Basic Model and Governing Equation of Solar Cells used in Power and Control Applications Afshin Izadian, Senior Member, IEEE, Arash Pourtaherian, and Sarasadat Motahari Abstract—This paper provides an overview of modeling of a group of commercially available solar cells to ease the study of solar powered electric systems. The models solar cells can be accurately used to predict the behavior of the system operation under different conditions. Index Terms—Solar cell equivalent circuits, Silicon based solar cells, Thin-films, Dye-sensitized, Organic solar cells. I. INTRODUCTION HE structure, material, and fabrication process of solar cells have been significantly improved since their introduction. Much of this effort has been focused on efficiency enhancement of energy conversion. The typical efficiency of current PV products for space applications is around 35%-38%. In average, non-concentrating terrestrial cells have efficiencies around 14%-15% for wafer-based Si, and around 9-10% for thin films. Energy conversion efficiencies are directly related to the type of material and structure of the cells [1]. The most common types of solar cells are made in silicon in form of single crystal, poly crystal, and amorphous. Other materials such as cadmium telluride, copper indium, and gallium arsenide have been used to obtain desired characteristics. Thin films and dye-sensitized solar cells use organic materials to lower the cost of the cells. Because of various materials, the structure of solar cells and therefore their behavior is different. To accurately express and predict the behavior of these cells, mathematical governing equations and equivalent circuits are required. In this paper, the mathematical modeling and equivalent circuit of a group of solar cells that are commonly used in industrial applications are studied. Various circuit elements and their physical effects are illustrated to help in better understanding of the cell behavior under various operating conditions and when connected to power converters. T II. CURRENT SOURCE Solar cells generate current in a large range independent from the load; thus, these cells are modeled as current sources. They are designed with built-in asymmetries to capture the photo-excited and released electrons and send them through an external circuit to build electric currents. The current generated from the cell is directly dependent on the illumination area and the probability that one photon can release one electron in the device. Solar cells in zero illumination behave more like a diode. Therefore, their current in dark condition is a function of the cell’s voltage. In illumination, however, based on the light intensity, the cell generates a current that affects the diode characteristics at the terminal. In open circuit, the voltage is created based on the recombination of carriers in solar cell. The open circuit voltage is defined as the voltage at which the short circuit current and the forward bias diffusion currents become equal with opposite polarities. Open circuit voltage has also been defined as the separation of Fermi energies at the equilibrium of electron-hole generation [1]. The short circuit current of the cell increases as the thickness of the cell increases. However, the open circuit voltage decreases as the thickness increases. Since thicker material absorb more photons and increase recombination, the optimum thickness is where rate of additional recombination and absorbed photons equalize [1]. In different cell types, several effects such as recombination (in the space charged region, at the surface, or in bulk) and diffusion may also cause a drop in the cell generated current. Applications and operating conditions may also change the cell’s voltages and current generations. For instance, to model the partial shading behavior, a voltage-controlled current source is required to model the mismatches between cells. III. BASIC MODEL OF SOLAR CELLS As mentioned earlier, a solar cell can be modeled as a current source. In its basic form, the current generated from the photocurrent source is directly conducted to the terminals. A diode is connected across the terminals to model the I-V curve normally generated from the cells. To obtain the model of illuminated solar cells, one technique is to use dark models. The Shockley equation [2] relates the current and voltage of the cell in zero-illumination condition by eV , (1) I D = I 0 exp − 1 kT where e is the charge of an electron, k is the Boltzmann constant, T is the temperature in ºK, and I0 is the inverse saturation current of the diode. The term kT is equal to the thermal voltage Vt. When the cell e is illuminated by a light source, the I-V curve is offset from the origin by the photo-generated current IL [1]. Therefore, its behavior can