System Specifications management. The individual flashlamps respond automatically to the programmed trigger pulse and deliver the full energy with each pulse. 4.2" (106 mm) spiral flashlamps and lamp housings are designed to specifically match the requirements of DVD/CD bonding. MODULAR COMPONENTS The RC-1002 system offers modular construction for ease of integration into automated machines. The low heat of a pulsed UV system, with the resulting low average power (400 watts), results in flashlamp and reflector cooling reduced to simple air cooling blowers. Additionally, because the RC-1002 is modular and compact in design, equipment such as power supply and control modules can be located as far as 20 feet away from the Lamp Housings. These additional features provide DVD bonder manufacturers with flexibility in placing components within their bonders. A family of flashlamps and Lamp Housings and related spectra are also available with this system. FEATURES • Modular components • Optically isolated user interface • Adjustable power range up to 2000 watts • Dual Flashlamp control SAFETY and ENVIRONMENTAL FEATURES • No toxic materials, such as mercury or microwaves are involved The pulsed high energy UV/Visible process is environmentally benign since it does not create or use volatile organic compounds (VOCs) or create suspended airborne particulates. RC-1002 pulsed flashlamps do not use microwaves or contain toxic materials, such as mercury, and therefore do not expose personnel to the potential hazards due to flashlamp breakage. APPLICATIONS • DVD Bonding • CD Lacquer Curing GENERAL DESCRIPTION LAMP HOUSING COOLING Model RC-1002 CoolCureXL-DVD® Ultraviolet/Visible Curing System is a modular light source designed to provide a broad spectrum of high intensity pulsed light ranging from 200 to 1000 nanometers. The average power per pulse is 100 w/cm² (measured at 10 pulses/sec, broadband, 1.25" (31.75 mm) from the face of the Lamp Housing). Peak power is 1000 w/cm². The RC-1002 system is designed to function as part of an integrated on-line processing system with low voltage DC control circuitry using a Programmable Logic Controller (PLC). The 4.2" Spiral Lamp Housing has been designed for continuous forced air cooling to insure the flashlamp temperature is maintained during operation. Air volume of 300 cubic feet per minute is required. Light blocking air exhaust filter is provided on the Lamp Housing. To provide adequate cooling for the Lamp Housing and flashlamp, a blower kit is available. This kit includes a blower, mains power cord, air filter, flexible aluminum ducting and hose clamps. DUAL FLASHLAMPS Model RC-1002 adds dual Lamp Housing capability to the benefits of pulsed UV/Visible light curing technology. The RC-1002 high speed Switch Logic module controls two flashlamps resulting in higher throughput, low substrate temperature and tilt CoolCureXL-DVD® is a registered trademark of Xenon Corporation 17 Chapter 8: RC-1002 System Specifications All specifications are typical unless otherwise noted (TAMBIENT @ +25 °C, VINPUT = 208 Vrms) System Units Construction PFN/Control Module Switch Logic Module High Voltage Power Supply Lamp Housing User Interface: PFN/Control Module Switch Logic Module High Voltage Power Supply Module 4.2" Lamp Housing (2/system) Blower Kit¹ (2/system) Steel, chromate over zinc plate Steel, chromate over zinc plate Gold anodized aluminum Steel, chromate over zinc plate 37-pin I/O connector located on the Switch Logic Module. System can accept from 3 VDC to 32 VDC (24 VDC preferred). Power Input PFN Control Module Switch Logic Module High Voltage Power Supply Module 4.2" Lamp Housing Module Lamp Housing Blower 1-phase 200-240 Vrms, 50/60 Hz, 1.0 amp 1-phase 200-240 Vrms, 50/60 Hz, 1.0 amp 1-phase 200-240 Vrms, 50/60 Hz, 15 amps Supplied from Switch Logic Module 1-phase 200-240 Vrms, 50/60 Hz, 4 amps Power Output to Flashlamp 2000 watts maximum 4.2" Spiral Lamp Housing Average Power² Peak Power² High Voltage Cable Trigger Cable Flashlamp Options Window Opening Light Footprint