For RICCA, SpectroPure, Red Bird, and Solutions Plus Brands Emergency Contact(24 hr) - CHEMTREC(! lRICCA COMPANY CH EMICAL Domestic: 800-424-9300 International: 703-527-3887 HYDROCHLORIC ACID, 0.5 - 2.0 Normal (Molar) Aqueous Solutions MSDS Material Safety Data Sheet ~ -i (X ~c: Section 1: Chemical Product and Company Identification Catalog Number: 3617.5,3650,3650.01,3650.2,3651,3652,3653,3654, 3655, 3665, 3667, 3670, 3673, 3680, 3690, 3700, , H-170, H-175, H-177, H-180, H04200, H044260, H044300, 3701,3701.3,3703,3707,3709,3710, BW4431 H044305, HX-900, HX-906, R3650200, R3677000, R3695000, R3700050, R3700100, R3700110, R3700120, R3700140, R3702000, SH04200, SH044250, SH044260, SH044300, SH044305, SH044400 Product Identity: HYDROCHLORIC ACID, 0.5 - 2.0 Normal (Molar) Aqueous Solutions Manufacturer's Name: Emergency Contact(24 hr) - CHEMTRECCI RICCA CHEMICAL COMPANY LLC Domestic: 800-424-9300 International: 703-527-3887 CAGE Code: 4TCW6, OV553, 4XZQ2 Address: Telephone Number For Information: 817-461-5601 448 West Fork Dr Arlington, TX 76012 Date Prepared: Revision: 29 12/8/98 Last Revised: 01/08/2009 Date Printed: 09/24/2010 3:25:01 pm Section 2. Compositionlnformation on Ingredients Component Hydrochloric Acid CAS Registry # 7647-01-0 Concentration 4 -16.9 C 5 ppm Balance Not Available C 7.5 mg/m3 Water, Deionized 7732-18-5 OSHA PEL ACGIH TLV Not Available C 5 ppm C 7 mg/m3 Not Available Not Available Section 3: Hazrd Identification Emergency Overview: Mildly corrosive, non-flammable, non-toxic. Wash areas of contact with water for at least 15 minutes. Hazards increase as concentration increases. Target Organs: eyes, skin, respiratory system. Eye Contact: May cause irrtion, redness, pain, and tearing. Inhalation: May cause mild irrtation. Skin Contact: May cause irration, redness, and pain. Ingestion: May cause nausea, vomitng, diarrea and cramps. Chronic Effects/Carcinogenicity: None IARC - Hydrochloric Acid is unclassifable as to carcinogenicit to humans. Hydrochloric Acid is unclassifable as to carcinogenicity to humans. NTP - No. OSHA - No. Page 1 of 4 For RICCA, SpectroPure, Red Bird, and Solutions Plus Brands Emergency Contact(24 hr) - CHEMTREC(! CHEMICAL l RICCA COMPANY Domestic: 800-424-9300 International: 703-527-3887 HYDROCHLORIC ACID, 0.5 - 2.0 Normal (Molar) Aqueous Solutions MSDS Reproductive Information: Reproductve effecs cited in 'Registry of Toxic Effect of Chemical Substances' for Hydrochloric Acid. Reproductve effects cited in 'Registr of Toxic Effec of Chemical Substances' for Hydrochloric Acid. Teratology (Birth Defect) Information: Mutation data cited in 'Registry of Toxic Effects of Chemical Substances' for Hydrochloric Acid. Mutation data crted in 'Registry of Toxic Effec of Chemical Substances' for Hydrochloric Acid. Section 4: First Aid Measures - In all cases, seek qualified evaluation. Eye Contact: Irrigate immediately wrth large quantity of water for at least 15 minutes. Call a physician if irrrtation develops. Inhalation: Remove to fresh air. Give artficial respiration if necessary. If breathing is difcult, give oxygen. Skin Contact: Flush wrth plenty of water for at least 15 minutes. Call a physician if irrtation develops. Ingestion: Dilute with water or milk. Do not induce vomiting. Call a physician if necssary. Section 5: Fire Fighting Measures Flash Point: Not Available. Method Used: Not Available. LFL: Not Available. UFL: Not Available. Extinguishing Media: Use any means suitable for ex1inguishing surrounding fire. Fire & Explosion Hazards: Not considered to be a fire or explosion hazard. May react with metals to release flammable Hydrogen gas. Fire Fighting Instructions: Use normal proceures/instructions. Fire Fighting Equipment: Use protective clothing and breathing equipment appropriate for the surrounding fire. Section 6: Accidental Release Measures Cover the spill wrth Sodium Carbnate or a soda ash-slaked lime mix1ure (50:50). Mix and add water to form slurry. Decnt the liquid to the drain with excess water. Treat