KYOCERA Corporation Die Attach Pastes for Electronic Devices Product Classification of Die Attach Paste Our die attach paste is classified in categories for semiconductors, LEDs and electronic components. Furthermore, there is standard type, high thermal conductivity addition type, low-temperature curable type, and available for large-size device type as a characteristic of each product. The below table gathered up the recommended products in each category and characteristic. There are the products with an each characteristic. In addition, we suggest a no listed product in this catalogue and a custom product developed to meet a need of customer. Please feel free to contact us. *1 *2 ○ ◆ Product Classification of Die Attach Paste Use Application Standard High Thermal Conductivity Low Temperatur e Curable (*1) For large size (*2) ○ ◆ CT2510 ○ Semiconductor ○ ○ ○ ○ QFP/QFN ○ BGA Visible light LED Coupler ○ ○ CT284T-1 CT262M CT285LT ○ CT285F ○ CT2001E ○ CT2020E ○ CT2100 ○ CT2021E ○ ◆ CT256 CT262K CT285 CT285-2 CT265L ◆ CT2021S ◆ CT256B LED ○ CT220HK-D2 ○ CT288-3 ○ ○ Electronic components Capacitor CT284R ◆ CT256BL2 CT212HS-F1 White LED Power LED Recommended product CT212H ○ SOP/DIP :Cure temperature <150℃ :Adhesive area >5mm2 :Recommended item :Insulation paste CT284T-1 ○ CT285LT ○ CT233KF Resonator ○ CT290K-1 High thermal resistivity ○ CT291 CT220HK-S1 CT285 CT227L CT285MK This product classification table is current as of February 2016, and is subject to change at any time depending on product development. For details, please contact our sales staff. Die Attach Paste for Semiconductors Our paste product for semiconductors has many actual achievements as die attach paste for IC, LSI, transistor and various discrete devices. We have contributed to improving the performance, function and productivity of semiconductor devices by responding to the needs of customers. Our line-up includes a standard type for good conductivity and a low-stress type for large-size devices or a low-temperature curable type and an in-line curable type or a high reliability type for in-vehicle applications. In addition, there is a series of insulation paste products which is highly rated by customers. We offer high reliability for a wide range of applications by having various products that match to device sizes and applications. Conductive Paste for Semiconductors Product name Viscosity (Pa・s) Elastic modul us (GPa) Tg (℃) Thermal conductivity (W/m・k) Volume resistivity (Ω・cm) Adhesive strength (N/4mm2) 25℃ 260℃ Cure condition (In-line) Applied chip size Characteristics CT212H 120 6.0 180 2.8 4x10-5 40 25 200℃x1.5h ~2mm2 For small-size IC good electrical conductivity CT262K 90 6.0 115 1.3 1x10-2 140 15 150℃x1h (180℃x120s) 2~8mm2 General type For in-vehicle 15 100℃x2h or 150℃x1h (180℃x60s) 2~8mm2 Low-temperature and fast cure Inhabitation of oxidation for Cu flame 135℃x2h or 150℃x1h 1~8mm2 For SOP/QFP/QFN Low-stress CT265L 80 6.2 110 1.0 1 150 CT2001E 30 6.7 50 0.5 6x10-1 190 (Cu) (Cu) CT2020E 20 0.6 50 0.5 8x10-1 100 (Cu) 30 (Cu) 170℃x1h 1~15mm2 For SOP/QFP/QFN Lead Flame : Cu Low-stress Low Moisture CT2021E 30 2.5 65 0.7 6x10-1 150 27 170℃x1h 1~15mm2 For BGA Low-stress Low Moisture (Cu) 18 (Cu) Insulator paste for semiconductor Product name Viscosity (Pa・s) Elastic modulus (GPa) Tg (℃) Thermal conductivity (W/m・k) Volume resistivity (Ω・cm) CT2021S 50 1.5 70 0.3 CT256B 75 6.5 95 CT256BL2 50 6.7 CT256BL2 B 45 CT2510 5 Adhesive strength (N/4mm2) Cure condition (In-line) Applied chip size Characteristics 25℃ 260℃ 5x1016 