CALFLO™ AF Heat Transfer Fluid Introduction Features and Benefits Petro-Canada CALFLO™ AF is a highly efficient heat transfer fluid formulated to lower operating costs in systems where fluid resistance to oxidative breakdown is critical. • Better oxidative resistance than leading competitors can extend fluid life and lower operating costs. • Higher resistance to oxidative breakdown versus leading competitive fluids. CALFLO AF’s unique chemistry starts with a blend of 99.9% pure base fluids, produced using the HT purity process. These crystal clear fluids are free of impurities that can hinder performance. Utilizing more than 25 years of formulating experience, Petro-Canada fortifies these thermally stable fluids with specially selected additives to provide stronger resistance to oxidative breakdown than leading competitive fluids. Applications Petro-Canada CALFLO AF is recommended for use in non pressurized, liquid phase, closed heat transfer systems operating at bulk temperatures up to 316°C (600°F). CALFLO AF’s outstanding resistance to oxidative breakdown can result in longer fluid life and lower operating costs in systems where exposure to air cannot be avoided, and oxidation is the most likely form of fluid degradation. Typical applications include temperature control units used in plastic extrusion, plastic moulding, and metal diecasting operations. –significantly reduce a fluid’s thermal efficiency –make the fluid more difficult to circulate through the heat transfer system –result in overheating of the fluid –necessitate a costly, premature fluid change-out CALFLO AF demonstrates significantly better resistance to viscosity increase versus a leading specialty fluid in a severe oxidation test conducted at an independent industry laboratory: FLUID THICKENING WITH OXIDATION IP 48/97 (modified) Oxidation Test 200°C (392°F) 1400 Viscosity Increase (%) The result is CALFLO AF, a heat transfer fluid that provides high thermal efficiency in systems operating up to 316°C (600°F). CALFLO AF’s breakthrough chemistry can extend fluid life longer than leading competitive fluids, lowering operating costs by reducing the frequency of fluid change-outs. As a fluid oxidizes, it becomes more viscous. This increase in viscosity can: 1200 1000 Significant thickening 800 600 400 200 0 CALFLO™ AF Leading Major Oil Company’s Fluid Leading Specialty Supplier’s Fluid Testing conducted at an independent laboratory • Less prone to carbon residue and sludge formation versus leading competitive fluids. CALFLO AF’s resistance to oxidative breakdown also minimizes the formation of carbonaceous deposits and sludge within heat transfer systems. These deposits can dramatically reduce heat transfer efficiency and increase operating costs. What is the HT difference? Petro-Canada starts with the HT purity process to produce water-white, 99.9% pure base oils. The result is a range of lubricants, specialty fluids and greases that deliver maximum performance for our customers. CALFLO AF demonstrates significantly better resistance to carbon residue formation versus a leading major oil company’s fluid and a leading specialty supplier’s fluid in a severe oxidation test conducted at an independent industry laboratory: CARBON RESIDUE FORMATION IP 48/97 (modified) Oxidation Test 200°C (392°F) Increase in Carbon Residue with Oxidation (%wt) 2.5 Significant carbon residue 1.0 0.5 0 CALFLOTM AF Leading Major Oil Company’s Fluid Leading Specialty Supplier’s Fluid Testing conducted at an independent laboratory Even at mild 135°C (275°F) temperature conditions, a second laboratory study conducted by PetroCanada Research and Development demonstrates CALFLO AF’s stronger resistance to sludge formation versus a leading major oil company’s fluid: SLUDGE FORMATION † Cincinnati Milacron Test †Aluminum test fixture was not used 80 Sludge Formation (mg/100ml) 70 60 50 40 • CALFLO AF does not require special handling. Shipments and storage of CALFO AF do not normally require special safety permits. Empty drums used to transport CALFLO AF are readily accepted by drum re-conditioners. In addition, used CALFLO AF may be responsibly disposed in the following ways **: • through re-sale to used oil recycling companies • in some jurisdictions, combined with BTU recovery systems Operational Considerations CALFLO AF’s high thermal stability provides long service life under normal operating conditions up to its maximum recommended temperature. However, actual fluid life is dependent upon system design and operating practice. Significant sludge 30 20 10 0 CALFLOTM AF • Unlike some alternative fluid chemistries, CALFLO AF is virtually odourless and is not considered a toxic* substance according to OSHA (United States), WHMIS (Canada) and EUDPD (Europe) criteria. • Because CALFLO AF produces no objectionable odours and is not a respiratory or skin irritant, workplace conditions remain pleasant and safe for continuous operations. 2.0 1.5 • No compromise to environmental and workplace health and safety. Leading Major Oil Company’s Fluid Leading Specialty Supplier’s Fluid Testing conducted by Petro-Canada Research & Development • Low vapour pressure can save on top-up costs while improving workplace safety. • CALFLO AF’s low vapour pressure can reduce or eliminate fluid leakage from control valves and pipe flanges. • Reduction or elimination of leaks provides a cleaner and safer operating environment, and results in operational savings by reducing the need for cleaning, maintenance and fluid top-up. • Natural lubricity extends operational savings. • CALFLO AF’s natural lubricating properties can also reduce maintenance costs by extending the service life of circulating pumps and other rotating parts. Special precautions should be taken to avoid operating conditions that can shorten fluid life. These include: • thermal shocking resulting from accelerated system temperature increases • thermal shocking from hot spots on a system’s heating coils • continuously running above the maximum recommended operating temperature Although CALFLO AF is highly resistant to oxidative breakdown, excessive air and water contamination can reduce thermal efficiency and shorten fluid life. Where practical, Petro-Canada recommends inert gas blanketing of a system’s expansion tank to guard against exposure to air and water and the need to change-out the fluid prematurely. While CALFLO AF has been formulated to resist breakdown when exposed to air and water, contamination with process chemicals or deteriorated residual fluids can shorten fluid life. To maximize system efficiency and fluid life, Petro-Canada highly recommends system cleaning and flushing to remove all contaminants, sludge and varnish prior to recharging a system with CALFLO AF. Thermal Data PROPERTY TEMPERATURE 15°C (59°F) 38°C (100°F) 260°C (500°F) 316°C (600°F) Density, kg/L (lb/ft3) 0.867 (54.1) 0.852 (53.2) 0.715 (44.7) 0.681 (42.5) Thermal Conductivity, W/m K (BTU/hr.°F.ft) 0.142 (0.082) 0.141 (0.082) 0.130 (0.075) 0.127 (0.073) Heat Capacity, kJ/kg K (BTU/lb. °F) 1.89 (0.45) 1.96 (0.47) 2.69 (0.64) 2.88 (0.69) Vapour Pressure, kPa (psia) 0.00 (0.00) 0.00 (0.00) 3.78 (0.55) 15.32 (2.20) For detailed heat transfer calculations please refer to our Engineering Assistant software which is available at no cost from your Petro-Canada representative. Typical Performance Data PROPERTY TEST METHOD RESULTS Colour ASTM D1500 Pour Point, °C (°F) ASTM D5950 -42 (-44) Flash Point, COC, ° C (°F) ASTM D92 225 (437) Fire Point, °C (°F) ASTM D92 240 (464) Autoignition Temperature, °C (°F) ASTM E659 343 (649) Viscosity, cSt at 