Composites: Part B 40 (2009) 522–529 Contents lists available at ScienceDirect Composites: Part B journal homepage: www.elsevier.com/locate/compositesb A multi-objective optimization approach for design of blast-resistant composite laminates using carbon nanotubes Mahmoud M. Reda Taha a,*, Arife B. Colak-Altunc a, Marwan Al-Haik b a b Department of Civil Engineering, Univ. of New Mexico, Centennial Engineering Center, Albuquerque, NM 87131-0001, USA Department of Mechanical Engineering, Univ. of New Mexico, Albuquerque, NM 87131-0001, USA a r t i c l e i n f o Article history: Received 28 January 2009 Received in revised form 22 April 2009 Accepted 23 April 2009 Available online 7 May 2009 Keywords: A. Carbon-carbon composites (CCCs) A. Nano-structures B. Impact behavior C. Laminate mechanics Blast-resistant composites a b s t r a c t A reliable process for the design of blast-resistance composite laminates is needed. We consider here the use of carbon nanotubes (CNTs) to enhance the mechanical properties of composite interface layers. The use of CNTs not only enhances the strength of the interface but also significantly alters stress propagation in composite laminates. A simplified wave propagation simulation is developed and the optimal CNT content in the interface layer is determined using multi-objective optimization paradigms. The optimization process targets minimizing the ratio of the stress developed in the layers to the strength of that layer for all the composite laminate layers. Two optimization methods are employed to identify the optimal CNT content. A case study demonstrating the design of five-layer composite laminate subjected to a blast event is used to demonstrate the concept. It is shown that the addition of 2% and 4% CNTs by weight to the epoxy interfaces results in significant enhancement of the composite ability to resist blast. Ó 2009 Elsevier Ltd. All rights reserved. 1. Introduction Structural fiber reinforced plastic (FRPs) composites have been used extensively in several high performance structural applications (e.g. vehicles, airplanes, etc.) for their significantly high strength-to-weight ratio. Other plausible features of FRPs include their manufacturing flexibility, which allows composites to achieve material properties that are difficult to attain using single-phase materials. However, typical structural composites exhibit limited ductility, which limit their ability to absorb energy under impact loading and ultimately leads to their failure [1]. This limited energy absorption is related to the lack of plasticity mechanisms and dominant debonding at weak interfaces [2]. The dominant failure mechanism in composite laminates subjected to impact-loading is a complex combination of delamination predominantly caused by mode II shear, matrix cracking caused by transverse shear, and translaminar fracture in terms of fiber fracture and kinking [3]. There are several factors that dictate the above fracture processes, such as the material variables, loading and environmental conditions and the source of impact. Amongst the material variables, the mechanical properties of fiber and matrix, particularly the failure strains, interface properties, fiber configuration and stacking sequence in angle-ply laminates play, important roles in determining the impact damage resistance of composites [4]. * Corresponding author. Tel.: +1 505 277 1258; fax: +1 505 277 1988. E-mail addresses: mrtaha@unm.edu (M.M. Reda Taha), burcu@unm.edu (A.B. Colak-Altunc), alhaik@unm.edu (M. Al-Haik). 1359-8368/$ - see front matter Ó 2009 Elsevier Ltd. All rights reserved. doi:10.1016/j.compositesb.2009.04.020 Significant efforts for developing blast-resistant composites have been conducted in the last three decades. Brennan and Prewo [5] reported a composite made of a glass–ceramic matrix reinforced with silicon carbide fibers that exhibited exceptional mechanical strength and toughness. Toughness measurements of new silicon carbide fiber composites were reported to be 50 times that of typical ceramic composites. Much interest was directed to examine the impact strength of carbon/epoxy composites [6]. Kang and Lee [7] reported a significant improvement in energy absorption of multi-laminate carbon composites by chain and plain stitching. More recently, Tekalura et al. [8] investigated the advantages of using polyurea and E-glass vinyl ester layered composites as a sandwich material for shock mitigation structures. Research was also devoted to developing computational tools to simulate composite behavior under impact loads and to quantify damage in laminated composites (cf. [9]). Riccio and Tessitore [10] demonstrated the strong dependence of composite behavior on the loading conditions using nonlinear finite-element modeling. Batra and Hassan [11] also used a continuum damage mechanics approach in their characterization of damage due to blast loading of