Evaluation of Biodiesel in an Urban Transit Bus Powered by a 1981 DDCSV71 Engine A Joint Project with the National Biodiesel Board MSED REPORT #95-26713-2 Prepared By: Peter Howes 8~ Greg Rideout I+1 Envirotmement Environnement Canada Ccinada NOTICE This report has not undergone detailed technical review by the Technology Development Directorate the content does not necessarily reflect the views and policies of Environment Canada. Mention of trade names or commercial products does not constitute endorsement for use. This unedited version is undergoing a limited distribution to transfer the information to people working in related studies. This distribution is not intended to signify publication and if the report is referenced. the author should cite it 3s an unpublished report of the Directorate indicated below. Any comments concerning its content should be directed to: Environment Canada Technology Development Directorate Environmental Technology Centre Ottawa Ontario KIA OH3 Table of Contents Page 1.0 Abstract 3 2.0 Background 4 3.0 Vehicle Description 4 4.0 Facility and Equipment Description 5 Gaseous Emissions Measurement and Analytical Techniques Chassis Dynamometer Description Driving Cycles 5.0 Test Procedure 9 6.0 Results 10 Regulated Emissions 7.0 Discussion 14 8.0 Summary 20 MSED Report +%-16743-Z List of Tables Table 1. Vehicle Specifications Table 2. Aldehyde - Ketone Target Compound List Table 3. Target Compounds of Light Hydrocarbon Analysis Table 4. Target Compounds of Detailed Hydrocarbon Analysis Table 5. Exhaust Emission Test Cycles Table 6. Ls Diesel Results, Central Business District Cycle, g/mile Table 7. LS Diesel Results, Arterial Cycle, g/mile Table 8. LS Diesel Results, New York Bus Composite Cycle, g/mile Table 9. 820 Results, Central Business District Cycle, g/mile Table 10. 820 Results, Arterial Cycle, g/mile Table 11. B20 Results, New York Bus Composite Cycle, g/mile Table 12. 820 Results with Catalyst, Central Business District Cycle, g/mile Table 13. B20 Results with Catalyst, Arterial Cycle, g/mile Table 14. B20 Results with Catalyst, New York Bus Composite Cycle, g/mile Table 15. B20 Results with Timing Retard, Central Business District Cycle, g/mile Table 16. B20 Results with Timing Retard, Arterial Cycle, g/mile Table 17. B20 Results with Timing Retard, New York Bus Composite Cycle, g/mile Table 18. B20 Results with Catalyst and Timing Retard, CBD Cycle, g/mile Table 19. B20 Results with Catalyst and Timing Retard, Arterial Cycle, g/mile Table 20. B20 Results with Catalyst and Timing Retard, NYBComp Cycle, g/mile Table 21. Percentage Change in Emissions from the Baseline Tests, % List of Figures Figure 1. NOx Emissions, g/mile Figure 2. Particulate Emissions, g/mile Figure 3. NOx/Particulate Ratio Figure 4. Particulate Composition Figure 5. Hydrocarbon Emissions, g/mile Figure 6. Carbon Monoxide Emissrons, g/mile Figure 7. Average Formaldehyde Emissions, g.mile 2 #95-36743-2 MSED Report 1.0 Abstract The exhaust emission rates of regulated, as well other unregulated components of the exhaust, were determined for an urban transit bus which was operated on commercial low sulphur diesel, and also a twenty percent blend of methyl soyate with the base diesel. In addition to comparing the fuels further tests were conducted to examine the effect of ignition timing and catalytic exhaust aftertreatment. The exhaust emission tests were conducted on a heavy duty chassis dynamometer capable of simulating the inertia weight and road loads that urban buses are subjected to during normal on-road operation. The emissions of total hydrocarbons, carbon monoxide, carbon dioxide, oxides of nitrogen, carbonyls, and total particulate were determined for the bus over various transient chassis dynamometer driving cycles. In addition to these emission components the exhaust hydrocarbons were analysed for 55 individual hydrocarbons, while the particulate samples were soxhlet extracted to quantify the soluble organic fraction of the material. The test cycles included in the project were the Central Business District (CBD), the New York Bus Composite (NYBCOMP), and Arterial cycles. #95-26743-Z 3 MSED Report 2.0 Background The emissions from urban transit buses have been considered a significant source of pollutants such as particulate matter and nitrogen oxides for several years. These vehicles are visible to the urban population and hence their emissions of smoke and other odorous compounds are perceived as obvious contributors to urban air quality problems. In recent years stringent emission standards have been introduced which limit the emission rates from new engines, while for the in-service engines emission limiting legislation was implemented in the United States in 1994. Engine manufacturers have been investigating a number of options in the areas of engine design, fuel management, exhaust aftertreatment, and alternative fuels to reduce emissions from new engines to the levels dictated by legislation. However, this activity does not provide a solution to the numerous in-use diesel engines, particularly those that operate in densely populated areas such as urban centers where the emissions have a widespread effect on the general public. For the in-use segment of the heavy duty engine applications, the potential emission reduction opportunities which have been investigated include retrofit exhaust aftertreatment systems such as diesel catalytic converters and particulate traps, and the conversion of the diesel engine to alternative fuels. In this study, the Mobile Sources Emissions Division of Environment Canada, conducted exhaust emission tests on an urban transit bus which was operated on conventional diesel fuel, and also a blend of the base diesel with twenty percent methyl soyate. The tests were conducted under a joint program with the National Biodiesel Board. The objective of the test program was to determine the potential emission reductions of the Biodiesel, and also to optimise the engine to realise further emission reductions. The optimisation portion of the project included a timing retard and also the application of a flow through catalyst. The following report describes the procedures and results of the emissions testing program. 3.0 Vehicle Description The test vehicle was an in-use city transit bus powered by a conventional, diesel fuelled engine typical of the year of manufacture. The chassis was a forty foot Flexbl bus operated by the South West Ohio Regional Transit Authority equipped with a 1981 DDC 8V71 engine. Table 1 provides further details of the vehicle and engine. The diesel fuel used during the testing was a low sulphur fuel purchased from the Petro Canada refinery located in h4ontreal Quebec. #95-267-13-Z 4 MSED Report Table 1. Vehicle Specifications Test Vehude S.W Oh10 Reg. T.A Model year 1989 Engme Type DDC 8V71 Number of cylinders 8 Exhaust Aftertreatment None (baseline) Engelhard CMX Transmissmn Automatic, 3 speed AU intake Turbocharged Test Inerha Weight (pounds) 30,320 Test Road Load Horsepower 88.05 (@ 50 mph) 4.0 Facility and Equipment Description Gaseous Emissions Measurement and Analvticai Techniques Gaseous and particulate emissions were obtained using a large single dilution constant volume sampler, which utilised a stainless steel tunnel ten inches in diameter, and one hundred inches in effective length, coupled to a secondary dilution tunnel which enabled particulate collection in accordance with accepted test procedures (“), The flow rate in the main tunnel was 1500 SCFM during the studies. The raw exhaust from the vehicle was transferred from the exhaust pipe of the bus to the dilution system through a flexible stainless steel pipe 20 feet in length and 4 inches in diameter. The gaseous sampling zone of the dilution system was equipped with three probes. One sample probe was used to draw sample from the tunnel into tedlar bags for analysis. The other probes directed samples of the dilute exhaust through heated lines (191OC) to silica gel cartridges which had been treated prior to testing with 2,4 dinitrophenylhydrazine (DNPH) for carbonyl collection, and then through tenax cartridges to another set of small tedlar bags. A dedicated heated probe upstream of this zone was used for continuous sample collection for total hydrocarbon and nitrogen oxides measurement. A second probe in the same area of the heated probe, was used to direct a sample from the main tunnel to the secondary tunnel, where a second dilution occurred and sample was drawn through 70mm teflon coated glass fiber filters for particulate collection. The soluble organic fraction of the particulate sample was determined following the test through soxhlet extraction using methylene chloride. The emission rates of CO, C02, as well as THC and NOx, were also determined by collecting a proportional sample of the dilute exhaust in tedlar bags and analysing the contents of the bag using nondispersive Infrared instruments for CO and C02, c h e m i l u m i n e s c e n c e i n s t r u m e n t f o r NOx. a n d f l a m e lonisation detector for #95-26743-Z 5 MSED Report hydrocarbons. A second set of bag samples were analysed for the concentrations of these components in the background dilution air. The carbonyls in the dilute exhaust were collected on the DNPH coated cartridges. This method measures the phenylhydrzone derivatives, which are formed by the reaction of the DNPH solution and the carbonyls, and are a function of the carbonyl concentration in the dilute exhaust. Measurement of the derivatives was determined using High Performance Liquid Chromatography. The following Table outlines the target compounds for this analysis Table 2. Aldehyde - Ketone Target Compounds Formaldehyde Proplonaldehyde Methyl ethyl ketone Acetophenone Acetaldeyde Methoxyacetone Benzaldehyde m&p-Tolualdehyde 2-3 Butandlone Crotonaldehyde Isovaleraldehyde Methyl isobutyl ketone Acroleln Methacroleln Tnmethylacetaldehyde Pinacolone Acetone Iso - & butyraldehyde Valeraldehyde Hexanaldehye During each of the tests, samples of the dilute exhaust were directed through a tenax cartridge. The cartridge traps the hydrocarbons with seven or more carbon atoms, with the remaining sample, the Cl to C6 hydrocarbons collected in separate tedlar bags which were connected in series with the tenax. These samples were subjected to analysis by gas chromatography to quantify the amount of methane and selected non-methane hydrocarbons. The light hydrocarbon (LHC) method employs a Hewlett Packard 5890 Series II gas chromatograph with an FID. The instrument is controlled and data is acquired and analysed via the Hewlett Packard 3365 Series II DOS ChemStation. A manually controlled valve injection of the gas sample is made directly on-column using a Valco 6 port heated valve is used. The target species for the LHC method are summarised in Table 3. The method is calibrated between 15 and 0.15 ppmV for each component, except Methane which is calibrated in the range 0.15 to 300 ppmV. The detection limit for the C,-C, compounds is approximately 0.03 ppmC and for Methane is 0.09 ppmC. Table 3. Target Compounds of Light Hydrocarbon Analysis Methane Propylene Ethylene Propane Acetylene Ethane Propyne n-Butane The detailed hydrocarbon speciation analysis is accomplished using cryogenic concentration followed by high resolution GC-FID separation and detection. The instrumentation consists of the ENTECH L a b o r a t o r y A u t o m a t i o n a u t o m a t e d V O C preconcentrator Model hf2000, a Hewlett Packard model 5890 Series II gas if95-26743-2 6 MSED Report chromatograph and the Hewlett Packard model 3365 Series II DOS ChemStation instrument control, data acquisition and analysis software. The ENTECH concentrator uses a two-stage cryogenic trapping technique to selectively retain the hydrocarbon species in a packed trap and to allow N, 0, and Ar to pass through. A known volume of sample gas (in the present case, 50 mL) is passed through a length of nickel tubing packed with glass beads and an adsorbent held at sub-ambient temperatures (-168°C). During this step the VOC’s are selectively retained on the cryogenic trap. A second trap made of deactivated fused silica tubing (0.53 mm i.d.) is cooled to -190°C and the first trap is heated quickly to 200 “C to transfer the VOC’s to the second trap. This second stage serves to focus the sample into a very small volume (CO.01 mL) for injection onto the analytical column. The focusing trap is then heated very quickly (600 “C/min) to perform the injection of the sample. A nafion membrane dryer is also used to selectively remove water vapour from the sample stream before injection. The VOC method is calibrated for 55 C2-C,, hydrocarbon species. The table below provides a complete list of target species. The method was developed for speciation of gasoline fuelled vehicle exhaust samples, and as such emphasises the lighter compounds. This list accounts for approximately 80% of the total mass emissions of gasoline exhaust samples. With heavier fuels (diesel, etc.) the fraction of total mass emissions accounted for decreases. The laboratory is currently extending the mass range of the analysis. Table 4. Target Compounds of Detailed Hydrocarbon Analysis ethylene acetylene ethane propylene i i?$jEe isobutylene I-butene 1,3-butadiene n-butane t2-butene 22-dm-propane 1 -butyne $95-26743-2 cyclopentane dt4m2-pentene 2m-pentane 3m-pentane 2ml-pentene/l-hexene n-hexane Ghexene 2m2-pentene t3mZ-pentene c2-hexene c3m2-pentene m-cyclopentane 1 m-cyclopentene benzene d-butene cyclohexane 3ml-butene Zm-butane 2ml-butene I-pentene 2-butyne n-pentane Gpentene c2-pentene 2m2-butene 22dm-butane cyclopentene 4ml-pentene 7 cyclohexene iso-octane n-heptane m-cyclohexane toluene 1 m-cyclohexene n-octane e-benzene m&p-xylene o-xylene n-nonane 124-trnbenzene n-decane MSED Report Chassis Dvnamometer Descrintion The chassis dynamometer used in the study was a Clayton Heavy Duty Vehicle Emission Dynamometer with twin rolls (split) 8.65 inches in diameter, 120 inches in length, and 20 inches between roll centers. Inertia simulation was selected through mechanical flywheels with electric compensation, while Road Load was simulated by an 300 horsepower electric DC motor. Maximum inertia and road load of the system is 45000 pounds, and 150 horsepower at 50 miles per hour. The rotating speed of the dynamometer rolls during a vehicle emissions test is measured by a pulse counter, which communicates this information to a microprocessor controller. The controller translates the pulses into the linear speed of the vehicle and it is displayed on a video screen as a cursor. The vehicle driver then uses the cursor to follow a selected speed versus time trace. In this way, the vehicle may be operated over a selected transient operation or driving cycle. The chassis dynamometer testing procedures followed for this type of emissions testing are outlined in a USEPA report entitled “Recommended Practise for Determining Exhaust Emissions from Heavy Duty Vehicles Under Transient Conditions” (‘). The exhaust sampling and vehicle set-up procedures were similar to those described for light duty emissions certification(3’ . The electronic programming feature of the dynamometer controller allows for a speed-power curve for each test vehicle. To calculate the curve the following equation was applied (? RLP= F * 0.67 * (H - 0.75) * W * (V/5O)3+ 0.00125 * LVW * (V/50) where: RLP = Road Load Power in Horsepower F = 1.00 for tractor trailers, 0.85 for urban buses H = Average maximum height in feet ‘CY = Average maximum width in feet LVW= Loaded Vehicle Weight in Pounds V = Vehicle Speed (mph) According to the procedure recommended by the US EPA, the inertia setting for the bus should be equal to the sum of the empty bus weight, half passenger load and the drover at 150 pounds each, and the equivalent inertia of the non-rotating wheel assemblies. 