140 22 170℃x1h 2~15mm2 For BGA Low-stress Low Moisture 0.3 5x1016 130 18 100℃x1.5h or 150℃x1h (180℃x60s) 2~8mm2 Low-temperature and fast curable Black color type 95 0.3 5x1016 200 < 10 100℃x1.5h or 150℃x1h (180℃x60s) 2~8mm2 Low-viscosity type of CT256B 6.7 95 0.3 5x1016 200 < 10 100℃x1.5h or 150℃x1h (180℃x60s) 2~8mm2 Thickness control type of CT256BL2 7.2 175 0.3 3x1015 150 25 150℃x1h ~5mm2 Support smallsize chip High-Tg micro dispensing High Thermal Conductive Paste Our high thermal conductive paste product was developed as a heat radiation countermeasure for small and high-density assembly of semiconductor packages and an environmentally friendly product for use as a substitute of lead solder. It has a thermal conductivity of the highest level in the industry from its high filling of silver filler and also has a high electrical conductivity. Therefore, it has been adopted by many customers since first developed. By applying our product adoption results, technical know-how and research results that we have accumulated as a market pioneer, we have succeeded in the paste development of a low temperature cure type and a low stress type. In the rapidly developing smart society, energy control technology is expected to become the most important key technology. Please consider our high thermal conductive paste for various power devices such as power IC, LSI and power LEDs. High Thermal Conductive Paste Thermal conduct ivity (W/m・ k) Viscos ity (Pa・s) Elastic modul us (GPa) Tg (℃) CT262M 100 10.0 115 5 CT284R 90 17.0 165 CT284T-1 90 15.0 CT285 100 CT285-2 Name Volume Resistivity (Ω・cm) Adhesive strength (N/4mm2) Cure condition (In-line) Applied chip size Characteristic 260℃ 6x10-4 160 20 150℃×1.5h 2~8mm2 Solventless Corresponding largesize IC 25 8x10-6 40 35 150℃x0.5h +200℃x1.5h ~3mm2 High electrical and thermal conductivity standard type 160 25 1x10-5 35 35 150℃x0.5h +200℃x1.5h ~3mm2 CT284R solventless long tack free 16.5 160 25 9x10-6 35 28 150℃x0.5h +200℃x1.5h ~4mm2 High electrical and thermal conductivity standard type 90 17.0 160 40 5x10-6 30 23 150℃x0.5h +200℃x1.5h ~3mm2 High electrical and thermal conductivity CT285 hi filling type CT285F 85 11.0 165 30 2x10-5 45 35 150℃x1h +200℃x1.5h ~6mm2 High electrical and thermal conductivity low-stress corresponding largesize chip CT285LT 100 15.0 120 25 3x10-5 50 25 160℃x1.5h ~4mm2 High electrical and thermal conductivity low-temperature cure CT2100 90 9.0 120 30 2x10-4 95 25 130℃x0.5h +180℃x1.0h ~6mm2 High Thermal Conductivity Low Stress Relation between silver-content rate and thermal conductivity CT284R / CT285 / CT285-2 Conventional product (75-80%) Silver content rate (wt%) Device reliability test Rate of change of thermal resistivity Thermal conductivity (W/mK) 25℃ Conventional silver paste Hi thermal conductive paste of other companies Hi thermal conductive paste CT285 PbSn solder Thermal sock cycles Pretreatment condition (P.C.): 85℃/85%/72h+260℃ TCT: -60℃(30min)⇔150℃(30min) reflow 3-times Conductive Pastes for LED and Electronic Components We have expanded the business of pastes for LED and electronic components, and we have the results from many customers. In particular, our silver paste for LEDs has had the best sales share in the world and can meet various needs. Because our paste for LEDs has characteristics of excellent conductivity, workability and reliability, it has got a high evaluation of standard pastes in the LED industry. Our paste for electronic components has been adopted for adhesion of capacitors and quartz resonators, and