be modeled [3-9] as eV , (2) I = IL − I0 exp − 1 mkT where m is the ideality factor which is defined as how closely a diode follows the ideal diode equations. This is mainly caused by recombination effect and can vary significantly between different types of cells and from 1 and 5. In the majority of practical cases, m is between 1 and 2 for high and low voltages, respectively [3]. In typical applications, a value of 1.3 can be considered initially, until more estimations determine the exact values [10]. The circuit elements of this model can be obtained as a photocurrent source IL to be the reverse current with amplitude linearly proportional to the solar irradiance G (W m-2) [2, 11]. The dark current diode across the source takes the current ID from the generated current IL [4] to deliver the current I in the terminals. The equivalent circuit of the ideal diode is shown in Figure 1. The paper was submitted on September 10, 2011. A. Izadian, A. Pourtaherian, and S. Motahari are with the Purdue School of Engineering and Technology, Indianapolis, IN, 46202, USA. E-mail: izadian@ieee.org. Fig. 1. A single diode equivalent circuit for the ideal solar cell. 978-1-4673-0803-8/12/$31.00 ©2012 IEEE 1483 The current source IL is a temperature-dependent value. It can be obtained by (3) I L = I L( T1 ) (1 + K 0 (T − T1 )) , where I L(T1 ) = GI SC (T1 ,nom ) / G( nom ) , K 0 = I SC (T ) − I SC (T1 ) / (T − T1 ) , ( ) (4) (5) and I SC(T ) is the short circuit current at temperature T. The reverse circuit elements. These effects are mostly shown in the photocurrent generation process; therefore, an extra current source, as required in the thin films, can be used to show the current loss. In advanced fault diagnosis of solar cells, a dynamic model that requires modeling junction capacitors is used. In this case, the model representation will have a capacitor across the diode in the basic model of solar cells. Next sections of this paper will illustrate these elements, their operations, and some values in various types of cells. saturation current from its value at temperature T1 can be obtained [4] by 3 T I 0 = I 0(T1 ) T1 eV m exp − g mk 1 1 − T T1 , (4) where Vg is the band-gap voltage (1.12eV for crystalline silicon and ~1.75eV for amorphous silicon). The saturation current at T1, I o (T1 ) can be calculated from the open-circuit voltage and short-circuit current [4] by I SC (T1 ) . (5) I0 = eV OC (T1 ) exp − 1 mkT 1 This basic model is useful to achieve I-V curves at different temperatures. However, the behavior of the cell at extreme short circuits and open circuits cannot be thoroughly investigated from this model. In addition, this model does not provide the details of power loss and contact characteristics of the cell. For instance, as the model implies, under short-circuit conditions, the diode should not conduct any current, but in reality, the diode conducts a small current [2]. Therefore, a more accurate circuit model is needed to express these effects and obtain detailed governing equations. A model with series and parallel resistors can illustrate some of these effects. A list of all circuit elements and physical effects that are used in solar cells is provided in Table I. TABLE I. CIRCUIT ELEMENTS, PHYSICAL EFFECTS, AND THEIR APPLICATION Circuit Element Physical Effect • Electron excitation and extraction by light photons • All cells Ideal Diode • Dark current • Diffusion current from base and emitter • All cells Series Resistor • Contact resistors • Layer resistors Parallel Resistor • Recombination modeling Avalanche Current Source • Generation-recombination in the junction space-charge region • Voltage-controlled current source • Reverse bias in shading A. Modeling of Voltage Drop with Series Resistance The series resistance represents the ohmic voltage drop at the contacts and through the layers of materials. Therefore, the value of the series resistance can vary under different illuminations and in various types of cells. This resistance relates the maximum power generation of the cell with the open circuit voltage [2]. Figure 2 illustrates a model that can be used for power generation analysis in a network of solar cells [2], [12-16]. Fig. 2. A single diode and a series resistance model equivalent circuit. The effects of series resistance on the current generation and terminal voltage is described by e (V − IRs ) − 1 , I = I L − I 0 exp mkT MPPT Power loss High power Fault diagnosis network analysis • High power • • • • • Polycrystalline • Cascade models • Partial shading • Network analysis • Mismatch of solar cells Recombination Current Source • Electron recombination in strong electric fields • Thin film Capacitors • Capacitance of cell layers • High frequency • Dye sensitized • Surface recombination • Most cells • Carrier