8 #95-26743-2 MSED Report Driving Cvcles The driving cycles for the exhaust emissions testing were the Central Business District (CBD), the New York Bus Composite Cycle (NYBUS), and the Arterial Cycle. Table 5 provides details of the test cycles while graphical representations of the speed versus time data for these driving cycles have been enclosed in the appendices of the report. TABLE 5. Exhaust Emission Test Cycles Test Duration (seconds) Distance (miles) Average Speed mph CBD 600 2.06 12.37 New York Bus Comp 1,030 2.51 8.77 Artenal 373 2 19.3 5.0 Test Procedure The test procedures which were followed for the exhaust emission testing of the heavy duty vehicle were outlined in the US-EPA report entitled “Recommended Practise for Determining Exhaust Emissions from Heavy-Duty Vehicles Under Transient Conditions”. The calculations of exhaust emissions and fuel economy were performed in accordance with the US-EPA Code of Federal Regulation, Schedule 40, Part 86. The bus was located on the dynamometer with the drive wheels cradled between the twin rolls of the dynamometer. Wheel chocks were placed in front of the vehicles steering wheels, and chain restraints located in the test cell floor were attached to the rear frame assembly of the vehicle as a safety precaution. The exhaust outlet pipe of the vehicle was connected to a heated, 4 inch diameter 20 feet in length, flexible stainless steel pipe, which was also connected to the inlet of the dilution tunnel. Fans were located in the vicinity of the drive wheels to create air flow across the tires and remove the heat generated ,by the tire to dynamometer roll contact During each of the test days the vehicle was brought to operating temperature by operating the vehicle at various steady state speeds. Following the warm-up the emission tests were conducted as hot starts. Driver variability was eliminated from the results by using the same technician for all of the vehicle testing. In general three repeats of each driving cycle were conducted in series, with a 3 minute “soak” between each repetition. Where it was identified that additional tests were required on a particular cycle, additional tests were conducted after an engine warm-up. The bus was first tested using low sulphur diesel. This was accomplished by plumbing both a supply and return line into a barrel of test fuel located beside the bus in the test cell. The results of this testing were to be considered as the baseline emissions of the bus and weye compared to data obtained from other vehicles of the type to ensure the 9 #?5-267G-3 MSED Report proper operation of the engine. At the conclusion of the baseline testing the bus was prepared for emissions testing on the Biodiesel fuel by replacing the baseline fuel with a barrel of the blended fuel, and purging the vehicle of any remaining baseline fuel. The following is a timetable of the test configurations which were examined in the project; i) Baseline testing on low sulphur diesel ii) Biodiesel testing iii) Biodiesel testing with exhaust aftertreatment iv) Biodiesel testing with engine timing retard v) Biodiesel testing with exhdust aftertreatment and engine timing retard. 6.0 Results Exhaust emission tests were conducted on an urban transit bus over various transient driving cycles. The following section provides the summarised results of this testing while the complete body of results are enclosed in the appendices of the report Regulated .._... . - . . .._...... _ .Emissions . . . . . . .._.......... Tables 6, through 20 list the emission rates of the regulated emissions (THC, CO, NOx, and particulate matter), and carbon dioxide over each of the tests conducted in the study. The formaldehyde (HCOH) and total aldehyde (RCOH) are presented in milligrams per mile while the other mass emission rates are in grams per mile. The percent soluble organic fractions @OF%) are also presented as well as the fuel economy in miles per U.S. gallon. The fuel economy was calculated using carbon balance. The arithmetic mean and standard deviation of the three tests in each vehicle/fuel configuration are presented in the Tables to provide an indication of the test repeatability. The differences between the configurations will be examined in the Discussion. 10 ti95-26743-2 USED Report Table 6. Ls Diesel Results Cl Itrill _ _ _ _ Blllsiness Dislricl E/mi rust I Trst 2__ rest 3 ;tDev r Table 8. LS Diesel Results N.Y Bus ( jmpc 1s#ite C cle ii wA rest 1 rest 2 Test 3 Mean $lDev Table 7. LS Diesel Red Is Ari ‘rid < rcle f mi 1rest i rest 2 Test 3 Mean SitDev Tl IC 2.71 2.79 3.23 2.91 0.23 TI IC 2.71 2.52 2.48 2.57 CO 43.77 11.11 45 07 43.31 1.65 co 21 .oo 21.26 23.91 22.07 NOX 32.79 28.31 26 74 29.28 2.56 NOx 24.61 24.84 28.45 25.97 CO2 2,8h? 2,786 2,875 2,841 39 co2 2,556 2,601 2,645 2,600 Phi 0.91 O.YY 0 86 0.92 0.05 PM 2.01 1.24 1.12 1.46 SOFZ 40.5 54.9 56.5 50.6 7.2 SOP% 71 .-I 49.4 36.5 52.4 HCOH 0.1 1 0.14 0.14 0.13 0.02 dCOH 0.13 0.12 0.12 0.12 RCOF T 0.19 0 25 0.22 0.22 0.03 7COH 0.25 0.21 0.18 0.21 hlPG 3.46 3.56 3.44 3.49 0.05 MPG 3.92 3.85 3.78 3.85 mi &De\ THC 317 h-a 11 hsirle: ss Di St rict 1 rest I __1 ‘cst 2 1rest 3 Tdean 1.98 2 01 1.99 1.97 0.03 CO 36.71 uI.12 32.83 35.89 2.24 NOx 32.08 32.52 13.78 32.59 0.45 NOx co2 2,729 1,792 2,789 2,770 28 Phf 0.68 0.65 0.64 0.65 SOFX 34.9 33.1 51.3 FICOH 0.11 0.13 RCOH 0.12 Ic11=c; 3.64 Table 9. B20 Results L Table 10. B20 Results Arterial Cvcle g/mi _I 0.1 1 THC 3.14 3.23 3.94 3.44 0.36 1.31 co 15.79 16.71 19.54 17.35 1.61 1.76 NOx 36.84 36.35 32.37 35.19 2.01 36 co2 2,755 2,758 2,839 2,784 39 0.39 PM 0.67 0.67 1.41 0.91 0.35 17.5 SOFZ 46 1 54.5 54.9 51.8 4.9 0.01 HCOH 0.15 0.13 0.18 0.16 0.02 0.03 RCOH 0.22 0.23 0.29 0.24 0.04 0.06 MPG 3.65 3.64 3.53 3.61 0.05 Table 11. B20 Results NYBus ComDosite C vc / :le g 1 7i Test 1blear jtDev 3.25 3.26 3.28 0.03 16.41 15.47 14.39 15.42 0.83 30.65 31.01 30.43 30.71 0.24 2,860 2,884 2,823 2,856 24 1.18 1.94 1.27 1.23 1.48 0.32 53.5 49.1 76.5 68.7 71.4 72.2 3.2 iCOH 0.07 0.08 0.21 0.17 0.17 0.18 0.02 0.04 KIOH 0.14 0.14 0.32 0.27 0.26 0.28 0.03 004 MPG 3.85 3.86 3.51 3.49 3.56 3.52 0.03 T rest 1 Test 2 Test 1 rest 2 THC 1.81 1.64 co 18.99 18.81 14.14 17.31 32.31 33.56 31.15 32.34 0.98 co2 2,605 2,601 2,497 0.02 PM 1.45 39.8 8.2 jOF% 0.12 0.12 0.01 0.19 0.18 0.16 3.56 3.57 3.59 3.32 11 #95-26743-2 2,568 50 -I- MSED Report ‘I’nhle 12. IS20 -Catalyst cc!I1 lral I Isine!jS Di;t -_ Test -_1 TM 2 rest 3 Results 2 g/ m i -- Table 13. 1120 -Catalyst Results Art rial C de g/ mi Tt1C 1.18 I.lb 0.98 1.11 0 09 THC 0.83 CO 1448 Y.32 9.92 11.24 2.31 c o NOX 2b.71 28.4Y 27.34 27.51 0.74 CO2 3,164 3,l b7 3;t 54 3,162 I’M 1.14 0.93 0.09 S@F% 19.1 37.1 I(‘01 I 0.07 <cotf hfPC &De1 0.73 0.77 0.04 TIIC 1.99 1.97 I.11 0.86 I .19 0.31 c o 3 31 NOx 25.15 25.41 25.55 0.41 NOx 5 co2 2,887 2,952 2,953 54 co2 1 .O2 0.09 PM 1.22 1.04 1.15 0.07 PM 30.2 28.8 7.4 ?