Optimum distance to target 100 w/cm² /pulse 1000 w/cm² 10-feet (3048 mm) 10-feet (3048 mm) 4.2" (106 mm) Spiral, Clear Fused Quartz, Type C 4.2" (106 mm) Spiral, Germisil, Type B 6" x 6" (152.4 x 152.4 mm) 5.50" (139.7 mm) diameter 1.25" (31.8 mm) from window face Control Optically isolated interface to computer PLC Flashlamp pulse rate (10 pulses/sec): factory set PFN level: factory set Interlocks Lamp Housing access cover, interconnect cables, and user interface connector Cooling PFN/Control Module - internal fan Switch Logic Module – static convection cooling HVPS Module - internal fan Lamp Housing Module- external blower providing 300 Cubic Feet per Minute @ 2.0 in. H2O (8.5 m3/min. @ 500 Pa) 18 Chapter 8: RC-1002 System Specifications Outline Dimensions PFN/Control Module Switch Logic Module High Voltage Power Supply Lamp Housing Height x Width x Depth 5.75" x 12.0" x 9.0" (146 x 305 x 229 mm) 5.75" x 12.0" x 9.0" (146 x 305 x 229 mm 5.80" x 6.60" x 12.5" (147 x 168 x 306 mm) 6.00" x 7.80" x 9.5" (152 x 198 x 241 mm) Weight PFN/Control Unit Switch Logic Module High Voltage Power Supply Lamp Housing Operating Environment Temperature Relative Humidity 40 pounds (18.2 kg) 23 pounds (10.5 kg) 11 pounds (5.0 kg) 12 pounds (5.4 kg) 0 - 40°C (32-104°F) 10 - 80% (non-condensing) Notes: 1 – Lamp Housing Blower Kit includes blower, blower filter, metallic ducting, duct clamps and mains power cord 2 – Power measured at 10 pulses/sec, broadband, 1.25” (31.8 mm) from face of window Specifications subject to change without notice. ORDERING GUIDE Model RC-1002 CoolCureXL-DVD® Curing Systems are modular. Listed below are the various components and accessories that are available. Consult with Xenon Corporation Sales for assistance in selecting the components that best match a specific application Item Part Number Pulse Forming Network (PFN)/Control Module 490-0189 Switch Control Module 490-0226 High Voltage Power Supply 289-0017 Lamp Housing Module, 4.2" Spiral 860-0100 Flashlamp, 4.2" Spiral, Clear Fused Quartz, Type C 890-1890 Flashlamp, 4.2" Spiral, Germisil, Type B 890-1886 Safety Glasses, UV Blocking 910-0001 Control Cable, 15 pin, 2 meter 580-0046 Control Cable, 37-pin 580-0076 Control Cable 580-0077 BNC Control Cable 580-0079 Blower Kit 390-0067 User Manual, Setup and Maintenance 810-0072 User Manual, 4.2" Spiral Lamp Housing 810-0069 19 Chapter 8: RC-1002 System Specifications PFN/Control Module Switch Control Module 20 Chapter 8: RC-1002 System Specifications DIMENSIONSARE IN INCHES MILLIMETERS DRAWNIN THIRDANGLEPROJECTION 11 79 on 01atior 180 pA or M C N On Nurbo EW X N O N E X z H 0 E 6 / s 0 5 v J/ e R A k3 5 2 1 V V k 0 8 7 4 1 3 0 2 - + 0 0 0 - 2 C 9 8 2 C D A t t u p u N p t u n O / P I 4 9 5 -3 8 3 -9 1 8 7 la l c ce i rve S d n a s le a S ro F 2 0 0 2 e r tu cfa u n a M f o e t a D ,. .A .S U in e d a M High Voltage Power Supply Module 4.2" Spiral Lamp Housing 21 Chapter 8: RC-1002 System Specifications GREEN/YELLOW BROWN BLUE C-14 SHROUDED PLUG MATES WITH C-13 CONNECTOR 200-240 VAC TO BLOWER MOTOR POWER CORD LENGTH: 84.0 / 2134 MOTOR Ø 4.00/10.2X 72/1828.8 LONG FLEXIBLE ALUMINUM AIR DUCT TOLAMP HOUSING 13.75 (MOTOR & BLOWER) 349.25 AIR BLOWER HOSE CLAMPS SUPPLIEDWITH DUCT AIR FILTER TO LAMP HOUSING 10.50 Ø 266.70 NOTES: 1. DIMENSIONS ARE IN INCHES/MILLIMETERS 20.25 514.35 7.00 (AIR FILTER) 177.80 FILTER IS WING-NUT REMOVABLE. FILTER ATTACHMENT KIT AND ASSEMBLY INSTRUCTIONSARE SUPPLIEDWITH BLOWER 12.89 327.32 Blower with Attached Components; Air Filter, Metallic Ducting, Hose Clamps, Mains Power Cord 2. DRAWNIN THIRD ANGLE PROJECTION 22 23 XENON Corporation 37 Upton Drive, Wilmington, Massachusetts 01887-1018 Tel: +1 978 661-9033, 800-936-6695 (U.S.A. only); Fax: +1 978 661-9055 E-mail: info@xenoncorp.com www.xenoncorp.com © 2004 Xenon Corporation All rights reserved. No part of the contents of this brochure may be reproduced without the written permission of Xenon Corporation. CoolCureXL-DVD is a registered trademark of Xenon Corporation. Printed in the United States of America SB103-05/04-500