NA-LUBE® AW 6000 Series
Ashless Multifunctional Antiwear Additives
www.kingindustries.com
NA-LUBE® AW 6000 Series
NA-LUBE® AW 6000 Series - Ashless Antiwear Additives
Ashless Multifunctional Antiwear Additives
The NA-LUBE AW 6000 Series consists of light-colored, 100% active antiwear additives based on various
phosphorous, nitrogen and sulfur chemistries. With the exception of AW-6010, all are multifunctional in
terms of providing excellent antiwear properties in combination with other property enhancing functions as
shown in the chart that follows.
Product
%P
%N
%S
Functions
Ashless Amine Phosphate-Based Antiwear
NA-LUBE AW-6010
5.3
4.8
-
AW
NA-LUBE AW-6110
8.2
1.8
-
AW, CI
NA-LUBE AW-6110P
5.3
3.7
-
AW, CI
NA-LUBE AW-6220
4.5
5.7
-
AW, CI, YMD
NA-LUBE AW-6400FG
8.3
2.4
-
EP/AW, CI
NA-LUBE AW-6330
4.5
-
10.0
EP/AW, AO, CI
NA-LUBE AW-6335
7.0
-
14.1
EP/AW
NA-LUBE AW-6310
4.2
3.0
9.1
AW, CI, YMD
NA-LUBE AW-6360
5.0
2.6
10.8
EP/AW, CI
Ashless Dialkyldithiophosphate
Multifunctional
NA-LUBE AW technology offers excellent antiwear and FZG
performance coupled with rust and corrosion inhibition.
Photos:
Far Left: Base Oil without any additives
Immediate Left: Base Oil with NA-LUBE AW technology
The NA-LUBE AW 6000 product line of unique ashless chemistries exhibits the following properties:
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
Excellent antiwear and extreme pressure (FZG) performance
Good rust and corrosion inhibition
Protection of non-ferrous metals
Good to excellent demulsification
Solubility in a wide range of base oils, including silicone fluids
Synergistic with other additives (i.e., King Industries’ NA-LUBE EP and K-CORR Series)
Good hydrolytic stability
Excellent thermal stability
Solubility
The NA-LUBE AW 6000 Series exhibits excellent solubility in a wide range of base oils, including
naphthenic oils, solvent refined Group I base oils, hydrotreated Group II base oils, Group III base oils,
polyalphaolefins, synthetic diesters, and silicone fluids (e.g., Dow Corning 200, 510, and 550).
NA-LUBE AW 6000 Series: Ashless Amine Phosphate-Based
Antiwear Additives
Description
NA-LUBE AW-6010
Amine phosphate with excellent antiwear properties at very low treat levels.
NA-LUBE AW-6110
Amine phosphate with excellent antiwear properties and excellent rust protection. Imparts
outstanding FZG performance (higher than 12 load stages) at low treat levels (0.10 – 0.15%).
NA-LUBE AW-6110P
Amine phosphate with excellent antiwear properties and excellent rust protection. Can be
used with NA-LUBE EP-5216 as an alternative to chlorinated paraffins.
NA-LUBE AW-6220
Complex composition of amine phosphate chemistries with excellent antiwear properties, excellent rust protection and yellow metal deactivating functionality.
Outstanding FZG performance at low treat levels.
NA-LUBE AW-6400FG
NSF HX-1 approved multifunctional additive.
 Performance in a Paraffinic ISO VG 46 Base Oil
The following table shows the performance of NA-LUBE AW-6010, AW-6110, and AW-6220 when added to
a paraffinic ISO VG 46 base oil.
0.25%
AW-6010
Tests
0.10%
AW-6110
Base Oil
0.10%
AW-6220
ISO VG 46 (Group II)
Steel Corrosion (ASTM D 665, DIN 51 585) A & B
Not Applicable
Pass
Pass
42-38-0
10
41-39-0
10
41-39-0
5
Copper Corrosion (ASTM D 130, DIN 51 759)
3 hours, 100°C
24 hours, 100°C
3 hours, 135°C
1a
1b
1b
1a
1b
1b
1a
1b
1b
FZG A/8.3/90 (ASTM D 5182, DIN 51 354 Part 2)
Damage Load Stage
>12
>12
12
Four Ball Wear (ASTM D 4172)
1 hour, 75°C, 1200 rpm, 30 kgf, Scar Diameter (mm)
1 hour, 75°C, 1200 rpm, 40 kgf, Scar Diameter (mm)
0.46
0.64
0.32
0.50
0.40
0.43
Demulsibility (ASTM D 1401, DIN 51 599)
Oil-Water-Emulsion
Separation Time (Minutes)
 Performance of NA-LUBE AW-6220 as a Yellow Metal Deactivator
The table below compares the performance of NA-LUBE AW-6220 to the performance of two common
yellow metal deactivators. At a treat level of 0.10%, NA-LUBE AW-6220 provides excellent yellow metal
protection, while also providing steel corrosion protection with good antiwear properties.