-OF% 32.b 24.2 28.2 3.4 SOFX 0 07 0.05 0.06 001 3COH 0.0-l 0.03 0.04 0.01 HCOH 0.1 1 0.1 2 0.08 0.11 0.02 <co1 1 0 07 O.Ob 0.07 0.01 RCOH 3.19 3.19 3.21 3.21 0.01 AjPC 3.52 3.44 3.44 0.07 MPG ‘ rahlc I5. B20-Timing Retard Results Ct ltral Business District g/mi T&l Test 2 lest , Ts Mean Mean ;tDev Table 14. B20 -Catalyst Results NYBus Composite Cvcle z;/mi ‘Table 16. B20-Timing Retard Results Arterial ( 3Vde g mi Test; Test 1 &De\ 1.93 1.9b 002 3.85 1.66 3.94 0.56 32.36 32.22 32.06 32.21 0.12 3,104 3,147 3,138 3,130 18 0.88 O.8b 0.94 0.89 0.03 49.7 48.7 4b.5 48.3 1.3 0.11 0.09 0.09 0.09 0.01 0.18 0.16 0.15 0.16 0.02 3.27 3.22 3.23 3.24 0.02 _ I ’ Table 17. B20-Timing Retard Results NYBus Comnosite Cvcle g/mi rest 2 Test 3 Mear THC 2 51 241 TkIC 2.09 1.86 1.71 1.89 THC co 33.lh 33.27 c o 17.b7 21.18 22.55 20.47 c o NOx 23.15 21 82 NOx 20.48 20.72 22.62 21.27 NOx co2 2,x29 2,755 co2 2,363 2,628 2,688 2,559 co2 Phi 2.23 1 .b2 PM 3.28 1.78 1.56 2.21 PM iOF% 54.8 41.2 ?OF% bb.8 42.9 38.5 49.4 SOF% KOH 0.17 0.1-I 1COH 0.1 b 0.11 0.11 0.13 KOH KOH 0 2’) 0.21 KZOH 0.28 0.18 0.22 0.23 RCOH h/l PG 3.52 3.62 MPG 4.24 3.82 3.73 3.93 MPG 12 #95-26743-2 Mean Test 1 rest i cz rcsl 3.16 3.Ob 3.11 ll.b3 9.73 12.31 26.78 25.77 26.33 2,791 2,759 2,756 1.91 1.31 1.44 66.X 70.8 63.5 0.19 0.1 b 0.16 0.36 0.26 0.29 3.61 3.66 3.bS 1 MSED Report Table 18. PO-CXalyst with Timing Retard Results Table 20. B20-Catalyst with Timing Retard Results NYBus Composite Cl f(:le dmi Table 19. B20-Catalyst with Central Busmess District E/mi Trst 2 rest 3 Mem SLDcv 1.02 0.98 1.11 0.14 Timing Retard Results Arterial ( 27rcle 1 ’ mi rest 1 rest 2 rest 3 Mea11 ‘ M.hJ THC 0.91 0.76 0.73 0.81 0.08 1093 11.66 10.86 0.69 c o 0.84 0.97 0.86 0.89 0.06 33.51 34.99 31.43 4.05 NOx 32.53 33.04 32.62 32.73 0.22 2,980 3,069 3,048 49 co2 2,586 2,666 2,597 2,616 35 1.31 1.26 1.36 0.11 PM 2.03 1.39 1.03 1.41 0.41 27.8 22.9 30.1 6.9 SOF% -10.1 24.4 24.4 29.6 7.4 0.07 0.07 0.0x 0.02 0.05 0.01 0.04 0.04 0.01 0.13 0.12 0.14 0.04 0.1 0.08 0.07 0.08 0.02 3 39 3.29 3.32 0.05 HCOH RCOH MPG 3.93 3.81 3.91 3.88 0.05 13 #95-26743-2 Test 1 Test Test1 Mea11 1.87 THC 1.71 co 4.39 5.63 NOx 30.72 37.09 c o 2 2,683 3,081 Phi 1.33 1.11 SOFZ 56.1 38.4 -ICOH 0.13 0.1 XCOH 0.22 0.18 AVG 3.77 3.29 ‘ ;tDev 1.77 1.78 0.07 3.65 4.56 0.82 35.13 34.31 2.66 3,009 2,925 173 0.92 1.12 0.17 53.9 49.4 7.9 0.1 0.11 0.02 0.17 0.19 0.03 3.37 3.48 0.21 MSED Report 7.0 Discussion In this study three strategies for reducing the vehicle emissions were examined. First, the fuels effect on the engine out emissions was investigated by blending conventional diesel with methyl soyate. Second, the ignition timing was retarded to quantify the effect on the engine out emissions, and thirdly, catalytic exhaust aftertreatment was introduced and the effect on the tallpipe emissions was determined. While these three strategies were investigated separately, the interrelation between the biodiesel and the effectiveness of the oxidation catalyst must be considered. In the following Table the percentage change in the emission rates from the baseline to the other test cotigurations are presented. A minus sign indicates that the emissions were lowered, while a positive sign indicates an increase. Table 21. Percentage Change in Emissions from the Baseline Tests 820 B20 - CMX 820 - CMX - 8.5 B20 - 8.5 CBD -HC CBD - CO -31.5 -17.3 -61.9 -74.1 -62.3 -74.9 -16.5 -22.1 CBD - PM CBD - SOF -29.0 -21.5 10.9 43.2 47.7 -40.7 95.0 -13.1 ART ART ART ART - -21.5 24.3 -14.6 5.09 -94.6 -1.6 -19.8 46.2 -68.1 -95.9 26.0 -3.3 -43.5 -24.9 -7.2 -18.1 5‘4.2 -5.8 CBD - NOx CO NOx PM SOF 11.3 -6.0 7.4 -25.0 The primary target pollutants of the study were the particulate matter and nitrogen oxides. This was largely because of the contribution of these pollutants from urban buses to urban air quality pollutant inventories, and also the current regulatory climate for new and in use heavy duty diesel engines in the United States. Whenever control measures for particulate are examined, an important consideration is the interrelationship between particulate and NOx emissions, also referred to as the NOx/particulate trade off. In general, techniques used to decrease NOx normally result in an increase of particulate while the opposite is also true. For example, retarding the ignition timing of the diesel engine has been widely reported as a technique for NOx reduction, however this is accompanied by a particulate increase. The composition and quality of the fuel has aiso been demonstrated to have a direct effect on the exhaust emissions although the cause of these effects can be very complex and are not well understood. Coupled with the complexity of fuel effects is the scarcity of data in this area which examine the fuels effects over transient driving cycles representative of tvpicai urban bus operation. 13 #?5-26743-T MSED Report The following paragraphs provide a general discussion of the overall test results. Nitrogen Oxides and Pnrticulnte Emissiorls The following Figures compare the emission rates of nitrogen oxides and particulate matter over the three test cycles. Figure 1. NOx Emissions, Grams per Mile 1 i f?iJ CBD 0 ART NYcomp L LSD B20-10 deg B20-8.5 deg BZO-cat-10 deg B20-cat-83 deg Figure 2. Particulate Emissions, Grams per Mile LSD B20-10 deg B20-8.5 deg BZO-cat-10 deg B20cat-8.5 deg i In Figures 1 and 2, the fuel effect of the biodiesel can be examined by the first two sets of data points; the low sulphur diesel (LSD) and the biodiesel blend (B20). These tests were conducted with the original ignition timing and without exhaust aftertreatment. With respect to NOx emissions there was an increase during the CBD and Arterial driving cycles when operating on the 820 fuel blend in comparison to the baseline LSD. However, NOx emissions were reduced when operating during the NYComp cycle using B20 in comparison to the LSD. The particulate emissions were lowered by 29 percent with the introduction of the methyl soyate over the CBD cycle, and 14.6 percent over the Arterial cvcie. Conversely, the particulate emissions increased sigmficantly, bl.9 %, over the NYComp drlvmg cycle. 15 $9526743-2 MSED Report In combining the cycles for an equally weighted average emission rate, the percentage change in the NOx emission rate was found to be an increase by 5.7 percent, and the particulate emissions were increased by 2.8 percent. If the Arterial cycle is given a double weighting due to its large percentage of acceleration and cruise time, this percentage change in the emissions was a 9.9 percent increase for NOx, and a 2.6 percent decrease for particulate. The effect of the ignition timing retard on the NOx emissions is clearly evident in the previous Figures. A decrease in NOx was observed during the B20 tests with the timing set at 8.5 degrees without the catalyst installed over all three transient test cycles in comparison to tests with the timing set at 10 degrees. However when the timing was retarded from 10 degrees to 8.5 degrees and the catalyst was installed, there was an increase in NOx emissions observed during all three test cycles. Some tests of oxidation catalysts have reported an increase in NOx emissions, possibly as a result of complex chemical reactions in the catalyst however this phenomena appears to be temperature dependent. The equally weighted average of NOx over these three test cycles when retarding the timing from 10 degrees to 8.5 degrees yielded a decrease of 27.3 percent without the catalyst, and an increase of 15.5 percent with the catalyst installed. A similar trend in the NOx emissions are observed when the Arterial cycle is given a double weighting. The particulate emissions followed the expected NOx/particulate trade-off where NOx was decreased by retarding the timing and the particulate increased without the catalyst installed. With the introduction of exhaust aftertreatment the mass emission rate of the particulate was increased for all test cycles when the timing was retarded. On average the biodiesel particulate increased by 65.7 percent when the timing was retarded without exhaust aftertreatment. With exhaust aftertreatment installed,the particulate emissions increased by 29.1 percent when the timing was retarded to 8.5 degrees. The catalyst effectiveness is evident when comparing the tests conducted with or without exhaust aftertreatment at the same ignition timing. In this comparison the catalyst produced an average reduction of particulate from the untreated exhaust by 8.6 percent at the original timing, and by 28.8 percent at the 8.5 degree retard. The lowest overall particulate emission rate was produced by the following combination; original ignition timing, biodiesel, with Engelhard catalyst. The lowest overall NOx/Particulate ratio was found to occur with the catalyst in combination with the ignition timing retard, while the highest was with the B20 fuel blend, as shown in the following Figure. 