Vol. 1 Issue 2 | February 2016 FOREWORD Mr. Tevin Vongvanich President and Chief Executive Officer PTT VISTEC focuses on producing excellent researchers and scientists with internationally accepted frontier research outputs that can be applied in a real industrial application. “Fostering Excellence, Creating an Intellectual Society, and Driving Thailand to Prosperity” is our ambition. In order to do so, all accepted students at VISTEC will receive a full scholarship and benefits with no obligation after graduation. VISTEC offers distinctive and creative ways of educational management that is perfectly designed to develop talented students with exceptional quality. We believe that education is a major tool in improving our lives and in turn enhancing the country’s human capital. We expect to mold our students into outstanding citizens with high morality and at the same time contributing towards national development and sustainable growth. NEWS On November 25, 2015, Professor Dr. Jumras Limtrakul, President of VISTEC, together with Mr. Supattanapong Punmeechaow, CEO and President of PTT Global Chemical PCL, signed the Memorandum of Understanding to conduct frontier research and scientific development. This project is a multi-disciplinary model aimed to advance material development as well as to develop chemicals which are derived from the value added greenhouse gas (carbon dioxide) that is the results from the research and development of clean and green technology. On September 2, 2015, Dr. Vichit Suraphongchai, Chairman of the Executive Committee and the management team of Siam Commercial Bank (SCB) visited VISTEC. Subsequently, on October 24, 2015 he revisited VISTEC and cycled over 18 km. in Wangchan Valley. On December 17 – 18, 2015, Mr. Anand Panyarachun, Chairman of PTT Green Globe Award Council of Trustees and the council members visited VISTEC. Mr. Anand expressed that VISTEC should be an example of Thailand’s new education generation that dares to change and make the difference in an innovative way. The most important things that the new generation should bear in mind are to develop and expand our mindset, accept the diversity, and welcome adebating atmosphere because without these things there would not be innovation. He also emphasized that “change is permanent, do not be afraid of change but do not change because of fear”. On December 22, 2015, Mr. Abhisit Vejjajiva, former prime minister of Thailand, Mr. Korn Chatikavanij and Democrat Party members visited VISTEC. Mr. Abhisit wished that PTT Group and VISTEC were able to reach their goals and drive Thailand to become one of the leading countries. Contact Us: Tel: (+66) 033-014-444 | E-Mail: contact@vistec.ac.th | Website: www.vistec.ac.th | Official Facebook Page: www.facebook.com/Vidyasirimedhi 1 SCIENCE AND ENGINEERING @ Study of the Hole Transport Processes in Solution-Processed Layers of the Wide Bandgap Semiconductor Copper(I) Thiocyanate (CuSCN) Flexible Electronic The development of new generation of semiconductors that can be additively constructed on pieces of glass, plastic, or even paper, using simple solution-based processes such as printing, is paving the way toward new kinds of electronic devices which are flexible, extremely lightweight, versatile, and can be integrated more into our lives. Examples include flexible circuits, large-area lighting panels, smart labels, and wearable electronics among others. Transparent CuSCN Film Coated on Glass There are still many challenges lying in the path, however. One of the missing key components is a material that can transport positive charges (holes) and at the same time show high optical transparency. Copper(I) thiocyanate (CuSCN) is one of a handful compounds that combine both characteristics. The use of CuSCN in transparent transistors as well as organic light-emitting diodes (OLEDs) and organic solar cells (OSCs) with improved efficiencies has been successfully demonstrated earlier by Pattanasattayavong et al. In this current work, we study this special material in deeper details for its electrical and