WHY WOULD ANYONE NOT GALVANIZE STEEL IF THEY CAN? Francis Gerace, P.E., Market Development Hubbell Galvanizing New York Mills, NY November 30,2010 Abstract: There are many products which protect structural steel from corrosion. There is also an intense focus on sustainability. Hot-dip galvanizing is one product that provides economical, long-lived, and sustainable corrosion protection. It is also more durable than most other barrier systems. Not all steel can be galvanized because sometimes the elements are too long and/or too heavy to be placed in the baths. Also, at times the intended environment is not conducive for zinc longevity such as acidic environments or immersed in salt water. But for those applications where galvanizing is appropriate, why would anyone not choose to hot-dip galvanize steel? INTRODUCTION In the public sector, most levels of government are feeling budget constraints. In the private sector, most businesses are watching every dollar to insure the “biggest bang for the buck”. Both sectors are very concerned with initial costs. Nevertheless, they are aware of downstream implications on operational and maintenance costs as well. Both initial and life cycle impacts are being taken into account when deciding on capital investments. In addition, with the growing consciousness of our surroundings and the effect we are having on the environment, there is also an intense focus on sustainability. Steel is one of the most economical choices for construction. Compared to other materials, it often provides initial cost savings over competitive materials. However, the use of steel has a major drawback. Left unprotected, it rusts, which shortens its service life. In a 2001 paper, jointly authored by the Federal Highway Administration (FHWA) and the NACE International, the total annual direct cost of corrosion was estimated at $121 billion, which is 1.38 percent of the U.S. GDP of $8.79 trillion in 1998. The largest portion (88.3 percent) of this cost is the organic coatings group at $107.2 billion. Galvanizing and metalizing accounted for $1.4 billion.1 Corrosion most often affects metal structures such as bridges, steel reinforced concrete, storage tanks, and pipelines. Corrosion problems often are not obvious but can lead to extensive structural failure and loss of capital investment. As the average age of facilities and structures continues to rise, corrosion problems will inevitably worsen. However, related expenses can be minimized by using proven technologies in the design, construction installation, maintenance, and repair of structures.2 However, these technologies have a cost, both initial and cyclical. In order to achieve economic and sustainable goals, enterprises are seeking solutions that are low in initial costs, low in cost over the life of the element, have extended service life, and have a minimum effect on the environment. Hot-dip galvanizing (HDG) is one product that protects steel from corrosion while providing economical, long-lived, and sustainable corrosion protection. It is also more durable 1 “Corrosion Costs and Preventive Strategies in the United States”, Publication No. FHWA-RD-01-156, 2001 2 “Corrosion and Corrosion Control” By Jorge E. Costa and Leandro Etcheverry Concrete Repair Bulletin, September/October 2005 Why Would Anyone NOT Galvanize Steel If They Can? Francis Gerace, P.E., Market Development Hubbell Galvanizing than most other barrier systems. In this paper we will examine the protective qualities of HDG. We will also explore the economics, both initial and life-cycle costs, of using HDG compared to competitive materials. Finally we will look at the effect of HDG on the environment and address the sustainability of HDG in comparison to paint, the most common alternative to HDG for steel corrosion protection. It is a fact not all steel can be galvanized; members may be too long or too heavy. But for those elements that can be, why would anyone not choose to galvanize steel? PROTECTIVE QUALITIES OF HDG There is a common perception that Hot-dip galvanizing protects steel by providing a sacrificial coating on the steel surface. Many also perceive the main benefit of HDG to be that the zinc provides cathodic protection, since zinc will corrode before iron. While these both are true, the main benefit of HDG is it presents an extremely robust barrier between the steel and the environment. Metal corrosion can be defined as the destructive attack of a metal through interaction with its environment.3 Metals are defined as being capable of conducting heat and electricity. Metals have free electrons which have the potential to move between positively charged areas (anode) to