16 #95-26743-I? MSED Report APPENDIX A. Regulated Emissions Test Results Al Baseline Diesel Tests #95-26743-I 23 USED Report Mobile Sources Emission Division of Environment Canada - Emissions Research Grow Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner / Operator Engine Model Engine Engine Cycle 95-86 S. W Ohio Reg. T A DDC 8V7 1 9.3 L V8 Diesel Non-Regulated Emission Sampling Required Soluble Organic Fraction Carbonyls voc Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) yes yes yes 0 15538 0.157 0.00162 THC Sample (ppm) THC Ambient (ppm) 31 82 8 62 CO Sample (ppm) CO Ambient (ppm) 192 66 2 69 NOs Sample (ppm) NOr Ambient (ppm) 92.20 1.60 CO2 Sample (%) CO2 Ambient (%) 0 84 0 05 Fuel Consumption mi/USgal 1 3.46 I Figure 3. NOx/Particulate Ratio B20 8 5 deg B20 LSD B20 cat 8 5 deg B20 ca The direct effect of the catalyst on the tailpipe emissions is most evident on the gaseous hydrocarbons and carbon monoxide. However, another target of the catalyst is the hydrocarbons which have condensed onto the particulate in the engine and exhaust system. These condensed hydrocarbons comprise the soluble organic fraction of the material. The following Figure compares the average mass of the non-SOF particulate material to that of the SOF. Figure 4. Particulate Composition, grams LSD B20 B20CMX B20CMX8 5 B20 8.5 In the tests, the SOF of the particulate was slightly increased when the methyl soyate was blended with the baseline fuel. This would be expected due to the composition of the blending agent which are primarily esters containing from 16 to 18 carbon atoms. The carbonaceous particulate core provides an excellent site for the condensation of these long chain hydrocarbons. The installation of the catalytic converter results in significant reductions of the SOF while the remaining particulate matter was largely unaffected. With the ignition delay the non SOF component of the exhaust was shown to increase while any increase in the SOF was negated by the activity of the catalvst. 17 #95-36743-2 MSED Report Hydrocarbon and Carbon Monoxide Emissiom The hydrocarbon and carbon monoxide emissions are the result of incomplete combustion of the fuel. Therefore the emission rates are a function of the driving cycle and the corresponding operation of the engine. In general the THC emissions were greatest over the NYComp cycle followed by the CBD and the Arterial cycles and CO emissions were greatest over the CBD cycle. With the installation of the oxidation catalyst the emissions were significantly reduced, however when the timing was retarded in combination with the catalyst the CO emission rate was shown to increase, The following Figures illustrate the trends in these emissions over the various test cycles. Figure 5. Hydrocarbon Emissions, Grams per Mile q CBD 0 ARTERIAL n B20 B20 cat B20 cat 8 5 NYEKZOMP B208 5 deg Figure 6. Carbon Monoxide Emissions, Grams per Mile B20 B20 cat B20 cat S 5 CBD G ARTERIAL B20 8 5 dep 18 #95-76743-Z ml MSED Report Aldehyde / Kefolle Emissions Total aldehyde/ketone emissions over the three test cycles was the highest over the New York Bus Composite test cycle. The primary constituent of the total aldehyde/ketone emissions being formaldehyde. In Figure 7, the highest average formaldehyde emission rates were observed during the NYBComp test cycles. The configuration which yielded the highest average formaldehyde emissions as well as total aldehyde emissions was conducted using the biodiesel blend without exhaust aftertreatment and the timing retarded to 8.5 degrees. Figure 7. Average Formaldehyde Emissions, Grams per Mile B20 B20 cat B20 cat 8 5 B20 8.5 deg 8.0 Summary #95-26743-Z 19 MSED Report 8.0 Summary The Mobile Sources Emission Division of Environment Canada performed heavy duty chassis dynamometer emissions testing on a standard forty foot urban transit bus while operating on diesel, and also on a blend of diesel with methyl soyate. The testing was conducted in support of a demonstration program involving the National Biodiesel Board. The objective of the emissions test program was to determine and compare the emissions from the bus while in the standard diesel configuration, and while operating with the biodiesel. Other parameters which were investigated included the effect of ignition timing and exhaust aftertreatment with an oxidation catalyst. Biodiesel uersus Baseline Diesel In comparing the biodiesel fuel and baseline diesel produced emissions, the biodiesel had its most significant impact on the emissions of carbon monoxide and total hydrocarbon during the Arterial cycle tests. This cycle has a higher percentage of time at acceleration and cruise than the other cycles and therefore may better illustrate the effect of the fuel composition at higher vehicle load. During the CBD test cycles particulate matter and SOF exhibited the largest reduction in emissions. If a double weighting is applied to the Arterial emission rates when averaging the three cycles, the percent change decrease in particulate was 2.6 percent, while NOx was increased by 10 percent. An equal weighting of the cycles yields a percentage decrease of 2.8 percent for particulate, and a 5.8 percent increase in NOx. Catalyst Effect With the installation of the Engelhard catalyst there were significant decreases in HC, CO, and particulate mass over each cycle. In addition, the soluble organic fraction of the particulate was also reduced over the test cycles. These results were to be expected due to the oxidation activity of the exhaust after-treatment device. In the tests conducted with the ignition retarded the NOx emissions decreased as expected, however this was accompanied by an increase in the particulate over all three test cycles. Interestingly, the SOF content of the particulate was lowered over the CBD and Arterial cvcles. With the catalyst in place the NOx emissions were not significantly changed from-the baseline LSD tests. 20 *95-16743-7 XISED Report References 1. USEPA Urban Bus Engine Reburld/Retrofit Regulation 2. France, C. J., Clemmens. W., Wysor, T.Recommended Practise for Determining Exhaust Emissions from Heaw Dutv Vehicles Under Transient Conditions. EPA Technical Report SDSB-79-08, PB80-17914-6, February 1979 3. US EPA Code of Federal Regulations, Schedule 40 Part 86 4. Urban, C.M. Dvnamometer Simulation of Truck and Bus Road Horsepower for Transient Evaluations SAE Report 840349, SAE Transactions Volume 93,1984 5. Urban, C.M. Calculation of Emissions and Fuel Economv When Using Alternative Fuels EPA Report EPA 460/3-83-009 Acknowledgements The authors would like to acknowledge the work of Gail Mosher, Karen McCuaig, Stephanie Bourgeau, and Stephen Brown who conducted the emission tests and performed the analysis required for the speciation of the exhaust components. The participation and co-operation of Mr. John VanGerpen of the National Biodiesel Board has been greatly appreciated. 21 #95-26743-2 MSED Report APPENDIX A. Regulated Emissions Test Results Al Baseline Diesel Tests A2 B20 Tests A3 B20 with Engelhard Catalyst A4 B20 with Engelhard Catalyst and Ignition Timing Retard A5 B20 with Ignition Timing Retard B. Aldehyde - Ketone Emissions Analysis - All Tests C. Soluble Organic Analysis All Tests D. Emission Test Cycles 22 #95-26743-2 MSED Report Mobile Sources Emission Division of Environment Canada - Emissions Research Grow Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner I Operator Engine Model Engine Engine Cycle 95-86 S. W Ohio Reg. T.A DDC 8V71 9.3 L V8 Diesel 2 Non-Regulated Emission Sampling Required 1 ~~ Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0.1518 0 15361 0 00181 THC Sample (ppm) THC Ambient (ppm) 31.51 7.21 ‘CO Sample (ppm) CO Ambient (ppm) 187 32 175 NOx Sample (ppm) iNOx Ambient (ppm) 86 52 2.44 CO2 0 s1 0 06 Sample (%) CO2 Ambient (%) Mobile Sources Emission Division of Environment Canada - Emissions Research Grout Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner / Operator Engine Model Engine Engine Cycle 95-86 S W Ohio Reg T.A DDC SV71 93LV8 Diesel 1 Non-Regulated Emission Sampling Required Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0.15077 0.15231 0 0015-l THC Sample (ppm) THC Ambient (ppm) 37.62 10 CO Sample (ppm) CO