unidirectional fiber reinforced composites. Moreover, Donadona et al. [12] successfully implemented and validated a 3D continuum damage mechanics finite-element modeling approach for composite laminates subjected to low-velocity impact. Such investigations provided a roadmap to identify the desired characteristics of composites to resist blast events. Here we suggest the addition of carbon nanotubes to enhance blast resistance of structural composites and we discuss below a numerical approach to determine the optimal carbon nanotubes content to enhance blast resistance. M.M. Reda Taha et al. / Composites: Part B 40 (2009) 522–529 2. Carbon nanotubes Carbon nanotubes (CNTs) have drawn significant attention from the research community for their attractive mechanical properties. CNTs represent a unique form of carbon that can be visualized by considering a single grapheme sheet representing a lattice of carbon atoms distributed in a hexagonal pattern [13]. A single wall carbon nanotube (SWCNT) is 1–3 nm in diameter [14]. The attractive properties of SWCNTs might be attributed to their unique nanostructure. SWCNTs possess exceptional mechanical [15] properties and superior thermal and electric properties compared to macroscale fibers such as graphite, Kevlar, SiC and alumina. The strength, elastic modulus and the fracture properties of carbon nanotubes are an order of magnitude higher than those of most common composite materials. The properties of CNTs are presented in Table 1 after [16]. A schematic representation of a SWCNT is shown in Fig. 1(a) and a transmission electronic microscope (TEM) image of several SWCNTs is shown in Fig. 1(b). Numerous experiments have been reported on the enhanced mechanical properties of SWCNTs. Of interest here is the significantly high stiffness (Young’s modulus of elasticity) of SWCNTs which was measured using atomic force microscopy [17]. These experiments suggested that the SWCNT Young’s modulus is usually around 1 TPa, and SWCNTs are slightly stiffer than multiwalled nanotubes. Moreover, the tensile strength of SWCNTs obtained from direct tension tests is found to vary between 50 and 150 GPa for different strain rates and temperatures [16,18]. In spite of the fact that the fracture toughness of SWCNTs are not yet measured experimentally, researchers [19] found that absorbed energy to failure of a composite based on polyvinyl-SWCNTs was 18 times higher than Kevlar fibers and 48 times higher than graphitic fibers. Various methods have been successfully utilized to synthesize CNTs, such as arc discharge, laser ablation pyrolysis and chemical vapor deposition [20]. Researchers reported successful inclusion of CNTs in polymer matrices using various techniques to avoid the difficulty of uniformly dispersing CNTs in polymer [21] including the use of magnetic fields [22]. We suggest here that CNTs can be dispersed in epoxy forming the interface of the composite laminates. CNTs at concentrations of 2–5% in epoxy can significantly enhance the tensile strength and tensile modulus of the composite interface. We suggest that using classical Voigt’s mixture rule [23]; we can approximately predict the properties of CNT strengthened epoxy. We hypothesize that such a change of strength and stiffness of the interface will play a major role in blast resistance as it alters the stress to strength distribution inside the composite laminate. 3. Stress waves propagation in composite laminates To simulate this effect, we adopt a simplified approach for stress wave propagation in bounded elastic media after Kolsky [24] and Al-Haik and Almyadmeh [25]. The velocity of longitudinal waves C 0 in a medium of density q and bulk modulus K can be computed as C0 ¼ sffiffiffiffi K ð1Þ q This method allows computing reflection and refraction of both dilation and distortion waves at free boundaries and at an interface between two media. We limit our discussion here to the propagation of longitudinal waves at the interface to predict the normal stresses at both sides of an interface in the composite laminate due to an incident pressure. However, the proposed approach can be extended to include torsional and flexural stress waves [24]. Considering a limited width dx of the composite layer as shown in Fig. 2 with the applied stress rxx and the transmitted wave produc@ rxx dx, one can ing the stress at the other side of the interface rxx þ @x write the following differential equation q Table 1 Mechanical properties of CNTs compared to typical structural materials [16]. 523 @2u @2u ¼E 2 2 @x @t ð2Þ This equation can be solved by considering a linear displacement time function uðtÞ. This leads us to realize the fundamental relationship of the stress with particle velocity as Material Modulus (GPa) Strength (MPa) Fracture toughness, K IC ðMPa m1=2 Þ Steel 4140 Ti–6Al–4V C–C composites Kevlar 49 SWCNTS 190–210 113 125 1646 910 1200–1600 54–62 44–66 70 rxx ¼ qC 0 186 12,000 3400 150,000 60–80 100 The term qC 0 is known as the characteristic impedance. Defining the particle velocity V ¼ @u=@t we can re-write Eq. (3) to relate the particle velocity to the stress as @u @t ð3Þ Fig. 1. (a) Schematic representation of single wall carbon nanotube (SWCNT). (b) TEM image showing SWCNTs produced by arc discharge (courtesy of Al-Haik M, 2008). 