negatively charged areas (cathode) within the Cathode Electrolyte structure of the metal. However, this movement is possible only through the presence of an electrolyte which transfers the electrons on the surface, resulting in corrosion. In the schematic, The Anode Corrosion Triangle, electrons migrate within the metal through an electron path from anodic areas to The Corrosion Triangle cathodic areas. The circuit is completed by the return current path provided by the electrolyte. . The most common method of corrosion protection is to isolate the metal from the electrolyte. This is done by creating a barrier between the two. Once the electrolyte is separated from the metal, the circuit is broken and no corrosion can take place. Corrosion protection is afforded as long as the barrier remains intact. Should the barrier be breached, corrosive attack of the underlying metal will take place. In the case of steel, barrier breaches create pockets of oxidation, i.e. rust. Since rust is more voluminous than iron, pressure is created as the rust expands. The breach then expands and is further exploited, lifting and undercutting the surrounding barrier allowing more exposure to the electrolyte and compounding the corrosion. 3 Fundamental of Corrosion Chemistry "Corrosion Control", NAVFAC MO-307, September 1992 <http://www.corrosionist.com/Corrosion_Fundamental.htm> (accessed September 1, 2010) Page 2 of 12 Why Would Anyone NOT Galvanize Steel If They Can? Francis Gerace, P.E., Market Development Hubbell Galvanizing Soon the barrier becomes compromised and results in section loss and the ultimate failure of the member. Remedies for barrier compromise are: the installation of a robust barrier that is resistant to breaching; providing a barrier that is extremely adherent to the steel to minimize undercutting of the barrier should a breach occur; and strict adherence to a cyclic preventive maintenance regiment to insure barrier integrity. Hot-dip galvanized steel addresses all of those remedies: the galvanized coating is extremely hard and durable; the galvanized coating is metallurgically bonded to the steel; and finally, the coating is extremely durable. We will examine each of these attributes in the following sections. The Galvanizing Process and Zinc Coating The galvanizing process is a documented, timed sequence and is done in a controlled environment, outside weather conditions are not a factor. Galvanizing is a process where, after preparatory steps (degreasing, acid cleaning, and fluxing), clean, bare steel is submerged in molten zinc. Galvanizing is complete when the temperature of the steel equalizes with the temperature of the molten zinc, typically 830 °F or higher (435 °C +) with the observable formation of a metallurgical bond of the zinc to the steel. The bond is extremely tenacious, with strip strength of greater than 3,000 psi. (This is in contrast with other barrier systems with strip strengths of approximately 600 psi.) In addition to the metallurgical bond, three alloy layers and a layer of pure zinc form. A micrograph of the zinc layer is shown below. As can be seen, the inter-metallic layers are composed of various percentages of iron and zinc. Using the diamond pyramid number (DPN) hardness scale, it can be seen that these layers are harder than the base steel. When coupled with the ductility of the pure zinc Eta layer, the result is a very hard, durable coating that resists breaching. While the coating can be removed by abrading, blasting or similar actions, the coating stands up to normal handling during construction without damage. Page 3 of 12 Why Would Anyone NOT Galvanize Steel If They Can? Francis Gerace, P.E., Market Development Hubbell Galvanizing The Longevity of Galvanized Coatings While the galvanized coating is unaffected by ultraviolet ray exposure, the corrosion rate of zinc is directly influenced by atmospheric conditions. Certain factors that specifically affect the corrosion of zinc include: temperature, humidity, rainfall, sulfur dioxide (pollution) concentration in the air, and air salinity. None of these factors can be singled out as the main contributor to zinc corrosion, but they all play a role in determining the corrosion protection hotdip galvanized (zinc) coatings can provide in certain environments. 