Ambient (ppm) 200.2 1 1 95 NO+ Sample (ppm) NOx Ambient (ppm) 78.15 1.95 CO2 Sample (%) CO2 Ambient (%) 0 SJ 0 05 Fuel Consumption mi/US~al 3 44 1 Mobile Sources Emission Division of Environment Canada - Emissions Research Group Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner / Operator Engine Model Eogioe Engine Cycle 95-86 S. W Ohio Reg. T.A DDC 8V7 1 9.3 L vs Diesel Non-Regulated Emission Sampling Required 1 j Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0.15128 0 15516 0.00388 THC Sample (ppm) THC Ambient (ppm) 47.61 6 88 CO Sample (ppm) CO Ambient (ppm) 161.91 3 06 NOx Sample (ppm) NOs Ambient (ppm) 147 21 5.8-I CO2 Sample (%) CO2 Ambient (%) 1.30 0 08 Mobile Sources Emission Division of Environment Canada - Emissions Research Group, Heavy Duty Chassis Dynamometer Emission Results Owner I Operator Initial Filter Mass (9) Final Filler Mass (g) Total Particulate Mass (g) 95% SW Ohio Reg. T.A DDC 8V71 93LVS 0 15146 0 15391 0.00245 THC Sample (ppm) THC Ambient (ppm) 47.18 9 02 CO Sample (ppm) CO Ambient (ppm) 166 81 3 s5 NOs Sample (ppm) NOx Ambient (ppm) 119 16 5 53 CO2 Sample (%) CO2 Ambient (%) 1.31 0 08 1 IDate /Cell # ( July 18195 1 ITest 2 L W (lbs.) 1 30320 1 IExhaust Aftertreatment 1 I Mobile Sources Emission Division of Environment Canada - Emissions Research Group Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner I Operator Engine Model Engine Engine Cycle 95-86 S W Ohio Reg. T.A DDC 8V71 9.3 L V8 Diesel Non-Regulated Emission Sampling Required 1 Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0.1482 0 15039 0.00219 THC Sample (ppm) THC Ambient (ppm) 47 83 10.22 CO Sample (ppm) CO Ambient (ppm) 189 54 1 92 NOx Sample (ppm) NOx Ambient (ppm) 176 46 9 04 CO2 Sample (%) CO2 Ambient (%) 1.10 0.10 Mobile Sources Emission Division of Environment Canada - Emissions Research Grow Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner I Operator Engine Model Engine Engine Cycle 95-86 S. W Oho Reg T.A DDC 8V71 93LVS Diesel Non-Regulated Emission Sampling Required Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0.15324 0 15461 0 00137 TEC Sample (ppm) THC Ambient (ppm) 26 98 88 CO Sample (ppm) CO Ambient (ppm) 16 s-1 0.29 NOx Sample (ppm) NOx Ambient (ppm) 70.38 I.73 CO2 Sample (%) CO2 Ambient (?h) 0 56 0 05 J J Mobile Sources Emission Division of Environment Canada - Emissions Research Group Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner / Operator Engine Model Engine Engine Cycle 95-86 Date 1 J u n e 28/95 1 /Test L W (lbs.) DDC 8V71 93LV8 Diesel Non-Regulated Emission Sampling Required r Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) ) S. W Oho Reg. T A 0.15272 0.1541 0.00138 THC Sample (ppm) THC Ambient (ppm) 28 36 9 63 CO Sample (ppm) CO Ambient (ppm) 50 02 0.91 NOx Sample (ppm) NOx Ambient (ppm) 69 59 1.71 CO2 Sample (%) CO2 Ambient (%) 0 05 0 56 Fuel Consumption I 30320 1 Mobile Sources Emission Division of Environment Canada - Emissions Research Group, Heavy Duty Chassis Dynamometer Emission Results 95-86 Owner I Operator S. W Ohio Reg T.A DDC XV71 9.3 L V8 Diesel Non-Regulated Emission Sampling Required Soluble Organic Fraction Carbonyls voc Total DPS Volume (scf) Particulate Volume (scf) Dilution Volume (scf) Dilution Factor Distance cmi.‘l 25130 51.4 30.13 21.899 2 465 Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (9) 0 15113 0.15407 0 00293 THC Sample (ppm) THC Ambient (ppm) 30 62 7 26 CO Sample (ppm) CO Ambient (ppm) 60 12 2 06 NOx Sample (ppm) NOx Ambient (ppm) 75 90 3 68 CO2 Sample (%) CO2 Ambient (%) 0 60 0.07 yes yes ves A. Regulated Emissions Test Results A2 B20 Tests 34 #95-26743-Z MSED Report Mobile Sources Emission Division of Environment Canada - Emissions Research Group, Heavy Duty Chassis Dynamometer Emission Results IVehicle Number Owner / Operator ‘Engine Model Engine ~Engine Cycle Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0 15288 0.15419 0.00131 THC Sample (ppm) THC Ambient (ppm) 27.23 9 1-l CO Sample (ppm) CO Ambient (ppm) 1712 2.71 NOx Sample (ppm) NOx Ambient (ppm) 87 34 2 04 CO2 Sample (%) CO2 Ambient (%) 0 85 0.05 Par&late (g/mi.) 0 675-i I, m 95-86 SW Ohlo Reg T.A DDC 8V71 9.3 L vs Diesel 1 No Exhaust Aftertreatment Mobile Sources Emission Division of Environment Canada - Emissions Research Grout, Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner / Operator Engine Model Engine Engine Cycle Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) I / J u n e 29/95 1 ITest L W (lbs.) 30320 1 ( T e s t HP@SOmph 1 85.05 ] 95-86 SW Oh10 Reg. T.A DDC 8V7 1 93LV8 Diesel No Exhaust Aftertreatment Non-Regulated Emission Sampling Required 0 15388 0.1551 0.00122 THC Ambient (ppm) 27 27 9 72 CO Ambient (ppm) 17751 3 36 NOx Sample (ppm) NOr Ambient (ppm) 85 36 2 25 I 0 86 0 05 \Particulate (timi.) 0 64% 1 1 Mobile Sources Emission Division of Environment Canada - Emissions Research Grout, Heavy Duty Chassis Dynamometer Emission Results ~Vehicle Number Owner I Operator ~Engine Model Engine Engine Cycle S. W Oh10 g5-86 Reg. T A DDC 8V71 9.3 L V8 Diesel I Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0 15422 0.15535 000113 ITHC Sample (ppm) THC Ambient (ppm) 27 15 Y 58 ICO Sample (ppm) ‘CO Ambient (ppm) 152.22 107 NOm Sample (ppm) NOn Ambient (ppm) 88.85 2 11 CO2 Sample (%) CO2 Ambient (%) 0.85 0 05 Particulate (timi. Mobile Sources Emission Division of Environment Canada - Emissions Research Group Heavy Duty Chassis Dynamometer Emission Results lVehicle Number Owner / Operator Engine Model Engine Engine Cycle Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 95-86 S W OIuo Reg. T.A DDC 8V71 93LV8 Dtesel 0 15376 0.15661 0.00288 THC Sample (ppm) THC Ambient (ppm) 34 53 6 78 CO Sample (ppm) CO hmbient (ppm) 150 25 1.72 NOx Sample (ppm) NOr Ambient (ppm) 202 66 2.31 CO.2 Sample (%) CO2 Ambient (9~) 1.35 0 05 I m Test Cycle Fuel Type ICell # 1, No Exhaust Aftertreatment Mobile Sources Emission Division of Environment Canada - Emissions Research Group Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner I Operator Engine Model Engine Engine Cycle Inilial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 95-86 S.W Oh10 Reg T A DDC 8V71 9.3 L V8 Diesel 0.15053 0.15288 0 00235 TEC Sample (ppm) TIlC Ambient (ppm) 33 62 8 69 CO Sample (ppm) CO Ambient (ppm) 118.6 2.46 NOa Sample (ppm) NOr Ambient (ppm) 205 72 6.02 CO2 Sample (%) CO2 Ambient (%1 c Date Test Cycle Fuel Type Cell # 1.31 0 06 Fuel Consumption mi/USgal 3 86 No Exhaust Aftertreatment Mobile Sources Emission Division of Environment Canada - Emissions Research GrouD Heavy Duty Chassis Dynamometer Emission Results 95-86 Owner I Operator SW Ohlo Reg T A DDC 8V71 93LVS Diesel 11 Non-Regulated Emission Sampling Required initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0 15357 0.15558 0.00201 THC Ambient (ppm) 33 49 8 45 CO Sample (ppm) CO Ambient (ppm) 111.42 2.95 NOr Sample (ppm) NOx Ambient (ppm) 187 US 6.02 1.28 0 06 Mobile Sources Emission Division of Environment Canada - Emissions Research Group, Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner I Operator Engine Model Engine Engine Cycle 95-86 S. W Ohio Reg. T.A DDC 8V71 9.3 L V8 IE;ye 1 INo E x 1 h a Bz” u s t Diesel A f t e r t r e a t m e n t , 11 Non-Regulated Emission Sampling Required 11 ~1 Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0 1547 0 15861 0.00391 THC Sample (ppm) THC Ambient (ppm) 2-i 99 5 92 CO Sample (ppm) CO Ambient (ppm) 36.04 0 33 NOx Sample (ppm) NOx Ambient (ppm) 68 57 0 91 CO2 Sample (%) CO2 Ambient (%) 0 57 0 04 IFuel Cnnsumntion 3 51 mi/USgal 1 1 I Mobile Sources Emission Division of Environment Canada - Emissions Research GrouD Heavy Duty Chassis Dynamometer Emission Results c Date Test Cycle Fuel Type Cell # 95-86 Owner I Operator S. W Ohio Reg. T.A DDC 8V7 1 9.3 L V8 Diesel (Bar. Pressure (in. HG) Cell Temp. (deg. C) Dew Point Temp. (deg. C) KH Factor 29 93 Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0.14533 0.14795 0.00262 THC Sample (ppm) THC Ambient (ppm) 25 11 6.06 CO Sample (ppm) CO Ambient (ppm) 46.25 NOx Sample (ppm) NOs Ambient (ppm) 71.86 I 17 CO2 Sample (%) CO2 Ambient (%) 0 73 0.59 0 05 1 Test LW (lbs.) Test HP@SOmph 30320 85.05 No Exhaust Aftertreatment (Non-Regulated Emission Sampling Required 1 Mobile Sources Emission Division of Environment Canada - Emissions Research GrouD Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner / Operator Engine Model Engine Engine Cycle Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 95-86 S.W Ohio Reg. T.A DDC 8V71 9.3 L V8 Diesel 0 11662 0.11915 0 00253 THC Sample (ppm) THC Ambient (ppm) 2177 5 73 CO Sample (ppm) CO Ambient (ppm) 42 55 NOx Sample (ppm) NOs Ambient (ppm) 68 82 CO?. Sample (%) CO2 Ambient (%) 0 57 0.05 041 130 No Exhaust Aftertreatment A. Regulated Emissions Test Results A3 B20 with Engelhard Catalyst 25 #95-26713-2 NSED Report Mobile Sources Emission Division of Environment Canada - Emissions Research Group Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner / Operator Engine Model Engine Engine Qcle 95-86 SW Ohio Reg. T.A DDC 8V7 1 93LV8 Diesel Non-Regulated Emission Sampling Required I Al Soluble Organic Carbonyls ~~ rInitial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0.152 12 0.15421 0.00212 THC Sample (ppm) THC Ambient (ppm) 15.75 53 CO Sample (ppm) CO Ambient (ppm) 66 62 0 97 NOs Sample (ppm) NOx Ambient (ppm) 93 30 2.24 CO2 Sample (%) CO2 Ambient (96) 0 96 0 05 Fraction I yes yes Mobile Sources Emission Division of Environment Canada - Emissions Research Grout Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner I Operator ~Engine Model Engine Engine Cpcle 95-86 S. W Oluo Reg. T.A DDC 8V7 1 93LV8 Diesel Test LW (lbs.) Test HP@Omph Exhaust Aftertreatment CMX Installed Non-Regulated Emission Sampling Required Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0 1516 0 1537 0.002 1 THC Sample (ppm) ITHC Ambient (ppm) 15 03 1.94 CO Sample @pm) ICO Ambient (ppm) 12 21 0.55 NOr Sample (ppm) NOx Ambient (ppm) 98 52 2 12 CO2 Sample (%) CO2 Ambient (%) 0.95 0 05 30320 85.05 1 I Mobile Sources Emission Division of Environment Canada - Emissions Research Grout Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner / Operator Engine Model Engine Engine Cycle 95-86 S.W Ohio Reg. T.A DDC 8V7 1 9.3 L V8 Diesel IBar. Pressure (in. HG) Cell Temp. (deg. C) Dew Point Temp. (deg. C) KH Factor 29 647 Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0.15112 0 15629 0 00187 THC Sample (ppm) THC Ambient (ppm) 13 92 5 29 CO Sample (ppm) CO Ambient (ppm) 46 12 1 17 NOr Sample (ppm) NOx Ambient (ppm) 98 84 1.71 CO2 Sample (%) CO2 Ambient (%) 0 96 0 05 Emrhaust Aftertreatment CMX Installed 1 INon-Regulated Emission Sampling Required I Mobile Sources Emission Division of Environment Canada - Emissions Research Group Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner / Operator Engine Model Engine Engine Cycle 95-86 SW Oh10 Reg T.A DDC 8V71 93LV8 Diesel CMX Installed Non-Regulated Emission Sampling Required <I Soluble Orgauic Fraction Carbonyls voc Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0.15365 0.15595 0.0023 THC Sample (ppm) THC Ambient (ppm) 16.83 5 75 CO Sample @pm) CO Ambient (ppm) 12 53 0 50 NOr Sample (ppm) 155.66 NOx Ambient (ppm) 3 58 CO2 Sample (%) CO2 Ambient (%) 1 52 0 06 Fuel Consumption 3.36 mi/USgal yes yes “es Mobile Sources Emission Division of Environment Canada - Emissions Research Group, Heavy Duty Chassis Dynamometer Emission Results Owner / Operator 95-86 S WOhioReg. TA DDC 8V71 93LV8 Diesel Exhaust Aftertreatment CMX Installed 2 Non-Regulated Emission Sampling Required Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0 15204 0.15381 0 0018 THC Sample (ppm) THC Ambient (ppm) 16 72 5 21 CO Sample (ppm) CO Ambient (ppm) 9 76 0 10 NOx Sample (ppm) NOx Ambient (ppm) 14 19 1 97 CO2 Sample (%) CO2 Ambient (%) 0 62 0 Oi Par&late &hi.) 0 8761 Mobile Sources Emission Division of Environment Canada - Emissions Research Group, Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner I Operator Engine Model Engine Engine Cycle 95-86 SW Ohio Reg. T.A DDC 8V71 9.3 L V8 Diesel Non-Regulated Emission Sampling Required Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0.15564 0 15798 0 00234 THC Sample (ppm) THC Ambient (ppm) 17.71 5.76 CO Sample (ppm) CO Ambient (ppm) 8.61 0 23 NOr Sample (ppm) NOx Ambient (ppm) 149 53 3.91 CO2 Sample (%) CO2 Ambient (%) 1 17 0 06 Fuel Consumption mi/USgal 3.52 I Mobile Sources Emission Division of Environment Canada - Emissions Research Groun Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner I Operator Engine Model Engine Engine Cycle 95-86 S. W Oh10 Reg. T A DDC 8V71 93LV8 Diesel cI Date Test Cycle Fuel Type Ceil # July 7195 NYCOMP-3 B20 2 Test LW (Ibs.) Test HP@>Omph Non-Regulated Emission Sampling Required Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0.15307 0 15502 0.00195 THC Sample (ppm) THC Ambient (ppm) 16.72 5 43 CO Sample (ppm) CO Ambient (ppm) 13 97 0 18 NOx Sample (ppm) NOr Ambient (ppm) 77.16 2 01 lCO2 0 63 0 05 Sample (%) ‘CO2 Ambient (%) 30320 85.05 A. Regulated Emissions Test Results A4 B20 with Engelhard Catalyst and Ignition Timing Retard 26 #95-26743-Z MSED Report Mobile Sources Emission Division of Environment Canada - Emissions Research GrouD Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner / Operator Engine Model Engine Engine Cycle 95-86 S.W Ohio Reg T.A DDC 8V7 1 9.3 L V8 Diesel CMX Installed Timing Retarded Non-Regulated Emission Sampling Required 11 Soluble Organic Fraction Carbonyls voc ~1 Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0 14858 0 15132 0.00274 THC Sample (ppm) THC Ambient (ppm) 18.23 7.06 CO Sample (ppm) CO Ambient (ppm) 45 63 1.21 NOa Sample (ppm) NOx Ambient (ppm) 90 06 3 92 CO2 Sample (%) CO2 Ambient (%) 0.94 0.06 yes yes yes Mobile Sources Emission Division of Environment Canada - Emissions Research Grout, Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner / Operator Engine Model Engine Engine Cycle 95-86 S.W Ohio Reg. T.A DDC 8V71 9.3 L vs Diesel CMX Installed Non-Regulated Emission Sampling Required Iuitial Filter Mass (s> Final Filter Mass (g) Total Particulate Mass (g) 0 15297 0.15532 0.00235 THC Sample (ppm) THC Ambient (ppm) 15.64 7.06 CO Sample (ppm) CO Ambient @pm) 19 35 NOx Sample (ppm) NOx Ambient (ppm) 115 06 3.92 CO2 Sample (%) CO2 Ambient (%) 1.21 0 89 0 nh Mobile Sources Emission Division of Environment Canada - Emissions Research Group Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner / Operator Engine Model Engine Engine Cycle 95-86 S.W Ohlo Reg. T.A DDC 8V71 93LV8 Diesel CMX Installed Non-Regulated Emission Sampling Required Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0 11984 0 1521 0.00226 THC Sample (ppm) lTHC Ambient (ppm) 15.25 7 06 CO Sample (ppm) ICO Ambient (ppm) 52 39 1 24 ,NOs Sample (ppm) NOr Ambient (ppm) 119 58 3.92 CO2 Sample (%) lCO2 Ambient (%) 0 92 0 06 Mobile Sources Emission Division of Environment Canada - Emissions Research Grout, Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner I Operator Engine Model Engine Engine Cycle July 12195 ART-l B20 2 Non-Regulated Emission Sampling Required Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0.15466 0 15858 0.00392 THC Sample (ppm) THC Ambient (ppm) 19.79 6 43 CO Sample (ppm) CO Ambient (ppm) 78 161 NOa Sample (ppm) NOx Ambient (ppm) 195 78 6.63 CO2 Sample (%) CO2 Ambient (%) 1.30 0 06 Mobile Sources Emission Division of Environment Canada - Emissions Research Group Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner! Operator Engine Model Engine Engine Cycle 95-86 SW Ohio Reg T.A DDC 8V71 9.3 L V8 Diesel CMX Installed Non-Regulated Emission Sampling Required 3 ~~ Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0 15088 0.15359 0.00271 THC Sample (ppm) THC Ambient (ppm) 17 63 6 13 CO Sample (ppm) CO Ambient (ppm) 8.9 161 NOx Sample (ppm) NOx Ambient (ppm) 202 11 6 63 CO2 Sample (%) CO2 Ambient (%) 1.36 0 06 Mobile Sources Emission Division of Environment Canada - Emissions Research Groun Heavy Duty Chassis Dynamometer Emission Results 95-86 Owner / Operator Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (p) S W Ohio Reg. T.A DDC 8V7 1 93LVS Diesel 0 14966 0 15166 0.002 THC Sample (ppm) THC Ambient (ppm) 17 06 6 13 CO Sample (ppm) CO Ambient (ppm) 8 03 NOx Sample (ppm) 202 41 6 63 NOx Ambient (ppm) CO2 Sample (%) CO2 Ambient (“/a) 161 1.32 0.06 Fuel Consumption mi/USeal 3 91 Mobile Sources Emission Division of Environment Canada - Emissions Research Group r Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner / Operator Engine Model Engine Engine Cycle 95-86 SW Ohio Reg. T.A DDC 8V71 9.3 L vs Diesel Date Test Cycle Fuel Type ICell # 1 Non-Regulated Emission Sampling Required Initial Filter Mass (g) Final Filter Mass (9) Total Particulate Mass (g) 0 15129 0 15101 0 00275 THC Sample (ppm) THC Ambient (ppm) 18 16 161 CO Sample (ppm) CO Ambient (ppm) 1158 1 70 NOs Sample (ppm) NOs Ambient (ppm) 75.60 3 61 CO2 Sample (%) CO2 Ambient (%) 0 56 0 06 Mobile Sources Emission Division of Environment Canada - Emissions Research Group Heavy Duty Chassis Dynamometer Emission Results Owner / Operator 95-S S W Oh10 Reg. T.A DDC 8V71 93LV8 Diesel c Date Test Cycle Fuel Type Cell # Test LW (lbs.) Test EP@5Omph Non-Regulated Emission Sampling Required Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0 15274 0 15501 0.00227 THC Sample (ppm) THC Ambient (ppm) 17 47 7.61 CO Sample (ppm) CO Ambient (ppm) 18.21 1.70 NOx Sample (ppm) NOa Ambient (ppm) 87.95 3 61 CO2 Sample (%) CO2 Ambient (%) 0.63 0 06 30320 85.05 Mobile Sources Emission Division of Environment Canada - Emissions Research Groun Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner / Operator Engine Model Engine Engine Cycle 95-86 SW Ohio Reg. T.A DDC 8V71 9.3 L vs Diesel Non-Regulated Emission Sampling Required Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0 15524 0 15711 0 00187 THC Sample (ppm) THC Ambient (ppm) 17 61 7 61 CO Sample (ppm) CO Ambient (ppm) 12 19 1.70 NOx Sample (ppm) NOx Ambient (ppm) 83 13 3 61 CO2 Sample (%) CO2 Ambient (%) 0.6 1 0.06 Regulated Emissions Test Results A5 B20 with Ignition Timing Retard 27 895-26743-2 ,MSED Report Mobile Sources Emission Division of Environment Canada - Emissions Research Grow Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner / Operator Engine Model Engine Engine Cycle 95-86 SW Ohio Reg. T.A DDC 8V71 9.3 L V8 Diesel IExhaust Aftertreatment ITiming Retarded 1 [Bar. Pressure (in. HG) Cell Temp. (deg. C) Dew Point Temp. (deg. C) 29.741 Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0.1535 0.15757 0 00407 THC Sample (ppm) THC Ambient (ppm) 28 28 6 18 CO Sample (ppm) CO Ambient (ppm) 151.19 3 12 NOx Sample (ppm) NOx Ambient (ppm) 82.22 3.25 CO2 Sample (%) iCO2 Ambient (%) 0 86 0 06 1 INon-Regulated Emission Sampling Required I I Soluble Organic Fraction yes 1 Mobile Sources Emission Division of Environment Canada - Emissions Research Grout, Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner / Operator Engine Model Engine Engine Cycle 95-86 S W Ohio Reg. T.A DDC 8V71 9.3 L V8 Diesel Non-Regulated Emission Sampling Required Soluble Organic Fraction Carbonyls voc Initial Filter Mass (g) Final Fitter Mass (g) Total Particulate Mass (g) THC Sample (ppm) THC Ambient (ppm) CO Sample (ppm) 0.15269 0.15566 0.00297 28 4 7 1-i CO Ambient (ppm) 15-I 61 6 08 NOx Sample (ppm) NOs Ambient (ppm) 81.66 4.5 1 CO2 Sample (%) CO2 Ambient (%) 0 85 0.07 Fuel Consumption mi/USgal 3.62 yes yes “es Mobile Sources Emission Division of Environment Canada - Emissions Research Group Heavy Duty Chassis Dynamometer Emission Results Vehicle Owner Engine Engine Engine Number / Operator Model Cycle 95-86 S. W Ohio Reg. T A DDC 8V7 1 93LVS Diesel me Timin Retarded Non-Regolated Emission Sampling Required Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0.15195 0.15471 0 00279 THC Sample (ppm) THC Ambient (ppm) 28 61 7 82 CO Sample (ppm) CO Ambient (ppm) 159 72 6 46 NOx Sample (ppm) NOx Ambient (ppm) 76 71 3.96 CO2 Sample (%) CO2 Ambient (%) 0.85 0 07 THC (g/mi.) CO (g/mi.) NOx (p/m;.) CO2 (g/mi.) Particulate (g/mi.) 32.;1 20 87 2817 16 1.5421 Mobile Sources Emission Division of Environment Canada - Emissions Research GrouD Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner / Operator Engine Model Engine Engine Cycle 95-86 SW Oluo Reg. T.A DDC 8V71 93LV8 Diesel IDate ) July 14/95 ) ITest L W (lbs.) Non-Regulated Emission Sampling Required Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0.1521 0.15845 0.00635 THC Sample (ppm) THC Ambient (ppm) 38.93 7.52 CO Sample (ppm) CO Ambient (ppm) 137.5 3 49 NOx Sample (ppm) NOn Ambient (ppm) 12-i 02 7 68 CO2 Sample (%) CO2 Ambient (%) 1.23 0 10 Fuel Consumption 4.24 milZTSga1 1 30320 1 Mobile Sources Emission Division of Environment Canada - Emissions Research Groun Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner / Operator Engine Model Engine Engine Cycle 95-86 S W Ohto Reg. T.A DDC 8V71 93LV8 Dtesel IDate 1 July 14195 1 ITest A ~ Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0 15 0 15338 0 00338 THC Sample (ppm) THC Ambient (ppm) 35 74 8.53 CO Sample (ppm) CO Ambient (ppm) 162 1 6 08 NOr Sample (ppm) NOr Ambient (ppm) 123 34 8.76 CO2 Sample (%) CO2 Ambient (%) 133 0 10 IFuel Cnnsumntion mi/USgal 1 3 82 LW (lbs.) ( 30320 1 Mobile Sources Emission Division of Environment Canada - Emissions Research Group Heavy Duty Chassis Dynamometer Emission Results Owner I Operator 95-86 S. W Ohio Reg T.A DDC 8V71 93LV8 Diesel c Date Test Cycle Fuel Type Cell # Non-Regulated Emission Sampling Required /Total DPS Volume (scf) Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0 15208 0 1551 0.00302 THC Sample (ppm) THC Ambient (ppm) 35 13 10 52 CO Sample (ppm) CO Ambient (ppm) 180 29 8 89 NOs Sample (ppm) NOx Ambient (ppm) 143.35 13 86 CO2 Sample (%) CO2 Ambient (%) 1.41 0.12 Mobile Sources Emission Division of Environment Canada - Emissions Research Group, Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner I Operator Engine Model Engine Engine Cycle 95-86 /Date ( July 13/95 1 ITest L W (lbs.) S. W Ohio Reg. T.A DDC 8V7 1 93LVS Diesel Non-Regulated Emission Sampling Required 11 ~~ Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0.15575 0.15969 0.00394 !THC Sample (ppm) THC Ambient (ppm) 25 01 6 43 ICO Sample (ppm) ‘CO Ambient (ppm) 36.13 2 17 NOa Sample (ppm) NOx Ambient (ppm) 62 51 2 89 CO2 Sample (%) CO2 Ambient (%) 0.57 0 06 1 30320 1 Mobile Sources Emission Division of Environment Canada - Emissions Research Group, Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner / Operator Engine Model Engine Engine Cycle 95-86 S.W Ohio Reg T.A DDC 8V71 9.3 L V8 Diesel Timing Retarded Non-Regulated Emission Sampling Required Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0 13616 0 13881 0 00268 THC Sample (ppm) THC Ambient (ppm) 25 18 78 CO Sample (ppm) CO Ambient (ppm) 30 24 NOx Sample (ppm) NOx Ambient (ppm) 61.03 3.17 CO2 Sample (%) CO2 Ambient (%) 0.57 0 06 191 Fuel Consumption 3.66 miAJSgal Mobile Sources Emission Division of Environment Canada - Emissions Research Groue Heavy Duty Chassis Dynamometer Emission Results Vehicle Number Owner! Operator Engine Model Engine Engine Cycle 95-86 S. W Ohio Reg. T.A DDC 8V7 1 9.3 L V8 Diesel e Exhaust Aftertreatment I Non-Regulated Emission Sampling Required Initial Filter Mass (g) Final Filter Mass (g) Total Particulate Mass (g) 0.15123 0.15123 0 003 THC Ambient (ppm) 26 32 8 09 CO Sample (ppm) CO Ambient (ppm) 38 1 2 98 NOs Sample (ppm) NOx Ambient (ppm) 61.92 3.06 0.33 CO2 Ambient (%) 0 06 B. Aldehyde - Ketone Emissions Analysis - All Tests 25 #95-26743-2 MSED Report I : F F r C. Soluble Organic Analysis - All Tests 29 $95-26743-2 MSED Report 0’1001 0'9L6 0’ 196 0’926 0’ LO6 0’9L8 0’198 0.928 0’108 0 9LL 0‘ LSL 0’92L O.LOL 0’9L9 0’ 199 0’929 0’109 0’9L9 0’1% 0.92s 0’10s 0’9LP O’ISP - - 0’9Zt 0’ COP 0’9LE 0’1% 0.92s O’LOE O’SLZ 0’ 1sz 3’922 3’LOZ 3’9L 1 3’lSL 3’9ZL 3’101 i? 3’9L 1’1s 3’92 3’1 : 8 $ .Fif! D. Emission Test Cycles 30 #S-26743-2 MSED Report 1 J I qdtu paads 0'009 O’SLS t om am r :. i , t am . . , . am 3al am . 3 !3 nm , I 3 17