Considerations for Designing Power Electronic Devices Based on Advanced SiC Technologies By Mark Loboda, Chief Scientist-Compound Semiconductors, Dow Corning Electronics Solutions Improvements in crystal quality Growth of SiC crystals is generally performed through sublimation (physical vapor transport) or chemical vapor deposition. Specific methodologies to control defect densities in large crystals are proprietary and closely guarded secrets. Since 2009, publications by the State University of New York and Dow Corning have demonstrated significant progress in the reduction of dislocations in SiC1. Dow Corning is now exploiting these defect reduction methods in recent efforts to supply 150-mm diameter substrates to the market. Thus, even at mainstream production volumes, 150-mm diameter SiC wafers are an expensive platform for device development, especially if the quality is poor. So, to take full advantage of large substrates, wafer makers must support high production yields by minimizing defects in the material – or at least maintaining defect densities offered by smaller wafers. In addition, the performance of epitaxial film parameters and the device fabrication process must also be sufficient to use the entire 150-mm wafer surface. 1 Darren Hansen, M.J. Loboda, Roman Drachev, Edward Sanchez, Jie Zhang, Eric P Carlson, Jianwei Wan and Gil Chung (2010). Defect Reduction in SiC Growth Using Physical Vapor Transport. MRS Proceedings, 1246 , 1246B01-04 doi:10.1557/PROC-1246-B01-04. M. Dudley, S. Byrappa, H. Wang, F. Wu, Y. Zhang, B. Raghothamachar, G. Choi, E. K. Sanchez, D. Hansen, R. Drachev, and M.J. Loboda,Analysis of Dislocation Behavior in Low Dislocation Density, PVT-Grown, Four-Inch Silicon Carbide Single Crystals, Material Research Symposium, San Francisco, CA, April 4-9, 2010. M. Dudley, S. Byrappa, H. Wang, F. Wu, Y. Zhang, B. Raghothamachar, G. Choi, E. K. Sanchez, D. Hansen, R. Drachev, and M.J. Loboda, Characterization of 100 mm Diameter 4H-Silicon Carbide Crystals With Extremely Low Basal Plane Dislocation Density, Materials Science Forum, 645-648, (2010) p.291. By far the most recognized defect and primary concern impacting adoption of large area SiC wafers is a form of screw dislocation called micropipes. But basal plane defects are also a concern – particularly for bipolar device designs. As Dow Corning developed its crystal technology to achieve 150-mm crystals, low micropipe performance was maintained at <1/cm2. In addition to minimizing these defects, Dow Corning also maintained low levels of both basal plane and threading edge dislocations. This is evident in the figure below. Comparison of Defects in 4H-SiC Wafers Expansion Crystals range 100-140 mm diameter. 100 mm Expansion Crystals Defect Density (cm-2) Silicon carbide (SiC) is increasingly viewed as the material of choice in the design of next-generation power electronics devices. But despite the clear performance advantages SiC provides over conventional silicon, widespread industry adoption of SiC has been limited to date. This is due to a number of outdated concerns over controlling defect densities in SiC substrates and the material’s physical idiosyncrasies. 3000 Screw 3000 2500 2500 2000 2000 1500 1500 1000 1000 500 500 0 0 -500 -500 100 mm Expansion Crystals BPD Wafer Diameter Another traditional concern has been that surface defects generated during the chemical vapor deposition (CVD) epitaxy process would limit SiC device yields. Today, these defects are the most likely to inhibit or kill device performance.2 Current state of the art in epitaxy defects depends on the film thickness target, and defect density of 1.5 to 2.0/cm2 is typical for wafers used in applications below 2 kV blocking voltage. The recent development of batch manufacturing epitaxy technology has supported the integration of 150-mm wafers. This technology has helped to assure continuity in epitaxy defect performance between 100-mm and 150-mm product generations. In addition, this epitaxy capability spans both n2 M.J. Loboda, G. Chung, E. Carlson, R. Drachev, D. Hansen, E. Sanchez, J. Wan, J. Zhang, “Advances in SiC Substrates for Power and Energy Applications,” CS MANTECH Conference Digest, presented at Compound Semiconductor MANTECH Conference, May 16th-19th, 2011, Palm Springs, California. and p-type dopants and the CVD process technology enables thickness ranges to >50 microns for high-voltage applications. These capabilities help promote 150-mm diameter substrate technology in all types of SiC device design strategies. Influences on SiC Device Cost Once low defect densities have been achieved, the value of larger SiC wafers becomes intuitive thanks to simple geometry. To date, SiC device work has been based on 76-mm and 100-mm diameter substrates. Compared to silicon devices made on 150- to 200-mm diameter wafers, the cost to manufacture devices on SiC substrates can be high due to the SiC wafer cost plus the additional costs to accommodate wafers of diameter smaller than 150 mm in the manufacturing process flow. With the advent of 150-mm diameter SiC substrates, device manufacturing costs can be reduced due to the increase in substrate size (e.g. increased device count per wafer fabrication pass). For device manufacturers who make special efforts to use 100-mm diameter substrates today in a manufacturing line designed for larger diameter wafers, there is the potential for additional savings. substrate with a larger number of die compared to a conventional silicon power device design. Clearly, as die count per wafer increases, costs should decline. However, it is important to note that the relationship between substrate costs and device manufacturing costs does not scale directly when die size is a variable. In simple terms for a fixed wafer diameter, the cost of the epiwafer (Wafer$) combined with the cost to execute the manufacturing and testing process (Fab$) represent the total manufacturing costs. Good manufacturing economics require that total costs taken relative to the number of dies per wafer should be a constant: (Wafer$ + Fab$)/(Device Count) = Constant As the price of the wafer increases, Fab$ costs generally do not change. Yet, with higher wafer price, the cost to manufacture