4 For corrosion classification purposes, atmospheres are generally divided into five groups rural, suburban, temperate marine, tropical marine, and industrial. Rural environments are usually the least aggressive of the five atmospheric types. This is primarily due to the relatively low level of sulfur and other emissions found in such environments. Suburban atmospheres are, as the term suggests, found in the largely residential, perimeter communities of urban or city areas with little or no heavy industry. Temperate marine atmospheres are influenced by proximity to the coastline and prevailing wind direction and intensity. In marine air, chlorides from sea spray can react with the normally protective zinc corrosion products to form soluble zinc chlorides. When these chlorides are washed away, fresh zinc is exposed to corrosion. Temperate marine atmospheres usually are more corrosive than suburban atmospheres. Tropical marine atmospheres are similar to temperate marine atmospheres except they are found in warmer climates. Tropical marine climates tend to be somewhat more corrosive than temperate marine climates. Finally, industrial environments are generally the most aggressive in terms of corrosion. Air emissions may contain some sulfides and phosphates that cause the most rapid consumption of the zinc coating. Automobiles, trucks, and industrial plant exhaust are examples of these emission sources. Most city or urban area atmospheres are classified as industrial. Independent and industry testing of galvanized steel samples over decades in industrial, urban, rural, and marine environments, with varying degrees of chlorides, sulfides and other corrosive elements, has yielded performance data for galvanized steel in real world applications. This data is portrayed in the Time to First Maintenance chart. The chart is a plot of the data accumulated Time to First Maintenance 4 Galvanizing Performance in the Atmosphere American Galvanizer’s Association, n. d. http://www.galvanizeit.org/aga/about-hot-dip-galvanizing/how-long-does-hdg-last/in-the-atmosphere accessed September 1, 2010 Page 4 of 12 Why Would Anyone NOT Galvanize Steel If They Can? Francis Gerace, P.E., Market Development Hubbell Galvanizing from galvanized steel samples performance in real-world applications. The chart was generated for the various environments listed above from the Zinc Coating Life Predictor5 developed by Dr. X. G., Zhang, Ph.D. of Teck Cominco Metals Ltd. for the International Zinc Association. The predictor performs calculations based on models developed using statistical methods, neural network technology, and an extensive corrosion database. The resulting chart estimates the anticipated time to first maintenance for HDG steel of varying coating thicknesses in a wide array of environments. First maintenance is when there is 5% red rust evident on the substrate steel. Options at that point are: touchup via one of the methods specified in ASTM A780 Practice for Repair of Damaged and Uncoated Areas of Hot-Dip Galvanized Coatings, painting or, if the feature can be taken out of service, re-galvanizing. Cathodic Protection In addition to the protection afforded by a superb barrier provided by the HDG coating, the presence of zinc in contact with iron provides cathodic protection from corrosion which means zinc will preferentially corrode to protect the underlying base steel. The Romans were aware of the protective qualities of zinc, with the first recorded use of zinc as a construction material in 79 A.D. The table on the left shows a series of metals arranged in order of electrochemical activity in seawater (the electrolyte). This arrangement of metals determines what metal will be the anode and cathode when the two are put in an electrolytic cell. Metals higher on the scale provide cathodic or sacrificial protection to the metals below them. Therefore, zinc protects steel. The scale indicates magnesium, aluminum, and cadmium also should protect steel. In most normal applications, magnesium is highly reactive and is too rapidly consumed. Aluminum forms a resistant oxide coating and its effectiveness in providing cathodic protection is limited. Cadmium provides the same cathodic protection for steel as zinc, but for technical and economic reasons, its applications are limited. Since zinc is anodic to steel, the galvanized coating will provide cathodic protection to exposed steel as well. When zinc and steel are connected in the presence of an electrolyte, the zinc is slowly consumed while the steel is protected. The zinc’s sacrificial action also offers protection where small areas of steel may be exposed due to cut edges, drill holes, scratches, or as the result of severe surface abrasion during rough handling or job site erection. Cathodic protection of the steel from corrosion continues until all the zinc is consumed. 