524 M.M. Reda Taha et al. / Composites: Part B 40 (2009) 522–529 form the step-by-step in-time analysis to obtain the stress pulse time history. 4. Multi-objective optimization Fig. 2. Assumptions for longitudinal wave propagation. V¼ rxx qC ð4Þ The above method can be extended to estimate the reflected and transmitted waves and stresses at an interface between two media. Assuming an incident stress to the interface rI , part of that stress will be transmitted to the second media and part will be reflected. The transmitted stress can be computed by considering the continuity of velocity across the interface plane V I ¼ V T þ V R where V I is the incident particle velocity, V R is the reflected particle velocity and V T is the transmitted particle velocity. This is shown schematically in Fig. 3. Relating the incident stress to the incident particle velocity at the first layer before the interface V I can be computed as VI ¼ rI qI C I ð5Þ Equilibrium at the interface also requires that ðrI þ rR ÞA1 ¼ rT A2 ð6Þ where A1 and A2 are areas of Layers 1 and 2, respectively. By substituting Eq. (5) in Eq. (2) and solving Eq. (6) one can deduce the transmitted stress rT and the reflected stress rR as 2A1 q2 C 2 rI A1 q1 C 1 þ A2 q2 C 2 A2 q2 C 2 A1 q1 C 1 ¼ rI A1 q1 C 1 þ A2 q2 C 2 rT ¼ ð7Þ rR ð8Þ For the composite laminates considered in the current investigation, all the areas will be assumed identical; A1 ¼ An ; n ¼ 1; . . . ; N where N is the total number of layers. It becomes obvious from Eqs. (7) and (8) that direction of the reflected pressure rR is a function of the characteristic impedance of each layer. The stress distribution can therefore be altered by optimally distributing the impedance (stiffness) of the composite layer. By adding CNTs to the epoxy interface, one will increase the characteristic impedance of the layer and alter the reflected and transmitted pressure. It is important to realize that the final stress in each layer is the algebraic sum of both the reflected and transmitted stress waves occurring in the layer at different time steps. Therefore, a step-by-step intime analysis is required to account for all the stress propagation in the laminate. A computer code is thus developed after [25] to per- The above simulation method can predict the stresses at the different composite layers due to an incident pressure applied to the composite laminate. We suggest that adding CNTs to the epoxy interface can alter the stress distribution in the composite layers. Moreover, adding CNTs to epoxy will also enhance the ultimate tensile strength of the interface and thus might alter the failure mode to occur in the composite fiber instead of the interface. However, CNTs are expensive materials and therefore one shall optimize the amount of CNTs to be added such that the composite strength against blast is enhanced while limiting the cost. Furthermore, if more than one interface exists (which is the case in most composite laminates), nonlinear behaviors can be observed with alternating the impedance of the interface layers by using different CNT content in each layer. Classical optimization approaches have always considered a single-objective function while dealing with all other objectives as constraints. The fundamental difference between single-objective and multi-objective optimization is the ability of multi-objective optimization to avoid the artificial fixes needed for singleobjective optimization methods in order to address tradeoffs between the two different objectives. For instance, we might need to limit failure of all interface layers, the optimal CNT contents of the layers are those needed to distribute the stress in the composite laminate such that the maximum stress in each interface layer does not exceed its strength, which is also a function of the CNT content. We suggest that such a design can be achieved by getting candidate designs to lie in the Pareto front, typically known as Pareto-optimal solutions after Pareto [26]. De Kruijf et al. [27] reported successful microstructural optimization to handle the tradeoffs between alternative microstructures to achieve desired conductivity and stiffness in composite materials. Two categories of multi-objective optimization methods are identified in the literature (cf. [28]). The first category utilizes classical single-objective optimization methods while reformulating the problem to address multi-objectives considering preferences between the different objective functions [29]. Methods in the first category include