electronic properties using extensive characterization methods. The results yield important information on the material parameters as well as give highly useful insights into further development of this material. (Pattanasattayavong et al., Advanced Functional Materials, 2015, 25(43), 6802-6813.) Turning Conductive Carbon Nanospheres into Nanosheets for High-Performance Supercapacitors of MnO2 Nanorods Oxidized carbon nanosheets (OCNs), produced from black carbon nanospheres and used as a conductive additive in the supercapacitor electrodes of MnO2 nanorods, can significantly improve the charge-storage performance of the symmetric MnO2-nanorod supercapacitors with a maximum specific energy of 64 W h kg−1 and power of 3870 W kg−1. An optimum material composition of the supercapacitor electrode finely tuned is 60 : 30 : 10 wt% of MnO2 : OCN : PVDF, respectively. Interestingly, after 5000 charge/discharge cycles, the oxidation numbers of Mn at the positive and negative electrodes of the as-fabricated supercapacitor are +3.22 and +3.04, respectively. (Sawangphruk et al., Chemical Communications, 2016, 52, 2585-2588.) 2 Fig. Turning conductive carbon nanospheres into nanosheets for high-performance supercapacitors of MnO2 nanorods Contact Us: Tel: (+66) 033-014-444 | E-Mail: contact@vistec.ac.th | Website: www.vistec.ac.th | Official Facebook Page: www.facebook.com/Vidyasirimedhi INTERNATIONAL WORKSHOP AND CONFERENCE @ International Workshop and Conference Materials by Design for Energy Applications November 30th – December 1st, 2015 This International Workshop and Conference covered frontier research topics including: Advanced Materials, Design & Fabrication of Materials, Materials for Energy and the Environment, Green Nanotech, and Nanoelectronics. In order to take full advantage of the wide range of perspectives available from the distinguished participants, the presentations were brief and the focus of the sessions was on practical work and discussion. This allowed the many attendees and participants to gain a greater understanding of these interdisciplinary research areas, and led to the creation of ideas for new common research projects among those attending the workshop. Our internationally recognized guest speakers were: 1. Prof. Alexander Kuhn (University of Bordeaux, Bordeaux, France) 2. Prof. Phillippe A. Bopp (University of Bordeaux, Bordeaux, France) 3. Prof. Daniel Crespy (Max Planck Institute for Polymer Research, Germany) VISTEC Symposium Hybrid and Biohybrid - Past, Present and Future February 12th, 2016 Synthetic inorganic materials (ceramic and metal) and organic materials (textile and polymer) became common materials to be used in our life and society. The developments in the synthetic materials was inspired by geo- and bio-materials (rock/stone and fiber/wood) from both structural and synthetic viewpoints. New materials have been responsible for the major changes of our life and society; plastics, synthetic fiber, semiconductor, optical fiber are examples. Nanotechnology (and nanochemistry) is regarded as a key for the next paradigm shift. By combining the concepts, information, skiils and materials in different fields of chemistry (biochemistry, inorganic solid-state chemistry, organic and polymer chemistry and chemistry at surface and interface) and materials science (structural, electronic, optical and bio), we have unlimited potential research fields as Advanced Hybrid Materials, which will contribute our life and environments in the future. Our prestigious speakers were: 1. Prof. Dr. Eduardo Ruiz-Hitzky (CSIC, Spain) 2. Dr. Yoshiaki Fukushima (CROSS, Japan) 3. Prof. Dr. Niyazi Serdar Sariciftci (LIOS, Austria) 4. Prof. Dr. Jean Roncali (University of Angers, France) 5. Asst. Prof. Dr. Nawee Kungwan (Chiang Mai University, Thailand) 6. Dr. Thanyada Rungrotmongkol (Chulalongkorn University, Thailand) 7. Prof. Dr. Thawatchai Tuntulani (Chulalongkorn University, Thailand) 8. Dr. Supawadee Namuangruk (NANOTEC, Thailand) 9. Assoc. Prof. Dr. Yasutaka Tanaka (Shizuoka University, Japan) 10. Assoc. Prof. Dr. Tatsuo Kaneko (JAIST, Japan) 11. Asst. Prof. Dr. Suwadee Kongparakul (Thammasat University, Thailand) 12. Prof. Dr. Jin-Ho Choy (CINBM, South Korea) 13. Prof. Dr. Katsuhiko Ariga (NIMS, Japan) Contact Us: Tel: (+66) 033-014-444 | E-Mail: contact@vistec.ac.th | Website: www.vistec.ac.th | Official Facebook Page: www.facebook.com/Vidyasirimedhi 3 EVENTS VISTEC Open House 2016 On January 23-24, 2016, VISTEC held the “Open House 2016” event. Over 150 prospective students from all over Thailand joined us for the event. They had the opportunity to visit the campus; VISTEC laboratory, and Frontier Research Center, meet VISTEC faculty members and get to know VISTEC students. 68% of the students stated their intention of wanting to join us here at VISTEC. VISTEC New Year Party 2016 On January 14, 2016, VISTEC celebrated the New Year with lots of fun and joyful activities. Assoc. Prof. Dr. Prasert Pavasant, Acting Vice-President for Administration was our honorary star of the night. Prof. Dr. Jumras Limtrakul, the President surprised us all with presents for the VISTEC Pioneer Team and the BIGGEST draw ever! SELECTED RECENT PUBLICATIONS @ 1. Turning Conductive Carbon Nanospheres into Nanosheets for High- Performance Supercapacitors of MnO2 Nanorods | N. Phattharasupakun, J. Wutthiprom , P. Chiochan, P. Suktha, M. Suksomboon, S. Kalasina, M. Sawangphruk | Chemical Communications, 2016, 52, 2585-2588. 2. One-Pot Synthesis of Novel Hierarchical Bifunctional Ga/HZSM-5 Nano Sheets for Propane Aromatization | W. Wannapakdee, C. Wattanakit, V. Paluka, T. Yutthalekha, J. Limtrakul | RSC Advances, 2016, 6, 2875-2881. 3. Highly Integrated CO2 Capture and Conversion: Direct Synthesis of Cyclic Carbonates from Industrial Flue Gas | A. Barthel, Y. Saih, M. Gimenez, J.D.A. Pelletier, F.E. Kühn, V. D´Elia, J.-M. Basset | Green Chemistry, 2016, DOI: 10.1039/C5GC03007B. 4. Controlling the Hydrogenolysis of SilicaSupported Tungsten Pentamethyl Leads to a Class of Highly Electron Deficient Partially Alkylated Metal Hydrides | N. Maity, S. Barman, E. Callens, M.K. Samantaray, E. Abou-Hamad, Y. Minenkov, V. D'Elia, A.S. Hoffman, C.M. Widdifield, L. Cavallo, B.C. Gates. J.-M. Basset | Chemical Science, 2016, 7, 1558-1568. 5. Relationship between Surface Roughness, Internal Crystal Perfection, and Crystal Growth Rate | S.C. Galbraith, A.E. Flood, S. Rugmai, P. Chirawatkul | Chemical Engineering and Technology, 2016, 39, 199-207. 6. Hydrogenation of CO2 to Formic Acid Over a Cu-embedded Graphene: A DFT Study | J. Sirijaraensre, J. Limtrakul | Applied Surface Science, 2016, 364, 241-248. 4 7. Multifunctional Clickable and ProteinRepellent Magnetic Silica Nanoparticles | D. Estupiñán, M.B. Bannwarth, S.E. Mylon, K. Landfester, R. Muñoz-Espí, D. Crespy | Nanoscale, 2016, 8, 3019-3030. 8. Biodiesel Production from Palm Oil Using Hydrated Lime-Derived CaO as a Low-Cost Basic Heterogeneous Catalyst | W. Roschat, T. Siritanon, B. Yoosuk, V. Promarak | Energy Conversion and Management, 2016, 108, 459-467. 9. Mechanistic Insight into the Selective Catalytic Reduction of NO by NH3 Over Low-Valent Titanium-Porphyrin: a DFT Study | P. Maitarad, J. Meeprasert, L. Shi, J. Limtrakul, D. Zhang, S. Namuangruk | Catalysis Science & Technology, 2016, DOI: 10.1039/C5CY02116B. 10. A DFT Study of Arsine Adsorption on Palladium Doped Graphene: Effects of Palladium Cluster Size | M. Kunaseth, T. Mudchimo, S. Namuangruk, N. Kungwan, V. Promarak, S. Jungsuttiwong | Applied Surface Science, 2016, DOI:10.1016/J.APSUSC.2016.01.139. 11. N-Doped Reduced Graphene Oxide Aerogel Coated on Carboxyl-Modified Carbon Fiber Paper for High-Performance Ionic-Liquid Supercapacitors | P. Iamprasertkun, A. Krittayavathananon, M. Sawangphruk | Carbon, 2016, DOI:10.1016/J. CARBON.2015.12.092. 12. Bipolar Electrografting on the Inner Wall of Carbon Nanotubes | C. Kumsapaya, J. Limtrakul, A. Kuhn, D. Zigah, C. Warakulwit | ChemElectroChem, 2016, DOI:10.1002/ CELC.201500379. Contact Us: Tel: (+66) 033-014-444 | E-Mail: contact@vistec.ac.th | Website: www.vistec.ac.th | Official Facebook Page: www.facebook.com/Vidyasirimedhi