5 “Zinc Coating Life Predictor”, Dr. X. G. Zhang, teckcominco and International Zinc Association, 2002 <http://www.galvinfo.com:8080/zclp/> accessed September 10, 2010 Page 5 of 12 Why Would Anyone NOT Galvanize Steel If They Can? Francis Gerace, P.E., Market Development Hubbell Galvanizing Zinc Patina As with many metals, the outer, pure zinc layer passivates over time with the formation of a patina. Passivation is the spontaneous formation of a hard non-reactive surface film that inhibits further corrosion. The galvanized outer surface converts from pure zinc to zinc oxide immediately after removal from the zinc bath and exposure to oxygen. After a few days, depending on humidity and storage, exposure to moisture converts the zinc oxide coating to zinc hydroxide. This coating develops over months and after exposure to carbon dioxide, the zinc hydroxide coating converts to zinc carbonate. This is the final patina film and it is a thin, compact and tightly adherent layer of corrosion products consisting mainly of basic zinc carbonate. Zinc carbonate is flannel grey in color. (All galvanized product, whether shiny or dull as it is removed from the kettle, turns grey after six months to a year.) The final patina is passivated and serves to retard further corrosion. The final rate of corrosion of the zinc patina is considerably below that of ferrous materials, some 10 to 100 times slower, depending upon the environment. The patina is stable and non-reactive unless exposed to aggressive chlorides or sulfides, and is a key component to HDG’s long life. The result is a long-lived barrier and cathodic coating protecting the steel for decades. Long Lasting Protection Working together, the three factors provide galvanizing its long-lasting protection because: • The zinc coating acts as a barrier against the penetration of water, oxygen, and atmospheric pollutants. • The zinc coating cathodically protects the steel from coating imperfections caused by accidental abrasion, cutting, drilling, or bending. • The zinc carbonate patina is passive, which slows the corrosion rate of the zinc.6 Additional Benefits of HDG7 In addition to barrier and cathodic protection, there are several other beneficial characteristics of the HDG. These include complete coverage and edge protection. Complete Coverage: Because the galvanizing process involves total immersion of the material into cleaning solutions and molten zinc, all interior and exterior surfaces are coated. 6 7 “Galvanize It! Seminar”, American Galvanizer’s Association, 2009 “Galvanize It! Seminar”, American Galvanizer’s Association, 2009 Page 6 of 12 Why Would Anyone NOT Galvanize Steel If They Can? Francis Gerace, P.E., Market Development Hubbell Galvanizing This includes the insides of hollow and tubular structures, and the threads of fasteners. Complete coverage is important because corrosion tends to occur at an increased rate on the inside of some hollow structures where the environment can be extremely humid and condensation occurs. Hollow structures that are painted have no corrosion protection on the inside. Additionally, fasteners with no protection on the threads are susceptible to corrosion, and corroded fasteners can lead to concerns about the integrity of structural connections. Edge Protection: As depicted in the photomicrograph of a cross-section of the edge of a galvanized part, the galvanizing process naturally produces coatings at least as thick at the corners and edges as the coating on the rest of the part. This is because the reaction between iron and zinc is a diffusion reaction and thus the crystalline structure of the coating forms perpendicular to the steel surface. As coating damage is most likely to occur at the edges, this is where added protection is needed most. Brush- or spray-applied coatings such as paints have a natural tendency to thin at corners and edges. WHEN GALVANIZING MAY NOT BE APPROPRIATE Large steel elements do not lend themselves easily to galvanizing. The average kettle size in the US is approximately 40 feet. Nevertheless, galvanizing plants capable of galvanizing pieces 95 feet long and weighing 55,000 pounds are available. Architects/Engineers should explore kettle capacities before specifying HDG to examine the economics of the coating. In addition, certain environments are not conducive to HDG longevity. Factors such as pH have a profound effect on HDG life. When galvanized steel is used in contact with liquids, a different set of conditions determines its resistance. A liquid’s degree of acidity or alkalinity is the factor of greatest importance. Zinc coatings dissolve in liquids with a pH below 4.5 or above 12.5. This should not be considered a hard and fast rule because such factors as agitation, aeration, temperature, polarization, and the presence of inhibitors may also change the rate of corrosion. However, generally