Tests
--
0.10% DMTD***
Derivative
0.10%
Tolytriazole
0.10% NA-LUBE
AW-6220
ISO VG 46 * +
ISO VG 46 +
ISO VG 46 +
ISO VG 46 +
100 ppm Sulfur**
100 ppm Sulfur
100 ppm Sulfur
100 ppm Sulfur
Steel Corrosion
(ASTM D 665, DIN 51 585) A & B
Fail
Fail
Fail
Pass
Copper Corrosion
(ASTM D 130, DIN 51 759)
3 hours, 100°C
3 hours, 135ºC
24 hours, 135ºC
4a
4b
4b
1b
1b
3b
1b
1b
3a
1b
1b
3a
0.75
0.66
0.71
0.50
Base Oil
Four Ball Wear
(ASTM D 4172)
Scar Diameter (mm)
1 hour, 75°C, 1200 rpm, 40 kgf
* Hydrotreated paraffinic oil (Group II) with less than 0.03% natural sulfur
** Elemental sulfur soluble in Group II oil
*** Dimercaptothiadiazole derivative
NA-LUBE® AW 6000 Series - Ashless Antiwear Additives
Product
 Enhancing the Antiwear Performance of Extreme Pressure Agents
Sulfurized EP agents typically provide very good extreme pressure properties and moderate antiwear
properties when used alone. One of the unique performance characteristics of an amine phosphate, such
as NA-LUBE AW-6010, is the ability to improve the antiwear performance of well selected sulfurized
extreme pressure agents. As depicted below, the addition of 2.0% NA-LUBE AW-6010, reduces the scar
diameter from 0.81 mm to 0.51 mm. However, additional NA-LUBE AW-6010 to approximately 6% is
required to return the weld load back to the starting level of >300 kgf.
Different Levels of NA-LUBE AW-6010 in Group II Oil containing 10% NA-LUBE EP-5218
0.9
350
0.8
300
0.6
200
0.5
150
0.4
0.3
100
Weld
0.2
Wear
50
0.1
0
0%
1%
2%
3%
4%
5%
6%
7%
8%
Average Scar
Diameter (mm)
0.7
250
Weld Load (kgf)
NA-LUBE® AW 6000 Series - Ashless Antiwear Additives
NA-LUBE AW-6010 in Combination with NA-LUBE EP-5218
9%
0
10%
% NA-LUBE AW-6010
 Antiwear Performance with Grease
The following table shows the performance of NA-LUBE AW-6110, AW-6110P, and AW-6220 in a lithium
12-hydroxystearate grease.
Tests
AW-6110
AW-6110
AW-6110P
AW-6110P
AW-6220
0.50
1.0
0.50
1.0
1.0
Li-12-OH
Li-12-OH
Li-12-OH
Li-12-OH
Li-12-OH
Distilled Water
0
0
0
0
0
5% Synthetic Sea Water
0
0
0
0
0
0
0
0
0
0
0.44
0.44
0.37
0.34
0.36
Treat Level, %
Grease
EMCOR (ASTM D 6138, IP 220)
Static Water Test
DIN 51 807
Color Change, 40ºC
Four Ball Wear
ASTM D 2266
1 hour, 75ºC, 40kgf, 1200 rpm (mm)
NA-LUBE AW 6000 Series: Ashless Dialkyldithiophosphate
Description
Functions
NA-LUBE AW-6330
Multifunctional additive with excellent extreme pressure/antiwear and antioxidation
properties. Can be used as an ashless alternative to zinc dialkyldithiophosphates in
industrial lubricants, greases, and metalworking fluids.
EP/AW, AO, CI
NA-LUBE AW-6335
Additive with excellent extreme pressure/antiwear properties. Can be used as an
ashless alternative to zinc dialkyldithiophosphates in industrial lubricants, greases,
and metalworking fluids.
EP/AW
 NA-LUBE AW-6330 as an Ashless Alternative to Zinc Dialkyldithiophosphates
NA-LUBE AW-6330 Comparison to ZnDTP
As shown below, NA-LUBE AW-6330 is an excellent ashless altenative to zinc dialkyldithiophosphates. It offers
outstanding performance in Group I, II, and synthetic base stocks.