trapping • Most cells Embedded in Photocurrent Source Embedded in Photocurrent Source The process of photocurrent and terminal-current generation is affected by many parasitic sources. To model these parasitic sources, series and parallel resistances are introduced as a practical technique. Series resistance at the terminal of the cell is used to model the voltage drop. The parallel resistance is used to model the current leakage in the device proportional to the terminal voltage [3]. The current leakage is distributed throughout the device and may not always be represented as a lumped element. Application Photocurrent Source Double Diode IV. MODELING OF CURRENT AND VOLTAGE DROPS As the table illustrates, each of the circuit elements represents a physical effect. Among all the physical effects, the surface recombination and carrier trapping effects are less represented by the (6) where RS is the series resistance. This equation illustrates the principle of reverse photocurrent generation. Several studies have been done to determine the best approximation of the internal series resistance [17-25]. Wolf [17], and Iles [18] showed the series resistance as Rs=rb+re/2. Where, re≡RES2 is the geometrical resistance in Ω.cm2, RE is the sheet resistance of the layer, and S is the length. rb≡ρBWB is the total resistance of the base, where ρB is the resistivity of the base, and WB is the base width. A more accurate expression of this resistance has been provided [27] as follows: 1) The series resistance will change in small current densities at which IRs≤ Vt ≈ mkT/e [26]. When rb»re, the resistance can be calculated by Rs=rb+re/3 [27]. 2) RS varies by illumination conditions. Its maximum reaches when the cell is saturated, Rs=rb+re/3, and its minimum reaches when the cell is an open circuit, RS=(rbre)2 [27]. In dark conditions, RS varies within the range of rb+re/3≥ RSdark≥(rbre)1/2 . The base resistance is a non-zero value rb ≠0, which sets a lower bound on RS [27]. Doping the boundary layers in silicon-based solar cells can achieve either an n+-p-p+ or a p+-n-n+ structure and can reduce the series resistance. In most commercially available solar cells (e.g. the passivated emitter solar cell PESC), this parameter is nearly independent of current density, irradiance, and illumination conditions. In modern solar cells, such as back-surface fields, SiN surface passivations, selective emitters, shallow emitters, backcontact cells, HIT cells, buried-contact cells, and floating-junction 1484 passivation of surfaces, the resistance of the bulk of the material does not contribute significantly to the series resistance. low as 1.15. As the material and structure of solar cells improve, their photocurrent densities increase, and their ideality factors decrease. C. Application of models with Series and Parallel Resistance B. Modeling of Current Loss with Parallel Resistor The current leakage around the edge of the cell, the diffusion path along dislocations, and the small internal short circuits can be represented by a parallel resistor in parallel to the dark current diode [3]. In crystalline silicon solar cells, this resistance has almost no effect under normal operating conditions. A parallel resistor has effects on the device in low voltage applications and can be eliminated in high current densities [17]. Figure 3 illustrates the equivalent circuit of the solar cell with parallel and series resistors. Circuits with parallel and series resistors are being used in many applications including studies considering high power applications [30], in the development of Maximum Power Point Tracking Techniques [31-44], and in fault diagnosis [45, 46]. This model can also be used to provide details on the effects of partial shading on PV arrays [47-51], in which some of the cells may operate in reverse bias, sinking the generated power of other cells [31]. Series resistance Rs is primarily related to the reduction of the maximum output current Isc, and Rsh is related to the reduction of the maximum available output voltage Voc [7]. V. PARTIAL SHADING Fig. 3. A single diode with series and parallel resistance equivalent circuits. The I-V characteristics of solar cells with series and parallel resistors can be represented by e (7) I = I L − I 0 exp (V + IRs ) − 1 − V + IRs . mkT Rsh The circuit parameters Rs, Rsh, I0, and m at a certain illumination and temperature can be obtained from the parameter values of Voc, Isc, Vm, Im, Rso, and Rsho, where Vm is the voltage at the maximum power point, Im is the current at the maximum power point, and Rso and Rsho are defined [28],[29] as dV , (8) Rso = − dI V =VOC and RshO = − dV . dI I =ISC , (10) Vm + RSO Im − VOC VOC Vm Im + VT ln I SC − − Im − ln I SC − Rsho Rsh I SC − (VOC Rsho ) V eV I s = I SC − OC exp − OC , R sh mkT R