techniques such as the weighted sum method, the e-constraint method and the hierarchical optimization method [29]. In the hierarchical optimization method the top priority objective function is initially optimized and then the second priority function is optimized subject to the constraint that the top priority is not adversely affected. This procedure repeats itself for all priority functions. In this paper, weighted sum method is used due to its ability and relative simplicity in demonstrating different optimization alternatives. The second category of multi-objective optimization methods establishes an optimization method that is multi-objective in nature by using evolutionary optimization such as non-sorted genetic algorithms [30]. 5. Case study Fig. 3. Schematic representation of wave transmission and reflection at the interface. Here we present a case study to demonstrate the integration of the above methods for designing a blast-resistant structural composite using carbon nanotubes. The composite of interest here is a five-layer carbon fiber composite shown schematically in Fig. 4. The properties of the materials used for the five composite layers are presented in Table 2. We simulated a blast event, using scaling laws after Smith and Hetherington [31]. This blast is aimed to produce an incident pressure of 140 MPa at the surface of the composite to assure the failure of the composite before the addition of M.M. Reda Taha et al. / Composites: Part B 40 (2009) 522–529 525 noted by a1 and a2 , are defined as the design variables subject to the following bounds 0 6 a1 6 amax and 0 6 a2 6 amax ð12Þ amax is the maximum CNT ratio, which is set at 5% for practical Fig. 4. Schematic representation of the composite laminate for the case study showing five-layer laminate. Table 2 Mechanical properties of the different layers of the structural composite. Material Modulus (GPa) Strength (MPa) Fracture toughness, K IC ðMPa m1=2 Þ Carbon fibers Epoxy SWCNTs 70 5.4 12,000 600 60 150,000 70 6 100 CNT. Using the stress wave propagation approach described above, the stresses in the structural composite layers at different time steps were simulated using the step-by-step in-time analysis. The stress at each layer was then compared to the material strength of that layer. Carbon nanotubes were then assumed to be added to the epoxy interface at Layers 2 and 4. Addition of carbon nanotubes increased the interface strength and altered the stiffness distribution in the composite and, therefore, the stress propagation in the composite. We implemented an optimization method to identify the Pareto-optimal design front. Two objective functions representing the maximum tension and compression stress to strength ratios in the composite denoted as f1 and f2 are defined as f1 ¼ max16m6N f2 ¼ max16m6N maxðrTm Þ rUT m maxðrCm Þ rUC m reasons. Two optimization methods (denoted here as OPT1 and OPT2) were used to find the optimal values of a1 and a2 . The first optimization method denoted OPT1 implemented the Broyden–Fletcher– Goldfarb–Shanno (BFGS) gradient based method which represents a modified version of the quasi-Newton methods as described below [32]. The second optimization method denoted OPT2 is a nongradient based global optimization algorithm after Jones [33] that balances between global and local search. The optimization process was developed under Design Analysis Kit for Optimization and Terascale Applications (DAKOTA) environment (cf. [34]). Fig. 5 provides a schematic representation of the optimization process and the optimization/simulation interface. Other optimization methods can also be used to perform the required optimization. We limit our discussion here to these two methods for space limitation. The choice of the two methods was to demonstrate the difference between gradient and non-gradient optimization approaches. ¼ fa1 a2 g is In this process, the vector of design variables a passed by the optimization environment (DAKOTA) to the simulation algorithm to compute the maximum tensile and compressive stresses in all the layers. The two objective functions f1 and f2 (Eqs. (9) and (10)) are computed and then used to compute the combined objective function f j (Eq. (11)) using one set of weights wj1 and wj2 . Once the optimization process terminates, the j þ 1th set of weights are used and the process is repeated until all assigned weights are examined. Variation of weights enables forming the Pareto front for multi-objective optimization. As the number of weights increases, a fine Pareto front can be established. However, increasing the number of weights results in increasing the computation time. Our preliminary experiments showed that 0.025 increments in weights are sufficient for obtaining a good Pareto front. Fig. 6 shows the surface of the objective function for three different sets of weights. The OPT1 method implements the BFGS algorithm. This algo 0 