40°C (104°F) ASTM D445 cSt at 100°C (212°F) cSt at 316°C (600°F) <0.5 32.1 5.4 0.7 Average Molecular Weight 371 Neutralization Value, TAN, mg KOH/g ASTM D664 < 0.1 Sulfur by XRF, wt% ASTM D4294 < 0.0001 Conradson Carbon Residue, wt % ASTM D189 Coefficient of Thermal Expansion, %/°C (%/°F) Distillation Range, °C (°F) ASTM D2887 10% 50% 90% 0.01 0.0907 (0.0504) 365 (689) 417 (783) 475 (887) The values quoted above are typical of normal production. They do not constitute a specification. *non-toxic defined as non-controlled under WHIMIS, non-hazardous under OSHA and non- dangerous under EUDPD. ** Any transport and disposal practice must be in compliance with federal, state, and provinical and/or local laws and regulations. TEMPERATURE F 0 100 CALFLO AF VISCOSITY 3 0.140 800 0.081 50 0.079 0.077 0.135 700 45 0.077 0.075 0.130 600 0.079 0.135 0.130 1 0.073 0.125 0.1 0.125 0.071 100 0 0 0 0 200 100 100 300 200 400 300 100 200 500 400 200 600 700 500 600 700 TEMPERATURE O F TEMPERATURE F W/m. K 0.145 0.140 60 55 3.0 900 2.8 0.135 50 2.6 800 7000.077 45 700 2.2 0.130 0.075 600 0.073 40 2.0 600 1.8 0.125 0.081 800 0.079 0.071 2.4 35 0 0 100 100 200 200 300 40 0.075 0.073 35 0.071 0 100 200 300 400 0 100 200 300 400 0 100 200 0 100 200 500 600 700 F 500 TEMPERATURE 600 700 TEMPERATURE OF 300 TEMPERATURE C 300 TEMPERATURE O C CALFLO AF HEAT CAPACITY kg/m3 kJ/kg K lb/ft3 9000.083 0.083 55 300 300 O TEMPERATURE C TEMPERATURE C CALFLO AF DENSITY kg/m3 Btu/h.ft F 300 300 TEMPERATURE C C TEMPERATURE 200 200 3 Btu/h.ft OF 60 0.081 10 100 100 CALFLO AF THERMAL CONDUCTIVITY kg/m lb/ft W/m. K 0.145 900 W/m. K cStBtu/h.ft F 0.145 100 0.083 0.140 00 300 TEMPERATURE C 200 300 400 400 lb/ft3 Btu/lb O F 60 0.75 0.70 55 0.65 50 0.60 0.55 45 0.50 40 0.45 35 0.40 500 600 700 O F 600TEMPERATURE 700 500 0 0 100 100 200 200 300 300 400 400 500 500 600 700 600 700 TEMPERATURE TEMPERATURE OFF TEMPERATURE F 0 0 kg/m3 900 800 700 kJ/kg K 3.0 60 2.8 55 2.6 2.4 2.2 2.0 600 lb/ft3 100 200 200 kJ/kg K 0.75 3.0 0.70 2.8 0.65 2.6 0.60 2.4 0.55 45 2.2 0.50 40 2.0 0.45 1.8 0.40 0 1.8 0 100 0 100 200 200 300 100 Health and Safety 0 0 0 300 TEMPERATURE O C 300 TEMPERATURE C Btu/lb F 50 35 100 100 300 400 200 400 500 500 600 700 600 700 TEMPERATURE F TEMPERATURE F 200 300 300 TEMPERATURE C TEMPERATURE C 100 100 300 300 TEMPERATURE TEMPERATURE O C C 200 200 Btu/lb F 0.75 0.70 0.65 0.60 0.55 0.50 0.45 0.40 0 100 0 200 300 100 400 200 500 600 700 TEMPERATURE F 300 TEMPERATURE C To obtain Material Safety Data Sheet (MSDS), contact one of Petro-Canada’s TechData Info Lines. TechData Info Lines Btu/lban F existing customer looking to place an order, If you are 0.75 please call a Customer Order Management Representative at: kJ/kg K 3.0 0.70 2.8 0.65 Canada (English). . . . . . . . . . . . . . . . Phone 0.60 2.4 (French). . . . . . . . . . . . . . . . Phone 0.55 United States . . . . . . . . . . . . . . . . . . Phone 2.2 0.50 Latin America/Europe/Asia. . . . . . . . Phone 2.0 2.6 1.8 0.45 0.40 1-800-268-5850 1-800-576-1686 1-877-730-2369 +1-866-957-4444 You can also at lubecsr@suncor.com 0 e-mail 100 us 200 300 400 500 600 700 TEMPERATURE F 0 100 IM-7852E (2014.04) Petro-Canada is a Suncor business Trademark of Suncor Energy Inc. Used under licence. ™ 200 300 TEMPERATURE C If you would like to become a Petro-Canada lubricants customer and require more information about specialty fluids, oils and greases that can help maximize your equipment performance, savings and productivity, please contact us at: North America. . . . . . . . . . . . .Phone Europe . . . . . . . . . . . . . . . . . . Phone Germany. . . . . . . . . . . . . . . . . Phone China. . . . . . . . . . . . . . . . . . . Phone 1-866-335-3369 +44 (0) 121-781-7264 0800-589-4751 +86 (21) 6362-0066 Visit us on the web at lubricants.petro-canada.com