at intermediate pH values, a protective film is formed on the zinc surface and the rate of corrosion is very slow. Since many liquids fall within this pH range, galvanized steel containers are widely used in storing and transporting many chemical solutions. Galvanizing is successfully used to protect steel in fresh water exposure. “Fresh water” is used loosely here to refer to all forms of water except sea water. Water with relatively high free oxygen or carbon dioxide content is more corrosive than water containing less of these gases. Hard water is much less corrosive toward zinc than soft water. Galvanized coatings provide considerable protection to steel when immersed in sea water and exposed to salt spray. However, it is the dissolved salts (primarily sulfides and chlorides) in Page 7 of 12 Why Would Anyone NOT Galvanize Steel If They Can? Francis Gerace, P.E., Market Development Hubbell Galvanizing sea water that are the prime determinants of the corrosion behavior of the zinc immersed in sea water. Other negative factors are water temperature and the amount of oxygen in the water. Although anticipated galvanized coating life is shorter in sea water than in many other exposures, galvanizing performs much better than many other coating systems in this environment. The negative effects of extreme pH values, sulfides and chlorides may be ameliorated by application of a duplex coating over the zinc surface. This coating, usually a zinc compatible paint or powder coating retards the deterioration of the zinc, extending longevity by one and one half to two times the expected life under harsh conditions. Welding galvanized surfaces directly is not recommended due to health and safety concerns. However, welding galvanized steel without removing the surrounding zinc coating can be accomplished provided the welder is experienced in doing so. Special breathing apparatuses and/or adequate ventilation must be in place to avoid inhalation of zinc fumes. Nevertheless, the American Welding Society recommends removing the galvanized coating 2 to 4 inches way from the weld area. The damaged area (caused by the burn of the weld torch) can be repaired using one of the accepted touch-up and repair compounds listed in ASTM A 780, which is the specification that governs repair of galvanized articles. It is also important to mention that when welding galvanized steel the surrounding coating in the Heat Affected Zone (HAZ) may be damaged from the heat applied by welding. Repair work may be necessary to remediate these areas to ensure the corrosion protection is not compromised. HOT-DIP GALVANIZING COSTS LESS We have discussed how HDG protects against corrosion, and how long it will last. The next area to explore is cost in relation to other coatings. Many people have heard galvanizing is a logical choice when looking at cost from a life-cycle basis; however, there is a common misconception galvanizing is cost-prohibitive on an initial basis. The following will provide a cost comparison of hot-dip galvanizing to a number of common paint systems on both an initial and life-cycle basis. Initial costs for paint systems include four components: material, shop cleaning labor, shop/field application, and field labor. All of these costs are included in the initial price for galvanizing as the cleaning process is a built-in part of the galvanizing process. The following table shows various paint systems and the equivalent cost of HDG for a typical project. The data sources (costs, time to first maintenance based on in-field performance) for the paint systems are from KTA Tator, Inc., NACE Paper Number 08279 (2008). HDG costs were derived from the American Galvanizers Association National Survey (2009). Project parameters are a structure less than 50 feet high; 100,000 ft2 to be coated consisting of a typical medium structural shapes (200 ft2/ton); and the corrosion environment is moderate industrial (C3). For the life-cycle cost analysis, a 7% interest rate was assumed with 4% inflation and a 35 year service life. Performing economic analyses including initial and life-cycle assessments can Page 8 of 12 Why Would Anyone NOT Galvanize Steel If They Can? Francis Gerace, P.E., Market Development Hubbell Galvanizing be a difficult and cumbersome practice, but the online calculator www.galvanizingcost.com8 was used to automate the process. Economic Analysis Project Size 100,000SF Coating System Initial Cost 2 /ft Initial Project Cost $125,000 $220,000 LifeCycle Cost/ 2 ft $4.74 $2.20 LifeCycle Project Cost $474,000 $220,000 Initial Project Difference to HDG ($95,000) $0 Life Time Project Difference to HDG $254,000 $0 Inorganic Zinc HDG Inorganic