Winter School on Photonics for Energy Uwe Zimmermann Winter School on Photonics for Energy Introduction Solar radiation Photovoltaics History Semiconductor physics Solid state solar cells Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future Uwe Zimmermann Solid State Electronics Uppsala university Solid state solar cells.1 Outline. Winter School on Photonics for Energy Uwe Zimmermann Introduction Solar radiation This lecture shall give answers to the following questions: Photovoltaics History • Why solar cells? Semiconductor physics Solar cells • What is a solid state solar cell? • What was the history of the solar cell? • What is the current state of solar cells? • What are the important parameters of a solar cell? • What is limiting the conversion efficiency? Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future • What can we expect from current solar cell technologies? • How sustainable are solar cells? • Where are we going from here? Solid state solar cells.2 Winter School on Photonics for Energy A glimpse into the future. Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future Shell energy scenarios to 2050 • Overall energy consumption of the world is expected to continue growing. • Future energy production must be affordable and sustainable. Solid state solar cells.3 Winter School on Photonics for Energy Grid Parity. Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future McKinsey Quarterly, June 2008 Solid state solar cells.4 PV potential in Europe. Winter School on Photonics for Energy Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future Solid state solar cells.5 Winter School on Photonics for Energy Direct and diffuse sunlight. Uwe Zimmermann Introduction isotropic diffuse from sky Solar radiation Photovoltaics History Semiconductor physics di ct re Solar cells Electrical parameters c cir ar l so um CIGS solar cells di Multijunction solar cells e s ffu Other solar cells Current market development diffuse from horizon ion reflekt ed reflect The future The global irradiation consists of • direct sunlight • diffuse sunlight • reflected sunlight Solid state solar cells.6 Direct light in Africa. Winter School on Photonics for Energy Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future • more than 80 % of the insolation in Africa come from direct sunlight Solid state solar cells.7 Diffuse light in Europe. Winter School on Photonics for Energy Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future • Up to 64 % of the insolation in northern Europe come from diffuse sunlight. • Diffuse sunlight can not be focused or concentrated. Solid state solar cells.8 Advantages of solar cells. Winter School on Photonics for Energy Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future • Solar cells have no moving parts. • Solar cells are emission-free during operation. • Solar cells are silent. • Solar cell installations can be compact. • Solar cell installations are scalable. Solid state solar cells.9 Some history. Winter School on Photonics for Energy Uwe Zimmermann 1839 1876 1954 1958 1970:s 1980 2001 2003 2008 2009 Alexandre-Edmond Becquerel (father of Henry B.) discovers the photovoltaic effect the selenium solid-state cell is invented the modern silicon solar cell is invented at Bell Labs with 6 % efficiency the first silicon solar cell in space the oil crisis leads to an increased interest in solar cells for terrestial use first thin film solar cell with > 10 % efficiency cumulative (1954-2001) worldwide installed PV power capacity reaches 1 GWp cumulative worldwide installed PV power capacity reaches 2 GWp Spain installs about 2.6 GWp new PV capacity Germany installs about 3 GWp new PV capacity Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future Solid state solar cells.10 The first modern solar cell. Winter School on Photonics for Energy Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells • The silicon solar cell was invented by D. Chapin, C. Fuller and G. Pearson at Bell Labs. Current market development The future • The transistor had been invented at the same location 7 years earlier. • 1958 the first commercial solar-cell driven transistor radio was available. • Also in 1958 the first solar cells were used in space. • . . . then for about 30 years not much happened. . . or did it? Solid state solar cells.11 Winter School on Photonics for Energy The first solar-cell satellite. Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells http://www.nasa.gov Current market development The future • Vanguard I, launched 1958-03-17 from Cape Canaveral. • The fourth artificial satellite, second US satellite. • 1.47 kg aluminum sphere 16.5 cm in diameter. • 10 mW, 108 MHz mercury-battery powered transmitter. • 5 mW, 108.03 MHz transmitter powered by six solar cells. • The batteries stopped working in June 1958, the solar cells in May 1964. Solid state solar cells.12 Teaching in the early years. Winter School on Photonics for Energy Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future • In the early 1960’s Bell Labs introduced a series of experimental kits. • Target audience were highschool teachers and their classes. • Bell Systems Science Experiment No. 2 contains everything to make your own silicon solar cells. Solid state solar cells.13 The solar cell. Winter School on Photonics for Energy Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future • Light can be understood as a flow of photons. • Photons are absorbed in the solar cell. • Electron-hole-pairs are created – one per photon. • Charge carriers drift/diffuse to the contacts. • An electrical current can leave the solar cell. Solid state solar cells.14 Winter School on Photonics for Energy Photon absorption. Uwe Zimmermann conduction band Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Eg Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells valence band Current market development The future • photons with E < Eg are not absorbed • photons with E ≥ Eg are absorbed • an electron-hole pair is created • photons with E Eg are absorbed • additional energy is absorbed by the crystal lattice Solid state solar cells.15 Winter School on Photonics for Energy Light absorption in semiconductors. Uwe Zimmermann photon flux [1x1021 m−2 s−1 eV−1 ] wave length [nm] 2500 1500 1000 800 600 Introduction 400 5.0 Solar radiation AM 1.5 black body 5800K 4.0 Photovoltaics History Semiconductor physics 3.0 absorption Solar cells Electrical parameters 2.0 CIGS solar cells Multijunction solar cells 1.0 0.0 0.0 Other solar cells Current market development 0.5 1.0 1.5 2.0 2.5 photon energy [eV] 3.0 3.5 The future Eg • • • A semiconductor with a bandgap Eg can absorb photons with E > Eg . A lower bandgap means there are more photons which can be absorbed: ⇒ more electron-hole-pairs ⇒ higher current ⇒ but lower voltage (V ≈ Eg/2q ) A wider bandgap means there are fewer photons which can be absorbed ⇒ fewer electron-hole-pairs ⇒ lower current ⇒ but higher voltage can be achieved Solid state solar cells.16 Winter School on Photonics for Energy Typical semiconductors. Uwe Zimmermann photon flux [1x1021 m−2 s−1 eV−1 ] wave length [nm] 2500 1500 1000 800 600 Introduction 400 5.0 Solar radiation AM 1.5 black body 5800K 4.0 Photovoltaics History CIS 3.0 Semiconductor physics CGS Solar cells CdTe 2.0 Electrical parameters GaAs Ge CIGS solar cells GaP Multijunction solar cells InP 1.0 Other solar cells Si 0.0 0.0 0.5 1.0 1.5 2.0 2.5 photon energy [eV] Current market development 3.0 3.5 Different semiconductors have different bandgaps. • Silicon is the most common semiconductor today. • Germanium, GaAs, InP och GaP are used in multijunction solar cells. • CdTe, CuInSe2 , CuGaSe2 and the alloy Cu(In, Ga)Se2 are used in thin-film solar cells. The future Solid state solar cells.17 Winter School on Photonics for Energy Available current. Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Ge Electrical parameters CIGS solar cells Si Multijunction solar cells CIS Other solar cells InP Current market development CGS GaAs CdTe The future GaP Green, M. A.: Solar Cells (1998) • The maximum current from a solar cell depends on the number of available photons with E ≥ Eg . Solid state solar cells.18 Making silicon wafer solar cells. Winter School on Photonics for Energy Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future Solid state solar cells.19 Winter School on Photonics for Energy Silicon solar cells. Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells image: US DoE Other solar cells Current market development The future per m3 Archer; Hill: Clean Electricity from Photovoltaics (2001) Solid state solar cells.20 Winter School on Photonics for Energy Energy bands – two examples. Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Cohen et.al., Phys. Rev.141, pp.789-796 (1966) 4 3 3 10 2 102 1 experimental theoretical AM1.5 spectrum 101 1.2 1.3 1.4 1.5 0 1.6 absorption coefficient [cm−1] 104 104 2 3 10 102 1 experimental theoretical AM1.5 spectrum 101 100 1.3 Current market development 3 10 photon flux [1x1021 s−1 m−2 eV−1 ] absorption coefficient [cm−1] 10 100 1.1 5 1.4 photon energy [eV] 1.5 1.6 1.7 photon flux [1x1021 s−1 m−2 eV−1 ] 5 The future 0 1.8 photon energy [eV] Raykanan et.al., Solid state electronics22, p.793 (1979) Φ(x) = Φ0 e Moss et.al., Infrared physics 1, p.111 (1961) −α x Solid state solar cells.21 Winter School on Photonics for Energy Making thin-film solar cells. Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics deposition of the back contact Solar cells patterning of the absorber layer Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells patterning of the back contact Current market development The future deposition of the front contact deposition of the absorber layer patterning of the front contact Solid state solar cells.22 Winter School on Photonics for Energy Thin-film solar cells. Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters Archer; Hill: Clean Electricity from Photovoltaics (2001) CIGS solar cells Multijunction solar cells image: Fuji Advanced Techn. Other solar cells Current market development The future image: Pacific Solar image: Uppsala university per m3 Solid state solar cells.23 Quantum efficiency. Winter School on Photonics for Energy Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future • The quantum efficiency describes the number of generated electron-hole pairs per incidcent photon. • The quantum efficiency is wavelength (or photon energy) dependent. • The internal quantum efficiency describes the number of generated charge carriers. • The external quantum efficiency describes the number of generated and collected charge carriers. Solid state solar cells.24 Winter School on Photonics for Energy The pn-junction – current transport. Uwe Zimmermann Introduction Solar radiation Ec Ec qVbi EF Ev Photovoltaics History EF Semiconductor physics Ev Electrical parameters Solar cells CIGS solar cells Multijunction solar cells Other solar cells Current market development • Electron-hole pairs are generated. The future • Charge carriers diffuse within the neutral regions. • Electrons drift towards lower energies. • Holes drift towards higher energies. • Electron-hole pairs can recombine. Solid state solar cells.25 Winter School on Photonics for Energy Current-voltage characteristics. Uwe Zimmermann current power P I Pmax eller Pmp Introduction Solar radiation V ·I Photovoltaics with light = in dark ness P maximum power point History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Vmp voltage Voc open circuit area = Vmp · Imp = Pmp The future efficiency η: η= Imp V Current market development Pmax Pin fill factor FF : Isc short circuit area = Voc · Isc FF ≡ Pmp Voc · Isc Solid state solar cells.26 Winter School on Photonics for Energy IV-curve – The one-diode model. Uwe Zimmermann Introduction Rseries + Solar radiation Photovoltaics Ilight D History Rshunt Semiconductor physics - Solar cells Electrical parameters CIGS solar cells Multijunction solar cells • A good solar cell is described by the one-diode model. • This model consists of • the pn-junction diode D • a current source with the light-generated current Ilight • a series resistance Rseries • a shunt resistance Rshunt or shunt conductance Gshunt Other solar cells Current market development The future • The current-voltage characterstics of this circuit is given by the implicit equation I(V ) = Idiode (V ) − Ilight + Gshunt V − Rseries I(V ) • Often the current density J = I/area, [J] = A cm−2 is used. Solid state solar cells.27 IV-curve – Assumptions. Winter School on Photonics for Energy Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future • The simulated IV-curves on the following slides are calculated for a 100 cm2 silicon solar cell with the following assumptions: • ideality factor A = 1.0 • saturation current density J0 = 4 × 10−13 A cm−2 • light-generated current density Jlight = 30 mA cm−2 Solid state solar cells.28 Winter School on Photonics for Energy IV-curve – Influence of the series resistance. Uwe Zimmermann current power P I Introduction Solar radiation Photovoltaics History voltage V Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future Rshunt Ω 1 000 000 Rseries mΩ 1 2 5 10 20 50 100 Voc V 0.650 Isc A 3.000 Vmp V 0.565 0.561 0.555 0.541 0.512 0.451 0.359 Imp A 2.864 ... ... ... ... ... ... Pmp W 1.618 1.608 1.588 1.544 1.450 1.254 0.879 FF % 83 82 81 79 74 64 45 η % 16.2 16.1 15.9 15.4 14.5 12.5 8.8 Solid state solar cells.29 Winter School on Photonics for Energy IV-curve – Influence of the shunt conductance. Uwe Zimmermann current power P I Introduction Solar radiation Photovoltaics History voltage V Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future Rshunt mΩ 10 000 5000 2000 1000 500 200 100 Rseries mΩ 1 Voc V 0.647 0.646 0.645 0.641 0.632 0.586 0.300 Isc A 3.000 Vmp V 0.563 0.562 0.560 0.553 0.530 0.324 0.150 Imp A ... ... ... ... ... ... ... Pmp W 1.586 1.549 1.471 1.305 0.965 0.483 0.223 FF % 82 80 76 68 51 28 25 η % 15.9 15.5 14.7 13.1 9.7 4.8 2.2 Solid state solar cells.30 Cu(In, Ga)Se2 solar cells. Winter School on Photonics for Energy Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future Solid state solar cells.31 Parasitic light absorption. Winter School on Photonics for Energy Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future Solid state solar cells.32 Winter School on Photonics for Energy Parasitic light absorption. Uwe Zimmermann Introduction Solar radiation Photovoltaics 160 History 140 Semiconductor physics Solar cells 120 current [mA] Electrical parameters 100 3102 Zn(O,S) 3126 CdS CIGS solar cells 80 Multijunction solar cells 60 Other solar cells 40 Current market development 20 The future 0 0 2 4 6 voltage [V] 8 10 12 Solid state solar cells.33 Winter School on Photonics for Energy Upper limit for efficiencies. Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Si InP GaAs Electrical parameters CdTe CIGS solar cells CIS CGS Multijunction solar cells Other solar cells GaP Current market development The future Ge Green, M. A.: Solar Cells (1998) • The Shockley-Queiser limit is based on thermodynamic principles. Solid state solar cells.34 Winter School on Photonics for Energy Ever increasing efficiencies? Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future http://www.nrel.gov/ • The efficiency is generally limited by • basic semiconductor physics • technological processes • electrical losses Solid state solar cells.35 Winter School on Photonics for Energy Multijunction solar cells. Uwe Zimmermann Eg1 Eg2 Eg3 Introduction Solar radiation Photovoltaics E2 History Semiconductor physics E1 E3 Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future • a conventional solar cell has one absorber with a single bandgap Eg1 • photons with energies E ≥ Eg1 are absorbed • photons with energies E < Eg1 are transmitted ⇒ in a multijunction solar cell several absorbers are stacked on top of each other Solid state solar cells.36 Winter School on Photonics for Energy Multijunction solar cells. Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future http://sunlab.site.uottawa.ca Solid state solar cells.37 Winter School on Photonics for Energy Multijunction solar cells. Uwe Zimmermann + I1 V1 I Introduction Solar radiation Photovoltaics History Semiconductor physics V Solar cells Electrical parameters + I2 V2 I CIGS solar cells Multijunction solar cells Other solar cells Current market development V + I3 V3 The future I V Solid state solar cells.38 Winter School on Photonics for Energy Multijunction solar cells. Uwe Zimmermann Introduction I Solar radiation Photovoltaics + History V1 Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells + Other solar cells V2 Current market development The future I + V3 V Solid state solar cells.39 Triple junction solar cells. Winter School on Photonics for Energy Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics http://www.ise.fraunhofer.de Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future http://pvlab.ioffe.ru Solid state solar cells.40 Winter School on Photonics for Energy Multijunction solar cells. Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future http://www.concentrix- solar.de/ http://psilab.ucsd.edu/ Solid state solar cells.41 Winter School on Photonics for Energy Active optics. Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells images: Prism Solar Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future Solid state solar cells.42 Winter School on Photonics for Energy Monograin solar cells. Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future Meissner, D.: Monograin Solar Cells – Time to Market Solid state solar cells.43 Winter School on Photonics for Energy A growing industry. Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future http://www.iea- pvps.org The cumulative installed solar cell power in IEA-reporting countries. • Since the year 2000 the installed capacity has doubled every second year. • Today the majority lies within grid-connected systems. Solid state solar cells.44 Winter School on Photonics for Energy Payback. Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future http://www.iea- pvps.org • On a system level solar cell installations take less than 2 years to break even (energy payback time). • The expected lifetime for a solar cell installation is more than 20 years. Solid state solar cells.45 Cost development for solar cell systems. Winter School on Photonics for Energy Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future http://www.iea- pvps.org Cost development for solar cell systems since 1997. • The price for solar cells has declined from 60 USD/watt (1976) to less than 4 USD/watt (2008). • However, since 2000 the decline has slowed down. Solid state solar cells.46 Winter School on Photonics for Energy Brandis/Waldpolenz. Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells UZ 2008 http://www.solarserver.de Current market development The future • Installed on a discontinued military air field in eastern Germany. • Planned to become the world’s largest PV power plant in 2008 with 40 MW. • About 500 000 cadmium-telluride thin-film modules from FirstSolar. Solid state solar cells.47 Size does matter. Winter School on Photonics for Energy Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future Solid state solar cells.48 The Future? Winter School on Photonics for Energy Uwe Zimmermann Introduction Solar radiation Photovoltaics History Semiconductor physics Solar cells Electrical parameters CIGS solar cells Multijunction solar cells Other solar cells Current market development The future Conclusions • In order to make an impact, we need to generate some TW of electricity by means of solar power. • A solar cell needs to • capture light • separate charge carriers • extract charge carriers Solid state solar cells.49