1.0%
AW-6330
Tests
1.0%
ZnDTP*
Base Oil
1.0% AW-6330
0.35% Blend**
1.0% ZnDTP
0.35% Blend**
ISO VG 46 (Group I)
Steel Corrosion (ASTM D 665, DIN 51 585) A & B
Pass
Pass
Pass
Pass
42-38-0
5
41-39-0
10
42-38-0
5
43-35-2
30
Copper Corrosion (ASTM D 130, DIN 51 759)
3 hours, 100°C
3 hours, 135°C
2a
2a
2a
2a
1b
1b
1a
-
FZG A/8.3/90 (ASTM D 5182, DIN 51 354 Part 2)
Damage Load Stage
12
12
12
12
0.42
-
0.37
-
0.54
0.45
Demulsibility (ASTM D 1401, DIN 51 599)
Oil-Water-Emulsion
Separation Time (Minutes)
Four Ball Wear (ASTM D 4172)
1 hour, 75°C, 1500 rpm, 30 kgf, Scar Diameter (mm)
1 hour, 75°C, 1800 rpm, 40 kgf, Scar Diameter (mm)
* ZnDTP based on 2-ethylhexanol (stabilized)
** 0.35% Blend of yellow metal deactivator, aminic, and phenolic antioxidants
NA-LUBE AW 6000 Series: Multifunctional AW Packages
Product
Description
Functions
NA-LUBE AW-6310
Multifunctional composition with excellent extreme pressure/antiwear properties, excellent rust protection, yellow metal deactivating functionality, and demulsification
AW, CI, YMD
properties. Imparts outstanding FZG performance (higher than 12 load stages) at
low treat levels (0.15 – 0.20%).
NA-LUBE AW-6360
Multifunctional additive with excellent extreme pressure/antiwear and outstanding
steel corrosion inhibiting properties.
EP/AW, CI
 Performance of the Unique NA-LUBE AW-6310
NA-LUBE AW-6310 is an innovative extension of the other NA-LUBE AW products. It is a proprietary
composition containing unique sulfur/phosphorus/nitrogen chemistries. NA-LUBE AW-6310 exhibits the
following properties:
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Superior FZG performance
Outstanding rust inhibition
Excellent demulsification
Good hydrolytic stability
Good thermal stability
Outstanding synergy with the NA-LUBE AO Series
Excellent solubility in a wide range of base oils, including some silicon fluids
NA-LUBE® AW 6000 Series - Ashless Antiwear Additives
Product
 Performance of NA-LUBE AW-6310
NA-LUBE® AW 6000 Series - Ashless Antiwear Additives
NA-LUBE AW-6310 is used in screw compressor oils, railroad type non-mineral oil (Group V) greases,
industrial gear oils, and automotive gear oils. It can also be used for formulating extremely effective ashless HF-2 type hydraulic fluids as shown below.
0.15% NA-LUBE AW-6310
0.20% NA-LUBE AO-210
0.10% NA-LUBE AO-130
0.03% K-CORR NF-200
Tests
Base Oil
ISO VG 46 (Group II)
Demulsibility (ASTM D 1401, DIN 51 599)
Oil-Water-Emulsion
Separation Time (Minutes)
40-40-0
10
Steel Corrosion (ASTM D 665, DIN 51 585) A & B
Pass
AFNOR Wet Filtration (E 68691)
Filterability Index
1.17
Copper Corrosion (ASTM D 130, DIN 51 759)
3 hours, 100°C
3 hours, 135°C
1b
1b
FZG A/8.3/90 (ASTM D 5182, DIN 51 354 Part 2)
Damage Load Stage
>12
CM Thermal Stability (ASTM D 2070)
CM Color Class: Copper
Steel
Viscosity Change, %
Acid Number Change (mg KOH/g)
Total Sludge (mg/100 ml)
5
3
0.51
0.03
14.80
Hydrolytic Stability (ASTM D 2619)
Copper Loss (mg/cm²)
Total Acidity of Water Layer (mg KOH)
Copper Appearance (ASTM D 130)
0.00
3.47
3b
 Performance of NA-LUBE AW-6310 in Grease
NA-LUBE AW-6310 also exhibits very good performance in greases. The table below depicts the performance of NA-LUBE AW-6310 in a synthetic lithium complex grease and a lithium 12-hydroxystearate
grease.
