Soil Water Interactions With Other Soil Characteristics With and Without Tile Soil and Soil Water Workshop 15 January 2013 Tom DeSutter Assistant Professor of Soil Science Program Leader for Soil Science Why use subsurface drains? • Decrease soil water content. – Increase gas exchange • • • • Increase trafficability. Allow for improved soil warming. Remove excess soluble salts. Overall, improve production. Soil Water Basics • Only drainable water leaves via drains – Total soil porosity minus soil moisture at field capacity • This is generally thought of as “gravitational water” • Drainable water depends on texture (and bulk density) Soil Texture Drainable Porosity (% by vol.) clays, clay loams, silty clays 3-11% well structured loams 10-15% sandy 18-35% http://www.extension.umn.edu/distribution/cropsystems/DC7644.html Why does one care? • Bulk density and water content drive most soilwater relationships. • AFP influences gas exchange • WFPS influences microbial activity • Water content influences heat capacity which influences warming of the soil Basic Soil-Water Concepts Bulk density (Bd; g/cm3 or kg/m3 )= Ms/V Total porosity or pore space (TP; %)= Pd = particle density; assume 2.65 g/cm3 or 2,650 kg/m3) Gravimetric water content (Θg; % or g/g)= Volumetric water content (Θv; % or cm3/cm3)= (water by volume)/(volume of soil) or Bd*Θg Air-filled porosity (AFP; % or cm3/cm3)= TP - Θv Water-filled pore space (WFPS; % or cm3/cm3)= water by volume/total porosity Example Problem 1 If Bd = 1.3 g/cm3 and the Θg = 26%, what is the Θv, the AFP, and how much of the TP space is filled with water? Step 1: calculate TP by Step 2: calculate Θv by Bd*Θg Step 3: calculate AFP by Step 4: calculate WFPS by water by volume/total porosity Next page… Step 1: TP = 1-(1.3/2.65)*100 = 51% Step 2: Θv = 1.3 * 26 = 33.8% Step 3: AFP = 51% - 33.8% = 17.2% Step 4: WFPS = (33.8%/51%)*100 = 66% What if the Bd changed to 1.5 g/cm3? Step 1: TP = 43% Step 2: Θv = 39% Step 3: AFP = 4% Step 4: WFPS = 91% Clay vs Sand: water retention • “Sand” and “clay” soils can have the same TP as long as their Bd and Pd are the same. – But the “sand” soil has larger pores and less surface area (SA), and thus lower water retention than the “clay” soil – SA of sand, silt, and clay are 30, 1,500, and 3,000,000 cm2/g, respectively • A SA example… Example Problem 2 A 49 g sample of “clay loam” has 29, 41, and 31% sand, silt, and clay, respectively. What is its total surface area? Sand:14g*30cm2/g = 420 cm2 Silt: 20g*1,500cm2/g = 30,000 cm2 Clay: 15g*3,000,000cm2/g=45,000,000 cm2 45,030,420 cm2 5X the surface area as a 10,000 ft2 lot! 10X the surface area as a basketball court! So, surface area and matric forces lead to this… http://www.extension.umn.edu/distribution/cropsystems/DC7644.html Soil Gas Exchange Flux and Efflux of Soil Gases • Driven by concentration gradients • Driven by the AFP – Which again depends on the Bd and Θv Fick’s Law of Diffusion for the “Gradient Approach” dC C F DS DS dz z -3 Molar Concentration, C (mol m ) Depth Below Surface, Z (m) 0 5e+4 1e+5 2e+5 2e+5 3e+5 3e+5 4e+5 4e+5 0.00 A1 0.05 A2) linear regression can be fit through the [CO2] concentration with depth data and CO2 gradient is the slope A3 0.10 A2 0.15 c Fitted model, C = a + bZ Actual data 0.20 A1) fit a function to the [CO2] w/depth and take first derivative at z = i A3) finite-difference (concentration data from discrete depth