s = R so − mkT eV OC , exp − eI s mkT V , eV I = I L − I0 exp − 1 M(V ) − R sh mkT M(V ) = R eI R (13) I L = I SC 1 + s + I s exp SC s − 1 . Rsh mkT A suitable initial guess for solving the Newton-Raphson or the Phang equations can be set for a 3" mono-crystalline solar cell under 1 sun (normally AM1 = 100 mW/cm2) illumination as IL = 1 A, Rs = 0.05 Ω, Rsh = 500 Ω, I0 = 10-7 A, m = 1.3, Voc = 0.545 V, Isc = 1 A, Rso = 0.0838 Ω, Rsho= 497 Ω, Vmax =0.415 V, Imax = 0.916 A, T= 27 °C, and Fill Factor as FF=0.698. A low fill factor may indicate a short across the diode, a high internal resistance, inadequate doping, or a high interface resistance. For a 20 µm thick cell, with light trapping, at exposure AM 1.5 the Isc=413 A/m2, Imax=401 A/m2, Voc=0.707 v, Vmax=0.702 V, FF=0.89 [1]. These values in a 6" square-shaped poly-silicon cell are Voc = 0.6V, and Isc = 8 A, and the ideality factor at the higher voltages can be as 1 (1 − (V Vb )) , (15) n where Vb is the breakdown voltage in reverse bias, and n is the Miller constant. Figure 4 shows the electric equivalent circuit of a partially shaded solar cell. Fig. 4. A solar cell equivalent circuit considering the avalanche effect [52]. The avalanche breakdown effect can also be modeled on the path of shunt resistor. The leakage current source E(V) is added into the shunt resistance and is expressed by (11) (12) (14) where M(V) is the multiplication factor as a voltage controlled current source, and represents the avalanche effect [52, 53]. This factor can be calculated by (9) The lumped circuit parameters can be obtained by solving the governing equations of the cell with the Newton-Raphson technique [28], or by using the Phang equations [29]. These equations represent an analytical approach to calculate the circuit parameters obtained by the following: m= Reverse bias occurs when PV modules are partially shaded. In this case, the shaded cell behaves like a load for the circuit [31]. A mismatch may occur where the current of the series string becomes higher than that of the shaded cell's short-circuit current and harm the cell. To model the mismatch, the avalanche breakdown effect can be represented as a dependent current source [52]. The mathematical model of the solar cell in reverse bias is expressed as V + IR s E(V ) = 1 + a 1 − Vb −n . (18) This model can express the mismatch between solar cell interconnections to form PV modules very accurately [54]. The current can be calculated by −n V + Rs I , (19) e(V + Rs I ) V + Rs I 1 + a1 − I = I L − I0 exp − 1 − Vb mkT Rsh where a is a constant. The corresponding equivalent circuit is shown in Figure 5. Fig. 5. Bishop’s equivalent circuit. 1485 Lorenzo has shown the reverse-bias saturation current and the open-circuit voltage as a function of temperature [3] by E go (16) , I 0 = KT 3 exp − kT VOC (T ) = E go e − kT KT 3 . ln e I L (17) where K and Ego (the band gap at 0º K) are approximately constant with respect to temperature. VI. MODEL OF THIN FILM SOLAR CELLS Thin film solar cells like other types of cells generate photocurrents in two steps: photogeneration (or release of electrons) and charge separation (or current creation) [34]. A built-in voltage separates charges across the p-n junctions in a layer called the space charge region. This is more sensible in thin film solar cells such as hydrogenated amorphous silicon (a-Si:H) [34] and hydrogenated microcrystalline silicon (mc-Si:H) [55]. The aging of solar cells degrades the space charge layer and provides a recombination center that sinks some of the generated current and, therefore, reduces the power of the solar cell. An additional recombination loss is represented by the current Irec to show the counteraction effect on the photogenerated current. The current source is added into the equivalent circuit, as shown in the dashed lines in Figure 6 [56]. The expression for the recombination current loss Irec within the space charge layer equals the generation current IL multiplied by the ratio of the cell thickness di over the effective drift length (µτ )eff E (Schubweg) in the space charge layer [57] as I rec = I L di (µτ )eff [Vbi − (V − IRs )] di (µτ )eff where =2 , µ noτ no .