Zinc primer/ Epoxy top coat Acrylic WB primer/ midcoat/ topcoat Epoxy zinc primer/Epoxy midcoat/Polyurethane topcoat $1.25 $2.20 $2.15 $214,800 $4.56 $456,000 ($5,200) $236,000 $2.69 $269,000 $7.01 $701,000 $49,000 $481,000 $3.30 $330,100 $5.13 $513,000 $101,000 $293,000 As mentioned before, it is not recommended to analyze only the initial cost for a corrosion protection system. However, if initial cost is the only analysis, galvanizing is still a solid choice, as it is initially less expensive than all but the minimal protection the one-coat inorganic zinc paint system provides and competitive when an epoxy top coat is added to the primer. Smaller projects with many components and light structural steel sections will yield an initial galvanizing cost lower than most paint systems, as the galvanizing process efficiently accommodates bundles and groups of steel. Economic Analysis Project Size 10,000SF 8 Coating System Initial Cost 2 /ft Inorganic Zinc HDG Inorganic Zinc primer/ Epoxy top coat Acrylic WB primer/ midcoat/ topcoat Epoxy zinc primer/Epoxy midcoat/Polyurethane topcoat $1.44 $1.76 Initial Project Cost $14,400 $17,600 LifeCycle Cost/ 2 ft $3.99 $1.76 LifeCycle Project Cost $39,900 $17,600 Initial Project Difference to HDG ($3,200) $0 Life Time Project Difference to HDG $22,200 $0 $2.47 $24,702 $6.01 $60,100 $7,102 $42,500 $3.10 $30,970 $8.07 $80,700 $13,370 $63,100 $3.80 $37,960 $5.90 $59,000 $20,360 $31,400 Galvanizing Cost Life-Cycle Cost Calculator,< www.galvanizingcost.com>, American Galvanizer’s Association, 2010 Page 9 of 12 Why Would Anyone NOT Galvanize Steel If They Can? Francis Gerace, P.E., Market Development Hubbell Galvanizing When life-cycle costs are considered, hot-dip galvanizing is the most economical system for corrosion protection. In fact, this analysis does not even include the hidden (or indirect) costs associated with paints when there is loss of use, traffic delays that may result when a bridge or road is closed or partially closed, and interruption of local commerce. Also, if deviations from the practical paint maintenance schedule used in the analysis above occur, life-cycle costs could be significantly higher than indicated. Sustainability There is a growing awareness of how our actions impact our surroundings and the environment, as well as the future implications of those actions. A commonly accepted definition of sustainable development (SD) is the social, economic, and environmental commitment to growth and development that meet the needs of the present without compromising the ability of future generations to meet their own needs. There are a number of systems used to measure how sustainable a product or process may be, and they are often highly subjective. Some systems such as LEED® presented by the US Green Building Council are prescriptive in that they assign values through a rigid formulation to assess the achievement towards meeting goals in prescribed categories. HDG, at 30% recycled content, contributes to LEED® credit in the Materials and Resources category since it contains so much recycled content. However, other methods such as Life Cycle Inventory (LCI) and Life Cycle Assessment (LCA) are more analytical and serve to assist designers and specifiers as to the effect of choices of materials on the environment. LCI is the study and measurement of the material flows, energy flows, and environmental releases for the production of a defined amount of a product. LCI does not consider energy consumed or environmental impact during use or end-of-life. It can be described as a cradle to gate analysis. In other words, it is the impact of preparing a material for construction. LCA goes beyond the manufacture of material and is a standardized scientific method for the systematic analysis of all mass and energy flows as well as environmental impacts attributed to a product system, from raw material acquisition to end-of-life management. LCA includes a product’s LCI as well as the downstream impacts of operations and maintenance and disposal at the end of the element’s life. As a part of the Zinc for Life program, the International Zinc Association (IZA) sponsored a study of the LCI and LCA of hot-dip galvanized steel by Five Winds International and PE International. Galvanizing data was collected from: the American Galvanizers Association (AGA), the European General Galvanizing Association (EGGA), the Galvanizers Association of Australia, and the Hot-Dip Galvanizers Association of South Africa. The study examined four criteria with which the LCI and LCA of Hot-Dip Galvanizing can be measured Primary Energy Demand (PED), the total energy consumed; Global Warming Potential (GWP), the Carbon footprint; Page 10 of 12 Why Would Anyone NOT Galvanize Steel If They Can? Francis Gerace, P.E., Market Development Hubbell Galvanizing Acidification Potential (AP), the creation of acid rain; Photochemical Ozone Creation Potential (POCP), the creation of smog. Using the above criteria and Complete PED GWP AP (SO2 POCP (C2H2 defining universal boundary LCA (CO2 equiv.) equiv.) conditions, the net effect of equiv.) 