the solid residue as normal refuse. Wash site with soda ash solution. Always dispose of in a=rdance with local regulations. Section 7. Handling and Storage As with all chemicals, wash hands thoroughly after handling. Avoid contact wrth eyes and skin. Protect from freezing and physical damage. Safety Storage Code: Corrsive Section 8: Exposure Control/Personal Protection Engineering Controls: No specifc controls are needed. Normal room ventilation is adequate. Respiratory Protection: Normal rom ventilation is adequate. Skin Protetion: Chemical resistant gloves. Eye Protection: Safety glasses or goggles. Section 9: Ph)'sical and Chemical Properties pH: "1 Appearance: Clear, colorless liquid Odor: Odorless to slighijy pungent Solubility In Water: Inifnite Bollng Point("C): Approximately 100 Specific Gravity: Approximately 1 - 1.03 Vapor Pressure: Not Applicable. Melting Polnt("C): Approximately 0 Section 10: Stabilty and Reactivity Chemical Stability: Stable under normal conditions of use and storage. Incompatibilty: Most metals, Alkalis, actve metals, Cyanides, Sulfdes, Sulfrtes, Metal Oxides, Formaldehyde. Hazardous Decomposition Products: Fumes of Hydrogen Chloride and Hydrogen in contact wrth metals, Chlorine gas from Oxidizers. Hazardous Polymerization: Will not occur. Page 2 of 4 For RICCA, SpectroPure, Red Bird, and Solutions Plus Brands Emergency Contact(24 hr) -- CHEMTREC(! CHEMICAL l RICCA COMPANY Domestic: 800-424-9300 International: 703-527-3887 HYDROCHLORIC ACID, 0.5 - 2.0 Normal (Molar) Aqueous Solutions MSDS Section 11. Toxicological Information LD50, Oral. Rabbrt (Hydrochloric Acid) 900 mg/kg; Details of toxic effects not reported other than lethal dose value. LCLo, inhalation, human: 3000 ppm/5 minutes; No toxic effects noted. Section 12. Ecological Information Ecotoxlcologlcallnfonnation: Hydrogen Chloride has slight acute and chronic toxicity to aquatic life. Chemical Fate Information: Virtually 100% of Hydrogen Chloride will eventually end up in the air. Section 13. Disposal Considerations Cover the spill with Sodium Carbonate or a soda ash-slaked lime mix1ure (50:50). Mix and add water to form slurry. Decant the liquid to the drain wrth excess water. Treat the solid residue as normal refuse. Always dispose of in a=rdance with local, state and federal regulations. Section 14. Transport Information Part Numbers: 3617.5-5, 3650-1, 3650-1CT, 3650-2.5, 3650-32, 3650-4, 3650-5, 3650-55, 3650-5HP, 3650.01-200F2, 3651-1, 3651-2.5, 3651-5, 3654-5, 3655-1, 3655-32, 3655-5, 3655-55, 3670-1, 3670-5, 3673-2.5, 3673-32, 3673-5, 3680-1, 3680-32, 3700-1, 3700-16, 3700-1 CT, 3700-2.5, 3700-30,3700-32,3700-4,3700-5,3700-55, 3700-5HP, 3701.3-1, 3703-1, 3703-32, 3707-16, 3710-1, 3710-16, 3710-2.5, 3710-32, 3710-5, 3710-55, BW4431-16, H-170 10-L T, H-170 20-L T, H-170 4-L T, H-170 500ML, H-170 L T, H-175 10-LT, H-175 20-L T, H-175 200-L T, H-175 4-L T, H-175 500ML, H-175 L T, H-177 4-L T, H-177 L T, H-180 10-L T, H-180 20-L T, H-180 4-L T, H-180 4-L TC, H-180 500ML, H-180 L T, HX-900 4-L T, HX-906 20-L T, HX-906 4-L T, HX-906 L T, R3650200-20F, R3650200-4A, R3677000-20F, R3695000-20F, R3700050-1 A, R3700100-120A, R37001 00-1 A, R37001 00-4A, R3700100-500A, R3700120-1A, R3700140-20F, R3702000-1A, SH044200-10F, SH044200-1A, SH044200-20F, SH044200-4A, SH04260-20F, SH044300-100A, SH044300-10F, SH044300-1A, SH044300-20F, SH044300-4A, SH044305-20F, SH044400-10F, SH044400-1A, SH044400-20F, SH044400-4A, SH044400-500A D.O.T. Shipping Name: Hydrochloric Acid Solution D.O.T. Hazard Class: 8 UN 1 N.A. Number: UN1789 Packing Group; ILL D.OT Label; 8 L.,-~ ,~~ .................................../............"".........~,. ~.~/.~.....".................'