µ poτ po , µ noτ no + µ poτ po (18) Fig. 7. An equivalent circuit model of a DSSC. The model is a combination of the photocurrent source, a diode to represent the dark current behavior, series and parallel resistors, and capacitors. The diode behaves more like a variable resistor, R2. Series resistance, RS, represents the effects of impedances related to charge transport at the electrode, photosensitized material, and electrolyte. R3 is the Warburg impedance, and Rh is defined as a resistance in the high-frequency range of about 106 Hz. C1 and C2 are capacitance elements of R1 and R2, respectively. Since dye-sensitized material can be made out of non-toxic and biocompatible material, they can be used in health care products as well as domestic applications such as paint pigmentation [76]. VIII. POLYCRYSTALLINE SOLAR CELLS Polycrystalline solar cells require more details in their equivalent circuits to represent accurate I-V characteristics. For accurate modeling, the diode should have a variable ideality factor m [62], or be replaced with two parallel diodes with different ideality factors m=1 and 2 [2, 11, 63]. Figure 8 illustrates the double diode equivalent circuit of the polycrystalline solar cells. The first diode with current ID1 models the diffusion current from the base and the emitter, and the second diode models the generation-recombination current ID2 in the junction space-charge region [64]. This recombination current is negligible in wafer-based silicon cells except for low-cost mass-produced cells. For this reason, the use of the double diode model is very limited except for polycrystalline devices [65, 66]. (19) µ no and τ po are the band mobility of the free carriers. This expression has been obtained by neglecting diffusion currents and is valid only for thin cells, strong fields in the space charge layer, and low defect densities in the space charge layer [57]. Fig. 6. An equivalent circuit for photovoltaic thin film solar cells and modules. The current sink (dashed lines) takes into account the current losses due to recombination in the space charge layer of the device [57]. VII. DYE-SENSITIZED SOLAR CELLS Dye-sensitized solar cells are in the same family of thin film solar cells. These cells are semiconductors formed between a photosensitized material and an electrolyte to generate current from light. Because of these semiconductors, the cell has large capacitors notable to be included in its model as shown in Figure 7. The cell can be modeled through electrochemical impedance spectroscopy [58]. Some models consider distributed elements similar to an electrical transmission line [59], while others point out a concentrated model [60, 61]. The equivalent circuit model of a dye-sensitized solar cell with capacitance is shown in Figure 7. Fig. 8. A double-diode equivalent circuit for the ideal solar cell. The I-V characteristics of double-diode equivalent circuits can be obtained by eV eV I = I L − I D1 − I D2 = I L − I01 exp − 1 − I02 exp − 1 , (20) kT mkT where m is the ideality factor of diode D2 ,and I01 and I02 are inverse saturation currents of diodes D1 and D2, respectively [64, 67]. The current source IL models the photocurrent source, I01 represents the first diode saturation current density resulting from the thermal generation of minority carriers, and I02 represents the second diode saturation current density resulting from the generation recombination [68]. A more accurate mathematical expression of the double-diode model for a single solar cell is identified as two-exponential transcendental models [69]. This can also be represented as a doublediode model [63], [66], [70], [71], [77], and two resistors, Rs and Rsh to determine the ohmic losses and the shunt leakages, respectively [64, 68]. The model is represented by e(V + IRs ) e(V + IRs ) V + IRs . (21) I = IL − I01exp −1 − I02exp −1 − kT mkT Rsh 1486 Figure 9 illustrates the equivalent circuit of the is shown in. R sh and Rs resistances are functions of externally applied voltage and are non-linear in nature. The parallel resistance can be modeled V as a constant value as R sh ≅ int . The series resistance is a variable IL Fig. 9. A double-diode lumped model equivalent circuit. The shunt resistance represents the loss of internal solar cells due to charge recombination, and the series resistance represents the charge extraction process. Ho and Morgan [72] used the double-diode model to represent the SPICE modeling of cascade solar cells [73, 74]. This model is used when the series resistance of two diodes cannot be separated. Several studies have identified the parameters of double-diode models [54, 75]. For instance, Veissid [75] used the standard deviation method to obtain the parameters. This method models the reverse bias currents as eV (22) I 01 = N 1T 3 exp − G , kT 3 eV (23) I02 = N2T 2 exp − G , 2kT where N1 and N2 are constant values. Polycrystalline cell model elements have been identified by Gow and Manning [63]. that depends on the magnitude of the current across it and can be represented [4] as R s = Vint − V . The magnitude of internal voltage is I net Vint = (I L − I − f (V ))Rsh , and the net current flowing through the series resistance is I net = I L − I − f (V ) . X. SUMMARY Commercially available solar cells are manufactured in various material types and are used in a variety of applications. 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