using an rithm is based on updating an initial variable vector a approximate Hessian matrix B0 . The approximate Hessian matrix can be initiated as the identity matrix similar to the gradient des- ð9Þ ð10Þ In this formulation, f1 is the maximum tensile stress to strength ratio in all individual layers and f2 is the maximum compressive stress to strength ratio in all individual layers. N is the total number of layers in the composite; maxðrTm Þ is the maximum tensile stress observed in the mth layer due to the applied stress wave; rUT m is the ultimate tensile strength of the mth layer; maxðrCm Þ is the maximum compressive stress observed in the mth layer due to the applied stress wave; rUC m is the ultimate compressive strength of the mth layer. The optimization problem is formulated as a multi-objective nonlinear unconstrained optimization that targets minimizing the combined objective function f j defined as min f j ¼ wj1 f1 þ wj2 f2 ð11Þ where wj1 and wj2 are the jth set of weights of the objective functions f1 and f2 such that wj2 ¼ 1 wj1 and j ¼ 1; 2; 3; . . . ; J where J depends on the weight increment. The CNT content in Layers 2 and 4, de- Fig. 5. Schematic representation of the optimization process combining gradient and non-gradient optimization methods. The figure shows the initialization steps, opt represents the vector of the kth optimization iteration and the update process. a j optimal solution for the jth set of weights. 526 M.M. Reda Taha et al. / Composites: Part B 40 (2009) 522–529 Fig. 6. Surface of the combined weighted objective function f j versus CNT content in Layer 2 and 4 represented by the variables a1 and a2 for three sets of weights: (a) w1 ¼ 0:1; w2 ¼ 0:9, (b) w1 ¼ 0:5; w2 ¼ 0:5 and (c) w1 ¼ 0:9; w2 ¼ 0:1. 527 M.M. Reda Taha et al. / Composites: Part B 40 (2009) 522–529 Fig. 7. Schematic representation of the search method used for non-gradient optimization OPT2. Fig. 8. Tensile stress to strength time history for all five layers of the original composite without CNTs showing failure at Layer 4 as the stress to strength ratio exceeds unity. cent method. The step size sk for the kth iteration can be computed k Þ as using the gradient of the objective function rf ða kÞ Bk sk ¼ rf ða ð13Þ A maximum step size smax is typically used to limit the trust region size. The maximum step size in the case study was set to 1000. The kþ1 can be identified as updated solutions a a kþ1 ¼ a k þ bk sk ð14Þ k where b is the optimal search direction satisfying Wolfe conditions [35]. The approximate Hessian matrix of the k þ 1 iteration is updated by computing the change in gradient Dk as kþ1 B k ¼B þ Dk DkT DkT sk Bk sk ðBk sk ÞT skT Bk sk ð15Þ Convergence is checked by observing the change in the objective k Þj. A convergence limit was set to function gradient norm jrf ða 1e4 in the case study. Termination of the OPT1 method for each set of weights was achieved by meeting the convergence limit or performing the maximum number of iterations (function evaluations) set to 1000. The second optimization method denoted OPT2 known as Dividing Rectangles (DIRECT) starts by scaling the feasible region into an n-dimensional unit hypercube. The search begins at the center point of the hypercube to find the optimal solution for the combined weighted objective function f. Sampling is used to select feasible points that will be the center of the potentially optimal rectangles and these rectangles are further divided into smaller rectangles until the termination criterion is met [36]. One can decide to divide a sub-region or a bigger sub-region by setting a threshold to the ratio of the sub-region of interest to the largest sub-region. Fig. 7 shows the design space partitioning with search method. Termination is based on meeting the maximum number of iterations (function evaluations) or reaching the minimum box size k Þ ðb ¼ bmin . The minimum box size bmin was set here to 1e8 and the maximum number of iterations was set to 1000. Fig. 9. Pareto front and results for multi-objective optimization using two optimization methods OPT1 and OPT2. Table 3 Results of multi-objective optimization showing the significance of changing CNT contents in interface Layers 2 and 4 represented by a1 % and a2 % on the objective functions f1 and f2 . Solution 3 is selected as the optimal design of composite laminates. Solution # a1 % a2 % Tensile stress/ strength ratio ðf1 Þ Compressive stress/ strength ratio ðf2 Þ 1 2 3 4 5 1.64 1.80 2.01 2.74 3.66 4.88 4.15 3.97 3.44 4.20 0.332 0.297 0.277 0.226 0.218 0.411 0.416 0.421 0.437 0.449 6. Results and discussion Numerical experiments for the case study were run under Ubuntu 8.04 with 4 GB RAM. Results of the stress to strength ratios at the different composite layers of the original composite (no carbon nanotubes) are presented in Fig. 8. It is obvious that the composite would have failed at the interface Layers 2 and 4, as the stress/strength ratio exceeded unity. The results of the optimization methods are shown in Fig. 9. Two Pareto-optimal curves are Fig. 10. Tensile stress to strength time history for all five layers of the composite laminate including CNTs (2% in Layer 2 and 4% in Layer 4). 