1 kg of HDG on the environment was 1 kg of HDG 17.3 MJ 1.80 kg 0.00615 kg 0. 000824 kg determined and is shown.9 † PED (primary energy demand) reflects production, use, and end-of-life The term net effect is used credit. because the LCA considered the entire life of HDG. At the end of life both the steel and zinc are 100% recyclable and are reclaimed with no loss of physical properties. Thus there is a credit assigned to the PED as it takes less energy to produce recycled HDG steel than from virgin sources. † There is a procedure defined by ISO to address the differences between competitive materials. In this case, the difference between HDG and paint on the environment would require both industries to reconcile parameters, boundary conditions, methods of measurement, etc. While there has been no such agreement, some conclusions can be made regarding the differences between the two on a qualitative basis. First, steel is the primary component for both LCA’s. Steel’s high recyclability and low environmental impact have large impact on LCA numbers. Nevertheless, a galvanized coating provides more advantages since there are no additional direct or indirect environmental costs during use since there is zero maintenance. Also, the zinc coating is recycled during end-of-life phase, leaving no permanent waste. However, painted steel will produce additional environmental costs because it will require regular maintenance on a predetermined cycle of 12 to 20 years. At the end of life, steel is the primary component recovered, whether it is galvanized or painted. However, unlike the recyclable zinc of the galvanized coating, the paint coating will become a permanent part of the waste stream. Nevertheless, there have been quantitative comparative studies done. VTT Technical Research in Finland conducted a life-cycle assessment study for a hot-dip galvanized balcony system compared with an identical constructed painted balcony system10. That study quantified the principal environmental impacts for a galvanized steel balcony and painted balcony. For the impact categories discussed above, the efficiency and durability of the galvanized balcony 9 “Hot-dipped Galvanizing is Green”, <http://www.galvanizeit.org/images/uploads/publicationPDFs/HDG_is_Green_Email.pdf>, the American Galvanizer’s Association, 2009 10 "Life-cycle Assessment Study for Hot-dip Galvanized Balcony System Compared with Painted Balcony System", VTT Technical Research Centre of Finland, April 2004 Page 11 of 12 Why Would Anyone NOT Galvanize Steel If They Can? Francis Gerace, P.E., Market Development Hubbell Galvanizing provided for significantly lower life-cycle environmental indicators than the painted system balcony. So, of the two barrier systems, galvanizing, or paint, HDG is the sustainable choice. In the production phase 30% of all zinc is from recycled sources. During the use phase, HDG is maintenance free and has no energy requirements, effectively a zero impact on the environment. Finally, at the end of life, 80% of all remaining zinc HDG products are reclaimed and put back to use with no degradation of mechanical and physical properties. With paint systems, by contrast, the amount of recycled material during the production phase is unknown, the required cyclical repainting represents an environmental impact, and at the end of life the spent paint is landfilled CONCLUSION From the above, Hot-dip galvanizing is clearly a superb corrosion protection system for steel. As a barrier from electrolytes, the coating has a metallurgic bond with 3000 psi strip strength, it is unaffected by UV rays, and provides complete coverage and edge protection. The zinc provides cathodic protection, since zinc is more anodic than iron. The galvanized coating provides long lasting protection since the zinc patina passivates the corrosion process. Economically, HDG compares favorably to all but the most simple paint systems on an initial cost basis. Since it is maintenance-free, it outshines all systems on a life-cycle cost basis. Compared to other systems, HDG is sustainable due to its 100% recyclability and its reclamation properties. So, if an element can be galvanized, why would anyone NOT choose HDG for steel corrosion protection? Page 12 of 12