...... ,-;'.. ,~' .,...... ,/ Section 15. Regulatory Information eliot meant to be all inclusive - selected regulation represented) OSHA Status:These items meet the OSHA Hazard Communication Standard (29 CFR 1910.1200) definition of a hazardous materiaL. TSCA Status:AII components of this solution are listed on the TSCA Inventory or are mix1res (hydrates) of items listed on the TSCA Inventory. Sara Title III: Section 302 Extremely Hazrdous Substances:Not Applicable. Section 311/312 Hazardous Catagorles:Acute: Yes Chronic, Fire, Pressure, Reactivit: No Section 313 Toxic Chemicals:Not Applicable. California: None Reported. Pennsylvania: Hydrochloric Acid is listed as an Environmental Hazard on the state's Hazardous Substances List. Hydrochloric Acid is listed as an Environmental Hazard on the state's Hazardous Substances List. RCRA Status: Not Applicable. CERCLA Reportble Quantity: Hydrochloric Acid - 5,000 pounds. Hydrochloric Acid - 5,000 pounds. WHMIS: E: Corrsive MateriaL. Section 16. Other Information Page 3 of 4 For RICCA, SpectroPure, Red Bird, and Solutions Plus Brands Emergency Contact(24 hr) - CHEMTREC(! CHEMICAL I RICCA COMPANY Domestic: 800-424-9300 International: 703-527-3887 HYDROCHLORIC ACID, 0.5 - 2.0 Normal (Molar) Aqueous Solutions MSDS NFPA Ratings: Health: 2 Flammability: 0 Reactvit: 0 Special Notice Key:None Flammability: 0 Reactivity: 0 Protecive Equipment:B (Protectve Eyewear, Gloves) HMIS Ratings: Health: 2 Rev 1,4-16-99: (Section 3) added mutation and reproductive data crted; IARC not classifable as to carcinogenicity to humans; Oral, Rat corrected to Oral, Rabbit, (Section 15) added Florida and Pennsylvania state information. Rev 2, 5-19-99: (Section 1) added catalog number 3701.3: Rev 3, 9-10-99: (Secton 1) added catalog number 3651. Rev 4, 12-10-99: (Section 1) Revised emergency telephone number to CHEMTRECiX 80~24-9300. Rev 5, 4-14-2000: Reformatted from WordPerfe~ to Microsoft WordQ; (Section 1) added catalog number 3673; (Section 2) revised exposure limits from mg/m3 to ppm: (Section 7) added storage code; (Section 15) added TPQ information. Rev 6, 10-09-2001: Reformatted to electronic data format: Rev 7, 12-06-2001: (Section 1) added catalog number 3650.1; Rev 8, 01-28-2002: (Section 1) removed catalog number 3650.1 after formulation change; Rev 9, 03-13-2002: (Section 1) added catalog number 3653; Rev 10, 12-18-2002: (Section 1) added catalog number 3654; (Rev 11,01-08-2003 (Secton 1) added catalog umber 3707. Rev 12, 09-05-2003: (Section 1) added catalog numbers 3650.01 and 3673; (Section 14) revise DOT name from Corrosive liquid, acidic, nos. Rev 13, 09-29-2003: (Section 1) added Solutions Plus catalog number H044300. Rev 14,10-24-2003: (Section 1) added Solutions Plus catalog number H044200. Rev 15, 11-03-2003: (Section 1) added Solutions Plus catalog number H044305. Rev 16, 03-01-2004: (Section 1) added catalog number R3677000. Rev 17, 3-5-04: (Sec 1) added catalog number 3617.5. Rev 18, 4-12-04: (Sec 1) added Solutions Plus catalog number H044260. Rev 19, 11-11-04: added cat number R3700100. Rev 20, 4-6-05 (Sec 1) added cat no R3695000. Rev 21,4-19-05: (See 1) added catalog numbers 3650.2 and 3667. Rev 22,09-29-2005: (Section 1) added Molar to title, added Red Bird catalog number H-177. Rev 23,11-29-2005: (Section 1) added Red Bird catalog numbers HX-900 and HX-906. Rev 24, 02-01-2006: (Section 1) added catalog number R3700050. Rev 25,07-17-2006: (Section 1) added SpectoPure catalog number BW4431 Rev 26,09-01-2006: (Section 1) added catalog number R3702000. Rev 27, 11-02-2006 (Section 1) added catalog number R3700110. Rev 28,03-25-2008: (Section 1) added catalog number R3700120. Rev 29, 01-08-2009 (Section 1) added catalog number R3700140. When handled properly by qualified personnel, the product described herein does not present a significant health or safety hazard. Alteration of its characteristics by concentration, evaporation, addition of other substances, or other means may present hazards not specifically addressed herein and which must be evaluated by the user. The information furnished herein is believed to be accurate and represents the best data currently available to us. No warranty, expressed or implied, is made and RICCA CHEMICAL COMPANY assumes no legal responsibility or liability whatsoever resulting from its use. Page 4 of 4