528 M.M. Reda Taha et al. / Composites: Part B 40 (2009) 522–529 ber of iterations was never reached by either of them. In average, OPT1 required 18 iterations and OPT2 required 819 iterations. Termination of OPT1 was due to the convergence limit and termination of OPT2 was due to the minimum box size limit. These might be attributed to the existence of a number of local minima in the surface of the combined weighted function f associated with some weight combinations. Such local minima might influence the performance of the gradient based method OPT1 but would not affect the non-gradient search method OPT2. This comparison is limited to the termination and convergence conditions imposed on each method as described above. 7. Conclusions Fig. 11. Comparison of maximum tensile stress to strength time-history of interface layers with and without CNTs for (a) Layer 2 and (b) Layer 4. shown in Fig. 9 using OPT1 and OPT2 optimization techniques. Each point on the Pareto-optimal curve represents a viable solution with a different combination of CNT contents a1 and a2 . It can be observed from Fig. 9 that the non-gradient search method (OPT2) was more successful than the gradient based optimization (OPT1) in finding solutions that resulted in a lower stress to strength ratio. The optimal CNTs contents based on OPT2 is presented in Table 3. While all the points on the Pareto front represent possible optimal solutions, we select the solution corresponding to a relatively minimized value of both functions f1 and f2 , with weights 0.225 and 0.775, respectively. This means that the addition of 2% and 4% CNTs to the two epoxy interface layers can significantly enhance the blast resistance of the structural composite. Fig. 10 shows the stress to strength time-history in the five layers of the composite laminates due to the blast with the optimal CNT contents. Fig. 11 compares the stress to strength time history of the interface (epoxy) layers with and without CNTs. It can be observed that the use of CNTs with the polymer interface (here epoxy) can alternate the stress wave propagation in structural composites and can significantly enhance the structural composite resistance to blast events. Optimization for OPT1 required 0.28 s of CPU time whereas optimization for OPT2 required 5.18 s of CPU time. That indicates that OPT2 method will typically need much longer computation time (about 19-folds) compared with OPT1 method. Computation time was not a significant influence on this case study because of its relatively inexpensive simulation. However, this issue might be of interest when computationally expensive simulation is considered. Finally, both optimization methods were capable of identifying the Pareto-optimal solution. However, the non-gradient search method OPT2 was capable of identifying better solutions than those found by the modified quasi-Newton method OPT1. By setting the maximum number of iterations to 1000, we gave sufficient tolerance for both methods to converge since the maximum num- A numerical approach for design of composite laminates for enhanced blast resistance using carbon nanotubes (CNTs) is presented. The hypothesis is based on the fact that mixing CNTs with the polymer interface can result in changing the interface mechanical characteristics including strength, stiffness and impedance. A simplified simulation for wave propagation in composite laminates is developed. An optimization approach based on determining the optimal CNT content in the composite interface is developed. A case study for enhancing the blast resistance of a five-layer composite laminate is presented. Optimal CNT contents of 2% and 4% are identified. Gradient and non-gradient based optimization methods were shown to be capable of establishing the Pareto front. The non-gradient method proved to be more capable of identifying the optimal solutions. Experimental investigations are underway to prove the proposed hypothesis. Acknowledgements This research is mainly funded by the Army Research Office (ARO) Grant # W911NF-08-1-0421. Moreover, Grants by Defense Threat Reduction Agency (DTRA) (Grant # HDTRA1-08-1-0017 P00001) and National Science Foundation (NSF) Award # CMMI0800249 shall also be greatly acknowledged. References [1] Langdon GS, Nuricka GN, Lemanskia SL, Simmons MC, Cantwell WJ, Schleyer GK. Failure characterization of blast-loaded fibre–metal laminate panels based on aluminum and glass–fibre reinforced polypropylene. Compos Sci Technol 2007;67(7):1385–405. [2] Tsai L, Prakash V. Structure of weak shock waves in 2-D layered material systems. 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