Tests
Treat Level, %
Base Grease
Without Additive
AW-6310
Without Additive
AW-6310
—
2.0
—
1.5
Synthetic Lithium Complex
Test Water
Lithium 12-OH
5% Synthetic Sea Water
EMCOR Rust Test (ASTM D 6138, IP 220)
2,2
0,0
3,3
0,0
Four Ball Wear (ASTM D 2266)
1 hour, 75˚C, 40 kgf, 1200 rpm
Scar Diameter (mm)
0.73
0.48
0.92
0.48
1b
1b
1b
1b
1b
1b
1b
1b
Copper Corrosion
(ASTM D 130, DIN 51 759)
3 hours, 100°C
3 hours, 135°C
 Performance of NA-LUBE AW-6310 in Synthetic Fluids
Tests
0.30% NA-LUBE AW-6310
1.05% NA-LUBE AO-130
0.30% NA-LUBE AO-242
0.09% KX1112
0.06% K-CORR NF-200
Base Oil
78.5% PAO 300
21.5% NA-LUBE KR-015 (Alkylated Naphthalene)
Demulsibility (ASTM D 1401, DIN 51 599)
Oil-Water-Emulsion
41-38-1
Time (minutes)
Steel Corrosion (ASTM D 665, DIN 51 585)
A&B
Pass
Four Ball Wear (ASTM D 4172)
1 hour, 25ºC, 30 kgf, 1500 rpm
Scar Diameter (mm)
0.40
RPVOT (ASTM D 2272)
Lifetime (minutes)
FZG A/16.6/90 (ASTM D 5182, DIN 51 354 Part 2)
Damage Load Stage
Oxidation Stability (ASTM D 2893)
312 hours @ 150°C
Viscosity Increase
1000 Hours Oil Sludge
Sludge (mg)
20
1525
>12
8.10%
139
 Performance of NA-LUBE AW-6360
NA-LUBE AW-6360 can be used to formulate various types of transmission fluids.
0.48% NA-LUBE AW-6360
1.00% Ashless FM
Tests
FZG A/8.3/90 (ASTM D 5182) (DIN 51 354 Part 2)
Damage Load Stage
0.50% Dispersant
0.75% AO (phenolic/aminic)
10.00% Ester
87.27% PAO 6
>12
FE8 Bearing Wear Test (DIN 51819 T1-T3)
Load (kN)
Speed (rpm)
Test Duration (hours)
Temperature (ºC)
80
7.5
80
80
Roller Wear (mg)
Cage Wear (mg)
6.9
64
Rust Test (ASTM D 665B)
Demulsibility (ASTM D 1401)
Oil-Water-Emulsion
Time (minutes)
RPVOT (ASTM D 2272)
Lifetime (minutes)
Pass
40-40-0
15
530
NA-LUBE® AW 6000 Series - Ashless Antiwear Additives
NA-LUBE AW-6310 can be formulated with other King Industries additives to impart excellent performance
using synthetic fluids, including NA-LUBE KR alkylated naphthalenes.
Applications for the NA-LUBE® AW 6000 Series
Because of their multifunctionality, the NA-LUBE AW 6000 Products are used in:
 Screw Compressor Oils

NA-LUBE AW-6310 is strongly recommended for high performance screw compressor oils.
 Rust and Oxidation Oils
 Automotive Gear Oils
 Industrial Gear Oils


NA-LUBE AW-6110 in combination with well selected sulfur carriers (SIB technology/
sulfurized esters) has proven to be an excellent antiwear additive for formulating industrial
gear oils requiring excellent performance in the FAG-FE8 test.
NA-LUBE AW-6310 is strongly recommended for industrial gear oils.
 Automatic and Manual Transmission Fluids
 Slide Way Oils
 Hydraulic Fluids

NA-LUBE AW-6310 is strongly recommended for ashless HF-2 type hydraulic fluids.
 Greases
 Food Grade Lubricants

NA-LUBE AW-6400FG is NSF HX-1 registered and complies with FDA 21 CFR 178.3750.
 “Neat Oil” Metalworking Fluids


The NA-LUBE AW 6000 Series can also be used in combination with the NA-LUBE EP
5000 Series for formulating heavy-duty chlorine-free “neat oil” metalworking fluids.
NA-LUBE AW-6010 and AW-6220 are specifically designed for “neat oil” metalworking
fluids, such as high-speed grinding fluids based on mineral oil or synthetic esters.
 Multifunctional Fluids (Hydraulic/Metalworking Fluids)

NA-LUBE AW-6310 in combination with inactive sulfurized products and aminic/phenolic
antioxidants can be used to formulate multifunctional fluids (hydraulic fluid/metalworking
fluid) based on Group I-V base oils, including canola and sunflower oils.
King Industries, Inc - USA
Lubricant Additives Division
Science Road
Norwalk, CT 06852
Phone (203) 866-5551
Email: info@kingindustries.com
King Industries - Europe
Dr. Dagmar Gartz
Noordkade 64
2741 EZ Waddinxveen
The Netherlands
Phone: +31 182-631360
Email: dgartz@kingindustries.com
King Industries - Asia
www.kingindustries.com
Dr. Zhiqiang Alex He
42 Ju Lin Ya Yuan
Rich Mond Hill (Juhaoyuan)
Bo Ai 7th Road
Zhongshan, Guangdong, China 528403
Phone: +86 760-88229866
Email: alex.he@kingindustries.com
11/2013
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