increments below the surface) = CO2 Sensor -1 cm -2 cm -6 cm -10 cm DP ML2x -1 cm -2 cm -6 cm -10 cm Tom DeSutter ver.5 30 Oct 2006 DP ML2x Diffusivity of Soil Gases Diffusivity in Air and Water Gas CO2 in air CO2 in water O2 in air O2 in water Diffusion Coefficient (cm2/sec) 1.64 x 10-1 1.6 x 10-5 10,000X slower in water 1.98 x 10-1 1.9 x 10-5 10,000X slower in water From Coyne and Thompson, 2006 Example Problem 3, find flux Soil Bd = 1.3 g/cm3 and 1) Θv = 9% (almost “air-dry”) 2) Θv = 40% (nearly saturated) Example Problem 3 cont. Step 1: Solve for AFP (=TP – Θv) Step 2: Solve for Ds (diffusivity for CO2 in soil) Step 3: Solve for ΔC/Δz Step 4: Solve for F For the “air-dry” soil… Step 1: AFP = (1-1.3/2.65) – 0.09 = 0.4 cm3/cm3 Step 2: Ds = Dco2(0.66)(AFP) Ds = 1.64 x 10-1(0.66)(0.4) = 0.04 cm2/sec Penman, 1940 Example Problem 3 cont. Step 3: (10,000-2,000)/(20-5) = 533µL/L cm conversion: 8.9µg CO2/cm4 Step 4: F = 0.04 * 8.9 = 0.36µg CO2/cm2 sec For a nearly saturated soil, F = 0.09µg CO2/cm2 sec, which is 4X slower than an “air-dry” soil Heat Capacity (C) • “Amount of energy that an object must absorb or lose for its temperature to change by 1 oC.” (Coyne and Thompson, 2006) – Most commonly reported on a volume basis: cal/cm3 oC or J/cm3 oC • Overall, Ctotal = fmineralsCminerals + fomCom + fwaterCwater + fairCair where C is the heat capacity and f is the volumetric fraction • C is strongly affected by water Heat Capacity of Soil Components Constituent Quartz Organic matter Water Air Density (g cm-3) 2.66 1.30 Heat Capacity (cal cm-3 oC-1) 0.48 0.60 1.00 1.00 0.00125 0.003 From Hillel, 1998 Ctotal = fmineralsCminerals + fomCom + fwaterCwater + fairCair Ctotal = fminerals0.48 + fom0.6 + fwater1.0 + fair0.003 Example Problem 4 What is the C of a soil that has a Bd of 1.3 g/cm3 , is saturated with water (Θv = TP), and has 2% OM? Note: it is okay to neglect the properties of air. Assume Pd is 2.65 g/cm3. Step 1: determine TP; = (1 – 1.3/2.65)*100 = 51% Step 2: volume of solids = 100 – 51 – 2 = 47% Step 3: solve for Ctotal Ctotal = fminerals0.48 + fom0.6 + fwater1.0 Ctotal = 0.47*0.48+ 0.02*0.6 + 0.51*1.0 Ctotal = 0.75 cal/cm3 oC Continued… What if the same soil was only half-saturated with water? Step 1: Since at full saturation Θv was 51%, so one-half saturation is 25.5%. -So, Θv is 25.5%, AFP is 25.5% Step 2: solve for Ctotal Ctotal = 0.51*0.48+ 0.02*0.6 + 0.255*1.0 Ctotal = 0.5 cal/cm3 oC Compared to 0.75 cal/cm3 oC at full saturation -less energy needed to “warm” dryer soil Heat Capacity (cal/cm 3 oC) 0.8 0.7 0.6 0.5 0.4 0.3 Y intercept = 0.26; C of dry soil 0.2 0.0 0.1 0.2 0.3 0.4 0.5 Volumetric Water Content (cm3/cm3) 0.6 Heat Capacity (cal/cm3 oC) 0.8 Bd = 1.3 g/cm3 Bd = 1.5 g/cm3 Bd = 1.1 g/cm3 0.7 0.6 0.5 Bd 1.1 1.3 1.5 0.4 C of solids only 0.20 0.235 0.27 0.3 0.2 0.0 0.1 0.2 0.3 0.4 0.5 Volumetric Water Content (cm3/cm3) 0.6 Summary • Bd and water drive many of the heat, biological, and gas exchange processes – Plus chemical reactions… • So, soil and water management can too… – compaction; tile vs no tile; surface drainage • Basic equations are simple, helpful tools • Easy to put actual numbers to what you are observing in the field – Quantitative vs Qualitative Soil Water Interactions With Other Soil Characteristics With and Without Tile Soil and Soil Water Workshop 15 January 2013 Tom DeSutter Assistant Professor of Soil Science Program Leader for Soil Science