devices using SiC will also increase, unless a larger die count is achieved. Consider the equation: (Wafer1$ + Fab$)/(Device Count1) = (Wafer2$ + Fab$)/(Device Count2) = Constant The potential manufacturing throughput requirements of SiC can be estimated by considering the case for 150-mm wafer diameters. For this example, Fab$=1000, silicon wafer costs=$100 and the ratio of the SiC/Silicon wafer price cases are 20x, 10x and 5x. This example is close to that for a power transistor, and it illustrates the typical decline in new wafer price as use volume increases. Wafer Cost Ratio 20 10 5 That raises the question of whether or not SiC devices can be manufactured at a cost point able to yield a device product that is cost competitive with silicon power devices in system applications. SiC’s properties enable design of power devices with smaller area. This offers the opportunity to populate a Relative Device Count for Constant Device Cost 2.6 1.7 1.3 The column on the right above indicates the fractional increase in the number of devices on a wafer, or the fractional reduction in die area of the SiC device necessary to achieve device fabrication cost parity with an equivalently specified silicon device. The properties of SiC, particularly its thermal conductivity, allow a device design strategy implementing a 2x reduction in die area. This calculation indicates that for Si and SiC there can be a large differential in price between wafers of the same size, but the cost to fabricate devices can be comparable. SiC Device Design and Fabrication As high-crystal quality 150-mm SiC substrates achieve commercial maturity over the next few quarters, examining integration and design considerations will become more and more important. Maximizing the benefits of SiC’s high voltage and thermal conductivity properties (compared to silicon) is critical to achieving successful device and system designs. Awareness of other high-performance properties of SiC wafers is also important in order to achieve successful device performance: Transparency. SiC wafers are transparent. This property can lead to some difficulty in photolithography utilizing steppers, in automated defect detection and in automated wafer handling. Automated defect detection may misidentify features below the surface as surface defects. In wafer handling, sensors set up for opaque materials may respond incorrectly, resulting in wafer breakage during load/unload events. Dopant Incorporation. Implantation and activation of dopant atoms in SiC is more challenging than in silicon. Dopant diffusion is extremely small compared to silicon. Implant activation in SiC requires temperatures in excess of 1500 C, and during this process the wafer surface must be adequately protected to prevent roughening. Activation efficiency may be lower than silicon, and total activation varies with the total dopant concentration. Substrate Resistivity. SiC substrates have higher resistivity than silicon substrates. Since the epitaxy thickness used in SiC designs is small compared to silicon, the SiC substrate can contribute more to the series resistance of a device. Ohmic contact formation on SiC wafers often requires high temperature anneal (T>800 C). This step must be performed early in the device fabrication flow since the anneal temperature may be detrimental to subsequent device processes. Process optimization is important to assure series resistance effects resulting from the ohmic contact are minimized, and optimum low forward voltage drop performance in SiC diodes and metal-oxide semiconductor field-effect transistors (MOSFETs) is achieved. Defects. The most critical defect associated with SiC devices are polycrystalline surface defects that form on the wafer surface during epitaxy. These killer defects are easily detected with automated optical spectrometry techniques. Surface protrusion from defects can lead to comet formation in photoresist layers, and result in fabrication failures in areas of the wafer away from the defect. Inspection of photoresist is an important inprocess step to identify potential fabrication issues. Other defects can also be present that can limit the performance of devices. Very light damage from polishing processes can result in shallow linear defects on the epitaxy surface that will become decorated during metallization steps. These defects can lead to hot spots on the device in the region under the gate or in the edge termination areas. Device Attributes. SiC devices like Schottky diodes and MOSFETs exhibit positive temperature coefficients for the forward bias on state resistance. Many results have been reported in the literature and the device suppliers’ application notes that SiC devices exhibit lower conduction losses and switching losses compared to silicon-based devices. There are many models used when designing SiC devices. But the models, while improving, still show offsets from experimental data measured on fabricated devices. Care should be made to ensure materials properties entered in the model are consistent with those of the materials used to fabricate the devices. The model should be evaluated such that it reflects internal wafer and wafer-to-wafer variations of the substrate and epitaxy to provide leading indication of the distribution of results. Summary The outstanding properties of SiC are recognized as being advantageous for fabrication of power devices. Substrate costs and defect densities are now continuously decreasing. While not yet as mature and consistent as silicon, improvements continue and significant progress is underway to more fully understand the cause-and-effect relationships between the variations and defects in SiC substrates and devices. Through numerous collaborations and partnerships focused on the materials characterization and device fabrication, expertise in product specification and application development can accelerate the efforts of semiconductor device manufacturers to implement SiC in next-generation power devices and systems. Learn More To find out how Dow Corning can support your power electronics applications visit dowcorning.com/powerelectronics or email us at electronics@dowcorning.com. 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