we have a characteristic product line-up. For customer requirements of cost reduction, we also have a line-up of paste products using silver coated conductive. Conductive Paste for LEDs Viscos ity (Pa・s) Elastic modul us (GPa) Tg (℃) CT212HS -F1 200 8.8 130 2.0 CT220HK -S1 115 6.3 115 CT220HK -D2 115 8.0 CT227L 90 CT288-3 85 Name Thermal conductiv ity (W/m・k) Volume Resistivity (Ω・cm) Adhesive strength (N/4mm2) Cure condition (In-line) Applied chip size Characteristic 25℃ 260℃ 4x10-5 120 30 200℃x1.5h ~2mm2 Low pollution by outgas For coupler application 2.0 1x10-4 60 13 150℃x1.5h ~2mm2 For general purpose LED standard type 115 2.0 1x10-4 80 15 150℃x1.5h ~2mm2 For general purpose LED High reliability 6.5 143 2.0 5x10-5 75 20 150℃x1.5h ~2mm2 Low temperature cure Good strength during hot state 7.8 90 1.8 2x10-4 150 20 150℃x1.0h ~4mm2 Good thermal and UV resistance High reliability Conductive Paste for Electronic Components Viscos ity (Pa・s) Elastic modul us (GPa) Tg (℃) CT233KF 80 9.5 130 6.0 CT290K-1 90 1.0 -40 2.0 Name Thermal conducti vity (W/m・k) Volume Resistivity (Ω・cm) Adhesive strength (N/4mm2) Cure condition (In-line) Applied chip size Characteristic 25℃ 260℃ 1x10-4 200 30 150℃x1.0h 1~3mm2 Low pollution by outgas For tantalum capacitor application 5x10-5 40 15 100℃x0.5h +180℃x1.0h 1~4mm2 Low modulus type Silicon modification Measurement conditions in the table Viscosity: E-type 3°cone, Value of 0.5min-1 Modulus: DMA25℃ Tg: DMA Adhesive strength: Cu/Ag plating flame vs. Bare-Si (2x2mm2) Pressure-less Silver Sintering Paste Recently, power devices such as IGBTs, LED power and automotive modules need more strict critical quality and are reaching their performance limit with resin-based DA pastes, so a new solution is needed to overcome technical hurdles. In addition, for environmental and health endangerment from lead, the semiconductor industry is making every effort to eliminate high-lead solder, when feasible. However, even now there is no single identified lead-free solution for all applications. The unique properties, such as the high melting point and thermal conductivity of these high-lead alloys are necessary for the level of reliability required for these products. Therefore, in order to achieve their requirement, we have developed pressure-less silver sintering paste based on nano-Ag technology. Our paste demonstrates a thermal conductivity of more than 200W/mK and excellent die shear adhesion to bare Cu as well as noble plating like gold and silver. Moreover, this paste shows excellent interface reliability in not only general automotive requirements but also in SiC applications with high Tj by adoption of an original resin dispersion system. Pressure-less Silver Sintering Paste Viscosity (Pa・s) Elastic modulus (GPa) Thermal conductivity (W/m・k) Volume Resistivity (Ω・cm) CT2700R6 60 17.6 200 CT2700R7 55 26.2 CT2700R7S 100 21.6 Name Adhesive strength (N/4mm2) Cure condition (Nitrogen) Applied chip size Characteristic 25℃ 260℃ 6x10-6 >400 >400 200deg.Cx1.5h (250deg.Cx1.5h) 2~6mm2 Standard High thermal conductivity 200 4x10-6 >400 >400 200deg.Cx1.5h (250deg.Cx1.5h) 1~10mm2 For Bare Cu application Excellent interface reliability 200 4x10-5 >400 >400 200deg.Cx1.5h (250deg.Cx1.5h) 0.3~ 12mm2 Printable Wide die size window Sintering Mechanism um size Ag Ag nano particle CT2700R7 Excellent heat conduction path by intermetalic bond between Ag particles Comparison with solder High Adhesion Thermal Resistance Rth (K/W) Die shear@260C (MPa) Adhesive Strength Low Thermal Resistance